CN105462348A - Plant-oil-based green heat-set ink - Google Patents
Plant-oil-based green heat-set ink Download PDFInfo
- Publication number
- CN105462348A CN105462348A CN201610019841.6A CN201610019841A CN105462348A CN 105462348 A CN105462348 A CN 105462348A CN 201610019841 A CN201610019841 A CN 201610019841A CN 105462348 A CN105462348 A CN 105462348A
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- Prior art keywords
- oil
- plant
- based green
- set ink
- green heat
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
- C09D11/103—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds of aldehydes, e.g. phenol-formaldehyde resins
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/06—Printing inks based on fatty oils
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses plant-oil-based green heat-set ink. The ink is prepared from, by mass, 55-75% of binder, 10-25% of pigment, 0-5% of alkyd resin, 0-5% of plant oil, 0-1% of dispersing agent, 0-2% of wax, 0.5-2% of dryer retarder and 5-10% of plant oil derivative. The binder is prepared from, by mass, 35-45% of rosin modified phenolic resin, 20-35% of plant oil, 10-40% of plant oil derivative and 0-2% of gel. The plant-oil-based green heat-set ink has the set and drying speed the same as and even higher than that of ordinary heat-set ink, has excellent color and luster and is free of petroleum solvent, and lots of recyclable resources are used.
Description
Technical field
The present invention relates to technical field of ink, particularly relate to a kind of heat-set ink.
Background technology
The dried forms of common thermosetting flexographic ink is the combination drying form of permeating set and having oxypolymerization and partial solvent vaporization at high temperature to combine: ink printing is on paper, solvent penetration is in the pore of paper, resin is separated out and set, dry vegetable oil in binder and chain polymer thereof are cross-linked into reticulated structure macromole through oxygenizement, printed matter is by high temperature drying tunnel, utilize vaporization at high temperature partial solvent to accelerate the speed of oxidation filming simultaneously, complete and solidify to form solid-state ink film.Dry vegetable oil in tradition flexographic ink mostly is the dry vegetable oils such as oleum lini, Chinese catalpa oil, tung oil, and diluting solvent is high-boiling point kerosene, and boiling range is between 240 ~ 290 DEG C.The more and more higher traditional heat-set ink of requirement along with environmental protection can not adapt to environmental requirement, although high-boiling point kerosene has made low aromatic hydrocarbons into by the kerosene of high aromatic hydrocarbons or even without aromatic hydrocarbons kerosene in recent years, but kerosene is petroleum chemicals eventually, be Nonrenewable resources.The heat fixed type ink now commercially sold, or traditional heat-set ink based on petroleum solvent, do not have the heatset offset ink of a environment-friendly type without petroleum solvent.In the face of day by day exhausted fossil resources research and development one does not use petroleum solvent, use the heat fixed type ink of a large amount of renewable resources to seem very meaningful, and have certain potential market.
Summary of the invention
The technical problem that the present invention mainly solves is to provide a kind of plant oil based green heat-set ink, possesses even faster set identical with common heat-set ink and rate of drying, has excellent glossiness, without petroleum solvent, and use renewable resources in a large number.
For solving the problems of the technologies described above, the technical scheme that the present invention adopts is:
Thering is provided a kind of plant oil based green heat-set ink, is be prepared from by the composition of following massfraction: binder 55 ~ 75%, pigment 10 ~ 25%, Synolac 0 ~ 5%, vegetables oil 0 ~ 5%, dispersion agent 0 ~ 1%, wax 0 ~ 2%, only dry agent 0.5 ~ 2% and vegetable oil derivatives 5 ~ 10%;
Described binder is prepared from by the composition of following massfraction: the rosin modified phenolic resin of 35 ~ 45%, the vegetables oil of 20 ~ 35%, the vegetable oil derivatives of 10 ~ 40% and the gelifying agent of 0 ~ 2% are prepared from.
In a preferred embodiment of the present invention, described Synolac is long oil alkyd, the Synolac that described Synolac adopts one or more modifications in oleum lini, soya-bean oil, Oleum Cocois, rapeseed oil obtained.
In a preferred embodiment of the present invention, described vegetables oil is that tung oil and dry vegetable oil or semi-drying vegetable oils mix, and described dry vegetable oil comprises oleum lini, perilla oil and Chinese catalpa oil, and described semi-drying oil comprises soya-bean oil, rapeseed oil and Viscotrol C.
In a preferred embodiment of the present invention, described vegetable oil derivatives is the cut cut substrate of soybean oil methyl ester, soya-bean oil ethyl ester, soya-bean oil isobutyl ester, palm oil methyl ester, plam oil ethyl ester, plam oil isobutyl ester, rapeseed methylester, rapeseed oil ethyl ester or rapeseed oil isobutyl ester.
In a preferred embodiment of the present invention, the boiling range of described cut cut substrate between 260 ~ 320 DEG C, pour point below 0 DEG C, cold filter clogging temperature is below 0 DEG C.
In a preferred embodiment of the present invention, described gelifying agent is aluminum chelate, and described aluminum chelate is the derivative of n-butoxy aluminium, isobutoxy aluminium or secondary butoxy aluminium.
In a preferred embodiment of the present invention, described pigment comprises fuchsin, Phthalocyanine Blue BGS, diarylide yellow, colour carbon black.
In a preferred embodiment of the present invention, the model of described only dry agent is MTBHQ or BHT.
In a preferred embodiment of the present invention, described wax is the mixture of one or more in polyethylene wax, PTFE wax or sasol wax.
The invention has the beneficial effects as follows: a kind of plant oil based green heat-set ink of the present invention, its composition major part is renewable resources, possesses the set identical and even higher with common heat-set ink and rate of drying, has excellent glossiness, without petroleum solvent, there is the remarkable feature of environmental protection.
Embodiment
Below preferred embodiment of the present invention is described in detail, can be easier to make advantages and features of the invention be readily appreciated by one skilled in the art, thus more explicit defining is made to protection scope of the present invention.
Embodiment 1:
A kind of plant oil based green heat-set ink is prepared from by the composition of following massfraction: binder 65%, pigment 20%, Synolac 2.5%, vegetables oil 2.5%, dispersion agent 0.5%, wax 0.5%, only dry agent 1.0% and vegetable oil derivatives 8%;
Described binder is prepared from by the composition of following massfraction: the rosin modified phenolic resin of 38 ~ 42%, the vegetables oil of 25 ~ 30%, the vegetable oil derivatives of 25 ~ 35% and the gelifying agent of 0.8 ~ 1.2% are prepared from.
Described rosin modified phenolic resin is two kinds of resol, and one is high viscosity, high structure, low solubility resin, for ink provides body bone, and anti-flies performance of ink, excellent wear resistance, sharpness of dots, print gloss and ink-water balance; Another kind is the resin of low viscosity, low structure, moderate solubility, for ink provides excellent gloss, levelling property and pigment wettability.
Described Synolac is long oil alkyd, the Synolac that described Synolac adopts one or more modifications in oleum lini, soya-bean oil, Oleum Cocois, rapeseed oil obtained.
Described vegetables oil is that tung oil and dry vegetable oil or semi-drying vegetable oils mix, and described dry vegetable oil comprises oleum lini, perilla oil and Chinese catalpa oil, and described semi-drying oil comprises soya-bean oil, rapeseed oil and Viscotrol C.
Described vegetable oil derivatives is the cut cut substrate of soybean oil methyl ester, soya-bean oil ethyl ester, soya-bean oil isobutyl ester, palm oil methyl ester, plam oil ethyl ester, plam oil isobutyl ester, rapeseed methylester, rapeseed oil ethyl ester or rapeseed oil isobutyl ester, the boiling range of described cut cut substrate between 250 ~ 290 DEG C, preferred cold filter clogging temperature below 0 DEG C, the fatty acid ester of zero pour below 0 DEG C.
Described gelifying agent is aluminum chelate, and described aluminum chelate is the derivative of n-butoxy aluminium, isobutoxy aluminium or secondary butoxy aluminium, and wherein n-butoxy, one of isobutoxy or secondary butoxy are substituted by ethyl acetate or methyl acetate.Gelifying agent can improve the visco-elasticity of binder, improves the anti-of ink and flies ink, demulsification performance, improves ink and urges dry effect.
Described pigment comprises fuchsin, Phthalocyanine Blue BGS, diarylide yellow, colour carbon black.
Described dispersion agent be model 17000,24000, the dispersion agent of CH-5 or CH-8M.
The model of described only dry agent is the unrestricted kind antioxidants such as MTBHQ or BHT.
Described wax is the mixture of one or more in polyethylene wax, PTFE wax or sasol wax.
Embodiment 2:
A kind of plant oil based green heat-set ink is prepared from by the composition of following massfraction: binder 60%, pigment 25%, Synolac 2%, vegetables oil 2%, dispersion agent 0.5%, wax 1.5%, only dry agent 1.5% and vegetable oil derivatives 7.5%;
Described binder is prepared from by the composition of following massfraction: the rosin modified phenolic resin of 40%, the vegetables oil of 30%, the vegetable oil derivatives of 28% and the gelifying agent of 2% are prepared from.
All the other moietys are with embodiment 1.
Embodiment 3:
A kind of plant oil based green heat-set ink is prepared from by the composition of following massfraction: binder 70%, pigment 15%, Synolac 3%, vegetables oil 2%, dispersion agent 0.5%, wax 0.5%, only dry agent 1.0% and vegetable oil derivatives 8%;
Described binder is prepared from by the composition of following massfraction: the rosin modified phenolic resin of 35%, the vegetables oil of 35%, the vegetable oil derivatives of 29% and the gelifying agent of 1% are prepared from.
All the other moietys are with embodiment 1.
The preparation method of above-mentioned three embodiments, comprises the steps:
1) prepare burden, get out the material of the mass fraction of being correlated with according to ink formulations;
2) binder is prepared, vegetables oil and rosin modified phenolic resin is added in reactor, heat up and stir, temperature reaches 200 DEG C of insulations and adds vegetable oil derivatives afterwards in one hour, be cooled to again after below 160 DEG C and add gelifying agent, then be warming up to 180 DEG C of insulations one hour, after filtering, discharging is stand-by, prepares binder;
3) pre-dispersed, pigment, Synolac, vegetables oil and dispersion agent are added in binder and carry out dispersion stirring;
4) grinding and stirring, is ground to fineness by the material obtained pre-dispersed in step 3) and reaches less than 7.5 microns, then adds wax, only dry agent and vegetable oil derivatives and stir;
5) aftertreatment, by warehouse-in after carrying out through the material of step 4) process detecting, packing.
Following table is the performance comparison data sheet of plant oil based green heat-set ink that in embodiment 1 ~ 3, any embodiment prepares and common heat fixed type ink.
The foregoing is only embodiments of the invention; not thereby the scope of the claims of the present invention is limited; every utilize description of the present invention to do equivalent structure or equivalent flow process conversion; or be directly or indirectly used in other relevant technical fields, be all in like manner included in scope of patent protection of the present invention.
Claims (9)
1. a plant oil based green heat-set ink, it is characterized in that, be prepared from by the composition of following massfraction: binder 55 ~ 75%, pigment 10 ~ 25%, Synolac 0 ~ 5%, vegetables oil 0 ~ 5%, dispersion agent 0 ~ 1%, wax 0 ~ 2%, only dry agent 0.5 ~ 2% and vegetable oil derivatives 5 ~ 10%;
Described binder is prepared from by the composition of following massfraction: the rosin modified phenolic resin of 35 ~ 45%, the vegetables oil of 20 ~ 35%, the vegetable oil derivatives of 10 ~ 40% and the gelifying agent of 0 ~ 2% are prepared from.
2. plant oil based green heat-set ink according to claim 1, it is characterized in that, described Synolac is long oil alkyd, the Synolac that described Synolac adopts one or more modifications in oleum lini, soya-bean oil, Oleum Cocois, rapeseed oil obtained.
3. plant oil based green heat-set ink according to claim 1, it is characterized in that, described vegetables oil is that tung oil and dry vegetable oil or semi-drying vegetable oils mix, described dry vegetable oil comprises oleum lini, perilla oil and Chinese catalpa oil, and described semi-drying oil comprises soya-bean oil, rapeseed oil and Viscotrol C.
4. plant oil based green heat-set ink according to claim 1, it is characterized in that, described vegetable oil derivatives is the cut cut substrate of soybean oil methyl ester, soya-bean oil ethyl ester, soya-bean oil isobutyl ester, palm oil methyl ester, plam oil ethyl ester, plam oil isobutyl ester, rapeseed methylester, rapeseed oil ethyl ester or rapeseed oil isobutyl ester.
5. plant oil based green heat-set ink according to claim 4, is characterized in that, the boiling range of described cut cut substrate between 260 ~ 320 DEG C, pour point below 0 DEG C, cold filter clogging temperature is below 0 DEG C.
6. plant oil based green heat-set ink according to claim 1, is characterized in that, described gelifying agent is aluminum chelate, and described aluminum chelate is the derivative of n-butoxy aluminium, isobutoxy aluminium or secondary butoxy aluminium.
7. plant oil based green heat-set ink according to claim 1, it is characterized in that, described pigment comprises fuchsin, Phthalocyanine Blue BGS, diarylide yellow, colour carbon black.
8. plant oil based green heat-set ink according to claim 1, is characterized in that, the model of described only dry agent is MTBHQ or BHT.
9. plant oil based green heat-set ink according to claim 1, is characterized in that, described wax is the mixture of one or more in polyethylene wax, PTFE wax or sasol wax.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610019841.6A CN105462348A (en) | 2016-01-13 | 2016-01-13 | Plant-oil-based green heat-set ink |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610019841.6A CN105462348A (en) | 2016-01-13 | 2016-01-13 | Plant-oil-based green heat-set ink |
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| Publication Number | Publication Date |
|---|---|
| CN105462348A true CN105462348A (en) | 2016-04-06 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610019841.6A Pending CN105462348A (en) | 2016-01-13 | 2016-01-13 | Plant-oil-based green heat-set ink |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107778967A (en) * | 2016-08-31 | 2018-03-09 | 天津天女化工集团股份有限公司 | A kind of antistatic resin ink vehicle and preparation method |
| CN107955454A (en) * | 2017-12-19 | 2018-04-24 | 赵云飞 | A kind of environment-friendly type compound oil ink and preparation method thereof |
| CN114517028A (en) * | 2020-11-19 | 2022-05-20 | 敬业（东莞）印刷包装厂有限公司 | Blue ink and preparation method thereof |
| CN115505295A (en) * | 2021-06-23 | 2022-12-23 | 上海深日化工有限公司 | Aromatic-hydrocarbon-free low-energy low-VOC (volatile organic compound) thermosetting offset printing rotary ink |
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| CN101914323A (en) * | 2010-08-19 | 2010-12-15 | 上海牡丹油墨有限公司 | Application of palm oil and palm oil derivative to ink vehicle |
| CN102108221A (en) * | 2011-01-14 | 2011-06-29 | 上海牡丹油墨有限公司 | Palm oil-base offset printing ink containing no mineral oil and preparation method thereof |
| CN102643577A (en) * | 2012-05-03 | 2012-08-22 | 中钞油墨有限公司 | Environment-friendly printing ink suitable for high speed rotary printing |
| CN103087587A (en) * | 2013-02-06 | 2013-05-08 | 茂名阪田油墨有限公司 | Preparation method for producing calcium-carbonate-containing lithographic ink through one-step kneading method |
| CN103725085A (en) * | 2013-12-26 | 2014-04-16 | 中山大学 | Stereoscopic offset printing ink prepared by using waste vegetable oil foots as well as preparation method and application of stereoscopic offset printing ink |
-
2016
- 2016-01-13 CN CN201610019841.6A patent/CN105462348A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101914323A (en) * | 2010-08-19 | 2010-12-15 | 上海牡丹油墨有限公司 | Application of palm oil and palm oil derivative to ink vehicle |
| CN102108221A (en) * | 2011-01-14 | 2011-06-29 | 上海牡丹油墨有限公司 | Palm oil-base offset printing ink containing no mineral oil and preparation method thereof |
| CN102643577A (en) * | 2012-05-03 | 2012-08-22 | 中钞油墨有限公司 | Environment-friendly printing ink suitable for high speed rotary printing |
| CN103087587A (en) * | 2013-02-06 | 2013-05-08 | 茂名阪田油墨有限公司 | Preparation method for producing calcium-carbonate-containing lithographic ink through one-step kneading method |
| CN103725085A (en) * | 2013-12-26 | 2014-04-16 | 中山大学 | Stereoscopic offset printing ink prepared by using waste vegetable oil foots as well as preparation method and application of stereoscopic offset printing ink |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107778967A (en) * | 2016-08-31 | 2018-03-09 | 天津天女化工集团股份有限公司 | A kind of antistatic resin ink vehicle and preparation method |
| CN107955454A (en) * | 2017-12-19 | 2018-04-24 | 赵云飞 | A kind of environment-friendly type compound oil ink and preparation method thereof |
| CN114517028A (en) * | 2020-11-19 | 2022-05-20 | 敬业（东莞）印刷包装厂有限公司 | Blue ink and preparation method thereof |
| CN115505295A (en) * | 2021-06-23 | 2022-12-23 | 上海深日化工有限公司 | Aromatic-hydrocarbon-free low-energy low-VOC (volatile organic compound) thermosetting offset printing rotary ink |
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Application publication date: 20160406 |
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