CN105385229A - Quick-dry high-gloss environment-friendly offset printing ink - Google Patents

Quick-dry high-gloss environment-friendly offset printing ink Download PDF

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Publication number
CN105385229A
CN105385229A CN201510850612.4A CN201510850612A CN105385229A CN 105385229 A CN105385229 A CN 105385229A CN 201510850612 A CN201510850612 A CN 201510850612A CN 105385229 A CN105385229 A CN 105385229A
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China
Prior art keywords
oil
quick
printing ink
percent
light environment
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Pending
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CN201510850612.4A
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Chinese (zh)
Inventor
徐晓花
吕伟
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SUZHOU BOLOIT PRINTING INK CO Ltd
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SUZHOU BOLOIT PRINTING INK CO Ltd
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Priority to CN201510850612.4A priority Critical patent/CN105385229A/en
Publication of CN105385229A publication Critical patent/CN105385229A/en
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Abstract

The invention discloses quick-dry high-gloss environment-friendly offset printing ink which is prepared from the following components in percentage by weight: 55 to 65 percent of environment-friendly bonding material, 20 to 28 percent of pigment and filler, 0 to 5 percent of alkyd resin, 0 to 5 percent of vegetable oil, 0 to 1 percent of dispersing agent, 0 to 2.5 percent of drier, 0 to 2 percent of wax and 5 to 10 percent of vegetable oil fatty acid ester, wherein the environment-friendly bonding material is prepared from the following components in percentage by weight: 35 to 45 percent of rosin modified phenolic resin, 20 to 40 percent of vegetable oil, 10 to 30 percent of vegetable oil fatty acid ester and 0 to 2 percent of gel. The quick-dry high-gloss environment-friendly offset printing ink disclosed by the invention has an identical or higher setting speed in comparison with that of general quick-dry high-gloss ink, is excellent in glossiness and is free from VOC (Volatile Organic Compounds); due to the use of a large amount of renewable resource, the quick-dry high-gloss environment-friendly offset printing ink is excellent in environment protection.

Description

A kind of quick-drying light environment-friendlyadhesive adhesive printing ink
Technical field
The present invention relates to technical field of ink, particularly relate to a kind of environment-friendlyadhesive adhesive printing ink.
Background technology
The dried forms of tradition flexographic ink is the combination drying form of permeating set and having oxypolymerization to combine: ink printing is on paper, solvent penetration was in the pore of paper before this, resin is separated out and set, dry vegetable oil then in binder and chain polymer thereof are cross-linked into reticulated structure macromole through oxygenizement, complete and solidify to form solid-state ink film.Dry vegetable oil in tradition flexographic ink mostly is the dry vegetable oils such as oleum lini, Chinese catalpa oil, tung oil, and diluting solvent is high-boiling point kerosene, and boiling range is between 270 ~ 320 DEG C.Along with the requirement of environmental protection is more and more higher, traditional quick-drying gloss ink is more and more not suitable with environmental requirement, although high-boiling point kerosene has made low aromatic hydrocarbons into by the kerosene of high aromatic hydrocarbons or even without aromatic hydrocarbons kerosene, kerosene is petroleum chemicals eventually, is Nonrenewable resources in recent years.The environment-friendly type flexographic ink now commercially the sold dry vegetable oil a large amount of in order to environmental protection employs, semi-drying vegetable oils substitute high-boiling point kerosene and sacrifice the fixation performance of ink, can not adapt to Modern High-Speed print request.Therefore, study a kind of not only environmental protection, but also can the quick-drying light environment-friendly ink of set be imperative fast on printed material.
Summary of the invention
The technical problem that the present invention mainly solves is to provide a kind of quick-drying light environment-friendlyadhesive adhesive printing ink, and common quick-drying gloss ink has identical or set speed faster, and glossiness is good, VOC free, uses a large amount of renewable resourcess, and the feature of environmental protection is remarkable.
For solving the problems of the technologies described above, the technical scheme that the present invention adopts is:
Thering is provided a kind of quick-drying light environment-friendlyadhesive adhesive printing ink, is be prepared from by the composition of following massfraction: environmental protection binder 55 ~ 65%, pigment and filler 20 ~ 28%, Synolac 0 ~ 5%, vegetables oil 0 ~ 5%, dispersion agent 0 ~ 1%, siccative 0 ~ 2.5%, wax 0 ~ 2%, vegetable fatty acid esters 5 ~ 10%;
Described environmental protection binder is prepared from by the composition of following masses mark: rosin modified phenolic resin 35 ~ 45%, vegetables oil 20 ~ 40%, vegetable fatty acid esters 10 ~ 30% and gelifying agent 0 ~ 2%.
In a preferred embodiment of the present invention, described rosin modified phenolic resin comprises the first rosin modified phenolic resin and the second rosin modified phenolic resin, the weight-average molecular weight of described first rosin modified phenolic resin is 150000 ~ 300000, and the weight-average molecular weight of described second rosin modified phenolic resin is 10000 ~ 60000.
In a preferred embodiment of the present invention, described Synolac is long oil alkyd, the Synolac that described Synolac adopts one or more modifications in oleum lini, soya-bean oil, Oleum Cocois, rapeseed oil obtained.
In a preferred embodiment of the present invention, described vegetables oil is that dry vegetable oil and semi-drying vegetable oils mix, and described dry vegetable oil comprises oleum lini, tung oil, perilla oil and Chinese catalpa oil, and described semi-drying oil comprises soya-bean oil, rapeseed oil and Viscotrol C.
In a preferred embodiment of the present invention, described vegetable fatty acid esters is the cut cut substrate of soybean oil methyl ester, soya-bean oil ethyl ester, soya-bean oil isobutyl ester, palm oil methyl ester, plam oil ethyl ester, plam oil isobutyl ester, rapeseed methylester, rapeseed oil ethyl ester or rapeseed oil isobutyl ester.
In a preferred embodiment of the present invention, the boiling range of described cut cut substrate between 260 ~ 320 DEG C, pour point below 0 DEG C, cold filter clogging temperature is below 0 DEG C.
In a preferred embodiment of the present invention, described gelifying agent is aluminum chelate, and described aluminum chelate is the derivative of n-butoxy aluminium, isobutoxy aluminium or secondary butoxy aluminium.
In a preferred embodiment of the present invention, described pigment is fuchsin, phthalocyanine blue b, diarylide yellow or colour carbon black, and described filler is nano-calcium carbonate.
In a preferred embodiment of the present invention, siccative is metal soap, comprises the mixture of one or more in cobalt iso-octoate, manganese iso-octoate, isocaprylic acid cerium, isocaprylic acid iron, cobalt naphthenate, manganese naphthenate.
In a preferred embodiment of the present invention, described wax is the mixture of one or more in polyethylene wax, PTFE wax or sasol wax.
The invention has the beneficial effects as follows: a kind of quick-drying light of the present invention environment-friendly ink, its composition major part is renewable resources, possesses the set identical and even higher with common flexographic ink and rate of drying, has excellent glossiness, without petroleum solvent, there is the remarkable feature of environmental protection.
Embodiment
Below preferred embodiment of the present invention is described in detail, can be easier to make advantages and features of the invention be readily appreciated by one skilled in the art, thus more explicit defining is made to protection scope of the present invention.
Embodiment 1:
A kind of quick-drying light environment-friendlyadhesive adhesive printing ink is be prepared from by the composition of following massfraction: environmental protection binder 60%, pigment and filler 25%, Synolac 2.5%, vegetables oil 2.5%, dispersion agent 0.5%, siccative 1.0%, wax 0.5%, vegetable fatty acid esters 8%;
Described environmental protection binder is prepared from by the composition of following masses mark: rosin modified phenolic resin 40%, vegetables oil 30%, vegetable fatty acid esters 28% and gelifying agent 2%.
Described rosin modified phenolic resin comprises the first rosin modified phenolic resin and the second rosin modified phenolic resin, the weight-average molecular weight of described first rosin modified phenolic resin is 150000 ~ 300000, for high viscosity, high structure, low-solubility resin, for ink provides body bone, and anti-fly performance of ink, excellent wear resistance, sharpness of dots, print gloss and ink-water balance; The weight-average molecular weight of described second rosin modified phenolic resin, 10000 ~ 60000, is the resin of low viscosity, low structure, moderate solubility, for ink provides excellent gloss, levelling property and pigment wettability.
Described Synolac is long oil alkyd, the Synolac that described Synolac adopts one or more modifications in oleum lini, soya-bean oil, Oleum Cocois, rapeseed oil obtained.
Described vegetables oil is that dry vegetable oil and semi-drying vegetable oils mix, and described dry vegetable oil comprises oleum lini, tung oil, perilla oil and Chinese catalpa oil, and described semi-drying oil comprises soya-bean oil, rapeseed oil and Viscotrol C.
Described vegetable fatty acid esters is the cut cut substrate of soybean oil methyl ester, soya-bean oil ethyl ester, soya-bean oil isobutyl ester, palm oil methyl ester, plam oil ethyl ester, plam oil isobutyl ester, rapeseed methylester, rapeseed oil ethyl ester or rapeseed oil isobutyl ester, the boiling range of described cut cut substrate between 260 ~ 320 DEG C, pour point below 0 DEG C, cold filter clogging temperature is below 0 DEG C.
Described gelifying agent is aluminum chelate, and described aluminum chelate is the derivative of n-butoxy aluminium, isobutoxy aluminium or secondary butoxy aluminium.
Described pigment is fuchsin, phthalocyanine blue b, diarylide yellow or colour carbon black, and described filler is nano-calcium carbonate.
Siccative is metal soap, comprises the mixture of one or more in cobalt iso-octoate, manganese iso-octoate, isocaprylic acid cerium, isocaprylic acid iron, cobalt naphthenate, manganese naphthenate.
Described wax is the mixture of one or more in polyethylene wax, PTFE wax or sasol wax.
Embodiment 2:
A kind of quick-drying light environment-friendlyadhesive adhesive printing ink is be prepared from by the composition of following massfraction: environmental protection binder 55%, pigment and filler 25%, Synolac 3%, vegetables oil 3%, dispersion agent 0.5%, siccative 1.5%, wax 2%, vegetable fatty acid esters 10%;
Described environmental protection binder is prepared from by the composition of following masses mark: rosin modified phenolic resin 35%, vegetables oil 35%, vegetable fatty acid esters 29% and gelifying agent 1%.
All the other moietys are with embodiment 1.
Embodiment 3:
A kind of quick-drying light environment-friendlyadhesive adhesive printing ink is be prepared from by the composition of following massfraction: environmental protection binder 65%, pigment and filler 20%, Synolac 1%, vegetables oil 2%, dispersion agent 1%, siccative 1.5%, wax 1.5%, vegetable fatty acid esters 8%;
Described environmental protection binder is prepared from by the composition of following masses mark: rosin modified phenolic resin 45%, vegetables oil 40%, vegetable fatty acid esters 14% and gelifying agent 1%.
All the other moietys are with embodiment 1.
The preparation method of above-mentioned three embodiments, comprises the steps:
1) prepare burden, get out the material of the mass fraction of being correlated with according to ink formulations;
2) environmental protection binder is prepared, vegetables oil and rosin modified phenolic resin is added in reactor, heat up and stir, temperature reaches 200 DEG C of insulations and adds vegetable fatty acid esters afterwards in one hour, be cooled to again after below 160 DEG C and add gelifying agent, then be warming up to 180 DEG C of insulations one hour, after filtering, discharging is stand-by, prepares environmental protection binder;
3) pre-dispersed, pigment and filler, Synolac, vegetables oil and dispersion agent are added in environmental protection binder and carries out dispersion stirring;
4) grinding and stirring, is ground to fineness by the material obtained pre-dispersed in step 3) and reaches less than 7.5 microns, then add wax and vegetable fatty acid esters stirs;
5) aftertreatment, by warehouse-in after carrying out through the material of step 4) process detecting, packing.
Following table is the performance comparison data sheet of quick-drying light environment-friendlyadhesive adhesive printing ink that in embodiment 1 ~ 3, any embodiment prepares and common flexographic ink, commercially available common environment-friendly ink.
The foregoing is only embodiments of the invention; not thereby the scope of the claims of the present invention is limited; every utilize description of the present invention to do equivalent structure or equivalent flow process conversion; or be directly or indirectly used in other relevant technical fields, be all in like manner included in scope of patent protection of the present invention.

Claims (10)

1. a quick-drying light environment-friendlyadhesive adhesive printing ink, it is characterized in that, be prepared from by the composition of following massfraction: environmental protection binder 55 ~ 65%, pigment and filler 20 ~ 28%, Synolac 0 ~ 5%, vegetables oil 0 ~ 5%, dispersion agent 0 ~ 1%, siccative 0 ~ 2.5%, wax 0 ~ 2%, vegetable fatty acid esters 5 ~ 10%;
Described environmental protection binder is prepared from by the composition of following masses mark: rosin modified phenolic resin 35 ~ 45%, vegetables oil 20 ~ 40%, vegetable fatty acid esters 10 ~ 30% and gelifying agent 0 ~ 2%.
2. quick-drying light environment-friendlyadhesive adhesive printing ink according to claim 1, it is characterized in that, described rosin modified phenolic resin comprises the first rosin modified phenolic resin and the second rosin modified phenolic resin, the weight-average molecular weight of described first rosin modified phenolic resin is 150000 ~ 300000, and the weight-average molecular weight of described second rosin modified phenolic resin is 10000 ~ 60000.
3. quick-drying light environment-friendlyadhesive adhesive printing ink according to claim 1, it is characterized in that, described Synolac is long oil alkyd, the Synolac that described Synolac adopts one or more modifications in oleum lini, soya-bean oil, Oleum Cocois, rapeseed oil obtained.
4. quick-drying light environment-friendlyadhesive adhesive printing ink according to claim 1, it is characterized in that, described vegetables oil is that dry vegetable oil and semi-drying vegetable oils mix, described dry vegetable oil comprises oleum lini, tung oil, perilla oil and Chinese catalpa oil, and described semi-drying oil comprises soya-bean oil, rapeseed oil and Viscotrol C.
5. quick-drying light environment-friendlyadhesive adhesive printing ink according to claim 1, it is characterized in that, described vegetable fatty acid esters is the cut cut substrate of soybean oil methyl ester, soya-bean oil ethyl ester, soya-bean oil isobutyl ester, palm oil methyl ester, plam oil ethyl ester, plam oil isobutyl ester, rapeseed methylester, rapeseed oil ethyl ester or rapeseed oil isobutyl ester.
6. quick-drying light environment-friendlyadhesive adhesive printing ink according to claim 5, is characterized in that, the boiling range of described cut cut substrate between 260 ~ 320 DEG C, pour point below 0 DEG C, cold filter clogging temperature is below 0 DEG C.
7. quick-drying light environment-friendlyadhesive adhesive printing ink according to claim 1, it is characterized in that, described gelifying agent is aluminum chelate, and described aluminum chelate is the derivative of n-butoxy aluminium, isobutoxy aluminium or secondary butoxy aluminium.
8. quick-drying light environment-friendlyadhesive adhesive printing ink according to claim 1, it is characterized in that, described pigment is fuchsin, phthalocyanine blue b, diarylide yellow or colour carbon black, and described filler is nano-calcium carbonate.
9. quick-drying light environment-friendlyadhesive adhesive printing ink according to claim 1, it is characterized in that, siccative is metal soap, comprises the mixture of one or more in cobalt iso-octoate, manganese iso-octoate, isocaprylic acid cerium, isocaprylic acid iron, cobalt naphthenate, manganese naphthenate.
10. quick-drying light environment-friendlyadhesive adhesive printing ink according to claim 1, is characterized in that, described wax is the mixture of one or more in polyethylene wax, PTFE wax or sasol wax.
CN201510850612.4A 2015-11-30 2015-11-30 Quick-dry high-gloss environment-friendly offset printing ink Pending CN105385229A (en)

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Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106336727A (en) * 2016-10-29 2017-01-18 常州亚环环保科技有限公司 Preparation method of offset printing ink quick to dry
CN106433292A (en) * 2016-12-15 2017-02-22 杨烨 Clean and quick-drying ink and processing method thereof
CN106893402A (en) * 2017-03-29 2017-06-27 南宁市青秀区嘉利林化有限公司 A kind of rosin ink dry solution and preparation method thereof
CN107474737A (en) * 2017-08-15 2017-12-15 南宁东印时代广告有限公司 A kind of paster making oil polish and preparation method thereof
CN107556810A (en) * 2017-06-23 2018-01-09 上海牡丹油墨有限公司 A kind of environmental-friendoffset offset printing ink antifriction liniment and preparation method thereof
CN107793834A (en) * 2017-11-20 2018-03-13 武汉红金龙印务股份有限公司 A kind of preparation method and application of the single-sheet offset printing ink of low VOC content
CN109021679A (en) * 2018-07-21 2018-12-18 浙江省邮电印刷股份有限公司 A kind of printing ink and its preparation process
CN110452617A (en) * 2019-08-30 2019-11-15 北京林业大学 A kind of environmental protection quick-drying wood wax oil and preparation method thereof
CN112300624A (en) * 2020-11-05 2021-02-02 合肥杏花印务股份有限公司 Formula and preparation method of ink for green printing
CN113150609A (en) * 2021-05-06 2021-07-23 洋紫荆油墨股份有限公司 High-gloss high-wear-resistance printing ink
CN114773903A (en) * 2022-04-25 2022-07-22 北京金印联国际供应链管理有限公司 Low-odor offset printing ink and preparation method thereof
CN114854244A (en) * 2022-04-27 2022-08-05 北京金印联国际供应链管理有限公司 Environment-friendly offset printing ink and preparation method thereof
CN115073968A (en) * 2022-07-27 2022-09-20 苏州市博来特油墨有限公司 Environment-friendly offset printing ink and preparation method thereof
CN115505295A (en) * 2021-06-23 2022-12-23 上海深日化工有限公司 Aromatic-hydrocarbon-free low-energy low-VOC (volatile organic compound) thermosetting offset printing rotary ink
CN115558332A (en) * 2022-09-19 2023-01-03 茂名阪田油墨有限公司 Novel quick-drying low-odor printing ink
WO2023179008A1 (en) * 2022-03-21 2023-09-28 中山市富日印刷材料有限公司 Vegetable oil-based low-halogen environmentally friendly ink and preparation method therefor

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Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106336727A (en) * 2016-10-29 2017-01-18 常州亚环环保科技有限公司 Preparation method of offset printing ink quick to dry
CN106433292A (en) * 2016-12-15 2017-02-22 杨烨 Clean and quick-drying ink and processing method thereof
CN106893402A (en) * 2017-03-29 2017-06-27 南宁市青秀区嘉利林化有限公司 A kind of rosin ink dry solution and preparation method thereof
CN107556810A (en) * 2017-06-23 2018-01-09 上海牡丹油墨有限公司 A kind of environmental-friendoffset offset printing ink antifriction liniment and preparation method thereof
CN107474737A (en) * 2017-08-15 2017-12-15 南宁东印时代广告有限公司 A kind of paster making oil polish and preparation method thereof
CN107793834B (en) * 2017-11-20 2021-05-04 武汉红金龙印务股份有限公司 Preparation method and application of single-sheet paper offset printing ink with low VOC content
CN107793834A (en) * 2017-11-20 2018-03-13 武汉红金龙印务股份有限公司 A kind of preparation method and application of the single-sheet offset printing ink of low VOC content
CN109021679A (en) * 2018-07-21 2018-12-18 浙江省邮电印刷股份有限公司 A kind of printing ink and its preparation process
CN110452617A (en) * 2019-08-30 2019-11-15 北京林业大学 A kind of environmental protection quick-drying wood wax oil and preparation method thereof
CN112300624A (en) * 2020-11-05 2021-02-02 合肥杏花印务股份有限公司 Formula and preparation method of ink for green printing
CN113150609A (en) * 2021-05-06 2021-07-23 洋紫荆油墨股份有限公司 High-gloss high-wear-resistance printing ink
CN115505295A (en) * 2021-06-23 2022-12-23 上海深日化工有限公司 Aromatic-hydrocarbon-free low-energy low-VOC (volatile organic compound) thermosetting offset printing rotary ink
WO2023179008A1 (en) * 2022-03-21 2023-09-28 中山市富日印刷材料有限公司 Vegetable oil-based low-halogen environmentally friendly ink and preparation method therefor
CN114773903A (en) * 2022-04-25 2022-07-22 北京金印联国际供应链管理有限公司 Low-odor offset printing ink and preparation method thereof
CN114773903B (en) * 2022-04-25 2023-12-12 北京金印联国际供应链管理有限公司 Low-odor offset printing ink and preparation method thereof
CN114854244A (en) * 2022-04-27 2022-08-05 北京金印联国际供应链管理有限公司 Environment-friendly offset printing ink and preparation method thereof
CN115073968A (en) * 2022-07-27 2022-09-20 苏州市博来特油墨有限公司 Environment-friendly offset printing ink and preparation method thereof
CN115558332A (en) * 2022-09-19 2023-01-03 茂名阪田油墨有限公司 Novel quick-drying low-odor printing ink

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