CN105860672A - Irreversible thermochromic ink and preparation method thereof - Google Patents
Irreversible thermochromic ink and preparation method thereof Download PDFInfo
- Publication number
- CN105860672A CN105860672A CN201610459300.5A CN201610459300A CN105860672A CN 105860672 A CN105860672 A CN 105860672A CN 201610459300 A CN201610459300 A CN 201610459300A CN 105860672 A CN105860672 A CN 105860672A
- Authority
- CN
- China
- Prior art keywords
- ink
- agent
- temperature
- oil
- potassium tungstate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000002360 preparation method Methods 0.000 title claims abstract description 23
- 230000002427 irreversible effect Effects 0.000 title abstract description 11
- 239000000049 pigment Substances 0.000 claims abstract description 50
- 229920000180 alkyd Polymers 0.000 claims abstract description 44
- 239000003208 petroleum Substances 0.000 claims abstract description 17
- 239000002904 solvent Substances 0.000 claims abstract description 17
- 238000003756 stirring Methods 0.000 claims abstract description 11
- 238000002156 mixing Methods 0.000 claims abstract description 5
- 229920005989 resin Polymers 0.000 claims abstract description 5
- 239000011347 resin Substances 0.000 claims abstract description 5
- AAQNGTNRWPXMPB-UHFFFAOYSA-N dipotassium;dioxido(dioxo)tungsten Chemical compound [K+].[K+].[O-][W]([O-])(=O)=O AAQNGTNRWPXMPB-UHFFFAOYSA-N 0.000 claims description 100
- NFYLSJDPENHSBT-UHFFFAOYSA-N chromium(3+);lanthanum(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Cr+3].[La+3] NFYLSJDPENHSBT-UHFFFAOYSA-N 0.000 claims description 71
- 239000003921 oil Substances 0.000 claims description 71
- 239000003795 chemical substances by application Substances 0.000 claims description 68
- 239000000084 colloidal system Substances 0.000 claims description 59
- 238000005253 cladding Methods 0.000 claims description 47
- SOKRNBGSNZXYIO-UHFFFAOYSA-N Resinone Natural products CC(=C)C1CCC2(C)C(O)CC3(C)C(CCC4C5(C)CCC(=O)C(C)(C)C5CCC34C)C12 SOKRNBGSNZXYIO-UHFFFAOYSA-N 0.000 claims description 37
- 239000000843 powder Substances 0.000 claims description 36
- 239000012752 auxiliary agent Substances 0.000 claims description 34
- -1 polyethylene Polymers 0.000 claims description 32
- 239000004094 surface-active agent Substances 0.000 claims description 28
- 239000013530 defoamer Substances 0.000 claims description 27
- 239000002274 desiccant Substances 0.000 claims description 26
- 238000009835 boiling Methods 0.000 claims description 25
- 239000000203 mixture Substances 0.000 claims description 23
- DTDCCPMQHXRFFI-UHFFFAOYSA-N dioxido(dioxo)chromium lanthanum(3+) Chemical compound [La+3].[La+3].[O-][Cr]([O-])(=O)=O.[O-][Cr]([O-])(=O)=O.[O-][Cr]([O-])(=O)=O DTDCCPMQHXRFFI-UHFFFAOYSA-N 0.000 claims description 19
- 239000003350 kerosene Substances 0.000 claims description 18
- 239000007788 liquid Substances 0.000 claims description 18
- 239000007864 aqueous solution Substances 0.000 claims description 15
- 229920006395 saturated elastomer Polymers 0.000 claims description 15
- 235000013870 dimethyl polysiloxane Nutrition 0.000 claims description 13
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 13
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims description 12
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical group [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- MMRGVZGCYVIMNX-CVBJKYQLSA-N CCCNN.CCCCCCCC\C=C/CCCCCCCC(O)=O.CCCCCCCC\C=C/CCCCCCCC(O)=O Chemical compound CCCNN.CCCCCCCC\C=C/CCCCCCCC(O)=O.CCCCCCCC\C=C/CCCCCCCC(O)=O MMRGVZGCYVIMNX-CVBJKYQLSA-N 0.000 claims description 9
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 9
- 235000011837 pasties Nutrition 0.000 claims description 9
- 239000004698 Polyethylene Substances 0.000 claims description 8
- XMHIUKTWLZUKEX-UHFFFAOYSA-N hexacosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCC(O)=O XMHIUKTWLZUKEX-UHFFFAOYSA-N 0.000 claims description 8
- 229920000573 polyethylene Polymers 0.000 claims description 8
- YEVQZPWSVWZAOB-UHFFFAOYSA-N 2-(bromomethyl)-1-iodo-4-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=CC=C(I)C(CBr)=C1 YEVQZPWSVWZAOB-UHFFFAOYSA-N 0.000 claims description 7
- QGBLCIBATKETJC-UHFFFAOYSA-N 3,7-dioxido-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane;manganese(2+) Chemical compound [Mn+2].O1B([O-])OB2OB([O-])OB1O2 QGBLCIBATKETJC-UHFFFAOYSA-N 0.000 claims description 7
- FUPMSLTYEIZSLZ-UHFFFAOYSA-N cobalt;naphthalene-1-carboxylic acid Chemical compound [Co].C1=CC=C2C(C(=O)O)=CC=CC2=C1 FUPMSLTYEIZSLZ-UHFFFAOYSA-N 0.000 claims description 7
- 239000000463 material Substances 0.000 claims description 7
- 230000015572 biosynthetic process Effects 0.000 claims description 6
- FATBGEAMYMYZAF-KTKRTIGZSA-N oleamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(N)=O FATBGEAMYMYZAF-KTKRTIGZSA-N 0.000 claims description 6
- FATBGEAMYMYZAF-UHFFFAOYSA-N oleicacidamide-heptaglycolether Natural products CCCCCCCCC=CCCCCCCCC(N)=O FATBGEAMYMYZAF-UHFFFAOYSA-N 0.000 claims description 6
- 239000012188 paraffin wax Substances 0.000 claims description 6
- 229920006389 polyphenyl polymer Polymers 0.000 claims description 6
- 238000003786 synthesis reaction Methods 0.000 claims description 6
- 239000004743 Polypropylene Substances 0.000 claims description 5
- 239000010941 cobalt Substances 0.000 claims description 5
- 229910017052 cobalt Inorganic materials 0.000 claims description 5
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 5
- 230000000694 effects Effects 0.000 claims description 5
- ZPPSOOVFTBGHBI-UHFFFAOYSA-N lead(2+);oxido(oxo)borane Chemical compound [Pb+2].[O-]B=O.[O-]B=O ZPPSOOVFTBGHBI-UHFFFAOYSA-N 0.000 claims description 5
- GEMHFKXPOCTAIP-UHFFFAOYSA-N n,n-dimethyl-n'-phenylcarbamimidoyl chloride Chemical compound CN(C)C(Cl)=NC1=CC=CC=C1 GEMHFKXPOCTAIP-UHFFFAOYSA-N 0.000 claims description 5
- 229920001155 polypropylene Polymers 0.000 claims description 5
- 239000001993 wax Substances 0.000 claims description 5
- 230000003213 activating effect Effects 0.000 claims description 4
- 150000001335 aliphatic alkanes Chemical class 0.000 claims description 4
- QAHREYKOYSIQPH-UHFFFAOYSA-L cobalt(II) acetate Chemical compound [Co+2].CC([O-])=O.CC([O-])=O QAHREYKOYSIQPH-UHFFFAOYSA-L 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- 235000013305 food Nutrition 0.000 claims 2
- 230000004936 stimulating effect Effects 0.000 claims 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical group CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims 1
- 229960000583 acetic acid Drugs 0.000 claims 1
- 239000000470 constituent Substances 0.000 claims 1
- 229910000077 silane Inorganic materials 0.000 claims 1
- 229920001971 elastomer Polymers 0.000 abstract description 18
- 238000001035 drying Methods 0.000 abstract description 4
- 230000009286 beneficial effect Effects 0.000 abstract description 2
- 239000003086 colorant Substances 0.000 abstract description 2
- 238000007645 offset printing Methods 0.000 abstract description 2
- 238000007650 screen-printing Methods 0.000 abstract description 2
- 239000000654 additive Substances 0.000 abstract 2
- 230000000996 additive effect Effects 0.000 abstract 2
- 239000000945 filler Substances 0.000 abstract 2
- 239000000976 ink Substances 0.000 description 94
- 239000002253 acid Substances 0.000 description 10
- 230000002441 reversible effect Effects 0.000 description 8
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 6
- 238000000227 grinding Methods 0.000 description 6
- 239000011591 potassium Substances 0.000 description 6
- 229910052700 potassium Inorganic materials 0.000 description 6
- 239000002994 raw material Substances 0.000 description 6
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 6
- 229910052721 tungsten Inorganic materials 0.000 description 6
- 239000010937 tungsten Substances 0.000 description 6
- 239000010408 film Substances 0.000 description 4
- 238000005987 sulfurization reaction Methods 0.000 description 4
- 239000010685 fatty oil Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000007639 printing Methods 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- 150000001924 cycloalkanes Chemical class 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 210000000981 epithelium Anatomy 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- FQNGRYARVHJPPC-UHFFFAOYSA-L [La].[Cr](=O)(=O)(O)O Chemical compound [La].[Cr](=O)(=O)(O)O FQNGRYARVHJPPC-UHFFFAOYSA-L 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 210000000988 bone and bone Anatomy 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000005189 flocculation Methods 0.000 description 1
- 230000016615 flocculation Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 150000002910 rare earth metals Chemical class 0.000 description 1
- 238000000518 rheometry Methods 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 230000009974 thixotropic effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/50—Sympathetic, colour changing or similar inks
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses irreversible thermochromic ink. The ink comprises the following components by mass percent: 30-40% of resin oil, 20-30% of gummy oil, 1-5% of alkyd resin, 1-10% of low organic volatile matter petroleum solvent, 10-18% of pigment, 5-9% of filler and 5-9% of additive, wherein the sum of the mass percents of the components is 100%. The invention discloses a preparation method of the irreversible thermochromic ink. The preparation method comprises the following steps: fully mixing the pigment, the resin oil, the gummy oil, alkyd resin and the filler to form paste, adding the low organic volatile matter petroleum solvent and the additive and stirring the components uniformly, thus obtaining the irreversible thermochromic ink. The irreversible thermochromic ink has the beneficial effects that the irreversible thermochromic ink changes color at 137 DEG C and the color changing temperature is in the range of the automobile rubber tube vulcanizing temperature; color change is irreversible, so whether an automobile rubber tube is vulcanized can be judged through changes of the appearance colors; and the irreversible thermochromic ink has the advantages of high drying speed and good ink film toughness and is suitable for offset printing and silk screen printing.
Description
Technical field
The invention belongs to printing technology and replicate field, be specifically related to a kind of temperature and cause to be irreversibly changed ink, this
Invention further relates to the preparation method of this color shifting ink.
Background technology
The purpose of automobile rubber pipe sulfuration is to strengthen its pulling force, hardness, the performance such as aging, elastic, non-sulfur
The automobile rubber pipe using value changed is little, is all mass disposal when generally vulcanizing automobile rubber pipe,
Do not vulcanize owing to each side reason there may be only a few automobile rubber pipe, therefore can be in sulfuration
On automobile rubber pipe, print one layer of color shifting ink, before and after entering sulfuration process according to automobile rubber pipe before
The color change of color shifting ink judges whether automobile rubber pipe vulcanizes.
The method of existing production temperature induced color changing ink see: invention entitled " heat-sensitive colour-changing ink prints
Dataller's skill " (patent No. CN93105185.1, publication number CN 1080593, publication date 1994.01.12),
The advantage of patent is to use easy typography, it is possible to prints out heat-sensitive variable colour leaflet, but becomes
Color is reversible and discoloring temperature ratio is relatively low, it is impossible to distinguish whether automobile rubber pipe vulcanizes by outward appearance.
Invention entitled " overstable thermochromic coatings and preparation method thereof " (patent No.
CN201310370140.3, publication number CN 103396721A, publication date 2013.11.20), patent
Advantage is by modified organic Reversible Thermochromic Materials so that it is be changed into low temperature overstable thermochromism material
Material, but discoloring temperature is 48 DEG C, it is impossible to distinguish whether automobile rubber pipe vulcanizes by outward appearance.Denomination of invention
For " preparation method of a kind of novel thermochromatic inks " (patent No. CN201410684198.X, disclosure
Number CN 104497709A, publication date 2015.04.8), the advantage of patent there is provided a kind of novel thermic
The preparation method of color shifting ink, be easy to implement, the excellent performance of moderate cost, ink, variable color sensitivity
Height, but variable color is reversible, and discoloring temperature ratio is relatively low, it is impossible to whether distinguish automobile rubber pipe by outward appearance
Sulfuration.Invention entitled " heat-sensitive colour-changing ink " (patent No. CN91109163.7, publication number CN
1071182, publication date 1993.04.21), the advantage of patent is that the temperature sensitive ink prepared is cheap, side
Just practical, but ink variable color is reversible, it is impossible to distinguish whether automobile rubber pipe vulcanizes by outward appearance.Send out
Bright entitled " a kind of low-temp reversible thermochromic material and its production and use " (patent No.
CN201510216523.4, publication number CN 104789206A, publication date 2015.07.22), patent
Advantage is that preparation process is simple, productivity is high, environmental pollution is little, production cost is low, variable color is sensitive,
But discoloring temperature is low and variable color is reversible, it is impossible to distinguish whether automobile rubber pipe vulcanizes by outward appearance.With
And invention entitled " a kind of rare earth composition reversible thermochromatic material and preparation method thereof " (patent No.
CN201110424436.X, publication number CN 102492415A, publication date 2012.06.13), patent
Advantage is that preparation process is simple, bright in colour, but discoloring temperature is low and variable color is reversible, it is impossible to
Distinguish whether automobile rubber pipe vulcanizes by outward appearance.
Summary of the invention
It is an object of the invention to provide a kind of temperature to cause to be irreversibly changed ink, solve existing temperature induced color changing oil
Ink can not accurately judge the problem whether automobile rubber pipe vulcanizes.
It is a further object to provide a kind of temperature and cause to be irreversibly changed the preparation method of ink.
The technical solution adopted in the present invention is, a kind of temperature causes to be irreversibly changed ink, by mass percentage
Composed of the following components: resinon 30%～40%, colloid oil 20%～30%, alkyd resin 1%～
5%, low VOC petroleum solvent 1%～10%, pigment 10%～18%, inserts 5%～9%,
Auxiliary agent 5%～9%, the mass percent sum of above each component is 100%.
The feature of the present invention also resides in:
Auxiliary agent is surfactant, anti-sassafras agent, desiccant, defoamer and the mixture of levelling agent composition,
In auxiliary agent, each component accounts for temperature and causes to be irreversibly changed the percentage ratio of ink gross mass and is: surfactant 0.1%～
1.0%, anti-sassafras agent 2.0%～5.0%, desiccant 0.2%～1.0%, defoamer 0.5%～1.0% and stream
Flat agent 0.1%～1.0%.
Surfactant is sodium polyacrylate, enuatrol and the one of amino propylamine dioleate；Anti-sassafras agent
For oleamide, synthesis paraffin, polyethylene cerate, polypropylene wax and the one of polyphenyl methyl siloxane；
Desiccant is the one of cobaltous acetate, naphthoic acid cobalt, cobalt naphthenate, lead borate and manganese borate or two kinds therein
Mixture by weight 1:1 composition；Defoamer is middle federal B-0941, middle federal B-0942, in
Federal B-0943, trioctyl phosphate and the one of dimethyl polysiloxane；Levelling agent is polydimethylsiloxanes
One in alkane, Polymethylphenylsilane and organic-silicon-modified siloxanes.
Resinon is 218 resinons, 289 resinons, JC3135 resinon, JC3189 resinon, JC3183
Resinon and the one of JC3118 resinon；Colloid oil be 588-1 colloid oil, 584-1 colloid oil,
DC3110 colloid oil, DC3106 colloid oil, JC3184 colloid oil and the one of JC3118 colloid oil；
Alkyd resin is JC115 alkyd resin, JC117B alkyd resin and 305 quick-dry type long oil alkyd trees
The one of fat.
Low VOC petroleum solvent is the kerosene of the narrow boiling range of high boiling point；Pigment is that potassium tungstate is coated with chromic acid
Lanthanum powder；Inserts is calcene.
Another technical scheme of the present invention is, a kind of temperature causes to be irreversibly changed the preparation side of ink
Method, specifically includes following steps:
Step 1, weighs resinon 30%～40% the most respectively, colloid oily 20%～30%,
Alkyd resin 1%～5%, low VOC petroleum solvent 1%～10%, pigment 10%～18%, fill out
Charge 5%～9%, auxiliary agent 5%～9%, the mass percent sum of above each component is 100%；
Step 2, pigment step 1 weighed, resinon, colloid oil, alkyd resin and inserts fill
Divide mixing furnishing pasty state, after being ground to qualified fineness, obtain ink base ink；
Step 3, adds low VOC petroleum solvent and help in step 2 in the ink base ink obtained
Agent, stirs, and obtains temperature and causes to be irreversibly changed ink.
The feature of the present invention also resides in,
In step 1, pigment is that potassium tungstate is coated with lanthanum chromate powder, and potassium tungstate is coated with the concrete of lanthanum chromate powder
Preparation method is:
Weigh 5% potassium tungstate, 95% Lanthanum Chromite (800 mesh powder), two kinds of components the most by mass percentage
Mass percent sum is 100%；
A2., it is in 40 DEG C～45 DEG C of water that potassium tungstate is dissolved in temperature, is configured to potassium tungstate saturated aqueous solution,
It is subsequently adding Lanthanum Chromite, is sufficiently stirred for, moistening, obtain the liquid/paste of potassium tungstate cladding Lanthanum Chromite；
A3., potassium tungstate is coated with the liquid/paste of Lanthanum Chromite volatilize under field conditions (factors) moisture, after dry, will
The potassium tungstate cladding Lanthanum Chromite of dry shape is fully ground, and is subsequently adding surfactant A, is sufficiently stirred for obtaining；
In a3, surfactant A is sodium polyacrylate, enuatrol and the one of amino propylamine dioleate.
In step 1, resinon is 218 resinons, 289 resinons, JC3135 resinon, JC3189
Resinon, JC3183 resinon and the one of JC3118 resinon；Colloid oil be 588-1 colloid oil,
584-1 colloid oil, DC3110 colloid oil, DC3106 colloid oil, JC3184 colloid oil and JC3118
The one of colloid oil；Alkyd resin is that JC115 alkyd resin, JC117B alkyd resin and 305 are quick-drying
The one of type long oil alkyd；Low VOC petroleum solvent is the kerosene of the narrow boiling range of high boiling point；
Inserts is calcene.
In step 1, auxiliary agent is surfactant, anti-sassafras agent, desiccant, defoamer and levelling agent composition
Mixture, in auxiliary agent, each component accounts for temperature and causes to be irreversibly changed the percentage ratio of ink gross mass and is: surface activity
Agent 0.1%～1.0%, anti-sassafras agent 2.0%～5.0%, desiccant 0.2%～1.0%, defoamer 0.5%～
1.0% and levelling agent 0.1%～1.0%.
Surfactant is sodium polyacrylate, enuatrol and the one of amino propylamine dioleate；Anti-sassafras agent
For oleamide, synthesis paraffin, polyethylene cerate, polypropylene wax and the one of polyphenyl methyl siloxane；
Desiccant is the one of cobaltous acetate, naphthoic acid cobalt, cobalt naphthenate, lead borate and manganese borate or two kinds therein
Mixture by weight 1:1 composition；Defoamer is middle federal B-0941, middle federal B-0942, in
Federal B-0943, trioctyl phosphate and the one of dimethyl polysiloxane；Levelling agent is polydimethylsiloxanes
One in alkane, Polymethylphenylsilane and organic-silicon-modified siloxanes.
The invention has the beneficial effects as follows, temperature of the present invention causes to be irreversibly changed ink, 137 DEG C of variable colors, becomes
Color temperature is in automobile rubber pipe sulfurizing temperature range, and its variable color is irreversible, it is possible to realize passing through outward appearance
Color change judges whether automobile rubber pipe vulcanizes；And temperature of the present invention causes irreversible ink and has dry
Dry speed is fast, and the advantage of ink film good toughness goes for offset printing, silk screen printing.
Detailed description of the invention
Below in conjunction with detailed description of the invention, the present invention is described in detail.
Temperature of the present invention causes to be irreversibly changed ink, the most composed of the following components: resinon
30%～40%, colloid oil 20%～30%, alkyd resin 1%～5%, low VOC oil is molten
Agent 1%～10%, pigment 10%～18%, inserts 5%～9%, auxiliary agent 5%～9%, above each group
The mass percent sum divided is 100%.
Auxiliary agent is surfactant, anti-sassafras agent, desiccant, defoamer and the mixture of levelling agent composition,
In auxiliary agent, each component accounts for temperature and causes to be irreversibly changed the percentage ratio of ink gross mass and is: surfactant 0.1%～
1.0%, anti-sassafras agent 2.0%～5.0%, desiccant 0.2%～1.0%, defoamer 0.5%～1.0% and stream
Flat agent 0.1%～1.0%.
Surfactant is sodium polyacrylate, enuatrol and the one of amino propylamine dioleate；Anti-sassafras agent
For oleamide, synthesis paraffin, polyethylene cerate, polypropylene wax and the one of polyphenyl methyl siloxane；
Desiccant is the one of cobaltous acetate, naphthoic acid cobalt, cobalt naphthenate, lead borate and manganese borate or two kinds therein
Mixture by weight 1:1 composition；Defoamer is middle federal B-0941, middle federal B-0942, in
Federal B-0943, trioctyl phosphate and the one of dimethyl polysiloxane；Levelling agent is polydimethylsiloxanes
One in alkane, Polymethylphenylsilane and organic-silicon-modified siloxanes.
Resinon is 218 resinons, 289 resinons, JC3135 resinon, JC3189 resinon, JC3183
Resinon and the one of JC3118 resinon；Colloid oil be 588-1 colloid oil, 584-1 colloid oil,
DC3110 colloid oil, DC3106 colloid oil, JC3184 colloid oil and the one of JC3118 colloid oil；
Alkyd resin is JC115 alkyd resin, JC117B alkyd resin and 305 quick-dry type long oil alkyd trees
The one of fat.
Low VOC petroleum solvent is the kerosene (270 DEG C-310 DEG C) of the narrow boiling range of high boiling point；Pigment is
Potassium tungstate cladding lanthanum chromate powder；Inserts is calcene.
The application temperature causes to be irreversibly changed the effect of each component in ink:
Resinon be offset ink mainly comprise composition, it determine rheological characteristic of printing-ink, viscosity,
The character such as drying property, film property and printing performance.Ink can be made to have preferable glossiness, site clear
Completely, rate of drying is fast, printability and good stability.
Colloid oil is the important component part of offset ink, and colloid oil is used in ink and makes ink increase viscosity
And do not increase viscosity, offset ink has the feature glued, improve body bone and site.Ink can be made
There is good viscoelasticity.
Alkyd resin is good to pigment wettability, has excellent levelability and transferability；Ink can be improved
Wettability and the mobility of ink to pigment.
Low VOC petroleum solvent acts primarily as dissolving binder in ink, reduces binder viscosity
Effect.Low VOC petroleum solvent used by the present invention be boiling range be the high boiling point narrow fraction of 270 DEG C-310 DEG C
Kerosene, feature is that the lowest volatilization of initial boiling point is unlikely to too fast and affects the stability of offset ink, evaporates eventually
Point is the highest, does not interferes with the seepage velocity of ink, and then affects ink curing rate on paper.
Pigment is a kind of to have the coloring matter that certain particle size is attritive powder state, is the color producing species of ink
Matter, in the present invention, pigment is that potassium tungstate is coated with lanthanum chromate powder, and it is a kind of along with variations in temperature, color
The thermochromism changed and variable color are irreversible, so that the ink of preparation has temperature induced color changing
Feature.
Inserts is close with film forming matter due to its folding color rate, thus is transparent or semitransparent in ink
, not there is the tinting strength, tinting power of coloring pigment, add and ink can reduce amount of pigment, reduce cost, with
Time also there is regulation ink rheology and thixotropic effect.Inserts used in the present invention is colloid carbon
Acid calcium, it is possible to increase ink stability and printability.
Surfactant has fixing hydrophilic, lipophilic group, can significantly reduce material surface tension force, prevent
Pigment flocculation, makes dispersion be in steady statue.Anti-sassafras agent and ink coordinate, can being dried at ink
Epithelium forms thin film, makes epithelium smooth, improves rub resistance；The viscosity of ink can also be reduced, prevent
Set-off and caking, make ink have resistance to water, repellency and regulation emulsibility, also delustring and prevent crystalline substance
The effects such as change.Anti-sassafras agent used by the present invention is polyethylene cerate, can significantly enhance the rub resistance of printing
And slickness.
Levelling agent is used to improve the flow leveling of ink, prevents the product of the layer of ink disadvantage such as shrinkage cavity and pinprick
Raw, make ink film smooth, it is possible to improve glossiness.
Above-mentioned temperature causes to be irreversibly changed the preparation method of ink, specifically includes following steps:
Step 1, weighs resinon 30%～40% the most respectively, colloid oily 20%～30%,
Alkyd resin 1%～5%, low VOC petroleum solvent 1%～10%, pigment 10%～18%, fill out
Charge 5%～9%, auxiliary agent 5%～9%, the mass percent sum of above each component is 100%；
Step 2, pigment step 1 weighed, resinon, colloid oil, alkyd resin and inserts fill
Divide mixing furnishing pasty state, after being ground to qualified fineness, obtain ink base ink；
Step 3, adds low VOC petroleum solvent and help in step 2 in the ink base ink obtained
Agent, stirs, and obtains temperature and causes to be irreversibly changed ink.
In step 1, pigment is that potassium tungstate is coated with lanthanum chromate powder, and potassium tungstate is coated with the concrete of lanthanum chromate powder
Preparation method is:
Weigh 5% potassium tungstate, 95% Lanthanum Chromite (800 mesh powder), two kinds of components the most by mass percentage
Mass percent sum is 100%；
A2., it is in 40 DEG C～45 DEG C of water that potassium tungstate is dissolved in temperature, is configured to potassium tungstate saturated aqueous solution,
It is subsequently adding Lanthanum Chromite, is sufficiently stirred for, moistening, obtain the liquid/paste of potassium tungstate cladding Lanthanum Chromite；
A3., potassium tungstate is coated with the liquid/paste of Lanthanum Chromite volatilize under field conditions (factors) moisture, after dry, will
The potassium tungstate cladding Lanthanum Chromite of dry shape is fully ground, and is subsequently adding surfactant A, is sufficiently stirred for obtaining；
In a3, surfactant A is sodium polyacrylate, enuatrol and the one of amino propylamine dioleate.
Embodiment 1
Step 1, the pigment of potassium tungstate cladding Lanthanum Chromite makes:
A1, weigh 5% potassium tungstate, 95% Lanthanum Chromite (800 mesh powder) by mass percentage；
A2, potassium tungstate is dissolved in temperature is in 40 DEG C of water, is configured to potassium tungstate saturated aqueous solution, then will
Load weighted Lanthanum Chromite is put in potassium tungstate saturated aqueous solution, is sufficiently stirred for, moistening, obtains potassium tungstate cladding
The liquid/paste of Lanthanum Chromite；
A3, potassium tungstate is coated with the liquid/paste of Lanthanum Chromite volatilizees under field conditions (factors) moisture, after dry,
The potassium tungstate of dry shape is coated with Lanthanum Chromite in grinder, is fully ground into powder, obtain the tungsten that fineness is qualified
The pigment of acid potassium cladding Lanthanum Chromite；
A4, take the pigment powder of the cladding Lanthanum Chromite of the potassium tungstate after grinding, add enuatrol, be sufficiently stirred for
Obtain potassium tungstate cladding Lanthanum Chromite pigment；
Step 2, weighs potassium tungstate cladding Lanthanum Chromite pigment 17%, 218 resins the most respectively
Oil 35%, 588-1 colloid oil 25%, 305 quick-dry type long oil alkyds 4%, high-boiling point kerosene
(270-310 DEG C) 3%, calcene 8%, auxiliary agent 8%, the mass percent of above each component it
With for 100%；Wherein, in auxiliary agent, each component accounts for the percentage ratio of above raw material gross mass and is respectively as follows: surface
Activating agent 0.9%, anti-sassafras agent 5.0%, desiccant 0.6%, defoamer 0.7% and levelling agent 0.8%；
Step 3, by weigh potassium tungstate cladding Lanthanum Chromite pigment, 218 resinons, 588-1 colloid oil,
305 quick-dry type long oil alkyds and calcene are sufficiently mixed furnishing pasty state, be ground to qualified carefully
Ink base ink is obtained after degree；
Step 4, adds high-boiling point kerosene and auxiliary agent in step 3 in the ink base ink obtained, stirring is all
Even, obtain temperature and cause to be irreversibly changed ink.
Wherein, surfactant is enuatrol, and anti-sassafras agent is polyethylene cerate, and desiccant is the acid of cycloalkanes cobalt,
Defoamer is trioctyl phosphate, and levelling agent is Polymethylphenylsilane.
Embodiment 2
Step 1, the pigment of potassium tungstate cladding Lanthanum Chromite makes:
A1, weigh 5% potassium tungstate, 95% Lanthanum Chromite (800 mesh powder) by mass percentage；
A2, potassium tungstate is dissolved in temperature is in 45 DEG C of water, is configured to potassium tungstate saturated aqueous solution, then will
Load weighted Lanthanum Chromite is put in potassium tungstate saturated aqueous solution, is sufficiently stirred for, moistening, obtains potassium tungstate cladding
The liquid/paste of Lanthanum Chromite；
A3, potassium tungstate is coated with the liquid/paste of Lanthanum Chromite volatilizees under field conditions (factors) moisture, after dry,
The potassium tungstate of dry shape is coated with Lanthanum Chromite in grinder, is fully ground into powder, obtain the tungsten that fineness is qualified
Acid potassium cladding lanthanum chromate powder；
A4, take the cladding lanthanum chromate powder of the potassium tungstate after grinding, add sodium polyacrylate, after being sufficiently stirred for
Obtain potassium tungstate cladding Lanthanum Chromite pigment；
Step 2, claims potassium tungstate cladding Lanthanum Chromite pigment 14%, 289 resinons the most respectively
37%, 584-1 colloid oil 22%, 305 quick-dry type long oil alkyds 2%, high-boiling point kerosene
(270-310 DEG C) 10%, calcene 6%, auxiliary agent 9%, the mass percent of above each component
Sum is 100%；Wherein, in auxiliary agent, each component accounts for the percentage ratio of above raw material gross mass and is respectively as follows: table
Face activating agent 1%, anti-sassafras agent 5.0%, desiccant 1.0%, defoamer 1.0% and levelling agent 1.0%；
Step 3, by weigh potassium tungstate cladding Lanthanum Chromite pigment, 289 resinons, 584-1 colloid oil,
305 quick-dry type long oil alkyds and calcene are sufficiently mixed furnishing pasty state, be ground to qualified carefully
Ink base ink is obtained after degree；
Step 4, adds high-boiling point kerosene and auxiliary agent in step 3 in the ink base ink obtained, stirring is all
Even, obtain temperature and cause to be irreversibly changed ink.
Wherein, surfactant is sodium polyacrylate, and anti-sassafras agent is polyethylene cerate, and desiccant is cycloalkanes
Cobalt acid, defoamer is trioctyl phosphate, and levelling agent is Polymethylphenylsilane.
Embodiment 3
Step 1, the pigment of potassium tungstate cladding Lanthanum Chromite makes:
A1, weigh 5% potassium tungstate, 95% Lanthanum Chromite (800 mesh powder) by mass percentage；
A2, potassium tungstate is dissolved in temperature is in 42 DEG C of water, is configured to potassium tungstate saturated aqueous solution, then will
Load weighted Lanthanum Chromite is put in potassium tungstate saturated aqueous solution, is sufficiently stirred for, moistening, obtains potassium tungstate cladding
The liquid/paste of Lanthanum Chromite；
A3, potassium tungstate is coated with the liquid/paste of Lanthanum Chromite volatilizees under field conditions (factors) moisture, after dry,
The potassium tungstate of dry shape is coated with Lanthanum Chromite in grinder, is fully ground into powder, obtain the tungsten that fineness is qualified
Acid potassium cladding lanthanum chromate powder；
A4, take the cladding lanthanum chromate powder of the potassium tungstate after grinding, add enuatrol, obtain after being sufficiently stirred for
Potassium tungstate cladding Lanthanum Chromite pigment；
Step 2, weighs potassium tungstate cladding Lanthanum Chromite pigment 18%, 289 resins the most respectively
Oil 33%, 588-1 colloid oil 26%, 305 quick-dry type long oil alkyds 4%, high-boiling point kerosene
(270-310 DEG C) 4%, calcene 8%, auxiliary agent 7%, the mass percent of above each component it
With for 100%；Wherein, in auxiliary agent, each component accounts for the percentage ratio of above raw material gross mass and is respectively as follows: surface
Activating agent 0.8%, anti-sassafras agent 4.0%, desiccant 0.8%, defoamer 0.9% and levelling agent 0.5%；
Step 3, by weigh potassium tungstate cladding Lanthanum Chromite pigment, 289 resinons, 588-1 colloid oil,
305 quick-dry type long oil alkyds and calcene are sufficiently mixed furnishing pasty state, be ground to qualified carefully
Ink base ink is obtained after degree；
Step 4, adds high-boiling point kerosene and auxiliary agent in step 3 in the ink base ink obtained, stirring is all
Even, obtain temperature and cause to be irreversibly changed ink.
Wherein surfactant is enuatrol, and anti-sassafras agent is synthesis paraffin, and desiccant is manganese borate and boric acid
The mixture of cobalt 1:1, defoamer is middle federal B-0941, and levelling agent is polydimethylsiloxane.
Embodiment 4
Step 1, the pigment of potassium tungstate cladding Lanthanum Chromite makes:
A1, weigh 5% potassium tungstate, 95% Lanthanum Chromite (800 mesh powder) by mass percentage；
A2, potassium tungstate is dissolved in temperature is in 40 DEG C of water, is configured to potassium tungstate saturated aqueous solution, then will
Load weighted Lanthanum Chromite is put in potassium tungstate saturated aqueous solution, is sufficiently stirred for, moistening, obtains potassium tungstate cladding
The liquid/paste of Lanthanum Chromite；
A3, potassium tungstate is coated with the liquid/paste of Lanthanum Chromite volatilizees under field conditions (factors) moisture, after dry,
The potassium tungstate of dry shape is coated with Lanthanum Chromite in grinder, is fully ground into powder, obtain the tungsten that fineness is qualified
Acid potassium cladding lanthanum chromate powder；
A4, take the cladding lanthanum chromate powder of the potassium tungstate after grinding, add amino propylamine dioleate, fully
Potassium tungstate cladding Lanthanum Chromite pigment is obtained after stirring；
Step 2, weighs potassium tungstate cladding Lanthanum Chromite pigment 10%, JC3135 tree the most respectively
Fatty oil 40%, JC3184 colloid oil 30%, JC115 alkyd resin 3%, high-boiling point kerosene (270-310 DEG C)
7%, calcene 5%, auxiliary agent 5%, the mass percent sum of above each component is 100%；Its
In, in auxiliary agent each component account for the percentage ratio of above raw material gross mass be respectively as follows: surfactant 0.6%,
Anti-sassafras agent 2.0%, desiccant 0.5%, defoamer 0.9% and levelling agent 1.0%；
Step 3, is coated with Lanthanum Chromite pigment, JC3135 resinon, JC3184 colloid oil, JC115 by potassium tungstate
Alkyd resin and calcene are sufficiently mixed furnishing pasty state, obtain ink base after being ground to qualified fineness
Ink；
Step 4, adds high-boiling point kerosene and auxiliary agent in step 3 in the ink base ink obtained, stirring is all
Even, obtain temperature and cause to be irreversibly changed ink.
Wherein surfactant makes as enuatrol, and anti-sassafras agent is oleamide, and desiccant is manganese borate and boron
The mixture of acid cobalt 1:1, defoamer is middle federal B-0942, and levelling agent is Polymethylphenylsilane.
Embodiment 5
Step 1, the pigment of potassium tungstate cladding Lanthanum Chromite makes:
A1, weigh 5% potassium tungstate, 95% Lanthanum Chromite (800 mesh powder) by mass percentage；
A2, potassium tungstate is dissolved in temperature is in 45 DEG C of water, is configured to potassium tungstate saturated aqueous solution, then will
Load weighted Lanthanum Chromite is put in potassium tungstate saturated aqueous solution, is sufficiently stirred for, moistening, obtains potassium tungstate cladding
The liquid/paste of Lanthanum Chromite；
A3, potassium tungstate is coated with the liquid/paste of Lanthanum Chromite volatilizees under field conditions (factors) moisture, after dry,
The potassium tungstate of dry shape is coated with Lanthanum Chromite in grinder, is fully ground into powder, obtain the tungsten that fineness is qualified
Acid potassium cladding lanthanum chromate powder；
A4, take the cladding lanthanum chromate powder of the potassium tungstate after grinding, add sodium polyacrylate, after being sufficiently stirred for
Obtain potassium tungstate cladding Lanthanum Chromite pigment；
Step 2, weighs potassium tungstate cladding Lanthanum Chromite pigment 16%, JC3189 tree the most respectively
Fatty oil 30%, JC3184 colloid oil 29%, JC115 alkyd resin 1%, high-boiling point kerosene (270-310 DEG C)
9%, calcene 9%, auxiliary agent 6%, the mass percent sum of above each component is 100%；Its
In, in auxiliary agent each component account for the percentage ratio of above raw material gross mass be respectively as follows: surfactant 0.8%,
Anti-sassafras agent 3.0%, desiccant 0.5%, defoamer 0.9% and levelling agent 0.8%；
Step 3, is coated with Lanthanum Chromite pigment, JC3189 resinon, JC3184 colloid oil, JC115 by potassium tungstate
Alkyd resin and calcene are sufficiently mixed furnishing pasty state, obtain ink base after being ground to qualified fineness
Ink；
Step 4, adds high-boiling point kerosene and auxiliary agent in step 3 in the ink base ink obtained, stirring is all
Even, obtain temperature and cause to be irreversibly changed ink.
Wherein surfactant uses enuatrol, and anti-sassafras agent uses Tissuemat E, and desiccant uses naphthoic acid cobalt,
Defoamer uses dimethyl polysiloxane, and levelling agent uses organic-silicon-modified siloxanes.
Embodiment 6
Step 1, the pigment of potassium tungstate cladding Lanthanum Chromite makes:
A1, weigh 5% potassium tungstate, 95% Lanthanum Chromite (800 mesh powder) by mass percentage；
A2, potassium tungstate is dissolved in temperature is in 43 DEG C of water, is configured to potassium tungstate saturated aqueous solution, then will
Load weighted Lanthanum Chromite is put in potassium tungstate saturated aqueous solution, is sufficiently stirred for, moistening, obtains potassium tungstate cladding
The liquid/paste of Lanthanum Chromite；
A3, potassium tungstate is coated with the liquid/paste of Lanthanum Chromite volatilizees under field conditions (factors) moisture, after dry,
The potassium tungstate of dry shape is coated with Lanthanum Chromite in grinder, is fully ground into powder, obtain the tungsten that fineness is qualified
Acid potassium cladding lanthanum chromate powder；
A4, take the cladding lanthanum chromate powder of the potassium tungstate after grinding, add enuatrol, obtain after being sufficiently stirred for
Potassium tungstate cladding Lanthanum Chromite pigment；
Step 2, weighs potassium tungstate cladding Lanthanum Chromite pigment 15%, JC3118 tree the most respectively
Fatty oil 34%, 584-1 colloid oil 28%, JC117B alkyd resin 5%, high-boiling point kerosene (270-310 DEG C)
1%, calcene 9%, auxiliary agent 8%, the mass percent sum of above each component is 100%；Its
In, in auxiliary agent each component account for the percentage ratio of above raw material gross mass be respectively as follows: surfactant 0.8%,
Anti-sassafras agent 4.8%, desiccant 0.5%, defoamer 0.9% and levelling agent 1.0%；
Step 3, is coated with Lanthanum Chromite pigment, JC3118 resinon, 584-1 colloid oil, JC117B by potassium tungstate
Alkyd resin and calcene are sufficiently mixed furnishing pasty state, obtain ink base after being ground to qualified fineness
Ink；
Step 4, adds high-boiling point kerosene and auxiliary agent in step 3 in the ink base ink obtained, stirring is all
Even, obtain temperature and cause to be irreversibly changed ink.
Wherein surfactant uses sodium polyacrylate, and anti-sassafras agent uses polyphenyl methyl siloxane, is dried
Agent uses naphthoic acid cobalt, and defoamer is federal B-0942 in using, and levelling agent uses polydimethylsiloxane.
Claims (10)
1. a temperature causes to be irreversibly changed ink, it is characterised in that by mass percentage by following components group
Become: resinon 30%～40%, colloid oil 20%～30%, alkyd resin 1%～5%, low organic wave
Stimulating food petroleum solvent 1%～10%, pigment 10%～18%, inserts 5%～9%, auxiliary agent 5%～9%,
The mass percent sum of the most each component is 100%.
Temperature the most according to claim 1 causes to be irreversibly changed ink, it is characterised in that auxiliary agent is table
Face activating agent, anti-sassafras agent, desiccant, defoamer and the mixture of levelling agent composition, each component in auxiliary agent
Accounting for the warm percentage ratio causing to be irreversibly changed ink gross mass is: surfactant 0.1%～1.0%, anti-sassafras
Agent 2.0%～5.0%, desiccant 0.2%～1.0%, defoamer 0.5%～1.0% and levelling agent 0.1%～
1.0%.
Temperature the most according to claim 2 causes to be irreversibly changed ink, it is characterised in that surface activity
Agent is sodium polyacrylate, enuatrol and the one of amino propylamine dioleate；Anti-sassafras agent be oleamide,
Synthesis paraffin, polyethylene cerate, polypropylene wax and the one of polyphenyl methyl siloxane；Desiccant is vinegar
Acid cobalt, naphthoic acid cobalt, cobalt naphthenate, lead borate and the one of manganese borate or therein two kinds by weight 1:
The mixture of 1 composition；Defoamer is middle federal B-0941, middle federal B-0942, middle federal B-0943,
Trioctyl phosphate and the one of dimethyl polysiloxane；Levelling agent is polydimethylsiloxane, polymethyl-benzene
One in base silane and organic-silicon-modified siloxanes.
Temperature the most according to claim 1 causes to be irreversibly changed ink, it is characterised in that resinon is
218 resinons, 289 resinons, JC3135 resinon, JC3189 resinon, JC3183 resinon
One with JC3118 resinon；Colloid oil is 588-1 colloid oil, 584-1 colloid oil, DC3110
Colloid oil, DC3106 colloid oil, JC3184 colloid oil and the one of JC3118 colloid oil；Alkyd tree
Fat is JC115 alkyd resin, JC117B alkyd resin and the one of 305 quick-dry type long oil alkyds
Kind.
Temperature the most according to claim 1 causes to be irreversibly changed ink, it is characterised in that low organic wave
Stimulating food petroleum solvent is the kerosene of the narrow boiling range of high boiling point；Pigment is that potassium tungstate is coated with lanthanum chromate powder；Fill
Material is calcene.
6. a temperature causes to be irreversibly changed the preparation method of ink, it is characterised in that specifically include following step
Rapid:
Step 1, weighs resinon 30%～40% the most respectively, colloid oily 20%～30%,
Alkyd resin 1%～5%, low VOC petroleum solvent 1%～10%, pigment 10%～18%, fill out
Charge 5%～9%, auxiliary agent 5%～9%, the mass percent sum of above each component is 100%；
Step 2, pigment step 1 weighed, resinon, colloid oil, alkyd resin and inserts fill
Divide mixing furnishing pasty state, grind and obtain ink base ink；
Step 3, adds low VOC petroleum solvent and help in step 2 in the ink base ink obtained
Agent, stirs, and obtains temperature and causes to be irreversibly changed ink.
Temperature the most according to claim 6 causes to be irreversibly changed the preparation method of ink, it is characterised in that
In step 1, pigment is that potassium tungstate is coated with lanthanum chromate powder, the concrete preparation of potassium tungstate cladding lanthanum chromate powder
Method is:
Weigh 5% potassium tungstate the most by mass percentage, 95% Lanthanum Chromite, two kinds of constituent mass percentage ratio it
With for 100%；
A2., it is in 40 DEG C～45 DEG C of water that potassium tungstate is dissolved in temperature, is configured to potassium tungstate saturated aqueous solution,
It is subsequently adding Lanthanum Chromite, is sufficiently stirred for, moistening, obtain the liquid/paste of potassium tungstate cladding Lanthanum Chromite；
A3., potassium tungstate is coated with the liquid/paste of Lanthanum Chromite volatilize under field conditions (factors) moisture, after dry, will
The potassium tungstate cladding Lanthanum Chromite of dry shape is fully ground, and is subsequently adding surfactant A, is sufficiently stirred for obtaining；
In a3, surfactant A is sodium polyacrylate, enuatrol and the one of amino propylamine dioleate.
Temperature the most according to claim 6 causes to be irreversibly changed the preparation method of ink, it is characterised in that
In step 1, resinon is 218 resinons, 289 resinons, JC3135 resinon, JC3189 resin
Oil, JC3183 resinon and the one of JC3118 resinon；Colloid oil is 588-1 colloid oil, 584-1
Colloid oil, DC3110 colloid oil, DC3106 colloid oil, JC3184 colloid oil and JC3118 colloid oil
One；Alkyd resin is JC115 alkyd resin, JC117B alkyd resin and 305 quick-dry type long oils
The one of degree alkyd resin；Low VOC petroleum solvent is the kerosene of the narrow boiling range of high boiling point；Inserts
For calcene.
Temperature the most according to claim 6 causes to be irreversibly changed the preparation method of ink, it is characterised in that
In step 1, auxiliary agent is surfactant, anti-sassafras agent, desiccant, defoamer and the mixing of levelling agent composition
Thing, in auxiliary agent, each component accounts for temperature and causes to be irreversibly changed the percentage ratio of ink gross mass and is: surfactant
0.1%～1.0%, anti-sassafras agent 2.0%～5.0%, desiccant 0.2%～1.0%, defoamer 0.5%～1.0%
With levelling agent 0.1%～1.0%.
Temperature the most according to claim 9 causes to be irreversibly changed the preparation method of ink, and its feature exists
In, surfactant is sodium polyacrylate, enuatrol and the one of amino propylamine dioleate；Anti-sassafras agent
For oleamide, synthesis paraffin, polyethylene cerate, polypropylene wax and the one of polyphenyl methyl siloxane；
Desiccant is the one of cobaltous acetate, naphthoic acid cobalt, cobalt naphthenate, lead borate and manganese borate or two kinds therein
Mixture by weight 1:1 composition；Defoamer is middle federal B-0941, middle federal B-0942, in
Federal B-0943, trioctyl phosphate and the one of dimethyl polysiloxane；Levelling agent is polydimethylsiloxanes
One in alkane, Polymethylphenylsilane and organic-silicon-modified siloxanes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610459300.5A CN105860672B (en) | 2016-06-22 | 2016-06-22 | A kind of cause of temperature is irreversibly changed ink and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610459300.5A CN105860672B (en) | 2016-06-22 | 2016-06-22 | A kind of cause of temperature is irreversibly changed ink and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105860672A true CN105860672A (en) | 2016-08-17 |
| CN105860672B CN105860672B (en) | 2019-07-23 |
Family
ID=56650164
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610459300.5A Expired - Fee Related CN105860672B (en) | 2016-06-22 | 2016-06-22 | A kind of cause of temperature is irreversibly changed ink and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105860672B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106752313A (en) * | 2017-01-04 | 2017-05-31 | 湖北中烟工业有限责任公司 | A kind of cigarette perfuming ink and its preparation method and application |
| CN109796813A (en) * | 2019-01-16 | 2019-05-24 | 深圳九星印刷包装集团有限公司 | Color shifting ink and preparation method thereof and its application |
| CN113122046A (en) * | 2021-04-27 | 2021-07-16 | 中山市富日印刷材料有限公司 | High-gloss quick-drying non-skinning printing ink and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1086246A (en) * | 1992-10-27 | 1994-05-04 | 中国科学院电子学研究所 | Colored thermally indicating material |
| CN104987766A (en) * | 2015-03-31 | 2015-10-21 | 安徽省嘉信包装印务有限公司 | Offset printing black ink formula |
-
2016
- 2016-06-22 CN CN201610459300.5A patent/CN105860672B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1086246A (en) * | 1992-10-27 | 1994-05-04 | 中国科学院电子学研究所 | Colored thermally indicating material |
| CN104987766A (en) * | 2015-03-31 | 2015-10-21 | 安徽省嘉信包装印务有限公司 | Offset printing black ink formula |
Non-Patent Citations (1)
| Title |
|---|
| 凌云星等: "《实用油墨技术指南》", 30 November 2007, 印刷工业出版社 * |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106752313A (en) * | 2017-01-04 | 2017-05-31 | 湖北中烟工业有限责任公司 | A kind of cigarette perfuming ink and its preparation method and application |
| CN109796813A (en) * | 2019-01-16 | 2019-05-24 | 深圳九星印刷包装集团有限公司 | Color shifting ink and preparation method thereof and its application |
| CN109796813B (en) * | 2019-01-16 | 2021-11-19 | 深圳九星印刷包装集团有限公司 | Color-changing ink and preparation method and application thereof |
| CN113122046A (en) * | 2021-04-27 | 2021-07-16 | 中山市富日印刷材料有限公司 | High-gloss quick-drying non-skinning printing ink and preparation method thereof |
| CN113122046B (en) * | 2021-04-27 | 2022-06-28 | 中山市富日印刷材料有限公司 | High-gloss quick-drying non-skinning printing ink and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105860672B (en) | 2019-07-23 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106833116B (en) | A kind of aqueous polyurethane printing ink and its preparation process | |
| CN107286732A (en) | A kind of water-based plastic inner printing is combined gravure printing ink and preparation method thereof | |
| CN100575423C (en) | A kind of advertisement poster pigment composition, advertisement poster pigment and preparation method thereof | |
| CN105860672A (en) | Irreversible thermochromic ink and preparation method thereof | |
| CN103666090B (en) | Alcohol-soluble environment-friendly printing ink for tipping paper and preparation method thereof | |
| CN104177917A (en) | Alcohol-soluble environment-friendly high-speed surface printing ink and preparation method thereof | |
| CN107778979A (en) | The sub- gravure ink of the general mute black appliances of insulation of PET and PI films and preparation method | |
| CN106590162B (en) | Water-based gravure plastic film surface printing ink and preparation method thereof | |
| CN101864210A (en) | Alcohol-soluble printing ink and preparation method thereof | |
| CN1290728A (en) | Water ink for plastic film relief printing and its producing method | |
| CN110698914A (en) | Water-based gravure matte gloss oil and preparation method thereof | |
| CN107337959B (en) | A kind of environmental printing ink | |
| CN103436098B (en) | Ultraviolet-curing offset printing ink and preparation method thereof | |
| CN106170519A (en) | Black ink composition | |
| CN106147401A (en) | A kind of preparation method of heat-sensitive colour-changing ink | |
| CN104830142A (en) | Environmental-friendly viscosity reducer used for printing ink | |
| CN105086608A (en) | Degradable UV offset printing ink and preparing method thereof | |
| CN106221360A (en) | High speed printing adaptive rub resistance environment-friendly ink | |
| CN103289478B (en) | Alcohol type gravure surface printing ink and preparation method thereof | |
| CN104559444B (en) | One kind printing simulating golden colour ink formulations and preparation method thereof | |
| CN105315782A (en) | Water-based paint gloss oil | |
| CN106280695A (en) | A kind of water color ink print film and preparation method thereof | |
| CN103589229B (en) | Brilliant black environment-friendly printing ink and preparation method thereof | |
| CN106433298A (en) | Binder and environment-friendly offset rotary ink containing same | |
| CN105713451A (en) | Benzene-free environment-friendly high-tolerance gravure ink |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20190723 |