CN104031469A - Formula of lithographic offset printing ink - Google Patents

Formula of lithographic offset printing ink Download PDF

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Publication number
CN104031469A
CN104031469A CN201410297866.3A CN201410297866A CN104031469A CN 104031469 A CN104031469 A CN 104031469A CN 201410297866 A CN201410297866 A CN 201410297866A CN 104031469 A CN104031469 A CN 104031469A
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CN
China
Prior art keywords
pigment
oil
binder
filler
additional material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201410297866.3A
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Chinese (zh)
Inventor
朱家昆
朱晓珍
刘瑞
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zhu Shi Yin Wu Of Fanchang County LLC
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Zhu Shi Yin Wu Of Fanchang County LLC
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Application filed by Zhu Shi Yin Wu Of Fanchang County LLC filed Critical Zhu Shi Yin Wu Of Fanchang County LLC
Priority to CN201410297866.3A priority Critical patent/CN104031469A/en
Publication of CN104031469A publication Critical patent/CN104031469A/en
Pending legal-status Critical Current

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Abstract

The invention relates to a formula of lithographic offset printing ink. The formula comprises the following components in percentage by mass: 30-50% of pigment, 10-30% of binder, 10-40% of filler and 5-20% of additional material, wherein the pigment is an organic pigment, the binder is prepared by dissolving natural resin, synthetic resin, cellulose and rubber derivatives in drying oil or a solvent, the filler is one or more selected from calcium carbonate, magnesium carbonate, barium sulfate, aluminum hydroxide, aluminum silicate and lithopone and the additional material comprises a desiccant, a diluent, a withdraw adhesive and a plasticizer. The formula of the ink is stable and reliable, and has the characteristics of good smoothness and bright color; during use, the color can be maintained in longer time, ingredients used are nontoxic and harmless and have an environment-friendly effect, and the used materials are convenient in sampling and suitable for printing.

Description

A kind of offset lithographic ink formulations
Technical field
The present invention relates to a kind of offset lithographic ink formulations, belong to printing technology.
Background technology
The manufacture of ink is a complicated chemical engineering, and its material has related to organic polymer and synthesized and redox, diazotization, replacement(metathesis)reaction, the chemical transformation such as complex reaction.Meanwhile, relate to mechanics, optics, chromatism, surface chemistry etc. and learn material.The firstth, the manufacture of various pigment and the manufacture of stopping composition.The secondth, the manufacture of various synthetic resins and the production of various types of low-melting ink vehicles, be dissolved in solid resin in vegetables oil, Dormant oils, solvent medium.The 3rd is the manufacture of ink.These three processes are to be mutually related, interactive, indispensable.In offset printing process, also higher to the specification of quality of ink, not only require to meet certain viscosity, also will have certain work-ing life and hue preserving, therefore, ink formulations often relates to plurality of raw materials composition, composition used not necessarily, also causes ink quality otherness obvious.
Summary of the invention
The object of the present invention is to provide a kind of offset lithographic ink formulations, to can prepare steady quality, flexographic ink formula easy to use, improves the effect of offset lithographic with this, extends ink functional quality and stability.
To achieve these goals, technical scheme of the present invention is as follows.
An offset lithographic ink formulations, is comprised of pigment, binder, filler, additional material, and it is that pigment accounts for 30~50% according to mass percent that above-mentioned each component forms, and binder accounts for 10~30%, filler accounts for 10~40%, additional material accounts for 5~20%.
Further, described pigment is pigment dyestuff, and this pigment dyestuff comprises one or several in sylvic oil, gummy oil or refining long oil alkyd.Wherein, resin oil viscosity is 33000-43000mPas at 25 ℃, and colloid oil viscosity is 100000-200000mPas at 25 ℃.
Further, described binder is that natural resin, synthetic resins, Mierocrystalline cellulose, rubber derivative are dissolved in siccative oil or solvent and make.
Further, described filler be in calcium carbonate, magnesiumcarbonate, barium sulfate, aluminium hydroxide, gloss white or pure aluminium silicate one or several.
Further, described additional material comprises siccative, thinner, removes stick, softening agent, described siccative is the organic or inorganic compound containing cobalt, manganese, lead, zinc, iron, calcium, vanadium, zirconium metallic element, and described thinner is one or several in aluminium hydroxide, barium sulfate or titanium dioxide; Described remove stick be in aluminum stearate, eight aluminium carbonates, oleum lini, low-viscosity Synolac or paraffin oil one or several; Described softening agent is polyvinyl chloride or phthalic ester.
In this invention formula, each several part effect is as follows:
(1) pigment: pigment plays coloration in ink, it has the direct powder that affects the high degree of dispersion of colour, black or white that pigment is water insoluble and organic solvent to some characteristics of ink again.Of the present invention is pigment dyestuff, and wide in variety, color is more complete, and performance is better than mineral dye.Dyestuff is organic compound, and its water soluble is also dissolved in organic solvent sometimes.The pigment using in printing-ink is required quite high, particularly color, dispersity, photostabilization, transparency etc., require the tone of coloured pigment to approach spectral color, saturation ratio should be large as far as possible, three-colour printing ink magenta used, green grass or young crops, yellow ultramarine transparency must be high, and all pigment is not only wanted water tolerance, and will be quickly and evenly and binder combination, the oil absorption of pigment should be too not large, and pigment preferably has the performances such as alkaline-resisting, acidproof, resistance to alcohol and resistance to gesture.
(2) binder: binder is the chief component composition of ink, plays dispersed color, give ink suitable clinging, mobility and transfer printing performance, and by film forming, make pigment be bonded to the effect of printed matter surface after printing.The rheological of ink, viscosity, neutrality, acid number, color and luster, water resisting property and printing performance etc. depend primarily on binder, and same pigment, is used different binders, can be made into dissimilar ink; And same binder is used different pigment.Made is still the ink of same type, because it can not change the basic performance of ink, so the quality of ink, except outside the Pass having with pigment, depends primarily on binder.
(3) filler: filler is white, transparent, translucent or uncomfortable bright flour.The main packing action that rises, filling pigment part, suitably adopts a little fillers, both can reduce amount of pigment, reduce costs, the character of adjustable ink again, as rare thick, mobility etc., the handiness that also improves formulating of recipe.
(4) additional material: additional material is in ink manufacture, and in printing is used, for improving some additional materials of performance of ink itself.Ink by essentially consist preparation, still can not meet the demands aspect some characteristic, or due to the variation of condition, and the printing that can not meet is used while requiring, and must add a small amount of subsidiary material to solve.Additional material has many, as: siccative, thinner, remove stick, softening agent etc.
This beneficial effect of the invention is: above-mentioned ink formulations, and reliable and stable, fluency is good, bright-colored, in use procedure, can stand the maintenance color of longer time, and composition used is nontoxic, there is environmental-protection function, and material used sampling is convenient, is applicable to printing and uses.
Embodiment
Below in conjunction with embodiment, the specific embodiment of the present invention is described, to better understand the present invention.
embodiment 1
Offset lithographic ink formulations in the present embodiment, is comprised of pigment, binder, filler, additional material, and it is that pigment accounts for 30% according to mass percent that above-mentioned each component forms, and binder accounts for 10%, filler accounts for 40%, additional material accounts for 20%.Described pigment is pigment dyestuff, and this pigment dyestuff is sylvic oil, and viscosity at 25 ℃ is
33000-40000mPa·s。Described binder is that natural resin, synthetic resins are dissolved in siccative oil or solvent and make.Described filler is calcium carbonate, magnesiumcarbonate, barium sulfate mixture.Described additional material comprises siccative, thinner, removes stick, softening agent, and described siccative is the organic or inorganic compound containing cobalt, manganese, lead, zinc, iron, calcium, vanadium, zirconium metallic element, and described thinner is aluminium hydroxide; The described stick of removing is aluminum stearate, eight aluminium carbonates; Described softening agent is polyvinyl chloride.
embodiment 2
Offset lithographic ink formulations in the present embodiment, is comprised of pigment, binder, filler, additional material, and it is that pigment accounts for 50% according to mass percent that above-mentioned each component forms, and binder accounts for 20%, filler accounts for 20%, additional material accounts for 10%.Described pigment is pigment dyestuff, and this pigment dyestuff is gummy oil, and colloid oil viscosity is 100000-200000mPas at 25 ℃.Described binder is that Mierocrystalline cellulose, rubber derivative are dissolved in siccative oil or solvent and make.Described filler is barium sulfate, aluminium hydroxide, gloss white mixture.Described additional material comprises siccative, thinner, removes stick, softening agent, and described siccative is the organic or inorganic compound of calcic, vanadium, zirconium metallic element, and described thinner is barium sulfate; The described stick of removing is oleum lini, low-viscosity alkyd resin mixture; Described softening agent is phthalic ester.
embodiment 3
Offset lithographic ink formulations in the present embodiment, is comprised of pigment, binder, filler, additional material, and it is that pigment accounts for 40% according to mass percent that above-mentioned each component forms, and binder accounts for 20%, filler accounts for 30%, additional material accounts for 10%.Described pigment is pigment dyestuff, and this pigment dyestuff is refining long oil alkyd.Described binder is that synthetic resins, Mierocrystalline cellulose are dissolved in siccative oil and make.Described filler is barium sulfate, aluminium hydroxide, gloss white or pure aluminium silicate mixture.Described additional material comprises siccative, thinner, removes stick, softening agent, and described siccative is the organic or inorganic compound containing zinc, iron, calcium metallic element, and described thinner is barium sulfate; The described stick of removing is oleum lini, low-viscosity alkyd resin mixture.Described softening agent is polyvinyl chloride.
The above is the preferred embodiment of the present invention; it should be pointed out that for those skilled in the art, under the premise without departing from the principles of the invention; can also make some improvements and modifications, these improvements and modifications are also considered as protection scope of the present invention.

Claims (5)

1. an offset lithographic ink formulations, it is characterized in that: by pigment, binder, filler, additional material, formed, it is that pigment accounts for 30~50% according to mass percent that above-mentioned each component forms, and binder accounts for 10~30%, filler accounts for 10~40%, additional material accounts for 5~20%.
2. offset lithographic ink formulations according to claim 1, is characterized in that: described pigment is pigment dyestuff, and this pigment dyestuff comprises one or several in sylvic oil, gummy oil or refining long oil alkyd; Described resin oil viscosity is 33000-43000mPas at 25 ℃, and described colloid oil viscosity is 100000-200000mPas at 25 ℃.
3. offset lithographic ink formulations according to claim 1, is characterized in that: described binder is that natural resin, synthetic resins, Mierocrystalline cellulose, rubber derivative are dissolved in siccative oil or solvent and make.
4. offset lithographic ink formulations according to claim 1, is characterized in that: described filler be in calcium carbonate, magnesiumcarbonate, barium sulfate, aluminium hydroxide, gloss white or pure aluminium silicate one or several.
5. offset lithographic ink formulations according to claim 1, it is characterized in that: described additional material comprises siccative, thinner, removes stick, softening agent, described siccative is the organic or inorganic compound containing cobalt, manganese, lead, zinc, iron, calcium, vanadium, zirconium metallic element, and described thinner is one or several in aluminium hydroxide, barium sulfate or titanium dioxide; Described remove stick be in aluminum stearate, eight aluminium carbonates, oleum lini, low-viscosity Synolac or paraffin oil one or several; Described softening agent is polyvinyl chloride or phthalic ester.
CN201410297866.3A 2014-06-29 2014-06-29 Formula of lithographic offset printing ink Pending CN104031469A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106497224A (en) * 2016-11-25 2017-03-15 河南工程学院 A kind of ink adhesive based on Bacterial cellulose and preparation method thereof
CN106928767A (en) * 2015-12-29 2017-07-07 天津天女化工集团股份有限公司 A kind of offset printing environment protecting plant oil-based ink
CN108357218A (en) * 2018-02-07 2018-08-03 福建鸣友新材料科技有限公司 A kind of anti-fake carbon ribbon of thermal transfer and its retracting device
CN113214706A (en) * 2021-04-27 2021-08-06 北京伊诺尔印务有限公司 Printing ink for thermal printing paper and preparation method thereof
CN114345173A (en) * 2021-12-14 2022-04-15 苏州市大象印刷包装有限公司 Environment-friendly material manufacturing process and device applied to printing and packaging

Citations (1)

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Publication number Priority date Publication date Assignee Title
CN101289587A (en) * 2007-12-17 2008-10-22 上海牡丹油墨有限公司 Joint material for waterless hectograph ink

Patent Citations (1)

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Publication number Priority date Publication date Assignee Title
CN101289587A (en) * 2007-12-17 2008-10-22 上海牡丹油墨有限公司 Joint material for waterless hectograph ink

Non-Patent Citations (1)

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Title
百度文库: "平版胶印四色墨配方表", 《HTTP://WENKU.BAIDU.COM/LINK?URL=CAHMSCWJCNZ9QKYZYINEMOBJXNVRGVK5HTEZ6UX3DEWXR4VVJUBLVEVCPOWLE_AWGRXKGWSVRFHR0ZO0LZNP1TJYK5IOKB4BUWXPVWWPYT3》, 12 June 2010 (2010-06-12), pages 1 - 4 *

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106928767A (en) * 2015-12-29 2017-07-07 天津天女化工集团股份有限公司 A kind of offset printing environment protecting plant oil-based ink
CN106497224A (en) * 2016-11-25 2017-03-15 河南工程学院 A kind of ink adhesive based on Bacterial cellulose and preparation method thereof
CN106497224B (en) * 2016-11-25 2019-08-02 河南工程学院 A kind of ink adhesive and preparation method thereof based on bacteria cellulose
CN108357218A (en) * 2018-02-07 2018-08-03 福建鸣友新材料科技有限公司 A kind of anti-fake carbon ribbon of thermal transfer and its retracting device
CN113214706A (en) * 2021-04-27 2021-08-06 北京伊诺尔印务有限公司 Printing ink for thermal printing paper and preparation method thereof
CN114345173A (en) * 2021-12-14 2022-04-15 苏州市大象印刷包装有限公司 Environment-friendly material manufacturing process and device applied to printing and packaging

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Application publication date: 20140910