CN106167646A - A kind of organic ink of degradable and manufacture method thereof - Google Patents

A kind of organic ink of degradable and manufacture method thereof Download PDF

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Publication number
CN106167646A
CN106167646A CN201610650302.2A CN201610650302A CN106167646A CN 106167646 A CN106167646 A CN 106167646A CN 201610650302 A CN201610650302 A CN 201610650302A CN 106167646 A CN106167646 A CN 106167646A
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CN
China
Prior art keywords
parts
organic
degradable
ink
auxiliary agents
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610650302.2A
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Chinese (zh)
Inventor
张东明
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Central Asia Suzhou Ink Co Ltd
Original Assignee
Central Asia Suzhou Ink Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Central Asia Suzhou Ink Co Ltd filed Critical Central Asia Suzhou Ink Co Ltd
Priority to CN201610650302.2A priority Critical patent/CN106167646A/en
Publication of CN106167646A publication Critical patent/CN106167646A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/106Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C09D11/107Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/03Printing inks characterised by features other than the chemical nature of the binder
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/03Printing inks characterised by features other than the chemical nature of the binder
    • C09D11/037Printing inks characterised by features other than the chemical nature of the binder characterised by the pigment
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/106Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)

Abstract

The invention discloses a kind of organic ink of degradable and manufacture method thereof.It is made up of maleic acrylic copolymer, polyhydric alcohol, Petropols, multi-functional acrylate, organic pigment, Colophonium, organic solvent, special decoloring agent and other auxiliary agents.The present invention is formed by plurality of raw materials rational proportion, and special decolorising agent is sodium dithionite.In the present invention, organic pigment and decolorising agent play respective advantage, the organic ink of degradable prepared has the advantages such as bright color, stable performance and recovery be degradable, the feature of environmental protection is strong simultaneously, overcomes that organic ink contamination is big, the shortcoming of organic oil ink print thing difficult degradation.People's requirement to leaflet aesthetics can be met, the requirement of environmental protection can be met again.

Description

A kind of organic ink of degradable and manufacture method thereof
Technical field
The present invention relates to printing supplies field, particularly relate to a kind of organic ink.
Background technology
The uniform slurry like material that organic ink is made up of materials such as link stuff, pigment, auxiliary agent and organic solvents.Traditional Auxiliary agent and solvent used by organic ink are organic solution, how can contain ethyl acetate, butyl acetate, benzene, toluene and dimethylbenzene Deng, this type organic is volatile, and has certain toxicity, the most degradable, therefore easily injures during not only manufacturing Operator is healthy, and the leaflet prepared reclaims degraded difficulty, endangers environment.But this type of organic ink solidification effect is good, Bright in color and good stability, and its preparation method is simple, low for equipment requirements, low cost.So a kind of quality height of invention is again The organic ink of degradable of environmental protection is made use of momentum and must gone.
Summary of the invention
The technical problem that present invention mainly solves is to provide a kind of organic ink of degradable, the degradable organic oil of the present invention Ink has that bright in color, good stability, low cost and the feature of environmental protection are strong, reclaim the advantages such as degradable simultaneously, can meet people couple The requirement of ink quality used by leaflet, can meet again the requirement of environmental protection.
The organic ink of degradable of the present invention is by maleic acrylic copolymer, polyhydric alcohol, Petropols, polyfunctional group third Olefin(e) acid ester, organic pigment, Colophonium, organic solvent, special decoloring agent and other auxiliary agents composition;
Described maleic acrylic copolymer is 50-60 part;
Described polyhydric alcohol is 7-10 part;
Described Petropols are 20-30 part;
Described multi-functional acrylate is 17-35 part;
Described organic pigment is 40-50 part;
Described Colophonium is 5-10 part;
Described organic solvent is 20-25 part;
Described special decoloring agent is 5-10 part;
Other auxiliary agents described are 10-13 part;
Described number is parts by weight.
Preferably:
Described maleic acrylic copolymer is 52 parts;
Described polyhydric alcohol is 8 parts;
Described Petropols are 24 parts;
Described multi-functional acrylate is 30 parts;
Described organic pigment is 45 parts;
Described Colophonium is 8 parts;
Described organic solvent is 22 parts;
Described special decoloring agent is 8 parts;
Other auxiliary agents described are 11 parts;
Described number is parts by weight.
Saying further, the special decoloring agent of the organic ink of degradable of the present invention is sodium dithionite.
Say further, other auxiliary agents of the organic ink of degradable of the present invention include levelling agent, antiwear additive, lubricant, Defoamer and drier;
Described levelling agent is 2-5 part;
Described antiwear additive is 4-8 part;
Described lubricant is 10-12 part;
Described defoamer is 6-9 part;
Described drier is 2-4 part;
Described number is parts by weight.
The preparation method of the organic ink of above-mentioned degradable, is carried out as steps described below:
One, maleic acrylic copolymer, polyhydric alcohol, Petropols and multi-functional acrylate are added in blender stir Mix so that it is mixing, the rotating speed of blender controls to turn at 80-90 per minute, and mixing time is 40-60 minute;
Two, organic pigment, Colophonium, organic solvent, special decoloring agent and other auxiliary agents are added stirring in blender so that it is mixed Closing, the rotating speed of blender controls to turn at 50-60 per minute, and mixing time is 30-40 minute;
Three, the mixture that mixture step one prepared and step 2 prepare adds in dispersion machine and disperses, then adjusts through roll squeezer Whole fineness is to less than 20 microns.
The invention has the beneficial effects as follows: the organic ink of degradable of the present invention uses plurality of raw materials rational proportion to form.Adopt Easily being adsorbed and the organic pigment of stable performance with having bright color, color, the sodium dithionite simultaneously used is special With decolorising agent, after ink goods reclaim, multiple organic solvent therein changes under the strong reducing action of sodium dithionite The material that environmental pollution is less, by greatly reducing the impact on environment of the direct processed material, complies fully with environmental protection concept.Additionally adopt Auxiliary agent too increase the stability of this kind of ink, coloring, levelability and manufacturability.The degradable organic oil of the present invention The manufacture method of ink is relatively easy, low cost, therefore the ink price prepared is easier to be readily accepted by customers, and has more market prospect.
Described above is only the general introduction of technical solution of the present invention, in order to better understand the technological means of the present invention, And can be practiced according to the content of description, after describing in detail such as with presently preferred embodiments of the present invention below.
Detailed description of the invention
Below in conjunction with embodiment, the detailed description of the invention of the present invention is described in further detail.
Embodiment 1: the organic ink of degradable of the present invention is by maleic acrylic copolymer, polyhydric alcohol, Petropols, many Functional group propenoic acid ester, organic pigment, Colophonium, organic solvent, special decoloring agent and other auxiliary agents composition;
Described maleic acrylic copolymer is 52 parts;
Described polyhydric alcohol is 8 parts;
Described Petropols are 24 parts;
Described multi-functional acrylate is 30 parts;
Described organic pigment is 45 parts;
Described Colophonium is 8 parts;
Described organic solvent is 22 parts;
Described special decoloring agent is 8 parts;
Other auxiliary agents described are 11 parts;
Described number is parts by weight.
Embodiment 2: the organic ink of degradable of the present invention is by maleic acrylic copolymer, polyhydric alcohol, Petropols, many Functional group propenoic acid ester, organic pigment, Colophonium, organic solvent, special decoloring agent and other auxiliary agents composition;
Described maleic acrylic copolymer is 54 parts;
Described polyhydric alcohol is 9 parts;
Described Petropols are 25 parts;
Described multi-functional acrylate is 30 parts;
Described organic pigment is 48 parts;
Described Colophonium is 9 parts;
Described organic solvent is 25 parts;
Described special decoloring agent is 9 parts;
Other auxiliary agents described are 12 parts;
Described number is parts by weight.
Saying further, the special decoloring agent of the organic ink of degradable of the present invention is sodium dithionite.
Say further, other auxiliary agents of the organic ink of degradable of the present invention include levelling agent, antiwear additive, lubricant, Defoamer and drier;
Described levelling agent is 2-5 part;
Described antiwear additive is 4-8 part;
Described lubricant is 10-12 part;
Described defoamer is 6-9 part;
Described drier is 2-4 part;
Described number is parts by weight.
The preparation method of the organic ink of degradable of embodiment 1 and embodiment 2, is carried out as steps described below:
One, maleic acrylic copolymer, polyhydric alcohol, Petropols and multi-functional acrylate are added in blender stir Mix so that it is mixing, the rotating speed of blender controls to turn at 80-90 per minute, and mixing time is 40-60 minute;
Two, organic pigment, Colophonium, organic solvent, special decoloring agent and other auxiliary agents are added stirring in blender so that it is mixed Closing, the rotating speed of blender controls to turn at 50-60 per minute, and mixing time is 30-40 minute;
Three, the mixture that mixture step one prepared and step 2 prepare adds in dispersion machine and disperses, then adjusts through roll squeezer Whole fineness is to less than 20 microns.
The foregoing is only embodiments of the invention, not thereby limit the scope of the claims of the present invention, every utilize this Equivalent structure or equivalence flow process that bright description is made convert, or are directly or indirectly used in other relevant technology necks Territory, is the most in like manner included in the scope of patent protection of the present invention.

Claims (5)

1. the organic ink of degradable, it is characterised in that: maleic acrylic copolymer, polyhydric alcohol, Petropols, multifunctional Group's acrylate, organic pigment, Colophonium, organic solvent, special decoloring agent and other auxiliary agents composition;
Described maleic acrylic copolymer is 50-60 part;
Described polyhydric alcohol is 7-10 part;
Described Petropols are 20--30 part;
Described multi-functional acrylate is 17-35 part;
Described organic pigment is 40-50 part;
Described Colophonium is 5-10 part;
Described organic solvent is 20-25 part;
Described special decoloring agent is 5-10 part;
Other auxiliary agents described are 10-13 part;
Described number is parts by weight.
The organic ink of degradable the most according to claim 1, it is characterised in that: special decoloring agent is sodium dithionite.
The organic ink of degradable the most according to claim 1, it is characterised in that: other auxiliary agents include levelling agent, antiwear additive, Lubricant, defoamer and drier;
Described levelling agent is 2-5 part;
Described antiwear additive is 4-8 part;
Described lubricant is 10-12 part;
Described defoamer is 6-9 part;
Described drier is 2-4 part;
Described number is parts by weight.
The organic ink of degradable the most according to claim 1, it is characterised in that:
Described maleic acrylic copolymer is 52 parts;
Described polyhydric alcohol is 8 parts;
Described Petropols are 24 parts;
Described multi-functional acrylate is 30 parts;
Described organic pigment is 45 parts;
Described Colophonium is 8 parts;
Described organic solvent is 22 parts;
Described special decoloring agent is 8 parts;
Other auxiliary agents described are 11 parts;
Described number is parts by weight.
The preparation method of the organic ink of degradable the most according to claim 1, it is characterised in that: enter as steps described below OK:
One, maleic acrylic copolymer, polyhydric alcohol, Petropols and multi-functional acrylate are added in blender stir Mix so that it is mixing, the rotating speed of blender controls to turn at 80-90 per minute, and mixing time is 40-60 minute;
Two, organic pigment, Colophonium, organic solvent, special decoloring agent and other auxiliary agents are added stirring in blender so that it is mixed Closing, the rotating speed of blender controls to turn at 50-60 per minute, and mixing time is 30-40 minute;
Three, the mixture that mixture step one prepared and step 2 prepare adds in dispersion machine and disperses, then adjusts through roll squeezer Whole fineness is to less than 20 microns.
CN201610650302.2A 2016-08-10 2016-08-10 A kind of organic ink of degradable and manufacture method thereof Pending CN106167646A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610650302.2A CN106167646A (en) 2016-08-10 2016-08-10 A kind of organic ink of degradable and manufacture method thereof

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Application Number Priority Date Filing Date Title
CN201610650302.2A CN106167646A (en) 2016-08-10 2016-08-10 A kind of organic ink of degradable and manufacture method thereof

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CN106167646A true CN106167646A (en) 2016-11-30

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107793832A (en) * 2017-11-24 2018-03-13 天长市天翔包装有限公司 A kind of degradable offset ink
CN116444835A (en) * 2023-04-20 2023-07-18 广东彩虹德记塑胶颜料股份有限公司 High density solvent pigment for decoloring colored plastics

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102220047A (en) * 2011-05-12 2011-10-19 商丘师范学院 Fadable printing ink and preparation method thereof
CN102838900A (en) * 2012-09-21 2012-12-26 山西大学 Aqueous degradable environment-friendly ink and decoloring agent thereof
CN105086608A (en) * 2015-08-07 2015-11-25 东莞市新星有机硅科技有限公司 Degradable UV offset printing ink and preparing method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102220047A (en) * 2011-05-12 2011-10-19 商丘师范学院 Fadable printing ink and preparation method thereof
CN102838900A (en) * 2012-09-21 2012-12-26 山西大学 Aqueous degradable environment-friendly ink and decoloring agent thereof
CN105086608A (en) * 2015-08-07 2015-11-25 东莞市新星有机硅科技有限公司 Degradable UV offset printing ink and preparing method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107793832A (en) * 2017-11-24 2018-03-13 天长市天翔包装有限公司 A kind of degradable offset ink
CN116444835A (en) * 2023-04-20 2023-07-18 广东彩虹德记塑胶颜料股份有限公司 High density solvent pigment for decoloring colored plastics

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Application publication date: 20161130

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