CN106049085B - A kind of discharge printing composition - Google Patents
A kind of discharge printing composition Download PDFInfo
- Publication number
- CN106049085B CN106049085B CN201610197292.1A CN201610197292A CN106049085B CN 106049085 B CN106049085 B CN 106049085B CN 201610197292 A CN201610197292 A CN 201610197292A CN 106049085 B CN106049085 B CN 106049085B
- Authority
- CN
- China
- Prior art keywords
- agent
- ink
- composition
- discharge
- moisturizer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/60—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing polyethers
- D06P1/613—Polyethers without nitrogen
- D06P1/6138—Polymerisation products of glycols, e.g. Carbowax, Pluronics
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/642—Compounds containing nitrogen
- D06P1/6426—Heterocyclic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/642—Compounds containing nitrogen
- D06P1/647—Nitrogen-containing carboxylic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/642—Compounds containing nitrogen
- D06P1/649—Compounds containing carbonamide, thiocarbonamide or guanyl groups
- D06P1/6495—Compounds containing carbonamide -RCON= (R=H or hydrocarbons)
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
- D06P1/67333—Salts or hydroxides
- D06P1/6735—Salts or hydroxides of alkaline or alkaline-earth metals with anions different from those provided for in D06P1/67341
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/15—Locally discharging the dyes
Abstract
The present invention relates to a kind of discharge printing ink sets, are used to prepare dawn ink, which is characterized in that are made of formaldehydeless white discharging agent, solubilizer, moisturizer and additive, weight percent content is ranging from：4%~10% formaldehydeless white discharging agent, 5~20% solubilizer, 5~20% moisturizer, 0.1~2% additive, 48~85.9% deionized waters.It is prepared into ink after formaldehydeless white discharging agent or formaldehydeless white discharging agent are mixed with the material of resistance to discharge, make discharge printing that can be combined with ink-jet printed, greatly having played discharge decorative pattern has the features such as careful, true to nature, level is abundant, plentiful gorgeous, color contrast is strong, clear-cut, background color is plentiful.
Description
Technical field
The present invention relates to a kind of compositions, and in particular to a kind of discharge printing composition.
Background technology
Discharge printing is the stamp on dyed fabric, and dyes can be destroyed by containing in print paste (printing paste)
Chemical substance (be known as white discharging agent), by the printing method of ground colour dye destruction or colour killing at stamp.The decorative pattern of discharge printing
It is abundant with careful, true to nature, level, it is plentiful gorgeous, color contrast is strong, clear-cut, background color is plentiful the features such as.Traditional discharge
Stamp is realized by sieve or pigment printing, and technique is cumbersome, and usage of sizing agent easily causes water pollution, and these printing methods more
The features such as discharge printing decorative pattern is careful, level is abundant, clear-cut is limited to a certain extent.
Existing discharge printing composition generally all contains white discharging agent, and white discharging agent discharges free in the production and use process
Formaldehyde is detrimental to health and ecological environment.
In view of the above shortcomings, the designer, is actively subject to research and innovation, to found a kind of non-hazardous and tool environmental protection
The discharge printing composition of type makes it with more the utility value in industry.
Invention content
In order to solve the above technical problems, the object of the present invention is to provide a kind of protection bad border and effect of igniting it is good, dyeing jail
Solid discharge printing composition for ink.
Technical scheme is as follows：
A kind of discharge printing composition for ink, is used to prepare dawn ink, which is characterized in that by formaldehydeless white discharging agent, increasing
Solvent, moisturizer and additive composition, weight percent content is ranging from：
A kind of discharge printing composition for ink, is used to prepare discharge ink, which is characterized in that by the material of resistance to discharge, formaldehydeless
White discharging agent, solubilizer, moisturizer and additive composition, weight percent content is ranging from：
Further, the additive is in viscosity-controlling agent, pH adjusting agent, antifoaming agent and metal ion chelation agent
It is one or more.
Further, the solubilizer is urea, caprolactam, N-Methyl pyrrolidone, glycols and dispersion
It is one or more in agent.
Further, which is characterized in that the moisturizer is one in caprolactam, glycols and ether fatty acids
Kind is a variety of.
Further, the metal ion chelation agent is disodium ethylene diamine tetraacetate or calgon.
Further, the glycols solubilizer is appointing in 2- ethylene glycol, 3- ethylene glycol, polyethylene glycol 200~600
It is a kind of.
Further, the glycols moisturizer is appointing in 2- ethylene glycol, 3- ethylene glycol, polyethylene glycol 200~600
It is a kind of.
Further, the material of resistance to discharge is water-soluble dye.
According to the above aspect of the present invention, the present invention has at least the following advantages：
(1) using formaldehydeless white discharging agent eliminate in the production and use process release free formaldehyde be detrimental to health and
The hidden danger of ecological environment.
(2) it is prepared into ink after mixing formaldehydeless white discharging agent or formaldehydeless white discharging agent with the material of resistance to discharge, makes discharge printing
It can be combined with ink-jet printed, greatly having played discharge decorative pattern, there is careful, true to nature, level to enrich, plentiful gorgeous, color pair
Than the features such as strong, clear-cut, background color is plentiful.
(3) technical solution of the present invention reduces the dosage of discharging agent, has saved the energy and cost, substantially increases formaldehydeless
The utilization rate of white discharging agent.
(4) present invention is simple, convenient, convenient for control, easy to implement and amplification.
Above description is only the general introduction of technical solution of the present invention, in order to better understand the technical means of the present invention,
And can be implemented in accordance with the contents of the specification, it is described in detail as after with presently preferred embodiments of the present invention below.
Specific implementation mode
With reference to the accompanying drawings and examples, the specific implementation mode of the present invention is described in further detail.Implement below
Example is not limited to the scope of the present invention for illustrating the present invention.
Dawn ink is prepared, each embodiment component is listed in table 1.
Embodiment 1：
Weighing mass fraction according to composition for ink is：8% formaldehydeless white discharging agent, 8%N- methyl pyrrolidones, 6% oneself
Lactams, 0.8% calgon, 1.2%Ph conditioning agents and 76% deionized water mix, and are fully stirred
It mixes 30 minutes, obtains dawn ink mixed solution, the dissolving for accelerating each component can be heated during this.
Embodiment 2：
Weighing mass fraction according to composition for ink is：4% formaldehydeless white discharging agent, 5% caprolactam and N- methylpyrroles
Alkanone mixture, 5% polyethylene glycol 400,0.1% calgon, 1%Ph conditioning agents and 84.9% deionized water mixing
Together, and be sufficiently stirred 45 minutes, obtain dawn ink mixed solution, can be heated during this and accelerate each component
Dissolving.
Embodiment 3：
Weighing mass fraction according to composition for ink is：10% formaldehydeless white discharging agent, 20% caprolactam, 20% poly- second two
Alcohol 200,0.5% disodium ethylene diamine tetraacetate/2.5%Ph conditioning agents and 47% deionized water mix, and carry out
It is sufficiently stirred 60 minutes, obtains dawn ink mixed solution, the dissolving for accelerating each component can be heated during this.
Table 1
Black ink is pulled out in preparation, and each embodiment component is listed in table 2.
Embodiment 1：
Weighing mass fraction according to composition for ink is：0.1% material of resistance to discharge, 4% formaldehydeless white discharging agent, 5%N- methyl
Pyrrolidones, 5% caprolactam, 0.1% calgon, 1%Ph conditioning agents and 79.8% deionized water are blended in one
It rises, and be sufficiently stirred 30 minutes, obtain pulling out tusche water mixed solution, can be heated during this and accelerate the molten of each component
Solution.
Embodiment 2：
Weighing mass fraction according to composition for ink is：5% material of resistance to discharge, 6% formaldehydeless white discharging agent, 5% caprolactam
With N-Methyl pyrrolidone mixture, 10% polyethylene glycol 200,1% calgon, 1.2%pH conditioning agents and 70.8%
Deionized water mix, and be sufficiently stirred 45 minutes, obtain pulling out tusche water mixed solution, can add during this
The dissolving of thermal acceleration each component.
Embodiment 3：
Weighing mass fraction according to composition for ink is：The acyl in oneself of 15% material of resistance to discharge, 10% formaldehydeless white discharging agent, 20%
Amine, 20% polyethylene glycol 200,0.5% disodium ethylene diamine tetraacetate, 2.5%pH conditioning agents and 32% deionized water mixing
Together, and be sufficiently stirred 60 minutes, obtain pulling out tusche water mixed solution, can be heated during this and accelerate each component
Dissolving.
Table 2
According to the above aspect of the present invention, the present invention has at least the following advantages：
(1) using formaldehydeless white discharging agent eliminate in the production and use process release free formaldehyde be detrimental to health and
The hidden danger of ecological environment.
(2) it is prepared into ink after mixing formaldehydeless white discharging agent or formaldehydeless white discharging agent with the material of resistance to discharge, makes discharge printing
It can be combined with ink-jet printed, greatly having played discharge decorative pattern, there is careful, true to nature, level to enrich, plentiful gorgeous, color pair
Than the features such as strong, clear-cut, background color is plentiful.
(3) technical solution of the present invention reduces the dosage of discharging agent, has saved the energy and cost, substantially increases formaldehydeless
The utilization rate of white discharging agent.
(4) present invention is simple, convenient, convenient for control, easy to implement and amplification.
The above is only a preferred embodiment of the present invention, it is not intended to restrict the invention, it is noted that for this skill
For the those of ordinary skill in art field, without departing from the technical principles of the invention, can also make it is several improvement and
Modification, these improvements and modifications also should be regarded as protection scope of the present invention.
Claims (7)
1. a kind of discharge printing composition for ink, is used to prepare dawn ink, which is characterized in that by formaldehydeless white discharging agent, solubilising
Agent, moisturizer and additive composition, weight percent content is ranging from：
Wherein, the additive is one kind or more in viscosity-controlling agent, pH adjusting agent, antifoaming agent and metal ion chelation agent
Kind；The moisturizer is one or more in caprolactam, glycols and ether fatty acids.
2. a kind of discharge printing composition for ink, is used to prepare discharge ink, which is characterized in that by the material of resistance to discharge, formaldehydeless pull out
White agent, solubilizer, moisturizer and additive composition, weight percent content is ranging from：
Wherein, the additive is one kind or more in viscosity-controlling agent, pH adjusting agent, antifoaming agent and metal ion chelation agent
Kind；The moisturizer is one or more in caprolactam, glycols and ether fatty acids.
3. composition for ink according to claim 1 or 2, it is characterised in that：The solubilizer is urea, acyl in oneself
It is one or more in amine, N-Methyl pyrrolidone, glycols and dispersant.
4. composition for ink according to claim 1 or 2, it is characterised in that：The metal ion chelation agent is ethylenediamine
Tetraacethyl disodium or calgon.
5. composition for ink according to claim 3, it is characterised in that：The glycols solubilizer be 2- ethylene glycol,
Any one of 3- ethylene glycol, polyethylene glycol 200~600.
6. composition for ink according to claim 1 or 2, it is characterised in that：The glycols moisturizer is 2- second two
Any one of alcohol, 3- ethylene glycol, polyethylene glycol 200~600.
7. composition for ink according to claim 2, it is characterised in that：The material of resistance to discharge is water-soluble dye.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610197292.1A CN106049085B (en) | 2016-03-31 | 2016-03-31 | A kind of discharge printing composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610197292.1A CN106049085B (en) | 2016-03-31 | 2016-03-31 | A kind of discharge printing composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106049085A CN106049085A (en) | 2016-10-26 |
| CN106049085B true CN106049085B (en) | 2018-07-13 |
Family
ID=57484300
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610197292.1A Active CN106049085B (en) | 2016-03-31 | 2016-03-31 | A kind of discharge printing composition |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106049085B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106906679A (en) * | 2017-01-17 | 2017-06-30 | 南通纺织丝绸产业技术研究院 | Digit printing ink |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101429730A (en) * | 2008-12-04 | 2009-05-13 | 浙江理工大学 | Silk broadcloth non-methanal discharge printing discharge paste and its discharge printing technique |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06287873A (en) * | 1991-11-06 | 1994-10-11 | Kanebo Ltd | Method for carrying out colored resist printing of fiber structure |
| JP2008274516A (en) * | 2007-03-30 | 2008-11-13 | Art:Kk | Method for dry transfer printing of synthetic fibrous material with disperse dye and transfer paper |
-
2016
- 2016-03-31 CN CN201610197292.1A patent/CN106049085B/en active Active
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101429730A (en) * | 2008-12-04 | 2009-05-13 | 浙江理工大学 | Silk broadcloth non-methanal discharge printing discharge paste and its discharge printing technique |
Non-Patent Citations (3)
| Title |
|---|
| 无甲醛拔白剂ZS—CH;叶建军等;《印染》;20150331;第41卷(第6期);第30页第1.2.2节、第31页第2.2节和2.3节以及第38页第3节 * |
| 无甲醛拔白剂ZS－CH涂料;孙小利;《印染助剂》;20160131;第33卷(第1期);第28-30页 * |
| 棉织物活性染料干热转移印花及其性能研究;苗赛男;《中国优秀硕士学位论文全文数据库工程科技Ⅰ辑》;20160215;全文 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106906679A (en) * | 2017-01-17 | 2017-06-30 | 南通纺织丝绸产业技术研究院 | Digit printing ink |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106049085A (en) | 2016-10-26 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103194121B (en) | Water-based gravure printing ink for thermal transfer printing | |
| CN103660669B (en) | A kind of fountain solution of exempting from alcohol and preparation method thereof | |
| CN101445687B (en) | Alcohol solution printing ink for wrapping paper of intaglio plate cigarette and preparation method thereof | |
| CN106590162B (en) | Water-based gravure plastic film surface printing ink and preparation method thereof | |
| CN103802522B (en) | A kind of environmental protection fountain solution containing aloe extract and preparation method thereof | |
| CN102952431A (en) | Cigarette tipping paper water-based ink and preparation method | |
| CN103786462B (en) | A kind of fountain solution soaking oil containing Flos Inulae and preparation method thereof | |
| EP3330330A1 (en) | Non-aqueous inkjet ink composition | |
| CN103613999A (en) | Water-based ink | |
| CN102229761B (en) | Water-based digital ink jet dispersed ink and preparation method and application thereof | |
| CN106049085B (en) | A kind of discharge printing composition | |
| CN103660668A (en) | Fountain solution with low-concentration ethyl alcohol and preparation method thereof | |
| CN108504175A (en) | A kind of alcohol water-base gravure composite inks for plastics and preparation method thereof | |
| CN103087585A (en) | Water-based ink | |
| CN108060608B (en) | Decorative paper and preparation method thereof | |
| CN101735691A (en) | High-performance water-based epoxy ink and preparation method thereof | |
| CN103396700B (en) | Eco-solvent disperse dye ink for digital inkjet printing of textiles and preparation method of eco-solvent disperse dye ink | |
| CN103450737B (en) | Printing ink as well asand preparation method and application thereof | |
| CN105113296A (en) | Printing paste and preparation method thereof | |
| CN105176186A (en) | Water-based metal ink for UV offset ink and preparation method thereof | |
| CN110735330A (en) | yellow fluorescent heat transfer printing color paste and preparation method and application thereof | |
| CN109371713A (en) | A kind of disperse dye ink and preparation method thereof for thin paper heat transfer printing | |
| CN108084777A (en) | Environmentally friendly chalk of articles for babies table print and preparation method thereof | |
| CN106167646A (en) | A kind of organic ink of degradable and manufacture method thereof | |
| CN113354981A (en) | Thermal transfer ink and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CP02 | Change in the address of a patent holder |
Address after: 226300 no.266, New Century Avenue, Tongzhou District, Nantong City, Jiangsu Province Patentee after: NANTONG TEXTILE & SILK INDUSTRIAL TECHNOLOGY Research Institute Address before: No.58 Chongchuan Road, Chongchuan District, Nantong City, Jiangsu Province 226000 Patentee before: NANTONG TEXTILE & SILK INDUSTRIAL TECHNOLOGY Research Institute |
|
| CP02 | Change in the address of a patent holder |