CN106049085A - Formula for discharge printing - Google Patents
Formula for discharge printing Download PDFInfo
- Publication number
- CN106049085A CN106049085A CN201610197292.1A CN201610197292A CN106049085A CN 106049085 A CN106049085 A CN 106049085A CN 201610197292 A CN201610197292 A CN 201610197292A CN 106049085 A CN106049085 A CN 106049085A
- Authority
- CN
- China
- Prior art keywords
- agent
- discharge
- ink set
- ink
- glycols
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/60—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing polyethers
- D06P1/613—Polyethers without nitrogen
- D06P1/6138—Polymerisation products of glycols, e.g. Carbowax, Pluronics
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/642—Compounds containing nitrogen
- D06P1/6426—Heterocyclic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/642—Compounds containing nitrogen
- D06P1/647—Nitrogen-containing carboxylic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/642—Compounds containing nitrogen
- D06P1/649—Compounds containing carbonamide, thiocarbonamide or guanyl groups
- D06P1/6495—Compounds containing carbonamide -RCON= (R=H or hydrocarbons)
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
- D06P1/67333—Salts or hydroxides
- D06P1/6735—Salts or hydroxides of alkaline or alkaline-earth metals with anions different from those provided for in D06P1/67341
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/15—Locally discharging the dyes
Abstract
The invention relates to a formula for discharge printing. The formula is used for preparation of white discharging ink and is characterized by comprising, by weight, 4 to 10% of a formaldehyde-free white discharging agent, 5 to 20% of a solubilizer, 5 to 20% of a humectant, 0.1 to 2% of an additive and 48 to 85.9% of deionized water. Ink is prepared from the formaldehyde-free white discharging agent or a mixture of the formaldehyde-free white discharging agent and discharge printing-resistant dyes, so discharge printing and inkjet printing can be integrated; thus, full play is given to the characteristics of delicateness, verisimilitude, hierarchy, brilliant and plump colors, sharp color contrast, edge sharpness, plump ground color, etc. of patterns obtained after discharge discharging.
Description
Technical field
The present invention relates to a kind of formula, be specifically related to a kind of discharge printing formula.
Background technology
Discharge printing is stamp on the most dyed fabric, containing destroying dye in print paste (printing paste)
Chemical substance (referred to as white discharging agent), by the ground colour dye destruction at stamp or the printing method of colour killing.The decorative pattern of discharge printing
There is careful, true to nature, levels are rich, plentiful gorgeous, the feature such as color contrast is strong, clear-cut, background color is plentiful.Traditional discharge
Stamp is to be realized by screen cloth or pigment printing, and technique is loaded down with trivial details, and usage of sizing agent easily causes water more and pollutes, and these printing methods
Limit that discharge printing decorative pattern is careful to a certain extent, levels are rich, the feature such as clear-cut.
Existing discharge printing formula the most all contains white discharging agent, and white discharging agent is the free first of release during producing and using
Aldehyde is detrimental to health and ecological environment.
Because above-mentioned defect, the design people, the most in addition research and innovation, to founding a kind of non-hazardous and tool environmental protection
The discharge printing formula of type so that it is have more the value in industry.
Summary of the invention
For solving above-mentioned technical problem, it is an object of the invention to provide a kind of protection bad border and ignite effective, dyeing jail
Solid discharge printing ink set.
Technical scheme is as follows:
A kind of discharge printing ink set, is used for preparing dawn ink, it is characterised in that by formaldehydeless white discharging agent, solubilising
Agent, wetting agent and additive composition, its weight percent content scope is:
A kind of discharge printing ink set, is used for preparing discharge ink, it is characterised in that by the material of resistance to discharge, formaldehydeless pull out
White agent, solubilizing agent, wetting agent and additive composition, its weight percent content scope is:
Further, during described additive is viscosity-controlling agent, pH adjusting agent, defoamer and metal ion chelation agent
One or more.
Further, described solubilizing agent is carbamide, caprolactam, N-Methyl pyrrolidone, glycols and dispersion
One or more in agent.
Further, it is characterised in that described wetting agent is in caprolactam, glycols and fatty acid ether
Plant or multiple.
Further, described metal ion chelation agent is disodiumedetate or sodium hexameta phosphate.
Further, appointing during described glycols solubilizing agent is 2-ethylene glycol, 3-ethylene glycol, polyethylene glycol 200～600
A kind of.
Further, appointing during described glycols wetting agent is 2-ethylene glycol, 3-ethylene glycol, polyethylene glycol 200～600
A kind of.
Further, the described material of resistance to discharge is water-soluble dye.
By such scheme, the present invention at least has the advantage that
(1) use formaldehydeless white discharging agent eliminate produce and use during discharge free formaldehyde be detrimental to health and
The hidden danger of ecological environment.
(2) it is prepared as ink after formaldehydeless white discharging agent or formaldehydeless white discharging agent being mixed with the material of resistance to discharge, makes discharge printing
Can combine with ink-jet printed, greatly play discharge decorative pattern and there is careful, true to nature, levels are rich, plentiful gorgeous, color pair
Than the feature such as strong, clear-cut, background color is plentiful.
(3) technical solution of the present invention reduces the consumption of discharging agent, has saved the energy and cost, substantially increases formaldehydeless
The utilization rate of white discharging agent.
(4) present invention is simple, convenient, it is simple to control, it is easy to implement and amplify.
Described above is only the general introduction of technical solution of the present invention, in order to better understand the technological means of the present invention,
And can be practiced according to the content of description, after describing in detail such as with presently preferred embodiments of the present invention below.
Detailed description of the invention
Below in conjunction with embodiment, the detailed description of the invention of the present invention is described in further detail.Following example are used for
The present invention is described, but is not limited to the scope of the present invention.
Preparation dawn ink, lists each embodiment component in Table 1.
Implement 1:
Weighing mass fraction according to ink set is: 8% formaldehydeless white discharging agent, 8%N-methyl pyrrolidone, 6% in oneself
The deionized water of amide, 0.8% sodium hexameta phosphate, 1.2%Ph regulator and 76% mixes, and is sufficiently stirred for
30 minutes, obtain dawn ink mixed solution, the dissolving accelerating each component during this, can be heated.
Embodiment 2:
Weighing mass fraction according to ink set is: 4% formaldehydeless white discharging agent, 5% caprolactam and N-crassitude
The deionized water of alcohol/ketone mixtures, 5% PEG400,0.1% sodium hexameta phosphate, 1%Ph regulator and 84.9% is blended in
Together, and carry out being sufficiently stirred for 45 minutes, obtain dawn ink mixed solution, can heat during this and accelerate each component
Dissolve.
Embodiment 3:
Weighing mass fraction according to ink set is: 10% formaldehydeless white discharging agent, 20% caprolactam, 20% Polyethylene Glycol
200,0.5% disodiumedetate/2.5%Ph regulator and 47% deionized water mix, and fill
Divide stirring 60 minutes, obtain dawn ink mixed solution, the dissolving accelerating each component during this, can be heated.
Table 1
Black ink is pulled out in preparation, lists each embodiment component in table 2.
Embodiment 1:
Weighing mass fraction according to ink set is: 0.1% material of resistance to discharge, 4% formaldehydeless white discharging agent, 5%N-methyl pyrrole
The deionized water of pyrrolidone, 5% caprolactam, 0.1% sodium hexameta phosphate, 1%Ph regulator and 79.8% mixes,
And carry out being sufficiently stirred for 30 minutes, obtain pulling out black ink mixed solution, the dissolving accelerating each component during this, can be heated.
Embodiment 2:
Weighing mass fraction according to ink set is: 5% material of resistance to discharge, 6% formaldehydeless white discharging agent, 5% caprolactam and
N-Methyl pyrrolidone mixture, 10% polyethylene glycol 200,1% sodium hexameta phosphate, 1.2%pH regulator and 70.8%
Deionized water mixes, and carries out being sufficiently stirred for 45 minutes, obtains pulling out black ink mixed solution, can heat during this
Accelerate the dissolving of each component.
Embodiment 3:
Weighing mass fraction according to ink set is: 15% material of resistance to discharge, 10% formaldehydeless white discharging agent, 20% own interior acyl
The deionized water mixing of amine, 20% polyethylene glycol 200,0.5% disodiumedetate, 2.5%pH regulator and 32%
Together, and carry out being sufficiently stirred for 60 minutes, obtain pulling out black ink mixed solution, can heat during this and accelerate each component
Dissolve.
Table 2
By such scheme, the present invention at least has the advantage that
(1) use formaldehydeless white discharging agent eliminate produce and use during discharge free formaldehyde be detrimental to health and
The hidden danger of ecological environment.
(2) it is prepared as ink after formaldehydeless white discharging agent or formaldehydeless white discharging agent being mixed with the material of resistance to discharge, makes discharge printing
Can combine with ink-jet printed, greatly play discharge decorative pattern and there is careful, true to nature, levels are rich, plentiful gorgeous, color pair
Than the feature such as strong, clear-cut, background color is plentiful.
(3) technical solution of the present invention reduces the consumption of discharging agent, has saved the energy and cost, substantially increases formaldehydeless
The utilization rate of white discharging agent.
(4) present invention is simple, convenient, it is simple to control, it is easy to implement and amplify.
The above is only the preferred embodiment of the present invention, is not limited to the present invention, it is noted that for this skill
For the those of ordinary skill in art field, on the premise of without departing from the technology of the present invention principle, it is also possible to make some improvement and
Modification, these improve and modification also should be regarded as protection scope of the present invention.
Claims (9)
1. a discharge printing ink set, is used for preparing dawn ink, it is characterised in that by formaldehydeless white discharging agent, solubilizing agent,
Wetting agent and additive composition, its weight percent content scope is:
2. a discharge printing ink set, is used for preparing discharge ink, it is characterised in that by the material of resistance to discharge, formaldehydeless dawn
Agent, solubilizing agent, wetting agent and additive composition, its weight percent content scope is:
Ink set the most according to claim 1 and 2, it is characterised in that: described additive is viscosity-controlling agent, pH regulator
One or more in agent, defoamer and metal ion chelation agent.
Ink set the most according to claim 1 and 2, it is characterised in that: described solubilizing agent be carbamide, caprolactam,
One or more in N-Methyl pyrrolidone, glycols and dispersant.
Ink set the most according to claim 1 and 2, it is characterised in that: it is characterized in that, in described wetting agent is oneself
One or more in amide, glycols and fatty acid ether.
Ink set the most according to claim 3, it is characterised in that: described metal ion chelation agent is ethylenediaminetetraacetic acid
Disodium or sodium hexameta phosphate.
Ink set the most according to claim 4, it is characterised in that: described glycols solubilizing agent is 2-ethylene glycol, 3-
Any one in ethylene glycol, polyethylene glycol 200～600.
Ink set the most according to claim 5, it is characterised in that: described glycols wetting agent is 2-ethylene glycol, 3-
Any one in ethylene glycol, polyethylene glycol 200～600.
Ink set the most according to claim 2, it is characterised in that: the described material of resistance to discharge is water-soluble dye.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610197292.1A CN106049085B (en) | 2016-03-31 | 2016-03-31 | A kind of discharge printing composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610197292.1A CN106049085B (en) | 2016-03-31 | 2016-03-31 | A kind of discharge printing composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106049085A true CN106049085A (en) | 2016-10-26 |
| CN106049085B CN106049085B (en) | 2018-07-13 |
Family
ID=57484300
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610197292.1A Active CN106049085B (en) | 2016-03-31 | 2016-03-31 | A kind of discharge printing composition |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106049085B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106906679A (en) * | 2017-01-17 | 2017-06-30 | 南通纺织丝绸产业技术研究院 | Digit printing ink |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06287873A (en) * | 1991-11-06 | 1994-10-11 | Kanebo Ltd | Method for carrying out colored resist printing of fiber structure |
| WO2008120681A1 (en) * | 2007-03-30 | 2008-10-09 | Art Inc. | Method of dry transfer printing of synthetic fibrous material with disperse dye and transfer paper |
| CN101429730A (en) * | 2008-12-04 | 2009-05-13 | 浙江理工大学 | Silk broadcloth non-methanal discharge printing discharge paste and its discharge printing technique |
-
2016
- 2016-03-31 CN CN201610197292.1A patent/CN106049085B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06287873A (en) * | 1991-11-06 | 1994-10-11 | Kanebo Ltd | Method for carrying out colored resist printing of fiber structure |
| WO2008120681A1 (en) * | 2007-03-30 | 2008-10-09 | Art Inc. | Method of dry transfer printing of synthetic fibrous material with disperse dye and transfer paper |
| CN101429730A (en) * | 2008-12-04 | 2009-05-13 | 浙江理工大学 | Silk broadcloth non-methanal discharge printing discharge paste and its discharge printing technique |
Non-Patent Citations (3)
| Title |
|---|
| 叶建军等: "无甲醛拔白剂ZS—CH", 《印染》 * |
| 孙小利: "无甲醛拔白剂ZS－CH涂料", 《印染助剂》 * |
| 苗赛男: "棉织物活性染料干热转移印花及其性能研究", 《中国优秀硕士学位论文全文数据库工程科技Ⅰ辑》 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106906679A (en) * | 2017-01-17 | 2017-06-30 | 南通纺织丝绸产业技术研究院 | Digit printing ink |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106049085B (en) | 2018-07-13 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP3225663B1 (en) | Coloring composition for dyeing, coloring composition for printing, printing method, inkjet printing ink, and dyed fabric | |
| CN105062208A (en) | Flexographic plate water-based ink for high-speed printing and preparation method thereof | |
| AU4601901A (en) | Novel ink jet inks and method of printing | |
| US10767065B2 (en) | Non-aqueous inkjet ink composition | |
| CN104372686A (en) | Four color separation printing dye-based ink formula, preparation and application method thereof | |
| CN103194121A (en) | Water-based gravure printing ink for thermal transfer printing | |
| CN103660668B (en) | A kind of low alcohol edition-0 moistening liquid and preparation method thereof | |
| CN102229761B (en) | Water-based digital ink jet dispersed ink and preparation method and application thereof | |
| CN106049085A (en) | Formula for discharge printing | |
| US7205341B2 (en) | Aqueous pigment dispersion, inkjet ink, and process for producing aqueous pigment dispersion | |
| CN108060608B (en) | Decorative paper and preparation method thereof | |
| CN103450737B (en) | Printing ink as well asand preparation method and application thereof | |
| CN105176186A (en) | Water-based metal ink for UV offset ink and preparation method thereof | |
| CN105113296A (en) | Printing paste and preparation method thereof | |
| US6302948B1 (en) | Textile ink-jet printing-purpose disperse dye micro-emulsion agent | |
| CN112457717A (en) | Water-based ceramic ink for ink-jet printing and preparation method and application thereof | |
| KR102233072B1 (en) | Black ink composition | |
| CN109853256A (en) | A kind of nylon fabric thermal transfer ink and preparation method thereof | |
| CN110358364A (en) | High Temperature Disperse direct-injection black ink and preparation method thereof | |
| CN110735330A (en) | yellow fluorescent heat transfer printing color paste and preparation method and application thereof | |
| CN110294964A (en) | Gravure water-based ink and preparation method thereof | |
| CN101597433B (en) | Method for adjusting magenta pigment colour difference and product thereof | |
| CN113214705A (en) | Pyrograph water-based white ink suitable for Epson nozzle and preparation method thereof | |
| CN107690460A (en) | A kind of decentralized waterborne general color chips | |
| CN105131705A (en) | Alcohol-soluble ink and preparing method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CP02 | Change in the address of a patent holder |
Address after: 226300 no.266, New Century Avenue, Tongzhou District, Nantong City, Jiangsu Province Patentee after: NANTONG TEXTILE & SILK INDUSTRIAL TECHNOLOGY Research Institute Address before: No.58 Chongchuan Road, Chongchuan District, Nantong City, Jiangsu Province 226000 Patentee before: NANTONG TEXTILE & SILK INDUSTRIAL TECHNOLOGY Research Institute |
|
| CP02 | Change in the address of a patent holder |