CN109371713A - A kind of disperse dye ink and preparation method thereof for thin paper heat transfer printing - Google Patents
A kind of disperse dye ink and preparation method thereof for thin paper heat transfer printing Download PDFInfo
- Publication number
- CN109371713A CN109371713A CN201811247926.5A CN201811247926A CN109371713A CN 109371713 A CN109371713 A CN 109371713A CN 201811247926 A CN201811247926 A CN 201811247926A CN 109371713 A CN109371713 A CN 109371713A
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- China
- Prior art keywords
- disperse dye
- dye ink
- agent
- disperse
- ink
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/16—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dispersed, e.g. acetate, dyestuffs
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/46—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- D06P1/525—Polymers of unsaturated carboxylic acids or functional derivatives thereof
- D06P1/5257—(Meth)acrylic acid
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/60—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing polyethers
- D06P1/613—Polyethers without nitrogen
- D06P1/6138—Polymerisation products of glycols, e.g. Carbowax, Pluronics
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/003—Transfer printing
- D06P5/004—Transfer printing using subliming dyes
- D06P5/006—Transfer printing using subliming dyes using specified dyes
Abstract
The disperse dye ink and preparation method thereof that the invention discloses a kind of for thin paper heat transfer printing, wherein the component for the disperse dye ink of thin paper heat transfer printing is constituted as follows by mass percentage: pigment 3-10%, dispersing agent 1-5%, moisturizer 1-3%, organic solvent 20-30%, surfactant 0.2-1.5%, pH adjusting agent 1.5-3%, bacteriostatic agent 0.5-2%, surplus are deionized water.Ink of the present invention can carry out number using heat sublimation technique, which has good fluency, color fastness, fabric good hand touch on from spray printing in piezoelectric type ink-jet printing machine to the heat-transferring printing paper of low grammes per square metre.
Description
Technical field
The disperse dye ink and preparation method thereof that the present invention relates to a kind of for thin paper heat transfer printing, belongs to and organises
And technical field of textile printing.
Background technique
Currently, using the ink-jet ink of printing in textiles mainly active dye ink, disperse dye ink, acid dye
Expect ink and paint ink.Heat sublimation ink is suitable for the stamp of chemical fibre class textile, process be with wide cut wide format printer or
Pattern is printed upon on heat-transferring printing paper by person's industry printing machine, and then pattern transfer printing to chemical fibre class is weaved by heating transfer
On product fabric.Used disperse dye ink can only adapt to the thermal transfer paper of certain thickness requirement on the market at present, to paper
The grammes per square metre opened has higher requirements (currently used is the paper of 80g).Under current energy-saving and environment-friendly main trend, designing one kind can be with
Using the disperse dye ink of thin paper heat transfer printing, the usage amount of thermal transfer paper can be greatly reduced, to reach reduction
Cost reduces the target of pollution, is one important developing goal of current digital Printing Industry.
Summary of the invention
In order to avoid above-mentioned the shortcomings of the prior art, the invention discloses a kind of points for thin paper heat transfer printing
Dye ink and preparation method thereof is dissipated, to reduce the grammes per square metre of currently used thermal transfer paper.Disperse dye ink of the present invention
With good fluency, color fastness, fabric good hand touch.
The present invention is used for the disperse dye ink of thin paper heat transfer printing, and component constitutes as follows by mass percentage:
Pigment 3-10%, dispersing agent 1-5%, moisturizer 1-3%, organic solvent 20-30%, surfactant 0.2-
1.5%, pH adjusting agent 1.5-3%, bacteriostatic agent 0.5-2%, surplus are deionized water.
The pigment is weld, orchil or cyan dye；Wherein, weld are as follows: disperse dyes Huang 54；It is red
Color dyestuff are as follows: disperse dyes red 60；Cyan dye are as follows: disperse dyes indigo plant 359.
The dispersing agent is the mixing of Eudragit E udragit S 100, sodium lignin sulfonate and cetomacrogol 1000
Object, three's mass ratio are 1-3:1-3:1-3.
The moisturizer is a kind of a kind of pure and mild mixture that ether mixes in equal volume；The alcohol is glycerol or second two
Alcohol, the ether are diethylene glycol ethers, ethylene glycol monomethyl ether or triethylene glycol ether.
The surfactant is nonionic surface active agent DC-105, RCOOCH2C(CH2OH)3、RO(C3H6O)m
(C2H4O)nH, one or both of Triton X-100 and polyoxyethylene polyols ether fatty acid ester Tween20 by etc. bodies
The mixture of accumulated amount.
The organic solvent is selected from glycerol or ethylene glycol.
The bacteriostatic agent is selected from chloreresol, N- octyl -4- isothiazoline -3- ketone, dodecyl benzyl dimethyl ammonium chloride
One or both of.
The pH adjusting agent is selected from monoethanolamine or oxyammonia.
Preparation method of the present invention for the disperse dye ink of thin paper heat transfer printing, includes the following steps:
Step 1: measuring pigment, dispersing agent and deionized water according to the ratio, be uniformly mixed, contained admittedly after grinding distribution
Amount is the dispersible pigment color paste of 10-15%；The solid content refers to that pigment weight accounts for the ratio of dispersible pigment color paste weight.
Step 2: dispersible pigment color paste, deionized water and the organic solvent ratio of 1:1:0.8 in mass ratio that step 1 obtains are mixed
Stirring is closed, moisturizer and surfactant are added while agitating, adjusting pH value with pH adjusting agent is 8-9, is then added
Bacteriostatic agent obtains mixed ink；
Step 3: the mixed ink that step 2 is obtained obtains filtrate with the filtering with microporous membrane of 0.5um-1um, then filtrate is used
The miillpore filter of 0.1um-0.5um carries out secondary filter up to disperse dye ink.
In step 1, the partial size of solids is 100-300nm in the dispersible pigment color paste that is prepared.
The present invention adds moisturizer, You Jirong by dispersible pigment color paste is made after disperse dyes and the ground dispersion of dispersing agent
Agent, surfactant, preservative, pH adjusting agent and deionized water are made using filtering with microporous membrane after fully mixed
Disperse dye ink.
Ink of the present invention can use heat sublimation on from spray printing in piezoelectric type ink-jet printing machine to the heat-transferring printing paper of low grammes per square metre
Technique carries out number, which has good fluency, color fastness, fabric good hand touch.
Compared with the prior art, the beneficial effects of the present invention are embodied in:
1, disperse dye ink of the present invention has the characteristic of quick-drying, drying will not can wrinkle rapidly on thin paper, can use 40-
The thin heat-transferring printing paper of 50 grammes per square metres can carry out printing in textiles operation.
2, the physical parameter of the Disperse Printing ink prepared using method of the invention are as follows: 25 DEG C of viscositys are 1-
3mPas, surface tension 25-40mN/m, pH value 8-9, have it is preferable print smooth performance, using Epson the
150 meters can be continuously printed on the digital decorating machine of five generation spray heads without broken string.
Specific embodiment
Below by way of specific embodiment, the invention will be further described.
Embodiment 1: yellow ink is prepared
1, the disperse dyes Huang 54 of 40g, the acrylic acid modified resin of 14g, the acrylic resin of 7.5g, the poly- second of 7.5g are taken
Glycol 1000, the deionized water of 7.5g sodium lignin sulfonate and 243ml first use 200 revs/min of blender of speed low speed
Stirring 30 minutes, then grinds 3 hours in 5000-10000 revs/min of grinding distribution machine, obtains the face that solid content is 10%
Expect mill base 400g, it is desirable that solid (pigment and dispersing agent) particle size therein is 100-300nm.
2, the deionized water of 300ml is added into dispersible pigment color paste, in blender, stirs (200 revs/min of revolving speed on one side
Clock), on one side plus 240g glycerol, diethylene glycol (DEG) and diethylene glycol ethers are in equal volume than moisturizer 15g, Triton X-100 table made of mixing
After 30 minutes pH adjusting agent monoethanolamine 20g is added, and bacteriostatic agent chloreresol 10g is added in face activating agent 5g.
3, then that filtrate is further with the miillpore filter of 0.2um by the filtering with microporous membrane of the ink 1um mixed
Filtering.Obtain ink products.
Yellow disperse dye ink made from the present embodiment, color is pure, and 25 DEG C of viscositys are 2.2-2.5mPas, surface
Tension is 30-33mN/m, and pH value 8.2, fluency is good, can on the digital decorating machine using the 5th generation spray head of Epson
Continuously to print 150 meters without broken string.It can be printed on the heat-transferring printing paper of 40g weight, it is wrinkle resistant, do not influence transferring effect.
Embodiment 2: preparation cyan
1, the disperse dyes indigo plant 359 of 40g, the acrylic resin of 7.5g, the cetomacrogol 1000 of 7.5g, 7.5g lignin are taken
The deionized water of sodium sulfonate and 243ml is first stirred at low speed 30 minutes with 200 revs/min of blender of speed, is then existed
It is ground 3 hours in 5000-10000 revs/min of grinding distribution machine, obtains the dispersible pigment color paste 400g that solid content is 10%, it is desirable that its
In solid (pigment and dispersing agent) particle size be 100-300nm.
2, the deionized water of 300ml is added into dispersible pigment color paste, in blender, stirs (200 revs/min of revolving speed on one side
Clock), on one side plus 240g glycerol, diethylene glycol (DEG) and diethylene glycol ethers are in equal volume than moisturizer 15g, Triton X-100 table made of mixing
Face activating agent 5g.After 30 minutes, pH adjusting agent monoethanolamine 20g is added, and bacteriostatic agent chloreresol 10g is added.
3, by the filtering with microporous membrane of the ink 0.8um mixed, then by filtrate with the miillpore filter of 0.2um into one
Step filtering, obtains ink products.
Cyan disperse dye ink made from the present embodiment, color is pure, and 25 DEG C of viscositys are 2.3-2.6mPas, surface
Tension is 29-32mN/m, and pH value 8.4, fluency is good, can on the digital decorating machine using the 5th generation spray head of Epson
Continuously to print 150 meters without broken string, can be printed on the heat-transferring printing paper of 40g weight, it is wrinkle resistant, do not influence transferring effect.
Embodiment 3: magenta ink is prepared
1, the disperse red 60 of 40g, the acrylic resin of 7.5g, the cetomacrogol 1000 of 7.5g, 7.5g lignin sulfonic acid are taken
The deionized water of sodium and 243ml is first stirred at low speed 30 minutes with 200 revs/min of blender of speed, then in 5000-
It is ground 3 hours in 10000 revs/min of grinding distribution machines, obtains the disperse dyes mill base 400g that dyestuff solid content is 10%, it is desirable that
It is 100-300nm that solid (pigment and dispersing agent) therein, which obtains particle size,.
2, the deionized water of 300ml is added into dispersible pigment color paste, in blender, stirs (200 revs/min of revolving speed on one side
Clock), on one side plus 240g glycerol, diethylene glycol (DEG) and diethylene glycol ethers are in equal volume than moisturizer 15g, Triton X-100 table made of mixing
After 30 minutes pH adjusting agent monoethanolamine 20g is added, and bacteriostatic agent chloreresol 10g is added in face activating agent 5g.
3, by the filtering with microporous membrane of the ink 1.0um mixed, then by filtrate with the miillpore filter of 0.2um into one
Step filtering, obtains ink products.
Red disperse dyes ink made from the present embodiment, color is pure, and 25 DEG C of viscositys are 2.6-2.9mPas, surface
Tension is 22-34mN/m, and pH value 8.1, fluency is good, can on the digital decorating machine using the 5th generation spray head of Epson
Continuously to print 150 meters without broken string.It can be printed on the heat-transferring printing paper of 40g weight, it is wrinkle resistant, do not influence transferring effect.
Claims (10)
1. a kind of disperse dye ink for thin paper heat transfer printing, it is characterised in that its component is constituted such as by mass percentage
Under:
Pigment 3-10%, dispersing agent 1-5%, moisturizer 1-3%, organic solvent 20-30%, surfactant 0.2-1.5%, pH
Regulator 1.5-3%, bacteriostatic agent 0.5-2%, surplus are deionized water.
2. disperse dye ink according to claim 1, it is characterised in that:
The pigment is weld, orchil or cyan dye；Wherein, weld are as follows: disperse dyes Huang 54；Red dye
Material are as follows: disperse dyes red 60；Cyan dye are as follows: disperse dyes indigo plant 359.
3. disperse dye ink according to claim 1, it is characterised in that:
The dispersing agent is the mixture of Eudragit E udragit S 100, sodium lignin sulfonate and cetomacrogol 1000,
Three's mass ratio is 1-3:1-3:1-3.
4. disperse dye ink according to claim 1, it is characterised in that:
The moisturizer is a kind of a kind of pure and mild mixture that ether mixes in equal volume；The alcohol is glycerol or ethylene glycol, institute
Stating ether is diethylene glycol ethers, ethylene glycol monomethyl ether or triethylene glycol ether.
5. disperse dye ink according to claim 1, it is characterised in that:
The surfactant is nonionic surface active agent DC-105, RCOOCH2C(CH2OH)3、RO(C3H6O)m(C2H4O)nH, one or both of Triton X-100 and polyoxyethylene polyols ether fatty acid ester Tween20 are by equal volume amounts
Mixture.
6. disperse dye ink according to claim 1, it is characterised in that:
The organic solvent is selected from glycerol or ethylene glycol.
7. disperse dye ink according to claim 1, it is characterised in that:
The bacteriostatic agent is in chloreresol, N- octyl -4- isothiazoline -3- ketone, dodecyl benzyl dimethyl ammonium chloride
It is one or two kinds of.
8. disperse dye ink according to claim 1, it is characterised in that:
The pH adjusting agent is selected from monoethanolamine or oxyammonia.
9. the preparation method of any disperse dye ink for thin paper heat transfer printing in a kind of claim 1-8, special
Sign is to include the following steps:
Step 1: measuring pigment, dispersing agent and deionized water according to the ratio, be uniformly mixed, solid content is obtained after grinding distribution is
The dispersible pigment color paste of 10-15%；
Step 2: the ratio for dispersible pigment color paste, deionized water and the organic solvent 1:1:0.8 in mass ratio that step 1 obtains being mixed and is stirred
It mixes, moisturizer and surfactant is added while agitating, adjusting pH value with pH adjusting agent is 8-9, is then added antibacterial
Agent obtains mixed ink；
Step 3: the mixed ink that step 2 is obtained obtains filtrate with the filtering with microporous membrane of 0.5um-1um, then filtrate is used
The miillpore filter of 0.1um-0.5um carries out secondary filter up to disperse dye ink.
10. preparation method according to claim 9, it is characterised in that:
In step 2, the ratio of dispersible pigment color paste, deionized water and organic solvent 1:1:0.8 in mass ratio are mixed.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811247926.5A CN109371713B (en) | 2018-10-25 | 2018-10-25 | Disperse dye ink for thermal transfer printing of thin paper and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811247926.5A CN109371713B (en) | 2018-10-25 | 2018-10-25 | Disperse dye ink for thermal transfer printing of thin paper and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN109371713A true CN109371713A (en) | 2019-02-22 |
| CN109371713B CN109371713B (en) | 2021-07-30 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201811247926.5A Active CN109371713B (en) | 2018-10-25 | 2018-10-25 | Disperse dye ink for thermal transfer printing of thin paper and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111235909A (en) * | 2020-03-13 | 2020-06-05 | 珠海纳思达企业管理有限公司 | Thermal sublimation ink and preparation method and application thereof |
| CN111254721A (en) * | 2020-03-25 | 2020-06-09 | 深圳市墨库图文技术有限公司 | Novel pyrograph printing ink and preparation method and application thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101760079A (en) * | 2010-02-05 | 2010-06-30 | 刘寒剑 | Pigment ink for cotton inkjet printing and preparation method thereof |
| CN103572615A (en) * | 2012-08-02 | 2014-02-12 | 绍兴县旭泰纺织有限公司 | Fluorescent disperse dye ink for inkjet printing and preparation method of fluorescent disperse dye ink |
| CN105542568A (en) * | 2016-03-08 | 2016-05-04 | 珠海保税区天然宝杰数码科技材料有限公司 | Thermal sublimation ink for low-gram-weight transfer paper and printing method of thermal sublimation ink |
-
2018
- 2018-10-25 CN CN201811247926.5A patent/CN109371713B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101760079A (en) * | 2010-02-05 | 2010-06-30 | 刘寒剑 | Pigment ink for cotton inkjet printing and preparation method thereof |
| CN103572615A (en) * | 2012-08-02 | 2014-02-12 | 绍兴县旭泰纺织有限公司 | Fluorescent disperse dye ink for inkjet printing and preparation method of fluorescent disperse dye ink |
| CN105542568A (en) * | 2016-03-08 | 2016-05-04 | 珠海保税区天然宝杰数码科技材料有限公司 | Thermal sublimation ink for low-gram-weight transfer paper and printing method of thermal sublimation ink |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111235909A (en) * | 2020-03-13 | 2020-06-05 | 珠海纳思达企业管理有限公司 | Thermal sublimation ink and preparation method and application thereof |
| CN111235909B (en) * | 2020-03-13 | 2022-12-06 | 珠海纳思达企业管理有限公司 | Thermal sublimation ink and preparation method and application thereof |
| CN111254721A (en) * | 2020-03-25 | 2020-06-09 | 深圳市墨库图文技术有限公司 | Novel pyrograph printing ink and preparation method and application thereof |
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| Publication number | Publication date |
|---|---|
| CN109371713B (en) | 2021-07-30 |
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