Novel pyrograph printing ink and preparation method and application thereof
Technical Field
The invention relates to the technical field of printing ink, in particular to novel pyrograph printing ink and a preparation method and application thereof.
Background
The digital pyrograph has no plate making, and can be printed with personalized patterns as required, and along with the development of digital printing, the digital pyrograph printing is more and more popular. The existing digital pyrograph technology mainly comprises the following two types: the first method is to complete the manufacture by the following four steps: 1. printing a designed pattern on a PET release film by using an ink-jet printer, 2. coating a layer of hot-melt glue or hot-melt powder on the printed pattern by a gluing process or a dusting process, 3. putting the film printed with the pattern on a cloth or a medium, and transferring the film onto the cloth or the medium by a pressing machine at a high temperature 4. tearing off the PET film by hot tearing or cold tearing after transferring to finish the manufacture; the second method comprises the following four steps: 1. printing a designed pattern on the pyrograph paper or the PET pyrograph film by using an ink-jet printer, 2. cutting the pattern by using a carving machine to remove more blank, 3. placing the carved pyrograph paper or the PET pyrograph film on cloth or a medium, and transferring the carved pyrograph paper or the PET pyrograph film to the cloth or the medium by using a pressing machine at high temperature 4. tearing off the pyrograph paper or the PET pyrograph film by hot tearing or cold tearing after transferring to finish the manufacturing; in addition, because the color ink cannot be directly used for pyrographing on the dark cloth, the pyrographing process is mainly applied to digital pyrographing of white or light cloth, and the digital pyrographing of the dark cloth (medium) can be completed by means of other pyrographing films or processes.
The pyrograph ink is used as a key material for pyrograph digital printing, the pyrograph ink is researched, production process links are reduced through the improvement of ink performance, the production efficiency can be effectively improved, the cost is saved, and the pyrograph ink is of great significance in research. The existing ink applicable to the pyrograph printing does not contain materials which can transfer pigments (printing patterns) to cloth (media) at high temperature, the digital patterns printed in the manufacturing processes need to be subjected to gluing or dusting process treatment, the digital patterns printed in the two manufacturing processes need to be subjected to hot melt adhesive coating or are cut and removed by an engraving machine, the deep color fabric cannot be directly pyrograph printed, and the production efficiency and the cost of the pyrograph are seriously influenced.
Disclosure of Invention
In order to solve the technical problem, the invention provides novel pyrograph printing ink which at least comprises the following raw materials in percentage by weight: 10-30% of pigment dispersion, 10-20% of water-based hot melt adhesive resin, 1-10% of water-based resin, 10-30% of humectant, 0.5-5% of surfactant, 0-1% of bactericide and the balance of water.
As a preferred technical scheme, the novel pyrograph printing ink disclosed by the invention at least comprises the following raw materials in percentage by weight: 15-25% of pigment dispersion, 12-18% of water-based hot melt adhesive resin, 3-8% of water-based resin, 12-20% of humectant, 1-3% of surfactant, 0.2-0.8% of bactericide and the balance of water.
In a preferred embodiment, the humectant is at least one selected from the group consisting of isopropyl alcohol, ethylene glycol, diethylene glycol, triethylene glycol, propylene glycol, ethylene glycol butyl ether, diethylene glycol diethyl ether, propylene glycol methyl ether, propylene glycol butyl ether, dipropylene glycol methyl ether, dipropylene glycol propyl ether, dipropylene glycol butyl ether, glycerin, and 2-pyrrolidone.
In a preferred embodiment, the surfactant in the present invention is at least one selected from the group consisting of a nonionic surfactant, an organosilicon surfactant, and an organofluorine surfactant.
In a preferred embodiment of the present invention, the aqueous resin is at least one selected from the group consisting of acrylic resin, polyurethane resin, vinyl chloride-vinyl acetate resin, alkyd resin, epoxy resin, silicone resin, and organic fluorine resin.
As a preferable technical scheme, the water-based hot melt adhesive resin is water-based acrylic hot melt adhesive and/or water-based polyurethane hot melt adhesive.
As a preferable technical scheme, the viscosity of the water-based hot melt adhesive resin is less than 800 cP.
In a preferred embodiment of the present invention, the pigment dispersion liquid includes at least one of a black pigment dispersion liquid, a yellow pigment dispersion liquid, a red pigment dispersion liquid, a blue pigment dispersion liquid, and a white pigment dispersion liquid.
The second aspect of the invention provides a preparation method of the novel pyrograph printing ink, which at least comprises the following steps: adding water, humectant, surfactant, bactericide, water-based hot melt adhesive resin, water-based resin and pigment dispersion liquid into a dispersing barrel, uniformly stirring to obtain a mixed liquid, and filtering the mixed liquid to obtain the pigment-based water-based paint.
The third aspect of the invention provides an application of the novel pyrograph printing ink, which is applied to pyrograph printing of cloth.
Compared with the prior art, the invention has the following excellent beneficial effects:
the invention provides novel pyrograph printing ink, which is prepared to contain white ink, wherein the ink formula design contains a water-based hot melt adhesive resin which is fused with the ink, so that an ink pattern printed on transparent PET can be directly transferred to a corresponding medium through high temperature without gluing and powdering, meanwhile, a dark color cloth can also be directly pyrograph printed without a conversion process, the production process of the pyrograph printing and the adaptability of the medium are greatly simplified, the production efficiency of the digital pyrograph printing is improved, and the cost is saved. In addition, in the invention, especially, the novel pyrograph printing ink contains the special resin aqueous hot melt adhesive resin and the prepared white pyrograph printing ink can be suitable for pyrograph printing of deep color cloth (medium), thereby perfectly solving the problem of difficulty in pyrograph printing of the deep color cloth.
Detailed Description
The technical features of the technical solutions provided by the present invention will be further clearly and completely described below with reference to the specific embodiments, and it should be apparent that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
It will be understood by those skilled in the art that, unless otherwise defined, all terms (including technical and scientific terms) used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. It will be further understood that terms, such as those defined in commonly used dictionaries, should be interpreted as having a meaning that is consistent with their meaning in the context of the prior art and will not be interpreted in an idealized or overly formal sense unless expressly so defined herein.
The words "preferred", "preferably", "more preferred", and the like, in the present invention, refer to embodiments of the invention that may provide certain benefits, under certain circumstances. However, other embodiments may be preferred, under the same or other circumstances. Furthermore, the recitation of one or more preferred embodiments does not imply that other embodiments are not useful, nor is it intended to exclude other embodiments from the scope of the invention.
The invention provides novel pyrograph printing ink which at least comprises the following raw materials in percentage by weight: 10-30% of pigment dispersion, 10-20% of water-based hot melt adhesive resin, 1-10% of water-based resin, 10-30% of humectant, 0.5-5% of surfactant, 0-1% of bactericide and the balance of water.
In some preferred embodiments, the novel pyrograph printing ink comprises the following raw materials in percentage by weight: 15-25% of pigment dispersion, 12-18% of water-based hot melt adhesive resin, 3-8% of water-based resin, 12-20% of humectant, 1-3% of surfactant, 0.2-0.8% of bactericide and the balance of water.
In some more preferred embodiments, the novel pyrograph printing ink comprises, by weight, at least: 25% of pigment dispersion, 15% of water-based hot melt adhesive resin, 5% of water-based resin, 20% of humectant, 1.5% of surfactant, 0.5% of bactericide and the balance of water.
In some embodiments, the humectant is selected from at least one of isopropyl alcohol, ethylene glycol, diethylene glycol, triethylene glycol, propylene glycol, ethylene glycol butyl ether, diethylene glycol diethyl ether, propylene glycol methyl ether, propylene glycol butyl ether, dipropylene glycol methyl ether, dipropylene glycol propyl ether, dipropylene glycol butyl ether, glycerin, 2-pyrrolidone.
In some preferred embodiments, the humectant is selected from at least one of ethylene glycol, propylene glycol, dipropylene glycol butyl ether, glycerin.
In some more preferred embodiments, the humectant is a mixture of ethylene glycol and glycerin.
In some embodiments, the weight ratio of ethylene glycol to glycerol is (1-5): 1; preferably, the weight ratio of the ethylene glycol to the glycerol is 3: 1.
in some embodiments, the surfactant is selected from at least one of a nonionic surfactant, a silicone surfactant, an organofluorine surfactant.
In some more preferred embodiments, the surfactant is a mixture of nonionic surfactants, silicone surfactants.
In some embodiments, the weight ratio of the nonionic surfactant to the silicone surfactant is 1: (0.1-0.5); preferably, the weight ratio of the nonionic surfactant to the organosilicon surfactant is 1: 0.5.
the kind of the nonionic surfactant in the present invention is not particularly limited, and the nonionic surfactant includes, but is not limited to, at least one of suryfnol 465, suryfnol 485, and suryfnol 104E.
The type of the silicone surfactant in the present invention is not particularly limited, and includes, but is not limited to, at least one of BYK-345, BYK-333, BYK-348, and tego wet 240.
In some embodiments, the aqueous resin is selected from at least one of acrylic resin, polyurethane resin, vinyl chloride-vinyl acetate resin, alkyd resin, epoxy resin, silicone resin, and organic fluorine resin.
In some preferred embodiments, the aqueous resin is selected from at least one of acrylic resin, polyurethane resin, and vinyl chloride-vinyl acetate resin.
In some more preferred embodiments, the aqueous resin is a vinyl chloride-vinyl acetate resin.
In the present invention, the source of the vinyl chloride-vinyl acetate copolymer is not particularly limited, and preferably, the vinyl chloride-vinyl acetate copolymer is at least one selected from VINYBLAN 700 and VINYBLAN 701, which are japanese letters.
The source of the acrylic resin in the present invention is not particularly limited, and preferably, the acrylic resin is selected from lubosun Carboset 514H.
The invention provides novel pyrograph printing ink, which is characterized in that in the using process, a designed pattern needs to be printed on pyrograph paper or a PET pyrograph film by using an ink-jet printer, but a PET material has lower surface energy, and the effect of the final pattern can be obviously influenced by the acting force between the PET material and ink when the PET material and the ink are transferred to cloth or a medium.
In some embodiments, the biocide is an oxazoline biocide.
In some preferred embodiments, the oxazoline fungicide is selected from at least one of isothiazolinone, benzisothiazolinone.
The oxazoline bactericide in the invention is preferably at least one of BIT-20 and Proxel GXL.
In some embodiments, the aqueous hot melt adhesive resin is an aqueous acrylic hot melt adhesive and/or an aqueous polyurethane hot melt adhesive.
In some embodiments, the viscosity of the aqueous hot melt adhesive resin is less than 800 cP; preferably, the viscosity of the aqueous hot melt adhesive resin is less than 500 cP.
In some preferred embodiments, the aqueous hot melt adhesive resin is an aqueous polyurethane hot melt adhesive.
The water-based hot melt adhesive resin is preferably YF9654 water-based hot melt adhesive purchased from Shanghai super-exhibition industry Co., Ltd or JW01 water-based heat transfer adhesive purchased from Enshi city Thailand Corp; more preferably, the aqueous hot melt adhesive resin is YF9654 aqueous hot melt adhesive.
The inventor finds that the water-based hot melt adhesive resin selected in the invention is a water-based hot melt adhesive with the viscosity of less than 500cP and the particle size of less than 300nm, can quickly compound pigment particles on cloth to realize adhesion and obtain good bonding fastness by pressing and ironing at 130 ℃, and particularly has more excellent effect of selecting the water-based polyurethane hot melt adhesive.
In some embodiments, the pigment dispersion liquid includes at least one of a black pigment dispersion liquid, a yellow pigment dispersion liquid, a red pigment dispersion liquid, a blue pigment dispersion liquid, and a white pigment dispersion liquid.
The black pigment dispersion liquid, the yellow pigment dispersion liquid, the red pigment dispersion liquid and the blue pigment dispersion liquid are at least one of ink-jet color paste series, ink-jet color paste series of British diamond company and self-made dispersion liquid series produced by the American Kabot company.
In some embodiments, the ink-jet color pastes produced by the U.S. cabot corporation family include, but are not limited to, 325K, 450C, 465M, 470Y.
In some embodiments, the uk diamond company inkjet color paste family includes, but is not limited to, D71Y, D71C, D71V19, D80K four color inkjet color pastes.
In some embodiments, the home-made dispersion series includes, but is not limited to, black, yellow, red, white, blue dispersions.
The white dispersion liquid is not specially limited, and the purchase source of the white dispersion liquid comprises but is not limited to at least one of taiwan nanochemistry, perpetual photochemical white dispersion liquid and self-made white dispersion liquid; preferably, the white dispersion has the trade mark of Taiwan nanometer NK-WNE 05.
The second aspect of the invention provides a preparation method of the novel pyrograph printing ink, which at least comprises the following steps: adding water, humectant, surfactant, bactericide, water-based hot melt adhesive resin, water-based resin and pigment dispersion liquid into a dispersing barrel, uniformly stirring to obtain a mixed liquid, and filtering the mixed liquid to obtain the pigment-based water-based paint.
In some preferred embodiments, the method for preparing the novel pyrograph printing ink at least comprises the following steps: (1) adding deionized water and a humectant into a dispersing barrel, and uniformly stirring to obtain a first mixed solution; (2) adding the surfactant and the bactericide into the mixed solution of the first mixed solution, and uniformly stirring to obtain a second mixed solution; (3) adding the water-based hot melt adhesive resin and the water-based resin into the second mixed solution, and uniformly stirring to obtain a third mixed solution; (4) and finally, adding the pigment dispersion liquid into the third mixed liquid, uniformly stirring, and then filtering for 2 times by using a negative pressure PP (polypropylene) filter membrane to obtain the pigment.
In the invention, the spray head for printing the novel pyrograph printing ink is not specially selected, and particularly preferred are Epson DX5/DX6, 513 and 4720.
The inventor unexpectedly discovers that the ink prepared by the invention contains the white pyrograph printing ink prepared by the special water-based hot melt adhesive resin, and the white pyrograph printing ink is attached to a colored ink layer in the transfer process to form a white layer, and has good adhesiveness and clear pattern printing effect when being transferred to a dark cloth (or medium); the inventors have found that it is particularly applicable to the nozzles of the Epson DX5/DX6, 513, 4720, while having good printing performance and standby performance.
The third aspect of the invention provides an application of the novel pyrograph printing ink, which is applied to pyrograph printing of cloth.
The present invention is described in detail below by way of examples, and it should be noted that the following examples are only for illustrating the present invention and should not be construed as limiting the scope of the present invention.
Examples 1 to 1
The novel pyrograph printing ink at least comprises the following raw materials in percentage by weight: 25% of pigment dispersion, 15% of water-based hot melt adhesive resin, 5% of water-based resin, 20% of humectant, 1.5% of surfactant, 0.5% of bactericide and the balance of water.
The humectant is a mixture of ethylene glycol and glycerol, and the weight ratio of the ethylene glycol to the glycerol is 3: 1.
the surfactant is a mixture of a nonionic surfactant and an organic silicon surfactant, and the weight ratio of the surfactant to the organic silicon surfactant is 1: 0.5, the nonionic surfactant is surfnol 465, and the organosilicon surfactant is BYK-348.
The water-based resin is vinyl acetate resin VINYBLAN 701.
The oxazoline bactericide is BIT-20.
The aqueous hot melt adhesive resin is preferably purchased from YF9654 aqueous hot melt adhesive of Shanghai super exhibition industry Co.
The pigment dispersion liquid is white dispersion liquid, namely Taiwan nanometer NK-WNE 05.
The preparation method of the novel pyrograph printing ink at least comprises the following steps: (1) adding deionized water and a humectant into a dispersing barrel, and uniformly stirring to obtain a first mixed solution; (2) adding the surfactant and the bactericide into the mixed solution of the first mixed solution, and uniformly stirring to obtain a second mixed solution; (3) adding the water-based hot melt adhesive resin and the water-based resin into the second mixed solution, and uniformly stirring to obtain a third mixed solution; (4) and finally, adding the pigment dispersion liquid into the third mixed liquid, uniformly stirring, and then filtering for 2 times by using a negative pressure PP (polypropylene) filter membrane to obtain the pigment.
Examples 1 to 2
This example differs from example 1-1 in that the pigment dispersion liquid was a black pigment dispersion liquid D80K.
Examples 1 to 3
This example differs from example 1-1 in that the pigment dispersion liquid is a blue pigment dispersion liquid 450C.
Examples 1 to 4
This example differs from example 1-1 in that the pigment dispersion liquid is a red pigment dispersion liquid 465M.
Examples 1 to 5
This example differs from example 1-1 in that the pigment dispersion liquid was a yellow pigment dispersion liquid D71Y.
Example 2
The novel pyrograph printing ink at least comprises the following raw materials in percentage by weight: 15% of pigment dispersion liquid, 12% of water-based hot melt adhesive resin, 3% of water-based resin, 12% of humectant, 1% of surfactant, 0.2% of bactericide and the balance of water.
The humectant is a mixture of ethylene glycol and glycerol, and the weight ratio of the ethylene glycol to the glycerol is 1: 1.
the surfactant is a mixture of a nonionic surfactant and an organic silicon surfactant, and the weight ratio of the surfactant to the organic silicon surfactant is 1: 0.1, the nonionic surfactant is suryfnol 485, and the organosilicon surfactant is BYK-345.
The water-based resin is vinyl acetate-vinyl chloride copolymer 700.
The oxazoline bactericide is BIT-20.
The aqueous hot melt adhesive resin is preferably a JW01 aqueous hot transfer adhesive available from Jiujie Kogyo, Enshi.
The pigment dispersion liquid is white dispersion liquid, namely Taiwan nanometer NK-WNE 05.
The preparation method of the novel pyrograph printing ink at least comprises the following steps: (1) adding deionized water and a humectant into a dispersing barrel, and uniformly stirring to obtain a first mixed solution; (2) adding the surfactant and the bactericide into the mixed solution of the first mixed solution, and uniformly stirring to obtain a second mixed solution; (3) adding the water-based hot melt adhesive resin and the water-based resin into the second mixed solution, and uniformly stirring to obtain a third mixed solution; (4) and finally, adding the pigment dispersion liquid into the third mixed liquid, uniformly stirring, and then filtering for 2 times by using a negative pressure PP (polypropylene) filter membrane to obtain the pigment.
Example 3
The novel pyrograph printing ink at least comprises the following raw materials in percentage by weight: 10% of pigment dispersion, 10% of water-based hot melt adhesive resin, 3% of water-based resin, 20% of humectant, 0.5% of surfactant, 0% of bactericide and the balance of water.
The humectant is a mixture of ethylene glycol and glycerol, and the weight ratio of the ethylene glycol to the glycerol is (5): 1.
the surfactant is a mixture of a nonionic surfactant and an organic silicon surfactant, and the weight ratio of the surfactant to the organic silicon surfactant is 1: 0.5, the nonionic surfactant is surfnol 104E, and the organosilicon surfactant is BYK-333.
The water-based resin is acrylic resin and Luborun Carboset 514H.
The oxazoline bactericide is Proxel GXL.
The aqueous hot melt adhesive resin is preferably purchased from YF9654 aqueous hot melt adhesive of Shanghai super exhibition industry Co.
The pigment dispersion liquid is white dispersion liquid, namely Taiwan nanometer NK-WNE 05.
The preparation method of the novel pyrograph printing ink at least comprises the following steps: (1) adding deionized water and a humectant into a dispersing barrel, and uniformly stirring to obtain a first mixed solution; (2) adding the surfactant and the bactericide into the mixed solution of the first mixed solution, and uniformly stirring to obtain a second mixed solution; (3) adding the water-based hot melt adhesive resin and the water-based resin into the second mixed solution, and uniformly stirring to obtain a third mixed solution; (4) and finally, adding the pigment dispersion liquid into the third mixed liquid, uniformly stirring, and then filtering for 2 times by using a negative pressure PP (polypropylene) filter membrane to obtain the pigment.
Performance testing
The novel pyrograph printing inks prepared in the above examples 1-1 to 1-5 are applied to a domestic Epson4720 nozzle digital printing machine respectively, and the test results are shown in table 1 as follows:
1. and (3) fluency evaluation: continuously printing 30 square meters of pure color blocks, judging that the broken line is less than or equal to 3 holes and the color blocks are good
2. And (3) evaluating standby performance: printing test strips in 24 hours of standby, judging that the test strips are good when the broken line is less than or equal to 3 holes
3. After a pure color block is printed on a PET film by a printer and pressed to cotton cloth at 130 ℃, the dry and wet rubbing fastness of a printed finished product is tested according to the AATCC 8 method.
Table 1 results of performance testing
Examples
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Fluency of printing
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Stand by for 24 hours
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Fastness to dry rubbing
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Fastness to wet rubbing
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Examples 1 to 1
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Good taste
|
Good taste
|
4-5 stages
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4 stage
|
Examples 1 to 2
|
Good taste
|
Good taste
|
4-5 stages
|
4 stage
|
Examples 1 to 3
|
Good taste
|
Good taste
|
4-5 stages
|
4 stage
|
Examples 1 to 4
|
Good taste
|
Good taste
|
4-5 stages
|
4 stage
|
Examples 1 to 5
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Good taste
|
Good taste
|
4-5 stages
|
4 stage
|
Example 2
|
Good taste
|
Good taste
|
4-5 stages
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4 stage
|
Example 3
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Good taste
|
Good taste
|
4-5 stages
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4 stage |
The above description is only a preferred embodiment of the present invention, and is not intended to limit the present invention in other forms, and any person skilled in the art may modify or change the technical content disclosed above into an equivalent embodiment with equivalent changes, but all those simple modifications, equivalent changes and modifications made on the above embodiment according to the technical spirit of the present invention still belong to the protection scope of the present invention.