CN107739553A - A kind of water-based flexographic ink - Google Patents

A kind of water-based flexographic ink Download PDF

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Publication number
CN107739553A
CN107739553A CN201711290417.6A CN201711290417A CN107739553A CN 107739553 A CN107739553 A CN 107739553A CN 201711290417 A CN201711290417 A CN 201711290417A CN 107739553 A CN107739553 A CN 107739553A
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CN
China
Prior art keywords
parts
water
ink
flexographic ink
based flexographic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711290417.6A
Other languages
Chinese (zh)
Inventor
刘玲红
纪敏
王凯
邱诗波
刘倞
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
HUBEI DANYAXIANG BIOLOGICAL TECHNOLOGY Co.,Ltd.
Original Assignee
Hubei Yellow Crane Tower Characteristic Packaging Material Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hubei Yellow Crane Tower Characteristic Packaging Material Co Ltd filed Critical Hubei Yellow Crane Tower Characteristic Packaging Material Co Ltd
Priority to CN201711290417.6A priority Critical patent/CN107739553A/en
Publication of CN107739553A publication Critical patent/CN107739553A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/106Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C09D11/107Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/03Printing inks characterised by features other than the chemical nature of the binder

Abstract

The present invention provides a kind of water-based flexographic ink, belongs to ink-printing techniques field.The water-based flexographic ink of the present invention, 10 20 parts of water-based acrylic resins, 20 30 parts of part cosolvents are included according to parts by weight.Using water-based acrylic resin and aqueous acrylic emulsion resin as binder, effectively strengthen the tack of ink, improve its preventing stick dirty and ink transfer.The low VOC of water-base resin, low smell.The auxiliary agent for increasing proper ratio is beneficial to the mobility of increase ink.Diluent is being configured with ink viscosity is too high, pH value is relatively low, print speed printing speed is very fast and printing technology personnel add dilutional hyponatremia, appropriate diluent can be added.The wearability and tack of Tissuemat E enhancing ink are added, ink environment close friend is pollution-free.

Description

A kind of water-based flexographic ink
Technical field
The present invention relates to ink-printing techniques field, more particularly to a kind of water-based flexographic ink.
Background technology
Flexible version printing (flexography), abbreviation flexographic printing, refer to pass using flexographic plate, by anilox roller Pass a kind of mode of printing that ink applies print.Flexographic printing, printing plate typically use thickness 1-5mm photopolymer plate.Ink point three Major class, it is water-based ink, alcohol-soluble printing ink, UV ink respectively.Due to ink used in flexographic printing meet it is green, at present Food, packages printing are largely used to, is had a extensive future.Flexographic printing belongs to convex print type.
Flexographic printing, hectographic printing, intaglio printing and silk-screen printing are most common four big mode of printings in the world, they With their own characteristics, it is each has something to recommend him.In the flourishing country of the printing industries such as America and Europe, flexographic printing have developed rapidly, packages printing from It is changed into based on gravure and offset printing based on flexographic printing, about 70% packaging material uses flexographic printing.
In China, development and people's living standards continue to improve with commodity economy, package printing industry is also positive High-grade, fine, multi items direction to develop.But offset printing and the market share shared by gravure are quite big, and flexographic plate is printed on The starting in China is then than later, particularly in terms of the printing of expensive goods.With the continuous application of new technology, flexographic printing is Through having made significant headway, product quality directly chases after offset printing and gravure, is provided with the great market competitiveness.
Compared with gravure, offset printing and traditional convex print, flexographic plate mode of printing has oneself salient feature:Cost It is low;Equipment is simple;Efficiency high;It is in extensive range;Quality is good;Environmental protection;And printed matter level is abundant, in bright gay color, visual effect It is good, it is particularly suitable for the requirement of packages printing.
Ink is mostly solvent typically by the material compositions such as link stuff, pigment, filler, solvent, auxiliary agent, traditional ink Ink often containing aromatic compounds such as toluene, dimethylbenzene, can cause air pollution during use, and volatilize carcinogenic substance Matter, the health of staff is damaged.Water-based ink is a kind of ink type of green non-pollution.In Chinese patent The aqueous ink of CN105820651A middle fingers nonflammable, model stability, does not corrode sheet material because its is cheap, simple to operate Outer packing especially suitable for video, beverage, cigarette etc. is printed.
But cause that the tack of water-based ink ink is poor, ink transfer is undesirable, ink because the surface tension of water is higher Water-resistance, the moisture-proof frictional behaviour for printing finished product are poor;Paper contraction is easily caused, limits the scope of application of water-based ink.
The content of the invention
It is poor to solve water-based ink wearability, tack, the undesirable technical problem of ink transfer, propose a kind of aqueous flexible plate Ink.
The technical scheme is that;
A kind of water-based flexographic ink, 10-20 parts water-based acrylic resin, 20-30 part aqueous acrylamide yogurts are included according to parts by weight Liquid resin, 20-30 parts pigment, 7-16.5 parts water-soluble additive and 10-20 part cosolvents.
The water-based flexographic ink of the present invention is helped by water-base resin link stuff, inorganic pigment, water-soluble additive and a part The uniform slurry like material of the material composition such as agent and water.The water-base resin binder of use is by water-based acrylic resin(Water-soluble)And Aqueous acrylic emulsion resin(Water-dispersion type)Deng composition, water-base resin is most important composition in water-based ink, and its composition is straight Connecing influences the attached function of ink, rate of drying, preventing stick dirty performance etc.;Ink and ink transfer are also influenceed simultaneously, to ink Provide necessary transfer performance.The preferably low VOC of ink of the present invention, the water-base resin of low smell etc..Water-soluble additive is one The mixture of kind or many kinds of substance.Cosolvent is needed to use to improve the water solubility of resinae.Cosolvent can be water and second Alcohol, mainly dissolving resin, adjust the viscosity and rate of drying of ink.
Preferably, water-based ink includes 15 parts of water-based acrylic resins, 28 parts of aqueous acrylic emulsion trees according to parts by weight Fat, 25 parts of pigment, 12 parts of water-soluble additives and 15 parts of cosolvents.
Preferably, pigment is the one or more in rutile titanium white powder, iron oxide, iron hydroxide, pearl essence, carbon black. Pigment is the present-color material of water-based ink, gives the particular color of ink one.To make trace beautiful in colour in flexo, colour saturation sense By force, the pigment of use is good from chemical stability, the high inorganic pigment of tinting strength, tinting power.
Preferably, pigment is iron hydroxide.
Preferably, aqueous promoter is the one or more in dispersant, defoamer, slipping agent, drying retardant and diluent.
Because water-based ink is a kind of soap composition, bubble is also easy to produce in use, therefore to add silicone oil material conduct Defoamer, to suppress and eliminate bubble, while improve the transfer performance of ink.Retarding agent is used for the dry speed for suppressing water-based ink Degree, prevents that ink is solid in anilox roll, reduces scumming etc..The mainly abundant ink " skeleton " of slipping agent, improves printing levelling, Increase color saturation etc..Diluent is the color for subtracting light water-based ink, can also be used as a kind of polishes, improves water-based ink Brightness.Some waxs are also added to increase its wearability in other water-based ink.
Preferably, aqueous promoter fraction by weight is smooth comprising 0.5-2 parts dispersant, 0.5-1.5 parts defoamer, 3-5 parts Agent, 3-8 part drying retardants.
Preferably, dispersant is dimethyl silicone polymer, and defoamer is silicone emulsion, and slipping agent is Tissuemat E, slow curing Agent is propane diols.
Preferably, aqueous promoter fraction by weight is smooth comprising 0.5-2 parts dispersant, 0.5-1.5 parts defoamer, 3-5 parts Agent, 3-8 parts drying retardant and 2-3.5 part diluents.
Preferably, diluent is in parts by weight comprising 10-20 parts water-based acrylic resin, 40-50 part water soluble acrylic acid trees Fat, 3-5 parts Tissuemat E, 0.5-1.5 parts silicone emulsion, 10-20 part ethanol.
Preferably, aqueous promoter also includes talcum powder, and the parts by weight of the talcum powder are 8-15 parts.
The present invention uses water-based acrylic resin and aqueous acrylic emulsion resin effectively to strengthen ink as binder Tack, improve its preventing stick dirty and ink transfer.The low VOC of water-base resin, low smell.The auxiliary agent for increasing proper ratio is beneficial to increase The mobility of inking up.
Embodiment
Embodiment one
The water-based flexographic ink of the present embodiment, 10 parts of water-based acrylic resins, 20 portions of aqueous acrylamide yogurts are included according to parts by weight Liquid resin, 20 parts of iron hydroxides, 7 parts of water-soluble additives(Fraction includes 0.5 part of dimethyl silicone polymer, 0.5 part of emulsification by weight Silicone oil, 3 parts of Tissuemat Es, 3 parts of propane diols)And 10 parts of ethanol.
Embodiment two
Water-based flexographic ink in the present embodiment, 20 parts of water-based acrylic resins, 30 parts of water soluble acrylic acids are included according to parts by weight Emulsion resin, 30 parts of rutile titanium white powder, 16.5 parts of water-soluble additives(Including including 2 parts of dimethyl silicone polymers, 1.5 parts of breasts SiClx oil, 5 parts of Tissuemat Es, 8 parts of propane diols)And 20 parts of ethanol.
Embodiment three
Water-based flexographic ink in the present embodiment, 20 parts of water-based acrylic resins, 30 parts of water soluble acrylic acids are included according to parts by weight Emulsion resin, 30 parts of rutile titanium white powder, 15 parts of ethanol and 16 parts of water-soluble additives, wherein aqueous promoter include poly- comprising 2 parts Dimethyl siloxane, 1.5 parts of silicone emulsions, 4 parts of Tissuemat Es, 6 parts of propane diols and 2 parts of diluents, the diluent are by weight Measure number and include 10 parts of water-based acrylic resins, 40 parts of water-based acrylic resins, 3 parts of Tissuemat Es, 0.5 part of silicone emulsion, 10 Part ethanol.
Example IV
The difference of example IV and embodiment three is that the number of diluent is 3.5 parts in example IV, and diluent is by weight Number includes 20 parts of water-based acrylic resins, 50 parts of water-based acrylic resins, 5 parts of Tissuemat Es, 1.5 parts of silicone emulsions, 20 parts of second Alcohol.
Embodiment five
Water-based flexographic ink in the present embodiment, 215 parts of water-based acrylic resins, 28 parts of water soluble acrylic acids are included according to parts by weight Emulsion resin, 25 parts of pearl powders, 15 parts of ethanol and 12 parts of water-soluble additives, aqueous promoter fraction by weight include 0.6 part Dispersant, 0.6 part of defoamer, 4 parts of slipping agents, 4 parts of drying retardants and 2.8 parts of diluents, the diluent include in parts by weight 15 parts of water-based acrylic resins, 45 parts of water-based acrylic resins, 4 parts of Tissuemat Es, 1.0 parts of silicone emulsions, 15 parts of ethanol.
Embodiment six
Embodiment six is a difference in that aqueous promoter also includes talcum powder with embodiment five, and the parts by weight of talcum powder are 8 parts. Other material numbers and embodiment five are identical.
Embodiment seven
Embodiment seven is a difference in that aqueous promoter also includes talcum powder with embodiment five, and the parts by weight of talcum powder are 10 Part.Other material numbers and embodiment five are identical.
Embodiment eight
Embodiment eight is a difference in that aqueous promoter also includes talcum powder with embodiment five, and the parts by weight of talcum powder are 15 Part.Other material numbers and embodiment five are identical.
Comparative example
Ink in the present embodiment, according to parts by weight include 8 parts of water-based acrylic resins, 15 parts of aqueous acrylic emulsion resins, 32 parts of iron hydroxides, 5 parts of water-soluble additives(Fraction includes 0.5 part of dimethyl silicone polymer, 0.5 part of silicone emulsion, 3 by weight Part Tissuemat E, 3 parts of propane diols)And 10 parts of ethanol.
The ink colors into embodiment eight of embodiment one are bright-coloured, approximate standard specimen;20 μm of fineness average out to;Viscosity is in normal model In enclosing;Solid content 0.4mm/30s.Ink transfer is good, is not in that ink coating is uneven, and color has good uniformity during use. Ink colors in comparative example have a long way to go with standard specimen, and average fineness is at 30 μm or so, and tack is very poor.
Using water-based acrylic resin and aqueous acrylic emulsion resin as binder, effectively strengthen the attachment of ink Property, improve its preventing stick dirty and ink transfer.The low VOC of water-base resin, low smell.The auxiliary agent for increasing proper ratio is beneficial to increase oil The mobility of ink.Diluent is being configured with ink viscosity is too high, pH value is relatively low, print speed printing speed is very fast and printing technology personnel add Dilutional hyponatremia, appropriate diluent can be added.The wearability and tack of Tissuemat E enhancing ink are added, ink environment is friendly It is pollution-free.
The present invention is not limited to above-mentioned specific embodiment, and the present invention can have various modifications and variations.Every foundation Any modification, equivalent substitution and improvements that the technical spirit of the present invention is made to embodiment of above etc., should be included in the present invention Protection domain.

Claims (10)

1. a kind of water-based flexographic ink, it is characterised in that include 10-20 parts water-based acrylic resin, 20-30 parts according to parts by weight Aqueous acrylic emulsion resin, 20-30 parts pigment, 7-16.5 parts water-soluble additive and 10-20 part cosolvents.
2. water-based flexographic ink according to claim 1, it is characterised in that include 15 parts of water soluble acrylic acids according to parts by weight Resin, 28 parts of aqueous acrylic emulsion resins, 25 parts of pigment, 12 parts of water-soluble additives and 15 parts of cosolvents.
3. water-based flexographic ink according to claim 1 or 2, it is characterised in that the pigment is rutile titanium white powder, oxygen Change the one or more in iron, iron hydroxide, pearl essence, carbon black.
4. water-based flexographic ink according to claim 1 or 2, it is characterised in that the pigment is iron hydroxide.
5. water-based flexographic ink according to claim 1, it is characterised in that the aqueous promoter be dispersant, defoamer, One or more in slipping agent, drying retardant and diluent.
6. water-based flexographic ink according to claim 5, it is characterised in that aqueous promoter fraction by weight includes 0.5-2 parts dispersant, 0.5-1.5 parts defoamer, 3-5 parts slipping agent, 3-8 part drying retardants.
7. water-based flexographic ink according to claim 6, it is characterised in that the dispersant is dimethyl silicone polymer, The defoamer is silicone emulsion, and the slipping agent is Tissuemat E, and the drying retardant is propane diols.
8. water-based flexographic ink according to claim 5, it is characterised in that aqueous promoter fraction by weight includes 0.5-2 parts dispersant, 0.5-1.5 parts defoamer, 3-5 parts slipping agent, 3-8 parts drying retardant and 2-3.5 part diluents.
9. water-based flexographic ink according to claim 6, it is characterised in that the diluent includes 10- in parts by weight 20 parts of water-based acrylic resins, 40-50 parts water-based acrylic resin, 3-5 parts Tissuemat E, 0.5-1.5 parts silicone emulsion, 10- 20 parts of ethanol.
10. the water-based flexographic ink described in any one in claim 6 to 9, it is characterised in that the aqueous promoter Also include talcum powder, the parts by weight of the talcum powder are 8-15 parts.
CN201711290417.6A 2017-12-08 2017-12-08 A kind of water-based flexographic ink Pending CN107739553A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
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CN111040512A (en) * 2019-12-26 2020-04-21 广东天龙油墨有限公司 Water-based flexographic printing ink for thin film printing and preparation method thereof
CN116102918A (en) * 2023-02-28 2023-05-12 广州市哲铭油墨涂料有限公司 Manufacturing process of water-based ink

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CN105199481A (en) * 2015-10-21 2015-12-30 广州市三国水性油墨有限公司 Double-PE water-based ink and preparation method thereof

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CN105199481A (en) * 2015-10-21 2015-12-30 广州市三国水性油墨有限公司 Double-PE water-based ink and preparation method thereof

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111040512A (en) * 2019-12-26 2020-04-21 广东天龙油墨有限公司 Water-based flexographic printing ink for thin film printing and preparation method thereof
CN116102918A (en) * 2023-02-28 2023-05-12 广州市哲铭油墨涂料有限公司 Manufacturing process of water-based ink

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Effective date of registration: 20200819

Address after: 430000 Room 303, floor 3, No. 1, Haikou 2nd Road, Jinyinhu office, Dongxihu District, Wuhan City, Hubei Province

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Address before: 430040 Hubei province Dongxihu District of Wuhan City Baiquan Office Zhang Bai Lu 226 attached to No. 9

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Application publication date: 20180227

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