CN104877437A - Antimicrobial environment-friendly offset printing ink and preparation method thereof - Google Patents
Antimicrobial environment-friendly offset printing ink and preparation method thereof Download PDFInfo
- Publication number
- CN104877437A CN104877437A CN201510222930.6A CN201510222930A CN104877437A CN 104877437 A CN104877437 A CN 104877437A CN 201510222930 A CN201510222930 A CN 201510222930A CN 104877437 A CN104877437 A CN 104877437A
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- Prior art keywords
- oil
- parts
- ink
- aluminium
- soybean oil
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
- C09D11/033—Printing inks characterised by features other than the chemical nature of the binder characterised by the solvent
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
- C09D11/103—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds of aldehydes, e.g. phenol-formaldehyde resins
Abstract
The invention relates to an antimicrobial environment-friendly offset printing ink which is prepared from the following raw materials in parts by weight: 4-5 parts of lavender essential oil, 0.3-0.4 part of limonene, 2-3 parts of oxidized starch, 0.5-0.6 part of active manganese peroxide, 0.5-0.6 part of phosphorus trichloride, 30-35 parts of rosin modified phenolic resin, 0.1-0.2 part of aluminum oxo-2-ethylhexoate, a right amount of mineral oil, 60-65 parts of soybean oil, 0.1-0.2 part of teri-butyl hydroperoxide, 20-30 parts of colorant, 1-2 parts of lanthanum isooctoate, 1.3-1.6 parts of methyl methacrylate and 2-3 parts of acrylic acid. By using the soybean oil instead of most of the petroleum solvent in the traditional ink, the VOC (volatile organic compound) of the offset printing ink is lowered to 15% below. By adding the oxidized starch, active manganese peroxide, acrylic acid and the like into the soybean oil, polymerization modification is performed to enhance the thixotropy of the ink, so that the ink can be easily solidified. By adding the lavender essential oil and limonene, the offset printing ink has mold resistance.
Description
Technical field
The present invention relates to flexographic ink field, particularly relate to a kind of antibacterial environment protection flexographic ink and preparation method thereof.
Background technology
Flexographic ink is mainly by the coloured material of the flow-like of pigment, auxiliary agent, high molecular polymer and solvent composition, and wherein, the primary solvent of flexographic ink is mineral oil and vegetables oil.The flexographic ink drying process be printed onto on paper is very complicated, and we can be understood as ink is undertaken dry by the oxidation filming of mineral oil infiltration and vegetables oil.
Since having flexographic ink, in flexographic ink, lack the existence that can't do without mineral oil all the time.Usually, be 25%-45% at the content of common flexographic ink mineral oil in fluid.Mineral oil is the Nonrenewable resources extract from oil, wherein containing harmful arene material.
Now, some ink enterprises successfully develop Soybean Oil Ink, make VOC (organic volatile) content be reduced to less than 15% from 30%-60%, greatly reduce the pollution of environment and be beneficial to health of human body, there is good theoretical significance and using value.But because soybean oil belongs to semi-drying oil, there is the problems such as ink dryness is poor, ink-water balance difficult control when substituting the petroleum solvent in traditional ink by soybean oil, the low inferior problem of production efficiency, therefore need to improve.
Also there are some rheological problems in current soybean oil offset ink, as thixotropy, tackyness, yield value, also has the performance needs such as rub resistance, splitting resistance, germ resistance, persistence to improve.
Summary of the invention
The object of the present invention is to provide a kind of antibacterial environment protection flexographic ink, this flexographic ink has anti-microbial property, and easy drying is solidified, Environmental Safety.
Technical scheme of the present invention is as follows:
A kind of antibacterial environment protection flexographic ink, is characterized in that being made up of the raw material of following weight part: Herba Lysimachiae foenumgraeci quintessence oil 4-5, limonene 0.3-0.4, Sumstar 190 2-3, activated manganese dioxide 0.5-0.6, phosphorus trichloride 0.5-0.6, rosin modified phenolic resin 30-35, oxo-2 ethyl hexanoic acid root close that the homopolymer 0.1-0.2 of aluminium, Dormant oils are appropriate, soybean oil 60-65, tertbutyl peroxide 0.1-0.2, tinting material 20-30, isocaprylic acid lanthanum 1-2, methyl methacrylate 1.3-1.6, vinylformic acid 2-3.
The production method of described antibacterial environment protection flexographic ink, is characterized in that:
(1) by soybean oil, Herba Lysimachiae foenumgraeci quintessence oil, limonene, Sumstar 190, activated manganese dioxide, phosphorus trichloride, methyl methacrylate, vinylformic acid mixing and stirring, be warming up to 60-70 DEG C, add tertbutyl peroxide, stir 20-30 minute, obtain soybean oil solvent;
(2) send in reactor by rosin modified phenolic resin, soybean oil solvent, stir and be warming up to 170-180 DEG C, do not stop to stir insulation 2-2.5 hour, naturally cooling, obtains sylvic oil;
(3) homopolymer oxo-2 ethyl hexanoic acid root being closed aluminium adds appropriate mineral oil, is mixed with the aluminium oil that aluminium content is 3%;
(4) sylvic oil is heated to 75-80 DEG C, drip aluminium oil, dropping limit, limit is stirred, and adds aluminium oil before 90 DEG C, continues warming while stirring to 175-180 DEG C, and insulation 40-50 minute, naturally cools to room temperature, obtain binder;
(5) binder is mixed with other remaining components, feeding three-roller is ground to the fineness that ink specifies, obtains final product.
Beneficial effect of the present invention
Flexographic ink of the present invention instead of the most of petroleum solvent in traditional ink by use soybean oil, VOC is made to be reduced to less than 15%, by adding the materials such as Sumstar 190, activated manganese dioxide, vinylformic acid in soybean oil, through polymeric modification, improve the thixotropy of ink, easily solidify, by adding Herba Lysimachiae foenumgraeci quintessence oil, limonene, there is anti-microbial property, simultaneously volatile, promote that ink setting solidifies; This ink objectionable impurities is few, environment protection health.
Embodiment
A kind of antibacterial environment protection flexographic ink, is made up of the raw material of following weight part (kilogram): Herba Lysimachiae foenumgraeci quintessence oil 4.5, limonene 0.3, Sumstar 190 2.5, activated manganese dioxide 0.5, phosphorus trichloride 0.5, rosin modified phenolic resin 33, the oxo-homopolymer 0.1 of 2 ethyl hexanoic acid root conjunction aluminium, Dormant oils are appropriate, soybean oil 64, tertbutyl peroxide 0.1, tinting material 26, isocaprylic acid lanthanum 1.5, methyl methacrylate 1.4, vinylformic acid 2.5.
The production method of described antibacterial environment protection flexographic ink, is characterized in that:
(1) by soybean oil, Herba Lysimachiae foenumgraeci quintessence oil, limonene, Sumstar 190, activated manganese dioxide, phosphorus trichloride, methyl methacrylate, vinylformic acid mixing and stirring, be warming up to 65 DEG C, add tertbutyl peroxide, stir 25 minutes, obtain soybean oil solvent;
(2) send in reactor by rosin modified phenolic resin, soybean oil solvent, stir and be warming up to 175 DEG C, do not stop to stir insulation 2 hours, naturally cooling, obtains sylvic oil;
(3) homopolymer oxo-2 ethyl hexanoic acid root being closed aluminium adds appropriate mineral oil, is mixed with the aluminium oil that aluminium content is 3%;
(4) sylvic oil is heated to 78 DEG C, drip aluminium oil, dropping limit, limit is stirred, and adds aluminium oil before 90 DEG C, continues warming while stirring to 178 DEG C, is incubated 47 minutes, naturally cools to room temperature, obtain binder;
(5) binder is mixed with other remaining components, feeding three-roller is ground to the fineness that ink specifies, obtains final product.
Experimental data:
The yield value of this ink is 19.6Pa, and viscosity is 2.88Pa.s, and set speed is 15min, and with the printing of high-speed lithographic offset machine, speed is 9200/h, and lines are smooth, and the full marking good attachment of image, can reach printing requirement.
Claims (2)
1. an antibacterial environment protection flexographic ink, is characterized in that being made up of the raw material of following weight part: Herba Lysimachiae foenumgraeci quintessence oil 4-5, limonene 0.3-0.4, Sumstar 190 2-3, activated manganese dioxide 0.5-0.6, phosphorus trichloride 0.5-0.6, rosin modified phenolic resin 30-35, oxo-2 ethyl hexanoic acid root close that the homopolymer 0.1-0.2 of aluminium, Dormant oils are appropriate, soybean oil 60-65, tertbutyl peroxide 0.1-0.2, tinting material 20-30, isocaprylic acid lanthanum 1-2, methyl methacrylate 1.3-1.6, vinylformic acid 2-3.
2. the production method of antibacterial environment protection flexographic ink according to claim 1, is characterized in that:
(1) by soybean oil, Herba Lysimachiae foenumgraeci quintessence oil, limonene, Sumstar 190, activated manganese dioxide, phosphorus trichloride, methyl methacrylate, vinylformic acid mixing and stirring, be warming up to 60-70 DEG C, add tertbutyl peroxide, stir 20-30 minute, obtain soybean oil solvent;
(2) send in reactor by rosin modified phenolic resin, soybean oil solvent, stir and be warming up to 170-180 DEG C, do not stop to stir insulation 2-2.5 hour, naturally cooling, obtains sylvic oil;
(3) homopolymer oxo-2 ethyl hexanoic acid root being closed aluminium adds appropriate mineral oil, is mixed with the aluminium oil that aluminium content is 3%;
(4) sylvic oil is heated to 75-80 DEG C, drip aluminium oil, dropping limit, limit is stirred, and adds aluminium oil before 90 DEG C, continues warming while stirring to 175-180 DEG C, and insulation 40-50 minute, naturally cools to room temperature, obtain binder;
(5) binder is mixed with other remaining components, feeding three-roller is ground to the fineness that ink specifies, obtains final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510222930.6A CN104877437A (en) | 2015-05-05 | 2015-05-05 | Antimicrobial environment-friendly offset printing ink and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510222930.6A CN104877437A (en) | 2015-05-05 | 2015-05-05 | Antimicrobial environment-friendly offset printing ink and preparation method thereof |
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| CN104877437A true CN104877437A (en) | 2015-09-02 |
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| CN201510222930.6A Pending CN104877437A (en) | 2015-05-05 | 2015-05-05 | Antimicrobial environment-friendly offset printing ink and preparation method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109593384A (en) * | 2018-12-25 | 2019-04-09 | 山东宇虹新颜料股份有限公司 | A kind of preparation method of pigment preparations used for offset ink |
| US10696471B2 (en) | 2017-10-31 | 2020-06-30 | Medline Industries, Inc. | Enclosure for gloves with antimicrobial ink coating and methods for making the same |
| CN114686040A (en) * | 2022-03-30 | 2022-07-01 | 张皓楠 | Preparation method of environment-friendly quick-drying offset printing ink |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101671504A (en) * | 2009-09-30 | 2010-03-17 | 太原印科油墨有限公司 | Soybean oil type offset printing color ink |
-
2015
- 2015-05-05 CN CN201510222930.6A patent/CN104877437A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101671504A (en) * | 2009-09-30 | 2010-03-17 | 太原印科油墨有限公司 | Soybean oil type offset printing color ink |
Non-Patent Citations (4)
| Title |
|---|
| 天津化工研究院等: "《无机盐工业手册（第二版）上册 》", 31 January 1996, 化学工业出版社 * |
| 常景玲: "《天然生物活性物质及其制备技术》", 31 August 2007, 河南科学技术出版社 * |
| 张小舟等: "《高分子化学》", 31 January 2015, 哈尔滨工业大学出版社 * |
| 徐宝财: "《表面活性剂原料手册》", 30 April 2007, 化学工业出版社 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10696471B2 (en) | 2017-10-31 | 2020-06-30 | Medline Industries, Inc. | Enclosure for gloves with antimicrobial ink coating and methods for making the same |
| CN109593384A (en) * | 2018-12-25 | 2019-04-09 | 山东宇虹新颜料股份有限公司 | A kind of preparation method of pigment preparations used for offset ink |
| CN109593384B (en) * | 2018-12-25 | 2020-09-25 | 宇虹颜料股份有限公司 | Preparation method of pre-dispersed pigment for offset printing ink |
| CN114686040A (en) * | 2022-03-30 | 2022-07-01 | 张皓楠 | Preparation method of environment-friendly quick-drying offset printing ink |
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Application publication date: 20150902 |