CN102977730A - Metal antirust paint treating modified attapulgite as filler, and its preparation method - Google Patents
Metal antirust paint treating modified attapulgite as filler, and its preparation method Download PDFInfo
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- CN102977730A CN102977730A CN201210432547XA CN201210432547A CN102977730A CN 102977730 A CN102977730 A CN 102977730A CN 201210432547X A CN201210432547X A CN 201210432547XA CN 201210432547 A CN201210432547 A CN 201210432547A CN 102977730 A CN102977730 A CN 102977730A
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- 229960000892 attapulgite Drugs 0.000 title claims abstract description 34
- 229910052625 palygorskite Inorganic materials 0.000 title claims abstract description 34
- 239000003973 paint Substances 0.000 title claims abstract description 24
- 238000002360 preparation method Methods 0.000 title claims abstract description 17
- 239000000945 filler Substances 0.000 title claims abstract description 16
- 229910052751 metal Inorganic materials 0.000 title abstract description 8
- 239000002184 metal Substances 0.000 title abstract description 8
- 239000000839 emulsion Substances 0.000 claims abstract description 37
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229920001661 Chitosan Polymers 0.000 claims abstract description 9
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000002131 composite material Substances 0.000 claims abstract description 9
- 239000005011 phenolic resin Substances 0.000 claims abstract description 9
- 229920000058 polyacrylate Polymers 0.000 claims abstract description 9
- -1 polybutylene terephthalate Polymers 0.000 claims abstract description 9
- 229920001707 polybutylene terephthalate Polymers 0.000 claims abstract description 9
- 239000011118 polyvinyl acetate Substances 0.000 claims abstract description 9
- 229920002689 polyvinyl acetate Polymers 0.000 claims abstract description 9
- 239000002253 acid Substances 0.000 claims description 20
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 14
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 12
- 239000000463 material Substances 0.000 claims description 10
- HVUMOYIDDBPOLL-UHFFFAOYSA-N 2-(3,4-Dihydroxyoxolan-2-yl)-2-hydroxyethyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)C1OCC(O)C1O HVUMOYIDDBPOLL-UHFFFAOYSA-N 0.000 claims description 8
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 8
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 8
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 claims description 8
- 239000004816 latex Substances 0.000 claims description 8
- 229920000126 latex Polymers 0.000 claims description 8
- 229940070721 polyacrylate Drugs 0.000 claims description 8
- 229910000077 silane Inorganic materials 0.000 claims description 8
- 229960004418 trolamine Drugs 0.000 claims description 8
- 239000000052 vinegar Substances 0.000 claims description 8
- 235000021419 vinegar Nutrition 0.000 claims description 8
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 8
- 229920002554 vinyl polymer Polymers 0.000 claims description 8
- 239000008367 deionised water Substances 0.000 claims description 6
- 229910021641 deionized water Inorganic materials 0.000 claims description 6
- 239000006185 dispersion Substances 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 3
- 230000007935 neutral effect Effects 0.000 claims description 3
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 3
- 238000003825 pressing Methods 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- 239000002994 raw material Substances 0.000 abstract description 4
- 238000001035 drying Methods 0.000 abstract description 3
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 abstract 1
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 abstract 1
- HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 abstract 1
- 238000005260 corrosion Methods 0.000 abstract 1
- 230000007797 corrosion Effects 0.000 abstract 1
- 230000007613 environmental effect Effects 0.000 abstract 1
- WOXXJEVNDJOOLV-UHFFFAOYSA-N ethenyl-tris(2-methoxyethoxy)silane Chemical compound COCCO[Si](OCCOC)(OCCOC)C=C WOXXJEVNDJOOLV-UHFFFAOYSA-N 0.000 abstract 1
- 238000011031 large-scale manufacturing process Methods 0.000 abstract 1
- RKISUIUJZGSLEV-UHFFFAOYSA-N n-[2-(octadecanoylamino)ethyl]octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NCCNC(=O)CCCCCCCCCCCCCCCCC RKISUIUJZGSLEV-UHFFFAOYSA-N 0.000 abstract 1
- 229920001568 phenolic resin Polymers 0.000 abstract 1
- 229920001610 polycaprolactone Polymers 0.000 abstract 1
- 239000004632 polycaprolactone Substances 0.000 abstract 1
- 239000002861 polymer material Substances 0.000 abstract 1
- 239000004922 lacquer Substances 0.000 description 5
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 238000010276 construction Methods 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
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- Paints Or Removers (AREA)
Abstract
The invention discloses a metal antirust paint treating modified attapulgite as a filler, and its preparation method. The metal antirust paint comprises the following raw materials, by weight, 22-27 parts of a water-soluble phenolic resin, 15-20 parts of a polyurethane-polyacrylate composite emulsion, 18-22 parts of the modified attapulgite, 7-9 parts of a silicone-acrylic emulsion, 1.0-1.5 parts of triethanolamine, 18-22 parts of polycaprolactone, 0.7-0.9 parts of Span-60, 0.1-0.3 parts of polybutylene terephthalate, 0.7-0.9 parts of poly-4-methyl-1-pentene, 0.4-0.6 parts of 2,6-di-t-butyl-alpha-dimethylamino-p-phenol, 1.5-2.5 parts of a modified acrylic emulsion, 0.5-0.8 parts of chitosan, 0.2-0.4 parts of ethylene bis-stearamide, 0.8-1.2 parts of tris(methoxyethoxy)vinylsilane and 1.3-1.8 parts of a polyvinyl acetate emulsion. The film of the metal antirust paint has the advantages of good adhesion, fast drying, good heat resistance, environmental protection and no pollution, and the modified attapulgite and the modified acrylic emulsion added to the raw materials improve the excellent performances of high-polymer materials in the raw materials and simultaneously increase the corrosion resistance and the heat resistance of the metal antirust paint; and the preparation method has the advantages of simplicity, low cost and suitableness for large-scale production.
Description
Technical field
The present invention relates to a kind ofly take attapulgite modified metallic anti-rust paint as filler and preparation method thereof, belong to the rush-resisting material technical field.
Background technology
Adopted in recent years industrial antirust paint protect metal take the epoxy zinc-rich lacquer as at most because the density ratio of metal zinc is larger, in order not make zinc powder settling or the settling velocity of the zinc powder that slows down, need in lacquer, add a certain amount of anti-sedimentation agent; The viscosity of the adding lacquer of anti-settling agent also increases thereupon, will select as much as possible the resin (E44) of small molecular weight when selecting polyamide resin; In order to satisfy brushing property, add a large amount of solvents in lacquer during construction, solvent serious harm workman's healthy, lacquer solvent evaporates contaminate environment, making of solvent in the air in drying process improved construction cost during construction; The fragility of paint film is large behind the small molecular weight resin solidification, metal heat-expansion shrinkage system greatly when temperature variation paint film easily chap or come off.
Summary of the invention
In order to alleviate shortcomings and deficiencies of the prior art, it is a kind of take attapulgite modified metallic anti-rust paint as filler and preparation method thereof that the object of the invention is to provide.
The present invention adopts following technical scheme to achieve these goals:
Take attapulgite modified metallic anti-rust paint as filler, the weight part of its constitutive material is: water soluble phenol resin 22-27, urethane-poly acrylate composite emulsion 15-20, attapulgite modified 18-22, organosilicon crylic acid latex 7-9, trolamine 1.0-1.5, vinegar 18-22 in the poly-caproic acid, sorbester p18 0.7-0.9, polybutylene terephthalate 0.1-0.3, poly--4-methyl-1-pentene 0.7-0.9,2,6-di-t-butyl-α-dimethylin Pyrogentisinic Acid 0.4-0.6, modified acrylic acid emulsion 1.5-2.5, chitosan 0.5-0.8, the two hard esteramides 0.2-0.4 of ethylene group, vinyl three ('beta '-methoxy oxyethyl group) silane 0.8-1.2 and polyvinyl acetate emulsion 1.3-1.8.
Take attapulgite modified metallic anti-rust paint as filler, the weight part of its constitutive material is: water soluble phenol resin 25, urethane-poly acrylate composite emulsion 18, attapulgite modified 20, organosilicon crylic acid latex 8, trolamine 1.2, vinegar 20 in the poly-caproic acid, sorbester p18 0.8, polybutylene terephthalate 0.2, poly--4-methyl-1-pentene 0.8,2,6-di-t-butyl-α-dimethylin Pyrogentisinic Acid 0.5, modified acrylic acid emulsion 2.0, chitosan 0.7, the two hard esteramides 0.3 of ethylene group, vinyl three ('beta '-methoxy oxyethyl group) silane 1.0 and polyvinyl acetate emulsion 1.5.
Preparation method take attapulgite modified metallic anti-rust paint as filler may further comprise the steps:
(1) weight part of pressing constitutive material is with water soluble phenol resin, urethane-poly acrylate composite emulsion, organosilicon crylic acid latex, modified acrylic acid emulsion, polyvinyl acetate emulsion, attapulgite modified and chitosan mixing and stirring, and high speed dispersion also is ground to below the 35um fineness;
(2) in above-mentioned reaction system, add by weight vinegar, sorbester p18, polybutylene terephthalate, poly--4-methyl-1-pentene, 2 in trolamine, the poly-caproic acid, 6-di-t-butyl-α-dimethylin Pyrogentisinic Acid, the two hard esteramides of ethylene group and vinyl three ('beta '-methoxy oxyethyl group) silane are at 700-800
Turn/
MinuteUnder the rotating speed high speed dispersion 10-15 minute, obtain finished product.
Described attapulgite modified preparation method is that attapulgite is used 10-15% salt acid soak 3-4 hour, and deionized water wash soaked 3-4 hour with the 10-12% sodium hydroxide solution again, and extremely neutral with deionized water wash again, oven dry obtains.
Described modified acrylic acid emulsion preparation method adds 4-5% magnetic, 3-5% aluminum oxide for adopting in the ACRYLIC EMULSION, be mixed and heated to 70-80 ℃, and cooling obtains after 30-40 minute.
Beneficial effect of the present invention:
, the fast drying good take attapulgite modified metallic anti-rust paint paint film adhesion as filler of the present invention preparation, good heat resistance, environment friendly and pollution-free, added attapulgite modified and modified acrylic acid emulsion in the raw material, by the modification to attapulgite and ACRYLIC EMULSION, improved the premium properties of the macromolecular material in the starting material, increased simultaneously erosion resistance and the thermotolerance of product, and preparation method of the present invention has been simple, cost is low, is fit to scale operation.
Embodiment
Embodiment:Take attapulgite modified metallic anti-rust paint as filler, the weight part of its constitutive material is: water soluble phenol resin 25, urethane-poly acrylate composite emulsion 18, attapulgite modified 20, organosilicon crylic acid latex 8, trolamine 1.2, vinegar 20 in the poly-caproic acid, sorbester p18 0.8, polybutylene terephthalate 0.2, poly--4-methyl-1-pentene 0.8,2,6-di-t-butyl-α-dimethylin Pyrogentisinic Acid 0.5, modified acrylic acid emulsion 2.0, chitosan 0.7, the two hard esteramides 0.3 of ethylene group, vinyl three ('beta '-methoxy oxyethyl group) silane 1.0 and polyvinyl acetate emulsion 1.5.
Preparation method take attapulgite modified metallic anti-rust paint as filler may further comprise the steps:
(1) weight part of pressing constitutive material is with water soluble phenol resin, urethane-poly acrylate composite emulsion, organosilicon crylic acid latex, modified acrylic acid emulsion, polyvinyl acetate emulsion, attapulgite modified and chitosan mixing and stirring, and high speed dispersion also is ground to below the 35um fineness;
(2) in above-mentioned reaction system, add by weight vinegar, sorbester p18, polybutylene terephthalate, poly--4-methyl-1-pentene, 2 in trolamine, the poly-caproic acid, 6-di-t-butyl-α-dimethylin Pyrogentisinic Acid, the two hard esteramides of ethylene group and vinyl three ('beta '-methoxy oxyethyl group) silane are at 700-800
Turn/
MinuteUnder the rotating speed high speed dispersion 10-15 minute, obtain finished product.
Described attapulgite modified preparation method is that attapulgite is used 10-15% salt acid soak 3-4 hour, and deionized water wash soaked 3-4 hour with the 10-12% sodium hydroxide solution again, and extremely neutral with deionized water wash again, oven dry obtains.
Described modified acrylic acid emulsion preparation method adds 4-5% magnetic, 3-5% aluminum oxide for adopting in the ACRYLIC EMULSION, be mixed and heated to 70-80 ℃, and cooling obtains after 30-40 minute.
Adopt the metallic anti-rust paint of embodiment 1 to carry out technology for detection, the result is as follows:
1, sticking power/level≤1 grade; 2, snappiness/level: 1 grade; 3, thermotolerance: 290 ℃ excellent; 4, alkali resistance: 20% sodium hydroxide stood intact in 33 days; 5, acid resistance 20% sulfuric acid stood intact in 32 days; 6, non-volatile content: 〉=81.5%.
Claims (5)
1. one kind take attapulgite modified metallic anti-rust paint as filler, the weight part that it is characterized in that its constitutive material is: water soluble phenol resin 22-27, urethane-poly acrylate composite emulsion 15-20, attapulgite modified 18-22, organosilicon crylic acid latex 7-9, trolamine 1.0-1.5, vinegar 18-22 in the poly-caproic acid, sorbester p18 0.7-0.9, polybutylene terephthalate 0.1-0.3, poly--4-methyl-1-pentene 0.7-0.9,2,6-di-t-butyl-α-dimethylin Pyrogentisinic Acid 0.4-0.6, modified acrylic acid emulsion 1.5-2.5, chitosan 0.5-0.8, the two hard esteramides 0.2-0.4 of ethylene group, vinyl three ('beta '-methoxy oxyethyl group) silane 0.8-1.2 and polyvinyl acetate emulsion 1.3-1.8.
2. according to claim 1 take attapulgite modified metallic anti-rust paint as filler, the weight part that it is characterized in that its constitutive material is: water soluble phenol resin 25, urethane-poly acrylate composite emulsion 18, attapulgite modified 20, organosilicon crylic acid latex 8, trolamine 1.2, vinegar 20 in the poly-caproic acid, sorbester p18 0.8, polybutylene terephthalate 0.2, poly--4-methyl-1-pentene 0.8,2,6-di-t-butyl-α-dimethylin Pyrogentisinic Acid 0.5, modified acrylic acid emulsion 2.0, chitosan 0.7, the two hard esteramides 0.3 of ethylene group, vinyl three ('beta '-methoxy oxyethyl group) silane 1.0 and polyvinyl acetate emulsion 1.5.
3. preparation method take attapulgite modified metallic anti-rust paint as filler as claimed in claim 1 is characterized in that may further comprise the steps:
(1) weight part of pressing constitutive material is with water soluble phenol resin, urethane-poly acrylate composite emulsion, organosilicon crylic acid latex, modified acrylic acid emulsion, polyvinyl acetate emulsion, attapulgite modified and chitosan mixing and stirring, and high speed dispersion also is ground to below the 35um fineness;
(2) in above-mentioned reaction system, add by weight vinegar, sorbester p18, polybutylene terephthalate, poly--4-methyl-1-pentene, 2 in trolamine, the poly-caproic acid, 6-di-t-butyl-α-dimethylin Pyrogentisinic Acid, the two hard esteramides of ethylene group and vinyl three ('beta '-methoxy oxyethyl group) silane are at 700-800
Turn/
MinuteUnder the rotating speed high speed dispersion 10-15 minute, obtain finished product.
4. according to claim 1 take attapulgite modified metallic anti-rust paint as filler, it is characterized in that: described attapulgite modified preparation method is that attapulgite is used 10-15% salt acid soak 3-4 hour, deionized water wash, soaked 3-4 hour with the 10-12% sodium hydroxide solution again, extremely neutral with deionized water wash again, oven dry obtains.
5. according to claim 1 take attapulgite modified metallic anti-rust paint as filler, it is characterized in that: described modified acrylic acid emulsion preparation method adds 4-5% magnetic, 3-5% aluminum oxide for adopting in the ACRYLIC EMULSION, be mixed and heated to 70-80 ℃, cool off after 30-40 minute and obtain.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210432547.XA CN102977730B (en) | 2012-11-02 | 2012-11-02 | Metal antirust paint treating modified attapulgite as filler, and its preparation method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210432547.XA CN102977730B (en) | 2012-11-02 | 2012-11-02 | Metal antirust paint treating modified attapulgite as filler, and its preparation method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102977730A true CN102977730A (en) | 2013-03-20 |
| CN102977730B CN102977730B (en) | 2015-05-06 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210432547.XA Expired - Fee Related CN102977730B (en) | 2012-11-02 | 2012-11-02 | Metal antirust paint treating modified attapulgite as filler, and its preparation method |
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| Country | Link |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103254708A (en) * | 2013-05-22 | 2013-08-21 | 江苏紫石化工科技有限公司 | Compound paint |
| CN103468113A (en) * | 2013-08-16 | 2013-12-25 | 安徽快来防水防腐有限公司 | Weather-resistant polyurethane waterproof coating |
| CN104263136A (en) * | 2014-09-05 | 2015-01-07 | 安徽桑瑞斯环保新材料有限公司 | Anticorrosive antibacterial waterproof coating |
| CN104313616A (en) * | 2014-11-07 | 2015-01-28 | 合肥大安印刷有限责任公司 | Metal surface cleaning agent containing attapulgite and preparation method thereof |
| CN104817948A (en) * | 2015-04-30 | 2015-08-05 | 广西高农机械有限公司 | Corrosion-resisting coating for agent spraying device |
| CN107163770A (en) * | 2017-07-04 | 2017-09-15 | 合肥择浚电气设备有限公司 | A kind of machinery antirust paint containing attapulgite and preparation method thereof |
| CN109135537A (en) * | 2018-07-30 | 2019-01-04 | 界首市鑫全龙粮食机械购销有限公司 | A kind of grain transporter rack coating |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5684764A (en) * | 1979-12-13 | 1981-07-10 | Suzuka Toryo Kk | Lustrous synthetic resin emulsion paint |
| CN1348485A (en) * | 1999-03-03 | 2002-05-08 | 利利工业有限公司 | Abrasion resistant coatings |
| CN1982386A (en) * | 2005-12-12 | 2007-06-20 | 天津鑫泰利科技发展有限公司 | Antirust paint of water acrylic resin |
-
2012
- 2012-11-02 CN CN201210432547.XA patent/CN102977730B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5684764A (en) * | 1979-12-13 | 1981-07-10 | Suzuka Toryo Kk | Lustrous synthetic resin emulsion paint |
| CN1348485A (en) * | 1999-03-03 | 2002-05-08 | 利利工业有限公司 | Abrasion resistant coatings |
| CN1982386A (en) * | 2005-12-12 | 2007-06-20 | 天津鑫泰利科技发展有限公司 | Antirust paint of water acrylic resin |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103254708A (en) * | 2013-05-22 | 2013-08-21 | 江苏紫石化工科技有限公司 | Compound paint |
| CN103468113A (en) * | 2013-08-16 | 2013-12-25 | 安徽快来防水防腐有限公司 | Weather-resistant polyurethane waterproof coating |
| CN104263136A (en) * | 2014-09-05 | 2015-01-07 | 安徽桑瑞斯环保新材料有限公司 | Anticorrosive antibacterial waterproof coating |
| CN104313616A (en) * | 2014-11-07 | 2015-01-28 | 合肥大安印刷有限责任公司 | Metal surface cleaning agent containing attapulgite and preparation method thereof |
| CN104817948A (en) * | 2015-04-30 | 2015-08-05 | 广西高农机械有限公司 | Corrosion-resisting coating for agent spraying device |
| CN107163770A (en) * | 2017-07-04 | 2017-09-15 | 合肥择浚电气设备有限公司 | A kind of machinery antirust paint containing attapulgite and preparation method thereof |
| CN109135537A (en) * | 2018-07-30 | 2019-01-04 | 界首市鑫全龙粮食机械购销有限公司 | A kind of grain transporter rack coating |
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| Publication number | Publication date |
|---|---|
| CN102977730B (en) | 2015-05-06 |
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Inventor after: Liu Li Inventor before: Xiao Ying Inventor before: Zhang Manqing |
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Effective date of registration: 20170926 Address after: 236600 Anhui city of Fuyang Province Taihe County Gao Miao Zhen song Cun Wei Hui Da Song Village No. 10 Patentee after: Liu Li Address before: 247127 Chuk Yuen Village, Copper Mt. Town, Tongling, Anhui Patentee before: Tongling Mingcheng Casting Co., Ltd. |
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Address after: 541600 Guanyang County, the Guangxi Zhuang Autonomous Region, Shuangqiao Road, Guanyang County, the Guangxi Zhuang Autonomous Region Patentee after: Liu Li Address before: 236600 Anhui city of Fuyang Province Taihe County Gao Miao Zhen song Cun Wei Hui Da Song Village No. 10 Patentee before: Liu Li |
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