CN104313616A - Metal surface cleaning agent containing attapulgite and preparation method thereof - Google Patents
Metal surface cleaning agent containing attapulgite and preparation method thereof Download PDFInfo
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- CN104313616A CN104313616A CN201410622240.5A CN201410622240A CN104313616A CN 104313616 A CN104313616 A CN 104313616A CN 201410622240 A CN201410622240 A CN 201410622240A CN 104313616 A CN104313616 A CN 104313616A
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- attapulgite
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/24—Cleaning or pickling metallic material with solutions or molten salts with neutral solutions
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- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
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Abstract
The invention discloses a metal surface cleaning agent containing attapulgite. The metal surface cleaning agent is characterized by being prepared from the following raw materials in parts by weight: 8-10 parts of attapulgite, 1-2 parts of borneol, 3-5 parts of coconut diethanolamide, 0.3-0.5 part of menthol, 1-2 parts of sodium dodecyl benzene sulfonate, 2-4 parts of sodium gluconate, 1-2 parts of polyoxyethylene hydrogenated castor oil, 0.05-0.1 part of methyl 4-hydroxybenzoate, 1-2 parts of hydroxyethyl urea, 0.1-0.2 part of carnosic acid, 3-5 parts of additive and 40-50 parts of water. The metal surface cleaning agent disclosed by the invention has the characteristics of low corrosion, low foam, low pollution and efficient decontamination, and the product is high in stability and long in quality guarantee period.
Description
Technical field
The present invention relates to metal treatment field, be specifically related to a kind of metal surface cleaning agent containing attapulgite and preparation method thereof.
Background technology
Metal and goods thereof often at the various dirt of surface contamination and impurity, as do not removed in time, can will affect the processing effect of next process, and then have influence on the overall performance of product in the course of processing.The Main Function of metal surface cleaning agent is exactly clean metal material surface oil, wax, rust, glue, paint, powder, carbon distribution, impression of the hand, sweat stain, cutting fluid and other dirt.Traditional metal surface cleaning agent is often solvent-borne type, and cost is high, toxicity is large, security is low and environmental pollution is large.Develop and apply environmental protection, safety, efficiently aqueous based surfactant shaped metal surface cleaning agent, becoming trend of the times.
Summary of the invention
The object of this invention is to provide a kind of metal surface cleaning agent containing attapulgite.
The present invention is achieved by the following technical solutions:
Containing a metal surface cleaning agent for attapulgite, it is characterized in that, it is obtained by the raw material of following weight parts:
Attapulgite 8-10, borneol 1-2, cocounut oil acyl diethanolamine 3-5, menthol 0.3-0.5, Sodium dodecylbenzene sulfonate 1-2, Sunmorl N 60S 2-4, polyoxyethylene hydrogenated castor oil 1-2, methyl p-hydroxybenzoate 0.05-0.1, hydroxyethyl urea 1-2, Salvin 0.1-0.2, auxiliary agent 3-5, water 40-50
Wherein auxiliary agent is made up of the raw material of following weight part:
Grape skin 15-20, oxalic acid 2-4, citric acid 2-4, tripoly phosphate sodium STPP 1-2, propylene glycol 3-5, polyoxyethylene nonylphenol ether 1-2, silica powder 1-2, water 20-30;
The preparation method of auxiliary agent is:
Stir after grape skin is mixed with the water that 1/3-1/2 measures, supersound process 0.5-1h, add oxalic acid, citric acid, tripoly phosphate sodium STPP and propylene glycol 200-400r/min, 60-80 DEG C of process 12-24h again, after filtration, filter residue is mixed with the water of surplus, add polyoxyethylene nonylphenol ether and silica powder 1000-1200r/min, 60-80 DEG C of process 6-8h, again filter and the filtrate that twice is obtained merging, pH is adjusted to neutrality, obtains final product.
Containing a preparation method for the metal surface cleaning agent of attapulgite, it is characterized in that, comprise the following steps:
(1) add in ethanol in proper amount by attapulgite, borneol, menthol and Salvin, 200-400r/min filters and drying after stirring 1-2h, crosses 200-300 mesh sieve, obtain component A after grinding evenly;
(2) cocounut oil acyl diethanolamine, Sodium dodecylbenzene sulfonate and hydroxyethyl urea are added to the water 800-1000r/min and stir 5-10min, stir 20-30min under adding methyl p-hydroxybenzoate and HCO60-80 DEG C, equally rotating speed again, obtain B component;
(3) first ultrasonic disperse 5-10min after component A, B component being mixed with all the other raw materials, then 400-600r/min stirs 15-30min, after packing and get final product.
Advantage of the present invention is:
1., by the improvement of recipe optimization, make metal surface cleaning agent have the feature of low corrosion, low foam, low stain and high-effective cleansing, and product stability is high, long quality-guarantee period;
2. being attached to the greasy dirt of metallic surface by adding attapulgite active adsorption, both shortening scavenging period, make again cleaning more thorough, contribute to the carrying out of next step treatment process; And when metal detergent discharge of wastewater by mode separating most pollutents such as centrifugal, filtrations, be conducive to alleviating sewage disposal burden, more easily reach emission standard.
Embodiment
Non-limiting examples of the present invention is as follows:
Containing a metal surface cleaning agent for attapulgite, be prepared from by the component raw material of following weight (kg):
Attapulgite 9, borneol 1.5, cocounut oil acyl diethanolamine 4, menthol 0.4, Sodium dodecylbenzene sulfonate 1.5, Sunmorl N 60S 3, polyoxyethylene hydrogenated castor oil 1.5, methyl p-hydroxybenzoate 0.08, hydroxyethyl urea 1.5, Salvin 0.15, auxiliary agent 4, water 45;
Wherein, auxiliary agent is made up of the raw material of following weight (kg):
Grape skin 18, oxalic acid 3, citric acid 3, tripoly phosphate sodium STPP 1.5, propylene glycol 4, polyoxyethylene nonylphenol ether 1.5, silica powder 1.5, water 25;
The preparation method of auxiliary agent:
Stir after grape skin is mixed with the water of 1/2 amount, supersound process 0.5h, add oxalic acid, citric acid, tripoly phosphate sodium STPP and propylene glycol 400r/min, 80 DEG C of process 24h again, after filtration, filter residue is mixed with the water of surplus, add polyoxyethylene nonylphenol ether and silica powder 1200r/min, 60 DEG C of process 8h, again filter and the filtrate that twice is obtained merging, pH is adjusted to neutrality, obtains final product.
Preparation method containing the metal surface cleaning agent of attapulgite comprises the following steps:
(1) add in ethanol in proper amount by attapulgite, borneol, menthol and Salvin, 400r/min filters and drying after stirring 2h, crosses 200 mesh sieves, obtain component A after grinding evenly;
(2) cocounut oil acyl diethanolamine, Sodium dodecylbenzene sulfonate and hydroxyethyl urea are added to the water 1000r/min and stir 5min, then stir 30min under adding methyl p-hydroxybenzoate and polyoxyethylene hydrogenated castor oil 80 DEG C, equally rotating speed, obtain B component;
(3) first ultrasonic disperse 5min after component A, B component being mixed with all the other raw materials, then 600r/min stirs 15min, after packing and get final product.
Through inspection, clean-out system cleaning rate >=95% of the present embodiment.
Claims (2)
1., containing a metal surface cleaning agent for attapulgite, it is characterized in that, it is obtained by the raw material of following weight parts:
Attapulgite 8-10, borneol 1-2, cocounut oil acyl diethanolamine 3-5, menthol 0.3-0.5, Sodium dodecylbenzene sulfonate 1-2, Sunmorl N 60S 2-4, polyoxyethylene hydrogenated castor oil 1-2, methyl p-hydroxybenzoate 0.05-0.1, hydroxyethyl urea 1-2, Salvin 0.1-0.2, auxiliary agent 3-5, water 40-50;
Described auxiliary agent is made up of the raw material of following weight part:
Grape skin 15-20, oxalic acid 2-4, citric acid 2-4, tripoly phosphate sodium STPP 1-2, propylene glycol 3-5, polyoxyethylene nonylphenol ether 1-2, silica powder 1-2, water 20-30;
The preparation method of described auxiliary agent is:
Stir after grape skin is mixed with the water that 1/3-1/2 measures, supersound process 0.5-1h, add oxalic acid, citric acid, tripoly phosphate sodium STPP and propylene glycol 200-400r/min, 60-80 DEG C of process 12-24h again, after filtration, filter residue is mixed with the water of surplus, add polyoxyethylene nonylphenol ether and silica powder 1000-1200r/min, 60-80 DEG C of process 6-8h, again filter and the filtrate that twice is obtained merging, pH is adjusted to neutrality, obtains final product.
2. the preparation method of a kind of metal surface cleaning agent containing attapulgite according to claim 1, is characterized in that, comprise the following steps:
(1) add in ethanol in proper amount by attapulgite, borneol, menthol and Salvin, 200-400r/min filters and drying after stirring 1-2h, crosses 200-300 mesh sieve, obtain component A after grinding evenly;
(2) cocounut oil acyl diethanolamine, Sodium dodecylbenzene sulfonate and hydroxyethyl urea are added to the water 800-1000r/min and stir 5-10min, stir 20-30min under adding methyl p-hydroxybenzoate and HCO60-80 DEG C, equally rotating speed again, obtain B component;
(3) first ultrasonic disperse 5-10min after component A, B component being mixed with all the other raw materials, then 400-600r/min stirs 15-30min, after packing and get final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410622240.5A CN104313616A (en) | 2014-11-07 | 2014-11-07 | Metal surface cleaning agent containing attapulgite and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410622240.5A CN104313616A (en) | 2014-11-07 | 2014-11-07 | Metal surface cleaning agent containing attapulgite and preparation method thereof |
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| CN104313616A true CN104313616A (en) | 2015-01-28 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201410622240.5A Pending CN104313616A (en) | 2014-11-07 | 2014-11-07 | Metal surface cleaning agent containing attapulgite and preparation method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104911617A (en) * | 2015-06-30 | 2015-09-16 | 杨高林 | Surface degreasant for machine part products |
| CN105651015A (en) * | 2016-03-04 | 2016-06-08 | 芜湖市金宇石化设备有限公司 | Drying process for spiral type workshop exhaust pipe |
| CN105839122A (en) * | 2016-03-30 | 2016-08-10 | 安徽青花坊瓷业股份有限公司 | Ceramic ware glaze preparation tank cleaning agent |
| CN107723715A (en) * | 2017-10-12 | 2018-02-23 | 三江县稻香山茶油生态发展有限公司 | A kind of tea seed powder rust remover and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102977730A (en) * | 2012-11-02 | 2013-03-20 | 铜陵市明诚铸造有限责任公司 | Metal antirust paint treating modified attapulgite as filler, and its preparation method |
| CN102993797A (en) * | 2012-10-15 | 2013-03-27 | 怀远县巨龙机械制造有限公司 | Alkali-proofing oil-proofing metal antirust paint and preparation method thereof |
-
2014
- 2014-11-07 CN CN201410622240.5A patent/CN104313616A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102993797A (en) * | 2012-10-15 | 2013-03-27 | 怀远县巨龙机械制造有限公司 | Alkali-proofing oil-proofing metal antirust paint and preparation method thereof |
| CN102977730A (en) * | 2012-11-02 | 2013-03-20 | 铜陵市明诚铸造有限责任公司 | Metal antirust paint treating modified attapulgite as filler, and its preparation method |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104911617A (en) * | 2015-06-30 | 2015-09-16 | 杨高林 | Surface degreasant for machine part products |
| CN105651015A (en) * | 2016-03-04 | 2016-06-08 | 芜湖市金宇石化设备有限公司 | Drying process for spiral type workshop exhaust pipe |
| CN105839122A (en) * | 2016-03-30 | 2016-08-10 | 安徽青花坊瓷业股份有限公司 | Ceramic ware glaze preparation tank cleaning agent |
| CN107723715A (en) * | 2017-10-12 | 2018-02-23 | 三江县稻香山茶油生态发展有限公司 | A kind of tea seed powder rust remover and preparation method thereof |
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Application publication date: 20150128 |