CN104313617A - Rust-removing metal surface cleaning agent and preparation method thereof - Google Patents

Rust-removing metal surface cleaning agent and preparation method thereof Download PDF

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Publication number
CN104313617A
CN104313617A CN201410622275.9A CN201410622275A CN104313617A CN 104313617 A CN104313617 A CN 104313617A CN 201410622275 A CN201410622275 A CN 201410622275A CN 104313617 A CN104313617 A CN 104313617A
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CN
China
Prior art keywords
parts
rust
metal surface
water
surface cleaning
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Application number
CN201410622275.9A
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Chinese (zh)
Inventor
姚侃
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HEFEI DAAN PRINTING Co Ltd
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HEFEI DAAN PRINTING Co Ltd
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Priority to CN201410622275.9A priority Critical patent/CN104313617A/en
Publication of CN104313617A publication Critical patent/CN104313617A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G1/00Cleaning or pickling metallic material with solutions or molten salts
    • C23G1/24Cleaning or pickling metallic material with solutions or molten salts with neutral solutions

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

The invention discloses a rust-removing metal surface cleaning agent. The rust-removing metal surface cleaning agent is characterized in that the rust-removing metal surface cleaning agent is prepared from the following raw materials in parts by weight: 4 to 8 parts of vermiculite powders, 2 to 4 parts of talcum powders, 1 to 2 parts of sodium Lauroamphoacetate, 2 to 4 parts of hydroxyethyl cellulose, 2 to 4 parts of triethanolamine oleate, 1 to 2 parts of rosin-polythylene oxide ester, 2 to 4 parts of sodium thiosulfate, 2 to 4 parts of triethanolamine, 1 to 2 parts of barium petroleum sulfonate, 0.5 to 1 part of ethylene glycol monostearate, 3 to 5 parts of an additive, and 40 to 50 parts of water. The metal surface cleaning agent provided by the invention has the functions of removing rust and cleaning away oil stains and impurities, achieves remarkable cleaning and rust-removing effects, can save resources and simplify processing steps, and is highly practical.

Description

A kind of rust cleaning metal surface cleaning agent and preparation method thereof
Technical field
The present invention relates to metal treatment field, be specifically related to a kind of rust cleaning metal surface cleaning agent and preparation method thereof.
Background technology
Metal and goods thereof often at the various dirt of surface contamination and impurity, as do not removed in time, can will affect the processing effect of next process, and then have influence on the overall performance of product in the course of processing.The Main Function of metal surface cleaning agent is exactly clean metal material surface oil, wax, rust, glue, paint, powder, carbon distribution, impression of the hand, sweat stain, cutting fluid and other dirt.Traditional metal surface cleaning agent is often solvent-borne type, and cost is high, toxicity is large, security is low and environmental pollution is large.Develop and apply environmental protection, safety, efficiently aqueous based surfactant shaped metal surface cleaning agent, becoming trend of the times.
Summary of the invention
The object of this invention is to provide a kind of rust cleaning metal surface cleaning agent.
The present invention is achieved by the following technical solutions:
A kind of rust cleaning metal surface cleaning agent, it is characterized in that, it is obtained by the raw material of following weight parts:
Vermiculite power 4-8, talcum powder 2-4, lauryl both sexes sodium-acetate 1-2, Natvosol 2-4, triethanolamine oleate 2-4, polyoxylethylene abietate 1-2, Sulfothiorine 2-4, trolamine 2-4, barium mahogany sulfonate 1-2, ethylene glycol monostearate 0.5-1, auxiliary agent 3-5, water 40-50;
Wherein auxiliary agent is made up of the raw material of following weight part:
Grape skin 15-20, oxalic acid 2-4, citric acid 2-4, tripoly phosphate sodium STPP 1-2, propylene glycol 3-5, polyoxyethylene nonylphenol ether 1-2, silica powder 1-2, water 20-30;
The preparation method of auxiliary agent is:
Stir after grape skin is mixed with the water that 1/3-1/2 measures, supersound process 0.5-1h, add oxalic acid, citric acid, tripoly phosphate sodium STPP and propylene glycol 200-400r/min, 60-80 DEG C of process 12-24h again, after filtration, filter residue is mixed with the water of surplus, add polyoxyethylene nonylphenol ether and silica powder 1000-1200r/min, 60-80 DEG C of process 6-8h, again filter and the filtrate that twice is obtained merging, pH is adjusted to neutrality, obtains final product.
Eliminate rust the preparation method of metal surface cleaning agent, it is characterized in that, comprise the following steps:
(1) trolamine and vermiculite power, talcum powder are ground 1-2h after mixing, then add the water of lauryl both sexes sodium-acetate and 1/4-1/3 amount, first ultrasonic disperse 10-15min, then 8000-10000r/min high-speed homogenization 15-30min, obtain component A;
(2) triethanolamine oleate, polyoxylethylene abietate and Natvosol are added 800-1000r/min in the water of surplus and stir 5-10min, stir 20-30min under adding barium mahogany sulfonate and ethylene glycol monostearate 60-80 DEG C, equally rotating speed again, obtain B component;
(3) 800-1000r/min after the mixing of component A, B component and all the other raw materials is stirred 15-30min, after packing and get final product.
Advantage of the present invention is:
1., by the improvement of recipe optimization, make product have antirust and cleaning greasy dirt, impurity function concurrently, cleaning and favorable rust preventing effect, economize on resources, simplify processes step, is conducive to the carrying out of next step operation;
2. being attached to the greasy dirt of metallic surface by adding vermiculite power energy active adsorption, both shortening scavenging period, and making again cleaning more thorough; And when metal detergent discharge of wastewater by mode separating most pollutents such as centrifugal, filtrations, be conducive to alleviating sewage disposal burden, more easily reach emission standard.
Embodiment
Non-limiting examples of the present invention is as follows:
A kind of rust cleaning metal surface cleaning agent, is prepared from by the component raw material of following weight (kg):
Vermiculite power 6, talcum powder 3, lauryl both sexes sodium-acetate 1.5, Natvosol 3, triethanolamine oleate 3, polyoxylethylene abietate 1.5, Sulfothiorine 3, trolamine 3, barium mahogany sulfonate 1.5, ethylene glycol monostearate 0.8, auxiliary agent 4, water 45;
Wherein, auxiliary agent is made up of the raw material of following weight (kg):
Grape skin 18, oxalic acid 3, citric acid 3, tripoly phosphate sodium STPP 1.5, propylene glycol 4, polyoxyethylene nonylphenol ether 1.5, silica powder 1.5, water 25;
The preparation method of auxiliary agent:
Stir after grape skin is mixed with the water of 1/2 amount, supersound process 0.5h, add oxalic acid, citric acid, tripoly phosphate sodium STPP and propylene glycol 400r/min, 80 DEG C of process 24h again, after filtration, filter residue is mixed with the water of surplus, add polyoxyethylene nonylphenol ether and silica powder 1200r/min, 60 DEG C of process 8h, again filter and the filtrate that twice is obtained merging, pH is adjusted to neutrality, obtains final product.
The preparation method of rust cleaning metal surface cleaning agent comprises the following steps:
(1) trolamine and vermiculite power, talcum powder are ground 1h after mixing, then add the water of lauryl both sexes sodium-acetate and 1/4 amount, first ultrasonic disperse 15min, then 8000r/min high-speed homogenization 30min, obtain component A;
(2) triethanolamine oleate, polyoxylethylene abietate and Natvosol are added 1000r/min in the water of surplus and stir 5min, then stir 30min under adding barium mahogany sulfonate and ethylene glycol monostearate 80 DEG C, equally rotating speed, obtain B component;
(3) 1000r/min after the mixing of component A, B component and all the other raw materials is stirred 15min, after packing and get final product.
Through inspection, clean-out system cleaning rate >=95% of the present embodiment.

Claims (2)

1. eliminate rust a metal surface cleaning agent, and it is characterized in that, it is obtained by the raw material of following weight parts:
Vermiculite power 4-8, talcum powder 2-4, lauryl both sexes sodium-acetate 1-2, Natvosol 2-4, triethanolamine oleate 2-4, polyoxylethylene abietate 1-2, Sulfothiorine 2-4, trolamine 2-4, barium mahogany sulfonate 1-2, ethylene glycol monostearate 0.5-1, auxiliary agent 3-5, water 40-50;
Described auxiliary agent is made up of the raw material of following weight part:
Grape skin 15-20, oxalic acid 2-4, citric acid 2-4, tripoly phosphate sodium STPP 1-2, propylene glycol 3-5, polyoxyethylene nonylphenol ether 1-2, silica powder 1-2, water 20-30;
The preparation method of described auxiliary agent is:
Stir after grape skin is mixed with the water that 1/3-1/2 measures, supersound process 0.5-1h, add oxalic acid, citric acid, tripoly phosphate sodium STPP and propylene glycol 200-400r/min, 60-80 DEG C of process 12-24h again, after filtration, filter residue is mixed with the water of surplus, add polyoxyethylene nonylphenol ether and silica powder 1000-1200r/min, 60-80 DEG C of process 6-8h, again filter and the filtrate that twice is obtained merging, pH is adjusted to neutrality, obtains final product.
2. the preparation method of a kind of metal surface cleaning agent that eliminates rust according to claim 1, is characterized in that, comprise the following steps:
(1) trolamine and vermiculite power, talcum powder are ground 1-2h after mixing, then add the water of lauryl both sexes sodium-acetate and 1/4-1/3 amount, first ultrasonic disperse 10-15min, then 8000-10000r/min high-speed homogenization 15-30min, obtain component A;
(2) triethanolamine oleate, polyoxylethylene abietate and Natvosol are added 800-1000r/min in the water of surplus and stir 5-10min, stir 20-30min under adding barium mahogany sulfonate and ethylene glycol monostearate 60-80 DEG C, equally rotating speed again, obtain B component;
(3) 800-1000r/min after the mixing of component A, B component and all the other raw materials is stirred 15-30min, after packing and get final product.
CN201410622275.9A 2014-11-07 2014-11-07 Rust-removing metal surface cleaning agent and preparation method thereof Pending CN104313617A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410622275.9A CN104313617A (en) 2014-11-07 2014-11-07 Rust-removing metal surface cleaning agent and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410622275.9A CN104313617A (en) 2014-11-07 2014-11-07 Rust-removing metal surface cleaning agent and preparation method thereof

Publications (1)

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CN104313617A true CN104313617A (en) 2015-01-28

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105018238A (en) * 2015-06-30 2015-11-04 安徽德诺化工有限公司 Cleaning liquid for sapphire substrate wafer
CN106591855A (en) * 2016-11-25 2017-04-26 南宁市黑晶信息技术有限公司 Metal surface cleaning agent and preparation method thereof
CN107653099A (en) * 2017-11-05 2018-02-02 包红珠 A kind of surface cleaning agent of pneumatic spherical Adjustable air port and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1050559A (en) * 1989-09-30 1991-04-10 中国科学院地质研究所 Household utensil detergent and method for making thereof
CN101268997A (en) * 2008-01-14 2008-09-24 尹吉山 Complexing form wash and bath liquid of natural mineral matter and micro-element, and preparation method
CN104119716A (en) * 2014-06-26 2014-10-29 安徽快来防水防腐有限公司 Self-cleaning waterproof coating

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1050559A (en) * 1989-09-30 1991-04-10 中国科学院地质研究所 Household utensil detergent and method for making thereof
CN101268997A (en) * 2008-01-14 2008-09-24 尹吉山 Complexing form wash and bath liquid of natural mineral matter and micro-element, and preparation method
CN104119716A (en) * 2014-06-26 2014-10-29 安徽快来防水防腐有限公司 Self-cleaning waterproof coating

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105018238A (en) * 2015-06-30 2015-11-04 安徽德诺化工有限公司 Cleaning liquid for sapphire substrate wafer
CN106591855A (en) * 2016-11-25 2017-04-26 南宁市黑晶信息技术有限公司 Metal surface cleaning agent and preparation method thereof
CN107653099A (en) * 2017-11-05 2018-02-02 包红珠 A kind of surface cleaning agent of pneumatic spherical Adjustable air port and preparation method thereof

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Application publication date: 20150128

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