CN1050559A - Household utensil detergent and method for making thereof - Google Patents
Household utensil detergent and method for making thereof Download PDFInfo
- Publication number
- CN1050559A CN1050559A CN 89107292 CN89107292A CN1050559A CN 1050559 A CN1050559 A CN 1050559A CN 89107292 CN89107292 CN 89107292 CN 89107292 A CN89107292 A CN 89107292A CN 1050559 A CN1050559 A CN 1050559A
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- clay
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- synthetic detergent
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3947—Liquid compositions
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- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
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- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
With the neutrality-weakly alkaline synthetic detergent of the silicate that contains basic metal, alkaline-earth metal of clay multiviscosisty (pasteization) and hydrocarbonate etc., performance is stable especially, antithixotropy, there are not wearing and tearing, corroding metal and people's skin not, and have disinfection, free from environmental pollution.This washing composition can be used for cleaning tableware, tea set and other vessel of various metals, pottery and the glass etc. that speckle with the greasy dirt dirt, the clean light of vessel surface treated and that cleaned.
Description
The present invention relates to synthetic detergent and preparation method thereof.
In recent years, along with the raising of people's living standard, the synthetic detergent consumption is quite big, but wherein uses organic substance to be main component mostly, also have use clay and other inorganic substance (as United States Patent(USP) Nos. 3843548; 3558496; 3684722; 4005027 and 4116849 etc.), general alkalescence is bigger, and the product that wherein has (as PH=9～13 of above-mentioned United States Patent(USP) Nos. 4116894 products) is overbasic, during use, people's skin is still had certain influence.As is generally known various household utensils are by metal as tableware, tea set and other household utensils mostly, especially use aluminium and pottery, glass and plastics etc. to make.If handle with abrasive material, then vessel surface is easily frayed, and metal products is subject to the erosion of alkali, and some organic synthesis material is also unfavorable to people's health.
In view of the foregoing, the objective of the invention is to, a kind of neutrality-weakly alkaline based on inorganic components (PH7～9) paste household utensil detergent is provided, and it is a kind ofly not have wearing and tearing, do not have burn into and have the nonthixotropic synthetic detergent of certain disinfection.
The essentially consist of synthetic detergent of the present invention has clay, basic metal and alkaline-earth metal salt, comprising alkali-metal vitriol or carbonate, nitrate, phosphoric acid salt, thiosulphate, sulfide, sulphite, oxalate, borate, oxyhydroxide, basic metal (sodium, potassium, lithium) supercarbonate (hydrocarbonate), or hydrosulfate, hydrosulphite, hydrophosphate, or boric acid, sulfuric acid, sodium, potassium, the perborate of lithium, alkali-metal silicate and alkali-metal tri-polyphosphate, the tricresyl phosphate sodium salt, with alkali-metal Oleum Cocois dodecyl sulfate or tallow dodecyl sulfate.
The vitriol of the inorganic washing agent that synthetic detergent of the present invention contained (sodium, potassium, lithium), or the content of alkali-metal thiosulphate, sulfide, nitrate, phosphoric acid salt, oxalate and oxyhydroxide generally can be per-cent used among 0.5～25%(the present invention and all is weight percentage, be preferably 2～5% down together).The amount of vitriol, thiosulphate or the sulfide that adds can not be too many, otherwise after using, be difficult for water and rinse well.The inorganic washing agent of other that contain is alkali-metal hydrocarbonate or hydrosulfate, boric acid, sulfuric acid, hydrosulphite and hydrophosphate, and content is 0.1～20%, is preferably 1～10%.Add this kind washing agent, be because their character is different with other washing agents, after in water, dissolving, increase the hydrogen ion in the synthetics, thereby both increased detergent power, can reduce the pH value of synthetics again, various salt components are adjusted reach plait point, make product become nonthixotropic stable product, and it is neutral to weakly alkaline that high alkalinity is become, pH value is between 7～9.Its advantage is the stability that has increased synthetics, and protects human body skin to be without prejudice better.
In the synthetic detergent of the present invention, contain the natural clay mineral (clay mineral of synthetic also can) of larger amt, as viscosifying agent and sanitas, simultaneously, clay also has soil removability and protection people's skin effect.Employed clay viscosifying agent comprises kaolin families, smectite class, sepiolite-polygorskite class, vermiculite class clay and zeolite minerals and their mixture, and wherein strong dilatancy can and adsorb the cationic montmorillonite of metal (being wilkinite), nontronite, saponite, vermiculite, sepiolite, palygorskite clay etc. for best to have very.The particle diameter of clay should be less than 200 orders, and preferably less than 300 orders, clay content is 10-40%, is preferably 20～30%.Use the viscosifying agent and the sanitas clay of more content, in order to forming stable paste better.Because clays such as smectite class have very strong expansion character when combining with water, thus in the process of making paste synthesising detergent, must make above-mentioned swelling clay through expanded fully, and fully stirring makes the product uniform and smooth.
The perborate that contains alkali metallic sodium, potassium, lithium in the synthetic detergent of the present invention as a kind of tensio-active agent, increases the soil removability of synthetics.Simultaneously, this kind component has bleaching action and disinfection ability again, can improve the performance of synthetics, makes its soft exquisiteness, and puffing is good, and is more stable, and consumption is 0.1-10%, is preferably 0.5-5%.In addition, also contain a kind of tensio-active agent, i.e. the Oleum Cocois dodecyl sulfate or the tallow dodecyl sulfate of basic metal (sodium, potassium, lithium).This component is effective especially to the removal animality greasy dirt that improves final product, and when cleaning vessel with this synthetics is manual, can prevent that greasy dirt is stained with on hand, and consumption is 0.1-5%, is preferably 0.5-2%.Except that above-mentioned two kinds, also contain alkali-metal silicate, also be a kind of tensio-active agent, it can strengthen soil removability, and consumption is 0.1-25%, is preferably 1-5%.This type of alkalimetal silicate can be selected silica gel, colloid silica and water glass etc. for use.Add this component in the synthetics, can increase the alkalescence of synthetics, improved pH value.In order to make final product reach neutral to weakly alkaline, the consumption of alkalimetal silicate what, match with the quantity of hydrocarbonate in adding synthetics, hydrosulfate, hydrophosphate etc.
Contain alkali-metal tri-polyphosphate and tricresyl phosphate sodium salt in the synthetic detergent of the present invention, as the decontamination toughener.Two kinds of phosphoric acid salt can be used, and the content ratio is 1: 1, and both total content is 0.5-20%, is preferably 5-10%.Adding this kind phosphoric acid salt can not make and contain free phosphorus and ion in the final product.
Synthetic detergent of the present invention is the hydration paste, so wherein contain the water of 40-60%.
In the synthetic detergent of the present invention, to replace perborate, also can form the thixotropic synthetics, handle, have similar washing usefulness through aforesaid method as the hypochlorite of the alkali metal containing that adds equal amts or hypobromite.
The characteristics of synthetic detergent of the present invention are compared with currently available products, mainly are: 1) material combination is different with proportioning; 2) contain the neutralized high alkalinity of other alkali metal salt of hydrogen salt and reach a neutral weakly alkaline owing to having adopted, its PH=7～9, safer to people's skin, and existing like product is high alkalinity mostly; 3) bleaching/sterilizing agent of adopting of this washing composition is a perborate, is different from currently available products with discharging the muriate of chlorion and the synthetics of hypochlorite, thereby this washing composition is antithixotropy, and the product proterties is more stable; 4) in this washing composition except that a small amount of additive is organism, 95-99% is the inorganic chemistry material, is different from the washing composition that contains large amount of organic.
Synthetic detergent preparation condition of the present invention and method are as follows: 1) under room temperature and condition of normal pressure, that the expanded back of a certain proportion of clay water in container is standby; 2) expanded clay is placed agitator or stirrer, the alkali metal perborate that adds suitable proportion stirs, and makes it to be adsorbed by clay; 3) tri-polyphosphate and the tricresyl phosphate sodium salt (the two was in 1: 1 ratio) of required ratio is soluble in water, and with in this solution adding said mixture; 4), and add alkali-metal Oleum Cocois dodecyl sulfate or salt, alkali-metal supercarbonate or same composition such as tallow dodecyl sulfate, alkali-metal vitriol or carbonate successively by required per-cent in room temperature or be heated under 40-50 ℃ the situation and constantly stir; 5) add the alkali-metal silicate of required ratio at last, and stir the paste that is uniform and smooth up to mixture.Further specify the present invention below in conjunction with embodiment.
Embodiment one
Under normal temperature and normal pressure, it is expanded that 20% wilkinite is put into the container water, then expanded wilkinite placed agitator or stirrer, and the basic metal Sodium peroxoborate of adding 1% stirs, and makes it to be adsorbed by wilkinite.3.5% basic metal tripoly phosphate sodium STPP and tertiary sodium phosphate is soluble in water, and in the mixture that this solution adding is above-mentioned, in room temperature or be heated under 40-50 ℃ the condition and constantly stir, add 0.5% Oleum Cocois sodium lauryl sulphate, 3% alkali metal sulphuric acid sodium, 8% sodium bicarbonate successively.Add 4% alkali metal silicate sodium at last, and stir the paste that is uniform and smooth until mixture.
Embodiment two
Under normal temperature and normal pressure, it is expanded that 30% wilkinite is put into the container water, then expanded wilkinite placed agitator or stirrer, adds 2% basic metal Sodium peroxoborate and stir, and makes it to be adsorbed by wilkinite.4% basic metal tripoly phosphate sodium STPP and tertiary sodium phosphate is soluble in water, and with in this solution adding said mixture, in room temperature or be heated under 40-50 ℃ the condition and constantly stir, add 0.8% Oleum Cocois sodium lauryl sulphate, 5% yellow soda ash, 7% sodium bicarbonate successively.Add 3% alkali metal silicate sodium at last, and stir the paste that is uniform and smooth until mixture.
Embodiment three
Under normal temperature and normal pressure, it is expanded that 25% wilkinite is put into molten device water, then expanded wilkinite placed agitator or stirrer, adds 3% basic metal Sodium peroxoborate and stir, and makes it to be adsorbed by wilkinite.5% basic metal tripoly phosphate sodium STPP and tertiary sodium phosphate is soluble in water, and this solution added in said mixture, under the condition of 40-50% ℃ of room temperature or heating, constantly stir, add 1% Oleum Cocois sodium lauryl sulphate, 4% salt of wormwood, 6% sodium bicarbonate successively.Add 2.5% alkali metal silicate sodium at last, and stir the paste that is uniform and smooth until mixture.
In addition to the implementation, the present invention also can form other prescriptions, and makes the synthetic detergent with identical function under corresponding preparation condition.
Synthetic detergent of the present invention can be used for cleaning the vessel that speckle with dirt, and its manual purging method is, a little is applied in the vessel surface that speckles with dirt with this detergent paste earlier, and water cleans up then; Its machinery cleans (as clean tableware etc. with dishwashers) method, earlier this paste is diluted with water to the 30-50 liquid doubly of paste weight, will speckle with the smeary vessel and be put in this liquid and soaked 1-2 minute, uses the aqueous cleaner ware then.Treated and cleaned vessel surface bright and clean.
Claims (9)
1, a kind ofly clean the paste synthesising detergent that household utensil is used, it is characterized in that neutrality one weakly alkaline synthetic detergent based on inorganic components is by clay, alkali-metal vitriol or carbonate, nitrate, phosphoric acid salt, thiosulphate, sulfide, sulphite, oxalate, borate, oxyhydroxide, basic metal (sodium, potassium, lithium) supercarbonate (hydrocarbonate), or hydrosulfate, hydrosulphite, hydrophosphate or boric acid, sulfuric acid, sodium, potassium, the perborate of lithium, alkali-metal silicate, alkali-metal tri-polyphosphate, the tricresyl phosphate sodium salt, alkali-metal Oleum Cocois dodecyl sulfate or tallow dodecyl sulfate and water are formed.
2, synthetic detergent as claimed in claim 1, it is characterized in that clay is meant smectite class, sepiolite-polygorskite class, kaolinite class, vermiculite class clay and zeolite minerals and their mixture, be preferably montmorillonite (being wilkinite), nontronite, saponite, vermiculite, sepiolite-palygorskite clay with high absorption property, the clay of can therefrom choosing any one kind of them, the clay particle diameter is less than 200 orders, preferably less than 300 orders, clay content is 10-40%, and optimum content is 20-30%.
3, synthetic detergent as claimed in claim 1, it is characterized in that alkali-metal vitriol or carbonate, nitrate, phosphoric acid salt, thiosulphate, sulfide, sulphite, oxalate, borate, oxyhydroxide content are respectively 0.5-25%, optimum content is 2-5%.
4, synthetic detergent as claimed in claim 1, the supercarbonate (hydrocarbonate) that it is characterized in that basic metal (sodium, potassium, lithium), or hydrosulfate, hydrosulphite, hydrophosphate or boric acid, vitriolic content is respectively 0.1-20%, and optimum content is 1-10%.
5, synthetic detergent as claimed in claim 1 is characterized in that the content of the perborate of sodium, potassium, lithium is respectively 0.1-10%, and optimum content is 0.5-5%.
6, synthetic detergent as claimed in claim 1, the content that it is characterized in that alkalimetal silicate is 0.1-25%, optimum content is 1-5%.
7, synthetic detergent as claimed in claim 1, the content that it is characterized in that alkali-metal Oleum Cocois dodecyl sulfate or tallow dodecyl sulfate is 0.1-5%, optimum content is 0.5-2%.
8, synthetic detergent as claimed in claim 1, the content that it is characterized in that alkali-metal tri-polyphosphate and tricresyl phosphate sodium salt is 0.5-20%, and optimum content is 5-10%, and the two ratio is used at 1: 1 simultaneously.
9, a kind of method for making for preparing the described synthetic detergent of claim 1, it is characterized in that, it is expanded under room temperature and condition of normal pressure the 10-40% clay to be put into the container water, expanded clay is placed agitator or stirrer, adding the 0.1-10% perborate stirs, make it to be adsorbed by clay, then that tri-polyphosphate and the tricresyl phosphate sodium salt (the two was in 1: 1 ratio) of 0.5-20% is soluble in water, this solution is added in the said mixture, in room temperature or be heated under 40-50 ℃ the situation and constantly stir, the Oleum Cocois dodecyl sulfate or the tallow dodecyl sulfate that add 0.1-5%, 0.5-25% vitriol, the 0.1-20% supercarbonate, add 0.1-25% silicate at last, be stirred to evenly, obtain fine and smooth paste neutrality-weakly alkaline synthetic detergent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 89107292 CN1050559A (en) | 1989-09-30 | 1989-09-30 | Household utensil detergent and method for making thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 89107292 CN1050559A (en) | 1989-09-30 | 1989-09-30 | Household utensil detergent and method for making thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1050559A true CN1050559A (en) | 1991-04-10 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 89107292 Pending CN1050559A (en) | 1989-09-30 | 1989-09-30 | Household utensil detergent and method for making thereof |
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| CN (1) | CN1050559A (en) |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7135446B1 (en) * | 2002-01-28 | 2006-11-14 | Diamondite, L.L.C. | System for cleaning and protecting windshields |
| US7282100B1 (en) * | 2002-01-28 | 2007-10-16 | Palm Beach Motoring Access Inc | Method of cleaning automobile painted surfaces and automobile glass surfaces |
| CN100519720C (en) * | 2007-02-06 | 2009-07-29 | 陕西科技大学 | Process for manufacturing tea set cleaning agent |
| CN104313617A (en) * | 2014-11-07 | 2015-01-28 | 合肥大安印刷有限责任公司 | Rust-removing metal surface cleaning agent and preparation method thereof |
| CN105969559A (en) * | 2016-06-23 | 2016-09-28 | 巢湖鹏远金属焊管有限公司 | Cleaning agent of automobile exhaust pipe |
| CN106590992A (en) * | 2016-11-03 | 2017-04-26 | 铜陵桂生生态养殖有限公司 | Bait dish washing liquid for centipede breeding |
| CN106978268A (en) * | 2017-04-22 | 2017-07-25 | 河南工业大学 | A kind of tea stain detergent |
| CN107012021A (en) * | 2017-04-26 | 2017-08-04 | 岑健 | A kind of solid glass cleaning agent and preparation method thereof |
| CN107287049A (en) * | 2017-06-30 | 2017-10-24 | 合肥利裕泰玻璃制品有限公司 | A kind of glass cleaner and preparation method thereof |
| CN108277095A (en) * | 2017-12-30 | 2018-07-13 | 安徽杜氏高科玻璃有限公司 | A kind of cleaning treatment technique of glass |
| CN109136965A (en) * | 2018-08-29 | 2019-01-04 | 衢州科创信息技术咨询有限公司 | A kind of bearing oil-removing cleaning agent and preparation method |
| CN110964610A (en) * | 2019-12-19 | 2020-04-07 | 芜湖航天特种电缆厂股份有限公司 | Cable surface treatment method |
-
1989
- 1989-09-30 CN CN 89107292 patent/CN1050559A/en active Pending
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7135446B1 (en) * | 2002-01-28 | 2006-11-14 | Diamondite, L.L.C. | System for cleaning and protecting windshields |
| US7282100B1 (en) * | 2002-01-28 | 2007-10-16 | Palm Beach Motoring Access Inc | Method of cleaning automobile painted surfaces and automobile glass surfaces |
| CN100519720C (en) * | 2007-02-06 | 2009-07-29 | 陕西科技大学 | Process for manufacturing tea set cleaning agent |
| CN104313617A (en) * | 2014-11-07 | 2015-01-28 | 合肥大安印刷有限责任公司 | Rust-removing metal surface cleaning agent and preparation method thereof |
| CN105969559A (en) * | 2016-06-23 | 2016-09-28 | 巢湖鹏远金属焊管有限公司 | Cleaning agent of automobile exhaust pipe |
| CN106590992A (en) * | 2016-11-03 | 2017-04-26 | 铜陵桂生生态养殖有限公司 | Bait dish washing liquid for centipede breeding |
| CN106978268A (en) * | 2017-04-22 | 2017-07-25 | 河南工业大学 | A kind of tea stain detergent |
| CN107012021A (en) * | 2017-04-26 | 2017-08-04 | 岑健 | A kind of solid glass cleaning agent and preparation method thereof |
| CN107287049A (en) * | 2017-06-30 | 2017-10-24 | 合肥利裕泰玻璃制品有限公司 | A kind of glass cleaner and preparation method thereof |
| CN108277095A (en) * | 2017-12-30 | 2018-07-13 | 安徽杜氏高科玻璃有限公司 | A kind of cleaning treatment technique of glass |
| CN109136965A (en) * | 2018-08-29 | 2019-01-04 | 衢州科创信息技术咨询有限公司 | A kind of bearing oil-removing cleaning agent and preparation method |
| CN110964610A (en) * | 2019-12-19 | 2020-04-07 | 芜湖航天特种电缆厂股份有限公司 | Cable surface treatment method |
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