CN107012021A - A kind of solid glass cleaning agent and preparation method thereof - Google Patents
A kind of solid glass cleaning agent and preparation method thereof Download PDFInfo
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- CN107012021A CN107012021A CN201710282891.8A CN201710282891A CN107012021A CN 107012021 A CN107012021 A CN 107012021A CN 201710282891 A CN201710282891 A CN 201710282891A CN 107012021 A CN107012021 A CN 107012021A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/044—Hydroxides or bases
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/06—Phosphates, including polyphosphates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/1253—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
- C11D3/1266—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite in liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/128—Aluminium silicates, e.g. zeolites
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
- C11D3/2013—Monohydric alcohols linear fatty or with at least 8 carbon atoms in the alkyl chain
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2065—Polyhydric alcohols
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2079—Monocarboxylic acids-salts thereof
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
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Abstract
The present invention provides a kind of solid glass cleaning agent and preparation method thereof, it is related to cleaning agent technical field, the solid glass cleaning agent is made up of Cocoamidopropyl betaine, D-sorbite, sodium benzoate, cocoanut fatty acid diethanolamide, sodium sulphate, tetradecyl alchohol, calcium silicates, salt, sodium tripolyphosphate, ethanol, zeolite powder, mica powder, cleaning solution and water.The solid glass cleaning agent of the present invention, in the absence of any peculiar smell, to human body without any harm, the surface of cleaning thing needed for being applied directly to when in use, plus a small amount of water or do not add water, directly being wiped with foam or rag can allow glass light as before, save a large amount of man power and materials, and in certain time after the cleaning, glass will not adsorption of dust again, its small volume in addition, lightweight and cost of transportation is low, no matter under normal temperature or low temperature, in the absence of any impurity and muddiness.
Description
【Technical field】
The present invention relates to cleaning agent technical field, and in particular to a kind of solid glass cleaning agent and preparation method thereof.
【Background technology】
At present, for the crusts such as metal, ceramics, plank, glass, fiberboard, slabstone, glass carry out cleaning decontamination be with
Based on various cleaning sprays, its active ingredient is that the various surfactants of chemical industry synthesis and the configuration of all kinds of auxiliary chemicals are formed
's.The waste water produced in the production and use process is rich in various surfactants, can be to environmental danger, i.e. variousization
Material is learned in user's skin residual packing, the health of user is endangered.Simultaneously after use, it is necessary to be cleaned multiple times with water, wave
Water wasting and time, pollution environment and water source.
Present people increasingly recognize harm of the chemical substance to environment, advocate the life and consumption of low-carbon；Social water money
Source scarcity is, it is necessary to using water wisely；The allegro life style of people is, it is necessary to save the time.Need one kind being capable of safety non-toxic, day
Right health, high-effective cleansing, cleaning agent with low cost, easy to use.Traditional cleaning agent is liquid solution, it is therefore desirable to such as may be used
The plastic bottles such as pleasure, mineral water are contained as container, and this brings great inconvenience to Product transport and sale.
In view of problem above, prepare that a kind of dirt-removing power is strong, cleaning efficiency is high, uses manpower and material resources sparingly, to human body and right
The hard surface cleaner of environment fanout free region is extremely urgent.
【The content of the invention】
In view of this, it is of the invention it is an object of the invention to provide a kind of solid glass cleaning agent and preparation method thereof
Solid glass cleaning agent, in the absence of any peculiar smell, to human body without any harm, needed for being applied directly to when in use
Clean the surface of thing, plus a small amount of water or do not add water, directly being wiped with foam or rag can allow glass light as before, save big
Measure in man power and material, and certain time after the cleaning, glass will not adsorption of dust again, its small volume in addition, it is lightweight and
Cost of transportation is low, no matter under normal temperature or low temperature, in the absence of any impurity and muddiness.
In order to solve the above-mentioned technical problem, present invention employs following technical scheme：
A kind of solid glass cleaning agent, the solid glass cleaning agent is made up of the raw material of following parts by weight：Coconut oleoyl amine
12-18 parts of CAB, 6-12 parts of D-sorbite, 4-8 parts of sodium benzoate, 4-8 parts of cocoanut fatty acid diethanolamide, sulphur
Sour sodium 5-10 parts, 4-8 parts of tetradecyl alchohol, 5-9 parts of calcium silicates, 1-5 parts of salt, 3-5 parts of sodium tripolyphosphate, 5-10 parts of ethanol, zeolite
15-20 parts of 6-12 parts of powder, 3-8 parts of mica powder, 10-20 parts of cleaning solution and water；
The cleaning solution is made up of the raw material of following parts by weight：12-18 parts of butter fruit, 10-15 parts of glycerine, Chinese honey locust oil 15-
20-28 parts of 22 parts, 5-10 parts of sodium hydroxide and water.
In the present invention, further, the solid glass cleaning agent is made up of the raw material of following parts by weight：Coconut oleoyl amine third
15 parts of base glycine betaine, 9 parts of D-sorbite, 6 parts of sodium benzoate, 6 parts of cocoanut fatty acid diethanolamide, 7 parts of sodium sulphate, 14
6 parts of alcohol, 7 parts of calcium silicates, 3 parts of salt, 4 parts of sodium tripolyphosphate, 7 parts of ethanol, 9 parts of zeolite powder, 6 parts of mica powder, 15 parts of cleaning solution
With 17 parts of water；
The cleaning solution is made up of the raw material of following parts by weight：15 parts of butter fruit, 12 parts of glycerine, Chinese honey locust oily 18 parts, hydrogen-oxygen
Change 24 parts of 7 parts of sodium and water.
In the present invention, further, the cleaning solution is obtained by the following method：
A. butter fruit 12-18 parts by weight, glycerine 10-15 parts by weight and Chinese honey locust oil 15-22 parts by weight are weighed, appearance is put into together
Heated in device, be sufficiently stirred for mixing, and keeping temperature is 40-48 DEG C, obtains miscella standby；
B. take the water of the 20-28 parts by weight to be placed in container, the sodium hydroxide of 5-10 parts by weight is added to the water, simultaneously
Quickly stirred with alkaline-resisting agitator, aqueous slkali is obtained after reaction standby；
C. aqueous slkali is poured into the container equipped with miscella, while quickly being stirred with alkaline-resisting agitator, until container
Interior mixture surface can mark 8 complete words, you can the cleaning solution is made.
In the present invention, further, the zeolite powder is modified zeolite powder, the modified zeolite powder be using inorganic base and
The method that sodium chloride carries out solution infusion method modification to zeolite powder as improved chemical is made.
In the present invention, further, the specific preparation method of the modified zeolite powder is as follows：
1. pre-process：Natural zeolite powder is taken, is rinsed for several times with water, removes soluble impurity, dried at 90-110 DEG C
3.5-5.5 hour；
2. modification：According to zeolite powder：Sodium chloride=1：1 mass ratio, by above-mentioned pretreated natural boiling powder and
Sodium chloride is mixed and is put into alkaline-resisting reactor, then the addition 1.0mol/L sodium hydroxide solutions into reactor so that hydroxide
Sodium solution just submerges natural zeolite powder and sodium chloride, and immersion rinsed zeolite powder to neutrality, Ran Houjin after 24-32 hours with water
Row ultrasonic disperse, then dried 3-6 hours under the conditions of 95-110 DEG C.
The present invention also provides a kind of preparation method of solid glass cleaning agent, specifically includes following steps：
(1) mixed liquor A is prepared：Take the water of the parts by weight to be heated to 40-50 DEG C, then add cocamidopropyl propyl amide sweet tea
Dish alkali, D-sorbite, sodium benzoate, cocoanut fatty acid diethanolamide, sodium tripolyphosphate, sodium sulphate, tetradecyl alchohol and silicic acid
Calcium is mixed evenly, and solution then is heated into 45-55 DEG C, obtains mixed liquor A standby；
(2) mixed liquid B is prepared：Salt, zeolite powder and mica powder are dissolved in and are heated in 50 DEG C of ethanol, it is agitated equal
Room temperature is naturally cooled to after even, mixed liquid B is obtained standby；
(3) mixed liquor C is prepared：Mixed liquor A is mixed with mixed liquid B, cleaning solution is added, then fully mixed three
It is even, obtain mixed liquor C standby；
(4) base substrate is prepared：Mold clean is clean, an olive oil is dipped in brush brush time inside mould, mixed liquor C is fallen
Enter mould, then mould is covered with plastic sheeting, in being placed 1-2 days in 30-38 DEG C of incubator, obtain base substrate standby；
(5) solid glass cleaning agent is prepared：Perfumed soap is removed from the molds, is placed at shady and cool ventilation, is put 4-8 weeks, then it is close
Package dress can obtain solid glass cleaning agent finished product.
In summary, by adopting the above-described technical solution, the beneficial effects of the invention are as follows：
1. cleaning solution, sodium sulphate and the tetradecyl alchohol in the solid glass cleaning agent of the present invention play cleaning action, with cocounut oil
Amido propyl betaine, sodium benzoate, cocoanut fatty acid diethanolamide are surfactant so that cleaning agent has more preferable
Dirt-removing power, ethanol can make solid cleaning agent keep uniform, exquisiteness at low temperature as solvent；Sodium tripolyphosphate is complexing
Agent, there is peptizaiton, is difficult crystallization and separates out so that the denseness of solid cleaning agent is varied with temperature less；Salt has stable make
With moisture pick-up properties is good, prevents the generation of crystalline polamer；The material combination science of the present invention, in the case where each composition is mutually coordinated, jointly
Play a role, be improved the combination property of solid glass cleaning agent.
2nd, solid glass cleaning agent of the invention, in the absence of any peculiar smell, to human body without any harm, when in use
The surface of cleaning thing needed for being applied directly to, plus a small amount of water or do not add water, glass can be allowed by directly being wiped with foam or rag
Glass light as before, saves a large amount of man power and materials, and in certain time after the cleaning, glass will not adsorption of dust again, separately
Its outer small volume, lightweight and cost of transportation is low, no matter under normal temperature or low temperature, in the absence of any impurity and muddiness.
【Embodiment】
The following examples can help those skilled in the art that the present invention is more fully understood, but cannot be with any
Mode limits the present invention.
Embodiment 1
A kind of solid glass cleaning agent that the present embodiment is provided is made up of the raw material of following parts by weight：Cocamidopropyl propyl amide
12 parts of glycine betaine, 6 parts of D-sorbite, 4 parts of sodium benzoate, 4 parts of cocoanut fatty acid diethanolamide, 5 parts of sodium sulphate, tetradecyl alchohol
4 parts, 5 parts of calcium silicates, 1 part of salt, 3 parts of sodium tripolyphosphate, 5 parts of ethanol, 6 parts of zeolite powder, 3 parts of mica powder, 10 parts of cleaning solution and
15 parts of water；Wherein, cleaning solution is made up of the raw material of following parts by weight：12 parts of butter fruit, 10 parts of glycerine, Chinese honey locust oily 15 parts, hydrogen-oxygen
Change 20 parts of 5 parts of sodium and water.
The preparation technology of above-mentioned solid glass cleaning agent comprises the following steps：
(1) cleaning solution is prepared
A. oily 15 parts by weight of the parts by weight of butter fruit 12, the parts by weight of glycerine 10 and Chinese honey locust are weighed, progress in container is put into together
Heating, is sufficiently stirred for mixing, and keeping temperature is 40 DEG C, obtains miscella standby；
B. take the water of 20 parts by weight to be placed in container, the sodium hydroxide of 5 parts by weight is added to the water, while with alkaline-resisting
Agitator quickly stir, aqueous slkali is obtained after reaction standby；
C. aqueous slkali is poured into the container equipped with miscella, while quickly being stirred with alkaline-resisting agitator, until container
Interior mixture surface can mark 8 complete words, you can the cleaning solution is made.
(2) zeolite powder is prepared
1. pre-process：Natural zeolite powder is taken, is rinsed for several times with water, removes soluble impurity, 3.5 are dried at 90 DEG C small
When；
2. modification：According to zeolite powder：Sodium chloride=1：1 mass ratio, by above-mentioned pretreated natural boiling powder and
Sodium chloride is mixed and is put into alkaline-resisting reactor, then the addition 1.0mol/L sodium hydroxide solutions into reactor so that hydroxide
Sodium solution just submerges natural zeolite powder and sodium chloride, and zeolite powder is rinsed to neutrality, then carried out by immersion after 24 hours with water
Ultrasonic disperse, then dried 3 hours under the conditions of 95 DEG C.
(3) solid glass cleaning agent is prepared
(1) mixed liquor A is prepared：Take the water of the parts by weight to be heated to 40 DEG C, then add cocamidopropyl propyl amide beet
Alkali, D-sorbite, sodium benzoate, cocoanut fatty acid diethanolamide, sodium tripolyphosphate, sodium sulphate, tetradecyl alchohol and calcium silicates
It is mixed evenly, solution is then heated to 45 DEG C, mixed liquor A is obtained standby；
(2) mixed liquid B is prepared：Salt, zeolite powder and mica powder are dissolved in and are heated in 50 DEG C of ethanol, it is agitated equal
Room temperature is naturally cooled to after even, mixed liquid B is obtained standby；
(3) mixed liquor C is prepared：Mixed liquor A is mixed with mixed liquid B, cleaning solution is added, then fully mixed three
It is even, obtain mixed liquor C standby；
(4) base substrate is prepared：Mold clean is clean, an olive oil is dipped in brush brush time inside mould, mixed liquor C is fallen
Enter mould, then mould is covered with plastic sheeting, in being placed 1 day in 30 DEG C of incubators, obtain base substrate standby；
(5) solid glass cleaning agent is prepared：Perfumed soap is removed from the molds, is placed at shady and cool ventilation, is put 4 weeks, then seal
Packaging can obtain solid glass cleaning agent finished product.
Embodiment 2
A kind of solid glass cleaning agent that the present embodiment is provided is made up of the raw material of following parts by weight：Cocamidopropyl propyl amide
15 parts of glycine betaine, 9 parts of D-sorbite, 6 parts of sodium benzoate, 6 parts of cocoanut fatty acid diethanolamide, 7 parts of sodium sulphate, tetradecyl alchohol
6 parts, 7 parts of calcium silicates, 3 parts of salt, 4 parts of sodium tripolyphosphate, 7 parts of ethanol, 9 parts of zeolite powder, 6 parts of mica powder, 15 parts of cleaning solution and
17 parts of water；Wherein, cleaning solution is made up of the raw material of following parts by weight：15 parts of butter fruit, 12 parts of glycerine, Chinese honey locust oily 18 parts, hydrogen-oxygen
Change 24 parts of 7 parts of sodium and water.
The preparation technology of above-mentioned solid glass cleaning agent comprises the following steps：
(1) cleaning solution is prepared
A. oily 18 parts by weight of the parts by weight of butter fruit 15, the parts by weight of glycerine 12 and Chinese honey locust are weighed, progress in container is put into together
Heating, is sufficiently stirred for mixing, and keeping temperature is 44 DEG C, obtains miscella standby；
B. take the water of 24 parts by weight to be placed in container, the sodium hydroxide of 7 parts by weight is added to the water, while with alkaline-resisting
Agitator quickly stir, aqueous slkali is obtained after reaction standby；
C. aqueous slkali is poured into the container equipped with miscella, while quickly being stirred with alkaline-resisting agitator, until container
Interior mixture surface can mark 8 complete words, you can the cleaning solution is made.
(2) zeolite powder is prepared
1. pre-process：Natural zeolite powder is taken, is rinsed for several times with water, removes soluble impurity, 4.0 are dried at 100 DEG C small
When；
2. modification：According to zeolite powder：Sodium chloride=1：1 mass ratio, by above-mentioned pretreated natural boiling powder and
Sodium chloride is mixed and is put into alkaline-resisting reactor, then the addition 1.0mol/L sodium hydroxide solutions into reactor so that hydroxide
Sodium solution just submerges natural zeolite powder and sodium chloride, and zeolite powder is rinsed to neutrality, then carried out by immersion after 28 hours with water
Ultrasonic disperse, then dried 5 hours under the conditions of 102 DEG C.
(3) solid glass cleaning agent is prepared
(1) mixed liquor A is prepared：Take the water of the parts by weight to be heated to 45 DEG C, then add cocamidopropyl propyl amide beet
Alkali, D-sorbite, sodium benzoate, cocoanut fatty acid diethanolamide, sodium tripolyphosphate, sodium sulphate, tetradecyl alchohol and calcium silicates
It is mixed evenly, solution is then heated to 50 DEG C, mixed liquor A is obtained standby；
(2) mixed liquid B is prepared：Salt, zeolite powder and mica powder are dissolved in and are heated in 50 DEG C of ethanol, it is agitated equal
Room temperature is naturally cooled to after even, mixed liquid B is obtained standby；
(3) mixed liquor C is prepared：Mixed liquor A is mixed with mixed liquid B, cleaning solution is added, then fully mixed three
It is even, obtain mixed liquor C standby；
(4) base substrate is prepared：Mold clean is clean, an olive oil is dipped in brush brush time inside mould, mixed liquor C is fallen
Enter mould, then mould is covered with plastic sheeting, in being placed 2 days in 35 DEG C of incubators, obtain base substrate standby；
(5) solid glass cleaning agent is prepared：Perfumed soap is removed from the molds, is placed at shady and cool ventilation, is put 6 weeks, then seal
Packaging can obtain solid glass cleaning agent finished product.
Embodiment 3
A kind of solid glass cleaning agent that the present embodiment is provided is made up of the raw material of following parts by weight：Cocamidopropyl propyl amide
18 parts of glycine betaine, 12 parts of D-sorbite, 8 parts of sodium benzoate, 8 parts of cocoanut fatty acid diethanolamide, 10 parts of sodium sulphate, 14
8 parts of alcohol, 9 parts of calcium silicates, 5 parts of salt, 5 parts of sodium tripolyphosphate, 10 parts of ethanol, 12 parts of zeolite powder, 8 parts of mica powder, cleaning solution 20
20 parts of part and water；Wherein, cleaning solution is made up of the raw material of following parts by weight：18 parts of butter fruit, 15 parts of glycerine, Chinese honey locust oil 22 parts,
28 parts of 10 parts of sodium hydroxide and water.
The preparation technology of above-mentioned solid glass cleaning agent comprises the following steps：
(1) cleaning solution is prepared
A. oily 22 parts by weight of the parts by weight of butter fruit 18, the parts by weight of glycerine 15 and Chinese honey locust are weighed, progress in container is put into together
Heating, is sufficiently stirred for mixing, and keeping temperature is 48 DEG C, obtains miscella standby；
B. take the water of 28 parts by weight to be placed in container, the sodium hydroxide of 10 parts by weight is added to the water, while with resistance to
The agitator of alkali is quickly stirred, and aqueous slkali is obtained after reaction standby；
C. aqueous slkali is poured into the container equipped with miscella, while quickly being stirred with alkaline-resisting agitator, until container
Interior mixture surface can mark 8 complete words, you can the cleaning solution is made.
(2) zeolite powder is prepared
1. pre-process：Natural zeolite powder is taken, is rinsed for several times with water, removes soluble impurity, 5.5 are dried at 110 DEG C small
When；
2. modification：According to zeolite powder：Sodium chloride=1：1 mass ratio, by above-mentioned pretreated natural boiling powder and
Sodium chloride is mixed and is put into alkaline-resisting reactor, then the addition 1.0mol/L sodium hydroxide solutions into reactor so that hydroxide
Sodium solution just submerges natural zeolite powder and sodium chloride, and zeolite powder is rinsed to neutrality, then carried out by immersion after 32 hours with water
Ultrasonic disperse, then dried 6 hours under the conditions of 110 DEG C.
(3) solid glass cleaning agent is prepared
(1) mixed liquor A is prepared：Take the water of the parts by weight to be heated to 50 DEG C, then add cocamidopropyl propyl amide beet
Alkali, D-sorbite, sodium benzoate, cocoanut fatty acid diethanolamide, sodium tripolyphosphate, sodium sulphate, tetradecyl alchohol and calcium silicates
It is mixed evenly, solution is then heated to 55 DEG C, mixed liquor A is obtained standby；
(2) mixed liquid B is prepared：Salt, zeolite powder and mica powder are dissolved in and are heated in 50 DEG C of ethanol, it is agitated equal
Room temperature is naturally cooled to after even, mixed liquid B is obtained standby；
(3) mixed liquor C is prepared：Mixed liquor A is mixed with mixed liquid B, cleaning solution is added, then fully mixed three
It is even, obtain mixed liquor C standby；
(4) base substrate is prepared：Mold clean is clean, an olive oil is dipped in brush brush time inside mould, mixed liquor C is fallen
Enter mould, then mould is covered with plastic sheeting, in being placed 2 days in 38 DEG C of incubators, obtain base substrate standby；
(5) solid glass cleaning agent is prepared：Perfumed soap is removed from the molds, is placed at shady and cool ventilation, is put 8 weeks, then seal
Packaging can obtain solid glass cleaning agent finished product.
Comparative analysis
In order to further prove the characteristic of the present invention, it is divided into four groups and does comparative testing below：
First group：Solid glass cleaning agent described in embodiment 1；
Second group：Solid glass cleaning agent described in embodiment 2；
3rd group：Solid glass cleaning agent described in embodiment 3；
4th group：The bright net glass cleaners of Wei Lushi purchased on the market.
In the case of condition identical, vehicle window cleaning effect is determined respectively, each situation such as following table is then recorded：
As can be seen from the above table, glass cleaner of the invention, free from extraneous odour is only needed to during cleaning with a small amount of
Water rinse, glass light is as new, and in certain time after the cleaning after cleaning, and glass is not easy adsorption of dust, in addition, this
The solid glass cleaning agent of invention also has a small volume, the lightweight and low feature of cost of transportation, no matter under normal temperature or low temperature,
In the absence of any impurity and muddiness, it is adapted to promote in the art.
Although above the present invention is described in detail with a general description of the specific embodiments,
On the basis of the present invention, it can be made some modifications or improvements, this will be apparent to those skilled in the art.Cause
This, these modifications or improvements, belong to the scope of protection of present invention without departing from theon the basis of the spirit of the present invention.
Claims (6)
1. a kind of solid glass cleaning agent, it is characterised in that the solid glass cleaning agent is made up of the raw material of following parts by weight：
12-18 parts of Cocoamidopropyl betaine, 6-12 parts of D-sorbite, 4-8 parts of sodium benzoate, cocoanut fatty acid diethanolamide
4-8 parts, 5-10 parts of sodium sulphate, 4-8 parts of tetradecyl alchohol, 5-9 parts of calcium silicates, 1-5 parts of salt, 3-5 parts of sodium tripolyphosphate, ethanol 5-10
Part, 6-12 parts of zeolite powder, 3-8 parts of mica powder, 10-20 parts of cleaning solution and 15-20 parts of water；
The cleaning solution is made up of the raw material of following parts by weight：12-18 parts of butter fruit, 10-15 parts of glycerine, 15-22 parts of Chinese honey locust oil,
20-28 parts of 5-10 parts of sodium hydroxide and water.
2. a kind of solid glass cleaning agent according to claim 1, it is characterised in that the solid glass cleaning agent by with
The raw material composition of lower parts by weight：15 parts of Cocoamidopropyl betaine, 9 parts of D-sorbite, 6 parts of sodium benzoate, coconut oil fat
Sour 6 parts of diglycollic amide, 7 parts of sodium sulphate, 6 parts of tetradecyl alchohol, 7 parts of calcium silicates, 3 parts of salt, 4 parts of sodium tripolyphosphate, 7 parts of ethanol,
17 parts of 9 parts of zeolite powder, 6 parts of mica powder, 15 parts of cleaning solution and water；
The cleaning solution is made up of the raw material of following parts by weight：15 parts of butter fruit, 12 parts of glycerine, Chinese honey locust oily 18 parts, sodium hydroxide 7
24 parts of part and water.
3. a kind of solid glass cleaning agent according to claim 1, it is characterised in that the cleaning solution is by with lower section
What method was obtained：
A. butter fruit 12-18 parts by weight, glycerine 10-15 parts by weight and Chinese honey locust oil 15-22 parts by weight are weighed, are put into together in container
Heated, be sufficiently stirred for mixing, and keeping temperature is 40-48 DEG C, obtains miscella standby；
B. take the water of the 20-28 parts by weight to be placed in container, the sodium hydroxide of 5-10 parts by weight is added to the water, while with resistance to
The agitator of alkali is quickly stirred, and aqueous slkali is obtained after reaction standby；
C. aqueous slkali is poured into the container equipped with miscella, while quickly being stirred with alkaline-resisting agitator, until in container
Mixture surface can mark 8 complete words, you can the cleaning solution is made.
4. a kind of solid glass cleaning agent according to claim 1, it is characterised in that the zeolite powder is modified zeolite
Powder, the modified zeolite powder carries out solution infusion method modification as improved chemical using inorganic base and sodium chloride to zeolite powder
Method is made.
5. a kind of solid glass cleaning agent according to claim 4, it is characterised in that the specific system of the modified zeolite powder
Preparation Method is as follows：
1. pre-process：Natural zeolite powder is taken, is rinsed for several times with water, removes soluble impurity, 3.5-5.5 is dried at 90-110 DEG C
Hour；
2. modification：According to zeolite powder：Sodium chloride=1：1 mass ratio, by above-mentioned pretreated natural boiling powder and chlorination
Sodium is mixed and is put into alkaline-resisting reactor, then the addition 1.0mol/L sodium hydroxide solutions into reactor so that sodium hydroxide is molten
Liquid just submerges natural zeolite powder and sodium chloride, and zeolite powder is rinsed to neutrality, then surpassed by immersion after 24-32 hours with water
Sound disperses, then is dried 3-6 hours under the conditions of 95-110 DEG C.
6. the preparation method of a kind of solid glass cleaning agent according to claim any one of 1-5, it is characterised in that described
Preparation method comprises the following steps：
(1) mixed liquor A is prepared：Take the water of the parts by weight to be heated to 40-50 DEG C, then add cocamidopropyl propyl amide beet
Alkali, D-sorbite, sodium benzoate, cocoanut fatty acid diethanolamide, sodium tripolyphosphate, sodium sulphate, tetradecyl alchohol and calcium silicates
It is mixed evenly, solution is then heated to 45-55 DEG C, obtains mixed liquor A standby；
(2) mixed liquid B is prepared：Salt, zeolite powder and mica powder are dissolved in and are heated in 50 DEG C of ethanol, it is agitated it is uniform after
Room temperature is naturally cooled to, mixed liquid B is obtained standby；
(3) mixed liquor C is prepared：Mixed liquor A is mixed with mixed liquid B, cleaning solution is added, then three is fully mixed thoroughly, obtained
It is standby to mixed liquor C；
(4) base substrate is prepared：Mold clean is clean, an olive oil is dipped in brush brush time inside mould, mixed liquor C is poured into mould
Tool, then mould is covered with plastic sheeting, in being placed 1-2 days in 30-38 DEG C of incubator, obtain base substrate standby；
(5) solid glass cleaning agent is prepared：Perfumed soap is removed from the molds, is placed at shady and cool ventilation, 4-8 weeks, then sealed bundle is put
Dress can obtain solid glass cleaning agent finished product.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710282891.8A CN107012021A (en) | 2017-04-26 | 2017-04-26 | A kind of solid glass cleaning agent and preparation method thereof |
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| CN201710282891.8A CN107012021A (en) | 2017-04-26 | 2017-04-26 | A kind of solid glass cleaning agent and preparation method thereof |
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| CN107012021A true CN107012021A (en) | 2017-08-04 |
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| CN108559676A (en) * | 2018-05-14 | 2018-09-21 | 合肥钢骨玻璃制品有限公司 | A kind of general glass cleaner and preparation method thereof |
| CN109261619A (en) * | 2018-10-15 | 2019-01-25 | 郑州旭飞光电科技有限公司 | The cleaning method of liquid crystal substrate glass surface stain spot |
| CN113234550A (en) * | 2021-04-06 | 2021-08-10 | 神美科技有限公司 | Sewage pipe network cleaning agent and preparation method thereof |
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| CN108559676A (en) * | 2018-05-14 | 2018-09-21 | 合肥钢骨玻璃制品有限公司 | A kind of general glass cleaner and preparation method thereof |
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| CN113234550A (en) * | 2021-04-06 | 2021-08-10 | 神美科技有限公司 | Sewage pipe network cleaning agent and preparation method thereof |
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Application publication date: 20170804 |