CN106190617A - A kind of glass Scale detergent and preparation method thereof - Google Patents
A kind of glass Scale detergent and preparation method thereof Download PDFInfo
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- CN106190617A CN106190617A CN201610543904.8A CN201610543904A CN106190617A CN 106190617 A CN106190617 A CN 106190617A CN 201610543904 A CN201610543904 A CN 201610543904A CN 106190617 A CN106190617 A CN 106190617A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/722—Ethers of polyoxyalkylene glycols having mixed oxyalkylene groups; Polyalkoxylated fatty alcohols or polyalkoxylated alkylaryl alcohols with mixed oxyalkylele groups
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/042—Acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/08—Silicates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
- C11D3/2013—Monohydric alcohols linear fatty or with at least 8 carbon atoms in the alkyl chain
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/2017—Monohydric alcohols branched
- C11D3/202—Monohydric alcohols branched fatty or with at least 8 carbon atoms in the alkyl chain
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2079—Monocarboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2082—Polycarboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
- C11D1/721—End blocked ethers
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Abstract
The invention discloses a kind of glass Scale detergent and preparation method thereof, it is made up of the raw material of following weight: surfactant 0.5～10 parts, fluoride 0.5～15 parts, weak acid 10～30 parts, acrylic acid homopolymer sodium salt 1～3 parts, Borax 1～10, solvent 5～20 parts, softening water 40～70 parts.Being made in accordance with the following methods: add the softening water of 40～50 DEG C in container, add in container by fluoride and Borax, thing to be fluorinated and Borax add weak acid after being completely dissolved and stir to solution transparent；In container, add surfactant and acrylic acid homopolymer sodium salt successively, and stir to acrylic acid homopolymer sodium salt and be completely dissolved, it is thus achieved that solution a；After solution a temperature is less than 40 DEG C, adds solvent and stir, it is thus achieved that solution b；Solution b is stood and makes contamination precipitation, finally filter and remove impurity in solution b.The cleaning agent of the present invention can old incrustation scale on fully erased glass or other crust, and the glass surface after cleaning will not hang the globule.
Description
Technical field
Present invention relates particularly to a kind of Scale detergent, particularly relate to a kind of glass Scale detergent and preparation side thereof
Method.
Background technology
Glass cleaner the most on the market is based on neutral cleaners, and the incrustation scale on glass is not almost had by this kind of abluent
There is a cleaning action, and a glass surface globule the most easy to hang after cleaning, it is necessary to scrape dry or dry and can be only achieved transparent, bright effect
Really.Containing many inorganic salts in the tap water used in our daily life or well water, this kind of material hard table the most after cleaning
Form the incrustation scale of mottle shape on face, combine the most firm the most on the glass surface.
Just being readily formed serious incrustation scale on the bathroom glass partition of domestic, newly-generated incrustation scale is clear by general acidity
Clean dose just can thoroughly clean up, and the time that once incrustation scale is formed exceedes half a year or more long, and common acidic glass cleaning agent is also
Just have no way out.
Summary of the invention
It is an object of the invention to overcome the shortcoming of prior art, it is provided that a kind of glass Scale detergent and preparation side thereof
Method, to solve the old incrustation scale that existing glass cleaner is difficult to clean off on glass or other crust, and the glass table after cleaning
The shortcoming of the face globule easy to hang.
For achieving the above object, the technical solution used in the present invention is:
On the one hand, a kind of glass Scale detergent, it is made up of the raw material of following weight:
Surfactant 0.5～10 parts, fluoride 0.5～15 parts, weak acid 10～30 parts, acrylic acid homopolymer sodium salt 1
～3 parts, Borax 1～10, solvent 5～20 parts, softening water 40～70 parts.
As preferably, described surfactant is selected from: isomeric alcohol polyethenoxy ether, low alveolitoid fatty alcohol alkoxyl chemical combination
Thing, alkoxyl surfactant, the sulfonate of fatty acid methyl ester ethoxylate, ethylenediamine PO-EO block polyether, fatty alcohol
EO-PO block polyether, polyether silicon, alkyl, polyether modified siloxane, phosphate ester, oleic alcohol polyoxyethylene ether, surfactant
Compound or its mixture.
As preferably, described fluoride is selected from: Fluohydric acid., ammonium acid fluoride, sodium bifluoride, sodium fluoride, prodan or its
Mixture.
As preferably, described weak acid is selected from: phosphoric acid, oxalic acid, glacial acetic acid, citric acid or its mixture.
As preferably, described solvent is selected from: ethanol, isopropanol or its mixture.
As preferably, the weight of described raw material is:
5 parts of surfactant, 5 parts of fluoride, weak acid 15 parts, acrylic acid homopolymer sodium salt 2 parts, Borax 5 parts, solvent 10
Part, soften 58 parts of water；
Described surfactant is that isomeric alcohol polyethenoxy ether and low alveolitoid fat alcohol alkoxy compound are by the weight of 3:2
Part proportioning is mixed to prepare, and described fluoride is ammonium acid fluoride, and described weak acid is phosphoric acid and citric acid is mixed by the weight of 2:1
Closing and prepare, described solvent is isopropanol.
As preferably, the weight of described raw material is:
7 parts of surfactant, 10.5 parts of fluoride, weak acid 25 parts, acrylic acid homopolymer sodium salt 1 part, Borax 3 parts, molten
Agent 5 parts, softens 48.5 parts of water；
Described surfactant is that isomeric alcohol polyethenoxy ether and alkoxyl surfactant are mixed by the weight of 4:3
Closing and prepare, described fluoride is Fluohydric acid. and prodan is mixed to prepare by the weight of 20:1, and described weak acid is ice vinegar
Acid and citric acid are mixed to prepare by the weight of 3:2, and described solvent is ethanol.
As preferably, the weight of described raw material is:
8 parts of surfactant, 1.5 parts of fluoride, weak acid 15 parts, acrylic acid homopolymer sodium salt 2 parts, Borax 1 part, solvent
10 parts, soften 62.5 parts of water；
Described surfactant is that alkoxyl surfactant and surfactant blend are mixed by the weight of 3:5
Closing and prepare, described fluoride is sodium bifluoride and prodan is mixed to prepare by the weight of 2:1, and described weak acid is oxalic acid
Being mixed to prepare by the weight of 1:2 with citric acid, described solvent is ethanol.
On the other hand, the preparation method of glass Scale detergent, comprise the following steps:
Step 1, adds the softening water of 40～50 DEG C in container, adds in container by fluoride and Borax, thing to be fluorinated
Add weak acid after being completely dissolved with Borax and stir to solution transparent；
Step 2, adds surfactant and acrylic acid homopolymer sodium salt successively in container, and stirs to acrylic acid equal
Polymer sodium salt is completely dissolved, it is thus achieved that solution a；
Step 3, after solution a temperature is less than 40 DEG C, adds solvent and stirs, it is thus achieved that solution b；Solution b is stood
Make contamination precipitation, finally filter and remove impurity in solution b.
As preferably, the softening water added in described step 1 is 45 DEG C.
Beneficial effects of the present invention is
1, fluoride and the weak acid synergism of the present invention can be completely dissolved old incrustation scale, and the old incrustation scale making glass surface is complete
Fully stripped comes off；Glass surface can be caused corrosion damage when cleaning glass by fluoride, makes glass surface glossiness and transparency
Declining, Borax and acrylic acid homopolymer sodium salt synergism can effectively suppress the fluoride corrosion damage to glass surface；Fluorine
Compound, Borax and weak acid synergism can improve the close demineralised aqueous energy of glass surface, and the glass surface after cleaning does not hang water
Pearl, it is not necessary to scraping dry or dry glass surface, natural drying i.e. can reach light, transparent effect.
2, the cleaning agent of the present invention is through actually used test, it is possible to effectively remove what glass surface produced because of damp and mouldy
Rainbow, white haze, white macula and paster phenomenon.
3, the cleaning agent of the present invention is through actually used test, also has excellent to other dirt on glass and other crust
Removal effect, such as: rust stain, oil stain, pigment, dust and earth.
Detailed description of the invention
For making the object, technical solutions and advantages of the present invention clearer, below in conjunction with the specific embodiment of the invention pair
Technical solution of the present invention is clearly and completely described.
Raw material introduction in following example:
Embodiment 1: take isomeric alcohol polyethenoxy ether (Lutensol XL70) and low alveolitoid fat alcohol alkoxy compound
(Plurafac LF221) is mixed to prepare 5 parts of surfactant by the weight of 3:2, ammonium acid fluoride 5 parts as fluoride,
Phosphoric acid and citric acid are mixed to prepare weak acid 15 parts, 2 parts of acrylic acid homopolymer sodium salt (445N), boron by the weight of 2:1
5 parts of sand, takes isopropanol 10 parts as solvent, and 58 parts of the softening water of 50 DEG C is standby.
Adding the softening water of 50 DEG C in container, fluoride and Borax are added in container, thing to be fluorinated and Borax are complete
Add weak acid after dissolving and stir to solution transparent.
In container, add surfactant and acrylic acid homopolymer sodium salt successively, and stir to acrylic acid homopolymer
Sodium salt is completely dissolved, it is thus achieved that solution a.
After solution a temperature is less than 40 DEG C, adds solvent and stir, it is thus achieved that solution b；Solution b is stood and makes impurity
Precipitation, finally filters and removes impurity in solution b.
Embodiment 2: take isomeric alcohol polyethenoxy ether (Lutensol XL70) and alkoxyl surfactant (ox-10m08)
Being mixed to prepare 7 parts of surfactant by the weight of 4:3, Fluohydric acid. and prodan press the weight mixing of 20:1
Preparing 10.5 parts of fluoride, glacial acetic acid and citric acid are mixed to prepare weak acid 25 parts, acrylic acid homopolymerization by the weight of 3:2
Compound sodium salt (445N) 1 part, Borax 3 parts, take ethanol 5 parts as solvent, 48.5 parts of the softening water of 50 DEG C, standby.
Adding the softening water of 50 DEG C in container, fluoride and Borax are added in container, thing to be fluorinated and Borax are complete
Add weak acid after dissolving and stir to solution transparent.
In container, add surfactant and acrylic acid homopolymer sodium salt successively, and stir to acrylic acid homopolymer
Sodium salt is completely dissolved, it is thus achieved that solution a.
After solution a temperature is less than 40 DEG C, adds solvent and stir, it is thus achieved that solution b；Solution b is stood and makes impurity
Precipitation, finally filters and removes impurity in solution b.
Embodiment 3: take alkoxyl surfactant (ox-10m08) and surfactant blend (CQ/AL100) by 3:5
Weight be mixed to prepare 8 parts of surfactant, sodium bifluoride and prodan and be mixed to prepare by the weight of 2:1
1.5 parts of fluoride, oxalic acid and citric acid are mixed to prepare weak acid 15 parts, acrylic acid homopolymer sodium salt by the weight of 1:2
(445N) 2 parts, Borax 1 part, take ethanol 10 parts as solvent, 62.5 parts of the softening water of 50 DEG C, standby.
Adding the softening water of 50 DEG C in container, fluoride and Borax are added in container, thing to be fluorinated and Borax are complete
Add weak acid after dissolving and stir to solution transparent.
In container, add surfactant and acrylic acid homopolymer sodium salt successively, and stir to acrylic acid homopolymer
Sodium salt is completely dissolved, it is thus achieved that solution a.
After solution a temperature is less than 40 DEG C, adds solvent and stir, it is thus achieved that solution b；Solution b is stood and makes impurity
Precipitation, finally filters and removes impurity in solution b.
Embodiment 4: take isomeric alcohol polyethenoxy ether and low alveolitoid fat alcohol alkoxy compound by the weight of 3:2
Being mixed to prepare 5 parts of surfactant, ammonium acid fluoride 5 parts presses the weight mixing of 2:1 as fluoride, phosphoric acid and citric acid
Prepare weak acid 15 parts, acrylic acid homopolymer sodium salt 2 parts, Borax 5 parts, take isopropanol 10 parts as solvent, the softening water of 45 DEG C
58 parts, standby.
Adding the softening water of 45 DEG C in container, fluoride and Borax are added in container, thing to be fluorinated and Borax are complete
Add weak acid after dissolving and stir to solution transparent.
In container, add surfactant and acrylic acid homopolymer sodium salt successively, and stir to acrylic acid homopolymer
Sodium salt is completely dissolved, it is thus achieved that solution a.
After solution a temperature is less than 40 DEG C, adds solvent and stir, it is thus achieved that solution b；Solution b is stood and makes impurity
Precipitation, finally filters and removes impurity in solution b.
Embodiment 5: take isomeric alcohol polyethenoxy ether and alkoxyl surfactant is mixed to prepare by the weight of 4:3
7 parts of surfactant, Fluohydric acid. and prodan are mixed to prepare 10.5 parts of fluoride by the weight of 20:1, glacial acetic acid and
Citric acid is mixed to prepare weak acid 25 parts, acrylic acid homopolymer sodium salt 1 part, Borax 3 parts by the weight of 3:2, takes ethanol 5
Part as solvent, 48.5 parts of the softening water of 43 DEG C, standby.
Adding the softening water of 43 DEG C in container, fluoride and Borax are added in container, thing to be fluorinated and Borax are complete
Add weak acid after dissolving and stir to solution transparent.
In container, add surfactant and acrylic acid homopolymer sodium salt successively, and stir to acrylic acid homopolymer
Sodium salt is completely dissolved, it is thus achieved that solution a.
After solution a temperature is less than 40 DEG C, adds solvent and stir, it is thus achieved that solution b；Solution b is stood and makes impurity
Precipitation, finally filters and removes impurity in solution b.
Embodiment 6: take alkoxyl surfactant and surfactant blend and be mixed to prepare by the weight of 3:5
8 parts of surfactant, sodium bifluoride and prodan are mixed to prepare 1.5 parts of fluoride, oxalic acid and lemon by the weight of 2:1
Lemon acid is mixed to prepare weak acid 15 parts, acrylic acid homopolymer sodium salt 2 parts, Borax 1 part, ethanol 10 parts by the weight of 1:2
As solvent, 62.5 parts of the softening water of 40 DEG C, standby.
Adding the softening water of 40 DEG C in container, fluoride and Borax are added in container, thing to be fluorinated and Borax are complete
Add weak acid after dissolving and stir to solution transparent.
In container, add surfactant and acrylic acid homopolymer sodium salt successively, and stir to acrylic acid homopolymer
Sodium salt is completely dissolved, it is thus achieved that solution a.
After solution a temperature is less than 40 DEG C, adds solvent and stir, it is thus achieved that solution b；Solution b is stood and makes impurity
Precipitation, finally filters and removes impurity in solution b.
Embodiment 7: take isomeric alcohol polyethenoxy ether and low alveolitoid fat alcohol alkoxy compound by the weight of 3:2
Being mixed to prepare 4 parts of surfactant, ammonium acid fluoride 4 parts presses the weight mixing of 2:1 as fluoride, phosphoric acid and citric acid
Prepare weak acid 13 parts, acrylic acid homopolymer sodium salt 1.5 parts, Borax 4 parts, take isopropanol 9 parts as solvent, the softening water of 50 DEG C
53 parts, standby.
Adding the softening water of 50 DEG C in container, fluoride and Borax are added in container, thing to be fluorinated and Borax are complete
Add weak acid after dissolving and stir to solution transparent.
In container, add surfactant and acrylic acid homopolymer sodium salt successively, and stir to acrylic acid homopolymer
Sodium salt is completely dissolved, it is thus achieved that solution a.
After solution a temperature is less than 40 DEG C, adds solvent and stir, it is thus achieved that solution b；Solution b is stood and makes impurity
Precipitation, finally filters and removes impurity in solution b.
Embodiment 8: take isomeric alcohol polyethenoxy ether and alkoxyl surfactant is mixed to prepare by the weight of 4:3
9 parts of surfactant, Fluohydric acid. and prodan are mixed to prepare 12 parts of fluoride, glacial acetic acid and lemon by the weight of 20:1
Lemon acid is mixed to prepare weak acid 27 parts, acrylic acid homopolymer sodium salt 2.5 parts, Borax 7 parts by the weight of 3:2, takes ethanol 7
Part as solvent, 45 parts of the softening water of 50 DEG C, standby.
Adding the softening water of 50 DEG C in container, fluoride and Borax are added in container, thing to be fluorinated and Borax are complete
Add weak acid after dissolving and stir to solution transparent.
In container, add surfactant and acrylic acid homopolymer sodium salt successively, and stir to acrylic acid and be all polymerized
Thing sodium salt is completely dissolved, it is thus achieved that solution a.
After solution a temperature is less than 40 DEG C, adds solvent and stir, it is thus achieved that solution b；Solution b is stood and makes impurity
Precipitation, finally filters and removes impurity in solution b.
Embodiment 9: take alkoxyl surfactant and surfactant blend and be mixed to prepare by the weight of 3:5
9.5 parts of surfactant, sodium bifluoride and prodan are mixed to prepare 1.7 parts of fluoride by the weight of 2:1, oxalic acid and
Citric acid is mixed to prepare weak acid 17 parts, acrylic acid homopolymer sodium salt 2.7 parts, Borax 1.3 parts by the weight of 1:2, takes
Ethanol 9.8 parts as solvent, 65 parts of the softening water of 50 DEG C, standby.
Adding the softening water of 50 DEG C in container, fluoride and Borax are added in container, thing to be fluorinated and Borax are complete
Add weak acid after dissolving and stir to solution transparent.
In container, add surfactant and acrylic acid homopolymer sodium salt successively, and stir to acrylic acid homopolymer
Sodium salt is completely dissolved, it is thus achieved that solution a.
After solution a temperature is less than 40 DEG C, adds solvent and stir, it is thus achieved that solution b；Solution b is stood and makes impurity
Precipitation, finally filters and removes impurity in solution b.
Above-mentioned embodiment is used for illustrating the present invention rather than limiting the invention, in the spirit of the present invention
With in scope of the claims, any modifications and changes that the present invention is made, both fall within protection scope of the present invention.
Claims (10)
1. a glass Scale detergent, it is characterised in that be made up of the raw material of following weight:
Surfactant 0.5～10 parts, fluoride 0.5～15 parts, weak acid 10～30 parts, acrylic acid homopolymer sodium salt 1～3
Part, Borax 1～10, solvent 5～20 parts, softening water 40～70 parts.
Glass Scale detergent the most according to claim 1, it is characterised in that described surfactant is selected from: isomery alcohol polyoxy
Vinyl Ether, low alveolitoid fat alcohol alkoxy compound, alkoxyl surfactant, the sulfonic acid of fatty acid methyl ester ethoxylate
Salt, ethylenediamine PO-EO block polyether, fatty alcohol EO-PO block polyether, polyether silicon, alkyl, polyether modified siloxane, phosphoric acid
Ester, oleic alcohol polyoxyethylene ether, surfactant blend or its mixture.
Glass Scale detergent the most according to claim 1, it is characterised in that described fluoride is selected from: Fluohydric acid., fluohydric acid gas
Ammonium, sodium bifluoride, sodium fluoride, prodan or its mixture.
Glass Scale detergent the most according to claim 1, it is characterised in that described weak acid is selected from: phosphoric acid, oxalic acid, glacial acetic acid,
Citric acid or its mixture.
Glass Scale detergent the most according to claim 1, it is characterised in that described solvent is selected from: ethanol, isopropanol or its mix
Compound.
6. according to the glass Scale detergent of any one of Claims 1 to 5, it is characterised in that the weight of described raw material
For:
5 parts of surfactant, 5 parts of fluoride, weak acid 15 parts, acrylic acid homopolymer sodium salt 2 parts, Borax 5 parts, solvent 10 parts,
Soften 58 parts of water；
Described surfactant is isomeric alcohol polyethenoxy ether and low alveolitoid fat alcohol alkoxy compound is joined by the weight portion of 3:2
Ratio is mixed to prepare, and described fluoride is ammonium acid fluoride, and described weak acid is that phosphoric acid and citric acid mix system by the weight of 2:1
, described solvent is isopropanol.
7. according to the glass Scale detergent of any one of Claims 1 to 5, it is characterised in that the weight of described raw material
For:
7 parts of surfactant, 10.5 parts of fluoride, weak acid 25 parts, acrylic acid homopolymer sodium salt 1 part, Borax 3 parts, solvent 5
Part, soften 48.5 parts of water；
Described surfactant is that isomeric alcohol polyethenoxy ether and alkoxyl surfactant mix system by the weight of 4:3
, described fluoride is Fluohydric acid. and prodan is mixed to prepare by the weight of 20:1, described weak acid be glacial acetic acid and
Citric acid is mixed to prepare by the weight of 3:2, and described solvent is ethanol.
8. according to the glass Scale detergent of any one of Claims 1 to 5, it is characterised in that the weight of described raw material
For:
8 parts of surfactant, 1.5 parts of fluoride, weak acid 15 parts, acrylic acid homopolymer sodium salt 2 parts, Borax 1 part, solvent 10
Part, soften 62.5 parts of water；
Described surfactant is that alkoxyl surfactant and surfactant blend mix system by the weight of 3:5
, described fluoride is sodium bifluoride and prodan is mixed to prepare by the weight of 2:1, and described weak acid is oxalic acid and lemon
Lemon acid is mixed to prepare by the weight of 1:2, and described solvent is ethanol.
The preparation method of glass Scale detergent the most according to claims 1 to 8, it is characterised in that comprise the following steps:
Step 1, adds the softening water of 40～50 DEG C in container, adds in container by fluoride and Borax, thing to be fluorinated and boron
Sand adds weak acid after being completely dissolved and stirs to solution transparent；
Step 2, adds surfactant and acrylic acid homopolymer sodium salt successively in container, and stirs to acrylic acid and be all polymerized
Thing sodium salt is completely dissolved, it is thus achieved that solution a；
Step 3, after solution a temperature is less than 40 DEG C, adds solvent and stirs, it is thus achieved that solution b；Solution b standing is made miscellaneous
Matter precipitates, and finally filters and removes impurity in solution b.
10. glass Scale detergent preparation method as claimed in claim 9, is characterized by, the softening water added in described step 1 is
45℃。
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Application publication date: 20161207 |