CN101880608A - Natural solid cleaning agent - Google Patents
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- CN101880608A CN101880608A CN 201010212838 CN201010212838A CN101880608A CN 101880608 A CN101880608 A CN 101880608A CN 201010212838 CN201010212838 CN 201010212838 CN 201010212838 A CN201010212838 A CN 201010212838A CN 101880608 A CN101880608 A CN 101880608A
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Abstract
The invention discloses a natural solid cleaning agent for cleaning stains on hard surfaces of objects, which is prepared from the following raw material in percentage by weight: 6 to 50 percent of kaolin, 4 to 36 percent of zeolite, 7 to 45 percent of calcite powder, 3 to 40 percent of pumice powder, 4 to 55 percent of feldspar powder, 2 to 17 percent of kieselguhr, 3 to 22 percent of montmorillonite powder, 4 to 40 percent of talcpowder, 1 to 15 percent of saponin, 3 to 18 percent of white carbon black and 0 to 40 percent of water. The natural solid cleaning agent has desirable cleaning effect on various stains, such as oil stains, sweat stains, tea stains, juice stains, milk stains, blood stains, ink stains, ash stains and dust stains on hard surfaces of metal, ceramic, wood, glass, fiber plates and stone plates. The raw materials are natural powder and plant extracts. The cleaning agent has high biodegradability and is safe, environmentally-friendly, pollution-free and convenient to use.
Description
Technical field
The invention belongs to the daily cleaning field, relate in particular to a kind of new type natural solid cleaning agent that is used for crusts such as metal, pottery, plank, glass, fiberboard, slabstone, glass are cleaned decontamination.
Background technology
At present, cleaning decontamination for crusts such as metal, pottery, plank, glass, fiberboard, slabstone, glass is based on various cleaning sprays, and its effective constituent is that chemical industry synthetic various surfactants and the configuration of all kinds of auxiliary chemicals form.The waste water that produces in production and use is rich in various tensio-active agents, all can produce harm to environment, and promptly various chemical substances endanger user's health at user's skin residual packing.After use, need water repeatedly to clean simultaneously, waste water and the time contaminate environment and water source.
People recognize the harm of chemical substance to environment day by day now, advocate the life and the consumption of low-carbon (LC); Society's water resources shortage needs water saving; The allegro mode of life of people need save time.Need a kind of can safety non-toxic, natural health, high-effective cleansing, hard surface cleaner with low cost, easy to use.
Summary of the invention
The objective of the invention is environment or human body to be produced the technical problem of harm, a kind of new type natural solid cleaning agent that is used for crusts such as metal, pottery, plank, glass, fiberboard, slabstone, glass are cleaned decontamination is provided in order to solve existing cleaning spray.
For achieving the above object, the natural solid cleaning agent that the present invention proposes is formed by the raw material configuration of following weight percentage:
Kaolin-6～50%, zeolite powder-4～36%, calcite in powder-7～45%, pumice sand-3～40%, Feldspar Powder-4～55%, diatomite-2～17%, montmorillonite powder-3～22%, talcum powder-4～40%, saponin-1～15%, white carbon black-3～18%, water-0～40%.
Preferred version of the present invention is formed by the configuration of the raw material of following weight percentage:
Kaolin-14%, zeolite powder-10%, calcite in powder-9%, pumice sand-8%, Feldspar Powder-13%, diatomite-4%, montmorillonite powder-7%, talcum powder-11%, saponin-5%, white carbon black-4%, water-15%.
Compare with existing cleaning spray, the present invention has following beneficial effect:
1, the present invention has excellent cleaning effect to crust spots such as metal, pottery, plank, glass, fiberboard, slabstone, glass, can remove various spots such as oil stain, sweat stain, tea stain, fruit stain, milk stain, bloodstain, ink blok, ash stain, dirt stain.
2, raw material of the present invention adopts natural ore powder and plant milk extract, does not contain the chemical industry synthetic, has favorable biological degradability, safety and environmental protection, and natural health, environmentally safe does not have injury to human body.
3, the present invention is easy to use, can directly be applied in the surface of required cleaning thing, adds less water or does not add water, gets final product with foam or the direct wiping of rag, and is easy to use.
4, the present invention makes simply, and only the mark mixed is even by weight with raw material for need, forms with pneumatic press or hydropress compacting and just can.Required equipment is few, and it is little to take up room, and produces easily noiseless and waste water.
5, the present invention mainly adopts natural ore powder and water, adds a small amount of plant milk extract again, and production operation is simple, so cost is cheap, and excellent cost performance is arranged.
6, finished product of the present invention is a solid state, long product lifecycle, and transportation stores easily.
Embodiment
The natural solid cleaning agent that the present invention proposes is formed by the raw material configuration of following weight percentage:
Kaolin-6～50%, zeolite powder-4～36%, calcite in powder-7～45%, pumice sand-3～40%, Feldspar Powder-4～55%, diatomite-2～17%, montmorillonite powder-3～22%, talcum powder-4～40%, saponin-1～15%, white carbon black-3～18%, water-0～40%.
Preferred version of the present invention is formed by the configuration of the raw material of following weight percentage:
Kaolin-14%, zeolite powder-10%, calcite in powder-9%, pumice sand-8%, Feldspar Powder-13%, diatomite-4%, montmorillonite powder-7%, talcum powder-11%, saponin-5%, white carbon black-4%, water-15%.
Wherein each component has following characteristic:
1, kaolin is a kind of important nonmetallic minerals, with mica, quartz, lime carbonate and be called four big nonmetalliferous ores.Mainly by forming less than kaolinite bunch mineral (kaolinite, dickite, nacrite, halloysite etc.) such as the small sheet of 2 microns, tubulose, lamination shapes, the ideal chemical formula is AL to kaolin
2O
3-2SiO
2-2H
2O, its essential mineral composition is kaolinite and halloysite, except that kaolinite bunch mineral, also has other mineral associations such as montmorillonite, illite, agalmatolite, quartz and feldspar.Contain a large amount of AL in the kaolinic chemical ingredients
2O
3, SiO
2With a spot of Fe
2O
3, TiO
2And the K of trace
2O, Na
2O, CaO and MgO etc.Kaolin have whiteness height, soft, the easy dispersion suspension of matter in water, good plasticity-and high cohesiveness, excellent electric insulation performance; Have good antiacid dissolubility, very low cation exchange capacity, physico-chemical property such as resistivity against fire preferably.
The kaolin that the present invention uses can be calcined kaolin not, also can be calcined kaolin.Kaolin need be through selecting, through mechanical workout and chemical treatment, to remove detrimental impurity such as wherein quartz, feldspar, mica, iron, titanium mineral.2, zeolite powder is to be pulverized by natural zeolite ore to form, and the general chemical formula of zeolite is: AmBpO
2PnH
2O, structural formula are A (x/q) [(AlO
2) * (SiO
2) y] n (H
2O) wherein: A is positively charged ions such as Ca, Na, K, Ba, Sr, and B is Al and Si, and p is the cationic compound valency, m is the positively charged ion number, and n is a water molecule number, and x is the Al atomicity, y is the Si atomicity, (y/x) usually between 1～5, (x+y) is tetrahedral number in the unit cell.Zeolite is the manosil AS mineral of a kind of aqueous basic metal or alkaline-earth metal.Be divided into frame shape, sheet, fibrous and unfiled four kinds by the zeolite group mineral feature, be divided into one dimension, two dimension, three-dimensional system by the pore canal system feature.Any zeolite all is made up of silicon-oxy tetrahedron and aluminum-oxygen tetrahedron.Tetrahedron can only link to each other with the summit, a promptly shared Sauerstoffatom, and can not " limit " or " face " link to each other.Aluminum-oxygen tetrahedron itself can not link to each other, and has a silicon-oxy tetrahedron therebetween at least.And silicon-oxy tetrahedron can directly link to each other.Silicon in the silicon-oxy tetrahedron can be constituted aluminum-oxygen tetrahedron by the aluminium atomic substitutions.But the aluminium atom is tervalent, so in aluminum-oxygen tetrahedron, have the electricity price of a Sauerstoffatom not obtain neutralization, beautiful generation charge unbalance makes whole aluminum-oxygen tetrahedron electronegative.In order to keep neutral, must there be the ion of positively charged to offset, generally be to compensate, as Na, Ca and Sr, Ba, metal ions such as K, Mg by basic metal and alkaline-earth metal ions.Because zeolite has unique internal structure and crystal chemistry character, so zeolite has performances such as adsorptivity, ion exchangeable, catalysis and acidproof heat-proof.
Zeolite powder of the present invention can be selected any in using natural clinoptilolite, euthalite, scolecite, heulandite, natrolite, the mordenite for use.
3, calcite in powder is pulverized by calcite and is formed, and calcite is a kind of calcium carbonate mineral, is the most important lithogenesis ore of earth's crust English name: calcite, belongs to becoming rock, carbonate minerals, chemical ingredients: CaCO
3, often contain isomorphism surrogates such as Mn, Fe, Zn, Mg, Pb, Sr, Ba, Co, TR, trigonal system-Rc; Rhombohedron structure cell: arh=0.637nm, α=46 ° 07 '; Z=2; If convert six sides (dual body-centered) grid to, then: ah=0.499nm, ch=1.706nm; Z=6.The crystal shape of calcite is varied, and their aggregate can be the crystal of cluster bunch, also can be granular, block, fibrous, stalactitic, earthy or the like.Knock calcite and can obtain a lot of square fragments, so the name calcite.
4, pumice sand is to be pulverized by float stone to form, and float stone claims pumice or foam again, and unit weight little (0.3-0.4) is a kind of porous, the acid volcano of light-weight glassiness extrusive rock, and its composition is equivalent to ryolite.Also can be referred to as volcanics, saying that volcanics is definite can be divided into plutonite, hypabyssal rock and extrusive rock, and foam herein is because the glassy lava of the porosity that fused magma forms with the volcanic eruption condensation, and its pore volume accounts for more than 50% of rock volume.Float stone surface irregularity, particle unit weight are 450kg/m
3, loose volume weight is 250kg/m
3About, the natural pumice porosity is 71.8-81%, water-intake rate is 50-60%., light weight many, unit weight because of hole less than 1 gram/cube li, can bubble through the water column and gain the name.Its feature is light weight, intensity height, acid and alkali-resistance, corrosion-resistant, and pollution-free, "dead" etc., be that ideal is natural, green, the product of environmental protection.
5, Feldspar Powder is to be pulverized by feldspar to form, and feldspar is the aluminium silicate mineral of basic metal such as potassium, sodium, calcium, barium or alkaline-earth metal, and crystalline structure belongs to frame shape structure.Its major ingredient is SiO
2, Al
2O
3, K
2O, Na
2O, CaO etc.Feldspar family mineral distribute the widest in the earth's crust, account for 50% of earth's crust total amount weight.They are a kind of ubiquitous rocks, wherein 60% compose and to exist in the magma, and 30% is distributed in the metamorphosed rock, and 10% to be present in sedimentogeneous rock mainly be in the petroclastic rock, but only when suitable enrichment feldspar just may become industrial mineral.
Feldspar Powder of the present invention can be selected any in albite, lime feldspar, celsian-felspar, the potassium felspar sand for use.
6, diatomite is a kind of siliceous rock, is that the dead later silicate remains of unicellular algae of diatom form, mainly by unbodied SiO
2Form, and contain small amount of Fe
2O
3, CaO, MgO, Al
2O
3And organic impurity.It is light yellow or light grey that diatomite is usually, and matter is soft, and porous and light has characteristics such as porosity is big, absorptivity is strong, chemical property is stable, wear-resisting, heat-resisting.
7, montmorillonite powder is to be pulverized by montmorillonite to form, and montmorillonite is the mineral that are made of the superfine hydrous alumino silicates of particle, and they are generally bulk or earthy.The montmorillonite crystal belongs to monoclinic moisture laminate structure silicate minerals.Title derives from the Montmorillon of the place of production France that at first finds.The montmorillonite particle is tiny, and about 0.2～1 micron, tool colloid dispersing characteristic all is bulk or earthy aggregate output usually.Chemical structure is: Ex (H
2O)
4{ (Al
2-x, Mgx)
2[(Si, Al)
4O
10] (OH)
2, E is the interlayer exchangeable cation in the following formula, is mainly Na
+, Ca
2+, next has K
+, Li
+Deng.X is the layer charge number of E as monovalent cation time unit chemical formula, generally between 0.2～0.6.Therefore montmorillonite has very strong adsorptive power and cation exchange property.
8, talcum powder is to be formed through pulverizing, pickling, washing, drying by talcum, and the talcum main component is the aqueous Magnesium Silicate q-agent of talcum, and molecular formula is Mg
3[Si
4O
10] (OH)
2Talcum belongs to oblique system.Crystal is false six sides or rhombohedral sheet, and is accidental.Be generally fine and close bulk, foliated lamellar, radial, fibrous agrregate.Water white transparency or white, but present light green, pale yellow, shallow palm fibre even light red because of containing a spot of impurity; Be pearliness on the cleavage surface.Hardness 1, proportion 2.7～2.8.Good physics, chemical propertys such as talcum powder has oilness, anti-sticks, helps that stream, resistivity against fire, resistance to acid, insulativity, fusing point height, chemical torpescence, opacifying power are good, softness, good luster, adsorptive power are strong.
Talcum powder of the present invention can be selected the talcum powder of medicine-food grade (YS) for use, also can select talcum powder in the cosmetics-stage (HZ) for use, and forms through selected, purification, pulverizing, drying, has nontoxic, tasteless, the strong characteristics of slickness.
9, saponin is a Saponin/TSM, claims the alkali soap body again, saponin, Saponin/TSM or saponin.Glycoside a kind of.Form by sapogenin and sugar, uronic acid or other organic acids.Being present in botanic is the general name of the glycoside of aglucon with the polycyclic compound.Aglucon is called sapogenin, the composition D-glucose normally of sugar, and the D-semi-lactosi, L-arabinose, but also have with methylpentose and furfural acid etc. as sugared composition.Most of Saponin/TSM are amorphous powders, and the Diluted Alcohol of water soluble methyl alcohol, heat is insoluble to other organic solvents.The aqueous solution has the generation of continuing foamy character, and demonstrates the character of protective colloid.Can be used for as washing composition, emulsifying agent, whipping agent.
The present invention is that saponin can be selected Chinese honey locust saponin(e or sapindoside for use, and its saponin content reaches more than 70%.
10, white carbon black is the general name of white powder X-ray amorphous silicic acid and silicate product, mainly is meant precipitated silica, aerosil, superfine silicon dioxide gel and aerogel, also comprises Powdered synthetic aluminium silicate and Calucium Silicate powder etc.White carbon black is a porous material, and it forms available SiO
2NH
2O represents, wherein nH
2O is that the form with surface hydroxyl exists.Can be dissolved in caustic alkali and hydrofluoric acid, water insoluble, solvent and acid (except for hydrofluoric acid).High temperature resistant, do not fire, tasteless, do not have and to smell, to have good absorption and rub resistance.
The present invention will be further described below in conjunction with specific embodiment.According to prescription of the present invention, dispose the material of the preparation new type natural solid cleaning agent of following different ratios.
Embodiment 1: raw material weight mark prescription:
Kaolin-9%, zeolite powder-22%, calcite in powder-7%, pumice sand-4%, Feldspar Powder-17%, diatomite-2%, montmorillonite powder-16%, talcum powder-4%, saponin-2%, white carbon black-7%, water-10%.
Embodiment 2: raw material weight mark prescription:
Kaolin-7%, zeolite powder-4%, calcite in powder-7%, pumice sand-3%, Feldspar Powder-19%, diatomite-6%, montmorillonite powder-3%, talcum powder-5%, saponin-3%, white carbon black-3%, water-40%.
Embodiment 3: raw material weight mark prescription:
Kaolin-45%, zeolite powder-4%, calcite in powder-7%, pumice sand-4%, Feldspar Powder-4%, diatomite-17%, montmorillonite powder-3%, talcum powder-7%, saponin-5%, white carbon black-4%, water-0%.
Embodiment 4: raw material weight mark prescription:
Kaolin-6%, zeolite powder-4%, calcite in powder-7%, pumice sand-3%, Feldspar Powder-4%, diatomite-2%, montmorillonite powder-21%, talcum powder-4%, saponin-15%, white carbon black-17%, water-17%.
Embodiment 5: raw material weight mark prescription:
Kaolin-20%, zeolite powder-12%, calcite in powder-11%, pumice sand-5%, Feldspar Powder-16%, diatomite-2%, montmorillonite powder-3%, talcum powder-7%, saponin-4%, white carbon black-5%, water-15%.
Embodiment 6: raw material weight mark prescription:
Kaolin-6%, zeolite powder-5%, calcite in powder-45%, pumice sand-4%, Feldspar Powder-4%, diatomite-2%, montmorillonite powder-3%, talcum powder-6%, saponin-3%, white carbon black-4%, water-18%.
Embodiment 7: raw material weight mark prescription:
Kaolin-6%, zeolite powder-9%, calcite in powder-7%, pumice sand-40%, Feldspar Powder-5%, diatomite-3%, montmorillonite powder-5%, talcum powder-5%, saponin-5%, white carbon black-5%, water-10%.
Embodiment 8: raw material weight mark prescription:
Kaolin-7%, zeolite powder-5%, calcite in powder-8%, pumice sand-3%, Feldspar Powder-11%, diatomite-5%, montmorillonite powder-3%, talcum powder-40%, saponin-4%, white carbon black-6%, water-8%.
Embodiment 9: raw material weight mark prescription:
Kaolin-50%, zeolite powder-4%, calcite in powder-7%, pumice sand-3%, Feldspar Powder-4%, diatomite-2%, montmorillonite powder-22%, talcum powder-4%, saponin-1%, white carbon black-3%, water-0%.
Embodiment 10: raw material weight mark prescription:
Kaolin-11%, zeolite powder-6%, calcite in powder-9%, pumice sand-3%, Feldspar Powder-4%, diatomite-12%, montmorillonite powder-5%, talcum powder-12%, saponin-15%, white carbon black-18%, water-5%.
Embodiment 11: raw material weight mark prescription:
Kaolin-15%, zeolite powder-36%, calcite in powder-12%, pumice sand-6%, Feldspar Powder-7%, diatomite-5%, montmorillonite powder-6%, talcum powder-4%, saponin-2%, white carbon black-3%, water-4%.
Embodiment 12: raw material weight mark prescription:
Kaolin-7%, zeolite powder-5%, calcite in powder-7%, pumice sand-10%, Feldspar Powder-55%, diatomite-2%, montmorillonite powder-3.5%, talcum powder-4%, saponin-1.5%, white carbon black-3%, water-2%.
Preparation of the present invention, the fineness of the kaolin of selecting for use, zeolite powder, calcite in powder, pumice sand, Feldspar Powder, diatomite, montmorillonite powder, talcum powder and white carbon black can be 800 orders～4000 orders, the fineness of saponin can be 200 orders～600 orders.Water is the municipal tap water.
According to the present invention is proportioning, with each component uniform mixing; According to desired shape and weight number, make mould; Mixed raw materials is put into mould, suppress beautiful one-tenth solid state with pneumatic press or hydropress and get final product.
Raw material of the present invention all adopts natural ore powder and plant milk extract, safety and environmental protection, and environmentally safe does not have injury to human body.Make simply, noiseless and waste water, cost is low.Easy to use, transportation stores easily.
Claims (7)
1. natural solid cleaning agent, it is characterized in that, described material is formed by the raw material configuration of following weight percentage: kaolin-6～50%, zeolite powder-4～36%, calcite in powder-7～45%, pumice sand-3～40%, Feldspar Powder-4～55%, diatomite-2～17%, montmorillonite powder-3～22%, talcum powder-4～40%, saponin-1～15%, white carbon black-3～18%, water-0～40%.
2. natural solid cleaning agent according to claim 1, it is characterized in that, the fineness of described kaolin, zeolite powder, calcite in powder, pumice sand, Feldspar Powder, diatomite, montmorillonite powder, talcum powder and white carbon black is 800 orders～4000 orders, and the fineness of saponin is 200 orders～600 orders.
3. natural solid cleaning agent according to claim 1 is characterized in that, described kaolin is not calcined kaolin or the calcined kaolin of having removed quartz, feldspar, mica, iron, titanium mineral.
4. natural solid cleaning agent according to claim 1 is characterized in that, described zeolite powder is a kind of in using natural clinoptilolite, euthalite, scolecite, heulandite, natrolite, the mordenite.
5. natural solid cleaning agent according to claim 1 is characterized in that, described Feldspar Powder is a kind of in albite, lime feldspar, celsian-felspar, the potassium felspar sand.
6. natural solid cleaning agent according to claim 1 is characterized in that described talcum powder is the talcum powder of medicine-food grade or the talcum powder of cosmetics-stage.
7. as claim 1 natural solid cleaning agent according to claim 1, it is characterized in that described saponin is Chinese honey locust saponin(e or sapindoside, its saponin content reaches more than 70%.
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|---|---|---|---|
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