CN105002000B - A kind of cleanser and its production and use - Google Patents
A kind of cleanser and its production and use Download PDFInfo
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- CN105002000B CN105002000B CN201510386029.2A CN201510386029A CN105002000B CN 105002000 B CN105002000 B CN 105002000B CN 201510386029 A CN201510386029 A CN 201510386029A CN 105002000 B CN105002000 B CN 105002000B
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- cleanser
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- sodium
- illite
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Abstract
The invention provides a kind of cleanser and its production and use, the cleanser is mainly prepared by base-material and auxiliary material, and the base-material is illite powder, and the auxiliary material includes surfactant, alkaline matter and emulsifying agent.Specifically, the cleanser is mainly prepared by mass fraction by the following raw material:65~80 parts of illite powder, 1~3 part of surfactant, 5~10 parts of alkaline matter, 5~12 parts of emulsifying agent.The adsorption capacity of heretofore described cleanser and exchange views relatively strong ability, good combination property and the cleanser base-material cost it is cheap, green, gently non-stimulated to human body skin, using the cleanser, tool face shaving will not be caused to scratch.
Description
Technical field
The invention belongs to articles for washing technical field, more particularly to a kind of cleanser and its production and use.
Background technology
In daily life, the apparatus such as kitchen, bathroom, plant equipment, labware, after long-time use, surface warp
It can often deposit or adhere to some oil stains and dirt, use the common more difficult removal of liquid articles for washing.Cleanser is a kind of washing
The stronger flour of ability, it can effectively remove the heavy oil stain under above-mentioned various operating mode occasions.
At present, using various natural stone-powders and its compound as the cleanser of main component, what is utilized is the suction of powder
Echo and exchange views function, and combine the common decontaminations such as alkaline matter such as sodium carbonate and emulsifying agent such as soap powder.Such as CN 1733880A
Disclose a kind of for entering to the surface and oil contaminant and dirt of pottery, enamelware, glassware, plastic products and aluminum products
The high-efficiency cleaning powder that row is removed and used, the cleanser is using flux calcination diatomite as major ingredient, with linear alkyl benzene sulfonic acid
Sodium, sodium carbonate or soap powder, sodium dichloro cyanurate and essence are that auxiliary material mixed preparing forms.CN 102911798A are disclosed
A kind of nontoxic natural cleaning powder, the cleanser are formed by the raw material configuration of following ratio of weight and number:20 parts of bentonite
~30 parts;1 part~3 parts of sodium dichloro cyanurate;5 parts~12 parts of surfactant;2 parts~5 parts of sodium carbonate;Polyoxyethylene-poly-
0.5 part~2 parts of oxypropylene copolymer;0.1 part~0.5 part of defoamer;50 parts of flavoring essence.CN 104087451A disclose one
The method that kind prepares cleanser using artificial synthesized zeolite as base-material, the cleanser are made up of following percentage by weight:60~
90% artificial synthesized zeolite, 1~10% sodium metasilicate, 1~3% sodium alkyl benzene sulfonate or lauryl sodium sulfate, 5~
20% soap powder and 0.1~0.3% spices.But these cleansers are because powder constituents are comparatively single, in reality
In use, lay particular stress on absorption, viscosity is larger, exchanges views that scarce capacity, combination property are poor, and dirt-removing power need further to improve.
The content of the invention
In view of the shortcomings of the prior art, it is an object of the invention to provide a kind of cleanser and its production and use,
The absorption of the cleanser and strong, the good combination property that exchanges views ability, and the base-material cost of the cleanser is cheap, green ring
Protect, it is gentle to human body skin, non-stimulated.
To use following technical scheme up to this purpose, the present invention:
On the one hand, the invention provides a kind of cleanser, it is mainly prepared by base-material and auxiliary material, and the base-material is for she
Sharp stone flour body, the auxiliary material include surfactant, alkaline matter and emulsifying agent.
Cleanser provided by the invention is using the illite powder after the processing of natural illites mineral as base-material, therefore its cost is low
It is honest and clean, green, gentle to human body skin, nonirritant effect.
As preferable technical scheme, cleanser of the present invention is mainly prepared by mass fraction by the following raw material:
Cleanser provided by the invention is mainly prepared by mass fraction by the following raw material:65~80 parts of illite powder
Body, such as 66 parts, 67 parts, 68 parts, 69 parts, 70 parts, 72 parts, 75 parts, 77 parts or 79 parts;5~12 parts of emulsifying agent, such as 6 parts, 7
Part, 8 parts, 9 parts, 10 parts or 11 parts etc.;5~10 parts of alkaline matter, such as 6 parts, 7 parts, 8 parts, 9 parts or 9.5 parts;1~3 part
Surfactant, such as 1 part, 1.5 parts, 2 parts, 2.2 parts or 3 parts.
As preferred technical scheme, the cleanser is mainly prepared by mass fraction by the following raw material:
The mass fraction of the builder be 1.5~3 parts, such as 1.6 parts, 1.7 parts, 1.9 parts, 2 parts, 2.2 parts, 2.5 parts or
2.8 parts etc.;The mass fraction of the bactericide is 1 part;The mass fraction of the defoamer is 0.5~1.5 part, such as 0.6 part,
0.7 part, 0.8 part, 0.9 part, 1 part, 1.2 parts or 1.4 parts etc..
The cleanser also includes flavouring agent, and the mass fraction of the flavouring agent is 2~5 parts, such as containing 2 parts, 2.5 parts, 3
Part, 3.5 parts, 4 parts, 4.5 parts or 5 parts etc..
Preferably, the flavouring agent is flavoring essence.
The granularity of the illite powder is 70~120 mesh, such as 70 mesh, 80 mesh, 90 mesh, 100 mesh, 110 mesh or 120 mesh
Deng.
Preferably, the illite powder wears into powdery by natural illites mineral, then dries, re-sieving is made.Institute
The temperature for stating drying is 80~120 DEG C, such as 85 DEG C, 90 DEG C, 95 DEG C, 100 DEG C, 105 DEG C, 110 DEG C or 115 DEG C.
After natural illites mineral grinding, sieved, and it is 70~120 mesh strictly to control the granularity of illite powder,
It can ensure that the powder granularity after screening is uniform, will not going out because of bulky grain powder so as to ensure the cleanser when in use
Tool face shaving is now caused to scratch.
The illite powder is contained by weight/mass percentage composition:35~45% illite and 50~60% free stone
English, such as percentage composition contains 36%, 37%, 38%, 39%, 40%, 41%, 42%, 43% or 44% Erie by weight
Stone;Containing 51%, 52%, 53%, 54%, 55%, 56%, 57%, 58% or 59% etc. Free quartz, the quality percentage
Content is on the basis of the quality of illite powder.
Illite powder specific-surface area detection is big, and adsorption capacity is strong;Meanwhile in illite powder association Free quartz hardness
Height, therefore, it exchanges views ability protrusion.So cleanser provided by the invention has absorption concurrently and exchanges views ability, combination property compared with
It is good.
The emulsifying agent is soap powder.
Preferably, the alkaline matter is sodium carbonate and/or sodium acid carbonate.
Preferably, the surfactant is sodium alkyl sulfonate and/or lauryl sodium sulfate.
Preferably, the builder is sodium citrate.The builder can also select sodium tripolyphosphate, but for environmental protection
Consider that present articles for washing uses phosphorus-free adjuvant more, therefore select sodium citrate as builder.
Preferably, the bactericide is sodium dichloro cyanurate.
Preferably, the defoamer is polyoxyethylene polyoxy propyl alcohol amidogen ether, polypropylene glycerol aether or polyoxypropylene polyoxy
Any of Ethylene Glycol ether or at least two mixture.
On the other hand, the invention provides a kind of preparation method of the cleanser, methods described to be:By going for formula ratio
Dirty powder raw material is well mixed, you can obtains cleanser.
As preferable technical scheme, the preparation method of the cleanser is:The illite powder of formula ratio, surface are lived
Property agent, alkaline matter, emulsifying agent, water and defoamer be well mixed, then add formula ratio builder, bactericide and flavouring agent
Further stir, finally give cleanser.
Present invention also offers the purposes of cleanser as described above, and it is used to remove ceramics, metal, glass or bathroom surface
Spot.
Compared with prior art, beneficial effects of the present invention are:
1st, cleanser adsorption capacity provided by the invention and relatively strong, the good combination property that exchanges views ability.
2nd, for the powder after cleanser provided by the invention is processed using natural illites mineral as main component, cost is cheap,
It is green, gentle to human body skin, nonirritant effect.
3rd, cleanser provided by the invention when in use, will not cause tool face shaving because of the appearance of bulky grain powder
Scratch.
Embodiment
Technical scheme is further illustrated below by embodiment.
Embodiment 1
A kind of cleanser, it is mainly prepared by mass fraction by the following raw material:
The granularity of the illite powder is 70~120 mesh.
It is formulated as described above, illite powder, soap powder, sodium carbonate and sodium alkyl sulfonate is well mixed and obtain decontamination
Powder.
Embodiment 2
A kind of cleanser, it is mainly prepared by mass fraction by the following raw material:
The granularity of the illite powder is 70~120 mesh.
The preparation method of the cleanser is same as Example 1.
Embodiment 3
A kind of cleanser, it is mainly prepared by mass fraction by the following raw material:
The granularity of the illite powder is 70~120 mesh.
The preparation method of the cleanser is same as Example 1.
Embodiment 4
A kind of cleanser, mainly it is prepared by mass fraction by the following raw material:
The granularity of the illite powder is 70~120 mesh.
The preparation method of the cleanser is as follows:
It is formulated, illite powder, sodium alkyl sulfonate, soap powder, sodium carbonate, water and defoamer is mixed equal as described above
It is even, then add sodium citrate, sodium dichloro cyanurate and flavoring essence and further stir, finally give cleanser.
Embodiment 5
A kind of cleanser, mainly it is prepared by mass fraction by the following raw material:
The granularity of the illite powder is 70~120 mesh.
The preparation method of the cleanser is:
It is formulated as described above, by illite powder, lauryl sodium sulfate, soap powder, sodium acid carbonate, water and defoamer
It is well mixed, then add sodium citrate, sodium dichloro cyanurate and flavoring essence and further stir, finally give decontamination
Powder.
Embodiment 6
A kind of cleanser, it is mainly prepared by mass fraction by the following raw material:
The granularity of the illite powder is 70~120 mesh.
The preparation method of the cleanser is as follows:
It is formulated as described above, by illite powder, lauryl sodium sulfate, soap powder, sodium acid carbonate and sodium carbonate, water
It is well mixed with defoamer, then adds sodium citrate, sodium dichloro cyanurate and flavoring essence and further stir, finally
Obtain cleanser.
Embodiment 7
A kind of cleanser, it is mainly prepared by mass fraction by the following raw material:
The granularity of the illite powder is 70~120 mesh.
Be formulated as described above, by illite powder, lauryl sodium sulfate and sodium alkyl sulfonate, soap powder, sodium carbonate,
Water and defoamer are well mixed, and are then added sodium citrate, sodium dichloro cyanurate and flavoring essence and are further stirred, most
Cleanser is obtained eventually.
Comparative example 1
The formula of comparative example 1 and the preparation method of cleanser are same as Example 6, and unique difference is:Use diatom
Native powder replaces illite powder.
Comparative example 2
The formula of comparative example 2 and the preparation method of cleanser are same as Example 6, and unique difference is:Use zeolite
Powder replaces illite powder.
Comparative example 3
The formula of comparative example 3 and the preparation method of cleanser are same as Example 6, and unique difference is:Use swelling
Native powder replaces illite powder.
Performance test
Performance test is carried out to cleanser made from embodiment 1~7 and comparative example 1~3, method of testing is as follows:
1. exchange views aptitude tests method:By cleanser made from embodiment 1~7 and comparative example 1~3,120g and 80g are respectively taken
Water is well mixed in 300ml beaker, and homemade 10 igelite agitating paddles are then respectively implanted mixed slurry
Among, the agitating paddle is twayblade (manufacturing process:One section of thin-walled pvc tube material is taken, in the axial direction in tube wall
On the long 60mm of clip × wide 10mm successively 10 thin slices, polishing deburring is consistent to size, then in the geometry of each thin slice
Centre-drilling hole, then the end of metal puddler is anchored on by nut, metal stirring pole length is 20cm, has been finally constituted
Whole agitating paddle), start motor and keep 500r/min rotating speed at the uniform velocity to stir 30min, stirring takes out agitating paddle after terminating, and cleans
Totally, the quality difference value of agitating paddle before and after stirring is weighed, the loss of weight by agitating paddle is the degree of wear, to judge corresponding cleanser
Exchange views ability.
2. adsorption capacity method of testing:By cleanser made from embodiment 1~7 and comparative example 1~3, respectively 10g is taken to put respectively
In on glass plate, while stirring cleanser with glass bar, while dibutyl phthalate is slowly added dropwise by buret, make
Dirty powder is well mixed with dibutyl phthalate, and when being added to last drop, cleanser bonds with dibutyl phthalate
It is agglomerating, without free drying sample, now by checking the consumption of dibutyl phthalate, to judge the absorption of cleanser
Ability.
3. pH value method of testing:In the test process for the ability of exchanging views, after cleanser is well mixed with water in beaker,
Micro clear liquid is dipped with glass bar to drip on pH test paper, checks after the final color of test paper the standard color card ratio carried with it
It is right, it is determined that the pH value of corresponding cleanser.
4. clean effect method of testing:Range estimation.
5. surface smoothness method of testing:During mill aptitude tests are rubbed with the hands, agitating paddle is taken out in stirring after terminating, and cleaning is dry
Only, the roughness on agitating paddle surface is detected with Portable Surface Roughometer, so that it is determined that its surface smoothness.
Test result is as shown in table 1.
Table 1
As can be seen from Table 1, cleanser provided by the invention is compared to using diatomite in powder, zeolite powder or bentonite in powder as base
The cleanser of material, have and preferably exchange views ability and adsorption capacity, and the close neutrality of its pH value, it is small to skin irritation, go
Dirty effect is more preferable, meanwhile, it is most bright and clean using the cleanser of the present invention, the surface for the article that is processed.
Particular embodiments described above, the purpose of the present invention, technical scheme and beneficial effect are carried out further in detail
Describe in detail it is bright, should be understood that the foregoing is only the present invention specific embodiment, be not intended to limit the invention, it is all
Within the spirit and principles in the present invention, any modification, equivalent substitution and improvements done etc., it should be included in the guarantor of the present invention
Within the scope of shield.
Claims (13)
1. a kind of cleanser, it is mainly prepared by base-material and auxiliary material, wherein, the auxiliary material includes surfactant, alkalescence
Material and emulsifying agent, it is characterised in that the base-material is illite powder;
The cleanser is mainly prepared by mass fraction by the following raw material:
The granularity of the illite powder is 70~120 mesh;The illite powder percentage composition by weight contains:35~45%
Illite and 50~60% Free quartz.
2. cleanser according to claim 1, it is characterised in that the cleanser is by mass fraction mainly by the following raw material
It is prepared:
3. cleanser according to claim 1, it is characterised in that the cleanser also includes flavouring agent, the flavouring agent
Mass fraction be 2~5 parts.
4. cleanser according to claim 3, it is characterised in that the flavouring agent is flavoring essence.
5. cleanser according to claim 1, it is characterised in that the illite powder by natural illites mineral first
Powdery is worn into, is then dried, re-sieving is made.
6. cleanser according to claim 1, it is characterised in that the emulsifying agent is soap powder.
7. cleanser according to claim 1, it is characterised in that the alkaline matter is sodium carbonate and/or sodium acid carbonate.
8. cleanser according to claim 1, it is characterised in that the surfactant is sodium alkyl sulfonate and/or ten
Sodium dialkyl sulfate.
9. cleanser according to claim 2, it is characterised in that the bactericide is sodium dichloro cyanurate.
10. cleanser according to claim 2, it is characterised in that the builder is sodium citrate.
11. cleanser according to claim 2, it is characterised in that the defoamer be polyoxyethylene polyoxy propyl alcohol amidogen ether,
Any of polypropylene glycerol aether or polyoxyethylene polyoxypropylene glycerin ether or at least two mixture.
12. the preparation method of the cleanser described in a kind of one of claim 1-11, it is characterised in that methods described is:It will go
Dirty powder raw material is well mixed by formula ratio, you can obtains cleanser.
13. the purposes of the cleanser described in a kind of one of claim 1-11, it is used to remove ceramics, metal, glass or bathroom
The spot on surface.
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CN107904055A (en) * | 2017-12-06 | 2018-04-13 | 孙中秋 | Kitchen vegetable bowl deoils detergent |
CN108192742A (en) * | 2018-02-08 | 2018-06-22 | 白银金奇化工科技有限公司 | A kind of cleanser and preparation method thereof |
CN113462481A (en) * | 2021-08-16 | 2021-10-01 | 曹云飞 | Biological enzyme multifunctional cleaning powder and preparation method thereof |
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CN1636048A (en) * | 2002-02-21 | 2005-07-06 | 雷克特本克斯尔有限公司 | Hard surface cleaning compositions |
CN1733880A (en) * | 2004-08-03 | 2006-02-15 | 邱宝辰 | Highly effective cleansing powder |
CN101880608A (en) * | 2010-06-28 | 2010-11-10 | 深圳市成为生物科技有限公司 | Natural solid cleaning agent |
CN102911798A (en) * | 2012-11-14 | 2013-02-06 | 沈阳信达信息科技有限公司 | Natural cleanser |
CN104087451A (en) * | 2014-06-06 | 2014-10-08 | 国能神州高科技股份有限公司 | Method of preparing cleaning powder by adopting synthetic zeolite as base material |
-
2015
- 2015-07-03 CN CN201510386029.2A patent/CN105002000B/en not_active Expired - Fee Related
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0139330A2 (en) * | 1983-10-20 | 1985-05-02 | Unilever N.V. | Rinse aid |
CN1636048A (en) * | 2002-02-21 | 2005-07-06 | 雷克特本克斯尔有限公司 | Hard surface cleaning compositions |
CN1733880A (en) * | 2004-08-03 | 2006-02-15 | 邱宝辰 | Highly effective cleansing powder |
CN101880608A (en) * | 2010-06-28 | 2010-11-10 | 深圳市成为生物科技有限公司 | Natural solid cleaning agent |
CN102911798A (en) * | 2012-11-14 | 2013-02-06 | 沈阳信达信息科技有限公司 | Natural cleanser |
CN104087451A (en) * | 2014-06-06 | 2014-10-08 | 国能神州高科技股份有限公司 | Method of preparing cleaning powder by adopting synthetic zeolite as base material |
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