CN103590044A - Metal polishing agent and preparation method thereof - Google Patents

Metal polishing agent and preparation method thereof Download PDF

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Publication number
CN103590044A
CN103590044A CN201310545882.5A CN201310545882A CN103590044A CN 103590044 A CN103590044 A CN 103590044A CN 201310545882 A CN201310545882 A CN 201310545882A CN 103590044 A CN103590044 A CN 103590044A
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acid
metal
metal polish
oleic acid
sodium
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CN103590044B (en
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刘树清
张力
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TIANJIN ZHENPENG CLEANING TECHNOLOGY DEVELOPMENT Co Ltd
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TIANJIN ZHENPENG CLEANING TECHNOLOGY DEVELOPMENT Co Ltd
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Abstract

The invention relates to a metal polishing agent which comprises the following raw materials in percentage by weight: 7%-10% of surfactants, 8%-10% of organic acids, 1.5%-2% of solutizers and the balance of water, wherein the surfactants are fatty alcohol-polyoxyethylene ether sodium sulfate, sodium dodecyl benzene sulfonate and fatty alcohol-polyoxyethylene ether, the organic acids are citric acid and oleic acid, and the solutizers are triethanolamine and sodium hydroxide. The prepared metal polishing agent is suitable for stainless steel tableware and contains organic acids-oleic acid and citric acid which can improve the metal surface activity, the polishing effect and the using effect of the polishing agent.

Description

A kind of metal polish and preparation method thereof
Technical field
The invention belongs to metal processing aid field, especially a kind of metal polish and preparation method thereof.
Background technology
Metal products in use, due to reasons such as oxidation in air, humidity or contact chemical substance and corrosive gasess, cause metal products surface corrosion, adhere to foul greasy dirt situation, in order to increase metal products any surface finish, usually adopt chemical metal detergent or metal polish to process.Metal polish is one important procedure of metallic surface processing, for the chemical substance of metalwork surface finish processing.Be divided into paste and liquid.Paste general types has: white rubbing paste, green polishing composition, red rubbing paste, paste rumbling compound etc.
Liquid metal rumbling compound product generally contains strong acid or phosphoric acid salt, contaminate environment, and cleaning efficiency is low.
Solid metal rubbing paste is with fine grinding sand, aluminum oxide and polishing wet goods mineral substance, and the toothpaste body of making through special processing and emulsify at a high speed, belongs to fine chemical product, with meticulous being as the criterion, does not do multiple granularity.Effect: metallic surface decontamination, polishing, manually polish the effect with metal surface protection.Can be divided into import and domestic two kinds.Imported and famous brand is a lot, and outward appearance is beautiful, but price is very expensive.For high-grade mould, precision instrument or part decontamination, polish.Domestic, metallic surface fine grinding is polished nursing cream, and import main raw material and technique utilize emulsify at a high speed to process the convenient use of toothpaste-like.Due to cheap, various metallic surfaces have been widely used in, decontamination, polish, nurse, because of abrasive sand finer and smoother, be again manual polishing, generally can not leave a trace in metallic surface, can reach again light as new outward appearance, according to bright stock and oxide mass, content, metal is polished cream also clean bright cream and common two kinds of the cream of polishing fast.
According to the retrieval, finding following patent documentation metal polish (CN101532137), is that 2-7% Sodium dodecylbenzene sulfonate, 1.5-5% sodium oleate, 8-15% ethanol, 4-8% emulsifying agent NP-10,5-8% emulsifying agent TW-80,0.2-0.8% oleic acid triglycolyl amine, 1-4% Oleum Cocois alkylol amide phosphate ester salt, 1-4% defoamer, 0.5-2.5% sodium phosphate, 1-3% Trisodium Citrate, 0.3-1.2% halfcystine LBGAS, 0.35-1% potassium hydroxide and the excess water by weight percent is prepared into.
Summary of the invention
The object of the invention is to overcome the deficiencies in the prior art, provide a kind of cleaning performance good, polishing efficiency is high, metal polish free from environmental pollution, cost is low and preparation method thereof.
The technical scheme that the present invention realizes object is as follows:
, become and weight percent as follows
Figure BDA0000409175970000011
Figure BDA0000409175970000021
Described tensio-active agent is polyoxyethylenated alcohol sodium sulfate, Sodium dodecylbenzene sulfonate and alkylphenol polyoxyethylene, and organic acid is citric acid and oleic acid, and solubilizing agent is trolamine and sodium hydroxide;
Or described tensio-active agent is that fatty alcohol-polyoxyethylene ether, dodecyl phenenyl sulfate and Sodium dodecylbenzene sulfonate, organic acid are that oleic acid, solubilizing agent are trolamine and sodium hydroxide;
Or described tensio-active agent is lauric acid amide of ethanol, fatty alcohol-polyoxyethylene ether and Sodium dodecylbenzene sulfonate, organic acid is citric acid and oleic acid, and solubilizing agent is trolamine and sodium hydroxide.
And the moiety of described metal polish and weight percent are:
Figure BDA0000409175970000022
And the moiety of described metal polish and weight percent are:
Figure BDA0000409175970000023
And, the consisting of of described metal polish:
Figure BDA0000409175970000024
Figure BDA0000409175970000031
Advantage of the present invention and beneficial effect are as follows:
1, the metal polish that prepared by the present invention is applicable to stainless steel tableware, contains organic acid oleic acid and citric acid, and oleic acid and citric acid can increase the activity of metallic surface, improves polishing effect, increases the result of use of this rumbling compound.
2, the metal polish that prepared by the present invention contains kinds of surface promoting agent, is that tensio-active agent of different nature carries out composite, obtains having the rumbling compound that functional effect is good.
3, the metal polish that prepared by the present invention can be used for shaking polishing, can be used for again tumbling, and cost is low, and making water is base solvent, environmental protection, and free from environmental pollution, preparation method is simple.
Embodiment
Below in conjunction with embodiment, the present invention is further described, and following embodiment is illustrative, is not determinate, can not limit protection scope of the present invention with following embodiment.
A cream, by tensio-active agent, solubilizing agent, organic acid, mineral alkali and water form, and the shared weight percent of various components is:
Figure BDA0000409175970000032
Concrete recommendation shown in following 3 embodiment of composition.
Embodiment 1:
, by polyoxyethylenated alcohol sodium sulfate, Sodium dodecylbenzene sulfonate, the acid of alkyl acid polyoxyethylene, citric acid, oleic acid and trolamine and sodium hydroxide, and water, add in retort and be uniformly mixed respectively.
The weight percent that various acid is shared:
Figure BDA0000409175970000033
Manufacture the preparation method of above-mentioned medal polish cream, water is added and in retort, dissolves citric acid and will after solid materials CL, add polyoxyethylenated alcohol sodium sulfate, Sodium dodecylbenzene sulfonate, alkyl acid Soxylat A 25-7 and trolamine, after add oleic acid and stir, aqueous sodium hydroxide solution, regulates ph=5, obtains.
Embodiment 2:
, by fatty alcohol-polyoxyethylene ether, dodecyl phenenyl sulfate, Sodium dodecylbenzene sulfonate, trolamine, oleic acid, sodium hydroxide and water, the weight percent that each component is shared:
Figure BDA0000409175970000041
Manufacture the preparation method of above-mentioned medal polish cream: after water is added, after dropping into, benzoic solid materials all dissolves, after add fatty alcohol-polyoxyethylene ether, dodecyl phenenyl sulfate, Sodium dodecylbenzene sulfonate and trolamine, after add oleic acid to stir, aqueous sodium hydroxide solution is progressively added to (regulating ph=5.5), obtain.
Embodiment 3:
A kind of metal polish, by lauric acid amide of ethanol, fatty alcohol-polyoxyethylene ether, Sodium dodecylbenzene sulfonate and trolamine, citric acid, oleic acid and sodium hydroxide and water, add respectively and in retort, be uniformly mixed the shared weight percent of each component:
Manufacture the preparation method of above-mentioned medal polish cream: after water is added, citric acid adds lauric acid amide of ethanol after adding rear whole dissolving, fatty alcohol-polyoxyethylene ether, Sodium dodecylbenzene sulfonate and trolamine, after add oleic acid stirring and evenly mixing, aqueous sodium hydroxide solution is progressively added to (regulating ph=5), obtain.
Above-mentioned rumbling compound is for the polishing of stainless steel tableware.
The present invention compares the experimental data of acquisition with the composition of the disclosed embodiment 1 of patent documentation CN1017128A.
Polishing fluid Embodiment 1 Embodiment 2 Contrast sample (CN1017128A)
Add concentration 3‰ 3‰ 3‰
The temperature of vibropolish Normal temperature Normal temperature Normal temperature
The average polished time 12-15 minute 8-10 minute 15-20 minute
Cost A 90%A 120%A
Color and luster Cold light Cold light White light

Claims (4)

1. a metal polish, is characterized in that: become and weight percent as follows
Figure FDA0000409175960000011
Described tensio-active agent is polyoxyethylenated alcohol sodium sulfate, Sodium dodecylbenzene sulfonate and alkylphenol polyoxyethylene, and organic acid is citric acid and oleic acid, and solubilizing agent is trolamine and sodium hydroxide;
Or described tensio-active agent is that fatty alcohol-polyoxyethylene ether, dodecyl phenenyl sulfate and Sodium dodecylbenzene sulfonate, organic acid are that oleic acid, solubilizing agent are trolamine and sodium hydroxide;
Or described tensio-active agent is lauric acid amide of ethanol, fatty alcohol-polyoxyethylene ether and Sodium dodecylbenzene sulfonate, organic acid is citric acid and oleic acid, and solubilizing agent is trolamine and sodium hydroxide.
2. metal polish according to claim 1, is characterized in that: the moiety of described metal polish and weight percent are:
Figure FDA0000409175960000012
3. metal polish according to claim 1, is characterized in that: the moiety of described metal polish and weight percent are:
Figure FDA0000409175960000013
4. metal polish according to claim 1, is characterized in that: the consisting of of described metal polish:
Figure FDA0000409175960000021
CN201310545882.5A 2013-11-06 2013-11-06 A kind of metal polish Active CN103590044B (en)

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Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104450246A (en) * 2014-11-13 2015-03-25 王爱国 Kitchen cleaning agent
CN104947114A (en) * 2014-10-13 2015-09-30 庆云昊天焊材科技有限公司 Cold-water copper-plated welding wire polishing solution
CN105239073A (en) * 2015-11-10 2016-01-13 荆门市拓达科技有限公司 Polishing solution for metal polishing
CN105463466A (en) * 2015-11-22 2016-04-06 全椒县志宏机电设备设计有限公司 Polishing liquid for stainless steel mechanical equipment and preparing method of polishing liquid
CN105671555A (en) * 2016-04-10 2016-06-15 李金平 Metal surface polishing agent
CN105778863A (en) * 2016-04-20 2016-07-20 廊坊市北方天宇机电技术有限公司 Grinding fluid for aluminum wheel barreling-fishing machining and preparation method thereof
CN105970230A (en) * 2016-07-10 2016-09-28 李金平 Environment-friendly chemical polishing solution
CN106435592A (en) * 2016-08-17 2017-02-22 安徽红桥金属制造有限公司 Chemical polishing agent used for stainless steel springs, and preparation method thereof
CN106637218A (en) * 2016-12-24 2017-05-10 李月巧 Polishing agent and preparation method thereof
CN106757040A (en) * 2016-12-01 2017-05-31 三达奥克化学股份有限公司 Powder metallurgical stainless steel precision workpiece light decorations process agent and production method
CN106987841A (en) * 2017-04-28 2017-07-28 舒城久联精密机械有限公司 Apply the stainless steel polishing agent in precision optical machinery process
CN107699141A (en) * 2017-11-27 2018-02-16 苏州市宽道模具机械有限公司 A kind of polishing agent and preparation method thereof
CN109023390A (en) * 2018-09-28 2018-12-18 天津圳鹏清洗技术开发有限公司 Medical metal cleaning polishing agent and preparation method thereof
CN109096925A (en) * 2018-07-02 2018-12-28 湖州师范学院 A kind of environmentally protective scratch resistance aqua type lapping liquid and preparation method thereof
WO2019006668A1 (en) * 2017-07-04 2019-01-10 深圳市恒兆智科技有限公司 Polishing agent, copper part and polishing process therefor
CN111015376A (en) * 2019-12-18 2020-04-17 安徽省潜山县志发机电配件有限公司 Surface polishing process for electromechanical equipment
CN115466574A (en) * 2022-09-21 2022-12-13 深圳市东方亮化学材料有限公司 Processing method of double-component metal grinding and polishing paste
CN116286202A (en) * 2022-09-07 2023-06-23 山东宙雨消防科技股份有限公司 Manufacturing method of environment-friendly cleaning fluid

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CN101532137A (en) * 2009-04-21 2009-09-16 刘丽 Metal polishing agent
CN101864247A (en) * 2010-07-20 2010-10-20 南京航空航天大学 Abrasive material-free polishing fluid for chemical mechanical polishing of rigid fragile material

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20030073311A1 (en) * 1999-07-19 2003-04-17 Joseph Levert Compositions and processes for spin etch planarization
CN1970665A (en) * 2006-12-07 2007-05-30 西北工业大学 Polishing liquid and method for polishing II-VI compound semiconductor wafer
CN101532137A (en) * 2009-04-21 2009-09-16 刘丽 Metal polishing agent
CN101864247A (en) * 2010-07-20 2010-10-20 南京航空航天大学 Abrasive material-free polishing fluid for chemical mechanical polishing of rigid fragile material

Cited By (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104947114A (en) * 2014-10-13 2015-09-30 庆云昊天焊材科技有限公司 Cold-water copper-plated welding wire polishing solution
CN104947114B (en) * 2014-10-13 2020-06-19 庆云昊天焊材科技有限公司 Cold water copper-plated welding wire polishing solution
CN104450246A (en) * 2014-11-13 2015-03-25 王爱国 Kitchen cleaning agent
CN105239073A (en) * 2015-11-10 2016-01-13 荆门市拓达科技有限公司 Polishing solution for metal polishing
CN105463466A (en) * 2015-11-22 2016-04-06 全椒县志宏机电设备设计有限公司 Polishing liquid for stainless steel mechanical equipment and preparing method of polishing liquid
CN105671555A (en) * 2016-04-10 2016-06-15 李金平 Metal surface polishing agent
CN105778863A (en) * 2016-04-20 2016-07-20 廊坊市北方天宇机电技术有限公司 Grinding fluid for aluminum wheel barreling-fishing machining and preparation method thereof
CN105778863B (en) * 2016-04-20 2018-06-29 廊坊市北方天宇机电技术有限公司 A kind of aluminium wheel centrifugal barrel finishing grinding fluid and preparation method thereof
CN105970230A (en) * 2016-07-10 2016-09-28 李金平 Environment-friendly chemical polishing solution
CN106435592A (en) * 2016-08-17 2017-02-22 安徽红桥金属制造有限公司 Chemical polishing agent used for stainless steel springs, and preparation method thereof
CN106435592B (en) * 2016-08-17 2018-08-21 安徽红桥金属制造有限公司 A kind of stainless steel spring chemical polishing agent and preparation method thereof
CN106757040A (en) * 2016-12-01 2017-05-31 三达奥克化学股份有限公司 Powder metallurgical stainless steel precision workpiece light decorations process agent and production method
CN106637218A (en) * 2016-12-24 2017-05-10 李月巧 Polishing agent and preparation method thereof
CN106987841A (en) * 2017-04-28 2017-07-28 舒城久联精密机械有限公司 Apply the stainless steel polishing agent in precision optical machinery process
WO2019006668A1 (en) * 2017-07-04 2019-01-10 深圳市恒兆智科技有限公司 Polishing agent, copper part and polishing process therefor
CN107699141A (en) * 2017-11-27 2018-02-16 苏州市宽道模具机械有限公司 A kind of polishing agent and preparation method thereof
CN109096925A (en) * 2018-07-02 2018-12-28 湖州师范学院 A kind of environmentally protective scratch resistance aqua type lapping liquid and preparation method thereof
CN109023390A (en) * 2018-09-28 2018-12-18 天津圳鹏清洗技术开发有限公司 Medical metal cleaning polishing agent and preparation method thereof
CN111015376A (en) * 2019-12-18 2020-04-17 安徽省潜山县志发机电配件有限公司 Surface polishing process for electromechanical equipment
CN116286202A (en) * 2022-09-07 2023-06-23 山东宙雨消防科技股份有限公司 Manufacturing method of environment-friendly cleaning fluid
CN115466574A (en) * 2022-09-21 2022-12-13 深圳市东方亮化学材料有限公司 Processing method of double-component metal grinding and polishing paste

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