CN103590044A - Metal polishing agent and preparation method thereof - Google Patents
Metal polishing agent and preparation method thereof Download PDFInfo
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- CN103590044A CN103590044A CN201310545882.5A CN201310545882A CN103590044A CN 103590044 A CN103590044 A CN 103590044A CN 201310545882 A CN201310545882 A CN 201310545882A CN 103590044 A CN103590044 A CN 103590044A
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- acid
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- metal polish
- oleic acid
- sodium
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- 229910052751 metal Inorganic materials 0.000 title claims abstract description 32
- 239000002184 metal Substances 0.000 title claims abstract description 32
- 238000005498 polishing Methods 0.000 title abstract description 15
- 238000002360 preparation method Methods 0.000 title description 8
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 39
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 36
- 239000005642 Oleic acid Substances 0.000 claims abstract description 17
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims abstract description 16
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims abstract description 16
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims abstract description 16
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims abstract description 16
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims abstract description 16
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims abstract description 16
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 claims abstract description 14
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims abstract description 13
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 claims abstract description 12
- 150000007524 organic acids Chemical class 0.000 claims abstract description 10
- 229940051841 polyoxyethylene ether Drugs 0.000 claims abstract description 10
- 229920000056 polyoxyethylene ether Polymers 0.000 claims abstract description 10
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims abstract description 7
- 229910052938 sodium sulfate Inorganic materials 0.000 claims abstract description 5
- 235000011152 sodium sulphate Nutrition 0.000 claims abstract description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 14
- 229960004418 trolamine Drugs 0.000 claims description 12
- 239000013543 active substance Substances 0.000 claims description 8
- 239000002904 solvent Substances 0.000 claims description 8
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 claims description 4
- ILRSCQWREDREME-UHFFFAOYSA-N dodecanamide Chemical group CCCCCCCCCCCC(N)=O ILRSCQWREDREME-UHFFFAOYSA-N 0.000 claims description 4
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 4
- -1 polyoxyethylene Polymers 0.000 claims description 4
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 3
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 10
- 230000000694 effects Effects 0.000 abstract description 8
- 239000003795 chemical substances by application Substances 0.000 abstract description 4
- 229910001220 stainless steel Inorganic materials 0.000 abstract description 3
- 239000010935 stainless steel Substances 0.000 abstract description 3
- 239000002994 raw material Substances 0.000 abstract description 2
- 235000005985 organic acids Nutrition 0.000 abstract 2
- 239000004094 surface-active agent Substances 0.000 abstract 2
- 239000006071 cream Substances 0.000 description 8
- 239000006072 paste Substances 0.000 description 6
- 239000002253 acid Substances 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- 238000000034 method Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 238000005202 decontamination Methods 0.000 description 3
- 230000003588 decontaminative effect Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 238000003912 environmental pollution Methods 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 230000008676 import Effects 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 229960002969 oleic acid Drugs 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- 229940083608 sodium hydroxide Drugs 0.000 description 2
- 239000011343 solid material Substances 0.000 description 2
- XUJNEKJLAYXESH-REOHCLBHSA-N L-Cysteine Chemical compound SC[C@H](N)C(O)=O XUJNEKJLAYXESH-REOHCLBHSA-N 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- BCKXLBQYZLBQEK-KVVVOXFISA-M Sodium oleate Chemical compound [Na+].CCCCCCCC\C=C/CCCCCCCC([O-])=O BCKXLBQYZLBQEK-KVVVOXFISA-M 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid group Chemical group C(C1=CC=CC=C1)(=O)O WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 1
- 229960004106 citric acid Drugs 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000013530 defoamer Substances 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000012847 fine chemical Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910001338 liquidmetal Inorganic materials 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000000474 nursing effect Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 150000003016 phosphoric acids Chemical class 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 229910000162 sodium phosphate Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000606 toothpaste Substances 0.000 description 1
- 229940034610 toothpaste Drugs 0.000 description 1
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 1
- 229940038773 trisodium citrate Drugs 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
- Cosmetics (AREA)
Abstract
The invention relates to a metal polishing agent which comprises the following raw materials in percentage by weight: 7%-10% of surfactants, 8%-10% of organic acids, 1.5%-2% of solutizers and the balance of water, wherein the surfactants are fatty alcohol-polyoxyethylene ether sodium sulfate, sodium dodecyl benzene sulfonate and fatty alcohol-polyoxyethylene ether, the organic acids are citric acid and oleic acid, and the solutizers are triethanolamine and sodium hydroxide. The prepared metal polishing agent is suitable for stainless steel tableware and contains organic acids-oleic acid and citric acid which can improve the metal surface activity, the polishing effect and the using effect of the polishing agent.
Description
Technical field
The invention belongs to metal processing aid field, especially a kind of metal polish and preparation method thereof.
Background technology
Metal products in use, due to reasons such as oxidation in air, humidity or contact chemical substance and corrosive gasess, cause metal products surface corrosion, adhere to foul greasy dirt situation, in order to increase metal products any surface finish, usually adopt chemical metal detergent or metal polish to process.Metal polish is one important procedure of metallic surface processing, for the chemical substance of metalwork surface finish processing.Be divided into paste and liquid.Paste general types has: white rubbing paste, green polishing composition, red rubbing paste, paste rumbling compound etc.
Liquid metal rumbling compound product generally contains strong acid or phosphoric acid salt, contaminate environment, and cleaning efficiency is low.
Solid metal rubbing paste is with fine grinding sand, aluminum oxide and polishing wet goods mineral substance, and the toothpaste body of making through special processing and emulsify at a high speed, belongs to fine chemical product, with meticulous being as the criterion, does not do multiple granularity.Effect: metallic surface decontamination, polishing, manually polish the effect with metal surface protection.Can be divided into import and domestic two kinds.Imported and famous brand is a lot, and outward appearance is beautiful, but price is very expensive.For high-grade mould, precision instrument or part decontamination, polish.Domestic, metallic surface fine grinding is polished nursing cream, and import main raw material and technique utilize emulsify at a high speed to process the convenient use of toothpaste-like.Due to cheap, various metallic surfaces have been widely used in, decontamination, polish, nurse, because of abrasive sand finer and smoother, be again manual polishing, generally can not leave a trace in metallic surface, can reach again light as new outward appearance, according to bright stock and oxide mass, content, metal is polished cream also clean bright cream and common two kinds of the cream of polishing fast.
According to the retrieval, finding following patent documentation metal polish (CN101532137), is that 2-7% Sodium dodecylbenzene sulfonate, 1.5-5% sodium oleate, 8-15% ethanol, 4-8% emulsifying agent NP-10,5-8% emulsifying agent TW-80,0.2-0.8% oleic acid triglycolyl amine, 1-4% Oleum Cocois alkylol amide phosphate ester salt, 1-4% defoamer, 0.5-2.5% sodium phosphate, 1-3% Trisodium Citrate, 0.3-1.2% halfcystine LBGAS, 0.35-1% potassium hydroxide and the excess water by weight percent is prepared into.
Summary of the invention
The object of the invention is to overcome the deficiencies in the prior art, provide a kind of cleaning performance good, polishing efficiency is high, metal polish free from environmental pollution, cost is low and preparation method thereof.
The technical scheme that the present invention realizes object is as follows:
, become and weight percent as follows
Described tensio-active agent is polyoxyethylenated alcohol sodium sulfate, Sodium dodecylbenzene sulfonate and alkylphenol polyoxyethylene, and organic acid is citric acid and oleic acid, and solubilizing agent is trolamine and sodium hydroxide;
Or described tensio-active agent is that fatty alcohol-polyoxyethylene ether, dodecyl phenenyl sulfate and Sodium dodecylbenzene sulfonate, organic acid are that oleic acid, solubilizing agent are trolamine and sodium hydroxide;
Or described tensio-active agent is lauric acid amide of ethanol, fatty alcohol-polyoxyethylene ether and Sodium dodecylbenzene sulfonate, organic acid is citric acid and oleic acid, and solubilizing agent is trolamine and sodium hydroxide.
And the moiety of described metal polish and weight percent are:
And the moiety of described metal polish and weight percent are:
And, the consisting of of described metal polish:
Advantage of the present invention and beneficial effect are as follows:
1, the metal polish that prepared by the present invention is applicable to stainless steel tableware, contains organic acid oleic acid and citric acid, and oleic acid and citric acid can increase the activity of metallic surface, improves polishing effect, increases the result of use of this rumbling compound.
2, the metal polish that prepared by the present invention contains kinds of surface promoting agent, is that tensio-active agent of different nature carries out composite, obtains having the rumbling compound that functional effect is good.
3, the metal polish that prepared by the present invention can be used for shaking polishing, can be used for again tumbling, and cost is low, and making water is base solvent, environmental protection, and free from environmental pollution, preparation method is simple.
Embodiment
Below in conjunction with embodiment, the present invention is further described, and following embodiment is illustrative, is not determinate, can not limit protection scope of the present invention with following embodiment.
A cream, by tensio-active agent, solubilizing agent, organic acid, mineral alkali and water form, and the shared weight percent of various components is:
Concrete recommendation shown in following 3 embodiment of composition.
Embodiment 1:
, by polyoxyethylenated alcohol sodium sulfate, Sodium dodecylbenzene sulfonate, the acid of alkyl acid polyoxyethylene, citric acid, oleic acid and trolamine and sodium hydroxide, and water, add in retort and be uniformly mixed respectively.
The weight percent that various acid is shared:
Manufacture the preparation method of above-mentioned medal polish cream, water is added and in retort, dissolves citric acid and will after solid materials CL, add polyoxyethylenated alcohol sodium sulfate, Sodium dodecylbenzene sulfonate, alkyl acid Soxylat A 25-7 and trolamine, after add oleic acid and stir, aqueous sodium hydroxide solution, regulates ph=5, obtains.
Embodiment 2:
, by fatty alcohol-polyoxyethylene ether, dodecyl phenenyl sulfate, Sodium dodecylbenzene sulfonate, trolamine, oleic acid, sodium hydroxide and water, the weight percent that each component is shared:
Manufacture the preparation method of above-mentioned medal polish cream: after water is added, after dropping into, benzoic solid materials all dissolves, after add fatty alcohol-polyoxyethylene ether, dodecyl phenenyl sulfate, Sodium dodecylbenzene sulfonate and trolamine, after add oleic acid to stir, aqueous sodium hydroxide solution is progressively added to (regulating ph=5.5), obtain.
Embodiment 3:
A kind of metal polish, by lauric acid amide of ethanol, fatty alcohol-polyoxyethylene ether, Sodium dodecylbenzene sulfonate and trolamine, citric acid, oleic acid and sodium hydroxide and water, add respectively and in retort, be uniformly mixed the shared weight percent of each component:
Manufacture the preparation method of above-mentioned medal polish cream: after water is added, citric acid adds lauric acid amide of ethanol after adding rear whole dissolving, fatty alcohol-polyoxyethylene ether, Sodium dodecylbenzene sulfonate and trolamine, after add oleic acid stirring and evenly mixing, aqueous sodium hydroxide solution is progressively added to (regulating ph=5), obtain.
Above-mentioned rumbling compound is for the polishing of stainless steel tableware.
The present invention compares the experimental data of acquisition with the composition of the disclosed embodiment 1 of patent documentation CN1017128A.
| Polishing fluid | Embodiment 1 | Embodiment 2 | Contrast sample (CN1017128A) |
| Add concentration | 3‰ | 3‰ | 3‰ |
| The temperature of vibropolish | Normal temperature | Normal temperature | Normal temperature |
| The average polished time | 12-15 minute | 8-10 minute | 15-20 minute |
| Cost | A | 90%A | 120%A |
| Color and luster | Cold light | Cold light | White light |
Claims (4)
1. a metal polish, is characterized in that: become and weight percent as follows
Described tensio-active agent is polyoxyethylenated alcohol sodium sulfate, Sodium dodecylbenzene sulfonate and alkylphenol polyoxyethylene, and organic acid is citric acid and oleic acid, and solubilizing agent is trolamine and sodium hydroxide;
Or described tensio-active agent is that fatty alcohol-polyoxyethylene ether, dodecyl phenenyl sulfate and Sodium dodecylbenzene sulfonate, organic acid are that oleic acid, solubilizing agent are trolamine and sodium hydroxide;
Or described tensio-active agent is lauric acid amide of ethanol, fatty alcohol-polyoxyethylene ether and Sodium dodecylbenzene sulfonate, organic acid is citric acid and oleic acid, and solubilizing agent is trolamine and sodium hydroxide.
2. metal polish according to claim 1, is characterized in that: the moiety of described metal polish and weight percent are:
3. metal polish according to claim 1, is characterized in that: the moiety of described metal polish and weight percent are:
4. metal polish according to claim 1, is characterized in that: the consisting of of described metal polish:
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310545882.5A CN103590044B (en) | 2013-11-06 | 2013-11-06 | A kind of metal polish |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310545882.5A CN103590044B (en) | 2013-11-06 | 2013-11-06 | A kind of metal polish |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103590044A true CN103590044A (en) | 2014-02-19 |
| CN103590044B CN103590044B (en) | 2016-05-04 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310545882.5A Active CN103590044B (en) | 2013-11-06 | 2013-11-06 | A kind of metal polish |
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| Country | Link |
|---|---|
| CN (1) | CN103590044B (en) |
Cited By (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104450246A (en) * | 2014-11-13 | 2015-03-25 | 王爱国 | Kitchen cleaning agent |
| CN104947114A (en) * | 2014-10-13 | 2015-09-30 | 庆云昊天焊材科技有限公司 | Cold-water copper-plated welding wire polishing solution |
| CN105239073A (en) * | 2015-11-10 | 2016-01-13 | 荆门市拓达科技有限公司 | Polishing solution for metal polishing |
| CN105463466A (en) * | 2015-11-22 | 2016-04-06 | 全椒县志宏机电设备设计有限公司 | Polishing liquid for stainless steel mechanical equipment and preparing method of polishing liquid |
| CN105671555A (en) * | 2016-04-10 | 2016-06-15 | 李金平 | Metal surface polishing agent |
| CN105778863A (en) * | 2016-04-20 | 2016-07-20 | 廊坊市北方天宇机电技术有限公司 | Grinding fluid for aluminum wheel barreling-fishing machining and preparation method thereof |
| CN105970230A (en) * | 2016-07-10 | 2016-09-28 | 李金平 | Environment-friendly chemical polishing solution |
| CN106435592A (en) * | 2016-08-17 | 2017-02-22 | 安徽红桥金属制造有限公司 | Chemical polishing agent used for stainless steel springs, and preparation method thereof |
| CN106637218A (en) * | 2016-12-24 | 2017-05-10 | 李月巧 | Polishing agent and preparation method thereof |
| CN106757040A (en) * | 2016-12-01 | 2017-05-31 | 三达奥克化学股份有限公司 | Powder metallurgy stainless steel precision workpiece light decoration treatment agent and production method |
| CN106987841A (en) * | 2017-04-28 | 2017-07-28 | 舒城久联精密机械有限公司 | Apply the stainless steel polishing agent in precision optical machinery process |
| CN107699141A (en) * | 2017-11-27 | 2018-02-16 | 苏州市宽道模具机械有限公司 | A kind of polishing agent and preparation method thereof |
| CN109023390A (en) * | 2018-09-28 | 2018-12-18 | 天津圳鹏清洗技术开发有限公司 | Medical metal cleaning polishing agent and preparation method thereof |
| CN109096925A (en) * | 2018-07-02 | 2018-12-28 | 湖州师范学院 | A kind of environmentally protective scratch resistance aqua type lapping liquid and preparation method thereof |
| WO2019006668A1 (en) * | 2017-07-04 | 2019-01-10 | 深圳市恒兆智科技有限公司 | Polishing agent, copper part and polishing process therefor |
| CN111015376A (en) * | 2019-12-18 | 2020-04-17 | 安徽省潜山县志发机电配件有限公司 | Surface polishing process for electromechanical equipment |
| CN115466574A (en) * | 2022-09-21 | 2022-12-13 | 深圳市东方亮化学材料有限公司 | A kind of processing method of two-component metal grinding and polishing paste |
| CN116200799A (en) * | 2022-08-29 | 2023-06-02 | 中国振华电子集团宇光电工有限公司（国营第七七一厂） | A kind of electromagnetic pure iron electrolytic polishing solution |
| CN116286202A (en) * | 2022-09-07 | 2023-06-23 | 山东宙雨消防科技股份有限公司 | Manufacturing method of environment-friendly cleaning fluid |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104947114A (en) * | 2014-10-13 | 2015-09-30 | 庆云昊天焊材科技有限公司 | Cold-water copper-plated welding wire polishing solution |
| CN104947114B (en) * | 2014-10-13 | 2020-06-19 | 庆云昊天焊材科技有限公司 | Cold water copper-plated welding wire polishing solution |
| CN104450246A (en) * | 2014-11-13 | 2015-03-25 | 王爱国 | Kitchen cleaning agent |
| CN105239073A (en) * | 2015-11-10 | 2016-01-13 | 荆门市拓达科技有限公司 | Polishing solution for metal polishing |
| CN105463466A (en) * | 2015-11-22 | 2016-04-06 | 全椒县志宏机电设备设计有限公司 | Polishing liquid for stainless steel mechanical equipment and preparing method of polishing liquid |
| CN105671555A (en) * | 2016-04-10 | 2016-06-15 | 李金平 | Metal surface polishing agent |
| CN105778863A (en) * | 2016-04-20 | 2016-07-20 | 廊坊市北方天宇机电技术有限公司 | Grinding fluid for aluminum wheel barreling-fishing machining and preparation method thereof |
| CN105778863B (en) * | 2016-04-20 | 2018-06-29 | 廊坊市北方天宇机电技术有限公司 | A kind of aluminium wheel centrifugal barrel finishing grinding fluid and preparation method thereof |
| CN105970230A (en) * | 2016-07-10 | 2016-09-28 | 李金平 | Environment-friendly chemical polishing solution |
| CN106435592A (en) * | 2016-08-17 | 2017-02-22 | 安徽红桥金属制造有限公司 | Chemical polishing agent used for stainless steel springs, and preparation method thereof |
| CN106435592B (en) * | 2016-08-17 | 2018-08-21 | 安徽红桥金属制造有限公司 | A kind of stainless steel spring chemical polishing agent and preparation method thereof |
| CN106757040A (en) * | 2016-12-01 | 2017-05-31 | 三达奥克化学股份有限公司 | Powder metallurgy stainless steel precision workpiece light decoration treatment agent and production method |
| CN106637218A (en) * | 2016-12-24 | 2017-05-10 | 李月巧 | Polishing agent and preparation method thereof |
| CN106987841A (en) * | 2017-04-28 | 2017-07-28 | 舒城久联精密机械有限公司 | Apply the stainless steel polishing agent in precision optical machinery process |
| WO2019006668A1 (en) * | 2017-07-04 | 2019-01-10 | 深圳市恒兆智科技有限公司 | Polishing agent, copper part and polishing process therefor |
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