CN106086910A - A kind of environmentally-friendly water-based mordant - Google Patents
A kind of environmentally-friendly water-based mordant Download PDFInfo
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- CN106086910A CN106086910A CN201610714807.0A CN201610714807A CN106086910A CN 106086910 A CN106086910 A CN 106086910A CN 201610714807 A CN201610714807 A CN 201610714807A CN 106086910 A CN106086910 A CN 106086910A
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- acid
- mordant
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
- C23G1/12—Light metals
- C23G1/125—Light metals aluminium
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- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
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Abstract
The invention discloses a kind of environmentally-friendly water-based mordant, it is characterised in that: include the raw material of following percentage by weight: pure water: 50～80%, organic acid: 15～49%, surfactant: 1～5%.Inventive formulation is simple, organic acid and biodegradable surfactant compound is used to obtain, after use completes, appropriate alkali can be added and be neutralized to neutrality, then it is directly discharged to sewer, does not results in the harm such as biological concentration, COD raising, environmentally friendly, it is made without individually processing, reduces the use cost of enterprise.
Description
Technical field
The invention belongs to abluent technical field, particularly to a kind of environmentally-friendly water-based mordant.
Background technology
In recent years, along with developing rapidly of national economy, chemical cleaning technique has had and has developed on a large scale very much, from single hydrochloric acid
The cleaning agent developing adding corrosion inhibiter extremely can use multiple different abluents for the dirty thing of unlike material and corrosion product etc., as
Fluohydric acid., EDTA etc., but existing every kind of abluent all also exists such or such shortcomings and limitations, and example hydrochloric acid does clearly
Lotion etching apparatus, Fluohydric acid. makees abluent and causes environment pollution, and EDTA is as abluent, expensive, and cost is high.The most such as
What selects reasonably acid as mordant, is the important topic in metal cleaning field.The present invention uses multiple organic acid to compound,
The mordant arrived, not only cleaning performance is good, and environmentally friendly, can add after making to be finished in appropriate alkali and after, can be straight
Run in and put, do not result in water and pollute.
Summary of the invention
For the problems referred to above, the present invention provides a kind of environmentally-friendly water-based mordant, uses multiple organic acid to compound, obtains
Mordant, not only cleaning performance is good, and environmentally friendly, can add after making to be finished in appropriate alkali and after, can directly arrange
Put, do not result in water and pollute.
The present invention solves above-mentioned technical problem and be the technical scheme is that a kind of environmentally-friendly water-based mordant, its feature
It is: include the raw material of following percentage by weight:
Pure water: 50～80%
Organic acid: 15～49%
Surfactant: 1～5%.
Further, described organic acid is 3-hydracrylic acid, hydroxyacetic acid, hydracrylic acid, sulfamic acid, alkyl sulfonic acid, lemon
In lemon acid, malic acid, tartaric acid any one or two or three or four kind or five kinds or six kinds or seven kinds or eight kinds.
Further, described surfactant is biodegradable surfactant, natural glycoside compound, straight chained alkyl
In benzene sulfonate, straight-chain alkyl sulfate, straight chain fatty polyoxyethylenated alcohol any one or two or three or four kind.
Further, described organic acid is sulfamic acid and citric acid, and the mass ratio of two kinds of organic acid is sulfamic acid: Fructus Citri Limoniae
Acid=1:4-5.
The aqueous solution of sulfamic acid has the highly acid equal with hydrochloric acid, sulphuric acid etc., therefore another name is again solid sulphuric acid, its tool
There are non-volatile, odorless and the feature minimum to human toxicity.Aqueous sulfamic acid is relatively slow to corrosion of metal effects such as ferrum,
The water scale and corrosion product of the equipment surface that the materials such as the removable ferrum of aqueous sulfamic acid, steel, copper, rustless steel manufacture.
Use citric acid to possess the performance improving cleaning product, not only can precipitate metal ion rapidly, prevent pollutant
It is re-attached on fabric；Make dirt and ash dispersion and suspend；And improve the performance of surfactant, it is a kind of excellent huge legendary turtle
Mixture.
The present invention use the compounding organic acid of sulfamic acid and citric acid as the effective ingredient of mordant, certain adding
The surfactant of amount, not only can effectively clean the dirt of metal surface, but also will not have more serious corrosion to metal, with
The performance of Shi Tigao surfactant, quickly carries out wrapping up and dissociating by dirt.
Further, described organic acid is hydracrylic acid and citric acid, and the mass ratio of two kinds of organic acid is hydracrylic acid: Fructus Citri Limoniae
Acid=4-5:1.
Further, described surfactant is APG.
Alkyl polyglucoside APG is dissolved in water, is relatively soluble in conventional organic solvent, presents excellent phase in acid, alkaline solution
Capacitive, stability and surface activity.APG can be biodegradable in nature completely, will not be formed be difficult to biodegradable
Metabolite, thus avoid and environment is caused new pollution.
Compounded the organic acid lotion obtained by above-mentioned formula, after use completes, appropriate alkali can be added and be neutralized to
Neutrality, is then directly discharged to sewer, does not results in the harm such as biological concentration, COD raising, environmentally friendly, it is not necessary to enter
Row individually processes, and reduces the use cost of enterprise.
A kind of method preparing the above-mentioned water base mordant of right, it is characterised in that: the water added in reactor, at low speed
Under stirring, it is sequentially added into organic acid and surfactant, stirs 5-10min, obtain water base mordant.
Further, the speed of described stirring is 30-50r/min.
It is an advantage of the current invention that: 1, inventive formulation is simple, use organic acid and biodegradable surfactant
Compound and obtain, after use completes, appropriate alkali can be added and be neutralized to neutrality, then be directly discharged to sewer, Bu Huizao
Becoming the harm such as biological concentration, COD raising, environmentally friendly, it is not necessary to individually to process, the use reducing enterprise becomes
This；
2, the present invention uses the compounding organic acid of sulfamic acid and citric acid as the effective ingredient of mordant, is adding one
Quantitative surfactant, not only can effectively clean the dirt of metal surface, but also will not corrode metal, improve surface simultaneously
The performance of activating agent, quickly carries out wrapping up and dissociating by dirt.
Detailed description of the invention
Below in conjunction with embodiment, technical scheme is clearly and completely described, it is clear that described reality
Executing example is a part of embodiment of the present invention rather than whole embodiments.Based on the embodiment in the present invention, the common skill in this area
The every other embodiment that art personnel are obtained under not making creative work premise, broadly falls into the model of present invention protection
Enclose.
Embodiment 1:
In reactor add 80% water, under 30-50r/min stirring at low speed, be sequentially added into 14% hydracrylic acid and
The citric acid of 5% and the APG of 1%, stir 5-10min, obtain water base mordant.
Embodiment 2:
In reactor, add the water of 80%, under 30-50r/min stirring at low speed, be sequentially added into 14% citric acid and 5%
Sulfamic acid and the APG of 1%, stir 5-10min, obtain water base mordant.
Cleaning:
The cleaning of aluminum stamped workpieces, mordant embodiment 1 and embodiment 2 obtained dilutes, is 100% by mordant
Concentration dilution, to mordant concentration 5-8%, puts the workpiece in ultrasound wave, temperature 50-60 DEG C, and scavenging period 3-5min is the purest
Water rinses twice, air-dries, and completes to clean.Workpiece light, clean up, and there is no evidence of corrosion.
Various embodiments above only in order to technical scheme to be described, is not intended to limit；Although with reference to aforementioned each reality
Execute example the present invention has been described in detail, it will be understood by those within the art that: its still can to aforementioned respectively
Technical scheme described in embodiment is modified, or the most some or all of technical characteristic is carried out equivalent；And
These amendments or replacement, do not make the essence of appropriate technical solution depart from the scope of various embodiments of the present invention technical scheme.
Claims (8)
1. an environmentally-friendly water-based mordant, it is characterised in that: include the raw material of following percentage by weight:
Pure water: 50～80%
Organic acid: 15～49%
Surfactant: 1～5%.
The environmentally-friendly water-based mordant of one the most according to claim 1, it is characterised in that: described organic acid is 3-hydroxyl third
Any one or two kinds in acid, hydroxyacetic acid, hydracrylic acid, sulfamic acid, alkyl sulfonic acid, citric acid, malic acid, tartaric acid
Or three kinds or four kinds or five kinds or six kinds or seven kinds or eight kinds.
The environmentally-friendly water-based mordant of one the most according to claim 1, it is characterised in that: described surfactant is for giving birth to
The surfactant of thing degraded, natural glycoside compound, linear alkylbenzene sulfonate (LAS), straight-chain alkyl sulfate, straight-chain fatty alcohol
In polyoxyethylene ether any one or two or three or four kind.
The environmentally-friendly water-based mordant of one the most according to claim 1, it is characterised in that: described organic acid is sulfamic acid
And citric acid, the mass ratio of two kinds of organic acid is sulfamic acid: citric acid=1:4-5.
The environmentally-friendly water-based mordant of one the most according to claim 1, it is characterised in that: described organic acid is hydracrylic acid
And citric acid, the mass ratio of two kinds of organic acid is hydracrylic acid: citric acid=4-5:1.
The environmentally-friendly water-based mordant of one the most according to claim 1, it is characterised in that: described surfactant is APG.
7. prepare the method for water base mordant described in claim 1-6 any one for one kind, it is characterised in that: add in reactor
The water entered, under stirring at low speed, is sequentially added into organic acid and surfactant, stirs 5-10min, obtain water base mordant.
A kind of method preparing water base mordant the most according to claim 7, it is characterised in that: the speed of described stirring is
30-50r/min。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610714807.0A CN106086910A (en) | 2016-08-24 | 2016-08-24 | A kind of environmentally-friendly water-based mordant |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610714807.0A CN106086910A (en) | 2016-08-24 | 2016-08-24 | A kind of environmentally-friendly water-based mordant |
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| CN106086910A true CN106086910A (en) | 2016-11-09 |
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| CN201610714807.0A Pending CN106086910A (en) | 2016-08-24 | 2016-08-24 | A kind of environmentally-friendly water-based mordant |
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Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106635450A (en) * | 2016-12-01 | 2017-05-10 | 东莞市联洲知识产权运营管理有限公司 | Biodegradable organic acid cleaning agent and application thereof in aspects of fruits and vegetables |
| CN107287603A (en) * | 2017-06-01 | 2017-10-24 | 杭州大家生物科技有限公司 | Soil preparations and its waste water utilization method are gone in a kind of multiple-effect derusting containing plant vinegar liquid |
| CN107937925A (en) * | 2017-06-01 | 2018-04-20 | 杭州大家生物科技有限公司 | Soil preparations and its waste water utilization method are gone in a kind of multiple-effect derusting containing organic acid |
| CN108251851A (en) * | 2018-01-12 | 2018-07-06 | 海宁汉得隆科技有限公司 | A kind of stainless steel surface environment-friendly cleaning agent |
| CN108301004A (en) * | 2017-01-11 | 2018-07-20 | 深圳富泰宏精密工业有限公司 | Aluminum component deashing agent and process for deashing |
| CN109680283A (en) * | 2019-01-16 | 2019-04-26 | 惠州市阿特斯润滑技术有限公司 | Magnesium alloy cleaning agent and its cleaning method |
| CN109852977A (en) * | 2019-03-11 | 2019-06-07 | 上海新阳半导体材料股份有限公司 | A kind of tin ball producing process, cleaning agent and preparation method thereof |
| CN110983345A (en) * | 2020-01-03 | 2020-04-10 | 瑞安市胜源泰表面技术有限公司 | Three-in-one treatment agent for metal surface, preparation method and use method |
| CN112746250A (en) * | 2020-12-29 | 2021-05-04 | 平湖市良正五金科技股份有限公司 | Coating processing technology for aluminum profile hot extrusion die |
| CN114854502A (en) * | 2022-05-23 | 2022-08-05 | 中国石油大学(华东) | Preparation method of biomass-based ethanol acid washing agent |
| CN114921792A (en) * | 2022-04-28 | 2022-08-19 | 台山市科美化学工业有限公司 | Preparation method of environment-friendly battery aluminum foil cleaning agent |
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| CN104651860A (en) * | 2013-11-25 | 2015-05-27 | 刘现梅 | Pickling solution for removing rust and oil on outer wall of hydraulic oil cylinder |
| CN105463480A (en) * | 2015-12-18 | 2016-04-06 | 南京巨鲨显示科技有限公司 | Non-phosphorus efficient rust remover |
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| CN104651860A (en) * | 2013-11-25 | 2015-05-27 | 刘现梅 | Pickling solution for removing rust and oil on outer wall of hydraulic oil cylinder |
| CN103642612A (en) * | 2013-12-09 | 2014-03-19 | 成都民航六维航化有限责任公司 | Cleaning agent for aircraft pipelines and preparation method thereof |
| CN105463480A (en) * | 2015-12-18 | 2016-04-06 | 南京巨鲨显示科技有限公司 | Non-phosphorus efficient rust remover |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106635450A (en) * | 2016-12-01 | 2017-05-10 | 东莞市联洲知识产权运营管理有限公司 | Biodegradable organic acid cleaning agent and application thereof in aspects of fruits and vegetables |
| CN108301004A (en) * | 2017-01-11 | 2018-07-20 | 深圳富泰宏精密工业有限公司 | Aluminum component deashing agent and process for deashing |
| CN107287603A (en) * | 2017-06-01 | 2017-10-24 | 杭州大家生物科技有限公司 | Soil preparations and its waste water utilization method are gone in a kind of multiple-effect derusting containing plant vinegar liquid |
| CN107937925A (en) * | 2017-06-01 | 2018-04-20 | 杭州大家生物科技有限公司 | Soil preparations and its waste water utilization method are gone in a kind of multiple-effect derusting containing organic acid |
| CN108251851A (en) * | 2018-01-12 | 2018-07-06 | 海宁汉得隆科技有限公司 | A kind of stainless steel surface environment-friendly cleaning agent |
| CN109680283A (en) * | 2019-01-16 | 2019-04-26 | 惠州市阿特斯润滑技术有限公司 | Magnesium alloy cleaning agent and its cleaning method |
| CN109852977A (en) * | 2019-03-11 | 2019-06-07 | 上海新阳半导体材料股份有限公司 | A kind of tin ball producing process, cleaning agent and preparation method thereof |
| CN109852977B (en) * | 2019-03-11 | 2024-02-02 | 上海新阳半导体材料股份有限公司 | Tin ball production process, cleaning agent and preparation method thereof |
| CN110983345A (en) * | 2020-01-03 | 2020-04-10 | 瑞安市胜源泰表面技术有限公司 | Three-in-one treatment agent for metal surface, preparation method and use method |
| CN112746250A (en) * | 2020-12-29 | 2021-05-04 | 平湖市良正五金科技股份有限公司 | Coating processing technology for aluminum profile hot extrusion die |
| CN114921792A (en) * | 2022-04-28 | 2022-08-19 | 台山市科美化学工业有限公司 | Preparation method of environment-friendly battery aluminum foil cleaning agent |
| CN114921792B (en) * | 2022-04-28 | 2023-01-06 | 台山市科美化学工业有限公司 | Preparation method of environment-friendly battery aluminum foil cleaning agent |
| CN114854502A (en) * | 2022-05-23 | 2022-08-05 | 中国石油大学(华东) | Preparation method of biomass-based ethanol acid washing agent |
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| CB02 | Change of applicant information |
Address after: 300000 Tianjin city Xiqing District North Industrial Park Fu Sheng Road No. 13 Applicant after: Tianjin new materials Co., Ltd. Address before: 300000 Tianjin city Xiqing District North Industrial Park Fu Sheng Road No. 13 Applicant before: Tianjin Primetech Chemical Co., Ltd. |
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Application publication date: 20161109 |
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| RJ01 | Rejection of invention patent application after publication |