CN106635450A - Biodegradable organic acid cleaning agent and application thereof in aspects of fruits and vegetables - Google Patents
Biodegradable organic acid cleaning agent and application thereof in aspects of fruits and vegetables Download PDFInfo
- Publication number
- CN106635450A CN106635450A CN201611088466.7A CN201611088466A CN106635450A CN 106635450 A CN106635450 A CN 106635450A CN 201611088466 A CN201611088466 A CN 201611088466A CN 106635450 A CN106635450 A CN 106635450A
- Authority
- CN
- China
- Prior art keywords
- organic acid
- acid
- cleaning agent
- parts
- biodegradable
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 150000007524 organic acids Chemical class 0.000 title claims abstract description 81
- 239000012459 cleaning agent Substances 0.000 title claims abstract description 70
- 235000012055 fruits and vegetables Nutrition 0.000 title claims abstract description 26
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 54
- 239000000440 bentonite Substances 0.000 claims abstract description 37
- 229910000278 bentonite Inorganic materials 0.000 claims abstract description 37
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical group O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims abstract description 37
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 35
- 238000004140 cleaning Methods 0.000 claims abstract description 34
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 claims abstract description 20
- ALRHLSYJTWAHJZ-UHFFFAOYSA-N 3-hydroxypropionic acid Chemical compound OCCC(O)=O ALRHLSYJTWAHJZ-UHFFFAOYSA-N 0.000 claims abstract description 19
- LNOPIUAQISRISI-UHFFFAOYSA-N n'-hydroxy-2-propan-2-ylsulfonylethanimidamide Chemical compound CC(C)S(=O)(=O)CC(N)=NO LNOPIUAQISRISI-UHFFFAOYSA-N 0.000 claims abstract description 19
- -1 alkyl sulfonic acid Chemical compound 0.000 claims abstract description 17
- 235000015165 citric acid Nutrition 0.000 claims abstract description 16
- 239000004094 surface-active agent Substances 0.000 claims abstract description 15
- 239000002253 acid Substances 0.000 claims abstract description 14
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 claims abstract description 10
- 150000008051 alkyl sulfates Chemical class 0.000 claims abstract description 10
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229960004275 glycolic acid Drugs 0.000 claims abstract description 10
- 239000001630 malic acid Substances 0.000 claims abstract description 10
- 235000011090 malic acid Nutrition 0.000 claims abstract description 10
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims abstract description 9
- 235000002906 tartaric acid Nutrition 0.000 claims abstract description 9
- 239000011975 tartaric acid Substances 0.000 claims abstract description 9
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims abstract description 7
- 239000007788 liquid Substances 0.000 claims abstract description 7
- 229930182470 glycoside Natural products 0.000 claims abstract description 5
- 229910001385 heavy metal Inorganic materials 0.000 claims abstract description 5
- 239000002699 waste material Substances 0.000 claims abstract description 5
- 150000004996 alkyl benzenes Chemical class 0.000 claims abstract 2
- 230000002378 acidificating effect Effects 0.000 claims description 23
- 238000002360 preparation method Methods 0.000 claims description 13
- 238000003756 stirring Methods 0.000 claims description 10
- 150000007513 acids Chemical class 0.000 claims description 8
- 150000002191 fatty alcohols Chemical class 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 7
- 241000894006 Bacteria Species 0.000 claims description 4
- 239000003905 agrochemical Substances 0.000 claims description 4
- 239000012752 auxiliary agent Substances 0.000 claims description 4
- 239000006210 lotion Substances 0.000 claims description 4
- 230000004048 modification Effects 0.000 claims description 4
- 238000012986 modification Methods 0.000 claims description 4
- 229910052751 metal Inorganic materials 0.000 claims description 3
- 239000002184 metal Substances 0.000 claims description 3
- 239000000575 pesticide Substances 0.000 abstract description 3
- 229930182478 glucoside Natural products 0.000 abstract 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- 230000001580 bacterial effect Effects 0.000 abstract 1
- 239000008213 purified water Substances 0.000 abstract 1
- UGTHTQWIQKEDEH-BQBZGAKWSA-N L-alanyl-L-prolylglycine zwitterion Chemical compound C[C@H](N)C(=O)N1CCC[C@H]1C(=O)NCC(O)=O UGTHTQWIQKEDEH-BQBZGAKWSA-N 0.000 description 13
- 239000003795 chemical substances by application Substances 0.000 description 11
- 239000000203 mixture Substances 0.000 description 10
- 238000009775 high-speed stirring Methods 0.000 description 8
- 230000007613 environmental effect Effects 0.000 description 6
- 239000000126 substance Substances 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 230000000740 bleeding effect Effects 0.000 description 4
- 230000007797 corrosion Effects 0.000 description 4
- 238000005260 corrosion Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- SRSXLGNVWSONIS-UHFFFAOYSA-N benzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-N 0.000 description 3
- 229940092714 benzenesulfonic acid Drugs 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000001179 sorption measurement Methods 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 150000001335 aliphatic alkanes Chemical class 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 239000013530 defoamer Substances 0.000 description 2
- RRAFCDWBNXTKKO-UHFFFAOYSA-N eugenol Chemical compound COC1=CC(CC=C)=CC=C1O RRAFCDWBNXTKKO-UHFFFAOYSA-N 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- 239000000419 plant extract Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 238000010010 raising Methods 0.000 description 2
- 238000013268 sustained release Methods 0.000 description 2
- 239000012730 sustained-release form Substances 0.000 description 2
- MGSRCZKZVOBKFT-UHFFFAOYSA-N thymol Chemical compound CC(C)C1=CC=C(C)C=C1O MGSRCZKZVOBKFT-UHFFFAOYSA-N 0.000 description 2
- DCXXMTOCNZCJGO-UHFFFAOYSA-N tristearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 1
- IMSODMZESSGVBE-UHFFFAOYSA-N 2-Oxazoline Chemical compound C1CN=CO1 IMSODMZESSGVBE-UHFFFAOYSA-N 0.000 description 1
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- JOOXCMJARBKPKM-UHFFFAOYSA-N 4-oxopentanoic acid Chemical compound CC(=O)CCC(O)=O JOOXCMJARBKPKM-UHFFFAOYSA-N 0.000 description 1
- NPBVQXIMTZKSBA-UHFFFAOYSA-N Chavibetol Natural products COC1=CC=C(CC=C)C=C1O NPBVQXIMTZKSBA-UHFFFAOYSA-N 0.000 description 1
- 239000005946 Cypermethrin Substances 0.000 description 1
- 102000002322 Egg Proteins Human genes 0.000 description 1
- 108010000912 Egg Proteins Proteins 0.000 description 1
- 239000005770 Eugenol Substances 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- UVMRYBDEERADNV-UHFFFAOYSA-N Pseudoeugenol Natural products COC1=CC(C(C)=C)=CC=C1O UVMRYBDEERADNV-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000005844 Thymol Substances 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 239000003929 acidic solution Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- KVBCYCWRDBDGBG-UHFFFAOYSA-N azane;dihydrofluoride Chemical compound [NH4+].F.[F-] KVBCYCWRDBDGBG-UHFFFAOYSA-N 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 229910052728 basic metal Inorganic materials 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 239000003139 biocide Substances 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- RECUKUPTGUEGMW-UHFFFAOYSA-N carvacrol Chemical compound CC(C)C1=CC=C(C)C(O)=C1 RECUKUPTGUEGMW-UHFFFAOYSA-N 0.000 description 1
- HHTWOMMSBMNRKP-UHFFFAOYSA-N carvacrol Natural products CC(=C)C1=CC=C(C)C(O)=C1 HHTWOMMSBMNRKP-UHFFFAOYSA-N 0.000 description 1
- 235000007746 carvacrol Nutrition 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 230000009920 chelation Effects 0.000 description 1
- 239000008139 complexing agent Substances 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- KAATUXNTWXVJKI-UHFFFAOYSA-N cypermethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-UHFFFAOYSA-N 0.000 description 1
- 229960005424 cypermethrin Drugs 0.000 description 1
- OWZREIFADZCYQD-NSHGMRRFSA-N deltamethrin Chemical compound CC1(C)[C@@H](C=C(Br)Br)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 OWZREIFADZCYQD-NSHGMRRFSA-N 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- JMGZBMRVDHKMKB-UHFFFAOYSA-L disodium;2-sulfobutanedioate Chemical compound [Na+].[Na+].OS(=O)(=O)C(C([O-])=O)CC([O-])=O JMGZBMRVDHKMKB-UHFFFAOYSA-L 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 229960002217 eugenol Drugs 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 238000003306 harvesting Methods 0.000 description 1
- 235000010299 hexamethylene tetramine Nutrition 0.000 description 1
- VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical group C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- WYXXLXHHWYNKJF-UHFFFAOYSA-N isocarvacrol Natural products CC(C)C1=CC=C(O)C(C)=C1 WYXXLXHHWYNKJF-UHFFFAOYSA-N 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 229960004011 methenamine Drugs 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- 229940049964 oleate Drugs 0.000 description 1
- 125000002811 oleoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 210000004681 ovum Anatomy 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 244000052769 pathogen Species 0.000 description 1
- 230000001717 pathogenic effect Effects 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229920000867 polyelectrolyte Polymers 0.000 description 1
- 150000008442 polyphenolic compounds Chemical class 0.000 description 1
- 235000013824 polyphenols Nutrition 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000002516 radical scavenger Substances 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- DPJRMOMPQZCRJU-UHFFFAOYSA-M thiamine hydrochloride Chemical compound Cl.[Cl-].CC1=C(CCO)SC=[N+]1CC1=CN=C(C)N=C1N DPJRMOMPQZCRJU-UHFFFAOYSA-M 0.000 description 1
- 229960000790 thymol Drugs 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical group CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
- C23G1/08—Iron or steel
- C23G1/088—Iron or steel solutions containing organic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/825—Mixtures of compounds all of which are non-ionic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/1253—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
- C11D3/1266—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite in liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/3409—Alkyl -, alkenyl -, cycloalkyl - or terpene sulfates or sulfonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/349—Organic compounds containing sulfur additionally containing nitrogen atoms, e.g. nitro, nitroso, amino, imino, nitrilo, nitrile groups containing compounds or their derivatives or thio urea
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
- C23G1/04—Cleaning or pickling metallic material with solutions or molten salts with acid solutions using inhibitors
- C23G1/06—Cleaning or pickling metallic material with solutions or molten salts with acid solutions using inhibitors organic inhibitors
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
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- C11D2111/14—
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- C11D2111/16—
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- C11D2111/22—
Abstract
The invention provides a biodegradable organic acid cleaning agent and application thereof in the aspects of fruits and vegetables. The biodegradable organic acid cleaning agent is prepared from the following components in percentage by weight: 15 to 49 percent of organic acid, 1 to 5 percent of a biodegradable surfactant and an assistant in total, and 50 to 80 percent of purified water, wherein the total amount is 100 percent; the organic acid is one or more of 3-hydroxypropionic acid, hydroxyacetic acid, hydroxypropionic acid, sulfamic acid, alkyl sulfonic acid, citric acid, malic acid and tartaric acid; the surfactant is one or more of a natural glucoside compound, linear alkyl benzene sulphonic acid, linear alkyl sulfate and linear alcohol ethoxylates; the natural glucoside compound is alkyl glycoside; the assistant is bentonite. For fruits and vegetables cleaned by adopting the biodegradable organic acid cleaning agent, the removing rate of dirt on the surface is 100 percent, the removing rate of pesticide is not lower than 85 percent, the removing rate of heavy metal is not lower than 95 percent, and the removing rate of a bacterial colony is not lower than 85 percent; in addition, cleaning waste liquid can be directly drained, so greenness, safety and environment friendliness are realized.
Description
Technical field
The invention belongs to cleaning agent field of material technology, and in particular to a kind of biodegradable organic acid cleaning agent and its
Application in terms of fruits and vegetables.
Background technology
Increasingly deteriorate in global ecological environment, the resource asymptotic exhausted present age, the concept of environmental protection is gradually deep into respectively
In the minds of each industry people of row.With the raising of industrialization degree, the consumption of cleaning agent is also rising year by year, and environment-friendly cleaning agent will
Become the dominant direction of cleaning industry.
At present, cleaning agent can be divided into physical cleaning, Chemical cleaning and biological cleaning, and Chemical cleaning is referred to chemically goes
Make it recover the process of original surface state except body surface dirt, Chemical cleaning according to the difference of cleaning agent be divided into alkali cleaning,
Acidity, complexing agent cleaning, polyelectrolyte cleaning, surfactant washing, biocide cleaning and organic solvent cleaning etc..Wherein acid
Property cleaning agent mainly use mostly be inorganic acid, such as hydrochloric acid, sulfuric acid, nitric acid, sulfamic acid, ammonium acid fluoride, these materials pair
There is effective cleaning to act on for the hard scale of basic metal carbonate composition and the corrosion product of metal oxide composition, but to gold
Category equipment has very strong corrosivity.
Organic acid cleaning agent is the scavenger specially by made by the organic compound with some specific functions, and organic acid is clear
Mainly include machine acid and its some active chelation groups for being carried of itself in lotion, and organic slow-release agent, have machine aided
Agent etc., it is excellent that organic acid cleaning agent mainly uses the oxidisability that itself has, active group that is acid and being carried
Sequestering power, adds the effect of compounding surfactant sustained release agent therein, bleeding agent etc., by the oxidation barrier layer stripping of attachment
From, infiltrate, disperse, chelating into washing lotion, reach the purpose of cleaning.One kind disclosed in Chinese patent CN 104860403A is used for
The liquid and using method of space division workshop appliance on-line cleaning, the cleaning liquid includes organic acid, corrosion inhibiter, bleeding agent, froth breaking
Agent and water are constituted, and organic acid is formic acid, hydroxyacetic acid, citric acid or sulfamic acid, and corrosion inhibiter is methenamine, oleoyl miaow
Oxazoline, trihydroxy ethylamine oleate soap or Lan-826, bleeding agent is AEO or Disodium sulfosuccinate, froth breaking
Agent is tributyl phosphate or silicone defoamer, and the organic acid that mainly becomes of the cleaning agent will not be rotten to workshop appliance generation
Erosion harm, but the sustained release agent, bleeding agent and defoamer used by it is not all Biodegradable material, is not directly discharged, or
Cleaning waste liquid can be produced, the concept of environmental protection is not met.It is a kind of disclosed in Chinese patent CN 101979490B to remove fruits and vegetables table
Face agricultural chemicals and the cleaning agent of microorganism, the cleaning agent include organic acid, surfactant, natural plant extracts, synergist and
Water, organic acid is levulic acid, citric acid, lactic acid or malic acid, and surfactant is polyethenoxy sorbitan list oil
Acid esters, lauryl sodium sulfate or glyceryl tristearate, plant extracts be vine polyphenol, eugenol, carvacrol or
Thymol, the cleaning agent can understand worm's ovum, black dirt, residues of pesticides and the pathogen of fruit and vegetable surfaces, pollution-free, environmental protection.
From above-mentioned prior art, current environment protection acidic cleaning agent concentrates on the environmentally friendly Journal of Sex Research in organic acid, for
Research in terms of the environmental protection of the surfactant of addition is simultaneously few, and applicant of the present invention selects in the technology of prior art
Biodegradable surfactant mixes with organic acid, and preparation forms the organic acid detergent of environmental protection.
The content of the invention
The technical problem to be solved in the present invention is to provide a kind of biodegradable organic acid cleaning agent and its in fruits and vegetables side
The application in face,
To solve above-mentioned technical problem, the technical scheme is that：
A kind of biodegradable organic acid cleaning agent, the component of the biodegradable organic acid cleaning agent, by weight
Amount percentages, including organic acid 15-49%, biodegradable surfactant and auxiliary agent total amount are 1-5% and pure water 50-
80%, total amount is 100%, the organic acid be 3- hydracrylic acids, hydroxyacetic acid, hydracrylic acid, sulfamic acid, alkyl sulfonic acid,
One or several in citric acid, malic acid, tartaric acid, the surfactant is natural glycoside compounds, straight chained alkyl
One or several in benzene sulfonic acid, straight-chain alkyl sulfate, straight-chain fatty alcohol APEO, the natural glycoside compounds
For APG, the auxiliary agent is bentonite.
As the preferred of above-mentioned technical proposal, the component of the biodegradable organic acid cleaning agent, by weight,
Including：1 part of sulfamic acid, citric acid 4-5 parts, APG 0.1-0.2 parts, bentonite 0.1-0.3 parts, pure water 85-90 parts.
The aqueous solution of sulfamic acid has the highly acid equal with hydrochloric acid, sulfuric acid etc., with non-volatile, odorless and to people
Body small toxicity it is specific, aqueous sulfamic acid to iron, steel, copper etc. have cleaning function, citric acid have improve cleaning product
Performance, not only can precipitate metal ion rapidly, make dirt and ash dispersion and suspend, and the property of surfactant can be improved
Can, chelating ability is excellent.APG water soluble, presents in an acidic solution excellent compatibility, stability and surface
Activity, and APG can be biodegradable completely, will not be formed and be difficult to biodegradable metabolin, it is right so as to avoid
Environment causes new pollution.
As the preferred of above-mentioned technical proposal, the component of the biodegradable organic acid cleaning agent, by weight,
Including：1 part of hydroxyacetic acid, 2 parts of malic acid, tartaric acid 2-3 parts, LABS 0.1-0.2 parts, bentonite 0.1-0.3
Part, pure water 85-90 parts.
As the preferred of above-mentioned technical proposal, the component of the biodegradable organic acid cleaning agent, by weight,
Including：1 part of 3- hydracrylic acids, 2 parts of hydracrylic acid, alkyl sulfonic acid 2-3 parts, straight-chain alkyl sulfate 0.1-0.2 parts, bentonite
0.1-0.3 parts, pure water 85-90 parts.
As the preferred of above-mentioned technical proposal, the component of the biodegradable organic acid cleaning agent, by weight,
Including：1 part of sulfamic acid, citric acid 4-5 parts, 0.1 part of APG, 0.1 part of straight-chain fatty alcohol APEO, bentonite
0.1-0.3 parts, pure water 85-90 parts.
LABS, straight-chain alkyl sulfate, straight-chain fatty alcohol APEO all have degradability, very
Easily it is degraded, biological degradability can reach more than 90%, significant impact will not be caused to environment.
Used as the preferred of above-mentioned technical proposal, the bentonite is the Acidic Bentonite of modification.
The solubility property of Acidic Bentonite is good, high adsorption capacity, can with Adsorption of Heavy Metals, phosphorus, etc. chemical substance, and will
Acidic Bentonite is combined with organic acid, can further improve bentonitic performance, improves the cleaning performance of organic acid cleaning agent, and
It is free of a burden to environment and bentonite is biodegradable.
Used as the preferred of above-mentioned technical proposal, the preparation method of biodegradable organic acid cleaning agent includes following step
Suddenly：
By bentonite Jing after acidic treatment, 200 mesh sieves are crossed, in being added to pure water, high-speed stirred, in gel, low speed
Stirring, sequentially adds organic acid and biodegradable surfactant, prevents bubble from producing, and obtains biodegradable organic
Acid cleaner.
Application of a kind of biodegradable organic acid cleaning agent in terms of fruits and vegetables, it is characterised in that described biological to drop
The method of application of the organic acid cleaning agent of solution in terms of fruits and vegetables is：The fresh biodegradable organic acid of fruits and vegetables will be plucked
Cleaning agent is cleaned, then rinses 5s with running water, and cleaning waste liquid directly discharges, fruits and vegetables are dried naturally, obtains the fruits and vegetables for cleaning.
Used as the preferred of above-mentioned technical proposal, the clearance rate of the dirt of the fruit and vegetable surfaces of the cleaning is 100%, agricultural chemicals
Clearance rate is not less than 85%, and the clearance rate of heavy metal is not less than 95%, and the clearance of bacterium colony is not less than 85%.
Used as the preferred of above-mentioned technical proposal, the biodegradable organic acid cleaning agent can be also used for Industrial Metal
Or industrial electronic cleaning.
Compared with prior art, the invention has the advantages that：
(1) biodegradable organic acid cleaning agent prepared by the present invention is lived using organic acid and biodegradable surface
Property agent compounding, and combine bentonite adsorption, the dirt and chemical pesticide residual of fruit and vegetable surfaces is carried out from physics and chemistry aspect
Remove, removing waste water can directly discharge, do not result in the harm such as biological concentration, COD raisings, it is environmentally friendly, it is not necessary to carry out
Individually process, reduce the use cost of enterprise.
(2) preparation method of biodegradable organic acid cleaning agent prepared by the present invention is simple, workable, uses
Method is easy, can be used for Industrial Metal or industrial electronic cleaning, is especially suitable for the cleaning of fruits and vegetables, can quickly wrap up dirt
With it is free, corrosion will not be produced to equipment, harm will not be produced to fruits and vegetables, it is good to the cleaning performance of various residues, also without residual
Stay, it is pollution-free, environmental protection is efficient.
Specific embodiment
Describe the present invention, the illustrative examples of the here present invention and explanation in detail below in conjunction with specific embodiment
It is for explaining the present invention but not as a limitation of the invention.
Embodiment 1：
The component of biodegradable organic acid cleaning agent, by weight, including：1 part of sulfamic acid, 4 parts of citric acid,
0.1 part of APG, 0.1 part of Acidic Bentonite, 85 parts of pure water.
Preparation method is：Acidic Bentonite is crossed into 200 mesh sieves, in being added to pure water, with the speed high-speed stirring of 2500rpm
Mix, be extremely in gel, then with the speed stirring at low speed of 200rpm, sequentially add sulfamic acid, citric acid and APG, prevent
Bubble is produced, and obtains biodegradable organic acid cleaning agent.
Embodiment 2：
The component of biodegradable organic acid cleaning agent, by weight, including：1 part of hydroxyacetic acid, 2 parts of malic acid,
2 parts of tartaric acid, 0.1 part of LABS, 0.1 part of Acidic Bentonite, 85 parts of pure water.
Preparation method is：Acidic Bentonite is crossed into 200 mesh sieves, in being added to pure water, with the speed high-speed stirring of 3000rpm
Mix, be extremely in gel, then with the speed stirring at low speed of 500rpm, sequentially add hydroxyacetic acid, malic acid, tartaric acid and straight chain alkane
Base benzene sulfonic acid, prevents bubble from producing, and obtains biodegradable organic acid cleaning agent.
Embodiment 3：
The component of biodegradable organic acid cleaning agent, by weight, including：1 part of 3- hydracrylic acids, hydracrylic acid
2 parts, 2 parts of alkyl sulfonic acid, 0.1 part of straight-chain alkyl sulfate, 0.1 part of Acidic Bentonite, 85 parts of pure water.
Preparation method is：Acidic Bentonite is crossed into 200 mesh sieves, in being added to pure water, with the speed high-speed stirring of 2800rpm
Mix, to being in gel, then with the speed stirring at low speed of 300rpm, sequentially add 3- hydracrylic acids, hydracrylic acid, alkyl sulfonic acid and
Straight-chain alkyl sulfate, prevents bubble from producing, and obtains biodegradable organic acid cleaning agent.
Embodiment 4：
The component of biodegradable organic acid cleaning agent, by weight, including：1 part of sulfamic acid, citric acid 4-5
Part, 0.1 part of APG, 0.1 part of straight-chain fatty alcohol APEO, 0.3 part of Acidic Bentonite, 90 parts of pure water.
Preparation method is：Acidic Bentonite is crossed into 200 mesh sieves, in being added to pure water, with the speed high-speed stirring of 2500rpm
Mix, be extremely in gel, then with the speed stirring at low speed of 500rpm, sequentially add sulfamic acid, citric acid, APG and straight chain
AEO, prevents bubble from producing, and obtains biodegradable organic acid cleaning agent.
Embodiment 5：
The component of biodegradable organic acid cleaning agent, by weight, including：1 part of sulfamic acid, 5 parts of citric acid,
0.2 part of APG, 0.3 part of Acidic Bentonite, 90 parts of pure water.
Preparation method is：Acidic Bentonite is crossed into 200 mesh sieves, in being added to pure water, with the speed high-speed stirring of 3000rpm
Mix, be extremely in gel, then with the speed stirring at low speed of 500rpm, sequentially add sulfamic acid, citric acid and APG, prevent
Bubble is produced, and obtains biodegradable organic acid cleaning agent.
Embodiment 6：
The component of biodegradable organic acid cleaning agent, by weight, including：1 part of hydroxyacetic acid, 2 parts of malic acid,
3 parts of tartaric acid, 0.2 part of LABS, 0.3 part of Acidic Bentonite, 90 parts of pure water.
Preparation method is：Acidic Bentonite is crossed into 200 mesh sieves, in being added to pure water, with the speed high-speed stirring of 3000rpm
Mix, be extremely in gel, then with the speed stirring at low speed of 500rpm, sequentially add hydroxyacetic acid, malic acid, tartaric acid and straight chain alkane
Base benzene sulfonic acid, prevents bubble from producing, and obtains biodegradable organic acid cleaning agent.
Embodiment 7：
The component of biodegradable organic acid cleaning agent, by weight, including：1 part of 3- hydracrylic acids, hydracrylic acid
2 parts, alkyl sulfonic acid 2-3 parts, 0.15 part of straight-chain alkyl sulfate, 0.2 part of Acidic Bentonite, 88 parts of pure water.
Preparation method is：Acidic Bentonite is crossed into 200 mesh sieves, in being added to pure water, with the speed high-speed stirring of 2600rpm
Mix, to being in gel, then with the speed stirring at low speed of 400rpm, sequentially add 3- hydracrylic acids, hydracrylic acid, alkyl sulfonic acid and
Straight-chain alkyl sulfate, prevents bubble from producing, and obtains biodegradable organic acid cleaning agent.
Embodiment 8：
The component of biodegradable organic acid cleaning agent, by weight, including：1 part of sulfamic acid, 4 parts of citric acid,
0.1 part of APG, 0.1 part of straight-chain fatty alcohol APEO, 0.1 part of Acidic Bentonite, 85 parts of pure water.
Preparation method is：Acidic Bentonite is crossed into 200 mesh sieves, in being added to pure water, with the speed high-speed stirring of 2600rpm
Mix, be extremely in gel, then with the speed stirring at low speed of 450rpm, sequentially add sulfamic acid, citric acid, APG and straight chain
AEO, prevents bubble from producing, and obtains biodegradable organic acid cleaning agent.
Using method：The fresh apple of the harvesting of embodiment 1-8 preparation is clear with biodegradable organic acid cleaning agent
Wash, then 5s is rinsed with running water, cleaning waste liquid directly discharges, fruits and vegetables are dried naturally, obtains the fruits and vegetables for cleaning.
After testing, the result of the cleaning of biodegradable organic acid cleaning agent prepared by embodiment 1-8 is as follows：
Note：Contain Bravo, cypermethrin, decis, lead, cadmium, copper, bacterium colony, grease and mud in unwashed apple
The residues such as soil.
As seen from the above table, the biodegradable organic acid cleaning agent that prepared by the present invention is to dirt, agricultural chemicals, heavy metal, bacterium
Falling etc. has good elimination effect good, and biodegradability is excellent.
The principle and its effect of above-described embodiment only illustrative present invention, it is of the invention not for limiting.It is any ripe
Know the personage of this technology all can carry out modifications and changes under the spirit and the scope without prejudice to the present invention to above-described embodiment.Cause
This, such as those of ordinary skill in the art is complete with institute under technological thought without departing from disclosed spirit
Into all equivalent modifications or change, should by the present invention claim be covered.
Claims (10)
1. a kind of biodegradable organic acid cleaning agent, it is characterised in that：The biodegradable organic acid cleaning agent
Component, by weight percentage, including organic acid 15-49%, biodegradable surfactant and auxiliary agent total amount are 1-5%
With pure water 50-80%, total amount is 100%, the organic acid be 3- hydracrylic acids, hydroxyacetic acid, hydracrylic acid, sulfamic acid,
One or several in alkyl sulfonic acid, citric acid, malic acid, tartaric acid, the surfactant be natural glycoside compounds,
One or several in LABS, straight-chain alkyl sulfate, straight-chain fatty alcohol APEO, the natural sugar
Glycoside compound is APG, and the auxiliary agent is bentonite.
2. a kind of biodegradable organic acid cleaning agent according to claim 1, it is characterised in that：It is described biological to drop
The component of the organic acid cleaning agent of solution, by weight, including：1 part of sulfamic acid, citric acid 4-5 parts, APG 0.1-
0.2 part, bentonite 0.1-0.3 parts, pure water 85-90 parts.
3. a kind of biodegradable organic acid cleaning agent according to claim 1, it is characterised in that：It is described biological to drop
The component of the organic acid cleaning agent of solution, by weight, including：1 part of hydroxyacetic acid, 2 parts of malic acid, tartaric acid 2-3 parts, straight chain
Alkyl benzene sulphonate 0.1-0.2 parts, bentonite 0.1-0.3 parts, pure water 85-90 parts.
4. a kind of biodegradable organic acid cleaning agent according to claim 1, it is characterised in that：It is described biological to drop
The component of the organic acid cleaning agent of solution, by weight, including：1 part of 3- hydracrylic acids, 2 parts of hydracrylic acid, alkyl sulfonic acid 2-3
Part, straight-chain alkyl sulfate 0.1-0.2 parts, bentonite 0.1-0.3 parts, pure water 85-90 parts.
5. a kind of biodegradable organic acid cleaning agent according to claim 1, it is characterised in that：It is described biological to drop
The component of the organic acid cleaning agent of solution, by weight, including：1 part of sulfamic acid, citric acid 4-5 parts, 0.1 part of APG,
0.1 part of straight-chain fatty alcohol APEO, bentonite 0.1-0.3 parts, pure water 85-90 parts.
6. a kind of biodegradable organic acid cleaning agent according to any one of claim 1-5, it is characterised in that described
Bentonite is the Acidic Bentonite of modification.
7. a kind of biodegradable organic acid cleaning agent according to claim 1, it is characterised in that preparation method includes
Following steps：
By bentonite Jing after acidic treatment, 200 mesh sieves are crossed, in being added to pure water, high-speed stirred, extremely in gel, stirring at low speed,
Organic acid and biodegradable surfactant are sequentially added, prevents bubble from producing, obtain biodegradable organic acid clear
Lotion.
8. application of a kind of biodegradable organic acid cleaning agent in terms of fruits and vegetables, it is characterised in that：It is described biodegradable
The method of application of the organic acid cleaning agent in terms of fruits and vegetables be：The fruits and vegetables for plucking fresh are clear with biodegradable organic acid
Lotion is cleaned, then rinses 5s with running water, and cleaning waste liquid directly discharges, fruits and vegetables are dried naturally, obtains the fruits and vegetables for cleaning.
9. application of a kind of biodegradable organic acid cleaning agent according to claim 8 in terms of fruits and vegetables, its feature
It is：The clearance rate of the dirt of the fruit and vegetable surfaces of the cleaning is 100%, and the clearance rate of agricultural chemicals is not less than 85%, heavy metal
Clearance rate is not less than 95%, and the clearance of bacterium colony is not less than 85%.
10. a kind of biodegradable organic acid cleaning agent according to any one of claim 1-5, it is characterised in that：Institute
State biodegradable organic acid cleaning agent and can be also used for Industrial Metal or industrial electronic cleaning.
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| CN108130230A (en) * | 2018-01-16 | 2018-06-08 | 白山市和硅藻科技有限公司 | A kind of fruit vegetable cleaning agent containing loaded modified diatom soil |
| CN108359538A (en) * | 2018-02-09 | 2018-08-03 | 宁夏智弘生物科技有限公司 | Green safe fruits and vegetables, birds, beasts and eggs and meat cleaning and fresh-keeping agent and preparation method thereof |
| CN109852977A (en) * | 2019-03-11 | 2019-06-07 | 上海新阳半导体材料股份有限公司 | A kind of tin ball producing process, cleaning agent and preparation method thereof |
| CN111363634A (en) * | 2020-03-06 | 2020-07-03 | 山东海天生物化工有限公司 | Fruit and vegetable cleaning agent |
| CN112779543A (en) * | 2020-12-25 | 2021-05-11 | 德蓝水技术股份有限公司 | Organic acid cleaning agent and preparation method thereof |
| CN114854502A (en) * | 2022-05-23 | 2022-08-05 | 中国石油大学(华东) | Preparation method of biomass-based ethanol acid washing agent |
| CN114921792A (en) * | 2022-04-28 | 2022-08-19 | 台山市科美化学工业有限公司 | Preparation method of environment-friendly battery aluminum foil cleaning agent |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108130230A (en) * | 2018-01-16 | 2018-06-08 | 白山市和硅藻科技有限公司 | A kind of fruit vegetable cleaning agent containing loaded modified diatom soil |
| CN108359538A (en) * | 2018-02-09 | 2018-08-03 | 宁夏智弘生物科技有限公司 | Green safe fruits and vegetables, birds, beasts and eggs and meat cleaning and fresh-keeping agent and preparation method thereof |
| CN109852977A (en) * | 2019-03-11 | 2019-06-07 | 上海新阳半导体材料股份有限公司 | A kind of tin ball producing process, cleaning agent and preparation method thereof |
| CN109852977B (en) * | 2019-03-11 | 2024-02-02 | 上海新阳半导体材料股份有限公司 | Tin ball production process, cleaning agent and preparation method thereof |
| CN111363634A (en) * | 2020-03-06 | 2020-07-03 | 山东海天生物化工有限公司 | Fruit and vegetable cleaning agent |
| CN112779543A (en) * | 2020-12-25 | 2021-05-11 | 德蓝水技术股份有限公司 | Organic acid cleaning agent and preparation method thereof |
| CN114921792A (en) * | 2022-04-28 | 2022-08-19 | 台山市科美化学工业有限公司 | Preparation method of environment-friendly battery aluminum foil cleaning agent |
| CN114921792B (en) * | 2022-04-28 | 2023-01-06 | 台山市科美化学工业有限公司 | Preparation method of environment-friendly battery aluminum foil cleaning agent |
| CN114854502A (en) * | 2022-05-23 | 2022-08-05 | 中国石油大学(华东) | Preparation method of biomass-based ethanol acid washing agent |
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Application publication date: 20170510 |