CN101993793A - Liquid detergent dedicated for underwear - Google Patents
Liquid detergent dedicated for underwear Download PDFInfo
- Publication number
- CN101993793A CN101993793A CN2009101946700A CN200910194670A CN101993793A CN 101993793 A CN101993793 A CN 101993793A CN 2009101946700 A CN2009101946700 A CN 2009101946700A CN 200910194670 A CN200910194670 A CN 200910194670A CN 101993793 A CN101993793 A CN 101993793A
- Authority
- CN
- China
- Prior art keywords
- underwear
- polyoxyethylene ether
- fatty alcohol
- liquid detergent
- dedicated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000007788 liquid Substances 0.000 title claims abstract description 41
- 239000003599 detergent Substances 0.000 title abstract description 6
- 229940051841 polyoxyethylene ether Drugs 0.000 claims abstract description 25
- 229920000056 polyoxyethylene ether Polymers 0.000 claims abstract description 25
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 18
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims abstract description 13
- 229910052938 sodium sulfate Inorganic materials 0.000 claims abstract description 12
- 235000011152 sodium sulphate Nutrition 0.000 claims abstract description 12
- 238000005406 washing Methods 0.000 claims description 36
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 24
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N EtOH Substances CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 23
- 239000000203 mixture Substances 0.000 claims description 21
- -1 ethanol amide Chemical class 0.000 claims description 15
- OSDLLIBGSJNGJE-UHFFFAOYSA-N 4-chloro-3,5-dimethylphenol Chemical compound CC1=CC(O)=CC(C)=C1Cl OSDLLIBGSJNGJE-UHFFFAOYSA-N 0.000 claims description 10
- DPDMMXDBJGCCQC-UHFFFAOYSA-N [Na].[Cl] Chemical compound [Na].[Cl] DPDMMXDBJGCCQC-UHFFFAOYSA-N 0.000 claims description 8
- SGTNSNPWRIOYBX-UHFFFAOYSA-N 2-(3,4-dimethoxyphenyl)-5-{[2-(3,4-dimethoxyphenyl)ethyl](methyl)amino}-2-(propan-2-yl)pentanenitrile Chemical compound C1=C(OC)C(OC)=CC=C1CCN(C)CCCC(C#N)(C(C)C)C1=CC=C(OC)C(OC)=C1 SGTNSNPWRIOYBX-UHFFFAOYSA-N 0.000 claims description 6
- QDWXBVYRECADHW-UHFFFAOYSA-N CNCC(=O)O.C(C(=O)O)(=O)O Chemical compound CNCC(=O)O.C(C(=O)O)(=O)O QDWXBVYRECADHW-UHFFFAOYSA-N 0.000 claims description 6
- 239000008139 complexing agent Substances 0.000 claims description 6
- 241000191967 Staphylococcus aureus Species 0.000 abstract description 5
- 238000004140 cleaning Methods 0.000 abstract description 3
- 230000002147 killing effect Effects 0.000 abstract description 3
- 230000007935 neutral effect Effects 0.000 abstract description 3
- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 abstract description 2
- 239000008267 milk Substances 0.000 abstract description 2
- 210000004080 milk Anatomy 0.000 abstract description 2
- 235000013336 milk Nutrition 0.000 abstract description 2
- 210000002700 urine Anatomy 0.000 abstract description 2
- QZXSMBBFBXPQHI-UHFFFAOYSA-N N-(dodecanoyl)ethanolamine Chemical compound CCCCCCCCCCCC(=O)NCCO QZXSMBBFBXPQHI-UHFFFAOYSA-N 0.000 abstract 1
- 241001523956 Parengyodontium album Species 0.000 abstract 1
- 241000194017 Streptococcus Species 0.000 abstract 1
- 229940073507 cocamidopropyl betaine Drugs 0.000 abstract 1
- 230000005764 inhibitory process Effects 0.000 abstract 1
- 230000000638 stimulation Effects 0.000 abstract 1
- 150000005846 sugar alcohols Polymers 0.000 abstract 1
- 230000001954 sterilising effect Effects 0.000 description 13
- 230000000694 effects Effects 0.000 description 12
- 238000004659 sterilization and disinfection Methods 0.000 description 10
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 9
- 239000002994 raw material Substances 0.000 description 9
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 6
- 238000005202 decontamination Methods 0.000 description 6
- 230000003588 decontaminative effect Effects 0.000 description 6
- 239000000686 essence Substances 0.000 description 6
- 241000894006 Bacteria Species 0.000 description 5
- 108091005804 Peptidases Proteins 0.000 description 5
- 230000000845 anti-microbial effect Effects 0.000 description 5
- 230000000249 desinfective effect Effects 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- 238000005303 weighing Methods 0.000 description 5
- 229920000742 Cotton Polymers 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
- 102000035195 Peptidases Human genes 0.000 description 3
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 3
- 235000011613 Pinus brutia Nutrition 0.000 description 3
- 241000018646 Pinus brutia Species 0.000 description 3
- 238000013019 agitation Methods 0.000 description 3
- 230000000844 anti-bacterial effect Effects 0.000 description 3
- 230000033228 biological regulation Effects 0.000 description 3
- 239000011575 calcium Substances 0.000 description 3
- 229910052791 calcium Inorganic materials 0.000 description 3
- 239000004744 fabric Substances 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 239000008233 hard water Substances 0.000 description 3
- 230000000968 intestinal effect Effects 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 230000008719 thickening Effects 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
- 241000233866 Fungi Species 0.000 description 2
- 239000004365 Protease Substances 0.000 description 2
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 description 2
- GTTSNKDQDACYLV-UHFFFAOYSA-N Trihydroxybutane Chemical compound CCCC(O)(O)O GTTSNKDQDACYLV-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 239000013543 active substance Substances 0.000 description 2
- JBIROUFYLSSYDX-UHFFFAOYSA-M benzododecinium chloride Chemical compound [Cl-].CCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 JBIROUFYLSSYDX-UHFFFAOYSA-M 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000000645 desinfectant Substances 0.000 description 2
- SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 229940079593 drug Drugs 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 235000013312 flour Nutrition 0.000 description 2
- 230000002070 germicidal effect Effects 0.000 description 2
- 229910001385 heavy metal Inorganic materials 0.000 description 2
- 235000019633 pungent taste Nutrition 0.000 description 2
- 238000007634 remodeling Methods 0.000 description 2
- 239000003352 sequestering agent Substances 0.000 description 2
- 230000009919 sequestration Effects 0.000 description 2
- 239000002453 shampoo Substances 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 230000003068 static effect Effects 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- 101100345345 Arabidopsis thaliana MGD1 gene Proteins 0.000 description 1
- 241000222122 Candida albicans Species 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 235000015459 Lycium barbarum Nutrition 0.000 description 1
- 244000241838 Lycium barbarum Species 0.000 description 1
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 229940095731 candida albicans Drugs 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 150000001896 cresols Chemical class 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 239000002085 irritant Substances 0.000 description 1
- 231100000021 irritant Toxicity 0.000 description 1
- 239000012669 liquid formulation Substances 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 235000012054 meals Nutrition 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 231100000957 no side effect Toxicity 0.000 description 1
- 231100000956 nontoxicity Toxicity 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 230000003204 osmotic effect Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000005201 scrubbing Methods 0.000 description 1
- 210000002374 sebum Anatomy 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 235000013599 spices Nutrition 0.000 description 1
- 239000003206 sterilizing agent Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 235000012976 tarts Nutrition 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- OHOTVSOGTVKXEL-UHFFFAOYSA-K trisodium;2-[bis(carboxylatomethyl)amino]propanoate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)C(C)N(CC([O-])=O)CC([O-])=O OHOTVSOGTVKXEL-UHFFFAOYSA-K 0.000 description 1
- 229960004418 trolamine Drugs 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
Abstract
The invention relates to a liquid detergent dedicated for underwear, which is composed of the following components in percentage by mass: 8-12% of fatty alcohol-polyoxyethylene ether (3) sodium sulphate (70%), 8-12% of cocamidopropyl betaine (30%), 1-3% of coconut monoethanol amide, 2-4% of fatty alcohol-polyoxyethylene ether (EO=6-12), 0.5-2% of C3-4 polyalcohol, 0.1-0.5% of 4-Cl-3,5 xylenol and the balance water. The liquid detergent dedicated for underwear of the invention has strong detergency, thoroughly removes stubborn dirt, such as bloodstains, milk stains, urine stains, greasy dirt and the like, and has obvious inhibition and killing actions on staphylococcus aureus, streptococcus and tritirachium album; the pH value of the liquid detergent is 6-8, and thus the liquid detergent has neutral formula and moderate property, does not hurt clothes, has no stimulation on skins, is moderate, protects hands, and is suitable for cleaning intimates, such as baby clothes, diaper, underwear, thermal underwear and the like.
Description
Technical field
The present invention relates to a kind of liquid washing agent, relate in particular to a kind of underwear dedicated liquid washing composition.
Background technology
The clothing cleaning is one of human lives's problem from start to finish.Generally speaking, clothes washing promptly is decontamination, and underwear is near the clothing of health, so must note cleaning more than coat, comfortable, maintenance etc.
For underwear, washing process is not only and is removed dirt, it should be noted that simultaneously: do not hinder material, colour-fast, and can effectively kill harmful germ.
General washing composition concerning underwear, can only play soil-removing action, but do not possess germicidal action, so people will carry out sterilization again with special sterilant, at present, sterilization mode mainly contains following a few class: chlorine-containing disinfectant, oxygen-containing disinfectant and cresols class sterilizing agent.Above sterilant all will use separately, and is very inconvenient, and not environmental protection, really can do washing, again can sterilization, and cost performance good, the human consumer can accept, the antibiotic product of the antimicrobial laundry liquid of disinfecting and decontaminating is not simultaneously seen as yet.
A kind of hyperconcentrated phosphate-free antiseptic disinfecting antimicrobial laundry liquid of disinfecting and decontaminating is simultaneously disclosed in the Chinese patent application 98113408.4.This simultaneously the antimicrobial laundry liquid of disinfecting and decontaminating it is characterized in that composition is C12-C15 fatty alcohol-polyoxyethylene ether, the basic sodium sulfonate of dodecane, trolamine, ethanol, Repone K, dodecyl dimethyl benzyl ammonium chloride and water.Only dodecyl dimethyl benzyl ammonium chloride is only arranged as sterilant in the prescription, sterilization effect is limited, and, not mentioned this quantized data of sterilization effect of the antimicrobial laundry liquid of disinfecting and decontaminating simultaneously in this patent application.
Summary of the invention
Technical problem to be solved by this invention provides a kind of underwear dedicated liquid washing composition, and neutral prescription has strong dirt-removing and the effect of efficient sterilizing antimicrobial.
For solving the problems of the technologies described above, the present invention is achieved through the following technical solutions:
A kind of underwear dedicated liquid washing composition, form by mass percentage by following component:
Fatty alcohol-polyoxyethylene ether (3) sodium sulfate (70%) 8%-12%
AMONYL 380LC (30%) 8%-12%
Oleum Cocois single ethanol amide 1%-3%
Fatty alcohol-polyoxyethylene ether (EO=6-12) 2%-4%
C3-4 polyvalent alcohol 0.5%-2%
4-chloro-3,5 xylenol 0.1%-0.5%
Water surplus.
Further, a kind of underwear dedicated liquid washing composition, form by mass percentage by following component:
Fatty alcohol-polyoxyethylene ether (3) sodium sulfate (70%) 8%-12%
AMONYL 380LC (30%) 8%-12%
Oleum Cocois single ethanol amide 1%-3%
Fatty alcohol-polyoxyethylene ether (EO=6-12) 2%-4%
C3-4 polyvalent alcohol 0.5%-2%
4-chloro-3,5 xylenol 0.1%-0.5%
Sodium-chlor 0.3%-1.0%
Sanitas 0.05%-0.2%
Citric acid 0.01%～0.05%
Essence 0.1%-0.5%
Water surplus.
Further, a kind of underwear dedicated liquid washing composition, form by mass percentage by following component:
Fatty alcohol-polyoxyethylene ether (3) sodium sulfate (70%) 8%-12%
AMONYL 380LC (30%) 8%-12%
Oleum Cocois single ethanol amide 1%-3%
Fatty alcohol-polyoxyethylene ether (EO=6-12) 2%-4%
C3-4 polyvalent alcohol 0.5%-2%
4-chloro-3,5 xylenol 0.1%-0.5%
Polyhexamethylene guanidine (25%) 0.05%-0.25%
Ultra 16XL proteinase-10 .15%～0.25%
Methylglycine oxalic acid 0.8%～1.0%
SECURON 540 organic complexing agents 0.8%～1.0%
Sodium-chlor 0.3%-1.0%
Sanitas 0.05%-0.2%
Citric acid 0.01%～0.05%
Essence 0.1%-0.5%
Water surplus.
In technique scheme,
The mass concentration of described fatty alcohol-polyoxyethylene ether (3) sodium sulfate (English name: Fatty alcoholpolyoxyethylene ether, sodium sulfate) is 70%.Molecular formula is: R (CH
2CH
2O)
3OSO
3Na, R=C
12～C
18It has good spumescence, lyotropy and soil removability, resistance to hard water is better, and pungency is less, and is soluble in water, and biological degradability is good.Can be used for that liquid scrubbing, meal are washed, shampoo, bath be with in the detergents and cosmetic industries such as washing.
Described AMONYL 380LC, English name: Cocoamidopropyl Betaine, be called for short (trade(brand)name): CAB, little yellow transparent liquid, active matter content are 30%.This raw material has good solvability and compatibleness, have good foaminess and significant thickening property, have low irritant and bactericidal properties, and compatibility uses softness, conditioning and the low-temperature stability that can significantly improve the washing series products, has good anti-hard water, static resistance and biological degradability.
Described Oleum Cocois single ethanol amide is called for short CMEA.Be a kind of nonionogenic tenside, solute and emulsifying property are all very strong, can be used as the pore forming material in the sanitising agent, thickening material.Pungency is low, is usually used in producing baby's sanitising agent, bath oil, the preparation of shampoo hand lotion and various special makeup.
Described fatty alcohol-polyoxyethylene ether (EO=6-12) is Fatty Alcohol(C12-C14 and C12-C18) and ethylene oxide condensate, EO=6-12, belong to nonionogenic tenside, soluble in water, in liquid washing agent important composition, good seepage force and detersive power are arranged, and degreasing power is stronger.Good to washing composition integral formula compatibleness.Reduce fabric fibre dyanainic friction coefficient and static friction coefficient effectively, strengthened the effect of treatment agent soft fluffy, and constant product quality.Have good softness and lubrication fabric and fiber are had good soft peaceful lubricant nature, also can improve fabric light, smooth, softness and elasticity.
Described C3-4 polyvalent alcohol comprises propylene glycol, glycerol, butyleneglycol, trihydroxybutane, butantetraol.C3-4 polyvalent alcohol and all kinds of spices have better mutual solubility, and add the C3-4 polyvalent alcohol in this prescription, can effectively improve the anti-freezing property and the froth stability of washing liquid, and are the stablizers of zymin in the prescription.What is more important, C3-4 polyvalent alcohol wetting ability is better, can promote soil dispersion, and it is residual to reduce the clothing dirt, therefore can improve the detersive power of prescription washings, promotes its scourability.
4-chloro-3,5-xylenol, English trade(brand)name: PCMX, its molecular formula: C
8H
9ClO.Be a kind of safe, wide-spectrum bactericide efficiently, most gram-positive microorganisms, negative bacterium, fungi, mould are all killed effect,, nontoxicity non-stimulated to skin are the first-selected germ killing drugs through drugs approved by FDA.Have sterilization and rot-resistant double effects concurrently, make playing a role that it can both be efficient and safe in various germicidal applications.
Described polyhexamethylene guanidine, environment-friendly type macromolecule polymkeric substance disinfection sanitizer.Has following premium properties: the sterilization wide spectrum; Effective concentration is low; Speed of action is fast; Stable in properties; Soluble in water; Can use at normal temperatures; Antibacterial for a long time, have no side effect; Non-corrosiveness.
Described
Ultra 16XL proteolytic enzyme is the match that Novozymes Company produces
The superpower stable form of liquid protease 16XL.This raw material is superpower stable form liquid protease, be applied in the higher washing liquid of the present invention prescription of water-content in, that has not only improved washing liquid smears effect in advance, and has increased it and remove the ability of special spot.
Described methylglycine oxalic acid is called for short MGDA acid.It has better biological degradability than sequestrant EDTA, NTA commonly used, and is more stable under the PH of broad scope and high temperature, has higher calcium sequestration capacity, and inorganic sediment is had higher solubility property, and heavy metal is had sequestering power preferably.In the present invention, the methylglycine oxalic acid selects for use BASF AG to produce
M liquid.
Described SECURON 540 organic complexing agents are that a kind of tensio-active agent that do not contain that Henkel Corp. produces is the complexing agent of main component with the organic acid, and trade name is SECURON540.SECURON 540 is a kind of complex compounds of multi-usage efficiently, can decompose and remove the calcium soap precipitates thing, and heavy metal and metal ion are had outstanding complex ability, and the size of this ability depends on pH value, and optimum pH value circle is between 7 and 12.
Composite use by SECURON 540 organic complexing agents and methylglycine oxalic acid can improve calcium sequestration capacity, and reaches with tensio-active agent
Ultra 16XL proteolytic enzyme has good compatibleness, thereby further improves detersive power of the present invention.Comparatively speaking, conventional sequestrant is present in as EDTA and can causes proteolytic enzyme to lose activity fast in the prescription, has a strong impact on the washing clean effect of washing liquid of the present invention, and is firmly abandoned by the present invention.
Described sodium-chlor plays thickening power in liquid formulations of the present invention.
Described sanitas adopts industry sanitas commonly used, can for ECOCIDE B50/2 sanitas, ECOCIDE ITH2 sanitas,
95 sanitass or card pine.
Citric acid has another name called matrimony vine acid.Clear crystal, odorless has very strong tart flavour, and is soluble in water.In the present invention, in order to regulate the pH value of washing liquid.
In prescription, can also can freely select corresponding essence and pigment as required.
The present invention can adopt industry method in common to be prepared.For example, in mixing kettle, drop into water, under agitation condition, add fatty alcohol-polyoxyethylene ether (3) sodium sulfate (70%), AMONYL 380LC (30%), Oleum Cocois single ethanol amide, fatty alcohol-polyoxyethylene ether (EO=6-12), C3-4 polyvalent alcohol, 4-chloro-3,5 xylenol, can also add sodium-chlor, sanitas, citric acid, essence, water again according to concrete needs, mix, can obtain underwear dedicated liquid washing composition of the present invention.
The advantage of technical solution of the present invention is mainly reflected in following several respects:
1, strong detergency, can rapid osmotic to the fiber deep layer, remove stupid dirts such as bloodstain, milk stain, urine stain and greasy dirt.
2, bacterium, fungies such as streptococcus aureus, suis, Candida albicans there is tangible inhibitory or killing effect.
3, character gentleness.PH value 6-8, neutral prescription does not damage clothing, to the skin nonirritant, gentle handguard.
4, gross activity thing content is greater than 12%, and formulation cost is cheap.
5, product is fit to clean underclothes such as infants' wear, diaper, underwear underclothes and cold-proof underwear.
Embodiment
Embodiment 1
According to table 1 specified corresponding embodiment 1 component and content, carry out raw material and take by weighing.
In mixing kettle, drop into water, under agitation condition, add other each raw materials, stir, can obtain underwear dedicated liquid washing composition of the present invention.
Embodiment 2
According to table 1 specified corresponding embodiment 2 components and content, carry out raw material and take by weighing.Be prepared according to embodiment 1 preparation method, produce underwear dedicated liquid washing composition of the present invention.
Embodiment 3
According to table 1 specified corresponding embodiment 3 components and content, carry out raw material and take by weighing.Be prepared according to embodiment 1 preparation method, produce underwear dedicated liquid washing composition of the present invention.
Embodiment 4
According to table 1 specified corresponding embodiment 4 components and content, carry out raw material and take by weighing.Be prepared according to embodiment 1 preparation method, produce underwear dedicated liquid washing composition of the present invention.
Table 1
| Component | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 |
| Fatty alcohol-polyoxyethylene ether (3) sodium sulfate (70%) | 8％ | 12％ | 10％ | 11％ |
| AMONYL 380LC (30%) | 12％ | 8％ | 10％ | 9％ |
| The Oleum Cocois single ethanol amide | 3％ | 1％ | 2％ | 2.5％ |
| Fatty alcohol-polyoxyethylene ether (EO=6) | 2％ | - | - | - |
| Fatty alcohol-polyoxyethylene ether (EO=12) | - | 4％ | - | - |
| Fatty alcohol-polyoxyethylene ether (EO=9) | - | - | 3％ | 3％ |
| Propylene glycol | - | - | 1％ | 1.5％ |
| Glycerol | 0.5％ | - | - | - |
| Trihydroxybutane | - | 2％ | - | - |
| 4-chloro-3,5 xylenol | 0.5％ | 0.1％ | 0.3％ | 0.5％ |
| Sodium-chlor | - | - | 0.7％ | 1％ |
| The card pine | - | - | 0.1％ | 0.2％ |
| Citric acid | - | - | 0.01％ | 0.05％ |
| Essence | - | - | 0.1％ | 0.5％ |
| Water | Surplus | Surplus | Surplus | Surplus |
Embodiment 5
According to following component and content, carry out raw material and take by weighing.
Fatty alcohol-polyoxyethylene ether (3) sodium sulfate (70%) 11%
AMONYL 380LC (30%) 12%
Oleum Cocois single ethanol amide 2%
Fatty alcohol-polyoxyethylene ether (EO=9) 3%
Propylene glycol 1%
4-chloro-3,5 xylenol 0.5%
Polyhexamethylene guanidine (25%) 0.25%
Methylglycine oxalic acid 0.9%
SECURON 540 organic complexing agents 0.9%
Sodium-chlor 0.8%
Card pine 0.1%
Citric acid 0.03%
Essence 0.5%
Water surplus.
In mixing kettle, drop into water, under agitation condition, add other each raw materials, stir, can obtain underwear dedicated liquid washing composition of the present invention.
Embodiment 6
Detergency test:
According to the method for QB/T 1224-2007 regulation, detect the detersive power of the embodiment of the invention 1, embodiment 2, embodiment 3, embodiment 4 and embodiment 5 described washing liquids.
The standard flour strength of solution is 0.2%, and washing liquid strength of solution to be measured is 0.3%, respectively with the preparation of 250mg/kg hard water, adopts the method and the soiled cotton of QB/T 13174-2008 regulation, measures the detersive power of washing liquid sample and standard flour with machine.
The concrete data that detect see table 2 for details.As seen, gross activity thing content about 12% embodiment 1,2,3 and 4 detersive power, meet C level decontamination standard.Embodiment 5, meet A level decontamination standard.
Table 2: the detersive power of washing liquid detects data
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | |
| Decontamination ratio, (carbon black soiled cotton), P | 1.08 | 1.06 | 1.11 | 1.14 | 1.21 |
| Decontamination ratio, (albumen soiled cotton), P | 0.73 | 0.71 | 0.87 | 0.84 | 1.18 |
| Decontamination ratio, (sebum soiled cotton), P | 0.85 | 0.83 | 0.90 | 0.86 | 1.03 |
Embodiment 7:
Sterilization experiment
According to the method for GB 19877.1-2005 regulation, detect the embodiment of the invention 1, embodiment 2, embodiment 3 and embodiment 4 described washing liquids to streptococcus aureus and intestinal bacteria sterilizing rate and bacteriostasis rate, concrete data see Table 3.
Table 3: sterilization effect data (unit: %)
| Technical requirements | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | |
| The streptococcus aureus sterilizing rate | - | 70.2 | 48.2 | 67.2 | 70.6 | 92.13 |
| The intestinal bacteria sterilizing rate | - | 50.6 | 25.8 | 32.2 | 48.8 | 90.83 |
| The streptococcus aureus bacteriostasis rate | ≥50 | 97.6 | 70.6 | 95.6 | 98.2 | 98.72 |
| The intestinal bacteria bacteriostasis rate | ≥50 | 70.8 | 50.4 | 59.0 | 70.2 | 97.54 |
Undoubtedly, the present invention can also have multiple conversion and remodeling, is not limited to the specific embodiment of above-mentioned embodiment.In a word, protection scope of the present invention should comprise those conspicuous to those skilled in the art conversion or substitute and remodeling.
Claims (3)
1. a underwear dedicated liquid washing composition is characterized in that, is made up of by mass percentage following component:
Fatty alcohol-polyoxyethylene ether (3) sodium sulfate (70%) 8%-12%
AMONYL 380LC (30%) 8%-12%
Oleum Cocois single ethanol amide 1%-3%
Fatty alcohol-polyoxyethylene ether (EO=6-12) 2%-4%
C3-4 polyvalent alcohol 0.5%-2%
4-chloro-3,5 xylenol 0.1%-0.5%
Water surplus.
2. underwear dedicated liquid washing composition as claimed in claim 1 is characterized in that, is made up of by mass percentage following component:
Fatty alcohol-polyoxyethylene ether (3) sodium sulfate (70%) 8%-12%
AMONYL 380LC (30%) 8%-12%
Oleum Cocois single ethanol amide 1%-3%
Fatty alcohol-polyoxyethylene ether (EO=6-12) 2%-4%
C3-4 polyvalent alcohol 0.5%-2%
4-chloro-3,5 xylenol 0.1%-0.5%
Sodium-chlor 0.3%-1.0%
Sanitas 0.05%-0.2%
Citric acid 0.01%～0.05%
Essence 0.1%-0.5%
Water surplus.
3. underwear dedicated liquid washing composition as claimed in claim 2 is characterized in that, is made up of by mass percentage following component:
Fatty alcohol-polyoxyethylene ether (3) sodium sulfate (70%) 8%-12%
AMONYL 380LC (30%) 8%-12%
Oleum Cocois single ethanol amide 1%-3%
Fatty alcohol-polyoxyethylene ether (EO=6-12) 2%-4%
C3-4 polyvalent alcohol 0.5%-2%
4-chloro-3,5 xylenol 0.1%-0.5%
Polyhexamethylene guanidine (25%) 0.05%-0.25%
Methylglycine oxalic acid 0.8%～1.0%
SECURON 540 organic complexing agents 0.8%～1.0%
Sodium-chlor 0.3%-1.0%
Sanitas 0.05%-0.2%
Citric acid 0.01%～0.05%
Essence 0.1%-0.5%
Water surplus.
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| CN2009101946700A CN101993793B (en) | 2009-08-27 | 2009-08-27 | Liquid detergent dedicated for underwear |
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| CN2009101946700A CN101993793B (en) | 2009-08-27 | 2009-08-27 | Liquid detergent dedicated for underwear |
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| CN101993793B CN101993793B (en) | 2012-11-21 |
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| CN104928064A (en) * | 2015-06-15 | 2015-09-23 | 马建剑 | Novel soaking type detergent used for underwear and preparation method thereof |
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Effective date of registration: 20221130 Address after: 7th Floor, Building 143, No. 2310, Yangshupu Road, Yangpu District, Shanghai 200090 Patentee after: Shanghai Soap Factory Co.,Ltd. Address before: No. 1340, Gulang Road, Putuo District, Shanghai, 200331 Patentee before: Shanghai Soap Co.,Ltd. |