CN101993793B - Liquid detergent dedicated for underwear - Google Patents
Liquid detergent dedicated for underwear Download PDFInfo
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- CN101993793B CN101993793B CN2009101946700A CN200910194670A CN101993793B CN 101993793 B CN101993793 B CN 101993793B CN 2009101946700 A CN2009101946700 A CN 2009101946700A CN 200910194670 A CN200910194670 A CN 200910194670A CN 101993793 B CN101993793 B CN 101993793B
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Abstract
The invention relates to a liquid detergent dedicated for underwear, which is composed of the following components in percentage by mass: 8-12% of fatty alcohol-polyoxyethylene ether (3) sodium sulphate (70%), 8-12% of cocamidopropyl betaine (30%), 1-3% of coconut monoethanol amide, 2-4% of fatty alcohol-polyoxyethylene ether (EO=6-12), 0.5-2% of C3-4 polyalcohol, 0.1-0.5% of 4-Cl-3,5 xylenol and the balance water. The liquid detergent dedicated for underwear of the invention has strong detergency, thoroughly removes stubborn dirt, such as bloodstains, milk stains, urine stains, greasy dirt and the like, and has obvious inhibition and killing actions on staphylococcus aureus, streptococcus and tritirachium album; the pH value of the liquid detergent is 6-8, and thus the liquid detergent has neutral formula and moderate property, does not hurt clothes, has no stimulation on skins, is moderate, protects hands, and is suitable for cleaning intimates, such as baby clothes, diaper, underwear, thermal underwear and the like.
Description
Technical field
The present invention relates to a kind of liquid washing agent, relate in particular to a kind of underwear dedicated liquid washing composition.
Background technology
The clothing cleaning is one of human lives's problem from start to finish.Generally speaking, clothes washing promptly is decontamination, and underwear is near the clothing of health, so must note cleaning more than coat, comfortable, maintenance etc.
As far as underwear, washing process is not only and is removed dirt, it should be noted that simultaneously: do not hinder material, colour-fast, and can effectively kill harmful germ.
General washing composition concerning underwear, can only play soil-removing action; But do not possess germicidal action; So people will carry out sterilization again with special sterilant, at present, sterilization mode mainly contains following several types: chlorine-containing disinfectant, oxygen-containing disinfectant and cresols class sterilizing agent.Above sterilant all will use separately, and is very inconvenient, and not environmental protection, really can do washing, again can sterilization, and cost performance good, the human consumer can accept, the antibiotic product of the antimicrobial laundry liquid of disinfecting and decontaminating is not simultaneously seen as yet.
A kind of hyperconcentrated phosphate-free antiseptic disinfecting antimicrobial laundry liquid of disinfecting and decontaminating is simultaneously disclosed in the one Chinese patent application 98113408.4.This simultaneously the antimicrobial laundry liquid of disinfecting and decontaminating it is characterized in that composition is C12-C15 AEO, the basic sodium sulfonate of dodecyl, trolamine, ethanol, Repone K, Zephirol and water.Only Zephirol is only arranged as sterilant in the prescription, sterilization effect is limited, and, not mentioned this quantized data of sterilization effect of the antimicrobial laundry liquid of disinfecting and decontaminating simultaneously in this patented claim.
Summary of the invention
Technical problem to be solved by this invention provides a kind of underwear dedicated liquid washing composition, and neutral prescription has strong dirt-removing and the effect of efficient sterilizing antimicrobial.
For solving the problems of the technologies described above, the present invention realizes through following technical scheme:
A kind of underwear dedicated liquid washing composition, form by mass percentage by following component:
AEO (3) sodium sulfate (70%) 8%-12%
AMONYL 380LC (30%) 8%-12%
Oleum Cocois single ethanol amide 1%-3%
AEO (EO=6-12) 2%-4%
C3-4 polyvalent alcohol 0.5%-2%
4-chloro-3,5 xylenol 0.1%-0.5%
Water surplus.
Further, a kind of underwear dedicated liquid washing composition, form by mass percentage by following component:
AEO (3) sodium sulfate (70%) 8%-12%
AMONYL 380LC (30%) 8%-12%
Oleum Cocois single ethanol amide 1%-3%
AEO (EO=6-12) 2%-4%
C3-4 polyvalent alcohol 0.5%-2%
4-chloro-3,5 xylenol 0.1%-0.5%
Sodium-chlor 0.3%-1.0%
Sanitas 0.05%-0.2%
Hydrocerol A 0.01%～0.05%
Essence 0.1%-0.5%
Water surplus.
Further, a kind of underwear dedicated liquid washing composition, form by mass percentage by following component:
AEO (3) sodium sulfate (70%) 8%-12%
AMONYL 380LC (30%) 8%-12%
Oleum Cocois single ethanol amide 1%-3%
AEO (EO=6-12) 2%-4%
C3-4 polyvalent alcohol 0.5%-2%
4-chloro-3,5 xylenol 0.1%-0.5%
Polyhexamethylene guanidine (25%) 0.05%-0.25%
Ultra 16XL proteinase-10 .15%～0.25%
Methylglycine oxalic acid 0.8%～1.0%
SECURON 540 organic complexing agents 0.8%～1.0%
Sodium-chlor 0.3%-1.0%
Sanitas 0.05%-0.2%
Hydrocerol A 0.01%～0.05%
Essence 0.1%-0.5%
Water surplus.
In technique scheme,
The mass concentration of described AEO (3) sodium sulfate (English name: Fatty alcoholpolyoxyethylene ether, sodium sulfate) is 70%.Molecular formula is: R (CH
2CH
2O)
3OSO
3Na, R=C
12～C
18It has good spumescence, lyotropy and soil removability, resistance to hard water is better, and pungency is less, and is soluble in water, and biological degradability is good.Can be used for that liquid scrubbing, meal are washed, shampoo, bath be with in the detergents and cosmetic industries such as washing.
Described AMONYL 380LC, English name: Cocoamidopropyl Betaine, be called for short (trade(brand)name): CAB, little yellow transparent liquid, active matter content are 30%.This raw material has good solvability and compatibleness, have good lathering property and significant thickening property, have low irritant and bactericidal properties, and compatibility uses softness, conditioning and the low-temperature stability that can significantly improve the washing series products, has good anti-hard water property, static resistance and biological degradability.
Described Oleum Cocois single ethanol amide is called for short CMEA.Be a kind of nonionogenic tenside, solute and emulsifying property are all very strong, can be used as the pore forming material in the sanitising agent, thickening material.Pungency is low, is usually used in producing baby's sanitising agent, bath oil, the preparation of shampoo hand lotion and various special makeup.
Described AEO (EO=6-12) is Fatty Alcohol(C12-C14 and C12-C18) and ethylene oxide condensate, and EO=6-12 belongs to nonionogenic tenside, and is soluble in water, in liquid washing agent, is important composition, and good seepage force and detersive power are arranged, and degreasing power is stronger.Good to washing composition integral formula compatibleness.Reduce fabric fibre dyanainic friction coefficient and static friction coefficient effectively, strengthened the effect of treatment agent soft fluffy, and constant product quality.Have good softness and lubrication fabric and fiber are had good soft peaceful lubricant nature, also can improve fabric light, smooth, softness and elasticity.
Described C3-4 polyvalent alcohol comprises Ucar 35, USP Kosher, butyleneglycol, trihydroxybutane, butantetraol.C3-4 polyvalent alcohol and all kinds of spices have better mutual solubility, and in this prescription, add the C3-4 polyvalent alcohol, can effectively improve the anti-freezing property and the froth stability of washing liquid, and are the stablizers of zymin in the prescription.What is more important, C3-4 polyvalent alcohol wetting ability is better, can promote soil dispersion, and it is residual to reduce the clothing dirt, therefore can improve the detersive power of prescription washings, promotes its scourability.
4-chloro-3,5-xylenol, English trade(brand)name: PCMX, its molecular formula: C
8H
9ClO.Be a kind of safe, wide-spectrum bactericide efficiently, most gram-positive microorganisms, negative bacterium, fungi, mould are all killed effect,, nontoxicity non-stimulated to skin are the first-selected germ killing drugs through drugs approved by FDA.Have sterilization and rot-resistant double effects concurrently, make playing a role that it can both be efficient and safe in various germicidal applications.
Described polyhexamethylene guanidine, environment-friendly type macromolecule polymkeric substance disinfection sanitizer.Has following premium properties: the sterilization wide spectrum; Effective concentration is low; Speed of action is fast; Stable in properties; Soluble in water; Can use at normal temperatures; Antibacterial for a long time, have no side effect; Non-corrosiveness.
Said
Ultra 16XL proteolytic enzyme is
superpower stable form of liquid protease 16XL that Novozymes Company produces.This raw material is superpower stable form liquid protease, be applied in the higher washing liquid of the present invention prescription of water-content in, not only improved the precoating of washing liquid and smeared effect, and increased it and remove the ability of special spot.
Described methylglycine oxalic acid is called for short MGDA acid.It has better biological degradability than sequestrant EDTA, NTA commonly used, and is more stable under the PH of broad scope and high temperature, has higher calcium sequestration capacity, and inorganic sediment is had higher solubility property, and heavy metal is had sequestering power preferably.In the present invention, the methylglycine oxalic acid is selected
M liquid that BASF AG produces for use.
Described SECURON 540 organic complexing agents are that a kind of tensio-active agent that do not contain that Henkel Corp. produces is the complexing agent of staple with the organic acid, and trade name is SECURON540.SECURON 540 is a kind of complex compounds of multi-usage efficiently, can decompose and remove the calcium soap precipitates thing, and heavy metal and metals ion are had outstanding complex ability, and the size of this ability depends on pH value, and optimum pH value circle is between 7 and 12.
Composite use through SECURON 540 organic complexing agents and methylglycine oxalic acid; Can improve calcium sequestration capacity; And have good compatibleness with tensio-active agent and
Ultra 16XL proteolytic enzyme, thereby further improve detersive power of the present invention.Comparatively speaking, conventional sequestrant is present in like EDTA and can causes proteolytic enzyme to lose activity fast in the prescription, has a strong impact on the washing clean effect of washing liquid of the present invention, and is firmly abandoned by the present invention.
Described sodium-chlor plays thickening power in liquid formulations of the present invention.
Described sanitas; Adopt industry sanitas commonly used, can be ECOCIDE B50/2 sanitas, ECOCIDE ITH2 sanitas,
95 sanitass or card pine.
Hydrocerol A has another name called matrimony vine acid.Clear crystal, odorless has very strong tart flavour, and is soluble in water.In the present invention, in order to regulate the pH value of washing liquid.
In prescription, can also can freely select corresponding essence and pigment as required.
The present invention can adopt industry method in common to prepare.For example, in mixing kettle, drop into water; Under agitation condition; Add AEO (3) sodium sulfate (70%), AMONYL 380LC (30%), Oleum Cocois single ethanol amide, AEO (EO=6-12), C3-4 polyvalent alcohol, 4-chloro-3,5 xylenol, can also add sodium-chlor, sanitas, Hydrocerol A, essence, water again according to concrete needs; Mix, can obtain underwear dedicated liquid washing composition of the present invention.
The advantage of technical scheme of the present invention is mainly reflected in following several respects:
1, strong detergency, can rapid osmotic to the fiber deep layer, remove stupid dirts such as bloodstain, milk stain, urine stain and greasy dirt.
2, bacterium, fungies such as streptococcus aureus, suis, Candida albicans there is tangible inhibitory or killing effect.
3, character is gentle.PH value 6-8, neutral prescription does not damage clothing, to the skin nonirritant, gentle handguard.
4, gross activity thing content is greater than 12%, and formulation cost is cheap.
5, product is fit to clean underclothes such as infants' wear, diaper, underwear underclothes and cold-proof underwear.
Embodiment
Embodiment 1
According to table 1 specified corresponding embodiment 1 component and content, carry out raw material and take by weighing.
In mixing kettle, drop into water, under agitation condition, add other each raw materials, stir, can obtain underwear dedicated liquid washing composition of the present invention.
Embodiment 2
According to table 1 specified corresponding embodiment 2 components and content, carry out raw material and take by weighing.Prepare according to embodiment 1 preparation method, produce underwear dedicated liquid washing composition of the present invention.
Embodiment 3
According to table 1 specified corresponding embodiment 3 components and content, carry out raw material and take by weighing.Prepare according to embodiment 1 preparation method, produce underwear dedicated liquid washing composition of the present invention.
Embodiment 4
According to table 1 specified corresponding embodiment 4 components and content, carry out raw material and take by weighing.Prepare according to embodiment 1 preparation method, produce underwear dedicated liquid washing composition of the present invention.
Table 1
| Component | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 |
| AEO (3) sodium sulfate (70%) | 8％ | 12％ | 10％ | 11％ |
| AMONYL 380LC (30%) | 12％ | 8％ | 10％ | 9％ |
| The Oleum Cocois single ethanol amide | 3％ | 1％ | 2％ | 2.5％ |
| AEO (EO=6) | 2％ | - | - | - |
| AEO (EO=12) | - | 4％ | - | - |
| AEO (EO=9) | - | - | 3％ | 3％ |
| Ucar 35 | - | - | 1％ | 1.5％ |
| USP Kosher | 0.5％ | - | - | - |
| Trihydroxybutane | - | 2％ | - | - |
| 4-chloro-3,5 xylenol | 0.5％ | 0.1％ | 0.3％ | 0.5％ |
| Sodium-chlor | - | - | 0.7％ | 1％ |
| The card pine | - | - | 0.1％ | 0.2％ |
| Hydrocerol A | - | - | 0.01％ | 0.05％ |
| Essence | - | - | 0.1％ | 0.5％ |
| Water | Surplus | Surplus | Surplus | Surplus |
Embodiment 5
According to following component and content, carry out raw material and take by weighing.
AEO (3) sodium sulfate (70%) 11%
AMONYL 380LC (30%) 12%
Oleum Cocois single ethanol amide 2%
AEO (EO=9) 3%
Ucar 35 1%
4-chloro-3,5 xylenol 0.5%
Polyhexamethylene guanidine (25%) 0.25%
Methylglycine oxalic acid 0.9%
SECURON 540 organic complexing agents 0.9%
Sodium-chlor 0.8%
Card pine 0.1%
Hydrocerol A 0.03%
Essence 0.5%
Water surplus.
In mixing kettle, drop into water, under agitation condition, add other each raw materials, stir, can obtain underwear dedicated liquid washing composition of the present invention.
Embodiment 6
Detergency test:
According to the method for QB/T 1224-2007 regulation, detect the detersive power of the embodiment of the invention 1, embodiment 2, embodiment 3, embodiment 4 and embodiment 5 said washing liquids.
The standard flour strength of solution is 0.2%, and washing liquid strength of solution to be measured is 0.3%, respectively with the preparation of 250mg/kg hard water, adopts the method and the soiled cotton of QB/T 13174-2008 regulation, measures the detersive power of washing liquid sample and standard flour with machine.
The concrete data that detect see table 2 for details.Thus it is clear that,, meet C level decontamination standard at embodiment 1,2,3 and 4 the detersive power of gross activity thing content about 12%.Embodiment 5, meet A level decontamination standard.
Table 2: the detersive power of washing liquid detects data
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | |
| Decontamination ratio, (carbon black soiled cotton), P | 1.08 | 1.06 | 1.11 | 1.14 | 1.21 |
| Decontamination ratio, (albumen soiled cotton), P | 0.73 | 0.71 | 0.87 | 0.84 | 1.18 |
| Decontamination ratio, (sebum soiled cotton), P | 0.85 | 0.83 | 0.90 | 0.86 | 1.03 |
Embodiment 7:
Sterilization experiment
According to the method for GB 19877.1-2005 regulation, detect the embodiment of the invention 1, embodiment 2, embodiment 3 and embodiment 4 said washing liquids to streptococcus aureus and intestinal bacteria sterilizing rate and bacteriostasis rate, concrete data are seen table 3.
Table 3: sterilization effect data (unit: %)
| Technical requirements | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | |
| The streptococcus aureus sterilizing rate | - | 70.2 | 48.2 | 67.2 | 70.6 | 92.13 |
| The intestinal bacteria sterilizing rate | - | 50.6 | 25.8 | 32.2 | 48.8 | 90.83 |
| The streptococcus aureus bacteriostasis rate | ≥50 | 97.6 | 70.6 | 95.6 | 98.2 | 98.72 |
| The intestinal bacteria bacteriostasis rate | ≥50 | 70.8 | 50.4 | 59.0 | 70.2 | 97.54 |
Undoubtedly, the present invention can also have multiple conversion and remodeling, is not limited to the specific embodiment of above-mentioned embodiment.In a word, protection scope of the present invention should comprise those conspicuous to those skilled in the art conversion or substitute and remodeling.
Claims (1)
1. a underwear dedicated liquid washing composition is characterized in that, is made up of by mass percentage following component:
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009101946700A CN101993793B (en) | 2009-08-27 | 2009-08-27 | Liquid detergent dedicated for underwear |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009101946700A CN101993793B (en) | 2009-08-27 | 2009-08-27 | Liquid detergent dedicated for underwear |
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|---|---|
| CN101993793A CN101993793A (en) | 2011-03-30 |
| CN101993793B true CN101993793B (en) | 2012-11-21 |
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| CN102559408B (en) * | 2011-12-30 | 2014-04-09 | 北京绿伞化学股份有限公司 | Pure plant type antibacterial cleanser and preparation method thereof |
| CN102888313B (en) * | 2012-10-10 | 2014-02-12 | 上海制皂有限公司 | Infant laundry detergent |
| CN103740491B (en) * | 2014-01-26 | 2016-08-17 | 广东景兴健康护理实业股份有限公司 | A kind of Antibacterial laundry detergent and processing technology thereof |
| CN103849493A (en) * | 2014-02-13 | 2014-06-11 | 上海方木精细化工有限公司 | Liquid laundry detergent for underwear |
| CN104928064A (en) * | 2015-06-15 | 2015-09-23 | 马建剑 | Novel soaking type detergent used for underwear and preparation method thereof |
| CN105713743A (en) * | 2016-01-26 | 2016-06-29 | 孟根森 | Antibacterial cleaning fluid for intelligent household articles |
| CN107723134A (en) * | 2017-11-30 | 2018-02-23 | 鹿寨卡森洗涤服务有限公司 | Cloth grass normal temperature neutral detergent |
| CN109957467A (en) * | 2017-12-25 | 2019-07-02 | 浙江神英科技有限公司 | A kind of Bactericidal underwear liquid detergent |
| CN108531315B (en) * | 2018-04-26 | 2020-12-18 | 内蒙古伊草恋生物科技有限责任公司 | Adult laundry detergent containing licorice extract |
| CN110713866B (en) * | 2018-07-13 | 2022-05-03 | 花王株式会社 | Liquid detergent composition for clothing |
| CN111748419A (en) * | 2020-06-30 | 2020-10-09 | 广州市金盛生物科技有限公司 | Antibacterial gel special for underwear and preparation method thereof |
| CN113004985A (en) * | 2021-03-15 | 2021-06-22 | 广州市家真惠实业有限公司 | Plant enzyme underwear laundry detergent |
| CN113621450A (en) * | 2021-08-10 | 2021-11-09 | 西埔(福建)医药用品有限公司 | Underwear laundry detergent with efficient sterilization function |
| CN115786041A (en) * | 2022-12-01 | 2023-03-14 | 济南鸿鹏生物科技发展有限公司 | Laundry detergent special for underwear |
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| CN1229335A (en) * | 1996-07-16 | 1999-09-22 | 普罗格特-甘布尔公司 | Use of combination of surfactants, chelating agents and essential oils for effective disinfection |
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2009
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Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1229335A (en) * | 1996-07-16 | 1999-09-22 | 普罗格特-甘布尔公司 | Use of combination of surfactants, chelating agents and essential oils for effective disinfection |
Non-Patent Citations (1)
| Title |
|---|
| 李秀安等."复方对氯间二甲基苯酚卫生洗液的杀菌效果与毒性试验观察".《中国消毒学杂志》.2006,第23卷(第3期), |
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Effective date of registration: 20221130 Address after: 7th Floor, Building 143, No. 2310, Yangshupu Road, Yangpu District, Shanghai 200090 Patentee after: Shanghai Soap Factory Co.,Ltd. Address before: No. 1340, Gulang Road, Putuo District, Shanghai, 200331 Patentee before: Shanghai Soap Co.,Ltd. |