CN102888313A - Infant laundry detergent - Google Patents
Infant laundry detergent Download PDFInfo
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- CN102888313A CN102888313A CN2012103830151A CN201210383015A CN102888313A CN 102888313 A CN102888313 A CN 102888313A CN 2012103830151 A CN2012103830151 A CN 2012103830151A CN 201210383015 A CN201210383015 A CN 201210383015A CN 102888313 A CN102888313 A CN 102888313A
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Abstract
The invention relates to infant laundry detergent, composed of 4-8% of fatty alcohol-polyoxyethylene ether, 12-16% of 70wt% methyl ester sulfonate, 4-8% of 50wt% alkyl glycoside, 2-4% of 25wt% potash soap, 8-10% of 35wt% cocamidopropyl betaine and the balance of water according to mass percentage, wherein main raw material used in the infant laundry detergent is degradable raw material and is biodegradable and environmental-friendly without containing matters such as fluorescent whitening agent, phosphorus, dioxane, nonyl/octyl phenol or nonyl/octyl phenol polyoxyethylene ether and the like; the infant laundry detergent is ecological and environmental-friendly and has good lime soap dispersing rate and soft and safe performance; the brightness, smoothness, softness and elasticity of textile can be improved; and the infant laundry detergent is characterized by low irritation, strong soil removability and easy rinsing and is suitable for washing infant clothes.
Description
Technical field
The present invention relates to a kind of washing liquid, relate in particular to a kind of infant liquid laundry detergent.
Background technology
Development along with the integrated and trade globalization of world economy, culture background, state of the art and environmental regulation become three large driving forces of articles for washing development of globalization gradually, the articles for washing in the whole world will tend to variation, but energy-conservation, water saving, product efficient, gentle, easy to use and that meet the safety and environment protection requirement will be the main flow directions that current and following cleaning product develops.
Because washing liquid has overcome some shortcomings of washing powder, develops very fast.As everyone knows, contain a large amount of weighting agent Sodium sulfate anhydrous.min(99) without any cleaning function in the washing powder, its massfraction having caused great waste aspect resource and the energy, also can cause dust pollution greater than 40% aborning, is unfavorable for environmental protection.And washing liquid has replaced Sodium sulfate anhydrous.min(99) with aboundresources and inexpensive water, adopts biodegradable tensio-active agent as main component and is aided with that phosphorus-free adjuvant is composite to be formed.Because facility investment is few, production technique is easy, and the performance gentleness is non-stimulated, is easy to dissolving and the characteristics such as easy to use, is accepted by people gradually.
But as a kind of emerging rising liquid product its deficiency is arranged also, that is exactly usually phosphorous, dioxan and white dyes etc. of conventional washing liquid.Infant liquid laundry detergent requires not contain the materials such as white dyes, phosphorus, dioxan, the ninth of the ten Heavenly Stems/octyl phenol and the ninth of the ten Heavenly Stems/polyoxyethylene octylphenol ether based on security consideration.
In order to improve Oeko-Tex Standard 100(ecological textile Valuation Standard) sign textiles security, simultaneously also more coordination and the better combination in order to promote that Oeko-Tex 100 authenticates and Oeko-Tex 1000 authenticates in the Oeko-Tex system, International Environmental Protection weaving association represents a few days ago, since in January, 2012, the NPEO among the APEO, OPEO, NP, OP have been included into sensing range.
Therefore, necessaryly develop a infant liquid laundry detergent that does not contain the materials such as white dyes, phosphorus, dioxan, the ninth of the ten Heavenly Stems/octyl phenol and the ninth of the ten Heavenly Stems/polyoxyethylene octylphenol ether.
Summary of the invention
Technical problem to be solved by this invention provides a kind of infant liquid laundry detergent, does not contain the materials such as white dyes, phosphorus, dioxan, the ninth of the ten Heavenly Stems/octyl phenol and the ninth of the ten Heavenly Stems/polyoxyethylene octylphenol ether.
For solving the problems of the technologies described above, the present invention is achieved through the following technical solutions:
A kind of infant liquid laundry detergent is made of by mass percentage following component:
Described fatty alcohol-polyoxyethylene ether, English name: Alcohol Ethoxylate.Its chemical formula is RO-(CH
2CH
2O)
n-H, R=C12-18 in the formula, n=6-18.Fatty alcohol-polyoxyethylene ether belongs to nonionic surface active agent, and outward appearance is oyster white or beige ointment shape, when molecular weight is higher, is solid state, and soluble in water, ethanol, ethylene glycol etc. have cloud point.Acidproof, alkaline-resisting, the anti-hard water of energy, heat-resisting, anti-heavy metallic salt.Have good wet performance, and have preferably emulsification, dispersion, the performance such as clean, can with various surfactants and dyestuff with molten use.
Preferably, described fatty alcohol-polyoxyethylene ether is AEO-9, i.e. fatty alcohol-polyoxyethylene ether-9, aliphatic alcohol polyethenoxy (9) ether.
Described methyl sodiosul foaliphatate is called for short MES.MES is a kind of efficient surfactant of making take the natural animal-plant grease as raw material, it has good wetting, emulsification, softness and anti-performance of hard water, solvability is good, biological degradation rate is high, little to skin irritation, foaming power is strong, particularly its foaming power is better than LAS and K12 in hard water, and detergency ability is good.Selecting mass content among the present invention is 70% methyl sodiosul foaliphatate.
Described alkyl glycoside, APG for short, synthetic by the pure and mild glucose of renewable resources natural fat, it is the more comprehensive new non-ionic surfactants of a kind of performance, have the characteristic of common nonionic and anion surfactant concurrently, having high surface, good ecological security and intermiscibility, is internationally recognized first-selection " green " functional surface promoting agent.Selecting mass content among the present invention is 50% alkyl glycoside.
Described potash soap claims again C12-18 lipid acid sylvite, its English name: Fatty acids, C12-18-potassium salts Fatty acids, C12-18-potassium salts, CAS number: 91032-02-9.Selecting mass content among the present invention is 25% potash soap.
The cocamidopropyl betaine of described 35wt% is called for short CAB-35.Cocamidopropyl betaine, CAS 86243-76-7.
Further,
A kind of infant liquid laundry detergent is made of by mass percentage following component:
Further,
A kind of infant liquid laundry detergent is made of by mass percentage following component:
Described organic complexing agent is a kind of or its mixture in aminocarboxylate, hydroxycarboxylate, organic phosphonate and the polyacrylic complexing agent.
Preferably, described organic complexing agent is Securon 540 organic complexing agents.
Described Securon 540 organic complexing agents are a kind of tensio-active agent complexing agents take organic acid as main component that do not contain that Henkel Corp. produces, and trade name is Securon 540.Securon 540 is a kind of efficient multi-usage complex compounds, can decompose and remove the calcium soap precipitates thing, and heavy metal and metal ion are had outstanding complex ability, and the size of this ability depends on the pH value, and optimum pH value circle is between 7 and 8.5.
Preferably, described organic complexing agent is made of by weight following component: the large acetic acid ferrisodium of quadrol two salicyls 40-60 part, two (the 2-amino-benzene oxygen)-ethane-N of 1,2-, N, N`, N`-tetraacethyl tetra-na salt 10-30 part, copolymer of maleic anhydride and acrylic acid 40-60 part.
Described sanitas adopts industry sanitas commonly used, can for ECOCIDE B50/2 sanitas, ECOCIDE ITH2 sanitas,
95 sanitass or Kathon CG.
Described essence adopts industry essence commonly used.In prescription, can freely select corresponding essence as required.
Obviously, in the present invention according to client's needs, can also freely add the pigment that is fit to, to adjust, to improve the color and luster of this product.
The present invention can adopt the general method of the industry to be prepared.For example, in mixing kettle, drop into water, under agitation condition, add other each raw materials, stir, can obtain infant liquid laundry detergent of the present invention.
The advantage of technical solution of the present invention is mainly reflected in following several respects:
1, green wash
The main raw material that uses in the prescription is the degradable starting material, can biological degradation, and be a kind of efficient surfactant of making as raw material take natural plant grease and glucose with MES, APG green material.
2, ecological, environmental protective
Adopt the natural environmental-protective raw material, product meets European Union and national professional institution authenticates, and this product is by the detection of ecological, without phosphorus, diox, white dyes etc.
3, adopt industry standard: QB 1224-2007 " dress material washes agent by liquid " detergent for silk and wool, wash association according to China: " washing composition and surfactant component are to the assessment of environment and human health safety ".
4, infant liquid laundry detergent has the gentle safety of good dispersion of calcium soap and performance, has improved the washing effect that is at hard water, has improved that fabric is bright, smooth, softness and elasticity.
Embodiment
Embodiment 1
According to table 1 specified corresponding embodiment 1 component and content, carry out raw material and take by weighing.
In mixing kettle, drop into water, be heated to 40-60 ℃, under agitation condition, add fatty alcohol-polyoxyethylene ether, the methyl sodiosul foaliphatate of 70wt%, the alkyl glycoside of 50wt%, the potash soap of 25wt% and the cocamidopropyl betaine of 35wt%, mix, can obtain infant liquid laundry detergent of the present invention.
Embodiment 2
According to table 1 specified corresponding embodiment 2 components and content, carry out raw material and take by weighing.
Preparation method according to embodiment 1 is prepared, and makes infant liquid laundry detergent of the present invention.
Embodiment 3
According to table 1 specified corresponding embodiment 3 components and content, carry out raw material and take by weighing.
In mixing kettle, drop into water, be heated to 40-60 ℃, under agitation condition, add fatty alcohol-polyoxyethylene ether, the methyl sodiosul foaliphatate of 70wt%, the alkyl glycoside of 50wt%, the potash soap of 25wt%, cocamidopropyl betaine and the organic complexing agent of 35wt%, mix, can obtain infant liquid laundry detergent of the present invention.
Embodiment 4
According to table 1 specified corresponding embodiment 4 components and content, carry out raw material and take by weighing.
Preparation method according to embodiment 3 is prepared, and makes infant liquid laundry detergent of the present invention.
Embodiment 5
According to table 1 specified corresponding embodiment 5 components and content, carry out raw material and take by weighing.
Preparation method according to embodiment 3 is prepared, and makes infant liquid laundry detergent of the present invention.
Embodiment 6
According to table 1 specified corresponding embodiment 6 components and content, carry out raw material and take by weighing.
In mixing kettle, drop into water, be heated to 40-60 ℃, under agitation condition, add fatty alcohol-polyoxyethylene ether, the methyl sodiosul foaliphatate of 70wt%, the alkyl glycoside of 50wt%, the potash soap of 25wt%, cocamidopropyl betaine, organic complexing agent, sanitas and the essence of 35wt%, mix, can obtain infant liquid laundry detergent of the present invention.
Table 1: formula table
| Component | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Embodiment 6 |
| Fatty alcohol-polyoxyethylene ether | 4% | 6% | 4% | 8% | 6% | 6% |
| The methyl sodiosul foaliphatate of 70wt% | 16% | 14% | 16% | 12% | 14% | 14% |
| The alkyl glycoside of 50wt% | 8% | 6% | 4% | 8% | 6% | 6% |
| The potash soap of 25wt% | 2% | 3% | 4% | 2% | 3% | 3% |
| The cocamidopropyl betaine of 35wt% | 10% | 9.2% | 8% | 10% | 9.2% | 9.2% |
| Organic complexing agent | / | / | 0.6% | 0.4% | 0.5% | 0.5% |
| Sanitas | / | / | / | / | / | 0.10% |
| Essence | / | / | / | / | / | 0.3% |
| Water | Surplus | Surplus | Surplus | Surplus | Surplus | Surplus |
Remarks: % all represents mass percent in the table 1, and each component sum of each embodiment is 100%.Table 2 is the concrete introduction of corresponding table 1 raw material.
Table 2: stock chart
| Material name | Concrete raw material introduction |
| Fatty alcohol-polyoxyethylene ether | The AEO-9 of BASF Aktiengesellschaft |
| The methyl sodiosul foaliphatate of 70wt% | The MES(70% of Zhejiang Province ZanYu Technology Co., Ltd) (top grade product) |
| The alkyl glycoside of 50wt% | The APG 1214 of China daily use chemicals institute |
| The potash soap of 25wt% | The potash soap of Shanghai Soap Making Co., Ltd. (25wt%) |
| The cocamidopropyl betaine of 35wt% | The CAB-35 of France Rhodia |
| Organic complexing agent | Securon 540 organic complexing agents of Henkel Corp. |
| Sanitas | The Kathon CG sanitas of Germany foreign cherry group |
Infant liquid laundry detergent of the present invention:
Material body: the transparent thick liquid of true qualities
Its physical and chemical index of fan board infant liquid laundry detergent detects by the QB/T1224-detergent for silk and wool.
Microbiological indicator: the requirement by relevant liquid product is carried out.
Control criterion in the infant liquid laundry detergent:
Total solids % 〉=20.0%;
PH (1% aqueous solution)=6.5-8.0
Viscosity (25 ℃) 〉=100S.
White dyes, dioxan, total Vanadium Pentoxide in FLAKES, nonyl phenol and octyl phenol do not detect.
The main raw material that uses in the infant liquid laundry detergent prescription of the present invention is the degradable starting material, energy biological degradation, environmental protection; Do not contain the materials such as white dyes, phosphorus, dioxan, the ninth of the ten Heavenly Stems/octyl phenol and the ninth of the ten Heavenly Stems/polyoxyethylene octylphenol ether, ecological, environmental protective; Have the gentle safety of good dispersion of calcium soap and performance, can improve bright property, slickness, pliability and the elasticity of fabric, pungency is low, and soil removability is strong, easily rinsing.Be suitable for the washing of infantile clothes.
Comparative example 1
Such as table 3, comparative example 1 is basic identical with embodiment 5 prescriptions, and unique difference is that comparative example 1 adopts EDTA-4Na as complexing agent, and embodiment 5 adopts Securon 540 organic complexing agents.
Preparation method according to embodiment 3 is prepared, and makes infant liquid laundry detergent.
Table 3: formula table
| The AEO-9 of BASF Aktiengesellschaft | 6% |
| The MES of Zhejiang Province ZanYu Technology Co., Ltd (70%) (top grade product) | 14% |
| The APG 1214 of China daily use chemicals institute | 6% |
| The potash soap of Shanghai Soap Making Co., Ltd. (25wt%) | 3% |
| The CAB-35 of France Rhodia | 9.2% |
| EDTA-4Na | 0.5% |
| Water | Surplus |
Test case
Detergency test:
According to the method for QB/T 1224-2007 regulation, detect the detersive power of infant liquid laundry detergent.
The standard flour strength of solution is 0.2%, and washing liquid strength of solution to be measured is 0.3%, respectively with the preparation of 250mg/kg hard water, adopts method and the soiled cotton of QB/T 13174-2008 regulation, measures the detersive power of washing liquid sample and standard flour with machine.
The concrete data that detect see table 4 for details.
Table 4
| Embodiment 2 | Embodiment 5 | Comparative example 1 | Embodiment 8 | |
| Decontamination ratio, (carbon black soiled cotton), P | 0.98 | 1.08 | 1.01 | 1.16 |
| Decontamination ratio, (albumen soiled cotton), P | 1.04 | 1.22 | 1.06 | 1.35 |
| Decontamination ratio, (sebum soiled cotton), P | 1.01 | 1.14 | 1.00 | 1.21 |
Embodiment 7
In the present invention, described organic complexing agent can also adopt following compound organic complexing agent, Securon 540 organic complexing agents among the embodiment 3-6 all available described compound organic complexing agent substitute, add-on is identical, and the stability of product also has no effect, and detersive power is significantly improved.
Described compound organic complexing agent is made of by weight following component: the large acetic acid ferrisodium of quadrol two salicyls 40-60 part, 1, two (the 2-amino-benzene oxygen)-ethane-N of 2-, N, N`, N`-tetraacethyl tetra-na salt 10-30 part, copolymer of maleic anhydride and acrylic acid 40-60 part.
The large acetic acid ferrisodium of quadrol two salicyls, CAS number: 16455-61-1.
Two (the 2-amino-benzene oxygen)-ethane-N of 1,2-, N, N`, N`-tetraacethyl tetra-na salt, CAS number: 126824-24-6.
Copolymer of maleic anhydride and acrylic acid is called for short AA/MA, CAS number: 26677-99-6.
Take by weighing: large acetic acid ferrisodium 50 weight parts of quadrol two salicyls, two (the 2-amino-benzene oxygen)-ethane-N of 1,2-, N, N`, N`-tetraacethyl tetra-na salt 20 weight parts, copolymer of maleic anhydride and acrylic acid 50 weight parts.Mix, namely make the compound organic complexing agent of present embodiment 7.
Embodiment 8
According to table 5 corresponding component and content, carry out raw material and take by weighing.
Preparation method according to embodiment 3 is prepared, and makes infant liquid laundry detergent of the present invention.
Table 5: formula table
| The AEO-9 of BASF Aktiengesellschaft | 6% |
| The MES of Zhejiang Province ZanYu Technology Co., Ltd (70%) (top grade product) | 14% |
| The APG 1214 of China daily use chemicals institute | 6% |
| The potash soap of Shanghai Soap Making Co., Ltd. (25wt%) | 3% |
| The CAB-35 of France Rhodia | 9.2% |
| The compound organic complexing agent of embodiment 7 | 0.5% |
| Water | Surplus |
Remarks: % all represents mass percent in the table 5, and each component sum of embodiment is 100%.
Embodiment 8 is carried out detergency test, and concrete data see Table 4.
Undoubtedly, the present invention can also have multiple conversion and remodeling, is not limited to the specific embodiment of above-mentioned embodiment.In a word, protection scope of the present invention should comprise those to those skilled in the art apparent conversion or substitute and change shape.
Claims (7)
1. an infant liquid laundry detergent is characterized in that, is comprised of by mass percentage following component:
2. an infant liquid laundry detergent is characterized in that, is comprised of by mass percentage following component:
3. an infant liquid laundry detergent is characterized in that, is comprised of by mass percentage following component:
4. such as each described infant liquid laundry detergent among the claim 1-3, it is characterized in that: described fatty alcohol-polyoxyethylene ether is AEO-9.
5. infant liquid laundry detergent as claimed in claim 2 or claim 3, it is characterized in that: described organic complexing agent is a kind of or its mixture in aminocarboxylate, hydroxycarboxylate, organic phosphonate and the polyacrylic complexing agent.
6. infant liquid laundry detergent as claimed in claim 5, it is characterized in that: described organic complexing agent is Securon 540 organic complexing agents.
7. infant liquid laundry detergent as claimed in claim 5, it is characterized in that: described organic complexing agent, formed by weight by following component: the large acetic acid ferrisodium of quadrol two salicyls 40-60 part, 1, two (the 2-amino-benzene oxygen)-ethane-N of 2-, N, N`, N`-tetraacethyl tetra-na salt 10-30 part, copolymer of maleic anhydride and acrylic acid 40-60 part.
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103849494A (en) * | 2014-02-13 | 2014-06-11 | 上海方木精细化工有限公司 | Infant laundry detergent |
| CN104194965A (en) * | 2014-09-02 | 2014-12-10 | 山东建筑大学 | Mild and degradable laundry detergent |
| CN104593170A (en) * | 2014-12-15 | 2015-05-06 | 深圳市中健科技产业投资有限公司 | Strong-basicity electrolyzed water laundry detergent and preparation method thereof |
| CN106281745A (en) * | 2016-08-08 | 2017-01-04 | 深圳市兴业卓辉实业有限公司 | A kind of cleaning method being applicable to the cleaning agent formula of toilet's cleaning wiping cloth, preparation method and cleaning wiping cloth |
| CN107129874A (en) * | 2017-05-23 | 2017-09-05 | 句容耀皮节能玻璃科技发展有限公司 | A kind of automobile glass water and preparation method thereof |
| CN106281745B (en) * | 2016-08-08 | 2019-07-16 | 深圳市兴业卓辉实业有限公司 | A kind of cleaning method suitable for the cleaning agent formula of toilet's wiper, preparation method and wiper |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103849494A (en) * | 2014-02-13 | 2014-06-11 | 上海方木精细化工有限公司 | Infant laundry detergent |
| CN104194965A (en) * | 2014-09-02 | 2014-12-10 | 山东建筑大学 | Mild and degradable laundry detergent |
| CN104593170A (en) * | 2014-12-15 | 2015-05-06 | 深圳市中健科技产业投资有限公司 | Strong-basicity electrolyzed water laundry detergent and preparation method thereof |
| CN106281745A (en) * | 2016-08-08 | 2017-01-04 | 深圳市兴业卓辉实业有限公司 | A kind of cleaning method being applicable to the cleaning agent formula of toilet's cleaning wiping cloth, preparation method and cleaning wiping cloth |
| CN106281745B (en) * | 2016-08-08 | 2019-07-16 | 深圳市兴业卓辉实业有限公司 | A kind of cleaning method suitable for the cleaning agent formula of toilet's wiper, preparation method and wiper |
| CN107129874A (en) * | 2017-05-23 | 2017-09-05 | 句容耀皮节能玻璃科技发展有限公司 | A kind of automobile glass water and preparation method thereof |
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Effective date of registration: 20221123 Address after: 7th Floor, Building 143, No. 2310, Yangshupu Road, Yangpu District, Shanghai 200090 Patentee after: Shanghai Soap Factory Co.,Ltd. Address before: No. 1340, Gulang Road, Putuo District, Shanghai, 200331 Patentee before: Shanghai Soap Co.,Ltd. |