CN102242023A - Laundry liquid with washing and caring functions - Google Patents
Laundry liquid with washing and caring functions Download PDFInfo
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- CN102242023A CN102242023A CN 201110144054 CN201110144054A CN102242023A CN 102242023 A CN102242023 A CN 102242023A CN 201110144054 CN201110144054 CN 201110144054 CN 201110144054 A CN201110144054 A CN 201110144054A CN 102242023 A CN102242023 A CN 102242023A
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- washing
- washing liquid
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Abstract
The invention relates to a laundry liquid with washing and caring functions, and the laundry liquid comprises the following components in percentage by weight: 0.5-8% of cationic alkyl polyglycoside, 5-20% of anionic surfactant, 0.5-10% of nonionic surfactant, 0.5-35 of ampholytic surfactant, 0.1-1% of chelant and the balance of deionized water. The laundry liquid with washing and caring functions provided by the invention has the advantages of a common laundry liquid and also has the characteristics of a softener because of the addition of a novel cationic surfactant alkyl polyglycoside, thus the laundry liquid has a dual function of washing and caring.
Description
Technical field
The present invention relates to a kind of washing composition, refer in particular to a kind of washing and protect two-in-one washing liquid.
Background technology
Along with expanding economy, people's standard of living is greatly improved, and bigger change also takes place consumption idea thereupon, and laundry detergent has been the cleaning consumer's goods that huge numbers of families be unable to do without.Traditional cleaning product is a washing powder, has occurred liquid washing agent in recent years in succession: washing liquid, collar cleaner, silk hair are clean, down jackets clean-out system and softener.The main active substances of washing powder is straight chain dodecylbenzene sulfonate and other washing assistants; The straight chain dodecylbenzene sulfonate derives from petroleum chemicals, belongs to non-renewable raw material, and the not anti-hard water of this raw material, and detersive power reduces greatly under the tap water environment, is unfavorable for washing; Other auxiliary agents contain phosphorus, aluminium as 4A zeolite, tripoly phosphate sodium STPP, are unfavorable for environment protection; Soda ash, caustic soda alkalescence are higher, and clothing is faded, the damage clothing; Saltcake belongs to weighting material, and invalid recycle can bring unnecessary waste to operation.In addition, the common liq washing composition utilizes conventional surfactants and alkaline assistant, only has the washing cleaning action, and submissive effect is not good enough.
Summary of the invention
In view of this, the object of the present invention is to provide a kind of washing to protect two-in-one washing liquid, adopt novel cation tensio-active agent APG, composite other anion surfactant, nonionogenic tenside and amphotericses commonly used, its raw material is easy to get, and environmental friendliness makes product of the present invention have washing, nursing double effects, energy-saving and emission-reduction, easy to use.
For achieving the above object, the invention provides a kind of washing and protect two-in-one washing liquid, described each component and the mass fraction thereof that protect two-in-one washing liquid washed is:
Kation alkyl polysaccharide glycosides 0.5-8%;
Anion surfactant 5-20%;
Nonionogenic tenside 0.5-10%;
Amphoterics 0.5-3%;
Sequestrant 0.1-1%;
The deionized water surplus.
Preferably, wherein said each component and the mass fraction thereof that protect two-in-one washing liquid washed is:
Kation alkyl polysaccharide glycosides 2-6%;
Anion surfactant 8-15%;
Nonionogenic tenside 1-5%;
Amphoterics 0.5-2%;
Sequestrant 0.1-0.5%;
The deionized water surplus.
Preferably, wherein said cats product is a kation alkyl polysaccharide glycosides.
Preferably, wherein said anion surfactant is selected from one of following or its combination: polyoxyethylenated alcohol sodium sulfate, alhpa olefin sodium sulfonate, methyl sodiosul foaliphatate, Seconary Alkane Sulphonate Sodium and aliphatic alcohol polyethenoxy (10) ether carboxylic acid sodium.
Preferably, wherein said nonionogenic tenside is selected from one of following or its combination: aliphatic alcohol polyethenoxy (3) ether, aliphatic alcohol polyethenoxy (7) ether, aliphatic alcohol polyethenoxy (9) ether, secondary alcohol Soxylat A 25-7 and alkyl glycoside.
Preferably, wherein said amphoterics is selected from one of following or its combination: cocamidopropyl betaine and dodecyl dimethyl amine second lactone.
Preferably, wherein said sequestrant is selected from one of following or its combination: Trisodium Citrate and polyacrylate.
Preferably, wherein said washing protected two-in-one washing liquid and is added with liquid protease.
Preferably, wherein said washing protected two-in-one washing liquid and is added with essence or spices.
Preferably, wherein said washing protected two-in-one washing liquid and is added with food dye.
Preferably, wherein said washing protected two-in-one washing liquid and is added with sanitas.
Than prior art, the present invention has the following advantages:
1) provided by the present invention washing protected two-in-one washing liquid, adopt novel cation tensio-active agent APG, this raw material has the green of alkyl glycoside, natural, low toxicity and low stimulation characteristics, readily biodegradable, and is environmentally friendly, has the various cationic characteristics of quaternary ammonium salt concurrently; It is composite miscible also to have energy and anion surfactant simultaneously, a small amount of adding promptly produces the performance of intensive synergy, solved the difficult problem that the common cation tensio-active agent can not be composite with negatively charged ion, and the surface-active agent that adopts is that compound property is good, moderate notoxic, readily biodegradable and reproducible green surfactant;
2) provided by the present invention washing protected two-in-one washing liquid, and pH value is 6-8, and near neutral, pungency is low, and the clothing pliability is good after washing, and strong detergency all has good clean effect in cold water and the warm water.
Embodiment
Embodiment 1: a kind of washing protected two-in-one washing liquid, and its each component and mass fraction thereof are:
Kation alkyl polysaccharide glycosides 2%;
Polyoxyethylenated alcohol sodium sulfate (AES) 10%;
Alhpa olefin sodium sulfonate (AOS) 3%;
Alkyl glycoside (APG) 3%;
Aliphatic alcohol polyethenoxy (9) ether (AEO-9) 2%;
Cocamidopropyl betaine (CAB) 2%;
2-methyl isothiazole-3 (2H)-ketone (MIT) (sanitas) 0.1%;
Polyacrylate 0.2%;
Liquid protease (16XL) 0.3%;
Propylene glycol 5%;
Essence 0.1%;
Sodium-chlor 1.5%;
Deionized water 70.8%;
Wherein, described kation alkyl polysaccharide glycosides is a cats product, and available from Henan provincial highway purifying worker technology company limited, polyacrylate is a sequestrant, and propylene glycol is an enzyme stabilizers; Described liquid protease (16XL) is available from Novozymes Company (novozymes).
Embodiment 2: the embodiment 1 described preparation method's (in massfraction) who protects two-in-one washing liquid that washes:
1) adds load weighted deionized water 40.8% earlier, add polyoxyethylenated alcohol sodium sulfate (AES) 10%, alhpa olefin sodium sulfonate (AOS) 3%, alkyl glycoside (APG) 3%, cocamidopropyl betaine (CAB) 2%, aliphatic alcohol polyethenoxy (9) ether 2%, propylene glycol 5% then respectively, open the high-shear homogeneous and stir, make material become the emulsus particle;
2) add remaining 30% deionized water, open common stirring, add kation alkyl polysaccharide glycosides 2%, stir and make it dissolving;
3) add 2-methyl isothiazole-3 (2H)-ketone (MIT) (sanitas) 0.1%, polyacrylate 0.2%, liquid protease (16XL) 0.3%, essence 0.1%, sodium-chlor 1.5%, stir and make it dissolving;
4) filtering the back with 300 mesh filter screens packs.
Embodiment 3: a kind of washing protected two-in-one washing liquid, and its each component and mass fraction thereof are:
Kation alkyl polysaccharide glycosides 6%;
Methyl sodiosul foaliphatate (MES) 1%;
Seconary Alkane Sulphonate Sodium (SAS) 13%;
Aliphatic alcohol polyethenoxy (7) ether (AEO-7) 2%;
Aliphatic alcohol polyethenoxy (9) ether (AEO-9) 3%;
Dodecyl dimethyl amine second lactone (BS-12) 2%;
2-methyl isothiazole-3 (2H)-ketone (MIT) (sanitas) 0.1%;
Trisodium Citrate 0.5%;
Liquid protease (16XL) 0.3%;
Propylene glycol 5%;
Essence 0.1%;
Sodium-chlor 1.0%;
Deionized water 66%.
Wherein, described kation alkyl polysaccharide glycosides be cats product available from Henan provincial highway purifying worker technology company limited, propylene glycol is an enzyme stabilizers, Trisodium Citrate is a sequestrant; Described liquid protease (16XL) is available from Novozymes Company (novozymes).
Embodiment 4: effect
1, clean effect
According to the QB/T1224-2007 requirement, washing liquid detersive power of the present invention: JB-01 (carbon black soiled cotton): 1.2; JB-02 (albumen soiled cotton): 2.6; JB-03 (sebum soiled cotton): 1.2.
Conclusion: reach the A level requirement of standard code.
2, submissive effect experiment
1. material
20 * 20cm
2Some of identical towels, graduated scale, 2000mL beaker, 5000mL beaker.
2. experimental procedure
Towel is divided into some groups, 10 every group, first group of test that is used for this product, other groups are used for reference product, and the difference label; Get each 6g of this product and reference product, add the 2000g tap water respectively, dispersed with stirring is even; With No. 1 beaker of this product dispersion liquid injection 5000mL, the reference product dispersion liquid injects other corresponding label beakers of 5000mL; Simultaneously first group, other group towels are immersed respectively No. 1, No. 2, No. 3 ... in the beaker of 5000mL, complete wetting 5 minutes uses the 10kg water rinse clean then respectively, takes out nature and dries; With twice doubling of every towel, stack by original group, measure every group of height with graduated scale, record also compares its height, and highly big submissive effect is better.The result is as shown in table 1.
Table 1 comparative test result
Sequence number | The washing liquid title | Stack height (cm) |
1 | Commercially available washing liquid (1) | 20.5 |
2 | Commercially available washing liquid (2) | 20.8 |
3 | Commercially available washing liquid (3) | 18.5 |
4 | Commercially available washing liquid (4) | 20.0 |
5 | Commercially available washing liquid (5) | 19.2 |
6 | Commercially available washing liquid (6) | 20.5 |
7 | Commercially available washing liquid (7) | 20.3 |
8 | Commercially available washing liquid (8) | 19.2 |
9 | Embodiment 1 | 22.6 |
10 | Embodiment 3 | 24.2 |
Conclusion, as can be seen from Table 1, the embodiment of the invention 1, embodiment 3 stack height greater than commercially available common washing liquid, and be submissive respond well.
Provided by the present invention washing protected two-in-one washing liquid, adopt novel cation tensio-active agent APG, this raw material is to be undertaken quaternised modified or be a directly quaternized class novel cation tensio-active agent that forms of raw material with glucose by nonionic alkyl glycoside, have the green of alkyl glycoside, natural, low toxicity and the low characteristics that stimulate, readily biodegradable, environmentally friendly, have the various cationic characteristics of quaternary ammonium salt concurrently, it is composite miscible also to have energy and anion surfactant simultaneously, and a small amount of adding promptly produces the performance of intensive synergy.Therefore, the present invention is except that the decontamination with general washing composition, wetting and penetrating quality, also have effects such as submissive, the anti-electrostatic of laundry care agent and sterilization, avoided cleaning with washing liquid earlier in the conventional washing process, the back is loaded down with trivial details with softener nursing, and one step of two step operations finishes, for the human consumer saves time, laborsaving, water-saving and power saving, for the producer saves production, transportation and packing cost, to reach the effect of energy-saving and emission-reduction.
The above is preferred embodiment of the present invention only, is not to be used to limit scope of patent protection of the present invention.
Claims (11)
1. wash and protect two-in-one washing liquid for one kind, it is characterized in that described each component and the mass fraction thereof that protect two-in-one washing liquid washed is:
Kation alkyl polysaccharide glycosides 0.5-8%;
Anion surfactant 5-20%;
Nonionogenic tenside 0.5-10%;
Amphoterics 0.5-3%;
Sequestrant 0.1-1%;
The deionized water surplus.
2. according to claim 1 washing protected two-in-one washing liquid, it is characterized in that, described each component and the mass fraction thereof that protect two-in-one washing liquid washed is:
Kation alkyl polysaccharide glycosides 2-6%;
Anion surfactant 8-15%;
Nonionogenic tenside 1-5%;
Amphoterics 0.5-2%;
Sequestrant 0.1-0.5%;
The deionized water surplus.
3. according to claim 1 and 2 washing protected two-in-one washing liquid, it is characterized in that, described cats product is a kation alkyl polysaccharide glycosides.
4. according to claim 1 and 2 washing protected two-in-one washing liquid, it is characterized in that described anion surfactant is selected from one of following or its combination: polyoxyethylenated alcohol sodium sulfate, alhpa olefin sodium sulfonate, methyl sodiosul foaliphatate, Seconary Alkane Sulphonate Sodium and aliphatic alcohol polyethenoxy (10) ether carboxylic acid sodium.
5. according to claim 1 and 2 washing protected two-in-one washing liquid, it is characterized in that described nonionogenic tenside is selected from one of following or its combination: aliphatic alcohol polyethenoxy (3) ether, aliphatic alcohol polyethenoxy (7) ether, aliphatic alcohol polyethenoxy (9) ether, secondary alcohol Soxylat A 25-7 and alkyl glycoside.
6. according to claim 1 and 2 washing protected two-in-one washing liquid, it is characterized in that, described amphoterics is selected from one of following or its combination: cocamidopropyl betaine and dodecyl dimethyl amine second lactone.
7. according to claim 1 and 2 washing protected two-in-one washing liquid, it is characterized in that, described sequestrant is selected from one of following or its combination: Trisodium Citrate and polyacrylate.
8. according to claim 1 and 2 washing protected two-in-one washing liquid, it is characterized in that, described washing protected two-in-one washing liquid and be added with liquid protease.
9. according to claim 1 and 2 washing protected two-in-one washing liquid, it is characterized in that, described washing protected two-in-one washing liquid and be added with essence or spices.
10. according to claim 1 and 2 washing protected two-in-one washing liquid, it is characterized in that, described washing protected two-in-one washing liquid and be added with food dye.
11. according to claim 1 and 2 washing protected two-in-one washing liquid, it is characterized in that, described washing protected two-in-one washing liquid and is added with sanitas.
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CN102517177A (en) * | 2011-12-07 | 2012-06-27 | 广州青能健日用品有限公司 | Biological eco-friendly multifunctional specific laundry detergent and preparation method thereof |
CN102851131A (en) * | 2012-08-31 | 2013-01-02 | 湖南日用化学科学研究所有限公司 | Detergent with functions of decontamination, sterilization and fabric softening |
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CN103666838A (en) * | 2012-09-24 | 2014-03-26 | 天津博克尼科技发展有限公司 | Low-foam liquid laundry detergent |
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CN103773617A (en) * | 2014-01-14 | 2014-05-07 | 昆明理工大学 | Special scrubbing solution for footgear and preparation method thereof |
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