CN109694783A - A kind of color protection soft liquid laundry detergent and preparation method thereof - Google Patents
A kind of color protection soft liquid laundry detergent and preparation method thereof Download PDFInfo
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- CN109694783A CN109694783A CN201811511160.7A CN201811511160A CN109694783A CN 109694783 A CN109694783 A CN 109694783A CN 201811511160 A CN201811511160 A CN 201811511160A CN 109694783 A CN109694783 A CN 109694783A
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- Prior art keywords
- color protection
- fatty alcohol
- liquid detergent
- softness
- ether
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/86—Mixtures of anionic, cationic, and non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/349—Organic compounds containing sulfur additionally containing nitrogen atoms, e.g. nitro, nitroso, amino, imino, nitrilo, nitrile groups containing compounds or their derivatives or thio urea
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/74—Carboxylates or sulfonates esters of polyoxyalkylene glycols
Abstract
The present invention relates to a kind of color protection soft liquid laundry detergents and preparation method thereof.A kind of Liquid laundry composition of color protection softness, it is made of the following raw material: fatty alcohol polyoxyethylene ether, polyethylene glycol stearate diester, alkyl glycosides, sodium sulfate of polyethenoxy ether of fatty alcohol, citric acid, polydimethyl diallyl ammonium chloride, ternary polymerization silicone oil, preservative, essence, surplus are deionized water.Inventive formulation composition enables the polydimethyl diallyl ammonium chloride of cationic property and ternary polymerization silicone oil and anionic surfactant with washing clean effect is stable coexists, and has synergistic effect to the decontamination of product, increases clean effect；Wherein polydimethyl diallyl ammonium chloride can close the hydrophilic radical on dyestuff, and clothes is made to be not easy to fade, and have colour-preserving function；Ternary polymerization silicone oil, which can enter, makes clothing become fluffy inside clothes fiber, and reduces the frictional force between clothes fiber, and clothes fiber is made to become fluffy softness.
Description
Technical field:
The present invention relates to daily use chemicals cleaning product technical field, specially a kind of color protection soft liquid laundry detergent and preparation method thereof.
Background technique:
With social development, the raising of living standards of the people, cleaning product is also more intended to diversified development, energy conservation,
It is water-saving, efficient, environmental protection, mild and functional product by be current and future cleaning product develop Main way.
Contain a large amount of inorganic base salts in washing powder, in use can damaging laundry, residual can stimulate skin, in production
A large amount of dust can be generated, and is unfavorable for environmental protection；For ordinary liquid laundry detergent due to production technology simplicity, Nature comparison is mild, overcomes
Some disadvantages of washing powder, but the function of ordinary liquid laundry detergent also has deficiency, after repeatedly washing clothing can also be hardened with it is old
It is old.
Summary of the invention:
For the technical disadvantages for overcoming existing product, a kind of strong detergency, soft and color protection laundry detergent compositions, this hair are provided
It is bright to disclose a kind of color protection soft liquid laundry detergent composition and preparation method thereof.
The present invention adopts the following technical scheme that realization:
A kind of liquid detergent of color protection softness, is made of by mass percentage following component:
Fatty alcohol polyoxyethylene ether is aliphatic alcohol polyethenoxy (7) ether and aliphatic alcohol polyethenoxy (9) ether；
Polyethylene glycol stearate diester is the double stearates of Macrogol 6000；
Alkyl glycosides is C12-16Alkyl glycosides；
Sodium sulfate of polyethenoxy ether of fatty alcohol is aliphatic alcohol polyethenoxy (3) ether sodium sulfate (70%)；
Polydimethyl diallyl ammonium chloride, physicochemical property are active constituent 39-41%, viscosity 4000-12000cps,
PH value 4-7；
Chelating agent is citric acid；
Ternary polymerization silicone oil, which is selected, steps figure MAGNASOFT SRS amido silicon oil, active quantities 60%, pH value 5-7；
Preservative is at least one of isothiazolinone and methyl p-hydroxybenzoate；
Essence is that daily use chemicals industry often uses essence.
In further preferred scheme, the liquid detergent of the color protection softness, the raw material composition including following mass fraction:
Fatty alcohol polyoxyethylene ether 10%；
Polyethylene glycol stearate diester 5%；
Alkyl glycosides 5%；
Sodium sulfate of polyethenoxy ether of fatty alcohol 10%；
Chelating agent 1%；
Polydimethyl diallyl ammonium chloride 2%；
Preservative 0.2%；
Essence 0.5%；
Ternary polymerization silicone oil 5%；
Surplus is water.
The color protection soft liquid laundry detergent preparation method, the specific steps are as follows:
It weighs: according to formula rate, accurately weighing raw material, it is spare.
Preparation: being added a certain amount of deionized water in a stirring kettle, and temperature is raised to 60 DEG C -70 DEG C, poly alkyl alcohol is added
Fatty alcohol polyoxyethylene ether sulfuric acid is added to being completely dissolved in ethylene oxide ether, polyethylene glycol stearate diester, alkyl glycosides, stirring
Sodium, chelating agent, stirring is to being completely dissolved；Then balance deionized water is added, and cools the temperature to 40 DEG C hereinafter, sequentially adding poly-
Dimethyl diallyl ammonium chloride, ternary polymerization silicone oil, preservative, essence, stirring are filtered to being completely dissolved.
Liquid laundry composition provided by the present invention not only has stronger detergency to clothing, can satisfy consumer day
The often demand to washing effect in life, and the color of clothing can be protected without damage, assign the comfortable soft feel of clothing.
Inventive formulation composition make cationic property polydimethyl diallyl ammonium chloride and ternary polymerization silicone oil and
With washing clean effect anionic surfactant can be stable coexist, and to the decontamination of product have collaboration make
With increase clean effect；Wherein polydimethyl diallyl ammonium chloride can close the hydrophilic radical on dyestuff, be not easy clothes
It fades, there is colour-preserving function；Ternary polymerization silicone oil, which can enter, makes clothing become fluffy inside clothes fiber, and reduces clothing fibre
Frictional force between dimension makes clothes fiber become fluffy softness.
Specific embodiment:
Specific embodiments of the present invention are as follows:
Embodiment 1
A kind of liquid detergent of color protection softness, is made of by mass percentage following component:
The color protection soft liquid laundry detergent the preparation method is as follows:
It weighs: according to formula rate, accurately weighing raw material, it is spare.
Preparation: being added a certain amount of deionized water in a stirring kettle, and temperature is raised to 60 DEG C -70 DEG C, poly alkyl alcohol is added
Fatty alcohol polyoxyethylene ether sulfuric acid is added to being completely dissolved in ethylene oxide ether, polyethylene glycol stearate diester, alkyl glycosides, stirring
Sodium, chelating agent, stirring is to being completely dissolved；Then balance deionized water is added, and cools the temperature to 40 DEG C hereinafter, sequentially adding poly-
Dimethyl diallyl ammonium chloride, ternary polymerization silicone oil, preservative, essence, stirring are filtered to being completely dissolved.
Embodiment 2
A kind of liquid detergent of color protection softness, is made of by mass percentage following component:
The color protection soft liquid laundry detergent the preparation method is as follows:
It weighs: according to formula rate, accurately weighing raw material, it is spare.
Preparation: being added a certain amount of deionized water in a stirring kettle, and temperature is raised to 60 DEG C -70 DEG C, poly alkyl alcohol is added
Fatty alcohol polyoxyethylene ether sulfuric acid is added to being completely dissolved in ethylene oxide ether, polyethylene glycol stearate diester, alkyl glycosides, stirring
Sodium, chelating agent, stirring is to being completely dissolved；Then balance deionized water is added, and cools the temperature to 40 DEG C hereinafter, sequentially adding poly-
Dimethyl diallyl ammonium chloride, ternary polymerization silicone oil, preservative, essence, stirring are filtered to being completely dissolved.
Embodiment 3
A kind of liquid detergent of color protection softness, is made of by mass percentage following component:
The color protection soft liquid laundry detergent the preparation method is as follows:
It weighs: according to formula rate, accurately weighing raw material, it is spare.
Preparation: being added a certain amount of deionized water in a stirring kettle, and temperature is raised to 60 DEG C -70 DEG C, poly alkyl alcohol is added
Fatty alcohol polyoxyethylene ether sulfuric acid is added to being completely dissolved in ethylene oxide ether, polyethylene glycol stearate diester, alkyl glycosides, stirring
Sodium, chelating agent, stirring is to being completely dissolved；Then balance deionized water is added, and cools the temperature to 40 DEG C hereinafter, sequentially adding poly-
Dimethyl diallyl ammonium chloride, ternary polymerization silicone oil, preservative, essence, stirring are filtered to being completely dissolved.
I, detergency test
According to method as defined in QB/T1224-2012, detects the embodiment of the present invention 1, embodiment 2, does washing described in embodiment 3
The dirt-removing power of liquid, test data see the table below:
Upper table shows that color protection soft liquid laundry detergent is intended to preferably, say to the dirt-removing power power of three kinds of soiled cottons than standard liquid detergent
Bright detergency of the invention is stronger.
II, color protection performance test
Test method: 5L tap water is measured respectively in small-sized roller washing machine, is separately added into ordinary liquid laundry detergent, color protection is soft
Soft each 5g of liquid detergent, stirs evenly, each ethereal blue cotton (20cm × 20cm) that same size is added, and washs 15 points under equal conditions
Clock takes and washes rear raffinate, tests transmitance T using 721 type spectrophotometers, the serious transmitance T that fades is relatively low, and fade slight transmission
Rate T is higher, protects color ability with this to evaluate the color protection of liquid detergent, surveys three groups and be averaged, test data see the table below:
It is shown by upper table, compared with ordinary liquid laundry detergent, color protection softness washing lotion washs the larger through rate score of raffinate,
Raffinate transmitance after being apparently higher than ordinary liquid laundry detergent washing illustrates that the present invention has good color protection to protect color ability.
The test of III, flexibility
Test method: 5L tap water is measured respectively in small-sized roller washing machine, is separately added into ordinary liquid laundry detergent, color protection is soft
Soft each 5g of liquid detergent, stirs evenly, and identical cotton towel is respectively added, and after washing 15 minutes under the same terms, rinsing twice, takes off
It is dried outside water rear chamber, repeats the above washing process after drying, dry softer degree afterwards three times.It is blind that pliability is evaluated as 10 people
Survey, softer degree, softness is best to obtain 3 points, secondly obtains 2 points, obtains 1 point again, and softness is worst to obtain 0 point, and comprehensive evaluation result is such as
Following table:
It is shown from upper table, the flexibility of the embodiment of the present invention is substantially better than the flexibility of ordinary liquid laundry detergent.
Claims (9)
1. a kind of liquid detergent of color protection softness, which is characterized in that be made of the raw material of following component by weight percent:
Fatty alcohol polyoxyethylene ether 5% ~ 10%；The double stearates 3% ~ 5% of Macrogol 6000；Alkyl glycosides 3% ~ 5%；Fatty alcohol
Polyethenoxy ether sodium sulfate 8% ~ 20%；Polydimethyl diallyl ammonium chloride 0.5% ~ 2%；Chelator acid citrate 0.5% ~ 2%；Step figure
MAGNASOFT SRS amido silicon oil 0.5% ~ 5%；Preservative 0.1% ~ 0.3%；Essence 0.3% ~ 1%；Deionized water surplus.
2. the liquid detergent of color protection softness according to claim 1, which is characterized in that the fatty alcohol polyoxyethylene ether is
- 9 ether of -7 ether of aliphatic alcohol polyethenoxy or aliphatic alcohol polyethenoxy.
3. the liquid detergent of color protection softness according to claim 1, which is characterized in that the alkyl glycosides is C12-16Alkyl
Glucosides.
4. the liquid detergent of color protection softness according to claim 1, which is characterized in that sodium sulfate of polyethenoxy ether of fatty alcohol is living
Property content be 65-75%.
5. the liquid detergent of color protection softness according to claim 1, which is characterized in that polydimethyl diallyl ammonium chloride
Active constituent is 39-41%, viscosity 4000-12000cps, pH value 4-7.
6. the liquid detergent of color protection softness according to claim 1, which is characterized in that ternary polymerization silicone oil, which is selected, steps figure
MAGNASOFT SRS amido silicon oil steps figure MAGNASOFT SRS amido silicon oil active quantities 58-65%, pH value 5-7.
7. the liquid detergent of color protection softness according to claim 1, which is characterized in that preservative is for isothiazolinone and to hydroxyl
At least one of yl benzoic acid methyl esters.
8. the liquid detergent of color protection softness according to claim 1, which is characterized in that by weight percent by following component
Raw material composition: fatty alcohol polyoxyethylene ether 10%；The double stearates 5% of Macrogol 6000；Alkyl glycosides 5%；Fatty alcohol polyoxy
Ethylene ether sodium sulfate 10%；Polydimethyl diallyl ammonium chloride 2%；Chelator acid citrate 1%；Ternary polymerization silicone oil 5%；Preservative
0.2%；Essence 0.5%；Deionized water surplus.
9. the preparation method of the liquid detergent of color protection softness according to claim 1-8, the specific steps are as follows:
It weighs: according to formula rate, accurately weighing raw material, it is spare；
Preparation: being added a certain amount of deionized water in a stirring kettle, and temperature is raised to 60 DEG C -70 DEG C, fatty alcohol polyoxy second is added
Sodium sulfate of polyethenoxy ether of fatty alcohol, chela is added to being completely dissolved in alkene ether, polyethylene glycol stearate diester, alkyl glycosides, stirring
Mixture, stirring is to being completely dissolved；Then balance deionized water is added, and cools the temperature to 40 DEG C hereinafter, sequentially adding poly- diformazan
Base diallyl ammonium chloride, ternary polymerization silicone oil, preservative, essence, stirring are filtered and filling to being completely dissolved, that is, are prepared into
To the liquid detergent of color protection softness.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811511160.7A CN109694783A (en) | 2018-12-11 | 2018-12-11 | A kind of color protection soft liquid laundry detergent and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811511160.7A CN109694783A (en) | 2018-12-11 | 2018-12-11 | A kind of color protection soft liquid laundry detergent and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN109694783A true CN109694783A (en) | 2019-04-30 |
Family
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811511160.7A Pending CN109694783A (en) | 2018-12-11 | 2018-12-11 | A kind of color protection soft liquid laundry detergent and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113481067A (en) * | 2021-06-02 | 2021-10-08 | 兰州石化职业技术学院 | Laundry detergent with anti-bacterial function and preparation method thereof |
| CN113583764A (en) * | 2021-09-03 | 2021-11-02 | 广州立白企业集团有限公司 | Mild detergent composition |
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| CN102242023A (en) * | 2011-05-31 | 2011-11-16 | 廊坊乐万家联合家化有限公司 | Laundry liquid with washing and caring functions |
| CN104562779A (en) * | 2015-02-04 | 2015-04-29 | 湖州申祥丝织有限责任公司 | Novel dyeing assistant for improving color fastness of textile and preparation method of novel dyeing assistant |
| CN105001423A (en) * | 2015-08-17 | 2015-10-28 | 东莞科特新材料技术有限公司 | Organosilicon softening finishing agent with ice-cold feeling and preparation method of organosilicon softening finishing agent |
| CN108532329A (en) * | 2018-04-09 | 2018-09-14 | 江苏尼美达科技有限公司 | A kind of one-bath process softening agent and preparation method thereof |
-
2018
- 2018-12-11 CN CN201811511160.7A patent/CN109694783A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101798552A (en) * | 2010-05-07 | 2010-08-11 | 北京绿伞化学股份有限公司 | Fabric detergent with colour-preserving function and preparation method thereof |
| CN102242023A (en) * | 2011-05-31 | 2011-11-16 | 廊坊乐万家联合家化有限公司 | Laundry liquid with washing and caring functions |
| CN104562779A (en) * | 2015-02-04 | 2015-04-29 | 湖州申祥丝织有限责任公司 | Novel dyeing assistant for improving color fastness of textile and preparation method of novel dyeing assistant |
| CN105001423A (en) * | 2015-08-17 | 2015-10-28 | 东莞科特新材料技术有限公司 | Organosilicon softening finishing agent with ice-cold feeling and preparation method of organosilicon softening finishing agent |
| CN108532329A (en) * | 2018-04-09 | 2018-09-14 | 江苏尼美达科技有限公司 | A kind of one-bath process softening agent and preparation method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113481067A (en) * | 2021-06-02 | 2021-10-08 | 兰州石化职业技术学院 | Laundry detergent with anti-bacterial function and preparation method thereof |
| CN113583764A (en) * | 2021-09-03 | 2021-11-02 | 广州立白企业集团有限公司 | Mild detergent composition |
| CN113583764B (en) * | 2021-09-03 | 2023-11-24 | 广州立白企业集团有限公司 | Mild detergent composition |
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