CN112646668B - Wool product detergent and preparation method thereof - Google Patents
Wool product detergent and preparation method thereof Download PDFInfo
- Publication number
- CN112646668B CN112646668B CN202011388014.7A CN202011388014A CN112646668B CN 112646668 B CN112646668 B CN 112646668B CN 202011388014 A CN202011388014 A CN 202011388014A CN 112646668 B CN112646668 B CN 112646668B
- Authority
- CN
- China
- Prior art keywords
- parts
- folic acid
- detergent
- surfactant
- detergent according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 210000002268 wool Anatomy 0.000 title claims abstract description 44
- 239000003599 detergent Substances 0.000 title claims abstract description 43
- 238000002360 preparation method Methods 0.000 title claims abstract description 24
- OVBPIULPVIDEAO-LBPRGKRZSA-N folic acid Chemical compound C=1N=C2NC(N)=NC(=O)C2=NC=1CNC1=CC=C(C(=O)N[C@@H](CCC(O)=O)C(O)=O)C=C1 OVBPIULPVIDEAO-LBPRGKRZSA-N 0.000 claims abstract description 27
- OVBPIULPVIDEAO-UHFFFAOYSA-N N-Pteroyl-L-glutaminsaeure Natural products C=1N=C2NC(N)=NC(=O)C2=NC=1CNC1=CC=C(C(=O)NC(CCC(O)=O)C(O)=O)C=C1 OVBPIULPVIDEAO-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000011724 folic acid Substances 0.000 claims abstract description 16
- 235000019152 folic acid Nutrition 0.000 claims abstract description 16
- 229960000304 folic acid Drugs 0.000 claims abstract description 16
- 239000000022 bacteriostatic agent Substances 0.000 claims abstract description 7
- 239000000203 mixture Substances 0.000 claims description 36
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 18
- 238000003756 stirring Methods 0.000 claims description 16
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 15
- 238000002156 mixing Methods 0.000 claims description 15
- 239000002736 nonionic surfactant Substances 0.000 claims description 15
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 14
- 150000002224 folic acids Chemical class 0.000 claims description 13
- 238000000034 method Methods 0.000 claims description 12
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 11
- 239000003945 anionic surfactant Substances 0.000 claims description 11
- 239000002888 zwitterionic surfactant Substances 0.000 claims description 11
- 238000001816 cooling Methods 0.000 claims description 10
- -1 folic acid compound Chemical class 0.000 claims description 9
- 239000004519 grease Substances 0.000 claims description 9
- 229920005862 polyol Polymers 0.000 claims description 9
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 8
- QMVPMAAFGQKVCJ-UHFFFAOYSA-N citronellol Chemical compound OCCC(C)CCC=C(C)C QMVPMAAFGQKVCJ-UHFFFAOYSA-N 0.000 claims description 8
- HSEMFIZWXHQJAE-UHFFFAOYSA-N hexadecanamide Chemical compound CCCCCCCCCCCCCCCC(N)=O HSEMFIZWXHQJAE-UHFFFAOYSA-N 0.000 claims description 8
- 239000008367 deionised water Substances 0.000 claims description 7
- 229910021641 deionized water Inorganic materials 0.000 claims description 7
- 150000003077 polyols Chemical class 0.000 claims description 7
- 239000011787 zinc oxide Substances 0.000 claims description 7
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 6
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 6
- 235000013599 spices Nutrition 0.000 claims description 6
- 239000003242 anti bacterial agent Substances 0.000 claims description 5
- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical group CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 claims description 5
- 229940073507 cocamidopropyl betaine Drugs 0.000 claims description 5
- 150000002191 fatty alcohols Chemical class 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 5
- QMVPMAAFGQKVCJ-SNVBAGLBSA-N (R)-(+)-citronellol Natural products OCC[C@H](C)CCC=C(C)C QMVPMAAFGQKVCJ-SNVBAGLBSA-N 0.000 claims description 4
- VVIAGPKUTFNRDU-UHFFFAOYSA-N 6S-folinic acid Natural products C1NC=2NC(N)=NC(=O)C=2N(C=O)C1CNC1=CC=C(C(=O)NC(CCC(O)=O)C(O)=O)C=C1 VVIAGPKUTFNRDU-UHFFFAOYSA-N 0.000 claims description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 4
- HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 claims description 4
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 4
- SZAMSYKZCSDVBH-CLFAGFIQSA-N [(z)-octadec-9-enyl] (z)-docos-13-enoate Chemical group CCCCCCCC\C=C/CCCCCCCCCCCC(=O)OCCCCCCCC\C=C/CCCCCCCC SZAMSYKZCSDVBH-CLFAGFIQSA-N 0.000 claims description 4
- JGQFVRIQXUFPAH-UHFFFAOYSA-N beta-citronellol Natural products OCCC(C)CCCC(C)=C JGQFVRIQXUFPAH-UHFFFAOYSA-N 0.000 claims description 4
- 235000000484 citronellol Nutrition 0.000 claims description 4
- 239000010633 clary sage oil Substances 0.000 claims description 4
- 235000008524 evening primrose extract Nutrition 0.000 claims description 4
- 239000010475 evening primrose oil Substances 0.000 claims description 4
- 229940089020 evening primrose oil Drugs 0.000 claims description 4
- 235000008191 folinic acid Nutrition 0.000 claims description 4
- 239000011672 folinic acid Substances 0.000 claims description 4
- VVIAGPKUTFNRDU-ABLWVSNPSA-N folinic acid Chemical compound C1NC=2NC(N)=NC(=O)C=2N(C=O)C1CNC1=CC=C(C(=O)N[C@@H](CCC(O)=O)C(O)=O)C=C1 VVIAGPKUTFNRDU-ABLWVSNPSA-N 0.000 claims description 4
- 229960001691 leucovorin Drugs 0.000 claims description 4
- 229940065207 methylfolic acid Drugs 0.000 claims description 4
- 229940120511 oleyl erucate Drugs 0.000 claims description 4
- 239000002304 perfume Substances 0.000 claims description 4
- 239000011734 sodium Substances 0.000 claims description 4
- 229910052708 sodium Inorganic materials 0.000 claims description 4
- 229940045790 sodium lauryl glycol carboxylate Drugs 0.000 claims description 4
- UIGBPGNEWMRLGK-UHFFFAOYSA-M sodium;2-(2-hydroxydodecoxy)acetate Chemical compound [Na+].CCCCCCCCCCC(O)COCC([O-])=O UIGBPGNEWMRLGK-UHFFFAOYSA-M 0.000 claims description 4
- 239000001587 sorbitan monostearate Substances 0.000 claims description 4
- 235000011076 sorbitan monostearate Nutrition 0.000 claims description 4
- 229940035048 sorbitan monostearate Drugs 0.000 claims description 4
- 240000001548 Camellia japonica Species 0.000 claims description 3
- 235000018597 common camellia Nutrition 0.000 claims description 3
- 239000003921 oil Substances 0.000 claims description 3
- 235000019198 oils Nutrition 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- 235000015112 vegetable and seed oil Nutrition 0.000 claims description 3
- 235000011187 glycerol Nutrition 0.000 claims 2
- 239000004615 ingredient Substances 0.000 claims 1
- 229910021653 sulphate ion Inorganic materials 0.000 claims 1
- 230000003647 oxidation Effects 0.000 abstract description 9
- 238000007254 oxidation reaction Methods 0.000 abstract description 9
- 239000000126 substance Substances 0.000 abstract description 5
- 239000003963 antioxidant agent Substances 0.000 abstract description 4
- 230000003078 antioxidant effect Effects 0.000 abstract description 4
- 239000004094 surface-active agent Substances 0.000 abstract description 4
- 230000003385 bacteriostatic effect Effects 0.000 abstract description 3
- 230000014759 maintenance of location Effects 0.000 abstract description 2
- 230000002035 prolonged effect Effects 0.000 abstract description 2
- 239000002994 raw material Substances 0.000 abstract 1
- 238000012360 testing method Methods 0.000 description 16
- 238000005406 washing Methods 0.000 description 14
- 239000000463 material Substances 0.000 description 11
- 230000000052 comparative effect Effects 0.000 description 10
- 239000000243 solution Substances 0.000 description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 8
- 238000009472 formulation Methods 0.000 description 8
- 230000000844 anti-bacterial effect Effects 0.000 description 7
- 239000007788 liquid Substances 0.000 description 5
- 241000894006 Bacteria Species 0.000 description 4
- 230000002354 daily effect Effects 0.000 description 4
- 229920001296 polysiloxane Polymers 0.000 description 4
- 102000004190 Enzymes Human genes 0.000 description 3
- 108090000790 Enzymes Proteins 0.000 description 3
- 230000001580 bacterial effect Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 239000003755 preservative agent Substances 0.000 description 3
- 230000002335 preservative effect Effects 0.000 description 3
- 235000019487 Hazelnut oil Nutrition 0.000 description 2
- 238000002835 absorbance Methods 0.000 description 2
- 210000000085 cashmere Anatomy 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 238000005202 decontamination Methods 0.000 description 2
- 230000003588 decontaminative effect Effects 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 239000010468 hazelnut oil Substances 0.000 description 2
- 238000011534 incubation Methods 0.000 description 2
- 238000011081 inoculation Methods 0.000 description 2
- 239000000693 micelle Substances 0.000 description 2
- CNNRPFQICPFDPO-UHFFFAOYSA-N octacosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCO CNNRPFQICPFDPO-UHFFFAOYSA-N 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 102000004169 proteins and genes Human genes 0.000 description 2
- 108090000623 proteins and genes Proteins 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- LDVVTQMJQSCDMK-UHFFFAOYSA-N 1,3-dihydroxypropan-2-yl formate Chemical compound OCC(CO)OC=O LDVVTQMJQSCDMK-UHFFFAOYSA-N 0.000 description 1
- 229960002666 1-octacosanol Drugs 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- 102000035195 Peptidases Human genes 0.000 description 1
- 108091005804 Peptidases Proteins 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000004365 Protease Substances 0.000 description 1
- 241000191967 Staphylococcus aureus Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000010495 camellia oil Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000012258 culturing Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000004042 decolorization Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- MGJZITXUQXWAKY-UHFFFAOYSA-N diphenyl-(2,4,6-trinitrophenyl)iminoazanium Chemical compound [O-][N+](=O)C1=CC([N+](=O)[O-])=CC([N+]([O-])=O)=C1N=[N+](C=1C=CC=CC=1)C1=CC=CC=C1 MGJZITXUQXWAKY-UHFFFAOYSA-N 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000003480 eluent Substances 0.000 description 1
- 238000012851 eutrophication Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 238000001727 in vivo Methods 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000005445 natural material Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 235000019832 sodium triphosphate Nutrition 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000008223 sterile water Substances 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0084—Antioxidants; Free-radical scavengers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/1213—Oxides or hydroxides, e.g. Al2O3, TiO2, CaO or Ca(OH)2
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2041—Dihydric alcohols
- C11D3/2044—Dihydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2065—Polyhydric alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2093—Esters; Carbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/28—Heterocyclic compounds containing nitrogen in the ring
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/44—Oxides or hydroxides of elements of Groups 2 or 12 of the Periodic Table; Zincates; Cadmates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/325—Amines
- D06M13/342—Amino-carboxylic acids; Betaines; Aminosulfonic acids; Sulfo-betaines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
- C11D1/06—Ether- or thioether carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/667—Neutral esters, e.g. sorbitan esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/12—Soft surfaces, e.g. textile
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/10—Animal fibres
- D06M2101/12—Keratin fibres or silk
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/50—Modified hand or grip properties; Softening compositions
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- Chemical & Material Sciences (AREA)
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- Oil, Petroleum & Natural Gas (AREA)
- Textile Engineering (AREA)
- Emergency Medicine (AREA)
- Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Microbiology (AREA)
- Inorganic Chemistry (AREA)
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Abstract
The invention relates to the technical field of daily chemical articles, in particular to a wool article detergent and a preparation method thereof. The invention utilizes proper raw materials and proportion to strengthen the retention of functional substances such as antioxidant, bacteriostatic agent and the like on the washed wool products. The oxidation resistance and the bacteriostatic ability of the washed wool product are prolonged. Meanwhile, the oxidation resistance of folic acid is improved when the folic acid is used in a detergent, and the oxidation resistance of folic acid is maintained by a proper surfactant.
Description
Technical Field
The invention belongs to the technical field of daily chemical articles, and particularly relates to a wool article detergent and a preparation method thereof.
Background
Wool products are common in daily life of people, such as woolen sweaters, cashmere overcoats, wool cushions and the like, are softer, skin-friendly and warm-keeping compared with other products, and play an important role in daily life of people. Because wool is inherently brittle, it is desirable to focus on the oxidative and antimicrobial properties of wool products in everyday use.
At present, the laundry detergent on the market has weak dirt-removing power and mild performance, is easy to damage clothes, cannot play a role in protecting clothes and skin, and particularly has the problems that wool materials of wool products are easy to damage and become hard when the wool products are washed, fading, shrinking and the like of the wool products are accelerated.
In the existing detergent, the washed wool product is hard in texture, dull in color and luster, generates static electricity and has no sterilization and disinfection functions. Moreover, because the main component of the wool product is protein fiber, the phenomenon of oxidation and yellowing is easily caused during daily sun irradiation.
Chinese patent application CN102660392A discloses a wool detergent, which is prepared from five components of natural or pure natural nonionic surfactant, dispersant, stabilizer, preservative and deionized water, wherein the mass ratio of the components is 5-30% of nonionic surfactant, 1-10% of dispersant, 1-10% of stabilizer, 0.1-2.0% of preservative and the balance of deionized water. The detergent is adopted to wash wool, and the surfactant is a natural source or a pure natural substance, so that the detergent is easy to degrade.
Chinese patent application CN106085616A discloses a shrink-resistant woolen sweater washing liquid containing hazelnut oil, which is characterized in that the washing liquid comprises the following components in parts by weight: hazelnut oil: 8-15 parts; monoglyceride: 3-7 parts; sodium tripolyphosphate: 12-20 parts; octacosanol: 2-5 parts; nonionic surfactant: 10-18 parts; plant essential oil: 0.1-3.5 parts; thickening agent: 0.5-5 parts; preservative: 0.1-1 part; ethylene glycol: 5-11 parts; water: 55-80 parts.
Chinese patent CN1025631C discloses a heavy duty liquid laundry detergent composition comprising synthetic anionic and ethoxylated nonionic surfactants, detergency builders, specific proteases, an enzyme stabilizing system and water. The composition has a pH of between about 7.0 and 9.0 in a 10% by weight aqueous solution at 20 ℃, a critical micelle concentration of less than or equal to about 200ppm, and an air/water interfacial tension of less than or equal to about 32 dynes/cm in distilled water at 35 ℃ above the critical micelle concentration. The compositions are clean, homogeneous, stable and provide good cleaning performance, especially on enzyme sensitive stains.
Chinese patent application CN1823156A discloses a liquid laundry detergent composition for treating non-keratinous substrates comprising (a) at least one surfactant selected from anionic surfactants, nonionic surfactants, zwitterionic surfactants, amphoteric surfactants, and combinations thereof; (B) a silicone blend comprising a non-functionalized silicone and a functionalized silicone; and (C) at least one additional non-silicone detergent additive selected from the group consisting of detergent builders, detersive enzymes, dye transfer inhibitors and combinations thereof.
At present, the wool product detergent with oxidation resistance and antibacterial performance is less in products.
Disclosure of Invention
In order to solve the existing problems, the invention aims to provide a wool product detergent and a preparation method thereof, wherein the wool product detergent has good foaming and antibacterial effects and strong dirt-removing capacity; the washed wool product is bright in color, fluffy and soft, can effectively reduce the shrinkage rate of the wool product, does not damage human skin, and also has the dustproof and antistatic effects; meanwhile, the wool product detergent is low in production cost, simple in preparation process and suitable for industrial production.
The purpose of the invention is realized by the following technical scheme.
A wool product detergent comprises the following components:
a non-ionic surfactant,
An anionic surfactant,
A zwitterionic surfactant,
Folic acid compound,
A bacteriostatic agent,
Grease,
A polyhydric alcohol,
A softener,
And (3) a perfume.
Further, the detergent comprises the following components in parts by weight:
8-20 parts of non-ionic surfactant,
3-9 parts of anionic surfactant,
4-8 parts of zwitterionic surfactant,
1-3 parts of folic acid compound,
1-3 parts of bacteriostatic agent,
2-7 parts of grease,
7-14 parts of micromolecular polyol,
1-3 parts of softener,
3-9 parts of perfume.
Further, the nonionic surfactant is selected from at least one of fatty alcohol-polyoxyethylene ether, sorbitan monostearate and palmitamide.
Further, the fatty alcohol-polyoxyethylene ether is selected from at least one of AEO7, AEO8 and AEO 9.
Further, the anionic surfactant is selected from at least one of sodium fatty alcohol ether sulfate and sodium lauryl glycol carboxylate.
Further, the zwitterionic surfactant is selected from cocamidopropyl betaine.
Further, the folic acid compounds are selected from at least one of folic acid, leucovorin, L-methyl folic acid, pharmaceutically acceptable salts of folic acid, active metabolites of folic acid or pharmaceutically acceptable salts of folic acid, and substances capable of metabolizing and/or generating folic acid in vivo.
Further, the folic acid compounds are selected from at least one of folic acid, leucovorin and L-methyl folic acid.
Further, the bacteriostatic agent is selected from nano zinc oxide.
Further, the average particle size of the nano zinc oxide is preferably 30 to 90 nm, and more preferably 50 nm.
Further, the oil and fat is at least one selected from oil tea seed oil and evening primrose oil.
Further, the small molecule polyol is at least one selected from glycerol and ethylene glycol.
Further, the softener is selected from oleyl erucate.
Further, the perfume is selected from at least one of citronellol and clary sage oil.
Further, the detergent comprises the following components in parts by weight:
5-10 parts of fatty alcohol-polyoxyethylene ether,
2-6 parts of sorbitan monostearate,
1-4 parts of palmitamide,
Sodium fatty alcohol ether sulfate: 1-3 parts of,
2-6 parts of sodium lauryl glycol carboxylate,
4-8 parts of cocamidopropyl betaine,
1-3 parts of folic acid compound,
1-3 parts of nano zinc oxide,
1-3 parts of camellia seed oil,
1-4 parts of evening primrose oil,
4-8 parts of glycerol,
3-6 parts of ethylene glycol,
1-3 parts of oleyl erucate,
2-5 parts of citronellol,
1-4 parts of clary sage oil.
Further, the fatty alcohol-polyoxyethylene ether is selected from at least one of AEO7, AEO8 and AEO 9.
Further, the average particle size of the nano zinc oxide is preferably 30 to 90 nm, and more preferably 50 nm.
The invention also provides a preparation method of the wool product detergent, which comprises the following steps:
1) mixing the nonionic surfactant, the anionic surfactant and the zwitterionic surfactant, heating to 70-85 ℃, and stirring and homogenizing at constant temperature;
2) uniformly mixing the softener, the grease and the antibacterial agent;
3) sequentially adding the mixture obtained in the step 2), micromolecular polyol and deionized water into the mixture obtained in the step 1), stirring for dissolving, and cooling to 40-50 ℃;
4) cooling to 20-30 ℃, sequentially adding folic acid compounds and spices into the mixture obtained in the step 3), and stirring and mixing uniformly to obtain the product.
The invention has the advantages that:
(1) the invention uses the compounding combination of various surfactants, has good decontamination effect, is easy to rinse, and can save water; the formula is mild, does not contain phosphorus, does not cause water eutrophication, and is more environment-friendly.
(2) The washed wool product has the advantages of no shrinkage, no decolorization and good softness.
(3) The invention utilizes the adhesion effect of grease to adhere the bacteriostatic agent on the surface of the wool product, and the washed wool product has wider antibacterial spectrum and can prevent the pollution and the mildew of bacteria and fungi.
(4) Has the functions of anti-pilling and anti-static electricity.
(5) Has the advantages of hard water resistance and acid and alkali resistance.
(6) It is especially suitable for washing wool products, such as woolen sweater, cashmere overcoat, wool cushion, etc.
(7) The invention utilizes the oxidation resistance of the folic acid compounds, and the folic acid compounds are better attached to the surface of the wool product by compounding with oily substances, thereby further improving the oxidation resistance of the washed wool product.
(8) The invention unexpectedly discovers that the degradation of folic acid compounds at normal temperature and under illumination can be inhibited by utilizing the cocamidopropyl betaine, and the antioxidant period of wool products washed by the detergent is prolonged.
Detailed Description
The materials used in the present invention are commercially available unless otherwise specified.
The nanometer zinc oxide is purchased from Hangzhou Wanjing New Material Co., Ltd, model VK-J50, and has an average particle size of 50 nm.
The detergent and comparative example formulations for each example are as follows:
table 1 detergent formulations table for each example
Preparation example 1
The materials are prepared according to the mixture ratio of the example 1 and by the following method:
1. mixing nonionic surfactant, anionic surfactant and zwitterionic surfactant, heating to 70 deg.C, stirring at constant temperature, and homogenizing;
2. uniformly mixing the softener, the grease and the antibacterial agent;
3. adding the mixture obtained in the step (2), micromolecular polyol and deionized water into the mixture obtained in the step (1), stirring for dissolving, and cooling to 50 ℃;
4. and (3) cooling to 30 ℃, sequentially adding the folic acid compounds and the spices into the mixture obtained in the step (3), and stirring and uniformly mixing to obtain the product.
Preparation example 2
The materials are prepared according to the mixture ratio of the example 2 and by the following method:
1. mixing nonionic surfactant, anionic surfactant and zwitterionic surfactant, heating to 85 deg.C, stirring at constant temperature, and homogenizing;
2. uniformly mixing the softener, the grease and the antibacterial agent;
3. adding the mixture obtained in the step (2), micromolecular polyol and deionized water into the mixture obtained in the step (1), stirring for dissolving, and cooling to 40 ℃;
4. and (3) cooling to 20 ℃, sequentially adding the folic acid compounds and the spices into the mixture obtained in the step (3), and stirring and uniformly mixing to obtain the product.
Preparation example 3
The materials are prepared according to the mixture ratio of the embodiment 3 and by the following method:
1. mixing nonionic surfactant, anionic surfactant and zwitterionic surfactant, heating to 80 deg.C, stirring at constant temperature, and homogenizing;
2. uniformly mixing the softener, the grease and the antibacterial agent;
3. adding the mixture obtained in the step (2), micromolecular polyol and deionized water into the mixture obtained in the step (1), stirring for dissolving, and cooling to 45 ℃;
4. and (3) cooling to 25 ℃, sequentially adding the folic acid compounds and the spices into the mixture obtained in the step (3), and stirring and uniformly mixing to obtain the product.
Preparation example 4
The materials were prepared according to the formulation of example 4 and the method of preparation 2.
Preparation example 5
The materials were prepared according to the formulation of example 5 and the method of preparation 2.
Preparation of comparative example 1
The materials were prepared according to the formulation of comparative example 1 and the method of preparation example 2.
Preparation of comparative example 2
The materials were prepared according to the method of preparation example 2, according to the formulation of comparative example 2.
Preparation of comparative example 3
The materials were prepared according to the method of preparation example 2, according to the formulation of comparative example 3.
Preparation of comparative example 4
The materials were prepared according to the method of preparation example 2, according to the formulation of comparative example 4.
Washing method-reference GB/T13174-2008
The wool product pollution method refers to a preparation method of protein polluted cloth in GB/T13174-2008.
Cutting the contaminated wool product into pieces of 8cm by 8cm, washing for 30min with RHLQ vertical decontamination tester at 30 deg.C, and stirring at 100 rpm. The amount of detergent used in each of the examples and comparative examples was 0.5% of the amount of water.
After washing, the water content was drained off, and after drying naturally, the subsequent tests were carried out.
Test example 1 characterization of antioxidant Performance Using DPPH free radical removal
Weighing the washed wool product, placing the wool product in an outdoor natural environment, and testing the DPPH free radical removal rate on the first day, the third day and the seventh day respectively.
Adding 500 mg of antioxidant cotton fabric into 8mL of ethanol solution with volume percentage concentration of 50% and 2mL of ethanol solution of LDPPH (0.lmmol/L) in a dark place, and adding 37oC, shaking in a constant temperature water bath for 30min, taking out and measuring the absorbance value A of the solution at 517nm1. Taking 8mL ethanol solution with volume percentage concentration of 50%, adding 2mL of LDPPH ethanol solution (0.lmmol/L), and adding 37oC, shaking in a constant temperature water bath for 30min, taking out and measuring the absorbance value A of the solution at 517nm2. DPPH radical clearance (%) = (a)2-A1)/A2x100%。
The test results are shown in Table 2.
TABLE 2DPPH radical removal test results (Unit/%)
It can be seen that the wool product has certain oxidation resistance after the detergent disclosed by the invention is used, and the oxidation resistance has better retention capability.
Test example 2 detergency
The standard washing powder in GB/T13174-2008 is taken as a reference, and the evaluation standard is as follows:
difference in whiteness Δ W = W2-W1
W1: whiteness before washing
W2: whiteness after washing
Stain removal ratio P =. DELTA.wi/. DELTA.Wj
Δ Wi: difference in whiteness of washing detergent composition
Δ Wj: difference in whiteness of washing with reference to washing powder
A P value of less than 1 indicates that the detergent composition has a lower detergency than the control and a P value of greater than 1 indicates that the detergent composition has a higher detergency than the control. The larger the P value, the stronger the detergency of the detergent composition. When the P value is >1.10, the detergent composition has good detergency performance on washing.
The test results are given in table 3 below.
TABLE 3 detergency test results
It can be seen that the detergent of the present invention has a good detergency.
Test example 3 bacteriostasis
1) The wool articles were washed using sterile water, washed according to the washing methods provided herein, dried in a sterile operating station, and then placed in a sterile petri dish.
2) Under aseptic operation, the concentration of staphylococcus aureus liquid is 1x1050.2mL CFU/mL is evenly dripped on the wool product for inoculation.
3) And (4) eluting by using a sterile bacterial eluent, and continuously culturing the eluted wool product.
4) The relative humidity should be controlled above 85% for 1 to 3 days of co-cultivation at 36 ℃. After the incubation time was reached, the bacteria on each test sample were eluted from the sample.
5) The eluate was subjected to bacterial count measurement.
6) Calculating the bacterial inhibition rate: and (5) calculating the bacteriostasis rate, and reserving two decimal points for the result. And taking the calculated value of the bacteriostasis rate as the long-acting antibacterial test result. When the calculated value of the bacteriostasis rate is negative, the calculated value is expressed as 0.00 percent, and when the calculated value of the bacteriostasis rate is more than 99.99 percent
When it is expressed, "> 99.99%". When the bacteriostasis rate is more than or equal to 90.00 percent in 3 times of tests, the test sample has long-acting antibacterial effect.
Bacteriostasis rate = (Ct-Tt)/Ct x 100%
Ct: the number of bacteria measured after inoculation and incubation of the control for a period of time;
tt: number of bacteria measured after the test sample was inoculated and incubated for a period of time.
The test results are given in table 4 below.
TABLE 4 results of bacteriostatic ability test (bacteriostatic rate/%)
It can be seen that the wool product has certain antibacterial ability after the detergent of the invention is used, and the antibacterial ability can be better maintained.
Finally, it should be noted that the above-mentioned contents are only used for illustrating the technical solutions of the present invention, and not for limiting the protection scope of the present invention, and that the simple modifications or equivalent substitutions of the technical solutions of the present invention by those of ordinary skill in the art can be made without departing from the spirit and scope of the technical solutions of the present invention.
Claims (9)
1. The wool product detergent comprises the following components in parts by weight:
8-20 parts of non-ionic surfactant,
3-9 parts of anionic surfactant,
4-8 parts of zwitterionic surfactant,
1-3 parts of folic acid compound,
1-3 parts of bacteriostatic agent,
2-7 parts of grease,
7-14 parts of micromolecular polyol,
1-3 parts of softener,
3-9 parts of a spice;
the zwitterionic surfactant is selected from cocamidopropyl betaine;
the folic acid compounds are selected from at least one of folic acid, leucovorin, L-methyl folic acid and folic acid pharmaceutically acceptable salts.
2. The detergent according to claim 1, wherein the nonionic surfactant is at least one selected from the group consisting of fatty alcohol polyoxyethylene ether, sorbitan monostearate and palmitamide.
3. A detergent according to claim 1, wherein said anionic surfactant is selected from at least one of sodium fatty alcohol ether sulphate and sodium lauryl glycol carboxylate.
4. Detergent according to claim 1, characterized in that the folic acid compounds are selected from at least one of folic acid, leucovorin and L-methylfolic acid.
5. A detergent according to claim 1, wherein said bacteriostatic agent is selected from nano zinc oxide.
6. The detergent according to claim 1, wherein the oil or fat is at least one selected from the group consisting of camellia seed oil and evening primrose oil.
7. The detergent according to claim 1, wherein the small molecule polyol is at least one selected from the group consisting of glycerin and ethylene glycol; the softener is selected from oleyl erucate; the perfume is at least one of citronellol and clary sage oil.
8. A detergent as claimed in any of claims 1 to 7, comprising the following ingredients in parts by weight:
5-10 parts of fatty alcohol-polyoxyethylene ether,
2-6 parts of sorbitan monostearate,
1-4 parts of palmitamide,
Sodium fatty alcohol ether sulfate: 1-3 parts of,
2-6 parts of sodium lauryl glycol carboxylate,
4-8 parts of cocamidopropyl betaine,
1-3 parts of folic acid compound,
1-3 parts of nano zinc oxide,
1-3 parts of camellia seed oil,
1-4 parts of evening primrose oil,
4-8 parts of glycerol,
3-6 parts of ethylene glycol,
1-3 parts of oleyl erucate,
2-5 parts of citronellol,
1-4 parts of clary sage oil.
9. A process for the preparation of a detergent according to any of claims 1 to 8:
1) mixing the nonionic surfactant, the anionic surfactant and the zwitterionic surfactant, heating to 70-85 ℃, and stirring and homogenizing at constant temperature;
2) uniformly mixing the softener, the grease and the antibacterial agent;
3) sequentially adding the mixture obtained in the step 2), micromolecular polyol and deionized water into the mixture obtained in the step 1), stirring for dissolving, and cooling to 40-50 ℃;
4) cooling to 20-30 ℃, sequentially adding folic acid compounds and spices into the mixture obtained in the step 3), and stirring and mixing uniformly to obtain the product.
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| CN105969548A (en) * | 2016-05-18 | 2016-09-28 | 太仓协大申泰羊毛衫有限公司 | Woolen sweater detergent and preparation method thereof |
| CN106085616A (en) * | 2016-05-31 | 2016-11-09 | 太仓协大申泰羊毛衫有限公司 | A kind of resisted shrinkage woollen sweater cleaning mixture containing hazelnut oil and preparation method thereof |
| CN106083765A (en) * | 2016-05-26 | 2016-11-09 | 深圳市海立方生物科技有限公司 | A kind of Environmental Safety abluent with antibacterial functions |
| CN107574028A (en) * | 2017-09-13 | 2018-01-12 | 安徽农业大学 | A kind of nanometer silver antimicrobial Wool cleaning agent |
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105969548A (en) * | 2016-05-18 | 2016-09-28 | 太仓协大申泰羊毛衫有限公司 | Woolen sweater detergent and preparation method thereof |
| CN106083765A (en) * | 2016-05-26 | 2016-11-09 | 深圳市海立方生物科技有限公司 | A kind of Environmental Safety abluent with antibacterial functions |
| CN106085616A (en) * | 2016-05-31 | 2016-11-09 | 太仓协大申泰羊毛衫有限公司 | A kind of resisted shrinkage woollen sweater cleaning mixture containing hazelnut oil and preparation method thereof |
| CN107574028A (en) * | 2017-09-13 | 2018-01-12 | 安徽农业大学 | A kind of nanometer silver antimicrobial Wool cleaning agent |
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