CN105039014A - Essential oil condensation beads for washing clothes and preparing method thereof - Google Patents
Essential oil condensation beads for washing clothes and preparing method thereof Download PDFInfo
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Abstract
The invention provides essential oil condensation beads for washing clothes. The essential oil condensation beads comprise, by weight, 20-25% of sodium C14-16 olefin sulfonate, 15-20% of fatty alcohol polyoxyethylene ether (9EO), 10-12% of sodium alcohol ether sulphate, 8-10% of lauryl alcohol sulphate triethanolamine, 2-4% of polyethylene glycol, 1-3% of cationic alkyl polysaccharide, 1-2% of D-panthenol, 0.3-0.7% of phenoxyethanol, 0.05-0.01% of disodium ethylenediamine tetraacetate, 0.5-1% of jasminum essential oil, 0.05-0.1% of triclosan, 0.1-0.2% of protease, 0.002-0.005% of red-33 pigment and the balance deionized water. The invention further provides a preparing method for the essential oil condensation beads. The essential oil condensation beads have the multiple effects of washing, caring, sterilizing, deodorizing and physical and mental delighting, and are convenient to use.
Description
Technical field
The present invention relates to detergent applications, particularly relate to the solidifying pearl of a kind of essential oil laundry, the invention still further relates to the preparation method of the solidifying pearl of above-mentioned essential oil laundry.
Background technology
Traditional washing liquid main active substances is linear dodecylbenzene sulfonate and other washing assistants; Linear dodecylbenzene sulfonate derives from petroleum chemicals, belongs to non-renewable raw material, and the not resistance to hard water of this raw material, under tap water environment, detersive power reduces greatly, is unfavorable for washing; Other auxiliary agents, 4A zeolite, to contain phosphorus, are unfavorable for environment protection as tripoly phosphate sodium STPP; Aluminium, soda ash, caustic soda alkalescence are higher, easily make clothing fade, damaging laundry; Saltcake belongs to weighting material, and inefficient cycle utilizes, and can bring unnecessary waste to operation.In addition, conventional liquid detergent utilizes conventional surfactants and alkaline assistant, only has washing cleaning action, submissive less effective.
Summary of the invention
In view of this, the object of the present invention is to provide a kind of essential oil to do washing and coagulate pearl, there is washing, nursing, sterilization, smelly eliminating, pleasant mental and body multi-efficiency, energy-saving and emission-reduction, easy to use, there is the superstrong pollution-removing of washing clothes and clean function, successful.
The invention allows for the preparation method of the solidifying pearl of above-mentioned essential oil laundry.
For solving the problems of the technologies described above, technology of the present invention by the following technical solutions:
The solidifying pearl of a kind of essential oil laundry, its weight percent composition comprises: the C14-16 alkene sulfonic acid sodium of 20 ~ 25%, the fatty alcohol-polyoxyethylene ether (9EO) of 15 ~ 20%, the polyoxyethylenated alcohol sodium sulfate of 10 ~ 12%, the lauryl alcohol sulfuric ester triethanolamine salt of 8 ~ 10%, the polyoxyethylene glycol of 2 ~ 4%, the kation alkyl polysaccharide glycosides of 1 ~ 3%, the D-panthenol of 1 ~ 2%, the Phenoxyethanol of 0.3 ~ 0.7%, the disodium ethylene diamine tetraacetate of 0.05 ~ 0.01%, the jasmin quintessence oil of 0.5 ~ 1%, the triclosan of 0.05 ~ 0.1%, the proteolytic enzyme of 0.1 ~ 0.2%, red 33 pigments of 0.002 ~ 0.005%, surplus is deionized water.
A preparation method for the solidifying pearl of essential oil laundry, is characterized in that: comprise the steps:
(1) deionized water, C14-16 alkene sulfonic acid sodium, fatty alcohol-polyoxyethylene ether (9EO), polyoxyethylenated alcohol sodium sulfate, lauryl alcohol sulfuric ester triethanolamine salt are added in reactor according to the above ratio stir, be heated to 75-85 DEG C, stir 30 minutes, and constant temperature carries out froth breaking in 30 minutes;
(2) add polyoxyethylene glycol and kation alkyl polysaccharide glycosides after being cooled to 60 DEG C, continue stirring 30 minutes;
(3) add D-panthenol, Phenoxyethanol, disodium ethylene diamine tetraacetate after being cooled to 45 DEG C, stir 30 minutes;
(4) add jasmin quintessence oil, triclosan, proteolytic enzyme, red 33 pigments after being cooled to 38 DEG C, stir 30 minutes;
(5) sample censorship, survey pH value is 7-8, viscosity 200-500, is accept system;
(6) the solidifying pearl product of laundry is made with polyvinyl alcohol water soluble film parcel.
The beneficial effect that the present invention compared with prior art has is: the present invention adopts Novel Cationic Surfactants APG, composite other conventional anion surfactant, nonionogenic tenside and amphotericses, liquid protease, triclosan, essential oil, product of the present invention is made to have washing, nursing, sterilization, smelly eliminating, pleasant mental and body multi-efficiency, energy-saving and emission-reduction, easy to use, there is the superstrong pollution-removing of washing clothes and clean function, successful.
Embodiment
For the understanding the present invention making those skilled in the art more clear and intuitive, below the present invention is further illustrated.
alkene sulfonic acid sodium(English name SodiumC14-16OlefinSulfonate) is a kind of anion surfactant-sulfonate.
Character: outward appearance: (1), liquid; (2), white or pale yellow powder.
Solvability: water-soluble.
Stability: stable.
Dangerous: there is pungency.Skin, eyes are had to the pungency of medium tenacity.Pungency is lower than alkylbenzene sulfonate.
Ecological: may harm to be had to environment, should pay special attention to water body.
Biological degradability: degradable.
Characteristic: have good decontamination, foaming, wetting, dispersion, emulsifying property, acid resistance is strong.
fatty alcohol-polyoxyethylene ether (9EO):nonionogenic tenside.
Product performance:
(1) there is excellent wetting, emulsification, penetrating quality,
(2) biological degradability is good,
(3) good scourability is had,
(4) can with negatively charged ion, amphoterics compatibility.
polyoxyethylenated alcohol sodium sulfate:smell is the basic anionic surfactant of typical soap taste.
Soluble in water, have excellent decontamination, emulsification, foam performance and anti-performance of hard water, gentle washing character can not injured skin.Please note during use: when not containing viscosity modifier, if will be the aqueous solution containing 30% or 60% active substance AES dilution, often can cause the gel that a kind of viscosity is high.For avoiding this phenomenon, correct method is added in the water of specified quantity by high reactivity product to go, and stirred simultaneously.And water is not added to high reactivity raw material, otherwise just may cause the formation of gel.
lauryl alcohol sulfuric ester triethanolamine salt: a kind of tensio-active agent, character: light yellow viscous liquid.
polyoxyethylene glycol:product is nontoxic, nonirritant, mildly bitter flavor, has good water-soluble, and has good intermiscibility with many organic matter components.They have excellent oilness, moisture retention, dispersiveness, caking agent, static inhibitor and softening agent etc., all have and apply very widely in the industries such as makeup, pharmacy, chemical fibre, rubber, plastics, papermaking, paint, plating, agricultural chemicals, intermetallic composite coating and food-processing.
kation alkyl polysaccharide glycosides: alkyl glycoside, APG for short, synthesized by renewable resources natural fat alcohol and glucose, it is the more comprehensive new non-ionic surfactants of a kind of performance, have the characteristic of conventional nonionic and anion surfactant concurrently, having high surface, good ecological security and intermiscibility, is internationally recognized first-selection " green " functional surfactant.
Performance characteristics: compatibility is good, can with various ionic, the composite generation synergism of nonionic surface active agent;
Whipability is good, and foaming abundancy is fine and smooth;
Solvability is good, resistance to highly basic and ionogen, has good thickening capabilities;
Good with skin intermiscibility, significantly improve the mildness of formula, nontoxic, non-stimulated, readily biodegradable.
disodium ethylene diamine tetraacetate: disodium ethylene diamine tetraacetate is called EDTA-2Na again, and be a kind of good Synergist S-421 95 in chemistry, it has six ligating atoms, and the title complex of formation is called huge legendary turtle compound, and EDTA often uses in complexometric titration, is generally the content measuring metal ion.EDTA has important use dyestuff, food, medicine etc. are industrial.
Feature:
1.EDTA has ligancy widely, almost can form stable inner complex with all metal ions.
Favourable part: provide the possibility (being better than soda acid, the precipitator method) extensively measuring element.
The M-EDTA coordination ratio overwhelming majority of 2.EDTA and formation is 1:1.
3. inner complex is most of electrically charged, therefore can be water-soluble, and be swift in response CASNo.:6381-92-6.
panthenol: the precursor being vitamin B5, therefore also known as dexpanthenol, it contains the D-panthenol being no less than 98% content, it is a kind of colourless liquid to micro-yellow transparent thickness, the special odor that tool is slight.
D-panthenol (99%) should be stored in shady and cool dry storehouse, all insensitive to light, oxygen and heavy metal, is stable water-soluble additive
phenoxyethanol: Phenoxyethanol, be medicine name, English name is: Phenoxyethanol, and Chinese name is again two phenoxyethyl alcohols, phenoxyethyl alcohol etc., and molecular formula is: C
8h
10o
2, Phenoxyethanol belongs to organic synthesis thing, is slightly with viscous liquid for colourless, micro-perfume (or spice), puckery.
Phenoxyethanol can be formed by ethylene glycol and menthylphenoxypolyethoxy ethanol, is common in protective skin cream and sunscreen.Phenoxyethanol is a kind of colourless oily liquids, has antibiotic effect, is used as having the substitute of the sodiumazide of severe toxicity in biological buffered soln of being everlasting, because the toxicity of 2-Phenoxyethanol is lower, and chemically to copper and plumbous and inactive.Usually the function of sanitas is played in makeup, vaccine and medicine.
jasmin quintessence oil: be called as " king of essential oil ".Jasmin quintessence oil output is few thus very expensive, and it has graceful smell, gloomy mood of can releiving, inspires enthusiasm, promotes self-confidence, genial scaly dry skin, lack of water can be nursed simultaneously, cross oil and responsive situation, desalination striae of pregnancy and scar, increase skin elasticity, allow skin feel more tender.
triclosan: triclosan, formal name used at school " triclosan ", chemical molecular formula is C
12h
7c
l3o
2, have another name called " triclosan ", " Triclosan " etc., triclosan normality is white or canescence crystalline powder, slightly phenol stink.Water insoluble, be soluble in alkali lye and organic solvent, triclosan is a kind of broad spectrum antimicrobicide.
Solubleness: be slightly soluble in water, in diluted alkaline, solubleness is moderate, in a lot of organic solvent, have higher solubleness, can be made into transparent concentrated liquid product after dissolving in water-soluble solvent or tensio-active agent;
Stability: there is excellent package stability: less than 280-290 DEG C can not be decomposed rapidly; 200 DEG C are heated 14 hours, only have 2% active substance to decompose, even under long-time UV-irradiation, only have slight decomposition.Its solution is to acid, alkali tool stability.
Volatility: the volatility that tool is very low, micro-tool aromatising flavour.
Fundamental characteristics:
The first, the high purity white powder of fragrant, is not infected with product and skin.
The second, be dissolved in multiple organic solvent and tensio-active agent.
3rd, to strong acid and strong base and heat, there is high stability.
4th, kill widely and restraining effect causing infection or pathogenicity bo Gram positive mattress, true mattress, yeast and virus (as first, hepatitis B, rabies virus, virus of AIDS HTV) etc. all to have.
5th, to no skin irritation.
6th, antagonism antibiotic bacterium and non-anti-antibiotic bacterium effective equally.
proteolytic enzyme: the bloodstain on clothing and albumen dirt can be removed, strengthen clothes cleaning speed and efficiency.
The present invention not only has ordinary liquid laundry detergent a little, and surfactant content is more than 55%, adds again kation alkyl polysaccharide glycosides, better effects if.Triclosan, proteolytic enzyme, make that product has highly enriched, low cost, use is easy to clean, cleaning capacity is strong, gentleness does not hinder hand and clothing and adopt Japanese import polyvinyl alcohol water soluble film to make the solidifying pearl of laundry, convenient to use, noresidue, one time one, therefore the present invention has washing, smelly eliminating, sterilization, pleasant mental and body, the multi-efficiency such as easy to use concurrently.
Embodiment 1
The solidifying pearl of a kind of essential oil laundry, its weight percent composition comprises: the C14-16 alkene sulfonic acid sodium of 20%, the fatty alcohol-polyoxyethylene ether (9EO) of 15%, 10% polyoxyethylenated alcohol sodium sulfate, the lauryl alcohol sulfuric ester triethanolamine salt of 8%, polyoxyethylene glycol, the kation alkyl polysaccharide glycosides of 1%, D-panthenol, the Phenoxyethanol of 0.3%, disodium ethylene diamine tetraacetate, the jasmin quintessence oil of 0.5%, triclosan, the proteolytic enzyme of 0.1%, red 33 pigments of 0.002% of 0.05% of 0.051% of 1% of 2%, surplus is deionized water.
Embodiment 2
The solidifying pearl of a kind of essential oil laundry, its weight percent composition comprises: the C14-16 alkene sulfonic acid sodium of 23%, the fatty alcohol-polyoxyethylene ether (9EO) of 18%, 11% polyoxyethylenated alcohol sodium sulfate, the lauryl alcohol sulfuric ester triethanolamine salt of 9%, polyoxyethylene glycol, the kation alkyl polysaccharide glycosides of 2%, D-panthenol, the Phenoxyethanol of 0.5%, disodium ethylene diamine tetraacetate, the jasmin quintessence oil of 0.8%, triclosan, the proteolytic enzyme of 0.15%, red 33 pigments of 0.004% of 0.07% of 0.07% of 1.5% of 3%, surplus is deionized water.
Embodiment 3
The solidifying pearl of a kind of essential oil laundry, its weight percent composition comprises: the C14-16 alkene sulfonic acid sodium of 25%, the fatty alcohol-polyoxyethylene ether (9EO) of 20%, 12% polyoxyethylenated alcohol sodium sulfate, the lauryl alcohol sulfuric ester triethanolamine salt of 10%, polyoxyethylene glycol, the kation alkyl polysaccharide glycosides of 3%, D-panthenol, the Phenoxyethanol of 0.7%, disodium ethylene diamine tetraacetate, the jasmin quintessence oil of 1%, triclosan, the proteolytic enzyme of 0.2%, red 33 pigments of 0.005% of 0.1% of 0.01% of 2% of 4%, surplus is deionized water.
Embodiment 4
A preparation method for the solidifying pearl of essential oil laundry, comprises the steps:
(1) deionized water, C14-16 alkene sulfonic acid sodium, fatty alcohol-polyoxyethylene ether (9EO), polyoxyethylenated alcohol sodium sulfate, lauryl alcohol sulfuric ester triethanolamine salt are added in reactor according to the above ratio stir, be heated to 75-85 DEG C, stir 30 minutes, and constant temperature carries out froth breaking in 30 minutes;
(2) add polyoxyethylene glycol and kation alkyl polysaccharide glycosides after being cooled to 60 DEG C, continue stirring 30 minutes;
(3) add D-panthenol, Phenoxyethanol, disodium ethylene diamine tetraacetate after being cooled to 45 DEG C, stir 30 minutes;
(4) add jasmin quintessence oil, triclosan, proteolytic enzyme, red 33 pigments after being cooled to 38 DEG C, stir 30 minutes;
(5) sample censorship, survey pH value is 7-8, viscosity 200-500, is accept system;
(6) the solidifying pearl product of laundry is made with polyvinyl alcohol water soluble film parcel.
The foregoing is only preferred embodiment of the present invention, not in order to limit the present invention, within the spirit and principles in the present invention all, any amendment done, equivalent replacement, improvement etc., all should be included within protection scope of the present invention.
Claims (2)
1. the solidifying pearl of essential oil laundry, it is characterized in that, its weight percent composition comprises: the C14-16 alkene sulfonic acid sodium of 20 ~ 25%, the fatty alcohol-polyoxyethylene ether (9EO) of 15 ~ 20%, the polyoxyethylenated alcohol sodium sulfate of 10 ~ 12%, the lauryl alcohol sulfuric ester triethanolamine salt of 8 ~ 10%, the polyoxyethylene glycol of 2 ~ 4%, the kation alkyl polysaccharide glycosides of 1 ~ 3%, the D-panthenol of 1 ~ 2%, the Phenoxyethanol of 0.3 ~ 0.7%, the disodium ethylene diamine tetraacetate of 0.05 ~ 0.01%, the jasmin quintessence oil of 0.5 ~ 1%, the triclosan of 0.05 ~ 0.1%, the proteolytic enzyme of 0.1 ~ 0.2%, red 33 pigments of 0.002 ~ 0.005%, surplus is deionized water.
2. the preparation method of the solidifying pearl of essential oil laundry according to claim 1, is characterized in that: comprise the steps:
(1) deionized water, C14-16 alkene sulfonic acid sodium, fatty alcohol-polyoxyethylene ether (9EO), polyoxyethylenated alcohol sodium sulfate, lauryl alcohol sulfuric ester triethanolamine salt are added in reactor according to the above ratio stir, be heated to 75-85 DEG C, stir 30 minutes, and constant temperature carries out froth breaking in 30 minutes;
(2) add polyoxyethylene glycol and kation alkyl polysaccharide glycosides after being cooled to 60 DEG C, continue stirring 30 minutes;
(3) add D-panthenol, Phenoxyethanol, disodium ethylene diamine tetraacetate after being cooled to 45 DEG C, stir 30 minutes;
(4) add jasmin quintessence oil, triclosan, proteolytic enzyme, red 33 pigments after being cooled to 38 DEG C, stir 30 minutes;
(5) sample censorship, survey pH value is 7-8, viscosity 200-500, is accept system;
(6) the solidifying pearl product of laundry is made with polyvinyl alcohol water soluble film parcel.
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| CN106318666A (en) * | 2016-08-23 | 2017-01-11 | 余姚市德派日用品有限公司 | Infant clothing laundry condensate bead and preparing method thereof |
| CN106318667A (en) * | 2016-08-23 | 2017-01-11 | 余姚市德派日用品有限公司 | Excellent bactericidal washing laundry condensate bead and preparing method thereof |
| CN106350244A (en) * | 2016-08-23 | 2017-01-25 | 余姚市德派日用品有限公司 | Domestic cleaner and preparation method thereof |
| CN106350284A (en) * | 2016-08-23 | 2017-01-25 | 余姚市德派日用品有限公司 | Laundry gel beads for washing real silk fabrics and preparation method of laundry gel beads |
| CN106350293A (en) * | 2016-08-23 | 2017-01-25 | 余姚市德派日用品有限公司 | Silky soft laundry condensate bead and preparation method thereof |
| CN106350270A (en) * | 2016-08-23 | 2017-01-25 | 余姚市德派日用品有限公司 | Undesirable odor removing type laundry condensate bead and preparation method thereof |
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| CN106544179A (en) * | 2016-10-28 | 2017-03-29 | 广州市南大实业有限公司 | A kind of infant coagulates pearl and preparation method and application with laundry |
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| CN108192778A (en) * | 2017-10-19 | 2018-06-22 | 成都孚吉科技有限责任公司 | Pearl and preparation method are coagulated in a kind of nontoxic, non-stimulated laundry |
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| CN106350284A (en) * | 2016-08-23 | 2017-01-25 | 余姚市德派日用品有限公司 | Laundry gel beads for washing real silk fabrics and preparation method of laundry gel beads |
| CN106350293A (en) * | 2016-08-23 | 2017-01-25 | 余姚市德派日用品有限公司 | Silky soft laundry condensate bead and preparation method thereof |
| CN106350270A (en) * | 2016-08-23 | 2017-01-25 | 余姚市德派日用品有限公司 | Undesirable odor removing type laundry condensate bead and preparation method thereof |
| CN106318667A (en) * | 2016-08-23 | 2017-01-11 | 余姚市德派日用品有限公司 | Excellent bactericidal washing laundry condensate bead and preparing method thereof |
| CN106436295A (en) * | 2016-08-23 | 2017-02-22 | 余姚市德派日用品有限公司 | Fabric softener and preparation method thereof |
| CN106544179A (en) * | 2016-10-28 | 2017-03-29 | 广州市南大实业有限公司 | A kind of infant coagulates pearl and preparation method and application with laundry |
| CN106544173A (en) * | 2016-10-28 | 2017-03-29 | 广州市南大实业有限公司 | Solidifying pearl of a kind of softening laundry and preparation method and application |
| CN106811335A (en) * | 2016-11-21 | 2017-06-09 | 浙江雅思丽化妆品有限公司 | A kind of environmentally friendly low foam laundry jelly |
| CN108192778A (en) * | 2017-10-19 | 2018-06-22 | 成都孚吉科技有限责任公司 | Pearl and preparation method are coagulated in a kind of nontoxic, non-stimulated laundry |
| CN108192778B (en) * | 2017-10-19 | 2020-06-30 | 成都孚吉科技有限责任公司 | Non-toxic and non-irritant washing gel bead and preparation method thereof |
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