CN106381234A - Brightening laundry bead and preparation method thereof - Google Patents
Brightening laundry bead and preparation method thereof Download PDFInfo
- Publication number
- CN106381234A CN106381234A CN201610713271.0A CN201610713271A CN106381234A CN 106381234 A CN106381234 A CN 106381234A CN 201610713271 A CN201610713271 A CN 201610713271A CN 106381234 A CN106381234 A CN 106381234A
- Authority
- CN
- China
- Prior art keywords
- laundry
- gorgeous
- light tone
- pearl
- alcohol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000002360 preparation method Methods 0.000 title claims abstract description 7
- 239000011324 bead Substances 0.000 title abstract 3
- 238000005282 brightening Methods 0.000 title abstract 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims abstract description 36
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 35
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 29
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims abstract description 24
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 23
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 20
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 14
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000007788 liquid Substances 0.000 claims abstract description 13
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims abstract description 13
- 239000011976 maleic acid Substances 0.000 claims abstract description 13
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims abstract description 13
- 102000004190 Enzymes Human genes 0.000 claims abstract description 11
- 108090000790 Enzymes Proteins 0.000 claims abstract description 11
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims abstract description 10
- 239000000600 sorbitol Substances 0.000 claims abstract description 10
- 239000003599 detergent Substances 0.000 claims abstract description 9
- 239000003755 preservative agent Substances 0.000 claims abstract description 9
- 230000002335 preservative effect Effects 0.000 claims abstract description 9
- 235000011187 glycerol Nutrition 0.000 claims abstract description 8
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 claims abstract description 6
- 239000000686 essence Substances 0.000 claims abstract description 6
- -1 alkyl phenol Chemical compound 0.000 claims description 16
- 239000000203 mixture Substances 0.000 claims description 16
- 229910052799 carbon Inorganic materials 0.000 claims description 14
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 14
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 14
- 239000012530 fluid Substances 0.000 claims description 13
- 238000002156 mixing Methods 0.000 claims description 13
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 12
- 229920006243 acrylic copolymer Polymers 0.000 claims description 12
- 229940088598 enzyme Drugs 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 10
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 8
- 239000002994 raw material Substances 0.000 claims description 8
- 238000004806 packaging method and process Methods 0.000 claims description 7
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 6
- 108010010803 Gelatin Proteins 0.000 claims description 5
- 229920002907 Guar gum Polymers 0.000 claims description 5
- 229920002125 Sokalan® Polymers 0.000 claims description 5
- 229920002472 Starch Polymers 0.000 claims description 5
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 claims description 5
- 150000001241 acetals Chemical class 0.000 claims description 5
- 229920001577 copolymer Polymers 0.000 claims description 5
- 229920000159 gelatin Polymers 0.000 claims description 5
- 239000008273 gelatin Substances 0.000 claims description 5
- 235000019322 gelatine Nutrition 0.000 claims description 5
- 235000011852 gelatine desserts Nutrition 0.000 claims description 5
- 239000000665 guar gum Substances 0.000 claims description 5
- 235000010417 guar gum Nutrition 0.000 claims description 5
- 229960002154 guar gum Drugs 0.000 claims description 5
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 claims description 5
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 claims description 5
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 claims description 5
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 claims description 5
- 239000004584 polyacrylic acid Substances 0.000 claims description 5
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims description 5
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims description 5
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 5
- 239000008107 starch Substances 0.000 claims description 5
- 235000019698 starch Nutrition 0.000 claims description 5
- 229920002554 vinyl polymer Polymers 0.000 claims description 5
- 229920001285 xanthan gum Polymers 0.000 claims description 5
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 4
- ONJQDTZCDSESIW-UHFFFAOYSA-N polidocanol Chemical compound CCCCCCCCCCCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO ONJQDTZCDSESIW-UHFFFAOYSA-N 0.000 claims description 4
- 108091005804 Peptidases Proteins 0.000 claims description 3
- 239000004365 Protease Substances 0.000 claims description 3
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 claims description 3
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 3
- BWDBEAQIHAEVLV-UHFFFAOYSA-N 6-methylheptan-1-ol Chemical compound CC(C)CCCCCO BWDBEAQIHAEVLV-UHFFFAOYSA-N 0.000 claims description 2
- 239000004382 Amylase Substances 0.000 claims description 2
- 102000013142 Amylases Human genes 0.000 claims description 2
- 108010065511 Amylases Proteins 0.000 claims description 2
- 108010059892 Cellulase Proteins 0.000 claims description 2
- WGQKYBSKWIADBV-UHFFFAOYSA-N aminomethyl benzene Natural products NCC1=CC=CC=C1 WGQKYBSKWIADBV-UHFFFAOYSA-N 0.000 claims description 2
- 235000019418 amylase Nutrition 0.000 claims description 2
- 229940106157 cellulase Drugs 0.000 claims description 2
- 229960002344 dexamethasone sodium phosphate Drugs 0.000 claims description 2
- PLCQGRYPOISRTQ-FCJDYXGNSA-L dexamethasone sodium phosphate Chemical compound [Na+].[Na+].C1CC2=CC(=O)C=C[C@]2(C)[C@]2(F)[C@@H]1[C@@H]1C[C@@H](C)[C@@](C(=O)COP([O-])([O-])=O)(O)[C@@]1(C)C[C@@H]2O PLCQGRYPOISRTQ-FCJDYXGNSA-L 0.000 claims description 2
- 102000038379 digestive enzymes Human genes 0.000 claims description 2
- 108091007734 digestive enzymes Proteins 0.000 claims description 2
- 235000019387 fatty acid methyl ester Nutrition 0.000 claims description 2
- 229920000259 polyoxyethylene lauryl ether Polymers 0.000 claims description 2
- 229940081974 saccharin Drugs 0.000 claims description 2
- 235000019204 saccharin Nutrition 0.000 claims description 2
- 239000000901 saccharin and its Na,K and Ca salt Substances 0.000 claims description 2
- GJCOSYZMQJWQCA-UHFFFAOYSA-N 9H-xanthene Chemical compound C1=CC=C2CC3=CC=CC=C3OC2=C1 GJCOSYZMQJWQCA-UHFFFAOYSA-N 0.000 claims 1
- VKEQBMCRQDSRET-UHFFFAOYSA-N Methylone Chemical compound CNC(C)C(=O)C1=CC=C2OCOC2=C1 VKEQBMCRQDSRET-UHFFFAOYSA-N 0.000 claims 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims 1
- 239000004698 Polyethylene Substances 0.000 claims 1
- 150000004996 alkyl benzenes Chemical class 0.000 claims 1
- 150000001412 amines Chemical class 0.000 claims 1
- 239000003292 glue Substances 0.000 claims 1
- 229920000573 polyethylene Polymers 0.000 claims 1
- 238000004140 cleaning Methods 0.000 abstract description 3
- WBIQQQGBSDOWNP-UHFFFAOYSA-N 2-dodecylbenzenesulfonic acid Chemical compound CCCCCCCCCCCCC1=CC=CC=C1S(O)(=O)=O WBIQQQGBSDOWNP-UHFFFAOYSA-N 0.000 abstract 1
- 229920002126 Acrylic acid copolymer Polymers 0.000 abstract 1
- 206010063659 Aversion Diseases 0.000 abstract 1
- 239000002738 chelating agent Substances 0.000 abstract 1
- 235000019864 coconut oil Nutrition 0.000 abstract 1
- 239000003240 coconut oil Substances 0.000 abstract 1
- 229940060296 dodecylbenzenesulfonic acid Drugs 0.000 abstract 1
- 238000005406 washing Methods 0.000 description 7
- 239000008367 deionised water Substances 0.000 description 6
- 229910021641 deionized water Inorganic materials 0.000 description 6
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 4
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 4
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 4
- 239000005642 Oleic acid Substances 0.000 description 4
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 4
- 229940014259 gelatin Drugs 0.000 description 4
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 4
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 4
- 229940032147 starch Drugs 0.000 description 4
- 239000000230 xanthan gum Substances 0.000 description 4
- 235000010493 xanthan gum Nutrition 0.000 description 4
- 229940082509 xanthan gum Drugs 0.000 description 4
- 229920000742 Cotton Polymers 0.000 description 3
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 3
- 244000299507 Gossypium hirsutum Species 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 150000001336 alkenes Chemical class 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 238000012856 packing Methods 0.000 description 3
- 238000007789 sealing Methods 0.000 description 3
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 2
- SNPLKNRPJHDVJA-ZETCQYMHSA-N D-panthenol Chemical compound OCC(C)(C)[C@@H](O)C(=O)NCCCO SNPLKNRPJHDVJA-ZETCQYMHSA-N 0.000 description 2
- 239000011703 D-panthenol Substances 0.000 description 2
- 235000004866 D-panthenol Nutrition 0.000 description 2
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- XEFQLINVKFYRCS-UHFFFAOYSA-N Triclosan Chemical compound OC1=CC(Cl)=CC=C1OC1=CC=C(Cl)C=C1Cl XEFQLINVKFYRCS-UHFFFAOYSA-N 0.000 description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- 229960003949 dexpanthenol Drugs 0.000 description 2
- SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 229930182478 glucoside Natural products 0.000 description 2
- 150000008131 glucosides Chemical class 0.000 description 2
- 230000003340 mental effect Effects 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 description 2
- 235000011152 sodium sulphate Nutrition 0.000 description 2
- 230000001954 sterilising effect Effects 0.000 description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 2
- 229960003500 triclosan Drugs 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- CHHHXKFHOYLYRE-UHFFFAOYSA-M 2,4-Hexadienoic acid, potassium salt (1:1), (2E,4E)- Chemical compound [K+].CC=CC=CC([O-])=O CHHHXKFHOYLYRE-UHFFFAOYSA-M 0.000 description 1
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 description 1
- 108091005658 Basic proteases Proteins 0.000 description 1
- 239000005711 Benzoic acid Substances 0.000 description 1
- VQPABOFQLUBEIQ-UHFFFAOYSA-N C(C)O.[O].C1=CC=CC=C1 Chemical compound C(C)O.[O].C1=CC=CC=C1 VQPABOFQLUBEIQ-UHFFFAOYSA-N 0.000 description 1
- BCZXFFBUYPCTSJ-UHFFFAOYSA-L Calcium propionate Chemical compound [Ca+2].CCC([O-])=O.CCC([O-])=O BCZXFFBUYPCTSJ-UHFFFAOYSA-L 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 235000018958 Gardenia augusta Nutrition 0.000 description 1
- 244000147568 Laurus nobilis Species 0.000 description 1
- 235000017858 Laurus nobilis Nutrition 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 235000005212 Terminalia tomentosa Nutrition 0.000 description 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 230000002159 abnormal effect Effects 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 125000005233 alkylalcohol group Chemical group 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- SRSXLGNVWSONIS-UHFFFAOYSA-M benzenesulfonate Chemical compound [O-]S(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-M 0.000 description 1
- 229940077388 benzenesulfonate Drugs 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- 229960004365 benzoic acid Drugs 0.000 description 1
- 235000010331 calcium propionate Nutrition 0.000 description 1
- 239000004330 calcium propionate Substances 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- PCHPORCSPXIHLZ-UHFFFAOYSA-N diphenhydramine hydrochloride Chemical compound [Cl-].C=1C=CC=CC=1C(OCC[NH+](C)C)C1=CC=CC=C1 PCHPORCSPXIHLZ-UHFFFAOYSA-N 0.000 description 1
- YRIUSKIDOIARQF-UHFFFAOYSA-N dodecyl benzenesulfonate Chemical compound CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 YRIUSKIDOIARQF-UHFFFAOYSA-N 0.000 description 1
- 229940071161 dodecylbenzenesulfonate Drugs 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical compound C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- 239000007943 implant Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000003094 microcapsule Substances 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 230000000474 nursing effect Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 229960005323 phenoxyethanol Drugs 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 235000010241 potassium sorbate Nutrition 0.000 description 1
- 239000004302 potassium sorbate Substances 0.000 description 1
- 229940069338 potassium sorbate Drugs 0.000 description 1
- 230000035943 smell Effects 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
- 229960003885 sodium benzoate Drugs 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- RSIJVJUOQBWMIM-UHFFFAOYSA-L sodium sulfate decahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.[Na+].[Na+].[O-]S([O-])(=O)=O RSIJVJUOQBWMIM-UHFFFAOYSA-L 0.000 description 1
- 235000019832 sodium triphosphate Nutrition 0.000 description 1
- 235000010199 sorbic acid Nutrition 0.000 description 1
- 239000004334 sorbic acid Substances 0.000 description 1
- 229940075582 sorbic acid Drugs 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents
- C11D11/0082—Special methods for preparing compositions containing mixtures of detergents one or more of the detergent ingredients being in a liquefied state, e.g. slurry, paste or melt, and the process resulting in solid detergent particles such as granules, powders or beads
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
- C11D17/042—Water soluble or water disintegrable containers or substrates containing cleaning compositions or additives for cleaning compositions
- C11D17/043—Liquid or thixotropic (gel) compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2041—Dihydric alcohols
- C11D3/2044—Dihydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2065—Polyhydric alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
- C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
- C11D1/721—End blocked ethers
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Dispersion Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
The invention relates to the detergent field, particularly to a brightening laundry bead and a preparation method thereof. The color-protecting laundry bead is composed of a water-soluble film and a cleaning liquid inside. And the cleaning liquid is prepared from the following components: propylene glycol, sorbitol, glycerin, dodecylbenzene sulfonic acid, ethanolamine, a nonionic surfactant, coconut oil, a maleic acid/acrylic acid copolymer, a chelating agent, ethanol, a brightening agent, water, essence, a preservative, an aversion agent, and enzyme. The product provided by the invention has very high detergency, and at the same time can make colored clothes brighter.
Description
Technical field
The present invention relates to detergent applications, more particularly to a kind of light tone increases solidifying pearl of gorgeous laundry and preparation method thereof.
Background technology
Traditional liquid detergent main active substances are linear dodecylbenzene sulfonate and other builders;Straight chain dodecane
Base benzene sulfonate derives from petroleum chemicals, belongs to non-renewable raw material, and this raw material is intolerant to hard water, goes down dirt in water environment from the beginning
Power substantially reduces, and is unfavorable for washing;Other auxiliary agents, 4A zeolite, such as sodium tripolyphosphate contain phosphorus, are unfavorable for environmental conservation;Aluminum is pure
Alkali, Caustic soda alkalescence are higher, so that medicated clothing is faded, damaging laundry;Natrii Sulfas belong to implant, and inefficient cycle utilizes, can be to operation band
Carry out unnecessary waste.Additionally, conventional liquid detergent utilizes conventional surfactants and alkaline assistant, only there is washing cleaning
Effect, submissive less effective.
It is many that Chinese invention patent application (application number CN201510437124.0 applying date 2015.07.23) discloses one kind
The solidifying pearl of function laundry, its weight percent composition includes:C14-16 alkene sulfonic acid sodium 30-35%, fatty alcohol-polyoxyethylene ether
(9EO) 15-20%, DBSA 10-12%, kation alkyl many glucosides 5-8%, disodiumedetate
0.01-0.03%, D-panthenol 1-2%, phenoxyethanol 0.3-0.7%, essence 0.1-0.3%, triclosan 0.05-0.1%, albumen
Enzyme 0.01-0.03%, balance of deionized water.This product has washing, nursing, sterilization, smelly eliminating, pleasant mental and body multi-efficiency,
Energy-saving and emission-reduction, easy to use.
Chinese invention patent application (application number CN201510436322.5 applying date 2015.07.23) discloses a kind of essence
Oil wash clothing coagulates pearl, and its weight percent composition includes:20~25% C14-16 alkene sulfonic acid sodium, 15~20% poly alkyl alcohol
Oxygen vinyl Ether (9EO), 10~12% polyoxyethylenated alcohol sodium sulfate, 8~10% Laurel alcohol sulfuric ester triethanolamine
Salt, 2~4% Polyethylene Glycol, 1~3% many glucosides of kation alkyl, 1~2% D-panthenol, 0.3~0.7% benzene oxygen
Ethanol, 0.05~0.01% disodiumedetate, 0.5~1% jasmin quintessence oil, 0.05~0.1% triclosan,
0.1~0.2% protease, 0.002~0.005% red 33 pigments, balance of deionized water.This product has washing, shield
Reason, sterilization, smelly eliminating, pleasant mental and body multi-efficiency, easy to use.
Chinese invention patent application (application number CN201610216176.X applying date 2016.04.09) discloses a kind of soft
Along solidifying pearl of laundry and preparation method thereof, this laundry coagulate pearl include 25~35% isomery C13 fatty alcohol-polyoxyethylene ether, 10~20%
Fatty alcohol-polyoxyethylene ether (9EO), 10~20% polyoxyethylenated alcohol sodium sulfate, 5~10% fatty alcohol-polyoxyethylene ether
(7EO), 1.5~2.5% washing synergist WR, 1.5~2.5% isomeric alcohol polyethenoxy ether, 0.8~1.5% cation are submissive
Agent, 0.02~0.05% antibacterial, 0.5~1.0% microcapsule essence, 0.01-0.03% alkaline protease and 20~38% are molten
Agent (propylene glycol), this product have stronger tax fragrance, safe and convenient to use, washability and submissive effect preferable the features such as.
Above-mentioned various laundries are coagulated pearl and are had different formulations, also have different functions and effect simultaneously, solidifying with laundry
The popularization of pearl, to laundry, solidifying pearl has different demands it is therefore necessary to develop production to the product of subdivision for consumer.
Content of the invention
First purpose of the present invention is to provide a kind of light tone to increase the solidifying pearl of gorgeous laundry, and this laundry is coagulated pearl and had high detergency
And colour clothes color can be made more bright-coloured.Second object of the present invention is the preparation method providing above-mentioned laundry to coagulate pearl.
In order to realize above-mentioned first purpose, present invention employs following technical scheme:
A kind of light tone increases the solidifying pearl of gorgeous laundry, is made up of water soluble film and its interior cleanout fluid, cleanout fluid is by mass percentage
Prepared by following component:
Propylene glycol 8-20%
Sorbitol 2-9%
Glycerol 2-5%
DBSA 10-40%
Ethanolamine 3-10%
Nonionic surfactant 10-40%
Cocinic acid 5-15%
Maleic acid/acrylic copolymer 0.5-2%
Chelating agen 0.5-2%
Ethanol 0.5-3%
Light tone agent 0.4-1.5%
Water 3-20%
Essence 0.7-2%
Preservative 0.05-0.2%
Aversive agent 0.0001-0.02%
Enzyme 0.05-2%.
Preferably, this cleanout fluid is prepared by following component by mass percentage:
Propylene glycol 10-20%
Sorbitol 2-7%
Glycerol 3-4%
DBSA 15-35%
Ethanolamine 4-8%
Nonionic surfactant 15-35%
Cocinic acid 8-12%
Maleic acid/acrylic copolymer 0.8-1.5%
Chelating agen 0.8-1.5%
Ethanol 0.8-2.5%
Light tone agent 0.4-1.3%
Water 5-15%
Essence 0.8-1.5%
Preservative 0.08-0.15%
Aversive agent 0.0001-0.02%
Enzyme 0.1-1.5%.
Preferably, described content of propylene glycol 12-19%, and sorbitol content is in 2-5%.Product moisture-retaining capacity is
Good, content of propylene glycol increases, and water soluble film easily becomes dry, becomes fragile.
Preferably, the water content of cleanout fluid is in 8-18%, product appearance and optimal stability.Water content is little, water-soluble
Film easily becomes dry, becomes fragile, and water content is big, and product is softer, is easily broken.
Preferably, during ethanol content 0.6-2%, optimal to product solubilising and the impact to abnormal smells from the patient, content is little, and product holds
Easily muddy, content is many, can affect the taste of final products.
Preferably, described nonionic surfactant includes the polyoxyethylene ether of alkyl phenol, aliphatic alcohol polyethenoxy
One or more of ether, fatty acid methyl ester APEO and detergent 6501.Preferably, described fatty alcohol polyoxy second
Alkene ether selects polyoxyethylene lauryl ether, 12-14 carbon primary alconol polyoxyethylene ether, 12-14 carbon secondary alcohol polyoxyethylene ether, collateralization 13
Carbon Guerbet polyoxyethylenated alcohol, collateralization 10 carbon Guerbet polyoxyethylenated alcohol, 10 carbon polyoxyethylenated alcohol of straight chain,
One or more of 8 carbon capryl alcohol polyoxyethylene ether of straight chain, 8 carbon isooctanol polyethoxylate of straight chain.
Preferably, AEO-7 in described nonionic surfactant:AEO-9=1.7:1-2.3:1 or AEO-9:AEO-
3=1:1.2–1:2;Described nonionic surfactant:DBSA=2:8-3:7.Above-mentioned formulation actives
The dirt-removing power brought is the strongest.
Ethanolamine is used for generating DBSA ethanolamine and cocinic acid ethanolamine.Preferably, described second
Hydramine selects one or more of monoethanolamine, triethanolamine, diethanolamine to mix.During neutralization DBSA,
Preferably select raw material to be ordered as:Monoethanolamine, triethanolamine, diethanolamine.
Preferably, in benzoic acid, sodium benzoate, sorbic acid, potassium sorbate, calcium propionate selected by described preservative
Plant or multiple mixing.
Preferably, described aversive agent selects one of saccharin benzylamine amide and benzene first DEXAMETHASONE SODIUM PHOSPHATE ammonium or two kinds of mixing.
Preferably, described enzyme selects one or more of protease, Digestive Enzyme, amylase, cellulase to mix.
In order to realize above-mentioned second purpose, present invention employs following technical scheme:
A kind of method that pearl is coagulated in laundry prepared described in any one technical scheme above-mentioned, the method includes following step
Suddenly:
1) propylene glycol, Sorbitol, glycerol, DBSA, monoethanolamine, nonionic surfactant, Cortex cocois radiciss are pressed
Oleic acid, maleic acid/acrylic copolymer, chelating agen order sequentially add raw material, when temperature is less than 50 DEG C, add ethanol, light tone
Agent, deionized water, essence, preservative, aversive agent and enzyme mixing;
2), after liquid is qualified, carry out water soluble film packaging.
Preferably, the optional material polyvinyl alcohol of described water soluble film, polyvinyl acetal, Polyvinylpyrrolidone,
Polyacrylic acid, maleic acid/acrylic copolymer, starch, gelatin, xanthan gum, guar gum, hydroxypropyl methyl cellulose, and with
One or more of the homopolymerization of upper composition, copolymer and altered contents mix.
The present invention, due to employing above-mentioned technical scheme, is compared with common aqueous based systems liquid detergent, can make active matter
Content dramatically increases (content is up to more than 80%), accomplishes the ultra concentration of real meaning, reduces packaging consumption, storage space and fortune
Defeated cost.The product of the present invention has high detergency, by the test of national standard QB/T1224, three blocks of soiled cottons that standard is required
Detergency is more than 5 times of standard liquid detergent;Especially to staple fibre and staple fibre/cotton textiles blending material cloth, use
WFK-20C and WFK-20D soiled cotton is tested, and detergency is up to 8 times of standard liquid detergent.Colour clothes color can be made fresher simultaneously
Gorgeous.
Specific embodiment
Embodiment 1
A kind of light tone increases the solidifying pearl of gorgeous laundry, is made up of water soluble film and its interior cleanout fluid, cleanout fluid is by mass percentage
Prepared by following component:
The method that pearl is coagulated in above-mentioned laundry, the method comprises the following steps:
1) propylene glycol, Sorbitol, glycerol, DBSA, monoethanolamine, nonionic surfactant, Cortex cocois radiciss are pressed
Oleic acid, maleic acid/acrylic copolymer, chelating agen order sequentially add raw material, when temperature is less than 50 DEG C, add ethanol, light tone
Agent, deionized water, essence, preservative, aversive agent and enzyme mixing;
2), after liquid is qualified, carry out water soluble film packaging.Manner of packing can be selected for water seal or heat-sealing.Water soluble film can be gathered material selection
Vinyl alcohol, polyvinyl acetal, Polyvinylpyrrolidone, polyacrylic acid, maleic acid/acrylic copolymer, starch, gelatin,
Xanthan gum, guar gum, hydroxypropyl methyl cellulose, and the homopolymerization of above composition, copolymer and altered contents.The composition of film can
To be the mixing of above single component or Multiple components.
Quantitative package of the present invention, easy to use, liquid will not be made to be stained with to hand;Reduce the waste in using;Concentrated formulations
Take less space in the family.Packaging uses water soluble film, in temperature 0-70 DEG C, can be all soluble in water in 4 minutes, no matter
Machine washing, hand washing, all easily.
Embodiment 2
A kind of light tone increases the solidifying pearl of gorgeous laundry, is made up of water soluble film and its interior cleanout fluid, cleanout fluid is by mass percentage
Prepared by following component:
The method that pearl is coagulated in above-mentioned laundry, the method comprises the following steps:
1) propylene glycol, Sorbitol, glycerol, DBSA, monoethanolamine, nonionic surfactant, Cortex cocois radiciss are pressed
Oleic acid, maleic acid/acrylic copolymer, chelating agen order sequentially add raw material, when temperature is less than 50 DEG C, add ethanol, light tone
Agent, deionized water, essence, preservative, aversive agent and enzyme mixing;
2), after liquid is qualified, carry out water soluble film packaging.Manner of packing can be selected for water seal or heat-sealing.Water soluble film can be gathered material selection
Vinyl alcohol, polyvinyl acetal, Polyvinylpyrrolidone, polyacrylic acid, maleic acid/acrylic copolymer, starch, gelatin,
Xanthan gum, guar gum, hydroxypropyl methyl cellulose, and the homopolymerization of above composition, copolymer and altered contents.The composition of film can
To be the mixing of above single component or Multiple components.
Embodiment 3
A kind of light tone increases the solidifying pearl of gorgeous laundry, is made up of water soluble film and its interior cleanout fluid, cleanout fluid is by mass percentage
Prepared by following component:
The method that pearl is coagulated in above-mentioned laundry, the method comprises the following steps:
1) propylene glycol, Sorbitol, glycerol, DBSA, monoethanolamine, nonionic surfactant, Cortex cocois radiciss are pressed
Oleic acid, maleic acid/acrylic copolymer, chelating agen order sequentially add raw material, when temperature is less than 50 DEG C, add ethanol, light tone
Agent, deionized water, essence, preservative, aversive agent and enzyme mixing;
2), after liquid is qualified, carry out water soluble film packaging.Manner of packing can be selected for water seal or heat-sealing.Water soluble film can be gathered material selection
Vinyl alcohol, polyvinyl acetal, Polyvinylpyrrolidone, polyacrylic acid, maleic acid/acrylic copolymer, starch, gelatin,
Xanthan gum, guar gum, hydroxypropyl methyl cellulose, and the homopolymerization of above composition, copolymer and altered contents.The composition of film can
To be the mixing of above single component or Multiple components.
Claims (10)
1. a kind of light tone increases the solidifying pearl of gorgeous laundry, by water soluble film and its interior cleanout fluid constitutes it is characterised in that cleanout fluid is by quality
Percentages are prepared by following component:
2. a kind of light tone according to claim 1 increase the gorgeous solidifying pearl of laundry it is characterised in that this cleanout fluid by mass percentage
Meter is prepared by following component:
3. a kind of light tone according to claim 1 and 2 increase the solidifying pearl of gorgeous laundry it is characterised in that:Content of propylene glycol is 12-
19%,
And sorbitol content is 2-5%.
4. a kind of light tone according to claim 1 increases the solidifying pearl of gorgeous laundry it is characterised in that nonionic surfactant includes
One of the polyoxyethylene ether of alkyl phenol, fatty alcohol-polyoxyethylene ether, fatty acid methyl ester APEO and detergent 6501
Or it is multiple;Preferably, fatty alcohol-polyoxyethylene ether selects polyoxyethylene lauryl ether, 12-14 carbon primary alconol polyoxyethylene ether, 12-14
Carbon secondary alcohol polyoxyethylene ether, collateralization 13 carbon Guerbet polyoxyethylenated alcohol, collateralization 10 carbon Guerbet alcohol polyoxyethylene
In ether, 10 carbon polyoxyethylenated alcohol of straight chain, 8 carbon capryl alcohol polyoxyethylene ether of straight chain, 8 carbon isooctanol polyethoxylate of straight chain
One or more.
5. a kind of light tone according to claim 1 increases the solidifying pearl of gorgeous laundry it is characterised in that in nonionic surfactant
AEO-7:AEO-9=1.7:1-2.3:1 or AEO-9:AEO-3=1:1.2–1:2;Described nonionic surfactant:12
Alkyl benzene sulphonate=2:8-3:7.
6. a kind of light tone according to claim 1 increase the solidifying pearl of gorgeous laundry it is characterised in that ethanolamine select monoethanolamine, three
One or more of ethanolamine, diethanolamine mix.
7. a kind of light tone according to claim 1 increases the solidifying pearl of gorgeous laundry it is characterised in that aversive agent selects saccharin benzylamine acyl
One of amine and benzene first DEXAMETHASONE SODIUM PHOSPHATE ammonium or two kinds of mixing.
8. a kind of light tone according to claim 1 increase the solidifying pearl of gorgeous laundry it is characterised in that;Enzyme select protease, Digestive Enzyme,
One or more of amylase, cellulase mix.
9. a kind of laundry prepared described in claim 1~8 any one claim coagulates the method for pearl it is characterised in that the party
Method comprises the following steps:
1) press propylene glycol, Sorbitol, glycerol, DBSA, monoethanolamine, nonionic surfactant, cocinic acid,
Maleic acid/acrylic copolymer, chelating agen order sequentially add raw material, when temperature is less than 50 DEG C, adds ethanol, light tone agent, go
Ionized water, essence, preservative, aversive agent and enzyme mixing;
2), after liquid is qualified, carry out water soluble film packaging.
10. laundry according to claim 9 coagulates the preparation method of pearl it is characterised in that water soluble film can material selection polyethylene
Alcohol, polyvinyl acetal, Polyvinylpyrrolidone, polyacrylic acid, maleic acid/acrylic copolymer, starch, gelatin, xanthan
Glue, guar gum, hydroxypropyl methyl cellulose, and one or more of the homopolymerization of above composition, copolymer and altered contents
Mixing.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610713271.0A CN106381234A (en) | 2016-08-23 | 2016-08-23 | Brightening laundry bead and preparation method thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610713271.0A CN106381234A (en) | 2016-08-23 | 2016-08-23 | Brightening laundry bead and preparation method thereof |
Publications (1)
Publication Number | Publication Date |
---|---|
CN106381234A true CN106381234A (en) | 2017-02-08 |
Family
ID=57916942
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201610713271.0A Pending CN106381234A (en) | 2016-08-23 | 2016-08-23 | Brightening laundry bead and preparation method thereof |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN106381234A (en) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106906059A (en) * | 2017-02-20 | 2017-06-30 | 广州市南大实业有限公司 | A kind of solidifying pearl of Low-foam and easily rinsing laundry and preparation method and application |
CN108330024A (en) * | 2018-05-03 | 2018-07-27 | 上海奥威日化有限公司 | Cleansing composition |
CN110484384A (en) * | 2019-09-06 | 2019-11-22 | 广州乐居日化用品有限公司 | A kind of solidifying pearl and preparation method thereof of doing washing |
CN111592942A (en) * | 2020-06-11 | 2020-08-28 | 浙江施维康生物医学材料有限公司 | Color-crossing-preventing washing condensation bead and preparation method thereof |
CN113278476A (en) * | 2021-05-26 | 2021-08-20 | 广州大白生物科技有限公司 | Water-soluble film-wrapped beadlets comprising cinnamon oil microcapsule film |
CN113736576A (en) * | 2021-10-21 | 2021-12-03 | 广州市迪梵日用品有限公司 | Washing gel bead and preparation method thereof |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102433225A (en) * | 2011-12-29 | 2012-05-02 | 青岛蔚蓝生物集团有限公司 | Alkaline proteinase coated micro-pill and preparation method thereof |
CN103154355A (en) * | 2010-03-09 | 2013-06-12 | 埃科莱布美国股份有限公司 | Liquid concentrated fabric softener composition |
WO2015134827A1 (en) * | 2014-03-07 | 2015-09-11 | The Procter & Gamble Company | Compositions comprising a bittering agent |
CN105039014A (en) * | 2015-07-23 | 2015-11-11 | 广州柏俐臣化妆品有限公司 | Essential oil condensation beads for washing clothes and preparing method thereof |
-
2016
- 2016-08-23 CN CN201610713271.0A patent/CN106381234A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103154355A (en) * | 2010-03-09 | 2013-06-12 | 埃科莱布美国股份有限公司 | Liquid concentrated fabric softener composition |
CN102433225A (en) * | 2011-12-29 | 2012-05-02 | 青岛蔚蓝生物集团有限公司 | Alkaline proteinase coated micro-pill and preparation method thereof |
WO2015134827A1 (en) * | 2014-03-07 | 2015-09-11 | The Procter & Gamble Company | Compositions comprising a bittering agent |
CN105039014A (en) * | 2015-07-23 | 2015-11-11 | 广州柏俐臣化妆品有限公司 | Essential oil condensation beads for washing clothes and preparing method thereof |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106906059A (en) * | 2017-02-20 | 2017-06-30 | 广州市南大实业有限公司 | A kind of solidifying pearl of Low-foam and easily rinsing laundry and preparation method and application |
CN108330024A (en) * | 2018-05-03 | 2018-07-27 | 上海奥威日化有限公司 | Cleansing composition |
CN110484384A (en) * | 2019-09-06 | 2019-11-22 | 广州乐居日化用品有限公司 | A kind of solidifying pearl and preparation method thereof of doing washing |
CN111592942A (en) * | 2020-06-11 | 2020-08-28 | 浙江施维康生物医学材料有限公司 | Color-crossing-preventing washing condensation bead and preparation method thereof |
CN113278476A (en) * | 2021-05-26 | 2021-08-20 | 广州大白生物科技有限公司 | Water-soluble film-wrapped beadlets comprising cinnamon oil microcapsule film |
CN113278476B (en) * | 2021-05-26 | 2023-08-11 | 广州大白生物科技有限公司 | Water-soluble film-coated gel bead containing cinnamon oil microcapsule film |
CN113736576A (en) * | 2021-10-21 | 2021-12-03 | 广州市迪梵日用品有限公司 | Washing gel bead and preparation method thereof |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN106381234A (en) | Brightening laundry bead and preparation method thereof | |
CN106350268A (en) | Laundry condensate bead and preparation method thereof | |
CN105062703B (en) | A kind of protease Superconcentrated washing liquid and preparation method thereof | |
CN102876489B (en) | Neutral washing powder and preparation method thereof | |
CN106350284A (en) | Laundry gel beads for washing real silk fabrics and preparation method of laundry gel beads | |
CN106916659A (en) | A kind of multilayer laundry sheet and preparation method thereof | |
US7417017B2 (en) | Detergent compositions with unique builder system for enhanced stain removal | |
CN106350291A (en) | Laundry condensate beads for washing underclothes, and preparation method of laundry condensate beads | |
CN106318667A (en) | Excellent bactericidal washing laundry condensate bead and preparing method thereof | |
CN102242022A (en) | Environment-friendly type hyperconcentration biological enzyme liquid laundry detergent and preparation method thereof | |
CN106350288A (en) | Cross-color-proof type laundry condensate bead and preparation method thereof | |
CN104388204B (en) | Ointment containing oxidative bleaches and enzyme/semi-solid detergent composition and preparation method thereof | |
CN106350271A (en) | Color-protecting clothes washing condensate beads and preparation method thereof | |
CN101671605A (en) | Quintupling hyperconcentrated liquid detergent for garment | |
CN106350293A (en) | Silky soft laundry condensate bead and preparation method thereof | |
CN106350287A (en) | Laundry gel beads for washing sportswear and preparation method of laundry gel beads | |
CN110396457A (en) | A kind of anti-colour contamination is done washing solidifying pearl and preparation method thereof | |
CN106318666A (en) | Infant clothing laundry condensate bead and preparing method thereof | |
CN106047526A (en) | Detergent sheet and preparation method thereof | |
US3776851A (en) | Detergents containing tetrahydroxysuccinic acid and salts thereof | |
US3966649A (en) | Liquid detergents containing chelidamic acids and salts thereof | |
CN104152284A (en) | High-efficiency concentrated detergent liquid | |
US4613448A (en) | Detergent compositions | |
EP2964741B1 (en) | A method of preparing anhydrous alkyl (ethoxy) sulphate compositions | |
CN104830561A (en) | Super-concentrated low-foam high-efficient laundry detergent |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
RJ01 | Rejection of invention patent application after publication | ||
RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170208 |