CN106381234A - Brightening laundry bead and preparation method thereof - Google Patents

Brightening laundry bead and preparation method thereof Download PDF

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Publication number
CN106381234A
CN106381234A CN201610713271.0A CN201610713271A CN106381234A CN 106381234 A CN106381234 A CN 106381234A CN 201610713271 A CN201610713271 A CN 201610713271A CN 106381234 A CN106381234 A CN 106381234A
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Prior art keywords
laundry
gorgeous
light tone
pearl
alcohol
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CN201610713271.0A
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Inventor
马赛波
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YUYAO DELPACK DAILY PRODUCT Co Ltd
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YUYAO DELPACK DAILY PRODUCT Co Ltd
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Priority to CN201610713271.0A priority Critical patent/CN106381234A/en
Publication of CN106381234A publication Critical patent/CN106381234A/en
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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/83Mixtures of non-ionic with anionic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D11/00Special methods for preparing compositions containing mixtures of detergents
    • C11D11/0082Special methods for preparing compositions containing mixtures of detergents one or more of the detergent ingredients being in a liquefied state, e.g. slurry, paste or melt, and the process resulting in solid detergent particles such as granules, powders or beads
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/04Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
    • C11D17/041Compositions releasably affixed on a substrate or incorporated into a dispensing means
    • C11D17/042Water soluble or water disintegrable containers or substrates containing cleaning compositions or additives for cleaning compositions
    • C11D17/043Liquid or thixotropic (gel) compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2003Alcohols; Phenols
    • C11D3/2006Monohydric alcohols
    • C11D3/201Monohydric alcohols linear
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2003Alcohols; Phenols
    • C11D3/2041Dihydric alcohols
    • C11D3/2044Dihydric alcohols linear
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2003Alcohols; Phenols
    • C11D3/2065Polyhydric alcohols
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/37Polymers
    • C11D3/3746Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3757(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
    • C11D3/3765(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/38Products with no well-defined composition, e.g. natural products
    • C11D3/382Vegetable products, e.g. soya meal, wood flour, sawdust
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/38Products with no well-defined composition, e.g. natural products
    • C11D3/386Preparations containing enzymes, e.g. protease or amylase
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50Perfumes
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/72Ethers of polyoxyalkylene glycols
    • C11D1/721End blocked ethers

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Dispersion Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

The invention relates to the detergent field, particularly to a brightening laundry bead and a preparation method thereof. The color-protecting laundry bead is composed of a water-soluble film and a cleaning liquid inside. And the cleaning liquid is prepared from the following components: propylene glycol, sorbitol, glycerin, dodecylbenzene sulfonic acid, ethanolamine, a nonionic surfactant, coconut oil, a maleic acid/acrylic acid copolymer, a chelating agent, ethanol, a brightening agent, water, essence, a preservative, an aversion agent, and enzyme. The product provided by the invention has very high detergency, and at the same time can make colored clothes brighter.

Description

A kind of light tone increases solidifying pearl of gorgeous laundry and preparation method thereof
Technical field
The present invention relates to detergent applications, more particularly to a kind of light tone increases solidifying pearl of gorgeous laundry and preparation method thereof.
Background technology
Traditional liquid detergent main active substances are linear dodecylbenzene sulfonate and other builders;Straight chain dodecane Base benzene sulfonate derives from petroleum chemicals, belongs to non-renewable raw material, and this raw material is intolerant to hard water, goes down dirt in water environment from the beginning Power substantially reduces, and is unfavorable for washing;Other auxiliary agents, 4A zeolite, such as sodium tripolyphosphate contain phosphorus, are unfavorable for environmental conservation;Aluminum is pure Alkali, Caustic soda alkalescence are higher, so that medicated clothing is faded, damaging laundry;Natrii Sulfas belong to implant, and inefficient cycle utilizes, can be to operation band Carry out unnecessary waste.Additionally, conventional liquid detergent utilizes conventional surfactants and alkaline assistant, only there is washing cleaning Effect, submissive less effective.
It is many that Chinese invention patent application (application number CN201510437124.0 applying date 2015.07.23) discloses one kind The solidifying pearl of function laundry, its weight percent composition includes:C14-16 alkene sulfonic acid sodium 30-35%, fatty alcohol-polyoxyethylene ether (9EO) 15-20%, DBSA 10-12%, kation alkyl many glucosides 5-8%, disodiumedetate 0.01-0.03%, D-panthenol 1-2%, phenoxyethanol 0.3-0.7%, essence 0.1-0.3%, triclosan 0.05-0.1%, albumen Enzyme 0.01-0.03%, balance of deionized water.This product has washing, nursing, sterilization, smelly eliminating, pleasant mental and body multi-efficiency, Energy-saving and emission-reduction, easy to use.
Chinese invention patent application (application number CN201510436322.5 applying date 2015.07.23) discloses a kind of essence Oil wash clothing coagulates pearl, and its weight percent composition includes:20~25% C14-16 alkene sulfonic acid sodium, 15~20% poly alkyl alcohol Oxygen vinyl Ether (9EO), 10~12% polyoxyethylenated alcohol sodium sulfate, 8~10% Laurel alcohol sulfuric ester triethanolamine Salt, 2~4% Polyethylene Glycol, 1~3% many glucosides of kation alkyl, 1~2% D-panthenol, 0.3~0.7% benzene oxygen Ethanol, 0.05~0.01% disodiumedetate, 0.5~1% jasmin quintessence oil, 0.05~0.1% triclosan, 0.1~0.2% protease, 0.002~0.005% red 33 pigments, balance of deionized water.This product has washing, shield Reason, sterilization, smelly eliminating, pleasant mental and body multi-efficiency, easy to use.
Chinese invention patent application (application number CN201610216176.X applying date 2016.04.09) discloses a kind of soft Along solidifying pearl of laundry and preparation method thereof, this laundry coagulate pearl include 25~35% isomery C13 fatty alcohol-polyoxyethylene ether, 10~20% Fatty alcohol-polyoxyethylene ether (9EO), 10~20% polyoxyethylenated alcohol sodium sulfate, 5~10% fatty alcohol-polyoxyethylene ether (7EO), 1.5~2.5% washing synergist WR, 1.5~2.5% isomeric alcohol polyethenoxy ether, 0.8~1.5% cation are submissive Agent, 0.02~0.05% antibacterial, 0.5~1.0% microcapsule essence, 0.01-0.03% alkaline protease and 20~38% are molten Agent (propylene glycol), this product have stronger tax fragrance, safe and convenient to use, washability and submissive effect preferable the features such as.
Above-mentioned various laundries are coagulated pearl and are had different formulations, also have different functions and effect simultaneously, solidifying with laundry The popularization of pearl, to laundry, solidifying pearl has different demands it is therefore necessary to develop production to the product of subdivision for consumer.
Content of the invention
First purpose of the present invention is to provide a kind of light tone to increase the solidifying pearl of gorgeous laundry, and this laundry is coagulated pearl and had high detergency And colour clothes color can be made more bright-coloured.Second object of the present invention is the preparation method providing above-mentioned laundry to coagulate pearl.
In order to realize above-mentioned first purpose, present invention employs following technical scheme:
A kind of light tone increases the solidifying pearl of gorgeous laundry, is made up of water soluble film and its interior cleanout fluid, cleanout fluid is by mass percentage Prepared by following component:
Propylene glycol 8-20%
Sorbitol 2-9%
Glycerol 2-5%
DBSA 10-40%
Ethanolamine 3-10%
Nonionic surfactant 10-40%
Cocinic acid 5-15%
Maleic acid/acrylic copolymer 0.5-2%
Chelating agen 0.5-2%
Ethanol 0.5-3%
Light tone agent 0.4-1.5%
Water 3-20%
Essence 0.7-2%
Preservative 0.05-0.2%
Aversive agent 0.0001-0.02%
Enzyme 0.05-2%.
Preferably, this cleanout fluid is prepared by following component by mass percentage:
Propylene glycol 10-20%
Sorbitol 2-7%
Glycerol 3-4%
DBSA 15-35%
Ethanolamine 4-8%
Nonionic surfactant 15-35%
Cocinic acid 8-12%
Maleic acid/acrylic copolymer 0.8-1.5%
Chelating agen 0.8-1.5%
Ethanol 0.8-2.5%
Light tone agent 0.4-1.3%
Water 5-15%
Essence 0.8-1.5%
Preservative 0.08-0.15%
Aversive agent 0.0001-0.02%
Enzyme 0.1-1.5%.
Preferably, described content of propylene glycol 12-19%, and sorbitol content is in 2-5%.Product moisture-retaining capacity is Good, content of propylene glycol increases, and water soluble film easily becomes dry, becomes fragile.
Preferably, the water content of cleanout fluid is in 8-18%, product appearance and optimal stability.Water content is little, water-soluble Film easily becomes dry, becomes fragile, and water content is big, and product is softer, is easily broken.
Preferably, during ethanol content 0.6-2%, optimal to product solubilising and the impact to abnormal smells from the patient, content is little, and product holds Easily muddy, content is many, can affect the taste of final products.
Preferably, described nonionic surfactant includes the polyoxyethylene ether of alkyl phenol, aliphatic alcohol polyethenoxy One or more of ether, fatty acid methyl ester APEO and detergent 6501.Preferably, described fatty alcohol polyoxy second Alkene ether selects polyoxyethylene lauryl ether, 12-14 carbon primary alconol polyoxyethylene ether, 12-14 carbon secondary alcohol polyoxyethylene ether, collateralization 13 Carbon Guerbet polyoxyethylenated alcohol, collateralization 10 carbon Guerbet polyoxyethylenated alcohol, 10 carbon polyoxyethylenated alcohol of straight chain, One or more of 8 carbon capryl alcohol polyoxyethylene ether of straight chain, 8 carbon isooctanol polyethoxylate of straight chain.
Preferably, AEO-7 in described nonionic surfactant:AEO-9=1.7:1-2.3:1 or AEO-9:AEO- 3=1:1.2–1:2;Described nonionic surfactant:DBSA=2:8-3:7.Above-mentioned formulation actives The dirt-removing power brought is the strongest.
Ethanolamine is used for generating DBSA ethanolamine and cocinic acid ethanolamine.Preferably, described second Hydramine selects one or more of monoethanolamine, triethanolamine, diethanolamine to mix.During neutralization DBSA, Preferably select raw material to be ordered as:Monoethanolamine, triethanolamine, diethanolamine.
Preferably, in benzoic acid, sodium benzoate, sorbic acid, potassium sorbate, calcium propionate selected by described preservative Plant or multiple mixing.
Preferably, described aversive agent selects one of saccharin benzylamine amide and benzene first DEXAMETHASONE SODIUM PHOSPHATE ammonium or two kinds of mixing.
Preferably, described enzyme selects one or more of protease, Digestive Enzyme, amylase, cellulase to mix.
In order to realize above-mentioned second purpose, present invention employs following technical scheme:
A kind of method that pearl is coagulated in laundry prepared described in any one technical scheme above-mentioned, the method includes following step Suddenly:
1) propylene glycol, Sorbitol, glycerol, DBSA, monoethanolamine, nonionic surfactant, Cortex cocois radiciss are pressed Oleic acid, maleic acid/acrylic copolymer, chelating agen order sequentially add raw material, when temperature is less than 50 DEG C, add ethanol, light tone Agent, deionized water, essence, preservative, aversive agent and enzyme mixing;
2), after liquid is qualified, carry out water soluble film packaging.
Preferably, the optional material polyvinyl alcohol of described water soluble film, polyvinyl acetal, Polyvinylpyrrolidone, Polyacrylic acid, maleic acid/acrylic copolymer, starch, gelatin, xanthan gum, guar gum, hydroxypropyl methyl cellulose, and with One or more of the homopolymerization of upper composition, copolymer and altered contents mix.
The present invention, due to employing above-mentioned technical scheme, is compared with common aqueous based systems liquid detergent, can make active matter Content dramatically increases (content is up to more than 80%), accomplishes the ultra concentration of real meaning, reduces packaging consumption, storage space and fortune Defeated cost.The product of the present invention has high detergency, by the test of national standard QB/T1224, three blocks of soiled cottons that standard is required Detergency is more than 5 times of standard liquid detergent;Especially to staple fibre and staple fibre/cotton textiles blending material cloth, use WFK-20C and WFK-20D soiled cotton is tested, and detergency is up to 8 times of standard liquid detergent.Colour clothes color can be made fresher simultaneously Gorgeous.
Specific embodiment
Embodiment 1
A kind of light tone increases the solidifying pearl of gorgeous laundry, is made up of water soluble film and its interior cleanout fluid, cleanout fluid is by mass percentage Prepared by following component:
The method that pearl is coagulated in above-mentioned laundry, the method comprises the following steps:
1) propylene glycol, Sorbitol, glycerol, DBSA, monoethanolamine, nonionic surfactant, Cortex cocois radiciss are pressed Oleic acid, maleic acid/acrylic copolymer, chelating agen order sequentially add raw material, when temperature is less than 50 DEG C, add ethanol, light tone Agent, deionized water, essence, preservative, aversive agent and enzyme mixing;
2), after liquid is qualified, carry out water soluble film packaging.Manner of packing can be selected for water seal or heat-sealing.Water soluble film can be gathered material selection Vinyl alcohol, polyvinyl acetal, Polyvinylpyrrolidone, polyacrylic acid, maleic acid/acrylic copolymer, starch, gelatin, Xanthan gum, guar gum, hydroxypropyl methyl cellulose, and the homopolymerization of above composition, copolymer and altered contents.The composition of film can To be the mixing of above single component or Multiple components.
Quantitative package of the present invention, easy to use, liquid will not be made to be stained with to hand;Reduce the waste in using;Concentrated formulations Take less space in the family.Packaging uses water soluble film, in temperature 0-70 DEG C, can be all soluble in water in 4 minutes, no matter Machine washing, hand washing, all easily.
Embodiment 2
A kind of light tone increases the solidifying pearl of gorgeous laundry, is made up of water soluble film and its interior cleanout fluid, cleanout fluid is by mass percentage Prepared by following component:
The method that pearl is coagulated in above-mentioned laundry, the method comprises the following steps:
1) propylene glycol, Sorbitol, glycerol, DBSA, monoethanolamine, nonionic surfactant, Cortex cocois radiciss are pressed Oleic acid, maleic acid/acrylic copolymer, chelating agen order sequentially add raw material, when temperature is less than 50 DEG C, add ethanol, light tone Agent, deionized water, essence, preservative, aversive agent and enzyme mixing;
2), after liquid is qualified, carry out water soluble film packaging.Manner of packing can be selected for water seal or heat-sealing.Water soluble film can be gathered material selection Vinyl alcohol, polyvinyl acetal, Polyvinylpyrrolidone, polyacrylic acid, maleic acid/acrylic copolymer, starch, gelatin, Xanthan gum, guar gum, hydroxypropyl methyl cellulose, and the homopolymerization of above composition, copolymer and altered contents.The composition of film can To be the mixing of above single component or Multiple components.
Embodiment 3
A kind of light tone increases the solidifying pearl of gorgeous laundry, is made up of water soluble film and its interior cleanout fluid, cleanout fluid is by mass percentage Prepared by following component:
The method that pearl is coagulated in above-mentioned laundry, the method comprises the following steps:
1) propylene glycol, Sorbitol, glycerol, DBSA, monoethanolamine, nonionic surfactant, Cortex cocois radiciss are pressed Oleic acid, maleic acid/acrylic copolymer, chelating agen order sequentially add raw material, when temperature is less than 50 DEG C, add ethanol, light tone Agent, deionized water, essence, preservative, aversive agent and enzyme mixing;
2), after liquid is qualified, carry out water soluble film packaging.Manner of packing can be selected for water seal or heat-sealing.Water soluble film can be gathered material selection Vinyl alcohol, polyvinyl acetal, Polyvinylpyrrolidone, polyacrylic acid, maleic acid/acrylic copolymer, starch, gelatin, Xanthan gum, guar gum, hydroxypropyl methyl cellulose, and the homopolymerization of above composition, copolymer and altered contents.The composition of film can To be the mixing of above single component or Multiple components.

Claims (10)

1. a kind of light tone increases the solidifying pearl of gorgeous laundry, by water soluble film and its interior cleanout fluid constitutes it is characterised in that cleanout fluid is by quality Percentages are prepared by following component:
2. a kind of light tone according to claim 1 increase the gorgeous solidifying pearl of laundry it is characterised in that this cleanout fluid by mass percentage Meter is prepared by following component:
3. a kind of light tone according to claim 1 and 2 increase the solidifying pearl of gorgeous laundry it is characterised in that:Content of propylene glycol is 12- 19%,
And sorbitol content is 2-5%.
4. a kind of light tone according to claim 1 increases the solidifying pearl of gorgeous laundry it is characterised in that nonionic surfactant includes One of the polyoxyethylene ether of alkyl phenol, fatty alcohol-polyoxyethylene ether, fatty acid methyl ester APEO and detergent 6501 Or it is multiple;Preferably, fatty alcohol-polyoxyethylene ether selects polyoxyethylene lauryl ether, 12-14 carbon primary alconol polyoxyethylene ether, 12-14 Carbon secondary alcohol polyoxyethylene ether, collateralization 13 carbon Guerbet polyoxyethylenated alcohol, collateralization 10 carbon Guerbet alcohol polyoxyethylene In ether, 10 carbon polyoxyethylenated alcohol of straight chain, 8 carbon capryl alcohol polyoxyethylene ether of straight chain, 8 carbon isooctanol polyethoxylate of straight chain One or more.
5. a kind of light tone according to claim 1 increases the solidifying pearl of gorgeous laundry it is characterised in that in nonionic surfactant AEO-7:AEO-9=1.7:1-2.3:1 or AEO-9:AEO-3=1:1.2–1:2;Described nonionic surfactant:12 Alkyl benzene sulphonate=2:8-3:7.
6. a kind of light tone according to claim 1 increase the solidifying pearl of gorgeous laundry it is characterised in that ethanolamine select monoethanolamine, three One or more of ethanolamine, diethanolamine mix.
7. a kind of light tone according to claim 1 increases the solidifying pearl of gorgeous laundry it is characterised in that aversive agent selects saccharin benzylamine acyl One of amine and benzene first DEXAMETHASONE SODIUM PHOSPHATE ammonium or two kinds of mixing.
8. a kind of light tone according to claim 1 increase the solidifying pearl of gorgeous laundry it is characterised in that;Enzyme select protease, Digestive Enzyme, One or more of amylase, cellulase mix.
9. a kind of laundry prepared described in claim 1~8 any one claim coagulates the method for pearl it is characterised in that the party Method comprises the following steps:
1) press propylene glycol, Sorbitol, glycerol, DBSA, monoethanolamine, nonionic surfactant, cocinic acid, Maleic acid/acrylic copolymer, chelating agen order sequentially add raw material, when temperature is less than 50 DEG C, adds ethanol, light tone agent, go Ionized water, essence, preservative, aversive agent and enzyme mixing;
2), after liquid is qualified, carry out water soluble film packaging.
10. laundry according to claim 9 coagulates the preparation method of pearl it is characterised in that water soluble film can material selection polyethylene Alcohol, polyvinyl acetal, Polyvinylpyrrolidone, polyacrylic acid, maleic acid/acrylic copolymer, starch, gelatin, xanthan Glue, guar gum, hydroxypropyl methyl cellulose, and one or more of the homopolymerization of above composition, copolymer and altered contents Mixing.
CN201610713271.0A 2016-08-23 2016-08-23 Brightening laundry bead and preparation method thereof Pending CN106381234A (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106906059A (en) * 2017-02-20 2017-06-30 广州市南大实业有限公司 A kind of solidifying pearl of Low-foam and easily rinsing laundry and preparation method and application
CN108330024A (en) * 2018-05-03 2018-07-27 上海奥威日化有限公司 Cleansing composition
CN110484384A (en) * 2019-09-06 2019-11-22 广州乐居日化用品有限公司 A kind of solidifying pearl and preparation method thereof of doing washing
CN111592942A (en) * 2020-06-11 2020-08-28 浙江施维康生物医学材料有限公司 Color-crossing-preventing washing condensation bead and preparation method thereof
CN113278476A (en) * 2021-05-26 2021-08-20 广州大白生物科技有限公司 Water-soluble film-wrapped beadlets comprising cinnamon oil microcapsule film
CN113736576A (en) * 2021-10-21 2021-12-03 广州市迪梵日用品有限公司 Washing gel bead and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102433225A (en) * 2011-12-29 2012-05-02 青岛蔚蓝生物集团有限公司 Alkaline proteinase coated micro-pill and preparation method thereof
CN103154355A (en) * 2010-03-09 2013-06-12 埃科莱布美国股份有限公司 Liquid concentrated fabric softener composition
WO2015134827A1 (en) * 2014-03-07 2015-09-11 The Procter & Gamble Company Compositions comprising a bittering agent
CN105039014A (en) * 2015-07-23 2015-11-11 广州柏俐臣化妆品有限公司 Essential oil condensation beads for washing clothes and preparing method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103154355A (en) * 2010-03-09 2013-06-12 埃科莱布美国股份有限公司 Liquid concentrated fabric softener composition
CN102433225A (en) * 2011-12-29 2012-05-02 青岛蔚蓝生物集团有限公司 Alkaline proteinase coated micro-pill and preparation method thereof
WO2015134827A1 (en) * 2014-03-07 2015-09-11 The Procter & Gamble Company Compositions comprising a bittering agent
CN105039014A (en) * 2015-07-23 2015-11-11 广州柏俐臣化妆品有限公司 Essential oil condensation beads for washing clothes and preparing method thereof

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106906059A (en) * 2017-02-20 2017-06-30 广州市南大实业有限公司 A kind of solidifying pearl of Low-foam and easily rinsing laundry and preparation method and application
CN108330024A (en) * 2018-05-03 2018-07-27 上海奥威日化有限公司 Cleansing composition
CN110484384A (en) * 2019-09-06 2019-11-22 广州乐居日化用品有限公司 A kind of solidifying pearl and preparation method thereof of doing washing
CN111592942A (en) * 2020-06-11 2020-08-28 浙江施维康生物医学材料有限公司 Color-crossing-preventing washing condensation bead and preparation method thereof
CN113278476A (en) * 2021-05-26 2021-08-20 广州大白生物科技有限公司 Water-soluble film-wrapped beadlets comprising cinnamon oil microcapsule film
CN113278476B (en) * 2021-05-26 2023-08-11 广州大白生物科技有限公司 Water-soluble film-coated gel bead containing cinnamon oil microcapsule film
CN113736576A (en) * 2021-10-21 2021-12-03 广州市迪梵日用品有限公司 Washing gel bead and preparation method thereof

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Application publication date: 20170208