CN106350288A - Cross-color-proof type laundry condensate bead and preparation method thereof - Google Patents

Cross-color-proof type laundry condensate bead and preparation method thereof Download PDF

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Publication number
CN106350288A
CN106350288A CN201610718715.XA CN201610718715A CN106350288A CN 106350288 A CN106350288 A CN 106350288A CN 201610718715 A CN201610718715 A CN 201610718715A CN 106350288 A CN106350288 A CN 106350288A
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Prior art keywords
pearl
color
colour contamination
type laundry
alcohol
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Inventor
马赛波
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YUYAO DELPACK DAILY PRODUCT Co Ltd
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YUYAO DELPACK DAILY PRODUCT Co Ltd
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Priority to CN201610718715.XA priority Critical patent/CN106350288A/en
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C11D1/831—Mixtures of non-ionic with anionic compounds of sulfonates with ethers of polyoxyalkylenes without phosphates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/08—Liquid soap, e.g. for dispensers; capsuled
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2006—Monohydric alcohols
    • C11D3/201—Monohydric alcohols linear
    • C11D3/2013—Monohydric alcohols linear fatty or with at least 8 carbon atoms in the alkyl chain
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2041—Dihydric alcohols
    • C11D3/2044—Dihydric alcohols linear
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2065—Polyhydric alcohols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof
    • C11D3/2079—Monocarboxylic acids-salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/30—Amines; Substituted amines ; Quaternized amines
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/32—Amides; Substituted amides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
    • C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/386—Preparations containing enzymes, e.g. protease or amylase
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/04—Carboxylic acids or salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • C11D1/721—End blocked ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/10—Objects to be cleaned
    • C11D2111/12—Soft surfaces, e.g. textile

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)

Abstract

The invention relates to the field of washing agents and in particular relates to a cross-color-proof type laundry condensate bead and a preparation method thereof. The cross-color-proof type laundry condensate bead is composed of a water-soluble film and washing liquid in the water-soluble film; the washing liquid is prepared from the following components: propylene glycol, sorbierite, glycerin, dodecylbenzenesulfonic acid, ethanolamine, a non-ionic surfactant, coconut oil acid, a maleic acid/acrylic acid copolymer, a chelating agent, ethanol, a cross-color-proof agent, de-ionized water, essence, a preservative, a bittering agent and an enzyme. The product provided by the invention has extremely high detergency power; meanwhile, a cationic polymer is added and can stably coexist through formula regulation; light-color clothes and deep-color clothes, which have different colors, are obviously improved, or cross color is obviously improved when the light-color clothes and the deep-color clothes are washed together.

Description

Pearl and preparation method thereof is coagulated in a kind of anti-colour contamination type laundry
Technical field
The present invention relates to detergent applications, solidifying pearl of more particularly to a kind of anti-colour contamination type laundry and preparation method thereof.
Background technology
Traditional liquid detergent main active substances are linear dodecylbenzene sulfonate and other builders；Straight chain dodecane Base benzene sulfonate derives from petroleum chemicals, belongs to non-renewable raw material, and this raw material is intolerant to hard water, goes down dirt in water environment from the beginning Power substantially reduces, and is unfavorable for washing；Other auxiliary agents, 4a zeolite, such as sodium tripolyphosphate contain phosphorus, are unfavorable for environmental conservation；Aluminum is pure Alkali, Caustic soda alkalescence are higher, so that medicated clothing is faded, damaging laundry；Natrii Sulfas belong to implant, and inefficient cycle utilizes, can be to operation band Carry out unnecessary waste.Additionally, conventional liquid detergent utilizes conventional surfactants and alkaline assistant, only there is washing cleaning Effect, submissive less effective.
It is many that Chinese invention patent application (application number cn201510437124.0 applying date 2015.07.23) discloses one kind The solidifying pearl of function laundry, its weight percent composition includes: c14-16 alkene sulfonic acid sodium 30-35%, fatty alcohol-polyoxyethylene ether (9eo) 15-20%, DBSA 10-12%, kation alkyl many glucosides 5-8%, disodiumedetate 0.01-0.03%, d- pantothenylol 1-2%, phenoxyethanol 0.3-0.7%, essence 0.1-0.3%, triclosan 0.05-0.1%, albumen Enzyme 0.01-0.03%, balance of deionized water.This product has washing, nursing, sterilization, smelly eliminating, pleasant mental and body multi-efficiency, Energy-saving and emission-reduction, easy to use.
Chinese invention patent application (application number cn201510436322.5 applying date 2015.07.23) discloses a kind of essence Oil wash clothing coagulates pearl, and its weight percent composition includes: 20～25% c14-16 alkene sulfonic acid sodium, 15～20% poly alkyl alcohol Oxygen vinyl Ether (9eo), 10～12% polyoxyethylenated alcohol sodium sulfate, 8～10% Laurel alcohol sulfuric ester triethanolamine Salt, 2～4% Polyethylene Glycol, 1～3% many glucosides of kation alkyl, 1～2% d- pantothenylol, 0.3～0.7% benzene oxygen Ethanol, 0.05～0.01% disodiumedetate, 0.5～1% jasmin quintessence oil, 0.05～0.1% triclosan, 0.1～0.2% protease, 0.002～0.005% red 33 pigments, balance of deionized water.This product has washing, shield Reason, sterilization, smelly eliminating, pleasant mental and body multi-efficiency, easy to use.
Chinese invention patent application (application number cn201610216176.x applying date 2016.04.09) discloses a kind of soft Along solidifying pearl of laundry and preparation method thereof, this laundry coagulate pearl include 25～35% isomery c13 fatty alcohol-polyoxyethylene ether, 10～20% Fatty alcohol-polyoxyethylene ether (9eo), 10～20% polyoxyethylenated alcohol sodium sulfate, 5～10% fatty alcohol-polyoxyethylene ether (7eo), 1.5～2.5% washing synergist wr, 1.5～2.5% isomeric alcohol polyethenoxy ether, 0.8～1.5% cation are submissive Agent, 0.02～0.05% antibacterial, 0.5～1.0% microcapsule essence, 0.01-0.03% alkaline protease and 20～38% are molten Agent (propylene glycol), this product have stronger tax fragrance, safe and convenient to use, washability and submissive effect preferable the features such as.
Above-mentioned various laundries are coagulated pearl and are had different formulations, also have different functions and effect simultaneously, solidifying with laundry The popularization of pearl, to laundry, solidifying pearl has different demands it is therefore necessary to develop production to the product of subdivision for consumer.
Content of the invention
First purpose of the present invention is to provide a kind of anti-colour contamination type laundry solidifying pearl, and this laundry is coagulated pearl and had high detergency And can stably coexist hence it is evident that improving the light medicated clothing of different colours, dark medicated clothing, or light medicated clothing is together with dark medicated clothing The colour contamination of washing.Second object of the present invention is the preparation method providing above-mentioned laundry to coagulate pearl.
In order to realize above-mentioned first purpose, present invention employs following technical scheme:
Pearl is coagulated in a kind of anti-colour contamination type laundry, is made up of water soluble film and its interior cleanout fluid, cleanout fluid is by mass percentage Prepared by following component:
Propylene glycol 8-20%
Sorbitol 2-9%
Glycerol 2-5%
DBSA 10-40%
Ethanolamine 3-10%
Nonionic surfactant 10-40%
Cocinic acid 5-15%
Maleic acid/acrylic copolymer 0.5-2%
Chelating agen 0.5-2%
Ethanol 0.5-3%
Anti- colour contamination agent 0.4-1.5%
Water 3-20%
Essence 0.7-2%
Preservative 0.05-0.2%
Aversive agent 0.0001-0.02%
Enzyme 0.05-2%.
Preferably, this cleanout fluid is prepared by following component by mass percentage:
Propylene glycol 10-20%
Sorbitol 2-7%
Glycerol 3-4%
DBSA 15-35%
Ethanolamine 4-8%
Nonionic surfactant 15-35%
Cocinic acid 8-12%
Maleic acid/acrylic copolymer 0.8-1.5%
Chelating agen 0.8-1.5%
Ethanol 0.8-2.5%
Anti- colour contamination agent 0.4-1.3%
Water 5-15%
Essence 0.8-1.5%
Preservative 0.08-0.15%
Aversive agent 0.0001-0.02%
Enzyme 0.1-1.5%.
Preferably, described content of propylene glycol 12-19%, and sorbitol content is in 2-5%.Product moisture-retaining capacity is Good, content of propylene glycol increases, and water soluble film easily becomes dry, becomes fragile.
Preferably, the water content of cleanout fluid is in 8-18%, product appearance and optimal stability.Water content is little, water-soluble Film easily becomes dry, becomes fragile, and water content is big, and product is softer, is easily broken.
Preferably, during ethanol content 0.6-2%, optimal to product solubilising and the impact to abnormal smells from the patient, content is little, and product holds Easily muddy, content is many, can affect the taste of final products.
Preferably, described nonionic surfactant includes the polyoxyethylene ether of alkyl phenol, aliphatic alcohol polyethenoxy One or more of ether, fatty acid methyl ester APEO and detergent 6501.Preferably, described fatty alcohol polyoxy second Alkene ether selects polyoxyethylene lauryl ether, 12-14 carbon primary alconol polyoxyethylene ether, 12-14 carbon secondary alcohol polyoxyethylene ether, collateralization 13 Carbon Guerbet polyoxyethylenated alcohol, collateralization 10 carbon Guerbet polyoxyethylenated alcohol, 10 carbon polyoxyethylenated alcohol of straight chain, One or more of 8 carbon capryl alcohol polyoxyethylene ether of straight chain, 8 carbon isooctanol polyethoxylate of straight chain.
Preferably, aeo-7:aeo-9=1.7:1-2.3:1 or aeo-9:aeo- in described nonionic surfactant 3=1:1.2 1:2；Described nonionic surfactant: DBSA=2:8-3:7.Above-mentioned formulation actives The dirt-removing power brought is the strongest.
Ethanolamine is used for generating DBSA ethanolamine and cocinic acid ethanolamine.Preferably, described second Hydramine selects one or more of monoethanolamine, triethanolamine, diethanolamine to mix.During neutralization DBSA, Preferably select raw material to be ordered as: monoethanolamine, triethanolamine, diethanolamine.
Preferably, in benzoic acid, sodium benzoate, sorbic acid, potassium sorbate, calcium propionate selected by described preservative Plant or multiple mixing.
Preferably, described aversive agent selects one of saccharin benzylamine amide and benzene first DEXAMETHASONE SODIUM PHOSPHATE ammonium or two kinds of mixing.
Preferably, described enzyme selects one or more of protease, Digestive Enzyme, amylase, cellulase to mix.
Preferably, acylamide polymer is selected in described anti-colour contamination agent.
In order to realize above-mentioned second purpose, present invention employs following technical scheme:
A kind of method that pearl is coagulated in laundry prepared described in any one technical scheme above-mentioned, the method includes following step Rapid:
1) propylene glycol, Sorbitol, glycerol, DBSA, monoethanolamine, nonionic surfactant, Cortex cocois radiciss are pressed Oleic acid, maleic acid/acrylic copolymer, chelating agen order sequentially add raw material, when temperature is less than 50 DEG C, add ethanol, anti-string Toner, deionized water, essence, preservative, aversive agent and enzyme mixing；
2), after liquid is qualified, carry out water soluble film packaging.
Preferably, the optional material polyvinyl alcohol of described water soluble film, polyvinyl acetal, Polyvinylpyrrolidone, Polyacrylic acid, maleic acid/acrylic copolymer, starch, gelatin, xanthan gum, guar gum, hydroxypropyl methyl cellulose, and with One or more of the homopolymerization of upper composition, copolymer and altered contents mix.
The present invention, due to employing above-mentioned technical scheme, is compared with common aqueous based systems liquid detergent, can make active matter Content dramatically increases (content is up to more than 80%), accomplishes the ultra concentration of real meaning, reduces packaging consumption, storage space and fortune Defeated cost.The product of the present invention has high detergency, by the test of national standard qb/t1224, three blocks of soiled cottons that standard is required Detergency is more than 5 times of standard liquid detergent；Especially to staple fibre and staple fibre/cotton textiles blending material cloth, use Wfk-20c and wfk-20d soiled cotton is tested, and detergency is up to 8 times of standard liquid detergent.Add cationic polymer simultaneously, pass through Formula adjustment, can stably coexist hence it is evident that improving the light medicated clothing of different colours, dark medicated clothing, or light medicated clothing and dark color The colour contamination that medicated clothing washs together.
Specific embodiment
Embodiment 1
Pearl is coagulated in a kind of anti-colour contamination type laundry, is made up of water soluble film and its interior cleanout fluid, cleanout fluid is by mass percentage Prepared by following component:
The method that pearl is coagulated in above-mentioned laundry, the method comprises the following steps:
1) propylene glycol, Sorbitol, glycerol, DBSA, monoethanolamine, nonionic surfactant, Cortex cocois radiciss are pressed Oleic acid, maleic acid/acrylic copolymer, chelating agen order sequentially add raw material, when temperature is less than 50 DEG C, add ethanol, anti-string Toner, deionized water, essence, preservative, aversive agent and enzyme mixing；
2), after liquid is qualified, carry out water soluble film packaging.Manner of packing can be selected for water seal or heat-sealing.Water soluble film can be gathered material selection Vinyl alcohol, polyvinyl acetal, Polyvinylpyrrolidone, polyacrylic acid, maleic acid/acrylic copolymer, starch, gelatin, Xanthan gum, guar gum, hydroxypropyl methyl cellulose, and the homopolymerization of above composition, copolymer and altered contents.The composition of film can To be the mixing of above single component or Multiple components.
Quantitative package of the present invention, easy to use, liquid will not be made to be stained with to hand；Reduce the waste in using；Concentrated formulations Take less space in the family.Packaging uses water soluble film, in temperature 0-70 DEG C, can be all soluble in water in 4 minutes, no matter Machine washing, hand washing, all easily.
Embodiment 2
Pearl is coagulated in a kind of anti-colour contamination type laundry, is made up of water soluble film and its interior cleanout fluid, cleanout fluid is pressed by mass percentage Meter is prepared by following component:
The method that pearl is coagulated in above-mentioned laundry, the method comprises the following steps:
1) propylene glycol, Sorbitol, glycerol, DBSA, monoethanolamine, nonionic surfactant, Cortex cocois radiciss are pressed Oleic acid, maleic acid/acrylic copolymer, chelating agen order sequentially add raw material, when temperature is less than 50 DEG C, add ethanol, anti-string Toner, deionized water, essence, preservative, aversive agent and enzyme mixing；
2), after liquid is qualified, carry out water soluble film packaging.Manner of packing can be selected for water seal or heat-sealing.Water soluble film can be gathered material selection Vinyl alcohol, polyvinyl acetal, Polyvinylpyrrolidone, polyacrylic acid, maleic acid/acrylic copolymer, starch, gelatin, Xanthan gum, guar gum, hydroxypropyl methyl cellulose, and the homopolymerization of above composition, copolymer and altered contents.The composition of film can To be the mixing of above single component or Multiple components.
Embodiment 3
Pearl is coagulated in a kind of anti-colour contamination type laundry, is made up of water soluble film and its interior cleanout fluid, cleanout fluid is pressed by mass percentage Meter is prepared by following component:
The method that pearl is coagulated in above-mentioned laundry, the method comprises the following steps:
1) propylene glycol, Sorbitol, glycerol, DBSA, monoethanolamine, nonionic surfactant, Cortex cocois radiciss are pressed Oleic acid, maleic acid/acrylic copolymer, chelating agen order sequentially add raw material, when temperature is less than 50 DEG C, add ethanol, anti-string Toner, deionized water, essence, preservative, aversive agent and enzyme mixing；
2), after liquid is qualified, carry out water soluble film packaging.Manner of packing can be selected for water seal or heat-sealing.Water soluble film can be gathered material selection Vinyl alcohol, polyvinyl acetal, Polyvinylpyrrolidone, polyacrylic acid, maleic acid/acrylic copolymer, starch, gelatin, Xanthan gum, guar gum, hydroxypropyl methyl cellulose, and the homopolymerization of above composition, copolymer and altered contents.The composition of film can To be the mixing of above single component or Multiple components.

Claims (10)

1. the solidifying pearl of a kind of anti-colour contamination type laundry, by water soluble film and its interior cleanout fluid constitutes it is characterised in that cleanout fluid is by quality Percentages are prepared by following component:
2. a kind of solidifying pearl of anti-colour contamination type laundry according to claim 1 it is characterised in that cleanout fluid pearl by mass percentage Meter is prepared by following component:
3. a kind of solidifying pearl of anti-colour contamination type laundry according to claim 1 and 2 it is characterised in that: content of propylene glycol is 12- 19%, and sorbitol content is 2-5%.
4. a kind of anti-colour contamination type laundry according to claim 1 coagulates pearl it is characterised in that nonionic surfactant includes One of the polyoxyethylene ether of alkyl phenol, fatty alcohol-polyoxyethylene ether, fatty acid methyl ester APEO and detergent 6501 Or it is multiple；Preferably, fatty alcohol-polyoxyethylene ether selects polyoxyethylene lauryl ether, 12-14 carbon primary alconol polyoxyethylene ether, 12-14 Carbon secondary alcohol polyoxyethylene ether, collateralization 13 carbon Guerbet polyoxyethylenated alcohol, collateralization 10 carbon Guerbet alcohol polyoxyethylene In ether, 10 carbon polyoxyethylenated alcohol of straight chain, 8 carbon capryl alcohol polyoxyethylene ether of straight chain, 8 carbon isooctanol polyethoxylate of straight chain One or more.
5. a kind of solidifying pearl of anti-colour contamination type laundry according to claim 1 is it is characterised in that in nonionic surfactant Aeo-7:aeo-9=1.7:1-2.3:1 or aeo-9:aeo-3=1:1.2 1:2；Described nonionic surfactant: 12 Alkyl benzene sulphonate=2:8-3:7.
6. a kind of solidifying pearl of anti-colour contamination type laundry according to claim 1 it is characterised in that ethanolamine select monoethanolamine, three One or more of ethanolamine, diethanolamine mix.
7. a kind of anti-colour contamination type laundry according to claim 1 coagulates pearl it is characterised in that aversive agent selects saccharin benzylamine acyl One of amine and benzene first DEXAMETHASONE SODIUM PHOSPHATE ammonium or two kinds of mixing；Enzyme selects one of protease, Digestive Enzyme, amylase, cellulase Or multiple mixing.
8. a kind of anti-colour contamination type solidifying pearl of laundry according to claim 1 is it is characterised in that anti-colour contamination agent is selected in anti-colour contamination agent From acylamide polymer.
9. a kind of laundry prepared described in claim 1～8 any one claim coagulates the method for pearl it is characterised in that the party Method comprises the following steps:
1) press propylene glycol, Sorbitol, glycerol, DBSA, monoethanolamine, nonionic surfactant, cocinic acid, Maleic acid/acrylic copolymer, chelating agen order sequentially add raw material, temperature be less than 50 DEG C when, add ethanol, anti-colour contamination agent, Deionized water, essence, preservative, aversive agent and enzyme mixing；
2), after liquid is qualified, carry out water soluble film packaging.
10. laundry according to claim 9 coagulates the preparation method of pearl it is characterised in that water soluble film can material selection polyethylene Alcohol, polyvinyl acetal, Polyvinylpyrrolidone, polyacrylic acid, maleic acid/acrylic copolymer, starch, gelatin, xanthan Glue, guar gum, hydroxypropyl methyl cellulose, and one or more of the homopolymerization of above composition, copolymer and altered contents Mixing.
CN201610718715.XA 2016-08-23 2016-08-23 Cross-color-proof type laundry condensate bead and preparation method thereof Pending CN106350288A (en)

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Application publication date: 20170125