DE102008047233A1 - Solid textile care composition, useful for conditioning textile fabrics and in detergents and cleaning products, comprises water-soluble carrier, water-soluble polymer, textile care compound, polysaccharide and fragrance - Google Patents

Abstract

Solid textile care composition comprises a water-soluble carrier, water-soluble polymer, a textile care compound, polysaccharide and fragrance, where the water-soluble carrier exists in a particulate form and exhibits a coating comprising water-soluble polymer and fragrance, and a mixture of the textile care compound and polysaccharide is at least partially incorporated into the coating. An independent claim is included for a process for preparing the solid, textile care composition, comprising: either melting a water soluble polymer in a molten state with mixing the fragrance, adding the resulting melt on a particulate carrier that is at least partially coated, and incorporating a mixture of textile care compound and polysaccharide into the molten coating; or melting a water soluble polymer in a molten state with mixing the fragrance, adding the resulting melt on a particulate carrier that is at least partially coated with a mixture of textile care compound and polysaccharide.

Description

The The invention relates to a solid, textile-care composition as well as their use and manufacture. Furthermore, the concerns Invention a detergent or cleaning agent containing the solid, textile-care Composition contains.

By Repeated washing often causes textiles to harden and lose their weight Softness. To give textiles their softness / flexibility, to give them a pleasant fragrance and / or their anti-static To improve properties, the textiles are after the actual Washing and cleaning process in a subsequent rinsing process treated with a fabric softener.

The Most softeners on the market are watery Formulations containing as cationic a main active ingredient Textile softening compound, one or two long-chain Contain alkyl groups in one molecule. Far common cationic fabric softening compounds For example, methyl N- (2-hydroxyethyl) -N, N-di (tallow acyloxyethyl) ammonium compounds or N, N-dimethyl-N, N-di (tallowacyloxyethyl) ammonium compounds.

These conventional softener formulations can because of the cationic, textile softening compounds not simultaneously with the detergent or cleaning agent in the actual Washing or cleaning process used as the cationic Textile softening compounds with the anionic surfactants the washing or cleaning agent undesirable interaction. Therefore, an additional flushing process is necessary but it is time and energy intensive.

One Another disadvantage is that conventional softener not the deposit of limescale during Prevent the rinsing process on the laundry. additionally leave the conventional softener often Unattractive deposit in the dispenser of the washing machine.

Also with other textile-care compounds, problems may arise occur, for example, a separate dosage and / or a separate rinse required.

From the WO 2007/115872 A1 are therefore solid textile treatment agents with a water-soluble carrier which comprises a coating of a water-soluble polymer and perfume, the coating being at least partially coated with a textile-care compound.

at However, production and storage can happen the individual textile treatment agent particles due to a high Glue stick together and not easily processed or can be dosed by the consumer.

It is therefore an object of the present invention, a solid Textile treatment agent with a water-soluble carrier, an enclosure of a water-soluble polymer, having a perfume and a textile-care compound, to provide, which in the manufacture and / or storage no or forms significantly less aggregates or clumps.

These Task is solved by a solid, textile care A composition comprising a water-soluble carrier, a water-soluble polymer, a textile-care compound, a polysaccharide and a perfume, wherein the water-soluble Carrier is present in particulate form and at least partially an envelope of the water-soluble Polymer and the perfume and a mixture of the Textile-care compound and the polysaccharide at least partially in and / or at least partially present on the wrapper is.

Surprisingly It has been shown that sticking of the textile treatment agent particles can be prevented if the serving a mixture from the fabric care agent and a polysaccharide. Neither in the production nor during storage showed such enveloped textile care compositions to clump together tendencies or to agglomerate. In addition, such are enveloped Textile treatment agent particles flowable. Furthermore, it has been shown that the freshly prepared textile treatment agent particles be filled at higher product temperatures which can lead to shorter production times.

As well It has been found that textile treatment agent particles whose coating a blend of the fabric care compound and a polysaccharide has retained its crystalline appearance for longer.

Farther It is advantageous that the solid, textile-care composition used in the wash cycle of a laundry cleaning process can be and so the textile-care compound and the perfume already directly at the beginning of the washing process for washing be transported and develop their full potential. Furthermore, this solid composition is simpler and better too handle as liquid compositions as there are no drops remain at the edge of the bottle, which in the subsequent Storage of the bottle to edges on the ground or lead to unsightly deposits in the area of the closure. The same is true in the event that when dosing something is accidentally spilled from the composition. The spilled composition can also be easier and be removed cleaner.

It it is preferred that the water-soluble carrier is selected from the group consisting of inorganic Alkali metal salts, organic alkali metal salts, inorganic Alkaline earth metal salts, organic alkaline earth metal salts, organic Acids, carbohydrates, silicates, urea and mixtures it.

These Materials are not only cheap, but dissolve very good in water. In addition, these materials are odorless or low odor.

It It is advantageous that the solid, textile-care composition 50 to 99 wt .-%, preferably 75 to 95 wt .-%, of the water-soluble Carrier contains.

Farther it is preferred that the textile-care compound be fabric softening Compounds, bleaches, bleach activators, enzymes, silicone oils, Anti redeposition agents, optical brighteners, grayness inhibitors, Inlet preventer, anti-crease agents, color transfer inhibitors, antimicrobial agents, germicides, fungicides, antioxidants, Antistatic agents, ironing aids, repellents and impregnating agents, Swelling and slipping agents, UV absorbers and mixtures thereof is selected.

It it is particularly preferred that the textile-care compound a textile softening compound. It is very special preferred that the textile softening compound of polysiloxanes, Textile softening clays, cationic polymers and blends selected from this.

One Such fabric softener can be used in the main wash of an automatic Washing or cleaning process can be used. The textile care Composition can, for example, together with the washing or Cleaning agent in the drum or the Einspülkammer be given a washing machine. This has the advantage that no additional rinse is necessary and no unsightly deposits in the dispenser occur The use of polysiloxanes and / or cationic polymers as textile-care compound in the textile-care composition is advantageous because these not only a softening effect show, but also the perfume impression on the laundry strengthen. The use of softening clays as Textile-care compound in the textile-care composition is advantageous as these additionally have a water-softening Have effect and so calcium deposits on the laundry be prevented. It can do it for optimal performance it may be preferred that a textile care composition has a Combination of at least two textile-care compounds contains.

It it is preferred that the water-soluble polymer is selected is from polyalkylene glycols, polyethylene terephthalates, polyvinyl alcohols and mixtures thereof. These water-soluble polymers function as a binder.

Also it is preferred that the water-soluble carrier Particle sizes in the range of 0.6 to 30 mm, in particular 0.8 to 7 mm and more preferably 1 to 3 mm.

Textile care Compositions with particle sizes in the range from 0.8 to 7 mm and more preferably in the range 1 to 3 mm to dose yourself particularly well and specifically.

It It is further preferred that the polysaccharide is selected is from the group comprising glycogen, starch, chitin, Callose, cellulose, dextran, tunicin, inulin, alginic acid, Xanthan, gellan, guar, locust bean gum, carrageenan, derivatives these compounds or mixtures of these compounds and their Derivatives.

It is particularly preferred that the mixture as the polysaccharide is cellulose or a cellulose derivative selected from the group comprising methylcellulose, ethylcellulose, propylcellulose, methylethylcellu loosely, carboxymethylcellulose, ethylcarboxymethylcellulose, hydroxyethylcellulose, hydroxypropylcellulose, carboxymethylhydroxyethylcellulose, methylhydroxyethylcellulose hydroxypropylmethylcellulose, ethylhydroxyethylcellulose, methylethylhydroxyethylcellulose, quaternized cellulose, quaternized cellulose derivatives, amine-modified cellulose, amine-modified cellulose derivatives or mixtures of these compounds.

cellulose and their derivatives are particularly effective in preventing sticking Particles of the textile treatment agent. It has also been shown that in particular cellulose or its derivatives, the color stability dyed, of solid textile-care compositions.

Around the application and / or aesthetic properties To improve the textile care composition, this can be contain additional ingredients, preferably selected from the group consisting of dyes, fillers, Pearlescing agents, skin care compounds, bitter substances and Mixtures thereof.

In a preferred embodiment contains the Fabric care composition 0.1 to 15% by weight, preferably 1 to 10% by weight and more preferably 2 to 7% by weight of perfume.

at conventional liquid fabric softener compositions with quaternary ammonium compounds as textile-care Compounds occurs at higher perfume concentration (> 0.4% by weight of perfume for regular fabric softener compositions and ≥ 1 % By weight for concentrated fabric softener compositions) a problem with the stability of the composition. In the textile-care compositions of the invention can easily handle larger quantities (≥ 1 % By weight) of perfume.

In a particularly preferred embodiment of the invention is the mixture of the textile-care compound and the polysaccharide at least partially incorporated into the envelope. In This embodiment is the advantages described above (reduced to nonexistent tendency to clumping or agglomeration, Color stability, preservation of crystalline appearance, improved Flow behavior, etc.) are particularly pronounced.

In an alternative embodiment is the enclosure or are the serving and the unencumbered ones Areas of the water-soluble carrier at least partly with a mixture of the textile care compound and the polysaccharide coated.

The The invention also relates to the use of an inventive solid, textile-care composition for conditioning of textile fabrics.

Furthermore The invention relates to a method for producing a solid, Textile-care composition comprising a particulate water-soluble carrier, a water-soluble Polymer, a textile-care compound, a polysaccharide and a perfume in which the water-soluble polymer is melted, in the molten state with the perfume is mixed, the melt thus obtained on the particulate Carrier is given that this at least partially enveloped and then into the still melted envelope a blend of the fabric care compound and the polysaccharide is incorporated.

The The invention also relates to a method for producing a solid, Textile-care composition comprising a particulate water-soluble carrier, a water-soluble Polymer, a textile-care compound, a polysaccharide and a perfume in which the water-soluble polymer is melted, in the molten state with the perfume is mixed, the melt thus obtained on the particulate carrier is given that this is at least partially enveloped and the at least partially enveloped particulate Carrier with a mixture of the textile-care compound and the polysaccharide is coated.

Further The invention relates to a washing or cleaning agent comprising a solid, textile-care Composition.

By introducing the textile-care composition according to the invention into a washing or cleaning agent, the consumer is provided with a textile-care washing or cleaning agent ("2 in 1" washing or cleaning agent) and does not need to dose two agents. Thus, when introducing a textile-softening composition into a washing or cleaning agent, the Ver Then you need a textile-softening detergent or cleaner ("2 in 1" washing or cleaning agent) and he does not need to use two agents (detergent, fabric softener) or a separate rinse.

Farther do not need the washing or cleaning and the textile-care Perfumed composition, but only one more the two agents, preferably the textile care composition. This not only leads to lower costs, but is also for consumers with sensitive skin and / or allergies advantageous.

in the The invention is intended below, inter alia, by way of examples be described in more detail.

The Solid textile care composition contains as essential Ingredients a water-soluble carrier, a water-soluble polymer, a textile-care compound, a polysaccharide and a perfume.

One essential ingredient of the textile-care composition the water-soluble carrier. This includes preferred inorganic alkali metal salts such as sodium chloride, Potassium chloride, sodium sulfate, sodium carbonate, potassium sulfate, potassium carbonate, Sodium bicarbonate, potassium bicarbonate or mixtures thereof, organic alkali metal salts such as sodium acetate, potassium acetate, Sodium citrate, sodium tartrate or potassium sodium tartrate, inorganic Alkaline earth metal salts such as calcium chloride, magnesium sulfate or magnesium chloride, organic alkaline earth metal salts such as like calcium lactate, carbohydrates, organic acids like for example, citric acid or tartaric acid, silicates such as water glass, sodium silicate or potassium silicate, Urea and mixtures thereof. The water-soluble carrier may in particular comprise a carbohydrate which, for example is selected from the group consisting of dextrose, fructose, Galactose, isoglucose, glucose, sucrose, raffinose, isomalt, Xylitol and mixtures thereof. The carbohydrate used can for example, sugar candy or hail sugar.

carbohydrates As carriers have the advantage that they reduce the corrosion of metallic components in automatic washing machines do not favor. Citric acid as a carrier has the advantage that the textile care composition is equal to a builder to reduce the water hardness.

Of the Water-soluble carrier can also be mixtures contain the materials mentioned.

It it is preferred that the water-soluble carrier is particulate and particle sizes in the Range of 0.6 to 30 mm, in particular 0.8 to 7 mm and especially preferably 1 to 3 mm.

Under A textile-care compound is in this context each Compound understood, the textile fabrics treated with it gives an advantageous effect, such as a textile-softening Effect, crease resistance or the harmful or negative Effects of cleaning and / or conditioning and / or wearing may occur, such as fading, graying, etc., reduced.

The Textile nourishing compound, for example, a textile-softening Compound, bleaching agents, bleach activators, enzymes, silicone oils, Anti redeposition agents, optical brighteners, grayness inhibitors, Inlet preventer, anti-crease agents, color transfer inhibitors, antimicrobial agents, germicides, fungicides, antioxidants, Antistatic agents, ironing aids, repellents and impregnating agents, Swelling and slipping agents, UV absorbers and mixtures thereof include. Specific examples of these textile-care compounds can be found in the description of the invention Washing or cleaning agent and can also be used in the solid, Textile-care composition can be used.

The Textile-care compound is preferably a textile softening Compound and is, for example, a polysiloxane, a fabric softening Clay, a cationic polymer or a mixture of at least two of these textile-care compounds. Accordingly is the fabric care composition is preferably a fabric softening Composition.

mit
R¹ = unabhängig von einander C₁-C₃₀-Alkyl, vorzugsweise C₁-C₄-Alkyl, insbesondere Methyl oder Ethyl,
n = 1 bis 5000, vorzugsweise 10 bis 2500, insbesondere 100 bis 1500.A preferably usable polysiloxane has at least the following structural unit

With
R ¹ = independently of one another C ₁ -C ₃₀ -alkyl, preferably C ₁ -C ₄ -alkyl, in particular methyl or ethyl,
n = 1 to 5000, preferably 10 to 2500, in particular 100 to 1500.

mit
R¹ = C₁-C₃₀-Alkyl, vorzugsweise C₁-C₄-Alkyl, insbesondere Methyl oder Ethyl,
Y = ggf. substituiertes, lineares oder verzweigtes C₁-C₂₀-Alkylen, vorzugsweise -(CH₂)_m- mit m = 1 bis 16, vorzugsweise 1 bis 8, insbesondere 2 bis 4, im speziellen 3,
R², R³ = unabhängig voneinander H oder gegebenenfalls substituiertes, lineares oder verzweigtes C₁-C₃₀-Alkyl, vorzugsweise mit Aminogruppen substituiertes C₁-C₃₀-Alkyl, besonders bevorzugt -(CH₂)_b-NH₂ mit b = 1 bis 10, äußerst bevorzugt b = 2,
x = 1 bis 5000, vorzugsweise 10 bis 2500, insbesondere 100 bis 1500.It may be preferred that the polysiloxane additionally has the following structural unit:

With
R ¹ = C ₁ -C ₃₀ -alkyl, preferably C ₁ -C ₄ -alkyl, in particular methyl or ethyl,
Y = optionally substituted, linear or branched C ₁ -C ₂₀ -alkylene, preferably - (CH ₂ ) _m - where m = 1 to 16, preferably 1 to 8, in particular 2 to 4, in particular 3,
R ² , R ³ = independently of one another are H or optionally substituted, linear or branched C ₁ -C ₃₀ -alkyl, preferably C ₁ -C ₃₀ -alkyl substituted by amino groups, more preferably - (CH ₂ ) _b -NH ₂ where b = 1 to 10, most preferably b = 2,
x = 1 to 5000, preferably 10 to 2500, in particular 100 to 1500.

If the polysiloxane has only the structural unit a) with R ¹ = methyl, it is a polydimethylsiloxane. Polydimethylpolysiloxanes are known as efficient fabric care compounds.

Suitable polydimethylsiloxanes include DC-200 (ex Dow Corning), Baysilone ^® M 50, Baysilone ^® M 100, Baysilone ^® M 350, Baysilone ^® M 500, Baysilone ^® M 1000, Baysilone ^® M 1500, Baysilone ^® M 2000 or Baysilone ^® M 5000 (all ex GE Bayer Silicones).

However, it may also be preferred that the polysiloxane contains the structural units a) and b). A particularly preferred polysiloxane has the following structure: (CH _{3) 3} Si- [O-Si (CH _{3) 2]} - [O-Si (CH ₃₎ {(CH _{2) 3} -NH- (CH _{2) 2} -NH _{2}] x} OSi (CH ₃ ) ₃ where the sum n + x is a number between 2 and 10,000.

Suitable polysiloxanes having the structural units a) and b) are for example commercially available under the trade names DC2-8663, DC2-8035, DC2-8203, DC05-7022 or DC2-8566 (all ex Dow Corning). According to the invention are also suitable for example the products commercially available Dow Corning ^® 7224, Dow Corning ^® 929 Cationic Emulsion or Formasil 410 (GE Silicones).

One suitable fabric softening clay is, for example, a smectite clay. Preferred smectite clays are beidellite clays, hectorite clays, laponite clays, Montmorillonite clays, nontronite clays, saponite clays, sauconite clays and mixtures thereof. Montmorillonite clays are the preferred ones softening clays. Bentonites contain mainly Montmorillonite and may be the preferred source for to serve the textile softening clay. The bentonites can be used as a powder or crystals.

Suitable bentonites are sold for example under the names Laundrosil® ^® from Sud-Chemie or under the name Detercal by the company Laviosa. It is preferable that the textile care composition contains a powdery bentonite as a fabric care compound.

Suitable cationic polymers include in particular those described in "CTFA International Cosmetic Ingredient Dictionary", Fourth Edition, JM Nikitakis, et al, Editors, published by the Cosmetic, Toiletry, and Fragrance Association, 1991 are described and summarized under the collective name "Polyquaternium". In the following, some suitable polyquaternium compounds are listed in more detail.

POLYQUATERNIUM-1 (CAS number: 68518-54-7)

• Definition: {(HOCH ₂ CH ₂ ) ₃ N ⁺ -CH ₂ CH = CHCH ₂ - [N ⁺ (CH ₃ ) ₂ -CH ₂ CH = CHCH ₂ ] _x -N ⁺ (CH ₂ CH ₂ OH) ₃ } [ Cl ^- ] _{x + 2}

POLYQUATERNIUM-2 (CAS number: 63451-27-4)

• Definition: [-N (CH ₃ ) ₂ -CH ₂ CH ₂ CH ₂ -NH-C (O) -NH-CH ₂ CH ₂ CH ₂ -N (CH ₃ ) ₂ -CH ₂ CH ₂ OCH ₂ CH ₂ - ] ²⁺ (Cl) ₂
• For example, available as Mirapol ^® A-15 (ex Rhodia)

Polyquaternium-3

• Definition: copolymer of acrylamide and trimethylammoniumethyl methacrylate methosulfate

POLYQUATERNIUM-4 (CAS number: 92183-41-0)

• Definition: Copolymer of hydroxyethylcellulose and diallyldimethylammonium chloride
• For example, available as Celquat H 100 ^® or Celquat ^® L200 (ex National Starch)

POLYQUATERNIUM-5 (CAS number: 26006-22-4)

• Definition: Copolymer of acrylamide and β-methacrylyloxyethyltrimethylammonium methosulfate.
• For example, available as Nalco 7113 (ex Nalco) or Reten ^® 210, Reten ^® 220, Reten ^® 230, Reten ^® 240, Reten ^® 1104 Reten ^® 1105 or Reten ^® 1106 (all ex Hercules)

POLYQUATERNIUM-6 (CAS number: 26062-79-3)

• Definition: Polymer of dimethyldiallylammonium chloride
• For example, available as Merquat ^® 100 (Ondeo Nalco-)

POLYQUATERNIUM-7 (CAS number: 26590-05-6)

• Definition: Polymeric quaternary ammonium salt consisting of acrylamide and dimethyldiallylammonium chloride monomers.
• For example, available as Merquat ^® 550 or Merquat ^® S (Ondeo-Nalco)

Polyquaternium-8

Definition: Polymeric quaternary ammonium salt of methyl and stearyldimethylaminoethyl methacrylate, which was quaternized with dimethyl sulfate

Polyquaternium-9

• Definition: Polymeric quaternary ammonium salt of polydimethylaminoethyl methacrylate, which with methyl bromide was quaternized

POLYQUATERNIUM-11 (CAS number: 53633-54-8)

• Definition: Quaternary ammonium polymer formed by reaction of diethyl sulfate with the copolymer of vinylpyrrolidone and dimethylaminoethyl methacrylate. For example, available as Luviquat ^® PQ 11 PN (ex BASF), Gafquat ^® 734, Gafquat ^® 755 or Gafquat ^® 755N (ex GAF)

POLYQUATERNIUM-12 (CAS number: 68877-50-9)

• Definition: Quaternary ammonium polymer salt, which by reacting the ethyl methacrylate / a-bidyl methacrylate / diethylaminoethyl methacrylate copolymer is obtainable with dimethyl sulfate

POLYQUATERNIUM-13 (CAS number: 68877-47-4)

• Definition: polymeric quaternary ammonium salt, which by reaction of the ethyl methacrylate / oleyl methacrylate / Diethylaminoethylmethacrylat copolymer is obtainable with dimethyl sulfate

POLYQUATERNIUM-14 (CAS number: 27103-90-8)

• Definition: Polymeric quaternary ammonium salt of the formula - {- CH ₂ -C- (CH ₃ ) - [C (O) O-CH ₂ CH ₂ -N (CH ₃ ) ₃ ^- ]) _x ⁺ [CH ₃ SO ₄ ] ^- _x

POLYQUATERNIUM-15 (CAS number: 35429-19-7)

• Definition: copolymer of acrylamide and β-methacrylyloxyethyltrimethylammonium chloride

POLYQUATERNIUM-16 (CAS number: 95144-24-4)

• Definition: polymeric quaternary ammonium salt, formed from methylvinylimidazolium chloride and vinylpyrrolidone
• For example, available as Luviquat ^® FC 370, Luviquat Style ^®, Luviquat ^® FC 550 or Luviquat Excellence ^® (all ex BASF)

POLYQUATERNIUM-17 (CAS number: 90624-75-2)

• Definition: polymeric quaternary ammonium salt, which by reaction of adipic acid and dimethylaminopropylamine is obtainable with dichloroethyl ether.
• For example, available as Mirapol ^® AD-1 (ex Rhodia)

Polyquaternium-18

• Definition: polymeric quaternary ammonium salt, which by reaction of azelaic acid and dimethylaminopropylamine is obtainable with dichloroethyl ether.
• For example, available as Mirapol ^® AZ-1 (ex Rhodia)

Polyquaternium-19

• Definition: polymeric quaternary ammonium salt, which by reaction of polyvinyl alcohol with 2,3-epoxypropylamine is available.

Polyquaternium-20

• Definition: polymeric quaternary ammonium salt, which by reaction of Polyvinyloctadecylether with 2,3-epoxypropylamine is available.

POLYQUATERNIUM-21 (CAS number: 102523-94-4)

• Definition: polysiloxane / polydimethyldialkylammonium acetate copolymer
• For example, available as Abil ^® B 9905 (ex Goldschmidt-Degussa)

POLYQUATERNIUM-22 (CAS number: 53694-17-0)

• Definition: dimethyldiallylammonium chloride / acrylic acid copolymer
• For example, available as Merquat ^® 280 (Ondeo Nalco-)

POLYQUATERNIUM-24 (CAS number: 107987-23-5)

• Definition: Polymeric quaternary ammonium salt from the reaction of hydroxyethylcellulose with one with lauryldimethylammonium substituted-epoxide
• For example, available as Quatrisoft ^® Polymer LM 200 (ex Amerchol)

Polyquaternium-27

• Definition: Block copolymer from the reaction of Polyquaternium-2 with Polyquaternium-17.

POLYQUATERNIUM-28 (CAS number: 131954-48-8)

• Definition: Vinylpyrrolidone / methacrylamidopropyltrimethylammonium chloride copolymer
• Available for example as Gafquat ^® HS-100 (ex GAF)

Polyquaternium-29

• Definition: chitosan, which is reacted with propylene oxide and quaternized with epichlorohydrin

Polyquaternium-30

• Definition: Polymeric quaternary ammonium salt of the formula: - [CH ₂ C (CH ₃ ) (C (O) OCH ₃ )] _x - [CH ₂ C (CH ₃ ) (C (O) OCH ₂ CH ₂ N ⁺ (CH ₃ ) ₂ CH ₂ COO ^- )] _y -

POLYQUATERNIUM-31 (CAS number: 136505-02-7)

POLYQUATERNIUM-32 (CAS number: 35429-19-7)

• Definition: Polymer of N, N, N-trimethyl-2 - [(2-methyl-1-oxo-2-propenyl) oxy] -ethanaminium chloride with 2-propenamide

POLYQUATERNIUM-37 (CAS number: 26161-33-1)

• Definition: homopolymer of methacryloyltrimethyl chloride
• For example, available as Synthalen CR ^® (ex 3V Sigma)

POLYQUATERNIUM-44 (CAS number: 150595-70-5)

• Definition: Quaternary ammonium salt of the copolymer of vinylpyrrolidone and quaternized imidazoline
• For example, available as Luviquat ^® Ultra Care (ex BASF)

POLYQUATERNIUM-68 (CAS-Number: 827346-45-2)

• Definition: Quaternized copolymer of vinylpyrrolidone, Methacrylamide, vinylimidazole and quaternized vinylimidazole
• For example, available as Luviquat ^® Supreme (ex BASF)

It may be preferred that the textile-care composition has a Textile softening compound and one or more other textile care products Contains compound (s).

The Amount of textile-care compound in the textile-care composition is 0.1 to 15 wt .-% and preferably between 2 and 12% by weight.

One Another component of the textile-care composition is the water-soluble polymer. Suitable water-soluble Polymers preferably have a melting or softening point in the range of 48 ° C to 300 ° C and can Polyalkylene glycols, in particular polyethylene glycols, polyethylene terephthalates and / or polyvinyl alcohols. Especially preferred the water-soluble polymers have a melting or softening point ranging from 48 ° C to 120 ° C.

With Melting point is the transition from a solid state meant in a liquid (free-flowing) state. The softening temperature describes the transition from one solid state in a rubbery to viscous Melt. The melting and the softening temperature can each either a certain temperature or a smaller range be within the range of 48 ° C to 300 ° C.

Suitable polyalkylene glycols include in particular polyethylene glycols, which are liquid or solid polymers depending on the chain length. From a molecular weight of 3000, the polyethylene glycols are solid substances and are sold as flakes or powders. Hardness and melting range increase with increasing molecular weight. Preferred for the present invention are polyethylene glycols having an average molecular weight of from 3,000 to 12,000, more preferably having an average molecular weight of from 4,000 to 10,000, and most preferably having an average molecular weight of between 2,000 and 12,000 between 6,000 and 8,000.

polyethylene terephthalate is a polyester, for example, in crystalline (opaque white) as well as in amorphous (transparent) form commercially available is. The melting point of crystalline polyethylene terephthalate is about 260 ° C. Polyethylene terephthalates are thermoplastic Thermoformable plastics into almost any shape. Furthermore For example, modified polyethylene terephthalates (such as blends with other polymers or polyethylene terephthalate with built-in foreign blocks) are used.

polyvinyl alcohols are as white-yellowish powders or granules with degrees of polymerization in the range of about 500-2500 (molecular weights of about 20,000-100,000 g / mol) are commercially available. The degree of hydrolysis is from 98-99 and 87-89 mol% and thus contain the Polyvinyl alcohols still have a residual content of acetyl groups. characterized the polyvinyl alcohols are indicated by the manufacturer the degree of polymerization of the starting polymer, the degree of hydrolysis and / or saponification number. Have fully saponified polyvinyl alcohols a softening temperature of 85 ° C and a melting point from 228 ° C. The corresponding values for partially saponified (87-89%) Products are around 58 ° C (softening point) or 186 ° C (melting point) significantly lower.

The Water-soluble polymer can also be a mixture of the contained materials. However, it is preferred that the textile-care composition is a polyalkylene glycol and in particular a Polyethylene glycol as a water-soluble polymer.

One another essential ingredient of the textile-care composition is the perfume. As perfume oils or perfumes can individual fragrance compounds, eg. B. the synthetic Products of the ester, ether, aldehyde, ketone, alcohol and type Hydrocarbons are used. However, mixtures are preferred different fragrances used, which together create an appealing Create a fragrance. Such perfume oils can also contain natural fragrance mixtures, as they are made vegetable sources are accessible.

The Amount of perfume in the textile-care composition is preferably between 0.1 and 15 wt .-%, particularly preferably between 0.5 and 10 wt .-% and very particularly preferably between 1 and 7 wt .-%.

In an alternative embodiment, it may be preferable that at least part of the perfume is in encapsulated form, especially in microcapsules, used in the enclosure becomes. The microcapsules may be water-soluble and / or water-insoluble microcapsules. It can for example, melamine-urea-formaldehyde microcapsules, melamine-formaldehyde microcapsules, Urea-formaldehyde microcapsules or starch microcapsules be used.

Farther contains the textile care composition as essential Ingredient a polysaccharide. Suitable polysaccharides include for example, glycogen, starch, chitin, callose, cellulose, Dextran, tunicin, inulin, alginic acid, xanthan, gellan, Guar, locust bean gum, carrageenan, derivatives of these compounds or mixtures of these compounds and their derivatives.

It is preferred that the polysaccharide comprises cellulose or a cellulose derivative. It is particularly preferred that the polysaccharide comprises a cellulose derivative. Suitable cellulose derivatives include, for example, methylcellulose, ethylcellulose, propylcellulose, methylethylcellulose, carboxymethylcellulose, ethylcarboxymethylcellulose, hydroxyethylcellulose, hydroxypropylcellulose, carboxymethylhydroxyethylcellulose, methylhydroxypropylcellulose, methylhydroxyethylcellulose hydroxypropylmethylcellulose, ethylhydroxyethylcellulose, methylethylhydroxyethylcellulose, quaternized cellulose, quaternized cellulose derivatives, amine-modified cellulose, amine-modified cellulose derivatives or mixtures of these compounds , Suitable methylhydroxypropylcelluloses are, for example, under the names Methocel ^© J MS 40 or Methocel ^© J 5 S (both ex Dow Chemical) are available. Hydroxyethylcelluloses which can be used in the present invention include, for example Cellosize HEC QP ^© (ex Dow Chemical). Suitable methylcelluloses include, for example Methocel ^© A (ex Dow Chemical). Suitable cationic cellulose derivatives are, for example, Polyquaternium-10 compounds Celquat ^® SC-240 (ex National Starch) or UCARE ^® Polymer JR-125, UCARE ^® Polymer JR-400, UCARE ^® Polymer JR-30M UCARE ^® Polymer LR 400 UCARE ^® Polymer LR 30M and Ucare ^® Polymer SR-10 (all ex Amerchol). For example, Finnfix BDA (ex Kelco) can be used as the carboxymethylcellulose.

there it is further preferred that the cellulose and / or cellulose derivatives be used in powder form.

In the mixture is the ratio of fabric care compound to polysaccharide preferably between 15: 1 and 1: 5, more preferred between 12: 1 and 1: 1, and more preferably between 9: 1 and 4: 1.

The Textile-conditioning composition may optionally contain other ingredients contain.

Around the aesthetic impression of the textile-care composition To improve, they can be dyed with suitable dyes become. Preferred dyes whose selection the expert no difficulty prepares, should have a high storage stability and insensitivity compared to the other ingredients of the washing or detergents and against light as well as no pronounced Substantivity to textile fibers to this not to dye.

Farther the textile-care composition can be a filler, like silica, included. The amount of filler can be between 0.1 and 10 wt .-% and is preferably 1 to 5% by weight.

The fabric care composition may also contain a pearlescer to increase gloss. Examples of suitable pearlizing agents are ethylene glycol mono- and distearate (for example Cutina ^® AGS from Cognis), and PEG-3 distearate.

Farther For example, the textile-care composition can be a skin care compound include.

Under a skin care compound becomes a compound or mixture understood from compounds that upon contact of a textile with the Apply detergent to the textile and contact the textile confer skin an advantage on the skin compared to a textile, which does not interfere with the inventive washing and Cleaning agent was treated. This advantage can for example the transfer of the skin care compound from the textile to the skin, a lower water transfer from the skin to the textile or a lower friction on the skin surface through the Textile include.

• a) Wachse wie Carnauba, Spermaceti, Bienenwachs, Lanolin, Derivate davon sowie Mischungen daraus;
• b) Pflanzenextrakte, zum Beispiel pflanzliche Öle wie Avokadoöl, Olivenöl, Palmöl, Palmenkernöl, Rapsöl, Leinöl, Sojaöl, Erdnussöl, Korianderöl, Ricinusöl, Mohnöl, Kakaoöl, Kokosnussöl, Kürbiskernöl, Weizenkeimöl, Sesamöl, Sonnenblumenöl, Mandelöl, Macadamianussöl, Aprikosenkernöl, Haselnussöl, Jojobaöl oder Canolaöl, Kamille, Aloe Vera sowie Mischungen daraus;
• c) höhere Fettsäuren wie Laurinsäure, Myristinsäure, Palmitinsäure, Stearinsäure, Behensäure, Ölsäure, Linolsäure, Linolensäure, Isostearinsäure oder mehrfach ungesättigte Fettsäuren;
• d) höhere Fettalkohole wie Laurylalkohol, Cetylalkohol, Stearylalkohol, Oleylalkohol, Behenylalkohol oder 2-Hexadecanol,
• e) Ester wie Cetyloctanoat, Lauryllactat, Myristyllactat, Cetyllactat, Isopropylmyristat, Myristylmyristat, Isopropylpalmitat, Isopropyladipat, Butylstearat, Decyloleat, Cholesterolisostearat, Glycerolmonostearat, Glyceroldistearat, Glyceroltristearat, Alkyllactat, Alkylcitrat oder Alkyltartrat;
• f) Kohlenwasserstoffe wie Paraffine, Mineralöle, Squalan oder Squalen;
• g) Lipide;
• h) Vitamine wie Vitamin A, C oder E oder Vitaminalkylester;
• i) Phospholipide;
• j) Sonnenschutzmittel wie Octylmethoxylcinnamat und Butylmethoxybenzoylmethan;
• k) Silikonöle wie lineare oder cyclische Polydimethylsiloxane, Amino-, Alkyl-, Alkylaryl- oder Arylsubstituierte Silikonöle und
• l) Mischungen daraus

umfassen.The skin care composition is preferably hydrophobic, may be liquid or solid, and must be compatible with the other ingredients of the solid, fabric care composition. For example, the skin care compound

• a) waxes such as carnauba, spermaceti, beeswax, lanolin, derivatives thereof and mixtures thereof;
• b) Plant extracts, for example vegetable oils such as avocado oil, olive oil, palm oil, palm kernel oil, rapeseed oil, linseed oil, soybean oil, peanut oil, coriander oil, castor oil, poppy seed oil, cocoa oil, coconut oil, pumpkin seed oil, wheat germ oil, sesame oil, sunflower oil, almond oil, macadamia nut oil, apricot kernel oil, hazelnut oil , Jojoba oil or canola oil, chamomile, aloe vera and mixtures thereof;
• c) higher fatty acids such as lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, oleic acid, linoleic acid, linolenic acid, isostearic acid or polyunsaturated fatty acids;
• d) higher fatty alcohols, such as lauryl alcohol, cetyl alcohol, stearyl alcohol, oleyl alcohol, behenyl alcohol or 2-hexadecanol,
• e) esters such as cetyloctanoate, lauryl lactate, myristyl lactate, cetyl lactate, isopropyl myristate, myristyl myristate, isopropyl palmitate, isopropyl adipate, butyl stearate, decyl oleate, cholesterol isostearate, glycerol monostearate, glyceryl distearate, glycerol tristearate, alkyl lactate, alkyl citrate or alkyl tartrate;
• f) hydrocarbons such as paraffins, mineral oils, squalane or squalene;
• g) lipids;
• h) vitamins such as vitamins A, C or E or vitamin alkyl esters;
• i) phospholipids;
• j) sunscreens such as octyl methoxyl cinnamate and butyl methoxybenzoyl methane;
• k) silicone oils such as linear or cyclic polydimethylsiloxanes, amino-, alkyl-, alkylaryl- or aryl-substituted silicone oils and
• l) mixtures thereof

include.

The amount of skin-care compound is preferably between 0.01 and 10% by weight, preferably between 0.1 and 5% by weight and very particularly preferably between 0.3 and 3% by weight, based on the solid, textile nourishing composition. It may be that the skin care compound adds Lich also has a textile-care effect.

In order to avoid oral ingestion of the textile care composition by people, especially children, or animals, such a bittering agent such as Bitrex ^® (ex Macfarlan Smith) may contain.

These other ingredients are preferably in the enclosure introduced from the water-soluble polymer.

In In a particularly preferred embodiment, the solid, textile-care composition of a water-soluble Carrier, a water-soluble polymer, a textile caring Compound, a polysaccharide and a perfume, wherein the water-soluble carrier in particulate Form is present and at least partially an envelope the water-soluble polymer and the perfume and wherein in the wrapping a mixture of the textile care Compound and the polysaccharide is incorporated.

to Preparation of such a solid, textile-care composition First, the water-soluble polymer is melted and mixed in the molten state with the perfume. The obtained melt is so on the particulate carrier given so that it is at least partially wrapped and then into the still melted envelope a blend of the fabric care compound and the polysaccharide incorporated. The mixture is preferably complete incorporated into the envelope. But it is also an alternative possible that a lot of the mix out the textile-care compound and the polysaccharide on the surface the serving is.

In an alternative embodiment comprises the solid, textile-care Composition a water-soluble carrier, a water-soluble polymer, a textile-care compound, a polysaccharide and a perfume, wherein the water-soluble Carrier is present in particulate form and at least partially an envelope of the water-soluble Polymer and the perfume and wherein the sheath or the cladding and non-clad areas the water-soluble carrier at least partially with a mixture of the textile care compound and the Polysaccharide is / are coated.

to Preparation of such a solid, textile-care composition First, the water-soluble polymer is melted and mixed in the molten state with the perfume. The obtained melt is so on the particulate carrier given so that it is at least partially wrapped and then the wrapper or will the cladding and non-clad areas the water-soluble carrier at least partially with a mixture of the textile care compound and the Polysaccharide coated.

It is preferred in both embodiments that the particulate Carrier is completely wrapped.

It is generally preferred that the textile-care compound a Bentonite and the polysaccharide is a cellulose derivative. Especially Preferably, the cellulose derivative is an N, N, N-trialkylaminohydroxyalkyl quaternized Hydroxyethylcellulose, an N, N, N-trialkylaminohydroxyalkyl quaternized Hydroxypropyl cellulose, a carboxymethyl cellulose, a methyl hydroxypropyl cellulose, a hydroxyethyl cellulose, an N, N-dialkylaminoalkyl substituted Cellulose derivative or a methylcellulose. It is also preferable that both compounds are used in powder form.

The Textile-care composition is particularly suitable for conditioning of textile fabrics and is together with a conventional washing or cleaning agent in the (main) wash cycle a conventional washing and cleaning process with brought into contact with the textile fabrics.

The Textile nourishing composition can be used in a washing or cleaning agent be introduced.

To is a solid washing or cleaning agent with 1 to 20 wt .-%, preferably 5 to 15 wt .-%, of the invention Textile care composition mixed.

The textile-care washing or cleaning compositions according to the invention contain, in addition to the textile-care composition, surfactant (s), it being possible to use anionic, nonionic, zwitterionic and / or amphoteric surfactants. From an application point of view, preference is given to mixtures of anionic and nonionic surfactants. The total surfactant content of a detergent is preferably un below 40 wt .-% and particularly preferably below 35 wt .-%, based on the total liquid detergent.

The nonionic surfactants used are preferably alkoxylated, advantageously ethoxylated, in particular primary, alcohols having preferably 8 to 18 carbon atoms and on average 1 to 12 moles of ethylene oxide (EO) per mole of alcohol, in which the alcohol radical can be linear or preferably methyl-branched in the 2-position or linear and methyl-branched radicals in the mixture can contain, as they are usually present in Oxoalkoholresten. In particular, however, alcohol ethoxylates with linear radicals of alcohols of native origin having 12 to 18 carbon atoms, for example of coconut, palm, tallow or oleyl alcohol, and on average 2 to 8 EO per mole of alcohol are preferred. The preferred ethoxylated alcohols include, for example, C _12-14 alcohols with 3 EO, 4 EO or 7 EO, C _9-11 alcohols with 7 EO, C _13-15 alcohols with 3 EO, 5 EO, 7 EO or 8 EO, C _12-18 -alcohols with 3 EO, 5 EO or 7 EO and mixtures of these, such as mixtures of C _12-14 -alcohol with 3 EO and C _12-18 -alcohol with 7 EO. The degrees of ethoxylation given represent statistical means which, for a particular product, may be an integer or a fractional number. Preferred alcohol ethoxylates have a narrow homolog distribution (narrow range ethoxylates, NRE). In addition to these nonionic surfactants, fatty alcohols with more than 12 EO can also be used. Examples include tallow fatty alcohol with 14 EO, 25 EO, 30 EO or 40 EO. Nonionic surfactants containing EO and PO groups together in the molecule can also be used according to the invention. Here, block copolymers with EO-PO block units or PO-EO block units can be used, but also EO-PO-EO copolymers or PO-EO-PO copolymers. Of course, it is also possible to use mixed alkoxylated nonionic surfactants in which EO and PO units are not distributed in blocks, but randomly. Such products are available by the simultaneous action of ethylene and propylene oxide on fatty alcohols.

In addition, as further nonionic surfactants and alkyl glycosides of the general formula RO (G) _x can be used in which R is a primary straight-chain or methyl-branched, especially in the 2-position methyl-branched aliphatic radical having 8 to 22, preferably 12 to 18 carbon atoms and G is the symbol which represents a glycose unit having 5 or 6 C atoms, preferably glucose. The degree of oligomerization x, which indicates the distribution of monoglycosides and oligoglycosides, is any number between 1 and 10; preferably x is 1.2 to 1.4. Alkyl glycosides are known, mild surfactants.

A another class of preferred nonionic surfactants, the either as the sole nonionic surfactant or in combination with other nonionic surfactants are alkoxylated, preferably ethoxylated or ethoxylated and propoxylated fatty acid alkyl esters, preferably having 1 to 4 carbon atoms in the alkyl chain, in particular Fatty acid methyl ester.

Also nonionic surfactants of the amine oxide type, for example N-cocoalkyl-N, N-dimethylamine oxide and N-tallow alkyl-N, N-dihydroxyethylamine oxide, and the fatty acid alkanolamide may be suitable. Other suitable surfactants are polyhydroxy fatty acid amides.

Of the The content of nonionic surfactants in the washing or cleaning agents preferably 5 to 30 wt .-%, preferably 7 to 20 wt .-% and in particular 9 to 15 wt .-%, each based on the entire washing or cleaning agent.

As anionic surfactants, for example, those of the sulfonate type and sulfates are used. The surfactants of the sulfonate type are preferably C _9-13 -alkylbenzenesulfonates, olefinsulfonates, ie mixtures of alkene and hydroxyalkanesulfonates and disulfonates, as are obtained, for example, from C _12-18 -monoolefins having terminal or internal double bonds by sulfonation with gaseous sulfur trioxide and subsequent alkaline or acid hydrolysis of the sulfonation products into consideration. Also suitable are alkanesulfonates which are obtained from C _12-18 alkanes, for example by sulfochlorination or sulfoxidation with subsequent hydrolysis or neutralization. Likewise suitable are the esters of α-sulfo fatty acids (ester sulfonates), for example the α-sulfonated methyl esters of hydrogenated coconut, palm kernel or tallow fatty acids.

Further Suitable anionic surfactants are sulfated fatty acid glycerol esters. Among fatty acid glycerol esters are the mono-, di- and triesters As well as their mixtures to understand, as in the production through Esterification of a monoglycerine with 1 to 3 moles of fatty acid or in the transesterification of triglycerides with 0.3 to 2 moles of glycerol to be obtained. Preferred sulfated fatty acid glycerol esters are the sulfonation of saturated fatty acids with 6 to 22 carbon atoms, for example caproic acid, Caprylic acid, capric acid, myristic acid, Lauric acid, palmitic acid, stearic acid or behenic acid.

Alk (en) ylsulfates are the alkali metal salts and in particular the sodium salts of the sulfuric monoesters of C ₁₂ -C ₁₈ fatty alcohols, for example coconut fatty alcohol, tallow fatty alcohol, lauryl, myristyl, cetyl or stearyl alcohol or the C ₁₀ -C ₂₀ oxo alcohols and those half-esters of secondary alcohols of these chain lengths are preferred. Also preferred are alk (en) ylsulfates of said chain length, which contain a synthetic, produced on a petrochemical basis straight-chain alkyl radical, which have an analogous degradation behavior as the adequate compounds based on oleochemical raw materials. Of washing technology interest, the C ₁₂ -C ₁₆ alkyl sulfates and C ₁₂ -C ₁₅ alkyl sulfates and C ₁₄ -C ₁₅ alkyl sulfates are preferred. Also 2,3-alkyl sulfates, which can be obtained as commercial products of Shell Oil Company under the name DAN ^® , are suitable anionic surfactants.

The sulfuric acid monoesters of straight-chain or branched C _7-21 -alcohols ethoxylated with from 1 to 6 mol of ethylene oxide, such as 2-methyl-branched C _9-11- alcohols having on average 3.5 mol of ethylene oxide (EO) or C _12-18 . Fatty alcohols with 1 to 4 EO are suitable. Due to their high foaming behavior, they are only used in detergents in relatively small amounts, for example in amounts of from 1 to 5% by weight.

Further suitable anionic surfactants are also the salts of alkylsulfosuccinic acid, which are also referred to as sulfosuccinates or as sulfosuccinic acid esters and the monoesters and / or diesters of sulfosuccinic acid with alcohols, preferably fatty alcohols and in particular ethoxylated fatty alcohols. Preferred sulfosuccinates contain C _8-18 fatty alcohol residues or mixtures of these. Particularly preferred sulfosuccinates contain a fatty alcohol residue derived from ethoxylated fatty alcohols, which by themselves are nonionic surfactants. Sulfosuccinates, whose fatty alcohol residues are derived from ethoxylated fatty alcohols with a narrow homolog distribution, are again particularly preferred. Likewise, it is also possible to use alk (en) ylsuccinic acid having preferably 8 to 18 carbon atoms in the alk (en) yl chain or salts thereof.

Especially preferred anionic surfactants are soaps. Suitable are saturated and unsaturated fatty acid soaps, such as the salts lauric, myristic, palmitic, Stearic acid, (hydrogenated) erucic acid and behenic acid and in particular from natural fatty acids, for example coconut, palm kernel, olive oil or tallow fatty acids, derived soap mixtures.

The anionic surfactants including soaps can in the form of their sodium, potassium or ammonium salts and as soluble Salts of organic bases, such as mono-, di- or triethanolamine, are present. The anionic surfactants are preferably in the form of their sodium or potassium salts, especially in the form of the sodium salts.

Of the Content of preferred detergents or cleaning agents on anionic surfactants is from 2 to 30 wt .-%, preferably 4 to 25 wt .-% and in particular 5 to 22% by weight, in each case based on the total washing or detergent. It can, however, if the Textile-care composition contains a cationic polymer, be advantageous that the detergent or cleaning agent only nonionic Contains surfactants.

additionally to the fabric care composition and surfactants the washing or cleaning agents contain other ingredients, the application and / or aesthetic properties of the detergent or cleaning agent on. As part of the present invention contain preferred detergents or cleaning agents additionally one or more substances from the group of builders, Bleaching agents, bleach activators, enzymes, perfumes, perfume carriers, Fluorescers, dyes, foam inhibitors, silicone oils, Anti redeposition agents, optical brighteners, grayness inhibitors, Inlet preventer, anti-crease agents, color transfer inhibitors, antimicrobial agents, germicides, fungicides, antioxidants, Preservatives, corrosion inhibitors, antistatic agents, bittering agents, Ironing aids, repellents and impregnating agents, Swelling and anti-slip agents, neutral filler salts as well UV absorbers.

When Builders used in detergents or cleaners may be contained in particular silicates, aluminum silicates (in particular zeolites), carbonates, salts of organic di- and polycarboxylic acids and To name mixtures of these substances.

Suitable crystalline layered sodium silicates have the general formula NaMSi _x O _{2x + 1} H ₂ O, where M is sodium or hydrogen, x is a number from 1.9 to 4 and y is a number from 0 to 20 and preferred values for x 2 , 3 or 4 are. Preferred crystalline layered silicates of the formula given are those in which M is sodium and x assumes the values 2 or 3. In particular, both β- and δ-sodium disilicates Na ₂ Si ₂ O ₅ .yH ₂ O are preferred.

It is also possible to use amorphous sodium silicates with a Na ₂ O: SiO ₂ modulus of from 1: 2 to 1: 3.3, preferably from 1: 2 to 1: 2.8 and in particular from 1: 2 to 1: 2.6, which Delayed and have secondary washing properties. The dissolution delay compared with conventional amorphous sodium silicates may have been caused in various ways, for example by surface treatment, compounding, compaction / densification or by overdrying. In the context of this invention, the term "amorphous" is also understood to mean "X-ray amorphous". This means that the silicates do not yield sharp X-ray reflections typical of crystalline substances in X-ray diffraction experiments, but at most one or more maxima of the scattered X-rays which have a width of several degrees of diffraction angle. However, it may well even lead to particularly good builder properties if the silicate particles provide blurred or even sharp diffraction maxima in electron diffraction experiments. This is to be interpreted as meaning that the products have microcrystalline regions of size 10 to a few hundred nm, with values of up to a maximum of 50 nm and in particular up to a maximum of 20 nm being preferred. Particularly preferred are compacted / compacted amorphous silicates, compounded amorphous silicates and overdried X-ray amorphous silicates.

The finely crystalline, synthetic and bound water-containing zeolite used is preferably zeolite A and / or P. As zeolite P, zeolite ^MAP® (commercial product from Crosfield) is particularly preferred. Also suitable, however, are zeolite X and mixtures of A, X and / or P. Commercially available and preferably usable in the context of the present invention is, for example, a cocrystal of zeolite X and zeolite A (about 80% by weight of zeolite X) which is sold by SASOL under the brand name VEGOBOND AX ^® and by the formula), n Na ₂ O. (1-n) K ₂ O. Al ₂ O _3. (2-2.5) SiO _2. (3.5-5.5) H ₂ O n = 0.90-1.0 can be described. The zeolite can be used as a spray-dried powder or else as undried, still moist, stabilized suspension of its preparation. In the event that the zeolite is used as a suspension, it may contain minor additions of nonionic surfactants as stabilizers, for example 1 to 3 wt .-%, based on zeolite, of ethoxylated C ₁₂ -C ₁₈ fatty alcohols having 2 to 5 ethylene oxide groups , C ₁₂ -C ₁₄ fatty alcohols having 4 to 5 ethylene oxide groups or ethoxylated isotridecanols. Suitable zeolites have an average particle size of less than 10 microns (volume distribution, measuring method: Counter Counter) and preferably contain 18 to 22 wt .-%, in particular 20 to 22 wt .-% of bound water.

Of course it is also possible to use the generally known phosphates as builders, if such use is not for environmental reasons should be avoided. Particularly suitable are the sodium salts the orthophosphates, the pyrophosphates and in particular the tripolyphosphates.

organic Builders, which may be present in the washing or cleaning agent may include polycarboxylate polymers such as polyacrylates and acrylic acid / maleic acid copolymers, polyaspartates and monomeric polycarboxylates such as citrates, gluconates, succinates or Malonates, which are preferably used as sodium salts.

Among the compounds serving as bleaches in water H ₂ O ₂ , sodium perborate tetrahydrate and sodium perborate monohydrate are of particular importance. Other useful bleaching agents are, for example, sodium percarbonate, peroxypyrophosphates, citrate perhydrates and H ₂ O ₂ -producing peracidic salts or peracids, such as perbenzoates, peroxophthalates, diperazelaic acid, phthaloiminoperacid or diperdodecanedioic acid.

In order to achieve an improved bleaching effect when washing at temperatures of 60 ° C and below, bleach activators can be incorporated into the detergents or cleaners. As bleach activators, it is possible to use compounds which, under perhydrolysis conditions, give aliphatic peroxo carboxylic acids having preferably 1 to 10 C atoms, in particular 2 to 4 C atoms, and / or optionally substituted perbenzoic acid. Suitable substances are those which carry O- and / or N-acyl groups of the stated C atom number and / or optionally substituted benzoyl groups. Preference is given to polyacylated alkylenediamines, in particular tetraacetylethylenediamine (TAED), acylated triazine derivatives, in particular 1,5-diacetyl-2,4-dioxohexahydro-1,3,5-triazine (DADHT), acylated glycolurils, in particular tetraacetylglyco luril (TAGU), N-acylimides, in particular N-nonanoylsuccinimide (NOSI), acylated phenolsulfonates, in particular n-nonanoyl or isononanoyloxybenzenesulfonate (n- or iso-NOBS), carboxylic anhydrides, in particular phthalic anhydride, acylated polyhydric alcohols, in particular triacetin, ethylene glycol diacetate and 2,5-diacetoxy-2,5-dihydrofuran.

additionally to the conventional bleach activators or in their place also so-called bleach catalysts in the detergents or cleaners be incorporated. These substances are bleach-enhancing transition metal salts or transition metal complexes such as Mn, Fe, Co, Ru or Mo saline complexes or carbonyl complexes. Also Mn, Fe, Co, Ru, Mo, Ti, V and Cu complexes with nitrogen-containing Tripod ligands as well as Co, Fe, Cu and Ru ammine complexes are used as bleach catalysts usable.

The Detergents may contain enzymes in encapsulated form and / or contained directly in the washing or cleaning agent. As enzymes especially those from the classes of hydrolases such as Proteases, esterases, lipases or lipolytic enzymes, Amylases, cellulases or other glycosyl hydrolases, hemicellulase, Cutinases, β-glucanases, oxidases, peroxidases, mannanases, Perhydrolases and / or laccases and mixtures of said enzymes in question. All of these hydrolases contribute to the wash Removal of stains such as protein, fat or starchy Stains and graying at. Cellulases and other glycosyl hydrolases In addition, by removing pilling and microfibrils for maintaining color and increasing the Softness of the textile contribute. For bleaching or inhibition of Color transfer can also Oxireduktasen used become. Particularly suitable are from bacterial strains or fungi such as Bacillus subtilis, Bacqillus licheniformis, Streptomyceus Griseus and Humicola insolens obtained enzymatic agents. Preferably, subtilisin-type proteases and in particular Proteases derived from Bacillus lentus. These are enzyme mixtures, for example from protease and amylase or protease and lipase or lipolytic enzymes or Protease and cellulase or from cellulase and lipase or lipolytic acting enzymes or from protease, amylase and lipase or lipolytic acting enzymes or protease, lipase or lipolytic acting Enzymes and cellulase, but in particular protease and / or lipase-containing Mixtures or mixtures with lipolytic enzymes of special interest. Examples of such lipolytic acting enzymes are the known cutinases. Also peroxidases or Oxidases have been found to be suitable in some cases. Suitable amylases include in particular α-amylases, Iso-amylases, pullulanases and pectinases. Being cellulases preferably cellobiohydrolases, endoglucanases and β-glucosidases, which are also called cellobiases, or mixtures of these used. Because different types of cellulase are affected by their CMCase and avicelase activities by targeted mixtures of cellulases the desired Activities are discontinued.

The Enzymes may be adsorbed to carriers, to protect against premature decomposition. The amount the enzymes or the enzyme granules directly in the detergent or cleaning agent may, for example, about 0.01 to 5 wt .-%, preferably 0.12 to about 2.5 wt .-% amount.

It can, for example, special detergents or cleaners for consumers with allergies and / or sensitive skin, but also preferred that the washing or cleaning agent contains no enzymes.

In an embodiment contains the washing or Detergent optionally one or more perfumes in an amount of usually up to 10% by weight, preferably 0.5 to 7 wt .-%, in particular 1 to 3 wt .-%. Here is the amount on perfume used also on the type of washing or Cleaning agent dependent. But it is particularly preferred that the perfume on the textile-care composition in the washing or cleaning agent is introduced. It is, however also possible that the washing or cleaning agent perfume contains, which does not have the textile care Composition introduced into the detergent or cleaning agent becomes.

Around the aesthetic impression of detergents or cleaners they can (if necessary only partially) improve dyed with suitable dyes. preferred Dyes whose selection does not present any difficulty to the skilled person have a high storage stability and insensitivity to the other ingredients of detergents or cleaners and against light as well as no pronounced substantivity to textile fibers so as not to stain them.

Suitable foam inhibitors which can be used in the detergents or cleaners are, for example, soaps, paraffins or silicone oils, which may be applied to support materials could be brought.

suitable Soil-release polymers, also referred to as "anti-redeposition agents" are, for example, nonionic cellulose ethers such as methyl cellulose and methylhydroxypropylcellulose with a proportion of methoxy groups from 15 to 30% by weight and of hydroxypropyl groups from 1 to 15% by weight, in each case based on the nonionic cellulose ether and the known from the prior art polymers of phthalic acid and / or terephthalic acid or derivatives thereof, in particular Polymers of ethylene terephthalates and / or polyethylene and / or Polypropylene glycol terephthalates or anionic and / or nonionic modified derivatives of these. Suitable derivatives include the sulfonated derivatives of phthalic and terephthalic acid polymers. Another class of suitable soil-release polymers, in particular for cotton-containing textiles, make modified, for example alkoxylated and / or quaternized and / or oxidized polyamines The polyamines are, for example, polyalkyleneamines, such as polyethyleneamines, or polyalkyleneimines such as polyethyleneimines. Preferred examples For this class of soil release polymers are ethoxylated Polyethyleneimines and ethoxylated polyethyleneamines.

optical Brightener (so-called "whiteners") can be added to detergents or cleaners, for graying and yellowing of the treated textile fabrics to eliminate. These substances are absorbed by the fiber and cause a whitening and fake bleaching effect by they invisible ultraviolet radiation into visible longer wavelength Convert light, with the ultraviolet absorbed from sunlight Light is emitted as a faint bluish fluorescence and with the yellow of the grayed or yellowed linen pure white results. Suitable compounds are derived, for example from the substance classes of 4,4'-diamino-2,2'-stilbenedisulfonic acids (Flavonic acids), 4,4'-distyrylbiphenyls, methylumbelliferones, Coumarins, dihydroquinolinones, 1,3-diarylpyrazolines, naphthalimides, Benzoxazole, benzisoxazole and benzimidazole systems and the by Heterocycles substituted pyrene derivatives. The optical brightener are usually used in amounts between 0% and 0.3% by weight, based on the finished detergent or cleaning agent used.

graying have the task, the detached from the fiber dirt to keep suspended in the fleet and so the recovery of the Prevent dirt. These are water-soluble colloids mostly organic nature suitable, for example, glue, gelatin, Salts of ether sulfonic acids of starch or Cellulose or salts of acidic sulfuric acid esters of Cellulose or starch. Also water-soluble, Acidic group-containing polyamides are for this purpose suitable. Furthermore, can be soluble starch preparations and use other than the starch products mentioned above, for example degraded starch, aldehyde starches etc. Also, polyvinylpyrrolidone is useful. However, preference is given Cellulose ethers such as carboxymethyl cellulose (Na salt), methyl cellulose, Hydroxyalkylcellulose and mixed ethers such as methylhydroxyethylcellulose, Methylhydroxypropylcellulose, methylcarboxymethylcellulose and their Mixtures in amounts of from 0.1 to 5% by weight, based on the washing or detergent used.

In order to effectively suppress dye release and / or dye transfer to other fabrics during washing and / or cleaning of dyed fabrics, the washing or cleaning agent may contain a dye transfer inhibitor. It is preferred that the dye transfer inhibitor is a polymer or copolymer of cyclic amines such as vinylpyrrolidone and / or vinylimidazole. Suitable color transfer inhibiting polymers include polyvinylpyrrolidone (PVP), polyvinylimidazole (PVI), copolymers of vinylpyrrolidone and vinylimidazole (PVP / PVI), polyvinylpyridine-N-oxide, poly-N-carboxymethyl-4-vinylpyridium chloride, and mixtures thereof. Particular preference is given to using polyvinylpyrrolidone (PVP), polyvinylimidazole (PVI) or copolymers of vinylpyrrolidone and vinylimidazole (PVP / PVI) as color transfer inhibitor. The polyvinylpyrrolidone (PVP) preferably have an average molecular weight of from 2,500 to 400,000, and are commercially available from ISP Chemicals as PVP K 15, PVP K 30, PVP K 60 or PVP K 90 or from BASF as Sokalan ^® HP 50 or Sokalan ^® HP 53 available. The copolymers of vinylpyrrolidone and vinylimidazole (PVP / PVI) used preferably have a molecular weight in the range from 5,000 to 100,000. A commercially available PVP / PVI copolymer is, for example, by BASF under the name Sokalan ^® HP 56th

The Amount of color transfer inhibitor based on the total amount of the washing or cleaning agent is preferably from 0.01 to 2 Wt .-%, preferably from 0.05 to 1 wt .-%, and more preferably from 0.1 to 0.5 wt .-%.

Alternatively, however, it is also possible to use enzymatic systems comprising a peroxidase and hydrogen peroxide or a substance which produces hydrogen peroxide in water as a color transfer inhibitor. The addition of a mediator compound for the peroxidase, for example an acetosyrin gons, a phenol derivative or a phenotiazine or phenoxazine, is preferred in this case, wherein additionally the above-mentioned polymeric dye transfer inhibiting agents can be used.

There textile fabrics, in particular of rayon, rayon, Cotton and its blends may tend to wrinkle, because the individual fibers against bending, bending, pressing and squeezing transverse to the fiber direction, the washing or detergents containing synthetic crease inhibitors. These include, for example, synthetic products the base of fatty acids, fatty acid esters, fatty acid amides, Alkylolestern, -alkylolamiden or fatty alcohols, usually with Ethylene oxide reacted or products based on lecithin or modified phosphoric acid ester.

to The control of micro-organisms can or detergents contain antimicrobial agents. in this connection a distinction is made depending on the antimicrobial spectrum and mechanism of action Bacteriostats and bactericides, fungistats and fungicides, etc. Important substances from these groups are, for example, benzalkonium chlorides, Alkylarylsulfonates, halophenols and Phenolmercuriacetat, wherein in the inventive detergents or cleaners also be completely dispensed with these compounds can.

The detergents or cleaners according to the invention may contain preservatives, it being preferred to use only those which have no or only a low skin-sensitizing potential. Examples are sorbic acid and its salts, benzoic acid and its salts, salicylic acid and its salts, phenoxyethanol, 3-iodo-2-propynyl butylcarbamate, sodium N- (hydroxymethyl) glycinate, biphenyl-2-ol and mixtures thereof. A suitable preservative provides the solvent-free, aqueous combination of diazolidinyl urea, sodium benzoate and potassium sorbate (available as Euxyl K 500 ^® from Schuelke & Mayr), which can be used in a pH range up. 7

Around undesirable, by oxygen action and other oxidative Processes caused changes to the detergent or cleaning agent and / or to prevent the treated textile fabrics, The detergents or cleaners can be antioxidants contain. For example, this class of connection includes substituted phenols, hydroquinones, catechols and aromatic Amines and organic sulfides, polysulfides, dithiocarbamates, phosphites, Phosphonates and vitamin E.

One increased wearing comfort can from the additional Use of antistatic agents that results in detergents or cleansers be attached. Enlarge antistatic agents the surface conductivity and allow thus an improved drainage of formed charges. Outer Antistatic agents are usually substances with at least one hydrophilic Molecule ligands and give on the surfaces a more or less hygroscopic film. These mostly surface-active Antistatic agents can be transformed into nitrogenous (amines, amides, quaternary Ammonium compounds), phosphorus-containing (phosphoric acid esters) and sulfur-containing (alkyl sulfonates, alkyl sulfates) antistatic agents. Lauryl (or stearyl) dimethylbenzylammonium chlorides are suitable as antistatics for textile fabrics or as an additive to detergents or cleaners, in addition a softening effect is achieved.

to Improvement of the rewettability of the treated textile Fabrics and to facilitate ironing the treated fabrics can in the washing or cleaning agents, for example, silicone derivatives be used. These additionally improve the rinsing behavior the washing or cleaning agent by its foam-inhibiting Properties. Preferred silicone derivatives are, for example, polydialkyl or alkylaryl siloxanes in which the alkyl groups are one to five Have C atoms and are completely or partially fluorinated. preferred Silicones are polydimethylsiloxanes which are optionally derivatized can be and then amino-functional or quaternized or Si-OH, Si-H and / or Si-Cl bonds. The Viscosities of the preferred silicones are 25 ° C ranging between 100 and 100,000 mPas, with the silicones in Amounts between 0.2 and 5% by weight, based on the total washing or cleaning agents can be used.

After all The washing or cleaning agents can also UV absorbers included on the treated fabrics and improve the light resistance of the fibers. Compounds that have these desired properties For example, those which are effective by nonradiative deactivation Compounds and derivatives of benzophenone having substituents in 2- and / or 4-position. Furthermore, substituted benzotriazoles, in the 3-position phenyl-substituted acrylates (cinnamic acid derivatives), optionally with cyano groups in the 2-position, salicylates, organic Ni complexes as well as natural products such as umbelliferone and the body's own Urocanoic acid suitable.

Around the catalyzed by heavy metals decomposition of certain detergent ingredients To avoid substances can be used, the heavy metals complex. Suitable heavy metal complexing agents are, for example the alkali metal salts of ethylenediaminetetraacetic acid (EDTA) or nitrilotriacetic acid (NTA) and alkali metal salts of anionic polyelectrolytes such as polymaleates and polysulfonates.

A preferred class of complexing agents are the phosphonates, which in preferred detergents or cleaners in amounts of from 0.01 to 2.5 wt .-%, preferably 0.02 to 2 wt .-% and in particular of 0.03 to 1.5 wt .-% are included. To these preferred compounds in particular include organophosphonates such as 1-hydroxyethane-1,1-diphosphonic acid (HEDP), aminotri (methylenephosphonic acid) (ATMP), diethylenetriamine penta (methylenephosphonic acid) (DTPMP or DETPMP) and 2-phosphonobutane-1,2,4-tricarboxylic acid (PBS-AM), which are mostly in the form of their ammonium or alkali metal salts be used.

additionally can still neutral filler salts such as sodium sulfate or sodium carbonate in the solid detergents or cleaners be included.

The Detergents or cleaning agents according to the invention especially for cleaning and conditioning of textile fabrics are used.

to Preparation of the washing or Detergent is first the detergent or cleaning agent without the textile-care compound according to known methods, which For example, drying steps, mixing steps, compaction steps, Shaping steps and / or the subsequent addition heat-sensitive Ingredients ("post-addition"), produced. Subsequently, the product obtained is with a solid textile-care composition mixed. For the production of washing or cleaning tablets can the Mixing step further compression and / or shaping steps connect.

• * Die Cellulosederivate wurden allesamt in Pulverform eingesetzt.

Table 1 shows textile-care compositions E1 to E4 according to the invention and a composition V1 not according to the invention. Table 1: V1 E1 E2 E3 E4 Sucrose crystals (1-4 mm) 69.99 69.99 69.99 69.99 69.99 Bentonite (powder) 10 9 9 9 9 methylhydroxypropylcellulose * - 1 - - - hydroxyethyl * - - 1 - - Methylcellulose * - - - 1 - cationic - - - - 1 hydroxyethyl * Perfume 5 5 5 5 5 PEG 8000 15 15 15 15 15 Dye (blue) 0.01 0.01 0.01 0.01 0.01

• * The cellulose derivatives were all used in powder form.

to Production of the textile care products according to the invention Compositions E1 to E4 was the polyethylene glycol with a melted average molecular weight of 8,000 (PEG 8,000) and in the Melt were added to the perfume and the dye. Subsequently the colored melt was on the sucrose crystals given and the coated sucrose crystals were under Stirring with a mixture of bentonite powder and cellulose derivative powder powdered while the melt from PEG 8000, perfume and dye was not completely solidified.

The compositions E1 to E4 according to the invention showed in the freshly prepared state better flow behavior than the comparative composition V1. In addition, all of the compositions E1 to E4 and V1 had a clear, crystalline appearance when fresh.

To 4 weeks of storage at room temperature, the textile-care began Composition V1 to lose clarity. Already after 8 weeks Storage, the crystals V1 had their clear appearance completely lost and even showed a significant color change on.

On the other hand In particular, the methylhydroxypropylcellulose, methylcellulose and hydroxyethyl cellulose-containing fabric care compositions E1 to E3 after 8 weeks storage at room temperature a clear Optics and no color changes. The methylcellulose and hydroxyethyl cellulose-containing fabric care compositions E2 and E3 showed a clear, even after 12 weeks storage time, crystalline appearance and showed no color changes on. Particularly stable in terms of clarity, the proved Hydroxyethyl cellulose-containing textile-care composition E3, which still showed a clear, crystalline appearance after 24 weeks. In addition, the crystals E3 showed no after 24 weeks Color changes. The textile-care composition E4 also showed a clear after 8 weeks storage at room temperature Optics, however, could also a slight tendency to the formation of smaller Aggregates are observed.

The Textile-care compositions E1 to E4 showed a very good Dissolution behavior on contact with water and in comparison with water a softening effect with respect to it treated textile fabrics. Furthermore The textile-care compositions E1 to E4 were moist, fresh washed laundry a significantly higher fragrance intensity compared with laundry with a conventional one liquid, esterquat-containing softener treated has been.

• * Das Cellulosederivat wurde in Pulverform eingesetzt.

Table 2 shows further textile care compositions E5 to E7 according to the invention and a composition V2 not according to the invention. Table 2: V2 E5 E6 E7 Sucrose crystals (1-4 mm) 69.99 69.99 69.99 69.99 Bentonite (powder) 10 9.5 9 8th Carboxymethyl cellulose, Na salt * - 0.5 1 2 Perfume 5 5 5 5 PEG 8000 15 15 15 15 Dye (blue) 0.01 0.01 0.01 0.01

• * The cellulose derivative was used in powder form.

to Production of the textile care products according to the invention Compositions E5 to E7 was the polyethylene glycol with a melted average molecular weight of 8000 (PEG 8000) and into the melt the perfume and the dye were given. Subsequently the colored melt was on the sucrose crystals and the enveloped sucrose crystals with a Powdered mixture of bentonite powder and the cellulose derivative powder while the melt of PEG 8000, and perfume Dye was not completely solidified.

The Compositions E5 to E7 and V2 were freshly prepared Condition a clear, crystalline appearance. After 4 weeks storage at Room temperature began the textile-care composition V2 on To lose clarity. Already after 8 weeks of storage at room temperature V2 had completely lost their clear optics and showed a clear color change.

The textile care composition E5 according to the invention also showed a loss in clarity after 4 weeks of storage. However, this loss of clarity was lower than in the non-inventive textile-care composition V2. The two erfindungsge MAESSEN textile-care composition E6 and E7 were clear and color-stable even after 8 weeks of storage, while the non-inventive textile-care composition V2 had completely changed their color and lost its clarity. The Fabric care composition E5 according to the invention showed, after 8 weeks of storage, a further slight loss in clarity and a slight change in color.

• *Das Cellulosederivat wurde in Pulverform eingesetzt.

A particularly color-stable textile care composition E8 with beautiful, crystalline appearance was obtained when using diethylaminoethyl-hydroxyethylcellulose as a polysaccharide. E8 Sucrose crystals (1-4 mm) 69.99 Bentonite (powder) 9.5 Amine-substituted cellulose derivative * 0.5 Perfume 5 PEG 8000 15 Dye (blue) 0.01

• * The cellulose derivative was used in powder form.

to Production of the textile care products according to the invention Composition E8 was the polyethylene glycol with a medium Molar mass of 8000 (PEG 8000) were melted and melted given the perfume and the dye. Subsequently The colored melt was added to the sucrose crystals and the enveloped sucrose crystals with a mixture powdered from bentonite powder and the cellulose derivative powder during the melt of PEG 8000, perfume and dye not yet was completely frozen.

The fabric care composition according to the invention E8 was still crystal clear after 20 weeks storage showed no change in color.

at the preparation of the textile-care compositions E1 to E8 as well as V1 and V2 could the inventive textile-care compositions E1 to E8 at significantly higher Final product temperatures compared to the textile-care compositions V1 and V2 are bottled. In addition, in particular, showed the textile-care compositions according to the invention E1 to E3 and E5 to E8 neither in the production nor in the Storage no tendency to clump or agglomerate. The Agglomerisationsneigung in the storage of textile-care Composition E4 was low and did not work negatively on the handling and in particular on the dosing of the Textile care composition E4 off.

to Preparation of a washing or Detergent was a solid, unperfumed wash or detergent with 15 wt .-% (based on the total amount on finished washing or cleaning agent) of the textile-care Composition E3 mixed.

The Detergents or cleaning agents according to the invention showed good cleansing and conditioning properties.

Neither with separate use of textile-care compound still introduced in a washing or cleaning agent lime deposits were on the laundry and / or deposits / residues in the Einspülkammer the washing machines observed. Furthermore the solid textile care compositions retained their color and its crystalline appearance.

QUOTES INCLUDE IN THE DESCRIPTION

This list The documents listed by the applicant have been automated generated and is solely for better information recorded by the reader. The list is not part of the German Patent or utility model application. The DPMA takes over no liability for any errors or omissions.

Cited patent literature

• - WO 2007/115872 A1 [0007]

Cited non-patent literature

• "CTFA International Cosmetic Ingredient Dictionary", Fourth Edition, JM Nikitakis, et al, Editors, published by the Cosmetic, Toiletry, and Fragrance Association, 1991 [0054]

Claims (19)

Solid textile care composition comprising a water-soluble carrier, a water-soluble carrier Polymer, a textile-care compound, a polysaccharide and a perfume, wherein the water-soluble carrier is present in particulate form and at least partially a Encased from the water-soluble polymer and the perfume and a mixture of the textile caring Compound and the polysaccharide at least partially in and / or at least partially present on the wrapper. Solid textile care composition according to claim 1, characterized in that the water-soluble carrier is selected from the group consisting of inorganic Alkali metal salts, organic alkali metal salts, inorganic Alkaline earth metal salts, organic alkaline earth metal salts, organic Acids, carbohydrates, silicates, urea and mixtures it. Solid textile care composition according to claim 1 or claim 2, characterized in that the solid, textile-care Composition 50 to 99 wt .-%, preferably 75 to 95 wt .-%, on the contains water-soluble carrier. Solid textile care composition according to one of claims 1 to 3, characterized in that the Textile-care compound of textile-softening compounds, Bleaching agents, bleach activators, enzymes, silicone oils, Anti redeposition agents, optical brighteners, grayness inhibitors, Inlet preventer, anti-crease agents, color transfer inhibitors, antimicrobial agents, germicides, fungicides, antioxidants, Antistatic agents, ironing aids, repellents and impregnating agents, Swelling and slipping agents, UV absorbers and mixtures thereof is selected. Solid textile care composition according to one of claims 1 to 4, characterized in that the Textile-conditioning compound a textile-softening compound is. Solid textile care composition according to claim 5, characterized in that the textile-softening compound from polysiloxanes, textile softening clays, cationic polymers and Mixtures thereof is selected. Solid textile care composition according to one of claims 1 to 6, characterized in that the water-soluble polymer is selected from polyalkylene glycols, Polyethylene terephthalates, polyvinyl alcohols and mixtures thereof. Solid textile care composition according to one of claims 1 to 7, characterized in that the water-soluble carrier particle sizes in the range of 0.6 to 30 mm, especially 0.8 to 7 mm and especially preferably 1 to 3 mm. Solid textile care composition according to claim 1 to 8, characterized in that the polysaccharide is selected is from the group comprising glycogen, starch, chitin, Callose, cellulose, dextran, tunicin, inulin, alginic acid, Xanthan, gellan, guar, locust bean gum, carrageenan, derivatives these compounds or mixtures of these compounds and their Derivatives. Solid textile care composition according to claim 9, characterized in that the mixture as a polysaccharide cellulose or a cellulose derivative selected from the group comprising Methylcellulose, ethylcellulose, propylcellulose, methylethylcellulose, Carboxymethylcellulose, ethylcarboxymethylcellulose, hydroxyethylcellulose, Hydroxypropylcellulose, carboxymethylhydroxyethylcellulose, methylhydroxyethylcellulose Hydroxypropylmethylcellulose, ethylhydroxyethylcellulose, methylethylhydroxyethylcellulose, quaternized Cellulose, quaternized cellulose derivatives, amine-modified cellulose, Amine-modified cellulose derivatives or mixtures of these compounds includes. Solid textile care composition according to one of claims 1 to 10, characterized in that the solid, textile-care composition additional ingredients contains, preferably selected from the group consisting of dyes, fillers, pearlescing agents, skin care compounds, bitter substances and mixtures thereof. Solid textile care composition according to one of claims 1 to 11, characterized in that the Amount of perfume 0.1 to 15% by weight, preferably 1 to 10% by weight and particularly preferably 2 to 7 wt .-% is. Solid textile care composition according to one of claims 1 to 12, characterized in that the Mixture of the textile-care compound and the polysaccharide at least partially incorporated in the enclosure. Solid textile care composition according to one of claims 1 to 12, characterized in that the Serving or serving and non-shrouded Areas of the water-soluble carrier at least partly with a mixture of the textile care compound and the polysaccharide is / are coated. Use of the solid, textile-care composition according to one of claims 1 to 14 for Conditioning of textile fabrics. Process for producing a solid, textile-care A composition comprising a particulate water-soluble Carrier, a water-soluble polymer, a textile caring Compound, a polysaccharide and a perfume in which the water-soluble polymer is melted in molten Condition mixed with the perfume, the melt obtained in such a way on the particulate carrier, that this is at least partially wrapped and then in the still melted wrapping a mixture of the Textile-care compound and the polysaccharide incorporated becomes. Process for producing a solid, textile-care A composition comprising a particulate water-soluble Carrier, a water-soluble polymer, a textile caring Compound, a polysaccharide and a perfume in which the water-soluble polymer is melted in molten Condition mixed with the perfume, the melt obtained in such a way on the particulate carrier, that this is at least partially enveloped and at least partially enveloped particulate carrier with a mixture of the textile care compound and the Polysaccharide is coated. Washing or cleaning compositions comprising a solid Textile-care composition according to one of Claims 1 to 14. Use of a washing or cleaning agent according to claim 18 for cleaning and conditioning fabrics.