EP2029716B1 - Solid textile care composition based on soap - Google Patents
Solid textile care composition based on soap Download PDFInfo
- Publication number
- EP2029716B1 EP2029716B1 EP07726684.9A EP07726684A EP2029716B1 EP 2029716 B1 EP2029716 B1 EP 2029716B1 EP 07726684 A EP07726684 A EP 07726684A EP 2029716 B1 EP2029716 B1 EP 2029716B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- textile
- care composition
- solid
- fatty acids
- care
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000007787 solid Substances 0.000 title claims description 37
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- 239000011976 maleic acid Substances 0.000 description 1
- 150000002690 malonic acid derivatives Chemical class 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- BRMYZIKAHFEUFJ-UHFFFAOYSA-L mercury diacetate Chemical compound CC(=O)O[Hg]OC(C)=O BRMYZIKAHFEUFJ-UHFFFAOYSA-L 0.000 description 1
- 229940102396 methyl bromide Drugs 0.000 description 1
- 150000004702 methyl esters Chemical class 0.000 description 1
- JZMJDSHXVKJFKW-UHFFFAOYSA-M methyl sulfate(1-) Chemical compound COS([O-])(=O)=O JZMJDSHXVKJFKW-UHFFFAOYSA-M 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 210000001724 microfibril Anatomy 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 239000001788 mono and diglycerides of fatty acids Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- 229940043348 myristyl alcohol Drugs 0.000 description 1
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229940078812 myristyl myristate Drugs 0.000 description 1
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 1
- 239000005445 natural material Substances 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical class OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
- SXLLDUPXUVRMEE-UHFFFAOYSA-N nonanediperoxoic acid Chemical compound OOC(=O)CCCCCCCC(=O)OO SXLLDUPXUVRMEE-UHFFFAOYSA-N 0.000 description 1
- 229910000273 nontronite Inorganic materials 0.000 description 1
- 239000010466 nut oil Substances 0.000 description 1
- 229960002446 octanoic acid Drugs 0.000 description 1
- 238000006384 oligomerization reaction Methods 0.000 description 1
- 150000007530 organic bases Chemical class 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- 239000000312 peanut oil Substances 0.000 description 1
- 150000004965 peroxy acids Chemical class 0.000 description 1
- 229960005323 phenoxyethanol Drugs 0.000 description 1
- PATMLLNMTPIUSY-UHFFFAOYSA-N phenoxysulfonyl 7-methyloctanoate Chemical compound CC(C)CCCCCC(=O)OS(=O)(=O)OC1=CC=CC=C1 PATMLLNMTPIUSY-UHFFFAOYSA-N 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
- 150000003904 phospholipids Chemical class 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 239000005077 polysulfide Substances 0.000 description 1
- 229920001021 polysulfide Polymers 0.000 description 1
- 150000008117 polysulfides Polymers 0.000 description 1
- 235000020777 polyunsaturated fatty acids Nutrition 0.000 description 1
- 239000010491 poppyseed oil Substances 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 235000010241 potassium sorbate Nutrition 0.000 description 1
- 239000004302 potassium sorbate Substances 0.000 description 1
- 229940069338 potassium sorbate Drugs 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000001944 prunus armeniaca kernel oil Substances 0.000 description 1
- 239000008171 pumpkin seed oil Substances 0.000 description 1
- 150000003220 pyrenes Chemical class 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000011369 resultant mixture Substances 0.000 description 1
- 150000003873 salicylate salts Chemical class 0.000 description 1
- 229960004889 salicylic acid Drugs 0.000 description 1
- 229910000275 saponite Inorganic materials 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 235000003441 saturated fatty acids Nutrition 0.000 description 1
- 229910000276 sauconite Inorganic materials 0.000 description 1
- 150000003333 secondary alcohols Chemical class 0.000 description 1
- 239000008159 sesame oil Substances 0.000 description 1
- 235000011803 sesame oil Nutrition 0.000 description 1
- 231100000940 skin sensitizing potential Toxicity 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
- 229960003885 sodium benzoate Drugs 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 239000012418 sodium perborate tetrahydrate Substances 0.000 description 1
- 229940045872 sodium percarbonate Drugs 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 235000019832 sodium triphosphate Nutrition 0.000 description 1
- RPACBEVZENYWOL-XFULWGLBSA-M sodium;(2r)-2-[6-(4-chlorophenoxy)hexyl]oxirane-2-carboxylate Chemical compound [Na+].C=1C=C(Cl)C=CC=1OCCCCCC[C@]1(C(=O)[O-])CO1 RPACBEVZENYWOL-XFULWGLBSA-M 0.000 description 1
- CITBNDNUEPMTFC-UHFFFAOYSA-M sodium;2-(hydroxymethylamino)acetate Chemical compound [Na+].OCNCC([O-])=O CITBNDNUEPMTFC-UHFFFAOYSA-M 0.000 description 1
- IBDSNZLUHYKHQP-UHFFFAOYSA-N sodium;3-oxidodioxaborirane;tetrahydrate Chemical compound O.O.O.O.[Na+].[O-]B1OO1 IBDSNZLUHYKHQP-UHFFFAOYSA-N 0.000 description 1
- 239000008247 solid mixture Substances 0.000 description 1
- 239000011877 solvent mixture Substances 0.000 description 1
- 235000010199 sorbic acid Nutrition 0.000 description 1
- 239000004334 sorbic acid Substances 0.000 description 1
- 229940075582 sorbic acid Drugs 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 229940032094 squalane Drugs 0.000 description 1
- YYGNTYWPHWGJRM-AAJYLUCBSA-N squalene Chemical compound CC(C)=CCC\C(C)=C\CC\C(C)=C\CC\C=C(/C)CC\C=C(/C)CCC=C(C)C YYGNTYWPHWGJRM-AAJYLUCBSA-N 0.000 description 1
- 229940031439 squalene Drugs 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 150000003890 succinate salts Chemical class 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 150000003470 sulfuric acid monoesters Chemical class 0.000 description 1
- 239000002600 sunflower oil Substances 0.000 description 1
- 230000000475 sunscreen effect Effects 0.000 description 1
- 239000000516 sunscreening agent Substances 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 229940095064 tartrate Drugs 0.000 description 1
- BORJONZPSTVSFP-UHFFFAOYSA-N tetradecyl 2-hydroxypropanoate Chemical compound CCCCCCCCCCCCCCOC(=O)C(C)O BORJONZPSTVSFP-UHFFFAOYSA-N 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- LOIYMIARKYCTBW-OWOJBTEDSA-N trans-urocanic acid Chemical compound OC(=O)\C=C\C1=CNC=N1 LOIYMIARKYCTBW-OWOJBTEDSA-N 0.000 description 1
- LOIYMIARKYCTBW-UHFFFAOYSA-N trans-urocanic acid Natural products OC(=O)C=CC1=CNC=N1 LOIYMIARKYCTBW-UHFFFAOYSA-N 0.000 description 1
- 238000005809 transesterification reaction Methods 0.000 description 1
- 230000001131 transforming effect Effects 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 229960002622 triacetin Drugs 0.000 description 1
- 150000003626 triacylglycerols Chemical class 0.000 description 1
- 150000003918 triazines Chemical class 0.000 description 1
- 150000005691 triesters Chemical class 0.000 description 1
- USFMMZYROHDWPJ-UHFFFAOYSA-N trimethyl-[2-(2-methylprop-2-enoyloxy)ethyl]azanium Chemical compound CC(=C)C(=O)OCC[N+](C)(C)C USFMMZYROHDWPJ-UHFFFAOYSA-N 0.000 description 1
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical group CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 1
- ORHBXUUXSCNDEV-UHFFFAOYSA-N umbelliferone Chemical compound C1=CC(=O)OC2=CC(O)=CC=C21 ORHBXUUXSCNDEV-UHFFFAOYSA-N 0.000 description 1
- HFTAFOQKODTIJY-UHFFFAOYSA-N umbelliferone Natural products Cc1cc2C=CC(=O)Oc2cc1OCC=CC(C)(C)O HFTAFOQKODTIJY-UHFFFAOYSA-N 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 235000019154 vitamin C Nutrition 0.000 description 1
- 239000011718 vitamin C Substances 0.000 description 1
- 229940046009 vitamin E Drugs 0.000 description 1
- 229940045997 vitamin a Drugs 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 239000010497 wheat germ oil Substances 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
- 239000002888 zwitterionic surfactant Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/44—Perfumes; Colouring materials; Brightening agents ; Bleaching agents
- C11D9/442—Perfumes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/001—Softening compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/22—Organic compounds, e.g. vitamins
- C11D9/26—Organic compounds, e.g. vitamins containing oxygen
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/22—Organic compounds, e.g. vitamins
- C11D9/36—Organic compounds, e.g. vitamins containing silicon
Definitions
- the invention relates to a solid, textile-care composition and its use and preparation, Furthermore, the invention relates to a washing or cleaning agent containing the solid, textile-care composition.
- cationic fabric softening compounds include, for example, methyl N- (2-hydroxyethyl) -N, N-di (tallowacyloxyethyl) ammonium compounds, methyl N- ⁇ 2-hydroxyethyl) -N, N-di (tallowacyloxyethyl) ammonium compounds or N , N-dimethyl-N, N-di (talgacyloxyethyl) ammonium compounds.
- US 3,915,882 A describes a detergent comprising smectite clay coated soap particles and a quaternary ammonium compound having anti-static properties.
- the soap particles also contain a compound having dispersing properties.
- the French patent application FR 2 725 456 A1 describes a granular composition comprising a matrix of soap in which liquid surfactants or fluid silicones are dispersed.
- the matrix may contain other additives that are bases for providing alkalinity.
- Cosmetic soap bars are described from fatty acids and synthetic surfactants.
- the soap bars may contain other adjuvants such as paraffins, fatty alcohols or glycerides.
- a solid textile-care composition comprising a matrix of soap and distributed therein a textile-care compound and a perfume, wherein the soap matrix further additives selected from the group consisting of propylene glycol, dipropylene glycol, ethylene glycol, diethylene glycol, 1 , 3-Butylene glycol, 2,3-butylene glycol, sorbitol, glycerol, mannitol, glucose, sucrose, galactose, fructose, lactose, dextrose and mixtures thereof
- Such a fabric care composition can be used in the main wash of an automatic washing or cleaning process.
- the textile-care composition can be added, for example, together with the detergent or cleaning agent in the drum or the dispenser of a washing machine. This has the advantage that no additional rinse is necessary and no unsightly deposits occur in the dispenser. Furthermore, this solid composition is easier and better to handle than liquid compositions, since no drops remain on the edge of the bottle, which lead to subsequent storage of the bottle to edges on the ground or to unsightly deposits in the region of the closure. The same applies in the event that some of the composition is accidentally spilled during dosing. Since soaps also have a water-softening effect, limescale deposits on the laundry are additionally prevented
- the textile-care compound and the perfume are already transported directly to the laundry at the beginning of the washing process and so can develop their full potential.
- the fabric conditioning compound is comprised of fabric softening compounds, bleaches, bleach activators, enzymes, silicone oils, anti redeposition agents, optical brighteners, grayness inhibitors, anti-shrinkage agents, crease inhibitors, color transfer inhibitors, antimicrobials, germicides, fungicides, antioxidants, antistatic agents, ironing aides, Phobies and impregnating agents, swelling and slipping agents, UV absorbers and mixtures thereof is selected.
- the fabric care compound is a fabric softening compound. It is most preferred that the fabric softening compound is selected from polysiloxanes, fabric softening clays, cationic polymers and mixtures thereof.
- the use of polysiloxanes and / or cationic polymers as a fabric softening compound in the fabric care composition is advantageous because they not only exhibit a softening effect but also enhance the perfume impression on the linen.
- the use of softening clays as a fabric softening compound in the fabric-care composition is advantageous because they additionally have a water-softening effect and thus lime deposits on the laundry are prevented.
- the fabric care composition contains a combination of at least two textile care, especially at least two fabric softening compounds.
- the soap contains sodium salts of fatty acids selected from the group consisting of palm oil fatty acids, palm kernel oil fatty acids, coconut fatty acids, peanut fatty acids, tallow fatty acids, stearic acids, oleic acid, soybean fatty acids, olive oil fatty acids, and mixtures.
- soaps are firm and can thus function particularly well as a matrix for the solid textile-care compositions.
- Textile-care compositions with such a soap matrix dissolve particularly well and quickly. Due to the good dissolving behavior, the textile-care compound and the perfume are quickly and evenly distributed in the wash liquor and can thus optimally achieve their effect. Furthermore, the additives increase the transparency of the textile-care composition.
- the amount of the perfume is 0.1 to 20% by weight, preferably 1 to 10% by weight, and particularly preferably 2 to 7% by weight.
- the matrix of the solid, fabric care composition contains from 50% to 98% by weight, preferably from 90% to 97% by weight, of soap.
- the solid textile care composition is in particulate form. It is particularly preferred that the solid textile-care composition particle sizes in the range of 0.6 to 30 mm, in particular 0.8 to 7 mm and particularly preferably 1 to 3 mm, textile-care composition having these particle sizes are particularly dosing well and exactly.
- the invention also relates to the use of a solid textile-care composition according to the invention for conditioning textile fabrics.
- the invention further relates to a process for the preparation of a solid, textile-care composition
- a process for the preparation of a solid, textile-care composition comprising a matrix of soap and further additives selected from the group consisting of propylene glycol, dipropylene glycol, ethylene glycol, diethylene glycol, 1,3-butylene glycol, 2,3-butylene glycol, Sorbitol, glycerin, mannitol, glucose, sucrose, galactose, fructose, lactose, dextrose, and mixtures thereof, as well as a fabric conditioning compound and a perfume, in which the ingredients are mixed and the resultant mixture is then extruded through a rhombic orifice plate.
- the invention relates to a washing or cleaning agent comprising a solid, textile-care composition according to the invention.
- the consumer By introducing the textile-care composition according to the invention into a washing or cleaning agent, the consumer is provided with a textile-care washing or cleaning agent ("2in1" washing or cleaning agent) and he does not need two agents (washing or cleaning agent and Textile-care composition) to dose.
- a textile-softening composition is introduced into a washing or cleaning agent, the consumer is then provided with a fabric-softening washing or cleaning agent ("2in1" washing or cleaning agent) and does not need two detergents or cleaners Fabric softener) and no separate rinse.
- the fabric care composition contains a matrix of soap as well as a fabric care compound, perfume and other additives distributed therein.
- the matrix of soap contains as its main ingredient the sodium salts of fatty acids selected from the group consisting of palm oil fatty acids, palm kernel oil fatty acids, coconut fatty acids, peanut fatty acids, tallow fatty acids, stearic acid, oleic acid, soybean fatty acids, olive oil fatty acids and mixtures thereof.
- the matrix of the solid, textile-care composition contains preferably 50 to 98% by weight, particularly preferably 90 to 97% by weight, of soap.
- the matrix may additionally contain potassium and / or ammonium salts of fatty acids.
- the proportion of these fatty acid soaps should be as low as possible.
- the matrix of soap contains further additives selected from the group consisting of propylene glycol, dipropylene glycol, ethylene glycol, diethylene glycol, 1,3-butylene glycol, 2,3-butylene glycol, sorbitol, glycerol, mannitol, glucose, sucrose, galactose, fructose, lactose, Dextrose and mixtures thereof are selected.
- additives increase the transparency of the textile-care composition.
- the amount of these additives is preferably between 0.1 and 25 wt .-% and particularly preferably between 5 and 15 wt .-%.
- a textile care compound is understood to mean any compound which gives textile fabrics treated therewith a beneficial effect, such as, for example, a textile softening effect, crease resistance or the harmful or negative effects which result during cleaning and / or conditioning and / or or wearing, such as fading, graying, etc., reduced.
- the fabric care composition may include, for example, a fabric softening compound, bleaches, bleach activators, enzymes, silicone oils, anti redeposition agents, optical brighteners, grayness inhibitors, anti-shrinkage agents, anti-crease agents, color transfer inhibitors, antimicrobial Active ingredients, germicides, fungicides, antioxidants, antistatic agents, ironing aids, repellents and impregnating agents, swelling and anti-slip agents, UV absorbers and mixtures thereof.
- a fabric softening compound for example, a fabric softening compound, bleaches, bleach activators, enzymes, silicone oils, anti redeposition agents, optical brighteners, grayness inhibitors, anti-shrinkage agents, anti-crease agents, color transfer inhibitors, antimicrobial Active ingredients, germicides, fungicides, antioxidants, antistatic agents, ironing aids, repellents and impregnating agents, swelling and anti-slip agents, UV absorbers and mixtures thereof.
- these fabric-care compounds can be found in the description of
- the fabric conditioning compound is preferably a fabric softening compound and is, for example, a polysiloxane, a textif softening clay, a cationic polymer, or a blend of at least two of these fabric softening compounds. Accordingly, the fabric care composition is preferably a fabric softening composition.
- Polydimethylpolysiloxanes are known as efficient textile softening compounds.
- Suitable polydimethysiloxanes include DC-200 (ex Dow Corning), Baysilone® M 50, Baysilone® M 100, Baysilone® M 350, Baysilone® M 500, Baysilone® M 1000, Baysilone® M 1500, Baysilone® M 2000 or Baysilone® M 5000 (all ex GE Bayer Silicones).
- the polysiloxane contains the structural units a) and b).
- a particularly preferred polysiloxane has the following structure: (CH 3 ) 3 Si [O-Si (CH 3 ) 2 ] n - [O-Si (CH 3 ) ⁇ (CH 2 ) 3 -NH- (CH 2 ) 2 -NH 2 ⁇ ] x -OSi ( CH 3 ) 3 where the sum n + x is a number between 2 and 10,000
- Suitable polysiloxanes having the structural units a) and b) are for example commercially available under the trade names DC2-8663, DC2-8035, DC2-8203, DC05-7022 or DC2-8566 (all ex Dow Corning). According to the invention are also suitable for example the products commercially available Dow Corning ® 7224, Dow Corning ® 929 Cationic Emulsion or Formasil 410 (GE Silicones).
- a suitable fabric softening clay is, for example, a smectite clay.
- Preferred smectite clays are beidellite clays, hectorite clays, laponite clays, montmorillonite clays, nontronite clays, saponite clays, sauconite clays, and mixtures thereof.
- Montmorillonite clays are the preferred softening clays.
- Bentonites contain mainly montmorillonites and can serve as a preferred source of fabric softening clay.
- Suitable bentonites are sold, for example, under the names Laundrosil® by Süd-Chemie or under the name Detercal by Laviosa.
- the fabric care composition contains a fabric softening compound and one or more other fabric care compounds.
- the amount of fabric care compound in the fabric care composition is from 0.1 to 10 weight percent, and preferably from 1 to 6 weight percent.
- perfume oils or fragrances individual perfume compounds, for example the synthetic products of the ester type, ethers, aldehydes, ketones, alcohols and hydrocarbons can be used. Preferably, however, mixtures of different fragrances are used, which together produce an attractive fragrance.
- perfume oils may also contain natural fragrance mixtures as are available from plant sources.
- the amount of perfume in the textile-care composition amounts to preferably between 0.1 and 20 wt .-%, particularly preferably between 1 and 10 wt .-% and most preferably between 2 and 7 wt .-%.
- the textile-care composition according to the invention may optionally contain further ingredients.
- dyes In order to improve the aesthetic impression of the textile-care composition, they can be dyed with suitable dyes.
- Preferred dyes the selection of which presents no difficulty to the skilled person, have a high storage stability and insensitivity to the other ingredients of detergents or cleaning agents and to light and no pronounced substantivity to textile fibers so as not to stain them.
- the fabric care composition may contain a filler such as silica.
- the amount of filler may be between 0.1 and 10 wt .-% and is preferably 1 to 5 wt .-%.
- the textile-care composition may also contain a pearlescent mortar to increase the gloss.
- suitable pearlescing agents are ethylene glycol mono- and distearate (for example Cutina AGS from Cognis) and PEG-3-distearate.
- the matrix may be added as a further ingredient, a chelating agent, in an amount of 0.01 to 0.03 wt .-%.
- Suitable chelating agents include ethylenediamine tetraacetic acid (EDTA) or (1-hydroxyethylidene) diphosphonic acid (HEDP).
- the fabric care composition may contain a skin care compound.
- a skin-care compound is understood to mean a compound or a mixture of compounds which, upon contact of a textile with the solid, textile and / or skin-care composition, draw on the textile and, on contact of the textile with skin, confer an advantage on the skin compared with a textile which has not been treated with the textile and / or skin care composition according to the invention.
- This benefit may include, for example, the transfer of the skin care compound from the textile to the skin, less water transfer from the skin to the textile, or less friction on the skin surface through the textile.
- the textile-care composition has particle sizes in the range of 0.6 to 30 mm, in particular 0.8 to 7 mm and particularly preferably 1 to 3 mm. It is further preferred that the textile care composition is an extrudate.
- the soap (s), the textile-care compound, the perfume and, if appropriate, further ingredients are mixed, and the resulting mixture is then extruded through a rhombic perforated plate.
- the textile-care composition of the invention is particularly suitable for conditioning textile fabrics and is used together with a conventional washing or Detergent in the (main) wash of a conventional washing and cleaning process brought into contact with the fabrics.
- the fabric care composition can be incorporated into a detergent or cleanser.
- a solid detergent or cleaning agent with 0.1 to 20 wt .-%, preferably 1 to 10 wt .-%, of the textile-care composition according to the invention is mixed.
- the detergents or cleaners according to the invention contain, in addition to the textile-care composition, surfactant (s), it being possible to use anionic, nonionic, zwitterionic and / or ampholytic surfactants. From an application point of view, preference is given to mixtures of anionic and nonionic surfactants.
- the total surfactant content of a detergent is preferably below 40% by weight and more preferably below 35% by weight, based on the total detergent.
- the nonionic surfactants used are preferably alkoxylated, advantageously ethoxylated, in particular primary, alcohols having preferably 8 to 18 carbon atoms and on average 1 to 12 moles of ethylene oxide (EO) per mole of alcohol, in which the alcohol radical can be linear or preferably methyl-branched in the 2-position or linear and methyl-branched radicals in the mixture can contain, as they are usually present in Oxoalkoholresten.
- alcohol ethoxylates with linear radicals of alcohols of native origin having 12 to 18 carbon atoms, for example of coconut, palm, tallow or oleyl alcohol, and on average 2 to 8 EO per mole of alcohol are preferred.
- Preferred ethoxylated alcohols include, for example, C 12 -C 14 alcohols with 3 EO, 7 EO or 4 EO, C9-11 alcohol containing 7 EO, C 13-15 alcohols containing 3 EO, 5 EO, 7 EO or 8 EO, C 12-18 alcohols with 3 EO, 5 EO or 7 EO and mixtures of these, such as mixtures of C 12-14 -alcohol with 3 EO and C 12-16 -alcohol with 7 EO.
- the degrees of ethoxylation given represent statistical means which, for a particular product, may be an integer or a fractional number.
- Preferred alcohol ethoxylates have a narrow homolog distribution (narrow range ethoxylates, NRE).
- fatty alcohols with more than 12 EO can also be used. Examples include tallow fatty alcohol with 14 EO, 25 EO, 30 EO or 40 EO.
- Nonionic surfactants which contain EO and PO groups together in the molecule can also be used according to the invention.
- block copolymers with EO-PO block units or PO-EO block units can be used, but also EO-PO-EO copolymers or PO-EO-PO copolymers.
- mixed alkoxylated nonionic surfactants can be used in which EO and PO units are not blockwise, but are statistically distributed. Such products are available by the simultaneous action of ethylene and propylene oxide on fatty alcohols.
- nonionic surfactants and alkyl glycosides of the general formula RO (G) x can be used in which R is a primary straight-chain or methyl-branched, especially in the 2-position methyl-branched aliphatic radical having 8 to 22, preferably 12 to 18 carbon atoms and G is the symbol which represents a glycose unit having 5 or 6 C atoms, preferably glucose.
- the degree of oligomerization x which indicates the distribution of monoglycosides and oligoglycosides, is any number between 1 and 10; preferably x is 1.2 to 1.4.
- Alkyl glycosides are known, mild surfactants.
- nonionic surfactants used either as the sole nonionic surfactant or in combination with other nonionic surfactants are alkoxylated, preferably ethoxylated or ethoxylated and propoxylated fatty acid alkyl esters, preferably having from 1 to 4 carbon atoms in the alkyl chain, especially fatty acid methyl esters.
- Nonionic surfactants of the amine oxide type for example N-cocoalkyl-N, N-dimethylamine oxide and N-tallowalkyl-N, N-dihydroxyethylamine oxide, and the fatty acid alkanolamides may also be suitable.
- the amount of these nonionic surfactants is preferably not more than that of the ethoxylated fatty alcohols, especially not more than half thereof.
- polyhydroxy fatty acid amides of the formula (VII) in which RCO is an aliphatic acyl radical having 6 to 22 carbon atoms, R 1 is hydrogen, an alkyl or hydroxyalkyl radical having 1 to 4 carbon atoms and [Z] is a linear or branched polyhydroxyalkyl radical having 3 to 10 carbon atoms and 3 to 10 hydroxyl groups.
- the polyhydroxy fatty acid amides are known substances which can usually be obtained by reductive amination of a reducing sugar with ammonia, an alkylamine or an alkanolamine and subsequent acylation with a fatty acid, a fatty acid alkyl ester or a fatty acid chloride.
- the group of polyhydroxy fatty acid amides also includes compounds of the formula (VIII) in the R is a linear or branched alkyl or alkenyl radical having 7 to 12 carbon atoms, R 1 is a linear, branched or cyclic alkyl radical or an aryl radical having 2 to 8 carbon atoms and R 2 is a linear, branched or cyclic alkyl radical or an aryl radical or an oxy-alkyl radical having 1 to 8 carbon atoms, with C 1-4 -alkyl or phenyl radicals being preferred and [Z] being a linear polyhydroxyalkyl radical whose alkyl chain is substituted by at least two hydroxyl groups, or alkoxylated, preferably ethoxylated or propoxylated Derivatives of this residue.
- R is a linear or branched alkyl or alkenyl radical having 7 to 12 carbon atoms
- R 1 is a linear, branched or cyclic alkyl radical or an
- [Z] is preferably obtained by reductive amination of a sugar, for example glucose, fructose, maltose, lactose, galactose, mannose or xylose.
- a sugar for example glucose, fructose, maltose, lactose, galactose, mannose or xylose.
- the N-alkoxy- or N-aryloxy-substituted compounds can then be converted into the desired polyhydroxy fatty acid amides by reaction with fatty acid methyl esters in the presence of an alkoxide as catalyst.
- the content of nonionic surfactants in the detergents or cleaners is preferably 5 to 30 wt .-%, preferably 7 to 20 wt .-% and in particular 9 to 15 wt .-%, each based on the total detergent or cleaning agent.
- anionic surfactants for example, those of the sulfonate type and sulfates are used.
- the surfactants of the sulfonate type are preferably C 9-13 -alkylbenzenesulfonates, olefinsulfonates, ie mixtures of alkene and hydroxyalkanesulfonates and disulfonates, as are obtained, for example, from C 12-16 -monoolefins having terminal or internal double bonds by sulfonation with gaseous sulfur trioxide
- alkanesulfonates which are obtained from C 12-18 -alkanes, for example by sulfochlorination or sulfoxidation with subsequent hydrolysis or neutralization.
- esters of ⁇ -sulfo fatty acids esters of ⁇ -sulfo fatty acids (ester sulfonates), for example the ⁇ -sulfonated methyl esters of hydrogenated coconut, palm kernel or tallow
- sulfated fatty acid glycerol esters are sulfated fatty acid glycerol esters.
- fatty acid glycerol esters are the mono-. To understand di- and triesters and their mixtures as they obtained in the preparation by esterification of a monoglycerol with 1 to 3 moles of fatty acid or in the transesterification of triglycerides with 0.3 to 2 moles of glycerol.
- Preferred sulfated fatty acid glycerol esters are the sulfonation products of saturated fatty acids having 6 to 22 carbon atoms, for example caproic acid, caprylic acid, capric acid, myristic acid, lauric acid, palmitic acid, stearic acid or behenic acid.
- Alk (en) ylsulfates are the alkali metal salts and in particular the sodium salts of the sulfuric monoesters of C 12 -C 16 fatty alcohols, for example coconut fatty alcohol, tallow fatty alcohol, lauryl, myristyl, cetyl or stearyl alcohol or the C 10 -C 20 oxo alcohols and those half-esters of secondary alcohols of these chain lengths are preferred. Also preferred are alk (en) ylsulfates of said chain length, which contain a synthetic, produced on a petrochemical basis straight-chain alkyl radical, which have an analogous degradation behavior as the adequate compounds based on oleochemical raw materials.
- C 12 -C 16 alkyl sulfates and C 12 -C 15 alkyl sulfates and C 14 -C 15 alkyl sulfates are preferred.
- 2,3-alkyl sulfates, which can be obtained as commercial products of Shell Oil Company under the name DAN M are suitable anionic surfactants.
- sulfuric acid monoesters of the straight-chain or branched C 7-21 -alkahoxyls ethoxylated with 1 to 6 mol of ethylene oxide such as 2-methyl-branched C 9-11- alcohols having on average 3.5 mol of ethylene oxide (EO) or C 12-16 Fatty alcohols with 1 to 4 EO are suitable. Due to their high foaming behavior, they are only used in detergents in relatively small amounts, for example in amounts of from 1 to 5% by weight.
- Suitable anionic surfactants are also the salts of alkylsulfosuccinic acid, which are also referred to as sulfosuccinates or as sulfosuccinic acid esters and the monoesters and / or diesters of sulfosuccinic acid with alcohols, preferably fatty alcohols and in particular ethoxylated fatty alcohols.
- alcohols preferably fatty alcohols and in particular ethoxylated fatty alcohols.
- Preferred sulfosuccinates contain C 6-18 fatty alcohol residues or mixtures of these.
- Particularly preferred sulfosuccinates contain a fatty alcohol residue derived from ethoxylated fatty alcohols, which by themselves are nonionic tesides.
- Sulfosuccinates whose fatty alcohol residues are derived from ethoxylated fatty alcohols with a narrow homolog distribution, are again particularly preferred.
- alk (en) ylsuccinic acid having preferably 8 to 18 carbon atoms in the alk (en) yl chain or salts thereof.
- Particularly preferred anionic surfactants are soaps.
- Suitable are saturated and unsaturated fatty acid soaps, such as the salts of lauric acid, myristic acid, palmitic acid, stearic acid, (hydrogenated) erucic acid and behenic acid and, in particular, soap mixtures derived from natural fatty acids, for example coconut, palm kernel, olive oil or tallow fatty acids.
- the anionic surfactants may be in the form of their sodium, potassium or ammonium salts and as soluble salts of organic bases, such as mono-, di- or triethanolamine.
- the anionic surfactants are preferably present in the form of their sodium or potassium salts, in particular in the form of the sodium salts.
- the content of preferred detergents or cleaning agents to anionic surfactants is 2 to 30 wt .-%, preferably 4 to 25 wt .-% and in particular 5 to 22 wt .-%, each based on the total washing or cleaning agent.
- the detergents or cleaning agents may contain further ingredients which further improve the performance and / or aesthetic properties of the washing or cleaning agent s.
- preferred washing or cleaning agents additionally contain one or more substances from the group of builders, bleaches, bleach activators, enzymes, perfumes, perfume carriers, fluorescers, dyes, foam inhibitors, silicone oils, antiredeposition agents, optical brighteners, grayness inhibitors, anti-shrinkage agents, anti-crease agents , Color transfer inhibitors, antimicrobial agents, germicides, fungicides, antioxidants, preservatives, corrosion inhibitors, antistatic agents, bittering agents, ironing aids, repellents and impregnating agents, swelling and anti-slip agents, neutral filler salts and UV absorbers.
- Suitable builders which may be present in the detergents or cleaners are in particular silicates, aluminum silicates (in particular zeolites), carbonates, salts of organic di- and polycarboxylic acids and mixtures of these substances.
- Suitable crystalline layered sodium silicates have the general formula NaMSi x O 2x + 1 H 2 O, where M is sodium or hydrogen, x is a number from 1.9 to 4 and y is a number from 0 to 20 and preferred values for x 2 , 3 or 4 are.
- Preferred crystalline layer silicates corresponding to the above formula are those in which M is sodium and x assumes the value 2 or 3. In particular, both .beta.- and ⁇ -sodium Na 2 Si 2 O 5 ⁇ yH 2 O preferred.
- amorphous sodium silicates with a Na 2 O: SiO 2 modulus of from 1: 2 to 1: 3.3, preferably from 1: 2 to 1: 2.8 and in particular from 1: 2 to 1: 2.6, which Delayed and have secondary washing properties.
- the dissolution delay compared with conventional amorphous sodium silicates may have been caused in various ways, for example by surface treatment, compounding, compaction / densification or by overdrying.
- the term "amorphous” is also understood to mean "X-ray amorphous”.
- the silicates do not yield sharp X-ray reflections typical of crystalline substances in X-ray diffraction experiments, but at most one or more maxima of the scattered X-rays which have a width of several degrees of diffraction angle. However, it may well even lead to particularly good builder properties if the silicate particles provide blurred or even sharp diffraction maxima in electron diffraction experiments. This is to be interpreted as meaning that the products have microcrystalline regions of size 10 to a few hundred nm, with values of up to a maximum of 50 nm and in particular up to a maximum of 20 nm being preferred. Particularly preferred are compacted / compacted amorphous silicates, compounded amorphous silicates and overdried X-ray amorphous silicates.
- the finely crystalline, synthetic and bound water-containing zeolite used is preferably zeolite A and / or P.
- zeolite P zeolite MAP® (commercial product from Crosfield) is particularly preferred.
- zeolite X and mixtures of A, X and / or P are particularly preferred.
- the zeolite can be used as a spray-dried powder or else as undried, still moist, stabilized suspension of its preparation.
- the zeolite may contain minor additions of nonionic surfactants as stabilizers, for example 1 to 3 wt .-%, based on zeolite, of ethoxylated C 12 -C 18 fatty alcohols having 2 to 5 ethylene oxide groups , C 12 -C 14 -fatty alcohols having 4 to 5 ethylene oxide groups or ethoxylated isotridecanols, suitable zeolites have an average particle size of less than 10 microns (volume distribution;
- Coulter Counter and preferably contain 18 to 22 wt .-%, in particular 20 to 22 wt .-% of bound water.
- phosphates as builders are possible, unless such use should not be avoided for environmental reasons.
- Organic builders that may be present in the detergent or cleaning agent include polycarboxylate polymers such as polyacrylates and acrylic acid / maleic acid copolymers, polyaspartates and monomeric polycarboxylates such as citrates, gluconates, succinates or malonates, which are preferably used as the sodium salts.
- sodium perborate tetrahydrate and sodium perborate monohydrate are of particular importance.
- Other useful bleaching agents are, for example, sodium percarbonate, peroxypyrophosphates, citrate perhydrates and H 2 O 2 -producing peracidic salts or peracids, such as perbenzoates, peroxophthalates, diperazelaic acid, phthaloiminoperacid or diperdodecanedioic acid.
- bleach activators can be incorporated into the detergents or cleaners.
- bleach activators it is possible to use compounds which, under perhydrolysis conditions, give aliphatic peroxycarboxylic acids having preferably 1 to 10 C atoms, in particular 2 to 4 C atoms, and / or optionally substituted perbenzoic acid.
- Suitable substances are those which carry O- and / or N-acyl groups of the stated C atom number and / or optionally substituted benzoyl groups.
- polyacylated alkylenediamines in particular tetraacetylethylenediamine (TAED), acylated triazine derivatives, in particular 1,5-diacetyl-2,4-dioxohexahydro-1,3,5-triazine (DADHT), acylated glycolurils, in particular tetraacetylglycoluril (TAGU), N- Acylimides, in particular N-nonanoylsuccinimide (NOSI), acylated phenolsulfonates, in particular n-nonanoyl or isononanoyloxybenzenesulfonate (n-iso-NOBS), carboxylic anhydrides, in particular phthalic anhydride, acylated polyhydric alcohols, in particular triacetin, ethylene glycol diacetate and 2,5-diacetoxy- 2,5-dihydrofuran.
- TAED tetraacety
- bleach catalysts can be incorporated into the detergents or cleaning agents.
- bleach-enhancing transition metal salts or transition metal complexes such as Mn, Fe, Co, Ru or Mo-salene complexes or carbonyl complexes.
- Mn, Fe, Co, Ru, Mo, Ti, V and Cu complexes with nitrogen-containing tripod ligands and Co, Fe, Cu and Ru ammine complexes can also be used as bleach catalysts.
- the washing or cleaning agent may contain enzymes in encapsulated form and / or directly in the washing or cleaning agent.
- Suitable enzymes include in particular those from the classes of hydrolases such as proteases, esterases, lipases or lipolytic enzymes, amylases, cellulases or other glycosyl hydrolases, hemicellulases, cutinases, ⁇ -glucanases, oxidases, peroxidases, perhydrolases, mannanases and / or laccases and mixtures of said enzymes in question. All of these hydrolases in the wash contribute to the removal of stains such as proteinaceous, greasy or starchy stains and graying.
- cellulases and other glycosyl hydrolases may contribute to color retention and to enhancing the softness of the fabric by removing pilling and microfibrils.
- Oxireductases can also be used for bleaching or inhibiting color transfer.
- Particularly suitable are enzymatic agents obtained from bacterial strains or fungi such as Bacillus subtilis, Bacillus licheniformis, Streptomyces griseus and Humicola insolens.
- subtilisin-type proteases and in particular proteases derived from Bacillus lentus are used.
- enzyme mixtures for example from protease and amylase or protease and lipase or lipolytic enzymes or protease and cellulase or from cellulase and lipase or lipolytic enzymes or from protease, amylase and lipase or lipolytic enzymes or protease, lipase or lipolytic enzymes and cellulase, but in particular protease and / or lipase-containing mixtures or mixtures with lipolytic enzymes of particular interest.
- lipolytic enzymes are the known cutinases. Peroxidases or oxidases have also proved suitable in some cases.
- ⁇ -amylases In particular, ⁇ -amylases, iso-amylases, pullulanases and pectinases pay particular attention to the suitable amylases.
- Cellulases used are preferably cellobiohydrolases, endoglucanases and ⁇ -glucosidases, which are also called cellobiases, or mixtures thereof. Since different types of cellulases differ in their CMCase and avicelase activities, targeted mixtures of the cellulases can set the desired activities become.
- the enzymes may be adsorbed to carriers to protect against premature degradation.
- the proportion of enzymes or enzyme granules directly in the washing or cleaning agent may for example be about 0.01 to 5 wt .-%, preferably 0.12 to about 2.5 wt .-% amount.
- washing or cleaning agent contains no enzymes.
- the washing or cleaning agent optionally contains one or more perfumes in an amount of usually up to 10 wt .-%, preferably 0.5 to 7 wt .-%, in particular 1 to 3 wt .-%.
- the amount of perfume used is also dependent on the type of detergent or cleaning agent. However, it is particularly preferred that the perfume is introduced into the washing or cleaning agent via the textile softening composition. However, it is also possible for the washing or cleaning agent to contain perfume which is not introduced into the washing or cleaning agent above the textile softening composition.
- the detergents or cleaners may (optionally only partially) be colored with suitable dyes.
- Preferred dyes the selection of which presents no difficulty to the skilled person, have a high storage stability and insensitivity to the other ingredients of detergents or cleaning agents and to light and no pronounced substantivity to textile fibers so as not to stain them.
- Suitable foam inhibitors which can be used in the detergents or cleaners are, for example, soaps, paraffins or silicone oils, which may optionally be applied to support materials.
- Suitable soil release polymers also referred to as "anti-redeposition agents” include, for example, nonionic cellulose ethers such as methyl cellulose and methyl hydroxypropyl cellulose having a methoxy group content of 15 to 30% by weight and hydroxypropyl groups of 1 to 15% by weight, respectively based on the nonionic cellulose ether and the known from the prior art polymers of phthalic acid and / or terephthalic acid or derivatives thereof, in particular polymers of ethylene terephthalates and / or polyethylene and / or polypropylene glycol terephthalates or anionic and / or nonionic modified derivatives thereof.
- nonionic cellulose ethers such as methyl cellulose and methyl hydroxypropyl cellulose having a methoxy group content of 15 to 30% by weight and hydroxypropyl groups of 1 to 15% by weight, respectively based on the nonionic cellulose ether and the known from the prior art polymers of phthalic acid and / or terephthalic
- Suitable derivatives include the sulfonated derivatives of the phthalic and terephthalic acid polymers.
- Another class of suitable soil-release polymers, in particular for cotton-containing textiles, are modified, for example alkoxylated and / or quaternized and / or oxidized, polyamines.
- the polyamines are, for example, polyalkyleneamines, such as polyethyleneamines, or polyalkylenimines, such as polyethylenimines, Preferred examples of this class of soil release polymers are ethoxylated polyethylenimines and ethoxylated polyethyleneamines.
- Optical brighteners can be added to the detergents or cleaners to eliminate graying and yellowing of the treated textile fabrics. These fabrics impinge on the fiber and cause whitening and bleaching by transforming invisible ultraviolet radiation into visible longer wavelength light, emitting the ultraviolet light absorbed from the sunlight as faint bluish fluorescence, and pure with the yellowness of the grayed or yellowed wash White results.
- Suitable compounds are derived, for example, from the substance classes of 4,4'-diamino-2,2'-stilbenedisultonic acids (flavonic acids), 4,4'-distyrylbiphenyls, methylumbelliferones, coumarins, dihydroquinolinones, 1,3-diarylpyrazolines, naphthalic acid imides, benzoxazole , Benzisoxazole and benzimidazole systems as well as heterocyclic substituted pyrene derivatives.
- the optical brighteners are usually used in amounts of from 0 to 0.3% by weight, based on the finished detergent or cleaning agent.
- Graying inhibitors have the task of keeping suspended from the fiber debris suspended in the fleet and so prevent the Nederaufutz the dirt.
- Water-soluble colloids of mostly organic nature are suitable for this purpose, for example glue, gelatine, salts of ether sulfonic acids or cellulose or salts of acidic sulfuric acid esters of cellulose or starch.
- water-soluble polyamides containing acidic groups are suitable for this purpose. It is also possible to use soluble starch preparations and starch products other than those mentioned above, for example degraded starch, aldehyde starches, etc. Polyvinylpyrrolidone is also useful.
- cellulose ethers such as carboxymethylcellulose (Na salt), methylcellulose, hydroxyalkylcellulose and mixed ethers such as methylhydroxyethylcellulose, methylhydroxypropylcellulose, methylcarboxymethylcellulose and mixtures thereof in amounts of from 0.1 to 5% by weight, based on the washing or cleaning agents.
- the washing or cleaning agent may contain a dye transfer inhibitor.
- the dye transfer inhibitor is a polymer or copolymer of cyclic amines such as Vinylpyrrolidone and / or vinylimidazole is.
- Suitable color transfer inhibiting polymers include polyvinylpyrrolidone (PVP), polyvinylimidazole (PVI), copolymers of vinylpyrrolidone and vinylimidazole (PVP / PVI), polyvinylpyridine-N-oxide, poly-N-carboxymethyl-4-vinylpyridium chloride, and mixtures thereof.
- polyvinylpyrrolidone PVP
- polyvinylimidazole PVI
- copolymers of vinylpyrrolidone and vinylimidazole PVP / PVI
- the polyvinylpyrrolidones (PVP) used preferably have an average molecular weight of 2,500 to 400,000 and are commercially available from ISP Chemicals as PVP K 15, PVP K 30, PVP K 60 or PVP K 90 or from BASF as Sokalan® HP 50 or Sokalan® HP 53 available.
- the copolymers of vinylpyrrolidone and vinylimidazole (PVP / PVI) used preferably have a molecular weight in the range from 5,000 to 100,000.
- a PVP / PVI copolymer for example from BASF under the name Sokalan® HP 56th
- the amount of dye transfer inhibitor based on the total amount of the detergent is preferably from 0.01 to 2% by weight, preferably from 0.05 to 1% by weight, and more preferably from 0.1 to 0.5% by weight. -%.
- enzymatic systems comprising a peroxidase and hydrogen peroxide or a substance which produces hydrogen peroxide in water as a color transfer inhibitor.
- a mediator compound for the peroxidase for example an acetosyringone, a phenol derivative or a phenotiazine or phenoxazine, is preferred in this case, whereby the abovementioned polymeric color transfer inhibitors may additionally be used.
- the detergents or cleaning agents may contain synthetic crease inhibitors. These include, for example, synthetic products based on fatty acids, fatty acid esters, fatty acid amides, alkylol esters, -alkylolamides or fatty alcohols, which are usually reacted with ethylene oxide, or products based on lecithin or modified phosphoric acid ester.
- washing or cleaning agents may contain antimicrobial agents.
- antimicrobial agents Depending on the antimicrobial spectrum and mechanism of action, a distinction is made between bacteriostats and bactericides, fungistatics and fungicides, etc.
- Important substances from these groups are, for example, benzalkonium chlorides, alkylarylsulfonates, halophenols and phenol mercuriacetate, it also being possible entirely to dispense with these compounds in the detergents or cleaners according to the invention.
- the detergents or cleaners according to the invention may contain preservatives, it being preferred to use only those which have no or only a low skin-sensitizing potential.
- preservatives examples are sorbic acid and its salts, benzoic acid and its salts, salicylic acid and its salts, phenoxyethanol, 3-iodo-2-propynyl butylcarbamate, sodium N- (hydroxymethyl) glycinate, biphenyl-2-ol and mixtures thereof.
- a suitable preservative is the solvent mixture, aqueous combination of diazolidinyl urea, sodium benzoate and potassium sorbate (available as Euxyl® K 500 ex Schuelke & Mayr), which can be used in a pH range up to 7.
- the detergents or cleaners may contain antioxidants.
- Class of compounds include, for example, substituted phenols, hydroquinones, catechols and aromatic amines, as well as organic sulfides, polysulfides, dithiocarbamates, phosphites, phosphonates and vitamin E.
- Antistatic agents increase the surface conductivity and thus enable an improved outflow of formed charges.
- External antistatic agents are generally substances with at least one hydrophilic molecule ligand and give a more or less hygroscopic film on the surfaces. These mostly surface-active antistatic agents can be subdivided into nitrogen-containing (amines, amides, quaternary ammonium compounds), phosphorus-containing (phosphoric acid esters) and sulfur-containing (alkyl sulfonates, alkyl sulfates) antistatic agents.
- Lauryl (or, stearyl) dimethylbenzylammonium chlorides are suitable as antistatic agents for textile fabrics or as an additive to laundry detergents or cleaners, wherein additionally a softening effect is achieved.
- silicone derivatives can be used in the detergents or cleaners. These additionally improve the rinsing out of the washing or cleaning agents by their foam-inhibiting
- Preferred silicone derivatives are, for example, polydialkyl or alkylaryl siloxanes in which the alkyl groups have one to five carbon atoms and are completely or partially fluorinated.
- Preferred silicones are polydimethylsiloxanes, which may optionally be derivatized and are then amino-functional or quaternized or have Si-OH, Si-H and / or Si-Cl bonds.
- the viscosities of the preferred silicones are in the range between 100 and 100,000 mPas at 25 ° C., wherein the silicones can be used in amounts of between 0.2 and 5% by weight, based on the total detergent or cleaning agent.
- the detergents or cleaners may also contain UV absorbers which are applied to the treated fabrics and improve the light fastness of the fibers.
- Compounds having these desired properties include, for example, the non-radiative deactivating compounds and derivatives of benzophenone having substituents in the 2- and / or 4-position. Also suitable are substituted benzotriazoles, phenyl-substituted acrylates (cinnamic acid derivatives) in the 3-position, optionally with cyano groups in the 2-position, salicylates, organic Ni complexes and natural substances such as umbelliferone and the body's own urocanic acid.
- Suitable heavy metal complexing agents are, for example, the alkali metal salts of ethylenediaminetetraacetic acid (EDTA) or nitrilotriacetic acid (NTA) and alkali metal salts of anionic polyelectrolytes such as polymaleates and polysulfonates.
- EDTA ethylenediaminetetraacetic acid
- NTA nitrilotriacetic acid
- anionic polyelectrolytes such as polymaleates and polysulfonates.
- a preferred class of complexing agents are the phosphonates, which in preferred detergents or cleaners in amounts of 0.01 to 2.5 wt .-%, preferably 0.02 to 2 wt .-% and in particular from 0.03 to 1, 5 wt .-% are included.
- These preferred compounds include in particular organophosphonates such as 1-hydroxyethane-1,1-diphosphonic acid (HEDP), aminotri (methylenephosphonic acid) (ATMP), diethylenetriamine penta (methylenephosphonic acid) (DTPMP or DETPMP) and 2-phosphonobutane-1,2 , 4-tricarboxylic acid (PBS-AM), which are used mostly in the form of their ammonium or alkali metal salts.
- organophosphonates such as 1-hydroxyethane-1,1-diphosphonic acid (HEDP), aminotri (methylenephosphonic acid) (ATMP), diethylenetriamine penta (methylenephosphonic acid) (DTPMP or DETPMP) and 2-phosphonobutan
- neutral fillers such as sodium sulfate or sodium bicarbonate may be included in the solid detergent or cleaner.
- washing or cleaning agents according to the invention can be used in particular for cleaning and conditioning textile fabrics.
- the washing or cleaning agent without the textile-care compound is first prepared by known processes, which may include, for example, topping steps, mixing steps, densification steps, shaping steps and / or the subsequent addition of heat-sensitive ingredients ("post-addition") , produced. Subsequently, the resulting product is mixed with a solid, textile-care composition according to the invention.
- the mixing step may be followed by further compaction and / or shaping steps.
- Table 1 shows textile care compositions E2 to E5 according to the invention.
- Table 1 E1 * E2 E3 E4 E5 Palm oil fatty acid soaps 96.99 88.99 81.99 80,99 88.99 glycerin - 7 8th 7 7 sorbitol - 1 1 1 1 1 bentonite - - 5 - - silica - - 2 - - Perfume 2 2 2 5 2 polydimethylsiloxane 1 1 - 6 - Polyquaternium-7 - - - - 1 dye 0.01 0.01 0.01 0.01 0.01 * not according to the invention
- the textile-care compositions according to the invention exhibited a softening effect in comparison with water (the fabrics treated with water or textile-care composition were tapped after treatment and hanging drying from a panel consisting of 5 persons).
- the fabric care compositions of the present invention are capable of reducing the hardness of water.
- the hardness of tap water was determined by means of analysis sticks "total hardness test" (Merck) according to the manufacturer's instructions.
- the tap water was then added to the solid textile care composition E2 according to the invention in a concentration as specified in the manufacturer's instructions, and the hardness of the water was determined.
- the water hardness was reduced from 16 ° dH to 3 ° dH.
- a solid, unscented washing or cleaning agent was mixed with 10% by weight (based on the total amount of finished washing or cleaning agent) of the textile-care composition E2 .
- the washing or cleaning agent according to the invention showed good cleaning and conditioning properties.
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Description
Die Erfindung betrifft eine feste, Textil-pflegende Zusammensetzung sowie deren Verwendung und Herstellung, Desweiteren betrifft die Erfindung ein Wasch- oder Reinigungsmittel, das die feste, Textil-pflegende Zusammensetzung enthält.The invention relates to a solid, textile-care composition and its use and preparation, Furthermore, the invention relates to a washing or cleaning agent containing the solid, textile-care composition.
Durch wiederholtes Waschen werden Textilien oft hart und verlieren ihre Weichheit. Um Textilien ihre Weichheit/Flexibilität wiederzugeben, um ihnen einen angenehmen Duft zu verleihen und/oder um ihre antistatischen Eigenschaften zu verbessern, werden die Textilien nach dem eigentlichen Wasch- und Reinigungsprozess in einem anschließenden Spülprozess mit einem Weichspüler behandelt:Repeated washing often causes textiles to harden and lose their softness. To give textiles their softness / flexibility, to give them a pleasant scent and / or to improve their antistatic properties, the textiles are treated after the actual washing and cleaning process in a subsequent rinsing process with a fabric softener:
Die meisten, im Markt befindlichen Weichspüler sind wässrige Formulierungen, die als Hauptwirkungsbestandteil eine kationische Textil-weichmachende Verbindung, die eine oder zwei langkettige Alkylgruppen in einem Molekül aufweisen, enthalten. Weitverbreitete kationische Textilweichmachende Verbindungen umfassen beispielsweise Methyl-N-(2-hydroxyethyl)-N,N-di(talgacyloxyethyl)ammonium-Verbindungen, Methyl-N-{2-hydroxyethyl)-N,N-di(talgacyloxyethyl)-ammoniumverbindungen oder N,N-Dimethyl-N,N-di(talgacyloxyethyl)ammonium-Verbindungen.Most fabric softeners on the market are aqueous formulations containing as the main active ingredient a cationic fabric softening compound having one or two long-chain alkyl groups in one molecule. Commonly used cationic fabric softening compounds include, for example, methyl N- (2-hydroxyethyl) -N, N-di (tallowacyloxyethyl) ammonium compounds, methyl N- {2-hydroxyethyl) -N, N-di (tallowacyloxyethyl) ammonium compounds or N , N-dimethyl-N, N-di (talgacyloxyethyl) ammonium compounds.
Diese herkömmlichen Weichspülerformulierungen können wegen der kationischen, Textil-weichmachenden Verbindungen nicht gleichzeitig mit dem Wasch- oder Reinigungsmittel im eigentlichen Wasch- oder Reinigungsprozess verwendet werden, da die kationischen Textil-weichmachenden Verbindungen mit den anionischen Tensiden der Wasch- oder Reinigungsmittel unerwünscht wechselwirken. Deshalb ist ein zusätzlicher Spülvorgang notwendig, der aber zeit- und energieintensiv ist.These conventional softener formulations can not be used concurrently with the detergent or cleaning agent in the actual washing or cleaning process because of the cationic fabric softening compounds because the cationic fabric softening compounds undesirably interact with the anionic surfactants of the detergents or cleaners. Therefore, an additional flushing process is necessary, but which is time and energy intensive.
Ein weiterer Nachteil ist, dass herkömmliche Weichspüler nicht die Ablagerung von Kalkrückständen während des Spülvorgangs auf der Wäsche verhindern. Zusätzlich hinterlassen die herkömmlichen Weichspüler oft unschöne Ablagerung in der Einspülkammer der Waschmaschine.Another disadvantage is that conventional softeners do not prevent the deposition of limescale during the rinse on the laundry. In addition, the conventional softener often leave unsightly deposit in the Einspülkammer the washing machine.
Auch bei anderen Textil-pflegenden Verbindungen können Probleme auftreten, die beispielsweise eine separate Dosierung und/oder einen separaten Spülgang erforderlich machen.Even with other textile-care compounds, problems may arise that require, for example, a separate dosage and / or a separate rinse.
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Es ist Aufgabe der vorliegenden Erfindung, eine Textil-pflegende Zusammensetzung bereitzustellen, die im Hauptwaschgang zusammen mit Wasch- oder Reinigungsmitteln eingesetzt werden kann.It is an object of the present invention to provide a fabric care composition which can be used in the main wash together with detergents or cleaners.
Diese Aufgabe wird gelöst durch eine feste, Textil-pflegende Zusammensetzung, umfassend eine Matrix aus Seife sowie darin verteilt eine Textil-pflegende Verbindung und ein Parfüm, wobei die Seifenmatrix weitere Zusätze ausgewählt aus der Gruppe bestehend aus Propylenglykol, Dipropylenglykol, Ethylenglykol, Diethylenglykol, 1,3-Butylenglykol, 2,3-Butylenglykol, Sorbit, Glycerin, Mannit, Glucose, Saccharose, Galactose, Fructose, Lactose, Dextrose und Mischungen daraus enthältThis object is achieved by a solid textile-care composition comprising a matrix of soap and distributed therein a textile-care compound and a perfume, wherein the soap matrix further additives selected from the group consisting of propylene glycol, dipropylene glycol, ethylene glycol, diethylene glycol, 1 , 3-Butylene glycol, 2,3-butylene glycol, sorbitol, glycerol, mannitol, glucose, sucrose, galactose, fructose, lactose, dextrose and mixtures thereof
Eine solche Textil-pflegende Zusammensetzung kann im Hauptwaschgang eines automatischen Wasch- oder Reinigungsverfahrens eingesetzt werden. Die Textil-pflegende Zusammensetzung kann beispielsweise zusammen mit dem Wasch- oder Reinigungsmittel in die Trommel oder die Einspülkammer einer Waschmaschine gegeben werden. Dies hat den Vorteil, dass kein zusätzlicher Spülgang notwendig ist und keine unschönen Ablagerungen in der Einspülkammer auftreten. Weiterhin ist diese feste Zusammensetzung einfacher und besser zu handhaben als flüssige Zusammensetzungen, da keine Tropfen am Flaschenrand zurückbleiben, die bei der anschließenden Lagerung der Flasche zu Rändern auf dem Untergrund oder zu unschönen Ablagerungen im Bereich des Verschlusses führen. Dasselbe gilt für den Fall, dass bei der Dosierung etwas von der Zusammensetzung versehentlich verschüttet wird. Da Seifen auch einen Wasser-enthärtenden Effekt aufweisen, werden zusätzlich Kalkablagerungen auf der Wäsche verhindertSuch a fabric care composition can be used in the main wash of an automatic washing or cleaning process. The textile-care composition can be added, for example, together with the detergent or cleaning agent in the drum or the dispenser of a washing machine. This has the advantage that no additional rinse is necessary and no unsightly deposits occur in the dispenser. Furthermore, this solid composition is easier and better to handle than liquid compositions, since no drops remain on the edge of the bottle, which lead to subsequent storage of the bottle to edges on the ground or to unsightly deposits in the region of the closure. The same applies in the event that some of the composition is accidentally spilled during dosing. Since soaps also have a water-softening effect, limescale deposits on the laundry are additionally prevented
Weiterhin ist vorteilhaft, dass die Textil-pflegende Verbindung und das Parfüm bereits direkt zu Beginn des Waschverfahrens zur Wäsche transportiert werden und so ihr volles Potential entfalten können.Furthermore, it is advantageous that the textile-care compound and the perfume are already transported directly to the laundry at the beginning of the washing process and so can develop their full potential.
Es ist bevorzugt, dass die Textil-pflegende Verbindung aus Textil-weichmachenden Verbindungen, Bleichmitteln, Bleichaktivatoren, Enzymen, Silikonölen, Antiredepositionsmittel, optischen Aufheller, Vergrauungsinhibitoren, Einlaufverhinderer, Knitterschutzmittel, Farbübertragungsinhibitoren, antimikrobiellen Wirkstoffen, Germiziden, Fungiziden, Antioxidantien, Antistatika, Bügelhilfsmitteln, Phobier- und Imprägniermitteln, Quell- und Schiebefestmitteln, UV-Absorber sowie Mischungen daraus ausgewählt ist.It is preferred that the fabric conditioning compound is comprised of fabric softening compounds, bleaches, bleach activators, enzymes, silicone oils, anti redeposition agents, optical brighteners, grayness inhibitors, anti-shrinkage agents, crease inhibitors, color transfer inhibitors, antimicrobials, germicides, fungicides, antioxidants, antistatic agents, ironing aides, Phobies and impregnating agents, swelling and slipping agents, UV absorbers and mixtures thereof is selected.
Es ist insbesondere bevorzugt, dass die Textil-pflegende Verbindung eine Textil-weichmachende Verbindung ist. Dabei ist ganz besonders bevorzugt, dass die Textil-weichmachende Verbindung aus Polysiloxanen, Textil-weichmachenden Tonen, kationischen Polymeren und Mischungen daraus ausgewählt ist.It is particularly preferred that the fabric care compound is a fabric softening compound. It is most preferred that the fabric softening compound is selected from polysiloxanes, fabric softening clays, cationic polymers and mixtures thereof.
Die Verwendung von Polysiloxanen und/oder kationischen Polymeren als Textil-weichmachende Verbindung in der Textil-pflegenden Zusammensetzung ist vorteilhaft, da diese nicht nur einen weichmachenden Effekt zeigen, sondern auch den Parfümeindruck auf der Wäsche verstärken. Die Verwendung von weichmachenden Tonen als Textil-weichmachende Verbindung in der Textil-pflegenden Zusammensetzung ist vorteilhaft, da diese zusätzlich einen Wasser-enthärtenden Effekt aufweisen und so Kalkablagerungen auf der Wäsche verhindert werden. Um eine optimale Leistung zu erzielen, kann es bevorzugt sein, dass die Textil-pflegende Zusammensetzung eine Kombination von wenigstens zwei Textil-pflegenden, insbesondere wenigstens zwei Textil-weichmachenden, Verbindungen enthält.The use of polysiloxanes and / or cationic polymers as a fabric softening compound in the fabric care composition is advantageous because they not only exhibit a softening effect but also enhance the perfume impression on the linen. The use of softening clays as a fabric softening compound in the fabric-care composition is advantageous because they additionally have a water-softening effect and thus lime deposits on the laundry are prevented. In order to achieve optimum performance, it may be preferred that the fabric care composition contains a combination of at least two textile care, especially at least two fabric softening compounds.
In einer bevorzugten Ausführungsform enthält die Seife Natriumsalze von Fettsäuren ausgewählt aus der Gruppe bestehend aus Palmölfettsäuren, Palmkernölfettsäuren, Kokosfettsauren, Erdnussfettsäuren, Talgfettsäuren, Stearinsäuren, Ölsäure, Sojafettsäuren, Olivenölfettsäuren und Mischungen enthält.In a preferred embodiment, the soap contains sodium salts of fatty acids selected from the group consisting of palm oil fatty acids, palm kernel oil fatty acids, coconut fatty acids, peanut fatty acids, tallow fatty acids, stearic acids, oleic acid, soybean fatty acids, olive oil fatty acids, and mixtures.
Diese Seifen sind fest und können so besonders gut als Matrix für die festen Textil-pflegenden Zusammensetzungen fungieren.These soaps are firm and can thus function particularly well as a matrix for the solid textile-care compositions.
Textil-pflegende Zusammensetzungen mit einer solchen Seifenmatrix lösen sich besonders gut und schnell auf. Durch das gute Auflöseverhalten werden die Textil-pflegende Verbindung und das Parfüm schnell und gleichmäßig in der Waschflotte verteilt und können so optimal ihre Wirkung erzielen. Weiterhin erhöhen die Zusätze die Transparenz der Textil-pflegenden Zusammensetzung.Textile-care compositions with such a soap matrix dissolve particularly well and quickly. Due to the good dissolving behavior, the textile-care compound and the perfume are quickly and evenly distributed in the wash liquor and can thus optimally achieve their effect. Furthermore, the additives increase the transparency of the textile-care composition.
Es ist bevorzugt, dass die Menge an Parfüm 0,1 bis 20 Gew.-%, bevorzugt 1 bis 10 Gew.-% und insbesondere bevorzugt 2 bis 7 Gew.-% beträgt.It is preferable that the amount of the perfume is 0.1 to 20% by weight, preferably 1 to 10% by weight, and particularly preferably 2 to 7% by weight.
Bei herkömmlichen flüssigen Weichspülerzusammensetzungen mit quaternären Ammoniumverbindungen als Textil-pflegende Verbindung tritt bei höheren Parfümkonzentration (> 0,4 Gew.-% Parfüm bei regulären Weichspülerzusammensetzungen und ≥ 1 Gew.-% bei konzentrierten Weichspülerzusammensetzungen) ein Problem mit der Stabilität der Zusammensetzung auf. Bei den erfindungsgemäßen Textil-pflegenden Zusammensetzungen können problemlos größere Mengen (≥ 1 Gew.-%) an Parfüm eingearbeitet werden.In conventional liquid fabric softener compositions containing quaternary ammonium compounds as the fabric care composition, a higher stability of the composition occurs at higher perfume concentration (> 0.4% by weight of perfume in regular fabric softener compositions and ≥ 1% by weight in concentrated fabric softener compositions). Both Textile-care compositions according to the invention can easily be incorporated with larger quantities (≥1% by weight) of perfume.
Es ist bevorzugt, dass die Matrix der festen, Textil-pflegenden Zusammensetzung 50 bis 98 Gew.-%, vorzugsweise 90 bis 97 Gew.-%, Seife enthält.It is preferred that the matrix of the solid, fabric care composition contains from 50% to 98% by weight, preferably from 90% to 97% by weight, of soap.
In einer bevorzugten Ausführungsform liegt die feste Textil-pflegende Zusammensetzung in partikulärer Form vor. Dabei ist es insbesondere bevorzugt, dass die feste Textil-pflegende Zusammensetzung Partikelgrößen im Bereich von 0,6 bis 30 mm, insbesondere 0,8 bis 7 mm und besonders bevorzugt 1 bis 3 mm, aufweist Textil-pflegende Zusammensetzung mit diesen Partikelgrößen lassen sich besonders gut und genau dosieren.In a preferred embodiment, the solid textile care composition is in particulate form. It is particularly preferred that the solid textile-care composition particle sizes in the range of 0.6 to 30 mm, in particular 0.8 to 7 mm and particularly preferably 1 to 3 mm, textile-care composition having these particle sizes are particularly dosing well and exactly.
Die Erfindung betrifft auch die Verwendung einer erfindungsgemäßen festen, Textil-pflegenden Zusammensetzung zum Konditionieren von textilen Flächengebilden.The invention also relates to the use of a solid textile-care composition according to the invention for conditioning textile fabrics.
Außerdem betrifft die Erfindung ein Verfahren zur Herstellung einer festen, Textil-pflegende Zusammensetzung, umfassend eine Matrix aus Seife und weiteren Zusätzen ausgewählt aus der Gruppe bestehend aus Propylenglykol, Dipropylenglykol, Ethylenglykol, Diethylenglykol, 1,3-Butylenglykol, 2,3-Butylenglykol, Sorbit, Glycerin, Mannit, Glucose, Saccharose, Galactose, Fructose, Lactose, Dextrose und Mischungen daraus, sowie darin verteilt eine Textil-pflegende Verbindung und ein Parfüm, bei dem die Inhaltsstoffe gemischt und die erhaltene Mischung anschließend durch eine rhombische Lochplatte extrudiert wird.The invention further relates to a process for the preparation of a solid, textile-care composition comprising a matrix of soap and further additives selected from the group consisting of propylene glycol, dipropylene glycol, ethylene glycol, diethylene glycol, 1,3-butylene glycol, 2,3-butylene glycol, Sorbitol, glycerin, mannitol, glucose, sucrose, galactose, fructose, lactose, dextrose, and mixtures thereof, as well as a fabric conditioning compound and a perfume, in which the ingredients are mixed and the resultant mixture is then extruded through a rhombic orifice plate.
Ferner betrifft die Erfindung ein Wasch- oder Reinigungsmittel, umfassend eine erfindungsgemäße feste, Textil-pflegende Zusammensetzung.Furthermore, the invention relates to a washing or cleaning agent comprising a solid, textile-care composition according to the invention.
Durch das Einbringen der erfindungsgemäßen Textil-pflegenden Zusammensetzung in ein Wasch- oder Reinigungsmittel steht dem Verbraucher ein Textil-pflegendes Wasch- oder Reinigungsmittel ("2in1"-Wasch- oder Reinigungsmittel) zur Verfügung und er braucht nicht zwei Mittel (Wasch- oder Reinigungsmittel und Textil-pflegenden Zusammensetzung) zu dosieren. So steht beim Einbringen einer Textil-weichmachenden Zusammensetzung in ein Wasch- oder Reinigungsmittel dem Verbraucher dann ein Textil-weichmachendes Wasch- oder Reinigungsmittel ("2in1"-Wasch- oder Reinigungsmittel) zur Verfügung und er braucht nicht zwei Mittel (Wasch- oder Reinigungsmittel und Weichspüler) zu dosieren sowie keinen separaten Spülgang.By introducing the textile-care composition according to the invention into a washing or cleaning agent, the consumer is provided with a textile-care washing or cleaning agent ("2in1" washing or cleaning agent) and he does not need two agents (washing or cleaning agent and Textile-care composition) to dose. Thus, when a textile-softening composition is introduced into a washing or cleaning agent, the consumer is then provided with a fabric-softening washing or cleaning agent ("2in1" washing or cleaning agent) and does not need two detergents or cleaners Fabric softener) and no separate rinse.
Weiterhin müssen nicht das Wasch- oder Reinigungsmittel und die Textil-pflegende Zusammensetzung parfümiert werden, sondern nur noch die Textil-pflegende Zusammensetzung. Dies führt nicht nur zu geringeren Kosten, sondern ist auch für Verbraucher mit empfindlicher Haut und/oder Allergien vorteilhaft.Furthermore, it is not necessary to perfume the washing or cleaning agent and the textile-care composition, but only the textile-care composition. this leads to Not only at a lower cost, but is also beneficial for consumers with sensitive skin and / or allergies.
Im Folgenden wird die Erfindung unter anderem anhand von Beispielen erläutertIn the following, the invention is explained, inter alia, by way of examples
Die Textil-pflegende Zusammensetzung enthält eine Matrix aus Seife sowie darin verteilt eine Textilpflegende Verbindung, ein Parfüm und weitere Zusätze.The fabric care composition contains a matrix of soap as well as a fabric care compound, perfume and other additives distributed therein.
Die Matrix aus Seife enthält als Hauptbestandteil die Natriumsalze von Fettsäuren ausgewählt aus der Gruppe bestehend aus Palmölfettsäuren, Palmkernölfettsäuren, Kokosfettsäuren, Erdnussfettsäuren, Talgfettsäuren, Stearinsäure, Ölsäure, Sojafettsäuren, Olivenôlfettsäuren und deren Mischungen. Dabei enthält die Matrix der festen, Textil-pflegenden Zusammensetzung vorzugsweise 50 bis 98 Gew.-%, besonders bevorzugt 90 bis 97 Gew.-% Seife.The matrix of soap contains as its main ingredient the sodium salts of fatty acids selected from the group consisting of palm oil fatty acids, palm kernel oil fatty acids, coconut fatty acids, peanut fatty acids, tallow fatty acids, stearic acid, oleic acid, soybean fatty acids, olive oil fatty acids and mixtures thereof. The matrix of the solid, textile-care composition contains preferably 50 to 98% by weight, particularly preferably 90 to 97% by weight, of soap.
Die Matrix kann zusätzlich auch Kalium- und/oder Ammoniumsalze von Fettsäuren enthalten. Der Anteil an diesen Fettsäureseifen sollte aber möglichst gering sein.The matrix may additionally contain potassium and / or ammonium salts of fatty acids. The proportion of these fatty acid soaps should be as low as possible.
Die Matrix aus Seife enthält weitere Zusätze, die aus der Gruppe bestehend aus Propylenglykol, Dipropylenglykol, Ethylenglykol, Diethylenglykol, 1,3-Butylenglykol, 2,3-Butylenglykol, Sorbit, Glycerin, Mannit, Glucose, Saccharose, Galactose, Fructose, Lactose, Dextrose und Mischungen daraus ausgewählt sind.The matrix of soap contains further additives selected from the group consisting of propylene glycol, dipropylene glycol, ethylene glycol, diethylene glycol, 1,3-butylene glycol, 2,3-butylene glycol, sorbitol, glycerol, mannitol, glucose, sucrose, galactose, fructose, lactose, Dextrose and mixtures thereof are selected.
Durch diese Zusätze wird die Transparenz der Textil-pflegenden Zusammensetzung erhöht. Die Menge an diesen Zusätzen beträgt vorzugsweise zwischen 0,1 und 25 Gew.-% und besonders bevorzugt zwischen 5 und 15 Gew.-%.These additives increase the transparency of the textile-care composition. The amount of these additives is preferably between 0.1 and 25 wt .-% and particularly preferably between 5 and 15 wt .-%.
Unter einer Textil-pflegenden Verbindung wird in diesem Zusammenhang jede Verbindung verstanden, die damit behandelten textilen Flächengebilden einen vorteilhaften Effekt vermittelt, wie beispielsweise einen Textil-weichmachenden Effekt, Knitterfestigkeit bzw. die schädliche oder negative Effekte, die beim Reinigen und/oder Konditionieren und/oder Tragen auftreten können, wie beispielsweise Verblassen, Vergrauung, usw., reduziert.In this context, a textile care compound is understood to mean any compound which gives textile fabrics treated therewith a beneficial effect, such as, for example, a textile softening effect, crease resistance or the harmful or negative effects which result during cleaning and / or conditioning and / or or wearing, such as fading, graying, etc., reduced.
Die Textil-pflegende Verbindung kann beispielsweise eine Textil-weichmachende Verbindung, Bleichmittel, Bleichaktivatoren, Enzyme, Silikonöle, Antiredepositionsmittel, optische Aufheller, Vergrauungsinhibitoren, Einlaufverhinderer, Knitterschutzmittel, Farbübertragungsinhibitoren, antimikrobiellen Wirkstoffe, Germizide, Fungizide, Antioxidantien, Antistatika, Bügelhilfsmittel, Phobier- und Imprägniermittel, Quell- und Schiebefestmitteln, UV-Absorber sowie Mischungen daraus umfassen. Konkrete Beispiele für diese Textil-pflegenden Verbindungen finden sich bei der Beschreibung des erfindungsgemäßen Wasch- oder Reinigungsmittels und können auch in der festen, Textil-pflegenden Zusammensetzung verwendet werden.The fabric care composition may include, for example, a fabric softening compound, bleaches, bleach activators, enzymes, silicone oils, anti redeposition agents, optical brighteners, grayness inhibitors, anti-shrinkage agents, anti-crease agents, color transfer inhibitors, antimicrobial Active ingredients, germicides, fungicides, antioxidants, antistatic agents, ironing aids, repellents and impregnating agents, swelling and anti-slip agents, UV absorbers and mixtures thereof. Concrete examples of these fabric-care compounds can be found in the description of the washing or cleaning agent of the invention and can also be used in the solid, textile-care composition.
Die Textil-pflegende Verbindung ist vorzugsweise eine Textil-weichmachende Verbindung und ist beispielsweise ein Polysiloxan, ein Textif-weichmachender Ton, ein kationisches Polymer oder eine Mischung aus wenigstens zwei dieser Textil-weichmachenden Verbindungen. Dementsprechend ist die Textil-pflegende Zusammensetzung vorzugsweise eine Textil-weichmachende Zusammensetzung.The fabric conditioning compound is preferably a fabric softening compound and is, for example, a polysiloxane, a textif softening clay, a cationic polymer, or a blend of at least two of these fabric softening compounds. Accordingly, the fabric care composition is preferably a fabric softening composition.
Ein bevorzugt einsetzbares Polysiloxan weist zumindest folgende Struktureinheit auf
- R1= unabhängig von einander C1-C30-Alkyl, vorzugsweise C1-C4-Alkyl, insbesondere Methyl oder Ethyl,
- n = 1 bis 5000, vorzugsweise 10 bis 2500, insbesondere 100 bis 1500.
- R 1 = independently of one another C 1 -C 30 -alkyl, preferably C 1 -C 4 -alkyl, in particular methyl or ethyl,
- n = 1 to 5000, preferably 10 to 2500, in particular 100 to 1500.
Es kann bevorzugt sein, dass das Polysiloxan zusätzlich auch folgende Struktureinheit aufweist
- R1= C1-C30-Alkyl, vorzugsweise C1-C4-Alkyl, insbesondere Methyl oder Ethyl,
- Y = ggf. substituiertes, lineares oder verzweigtes C1-C20-Alkylen, vorzugsweise -(CH2)m- mit m= 1 bis 16, vorzugsweise 1 bis 8, insbesondere 2 bis 4, im speziellen 3,
- R2, R3 = unabhängig voneinander H oder gegebenenfalls substituiertes, lineares oder verzweigtes C1-C30-Alkyl, vorzugsweise mit Aminogruppen substituiertes C1-C30-Alkyl, besonders bevorzugt -(CH2)b-NH2 mit b = 1 bis 10, äußerst bevorzugt b = 2,
- x = 1 bis 5000, vorzugsweise 10 bis 2500, insbesondere 100 bis 1500.
- R 1 = C 1 -C 30 -alkyl, preferably C 1 -C 4 -alkyl, in particular methyl or ethyl,
- Y = optionally substituted, linear or branched C 1 -C 20 -alkylene, preferably - (CH 2 ) m- where m = 1 to 16, preferably 1 to 8, in particular 2 to 4, in particular 3,
- R 2 , R 3 = independently of one another are H or optionally substituted, linear or branched C 1 -C 30 -alkyl, preferably C 1 -C 30 -alkyl substituted by amino groups, more preferably - (CH 2 ) b -NH 2 where b = 1 to 10, most preferably b = 2,
- x = 1 to 5000, preferably 10 to 2500, in particular 100 to 1500.
Weist das Polysiloxan nur die Struktureinheit a) mit R1 = Methyl auf, handelt es sich um ein Polydimethylsiloxan. Polydimethylpolysiloxane sind als effiziente Textil-weichmachende Verbindungen bekannt.If the polysiloxane has only the structural unit a) with R 1 = methyl, it is a polydimethylsiloxane. Polydimethylpolysiloxanes are known as efficient textile softening compounds.
Geeignete Polydimethysiloxane umfassen DC-200 (ex Dow Corning), Baysilone® M 50, Baysilone® M 100, Baysilone® M 350, Baysilone® M 500, Baysilone® M 1000, Baysilone® M 1500, Baysilone® M 2000 oder Baysilone® M 5000 (alle ex GE Bayer Silicones).Suitable polydimethysiloxanes include DC-200 (ex Dow Corning), Baysilone® M 50, Baysilone® M 100, Baysilone® M 350, Baysilone® M 500, Baysilone® M 1000, Baysilone® M 1500, Baysilone® M 2000 or Baysilone® M 5000 (all ex GE Bayer Silicones).
Es kann allerdings auch bevorzugt sein, dass das Polysiloxan die Struktureinheiten a) und b) enthält. Ein besonders bevorzugtes Polysiloxan weist die folgende Struktur auf:
(CH3)3Si-[O-Si(CH3)2]n-[O-Si(CH3){(CH2)3-NH-(CH2)2-NH2}]x-OSi(CH3)3
wobei die Summe n + x eine Zahl zwischen 2 und 10.000 istHowever, it may also be preferred that the polysiloxane contains the structural units a) and b). A particularly preferred polysiloxane has the following structure:
(CH 3 ) 3 Si [O-Si (CH 3 ) 2 ] n - [O-Si (CH 3 ) {(CH 2 ) 3 -NH- (CH 2 ) 2 -NH 2 }] x -OSi ( CH 3 ) 3
where the sum n + x is a number between 2 and 10,000
Geeignete Polysiloxane mit den Struktureinheiten a) und b) sind beispielsweise kommerziell unter den Markennamen DC2-8663, DC2-8035, DC2-8203, DC05-7022 oder DC2-8566 (alle ex Dow Corning) erhältlich. Erfindungsgemäß ebenfalls geeignet sind beispielsweise die im Handel erhältlichen Produkte Dow Corning® 7224, Dow Corning® 929 Cationic Emulsion oder Formasil 410 (GE Silicones).Suitable polysiloxanes having the structural units a) and b) are for example commercially available under the trade names DC2-8663, DC2-8035, DC2-8203, DC05-7022 or DC2-8566 (all ex Dow Corning). According to the invention are also suitable for example the products commercially available Dow Corning ® 7224, Dow Corning ® 929 Cationic Emulsion or Formasil 410 (GE Silicones).
Ein geeigneter Textil-weichmachender Ton ist beispielsweise ein Smectit-Ton. Bevorzugte Smectit-Tone sind Beidellit-Tone, Hectorit-Tone, Laponit-Tone, Montmorillonit-Tone, Nontronit-Tone, Saponit-Tone, Sauconit-Tone und Mischungen daraus. Montmorillonit-Tone sind die bevorzugten weichmachenden Tone. Bentonite enthalten hauptsächlich Montmorillonite und können als bevorzugte Quelle für den Textil-weichmachenden Ton dienen.A suitable fabric softening clay is, for example, a smectite clay. Preferred smectite clays are beidellite clays, hectorite clays, laponite clays, montmorillonite clays, nontronite clays, saponite clays, sauconite clays, and mixtures thereof. Montmorillonite clays are the preferred softening clays. Bentonites contain mainly montmorillonites and can serve as a preferred source of fabric softening clay.
Geeignete Bentonite werden beispielsweise unter den Bezeichnungen Laundrosil® von der Firma Süd-Chemie oder unter der Bezeichnung Detercal von der Firma Laviosa vertrieben.Suitable bentonites are sold, for example, under the names Laundrosil® by Süd-Chemie or under the name Detercal by Laviosa.
Geeignete kationische Polymere umfassen insbesondere solche, die in "
- POLYQUATERNIUM-1 (CAS-Nummer: 68518-54-7)
Definition: {(HOCH2CH2)3N+-CH2CH=CHCH2-[N+(CH3)2-CH2CH=CHCH2]x-N+(CH2CH2OH)3}[Cl-]x+2 - POLYQUATERNIUM-2 (CAS-Nummer: 63451-27-4)
Definition: [-N(CH3)2-CH2CH2CH2-NH-C(O)-NH-CH2CH2CH2-N(CH3)2-CH2CH2OCH2CH2-]2+ (Cl-)2
Beispielsweise erhältlich als Mirapol® A-15 (ex Rhodia) - POLYQUATERNIUM-3
Definition: Copolymer von Acrylamid und Trimethylammoniumethylmethacrylatmethosulfat - POLYQUATERNIUM-4 (CAS-Nummer: 92183-41-0)
Definition: Copolymer von Hydroxyethylcellulose und Diallyldimethylammoniumchlorid
Beispielsweise erhältlich als Celquat® H 100 oder Celquat® L200 (ex National Starch) - POLYQUATERNIUM-5 (CAS-Nummer: 26006-22-4)
Definition: Copolymer von Acrylamid und β-Methacrylyloxyethyltrimethylammoniummethosulfat.
Beispielsweise erhältlich als Nalco 7113 (ex Nalco) oder Reten® 210, Reten® 220, Reten® 230, Reten® 240, Reten® 1104, Reten® 1105 oder Reten® 1106 (alle ex Hercules) - POLYQUATERNIUM-6 (CAS-Nummer: 26062-79-3)
Definition: Polymer von Dimethyldiallylammoniumchlorid
Beispielsweise erhältlich als Merquat® 100 (ex Ondeo-Nalco) - POLYQUATERNIUM-7 (CAS-Nummer: 26590-05-6)
Definition: Polymeres quaternäres Ammoniumsalz bestehend aus Acrylamid- und Dimethyldiallylammoniumchlorid-Monomeren.
Beispielsweise erhältlich als Merquat® 550 oder Merquat® S (ex Ondeo-Nalco) - POLYQUATERNIUM-8
Definition: Polymeres quaternäres Ammoniumsalz von Methyl- und Stearyldimethylaminoefhylmethacrylat, welches mit Dimethylsulfat quaternierte wurde. - POLYQUATERNIUM-9
Definition: Polymeres quaternäres Ammoniumsalz von Polydimethylaminoethylmethacrylat, welches mit Methylbromid quaternierte wurde. - POLYQUATERNIUM-10 (CAS-Numnem: 53568-66-4; 55353-19-0; 54351- 50-7; 81859-24-7; 68610-92-4; 81859-24-7)
Definition: Polymeres quaternäres Ammoniumsalz von hydroxyethylcellulose, die mit einem Trimethylammonium-substitutierten Epoxid umgesetzt wurde.
Beispielsweise erhältlich als Celquat® SC-240 (ex National Starch), UCARE® Polymer JR-125, UCARE® Polymer JR-400, UCARE® Polymer JR-30M, UCARE® Polymer LR 400, UCARE® Polymer LR 30M, Ucare® Polymer SR-10 (alle ex Amerchol) - POLYQUATERNIUM-11 (CAS-Nummer: 53633-54-8)
Definition: Quaternäres Ammoniumpolymer, welches durch Umsetzung von Diethylsulfat mit dem Copolymer von Vinylpyrrolidon und Dimethylaminoethylmethacrylat gebildet wird. Beispielsweise erhältlich als Luviquat®PQ 11 PN (ex BASF), Gafquat® 734, Gafquat® 755 oder Gafquat® 755N (ex GAF) - POLYQUATERNIUM-12 (CAS-Nummer: 68877-50-9)
Definition: Quatemäres Ammoniumpolymersalz, welches durch Umsetzung des Ethylmethacrylat/-Abietylmethacrylat/Diethylaminoethylmethacrylat-Copolymers mit Dimethylsulfat erhältlich ist - POLYQUATERNIUM-13 (CAS Nummer 68877-47-4)
Definition: Polymeres quaternäres Ammoniumsalz, welches durch Umsetzung des Ethylmethacrylat/Oleylmethacrylat/Diethylaminoethylmethacrylat-Copolymers mit Dimethylsulfat erhältlich ist - POLYQUATERNIUM-14 (CAS-Nummer: 27103-90-8)
Definition: Polymeres quaternäres Ammoniumsalz der Formel -{-CH2-C-(CH3)-[C(O)O-CH2CH2-N(CH3)3 -]}x + [CH3SO4]- x - POLYQUATERNIUM-15 (CAS-Nummer: 35429-19-7)
Definition: Copolymer von Acrylamid und β-Methacrylyloxyethyltrimethylammoniumchlorid - POLYQUATERNIUM-16 (CAS-Nummer: 95144-24-4)
Definition: Polymeres quaternäres Ammoniumsalz, gebildet aus Methylvinylimidazoliumchlorid und Vinylpyrrolidon.
Beispielsweise erhältlich als Luviquat® FC 370, Luviquat® Style, Luviquat® FC 550 oder Luviquat® Excellence (alle ex BASF) - POLYQUATERNIUM-17 (CAS-Nummer: 90624-75-2)
Definition: Polymeres quaternäres Ammoniumsalz, welches durch Umsetzung von Adipinsäure und Dimethylaminopropylamin mit Dichlorethylether erhältlich ist.
Beispielsweise erhältlich als Mirapol® AD-1 (ex Rhodia) - POLYQUATERNIUM-18
Definition: Polymeres quaternäres Ammoniumsalz, welches durch Umsetzung von Azelainsäure und Dimethylaminopropylamin mit Dichlorethylether erhältlich ist.
Beispielsweise erhältlich als Mirapol® AZ-1 (ex Rhodia) - POLYQUATERNIUM-19
Definition: Polymeres quaternäres Ammoniumsalz, welches durch Umsetzung von Polyvinylalkohol mit 2,3-Epoxypropylamin erhältlich ist.
POLYQUATERNIUM-20
Definition: Polymeres quaternäres Ammoniumsalz, welches durch Umsetzung von Polyvinyloctadecylether mit 2,3-Epoxypropylamin erhältlich ist. - POLYQUATERNIUM-21 (CAS-Nummer: 102523-94-4)
Definition: Polysiloxan/Polydimethyldialkylammoniumacetat-Copolymer
Beispielsweise erhältlich als Abil® B 9905 (ex Goldschmidt-Degussa) - POLYQUATERNIUM-22 (CAS-Nummer: 53694-17-0)
Definition: Dimethyldiallylammoniumchlorid/Acrylsäure-Copolymer
Beispielsweise erhältlich als Merquat® 280 (ex Ondeo-Nalco) - POLYQUATERNIUM-24 (CAS-Nummer: 107987-23-5)
Definition: Polymeres quaternäres Ammoniumsalz aus der Umsetzung von Hydroxyethylcellulose mit einem mit Lauryldimethylammonium substituierten-Epoxid
Beispielsweise erhältlich als Quatrisoft - POLYQUATERNIUM-27
Definition: Blockcopolymer aus der Umsetzung von Polyquaternium-2 mit Polyquaternium-17. - POLYQUATERNIUM-28 (CAS-Nummer: 131954-48-8)
Definition: Vinylpyrrolidon/Methacrylamidopropyltrimethylammoniumchlorid-Copolymer
Beispielsweise erhältlich als Gafquat® HS-100 (ex GAF) - POLYQUATERNIUM-29
Definition: Chitosan, welches mit Propylenoxid umgesetzt und mit Epichlorhydrin quaternisiert wurde - POLYQUATERNIUM-30
Definition: Polymeres quaternäres Ammoniumsalz der Formel: -[CH2C(CH3)(C(O)OCH3)]x-[CH2C(CH3)(C(O)OCH2CH2N+(CH3)2CH2COO-)]y- - POLYQUATERNIUM-31 (CAS-Nummer: 136505-02-7)
- POLYQUATERNIUM-32 (CAS-Nummer: 35429-19-7)
Definition: Polymer von N,N,N-Trimethyl-2-[(2-methyl-1-oxo-2-propenyl)oxy]-ethanaminiumchlorid mit 2-Propenamid - POLYQUATERNIUM-37 (CAS-Nummer: 26161-33-1)
Definition: Homopolymer von Methacryloyltrimethylchlorid
Beispielsweise erhältlich als Synthalen® CR (ex 3V Sigma) - POLYQUATERNIUM-44 (CAS-Nummer: 150595-70-5)
Definition: Quaternäres Ammoniumsalz des Copolymers von Vinylpyrrolidon und quaternisiertem Imidazolin
Beispielsweise erhältlich als Luviquat® Ultracare (ex BASF) - POLYQUATERNIUM-68 (CAS-Nummer: 827346-45-2)
Definition: Quatemisiertes Copolymer von Vinylpyrrolidon, Methacrylamid, Vinylimidazol und quaternisiertem Vinylimidazol
Beispielsweise erhältlich als Luviquat® Supreme (ex BASF)
- POLYQUATERNIUM-1 (CAS number: 68518-54-7)
Definition: {(HOCH 2 CH 2 ) 3 N + -CH 2 CH = CHCH 2 - [N + (CH 3 ) 2 -CH 2 CH = CHCH 2 ] x -N + (CH 2 CH 2 OH) 3 } [ Cl - ] x + 2 - POLYQUATERNIUM-2 (CAS number: 63451-27-4)
Definition: [-N (CH 3 ) 2 -CH 2 CH 2 CH 2 -NH-C (O) -NH-CH 2 CH 2 CH 2 -N (CH 3 ) 2 -CH 2 CH 2 OCH 2 CH 2 - ] 2+ (Cl - ) 2
For example, available as Mirapol® A-15 (ex Rhodia) - Polyquaternium-3
Definition: copolymer of acrylamide and trimethylammoniumethyl methacrylate methosulfate - POLYQUATERNIUM-4 (CAS number: 92183-41-0)
Definition: Copolymer of hydroxyethylcellulose and diallyldimethylammonium chloride
For example, available as Celquat® H 100 or Celquat® L200 (ex National Starch) - POLYQUATERNIUM-5 (CAS number: 26006-22-4)
Definition: Copolymer of acrylamide and β-methacrylyloxyethyltrimethylammonium methosulfate.
For example, available as Nalco 7113 (ex Nalco) or Reten® 210, Reten® 220, Reten® 230, Reten® 240, Reten® 1104, Reten® 1105 or Reten® 1106 (all ex Hercules) - POLYQUATERNIUM-6 (CAS number: 26062-79-3)
Definition: Polymer of dimethyldiallylammonium chloride
For example, available as Merquat® 100 (ex Ondeo-Nalco) - POLYQUATERNIUM-7 (CAS number: 26590-05-6)
Definition: Polymeric quaternary ammonium salt consisting of acrylamide and dimethyldiallylammonium chloride monomers.
For example, available as Merquat® 550 or Merquat® S (ex Ondeo-Nalco) - Polyquaternium-8
Definition: Polymeric quaternary ammonium salt of methyl and stearyldimethylaminoethyl methacrylate quaternized with dimethyl sulfate. - Polyquaternium-9
Definition: Polymeric quaternary ammonium salt of polydimethylaminoethyl methacrylate quaternized with methyl bromide. - POLYQUATERNIUM-10 (CAS Numeral: 53568-66-4; 55353-19-0; 54351-50-7; 81859-24-7; 68610-92-4; 81859-24-7)
Definition: Polymeric quaternary ammonium salt of hydroxyethylcellulose reacted with a trimethylammonium substituted epoxide.
For example, available as Celquat® SC-240 (ex National Starch), UCARE® Polymer JR-125, UCARE® Polymer JR-400, UCARE® Polymer JR-30M, UCARE® Polymer LR 400, UCARE® Polymer LR 30M, Ucare® Polymer SR-10 (all ex Amerchol) - POLYQUATERNIUM-11 (CAS number: 53633-54-8)
Definition: Quaternary ammonium polymer formed by reaction of diethyl sulfate with the copolymer of vinylpyrrolidone and dimethylaminoethyl methacrylate. For example, available as Luviquat®PQ 11 PN (ex BASF), Gafquat® 734, Gafquat® 755 or Gafquat® 755N (ex GAF) - POLYQUATERNIUM-12 (CAS number: 68877-50-9)
Definition: Quaternary ammonium polymer salt obtainable by reacting the ethyl methacrylate / a-bidyl methacrylate / diethylaminoethyl methacrylate copolymer with dimethyl sulfate - POLYQUATERNIUM-13 (CAS number 68877-47-4)
Definition: Polymeric quaternary ammonium salt obtainable by reaction of the ethyl methacrylate / oleyl methacrylate / diethylaminoethyl methacrylate copolymer with dimethyl sulfate - POLYQUATERNIUM-14 (CAS number: 27103-90-8)
Definition: Polymeric quaternary ammonium salt of the formula - {- CH 2 -C- (CH 3 ) - [C (O) O-CH 2 CH 2 -N (CH 3 ) 3 - ]} x + [CH 3 SO 4 ] - x - POLYQUATERNIUM-15 (CAS number: 35429-19-7)
Definition: copolymer of acrylamide and β-methacrylyloxyethyltrimethylammonium chloride - POLYQUATERNIUM-16 (CAS number: 95144-24-4)
Definition: Polymeric quaternary ammonium salt formed from methylvinylimidazolium chloride and vinylpyrrolidone.
For example, available as Luviquat® FC 370, Luviquat® Style, Luviquat® FC 550 or Luviquat® Excellence (all ex BASF) - POLYQUATERNIUM-17 (CAS number: 90624-75-2)
Definition: Polymeric quaternary ammonium salt obtainable by reaction of adipic acid and dimethylaminopropylamine with dichloroethyl ether.
For example, available as Mirapol® AD-1 (ex Rhodia) - Polyquaternium-18
Definition: Polymeric quaternary ammonium salt, which is obtainable by reaction of azelaic acid and dimethylaminopropylamine with dichloroethyl ether.
For example, available as Mirapol® AZ-1 (ex Rhodia) - Polyquaternium-19
Definition: Polymeric quaternary ammonium salt, which is obtainable by reaction of polyvinyl alcohol with 2,3-epoxypropylamine.
Polyquaternium-20
Definition: Polymeric quaternary ammonium salt, obtainable by reaction of polyvinyloctadecyl ether with 2,3-epoxypropylamine. - POLYQUATERNIUM-21 (CAS number: 102523-94-4)
Definition: polysiloxane / polydimethyldialkylammonium acetate copolymer
For example, available as Abil® B 9905 (ex Goldschmidt-Degussa) - POLYQUATERNIUM-22 (CAS number: 53694-17-0)
Definition: dimethyldiallylammonium chloride / acrylic acid copolymer
For example, available as Merquat® 280 (ex Ondeo-Nalco) - POLYQUATERNIUM-24 (CAS number: 107987-23-5)
Definition: Polymeric quaternary ammonium salt from the reaction of hydroxyethylcellulose with a lauryldimethylammonium substituted epoxide
For example, available as Quatrisoft - Polyquaternium-27
Definition: Block copolymer from the reaction of Polyquaternium-2 with Polyquaternium-17. - POLYQUATERNIUM-28 (CAS number: 131954-48-8)
Definition: Vinylpyrrolidone / methacrylamidopropyltrimethylammonium chloride copolymer
For example, available as Gafquat® HS-100 (ex GAF) - Polyquaternium-29
Definition: Chitosan, which was reacted with propylene oxide and quaternized with epichlorohydrin - Polyquaternium-30
Definition: Polymeric quaternary ammonium salt of the formula: - [CH 2 C (CH 3 ) (C (O) OCH 3 )] x - [CH 2 C (CH 3 ) (C (O) OCH 2 CH 2 N + (CH 3 ) 2 CH 2 COO - )] y - - POLYQUATERNIUM-31 (CAS number: 136505-02-7)
- POLYQUATERNIUM-32 (CAS number: 35429-19-7)
Definition: Polymer of N, N, N-trimethyl-2 - [(2-methyl-1-oxo-2-propenyl) oxy] -ethanaminium chloride with 2-propenamide - POLYQUATERNIUM-37 (CAS number: 26161-33-1)
Definition: homopolymer of methacryloyltrimethyl chloride
For example, available as Synthalen® CR (ex 3V Sigma) - POLYQUATERNIUM-44 (CAS number: 150595-70-5)
Definition: Quaternary ammonium salt of the copolymer of vinylpyrrolidone and quaternized imidazoline
For example, available as Luviquat® Ultracare (ex BASF) - POLYQUATERNIUM-68 (CAS-Number: 827346-45-2)
Definition: Quaternized copolymer of vinylpyrrolidone, methacrylamide, vinylimidazole and quaternized vinylimidazole
For example, available as Luviquat® Supreme (ex BASF)
Es kann bevorzugt sein, dass die Textil-pflegende Zusammensetzung eine Textil-weichmachende Verbindung und eine oder mehr weitere Textil-pflegende Verbindung(en) enthält.It may be preferred that the fabric care composition contains a fabric softening compound and one or more other fabric care compounds.
Die Menge an Textil-pflegender Verbindung in der Textil-pflegenden Züsammensetzung beträgt 0,1 bis 10 Gew.-% und bevorzugt zwischen 1 und 6 Gew.-%.The amount of fabric care compound in the fabric care composition is from 0.1 to 10 weight percent, and preferably from 1 to 6 weight percent.
Ein weiterer essentieller Bestandtell der Textil-pflegenden Zusammensetzung ist das Parfüm. Als Parfümöle bzw. Duftstoffe können einzelne Riechstoffverbindungen, z.B. die synthetischen Produkte vom Typ der Ester, Ether, Aldehyde, Ketone, Alkohole und Kohlenwasserstoffe verwendet werden. Bevorzugt werden jedoch Mischungen verschiedener Riechstoffe verwendet, die gemeinsam eine ansprechende Duftnote erzeugen. Solche Parfümöle können auch natürliche Riechstoffgemische enthalten, wie sie aus pflanzlichen Quellen zugänglich sind.Another essential ingredient of the textile-care composition is the perfume. As perfume oils or fragrances, individual perfume compounds, for example the synthetic products of the ester type, ethers, aldehydes, ketones, alcohols and hydrocarbons can be used. Preferably, however, mixtures of different fragrances are used, which together produce an attractive fragrance. Such perfume oils may also contain natural fragrance mixtures as are available from plant sources.
Die Menge an Parfüm in der Textil-pflegenden Zusammensetzung betragt dabei vorzugsweise zwischen 0,1 und 20 Gew.-%, insbesondere bevorzugt zwischen 1 und 10 Gew.-% und ganz besonders bevorzugt zwischen 2 und 7 Gew.-%.The amount of perfume in the textile-care composition amounts to preferably between 0.1 and 20 wt .-%, particularly preferably between 1 and 10 wt .-% and most preferably between 2 and 7 wt .-%.
Die erfindungsgemäße Textil-pflegende Zusammensetzung kann optional weitere Inhaltsstoffe enthalten.The textile-care composition according to the invention may optionally contain further ingredients.
Um den ästhetischen Eindruck der der Textil-pflegenden Zusammensetzung zu verbessern, können sie mit geeigneten Farbstoffen eingefärbt werden. Bevorzugte Farbstoffe, deren Auswahl dem Fachmann keinerlei Schwierigkeit bereitet, besitzen eine hohe Lagerstabilität und Unempfindlichkeit gegenüber den übrigen Inhaltsstoffen der Wasch- oder Reinigungsmittel und gegen Licht sowie keine ausgeprägte Substantivität gegenüber Textilfasern, um diese nicht anzufärben.In order to improve the aesthetic impression of the textile-care composition, they can be dyed with suitable dyes. Preferred dyes, the selection of which presents no difficulty to the skilled person, have a high storage stability and insensitivity to the other ingredients of detergents or cleaning agents and to light and no pronounced substantivity to textile fibers so as not to stain them.
Weiterhin kann die Textil-pflegende Zusammensetzung einen Füllstoff, wie Silica, enthalten. Die Menge an Füllstoff kann zwischen 0,1 und 10 Gew.-% betragen und beträgt bevorzugt 1 bis 5 Gew.-%.Further, the fabric care composition may contain a filler such as silica. The amount of filler may be between 0.1 and 10 wt .-% and is preferably 1 to 5 wt .-%.
Die Textil-pflegende Zusammensetzung kann zur Erhöhung des Glanzes auch ein Perlglanzmütel enthalten. Beispiele für geeignete Perlglanzmittel sind Ethylenglykolmono- und -distearat (zum Beispiel Cutina® AGS von Cognis) sowie PEG-3-distearat.The textile-care composition may also contain a pearlescent mortar to increase the gloss. Examples of suitable pearlescing agents are ethylene glycol mono- and distearate (for example Cutina AGS from Cognis) and PEG-3-distearate.
Um Verfärbungen der Matrix aus Seife zu verhindern, kann der Matrix als weiterer Inhaltsstoff ein Chelatbildner, in einer Menge von 0,01 bis 0,03 Gew.-% zugesetzt werden. Geeignete Chelatbildner umfassen Ethylendiamintetraessigsäure (EDTA) oder (1-Hydroxyethyliden)-diphosphonsäure (HEDP).In order to prevent discoloration of the matrix of soap, the matrix may be added as a further ingredient, a chelating agent, in an amount of 0.01 to 0.03 wt .-%. Suitable chelating agents include ethylenediamine tetraacetic acid (EDTA) or (1-hydroxyethylidene) diphosphonic acid (HEDP).
Weiterhin kann die Textil-pflegende Zusammensetzung eine hautpflegende Verbindung enthalten.Furthermore, the fabric care composition may contain a skin care compound.
Unter einer hautpflegenden Verbindung wird eine Verbindung oder eine Mischung aus Verbindungen verstanden, die bei Kontakt eines Textils mit der festen, textil- und/oder hautpflegenden Zusammensetzung auf das Textil aufziehen und bei Kontakt des Textils mit Haut der Haut einen Vorteil verleihen verglichen mit einem Textil, welches nicht mit der erfindungemäßen textil- und/oder hautpflegenden Zusammensetzung behandelt wurde. Dieser Vorteil kann beispielsweise den Transfer der hautpflegenden Verbindung vom Textil auf die Haut, einen geringeren Wassertransfer von der Haut auf das Textil oder eine geringere Reibung auf der Hautoberfläche durch das Textil umfassen.A skin-care compound is understood to mean a compound or a mixture of compounds which, upon contact of a textile with the solid, textile and / or skin-care composition, draw on the textile and, on contact of the textile with skin, confer an advantage on the skin compared with a textile which has not been treated with the textile and / or skin care composition according to the invention. This benefit may include, for example, the transfer of the skin care compound from the textile to the skin, less water transfer from the skin to the textile, or less friction on the skin surface through the textile.
Die hautpflegende Verbindung ist vorzugsweise hydrophob, kann flüssig oder fest sein und muss kompatibel mit den anderen Inhaltsstoffen der festen, textil- und oder hautpflegenden Zusammensetzung sein. Die hautpflegende Verbindung kann beispielsweise
- a) Wachse wie Carnauba, Spermaceti, Bienenwachs, Lanolin, Derivate davon sowie Mischungen daraus;
- b) Pflanzenextrakte, zum Beispiel pflanzliche Öle wie Avokadoöl, Olivenöl, Palmöl, Palmenkemöl, Rapsöl, Leinöl, Sojaöl, Erdnussöl, Korianderöl, Ricinusöl, Mohnöl. Kakaoöl, Kokosnussöl, Kürbiskemöl, Weizenkeimöl, Sesamöl, Sonnenblumenöl, Mandelöl, Macadamianussöl, Aprikosenkernöl, Haselnussöl, Jojobaöl oder Canolaöl, Kamille, Aloe Vera sowie Mischungen daraus;
- c) höhere Fettsäuren wie Laurinsäure, Myristinsäure, Palmitinsâure, Stearinsäure, Behensäure, Ölsäure, Linolsäure, Linolensäure, Isostearinsäure oder mehrfach ungesättigte Fettsäuren;
- d) höhere Fettalkohole wie Laurylalkohol, Cetylalkohol, Stearylalkohol, Oleylalkohol, Behenylalkohol oder 2-Hexadecanol,
- e) Ester wie Cetyloctanoat, Lauryllactat, Myristyllactat, Cetyllactat, Isopropylmyristat, Myristylmyristat, Isopropylpalmitat, Isopropyladipat, Butylstearat, Decyloleat, Cholesterolisostearat, Glycerolmonostearat, Glyceroldistearat, Glyceroltristearat, Alkyllactat, Alkylcitrat oder Alkyltartrat;
- f) Kohlenwasserstoffe wie Paraffine, Mineralöle, Squalan oder Squalen;
- g) Lipide;
- h) Vitamine wie Vitamin A, C oder E oder Vitaminalkylester;
- i) Phospholipide;
- j) Sonnenschutzmittel wie Octylmethoxylcinnamat und Butylmethoxybenzoylmethan;
- k) Silikonöle wie lineare oder cyclische Polydimethylsiloxane, Amino-, Alkyl-, Alkylaryl- oder Arylsubstituierte Silikonöle und
- l) Mischungen daraus
- a) waxes such as carnauba, spermaceti, beeswax, lanolin, derivatives thereof and mixtures thereof;
- b) plant extracts, for example vegetable oils such as avocado oil, olive oil, palm oil, palm kernel oil, rapeseed oil, linseed oil, soybean oil, peanut oil, coriander oil, castor oil, poppy seed oil. Cocoa oil, coconut oil, pumpkin seed oil, wheat germ oil, sesame oil, sunflower oil, almond oil, macadamia nut oil, apricot kernel oil, hazelnut oil, jojoba oil or canola oil, chamomile, aloe vera and mixtures thereof;
- c) higher fatty acids such as lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, oleic acid, linoleic acid, linolenic acid, isostearic acid or polyunsaturated fatty acids;
- d) higher fatty alcohols, such as lauryl alcohol, cetyl alcohol, stearyl alcohol, oleyl alcohol, behenyl alcohol or 2-hexadecanol,
- e) esters such as cetyloctanoate, lauryl lactate, myristyl lactate, cetyl lactate, isopropyl myristate, myristyl myristate, isopropyl palmitate, isopropyl adipate, butyl stearate, decyl oleate, cholesterol isostearate, glycerol monostearate, glyceryl distearate, glycerol tristearate, alkyl lactate, alkyl citrate or alkyl tartrate;
- f) hydrocarbons such as paraffins, mineral oils, squalane or squalene;
- g) lipids;
- h) vitamins such as vitamins A, C or E or vitamin alkyl esters;
- i) phospholipids;
- j) sunscreens such as octyl methoxyl cinnamate and butyl methoxybenzoyl methane;
- k) silicone oils such as linear or cyclic polydimethylsiloxanes, amino-, alkyl-, alkylaryl- or aryl-substituted silicone oils and
- l) mixtures thereof
Es ist bevorzugt, dass die Textil-pflegende Zusammensetzung Partikelgrößen im Bereich von 0,6 bis 30 mm, insbesondere 0,8 bis 7 mm und besonders bevorzugt 1 bis 3 mm, aufweist. Weiterhin ist bevorzugt, dass die Textil-pflegende Zusammensetzung ein Extrudat ist.It is preferred that the textile-care composition has particle sizes in the range of 0.6 to 30 mm, in particular 0.8 to 7 mm and particularly preferably 1 to 3 mm. It is further preferred that the textile care composition is an extrudate.
Zur Herstellung der Textil-pflegenden Zusammensetzung werden die Seife(n), die Textil-pflegende Verbindung, das Parfüm sowie gegebenenfalls weitere Inhaltsstoffe, gemischt und die erhaltene Mischung anschließend durch eine rhombische Lochplatte extrudiert.To prepare the textile-care composition, the soap (s), the textile-care compound, the perfume and, if appropriate, further ingredients are mixed, and the resulting mixture is then extruded through a rhombic perforated plate.
Die erfindungsgemäße Textil-pflegende Zusammensetzung eignet sich insbesondere zum Konditionieren von textilen Flächengebilden und wird dazu zusammen mit einem herkömmlichen Waschoder Reinigungsmittel im (Haupt)Waschgang eines herkömmlichen Wasch- und Reinigungsprozesses mit den textilen Flächengebilden in Kontakt gebracht.The textile-care composition of the invention is particularly suitable for conditioning textile fabrics and is used together with a conventional washing or Detergent in the (main) wash of a conventional washing and cleaning process brought into contact with the fabrics.
Die Textil-pflegende Zusammensetzung kann in ein Wasch- oder Reinigungsmittel eingebracht werden.The fabric care composition can be incorporated into a detergent or cleanser.
Dazu wird ein festes Wasch- oder Reinigungsmittel mit 0,1 bis 20 Gew.-%, vorzugsweise 1 bis 10 Gew.-%, der erfindungsgemäßen Textil-pflegenden Zusammensetzung gemischt.For this purpose, a solid detergent or cleaning agent with 0.1 to 20 wt .-%, preferably 1 to 10 wt .-%, of the textile-care composition according to the invention is mixed.
Die erfindungsgemäßen Wasch- oder Reinigungsmittel enthalten neben der Textil-pflegenden Zusammensetzung Tensid(e), wobei anionische, nichtionische, zwitterionische und/oder amphötere Tenside eingesetzt werden können. Bevorzugt sind aus anwendungstechnischer Sicht Mischungen aus anionischen und nichtionischen Tensiden. Der Gesamttensidgehalt eines Waschmittels liegt vorzugsweise unterhalb von 40 Gew.-% und besonders bevorzugt unterhalb von 35 Gew.%, bezogen auf das gesamte Waschmittel.The detergents or cleaners according to the invention contain, in addition to the textile-care composition, surfactant (s), it being possible to use anionic, nonionic, zwitterionic and / or ampholytic surfactants. From an application point of view, preference is given to mixtures of anionic and nonionic surfactants. The total surfactant content of a detergent is preferably below 40% by weight and more preferably below 35% by weight, based on the total detergent.
Als nichtionische Tenside werden vorzugsweise alkoxylierte, vorteilhafterweise ethoxylierte, insbesondere primäre Alkohole mit vorzugsweise 8 bis 18 C-Atomen und durchschnittlich 1 bis 12 Mol Ethylenoxid (EO) pro Mol Alkohol eingesetzt, in denen der Alkoholrest linear oder bevorzugt in 2-Stellung methylverzweigt sein kann bzw. lineare und methylverzweigte Reste im Gemisch enthalten kann, so wie sie üblicherweise in Oxoalkoholresten vorliegen. Insbesondere sind jedoch Alkoholethoxylate mit linearen Resten aus Alkoholen nativen Ursprungs mit 12 bis 18 C-Atomen, zum Beispiel aus Kokos-, Palm-, Talgfett- oder Oleylalkohol, und durchschnittlich 2 bis 8 EO pro Mol Alkohol bevorzugt. Zu den bevorzugten ethoxylierten Alkoholen gehören beispielsweise C12-C14-Alkohole mit 3 EO, 4 EO oder 7 EO, C9-11-Alkohol mit 7 EO, C13-15-Alkohole mit 3 EO, 5 EO, 7 EO oder 8 EO, C12-18-Alkohole mit 3 EO, 5 EO oder 7 EO und Mischungen aus diesen, wie Mischungen aus C12-14-Alkohol mit 3 EO und C12-16-Alkohol mit 7 EO. Die angegebenen Ethoxylierungsgrade stellen statistische Mittelwerte dar, die für ein spezielles Produkt eine ganze oder eine gebrochene Zahl sein können. Bevorzugte Alkoholethoxylate weisen eine eingeengte Homologverteilung auf (narrow range ethoxylates, NRE). Zusätzlich zu diesen nichtionischen Tensiden können auch Fettalkohole mit mehr als 12 EO eingesetzt werden. Beispiele hierfür sind Talgfettalkohol mit 14 EO, 25 EO, 30 EO oder 40 EO. Auch nichtionische Tenside, die EO-und PO-Gruppen zusammen im Molekül enthalten, sind erfindungsgemäß einsetzbar. Hierbei können Blockcopolymere mit EO-PO-Blockeinheiten bzw. PO-EO-Blockeinheiten eingesetzt werden, aber auch EO-PO-EO-Copolymere bzw. PO-EO-PO-Copolymere. Selbstverständlich sind auch gemischt alkoxylierte Niotenside einsetzbar, in denen EO- und PO-Einheiten nicht blockweise, sondern statistisch verteilt sind. Solche Produkte sind durch gleichzeitige Einwirkung von Ethylen- und Propylenoxid auf Fettalkohole erhältlich.The nonionic surfactants used are preferably alkoxylated, advantageously ethoxylated, in particular primary, alcohols having preferably 8 to 18 carbon atoms and on average 1 to 12 moles of ethylene oxide (EO) per mole of alcohol, in which the alcohol radical can be linear or preferably methyl-branched in the 2-position or linear and methyl-branched radicals in the mixture can contain, as they are usually present in Oxoalkoholresten. In particular, however, alcohol ethoxylates with linear radicals of alcohols of native origin having 12 to 18 carbon atoms, for example of coconut, palm, tallow or oleyl alcohol, and on average 2 to 8 EO per mole of alcohol are preferred. Preferred ethoxylated alcohols include, for example, C 12 -C 14 alcohols with 3 EO, 7 EO or 4 EO, C9-11 alcohol containing 7 EO, C 13-15 alcohols containing 3 EO, 5 EO, 7 EO or 8 EO, C 12-18 alcohols with 3 EO, 5 EO or 7 EO and mixtures of these, such as mixtures of C 12-14 -alcohol with 3 EO and C 12-16 -alcohol with 7 EO. The degrees of ethoxylation given represent statistical means which, for a particular product, may be an integer or a fractional number. Preferred alcohol ethoxylates have a narrow homolog distribution (narrow range ethoxylates, NRE). In addition to these nonionic surfactants, fatty alcohols with more than 12 EO can also be used. Examples include tallow fatty alcohol with 14 EO, 25 EO, 30 EO or 40 EO. Nonionic surfactants which contain EO and PO groups together in the molecule can also be used according to the invention. Here, block copolymers with EO-PO block units or PO-EO block units can be used, but also EO-PO-EO copolymers or PO-EO-PO copolymers. Of course, mixed alkoxylated nonionic surfactants can be used in which EO and PO units are not blockwise, but are statistically distributed. Such products are available by the simultaneous action of ethylene and propylene oxide on fatty alcohols.
Außerdem können als weitere nichtionische Tenside auch Alkylglykoside der allgemeinen Formel RO(G)x eingesetzt werden, in der R einen primären geradkettigen oder methylverzweigten, insbesondere in 2-Stellung methylverzweigten aliphatischen Rest mit 8 bis 22, vorzugsweise 12 bis 18 C-Atomen bedeutet und G das Symbol ist, das für eine Glykoseeinheit mit 5 oder 6 C-Atomen, vorzugsweise für Glucose, steht. Der Oligomerisierungsgrad x, der die Verteilung von Monoglykosiden und Oligoglykosiden angibt, ist eine beliebige Zahl zwischen 1 und 10; vorzugsweise liegt x bei 1,2 bis 1,4. Alkylglykoside sind bekannte, milde Tenside.In addition, as further nonionic surfactants and alkyl glycosides of the general formula RO (G) x can be used in which R is a primary straight-chain or methyl-branched, especially in the 2-position methyl-branched aliphatic radical having 8 to 22, preferably 12 to 18 carbon atoms and G is the symbol which represents a glycose unit having 5 or 6 C atoms, preferably glucose. The degree of oligomerization x, which indicates the distribution of monoglycosides and oligoglycosides, is any number between 1 and 10; preferably x is 1.2 to 1.4. Alkyl glycosides are known, mild surfactants.
Eine weitere Klasse bevorzugt eingesetzter nichtionischer Tenside, die entweder als alleiniges nicht-ionisches Tensid oder in Kombination mit anderen nichtionischen Tensiden eingesetzt werden, sind alkoxylierte, vorzugsweise ethoxylierte oder ethoxylierte und propoxylierte Fettsäurealkylester, vorzugsweise mit 1 bis 4 Kohlenstoffatomen in der Alkylkette, insbesondere Fettsäuremethylester.Another class of preferred nonionic surfactants used either as the sole nonionic surfactant or in combination with other nonionic surfactants are alkoxylated, preferably ethoxylated or ethoxylated and propoxylated fatty acid alkyl esters, preferably having from 1 to 4 carbon atoms in the alkyl chain, especially fatty acid methyl esters.
Auch nichtionische Tenside vom Typ der Aminoxide, beispielsweise N-Kokosalkyl-N,N-dimethylaminoxid und N-Talgalkyl-N,N-dihydroxyethylaminoxid, und der Fettsäurealkanolamide können geeignet sein. Die Menge dieser nichtionischen Tenside beträgt vorzugsweise nicht mehr als die der ethoxylierten Fettalkohole, insbesondere nicht mehr als die Hälfte davon.Nonionic surfactants of the amine oxide type, for example N-cocoalkyl-N, N-dimethylamine oxide and N-tallowalkyl-N, N-dihydroxyethylamine oxide, and the fatty acid alkanolamides may also be suitable. The amount of these nonionic surfactants is preferably not more than that of the ethoxylated fatty alcohols, especially not more than half thereof.
Weitere geeignete Tenside sind Polyhydroxyfettsäureamide der Formel (VII),
Zur Gruppe der Polyhydroxyfettsäureamide gehören auch Verbindungen der Formel (VIII),
[Z] wird vorzugsweise durch reduktive Aminierung eines Zuckers erhalten, beispielsweise Glucose, Fructose, Maltose, Lactose, Galactose, Mannose oder Xylose. Die N-Alkoxy- oder N-Aryloxy-substituierten Verbindungen können dann durch Umsetzung mit Fettsäuremethylestern in Gegenwart eines Alkoxids als Katalysator in die gewünschten Polyhydroxyfettsäureamide überführt werden.[Z] is preferably obtained by reductive amination of a sugar, for example glucose, fructose, maltose, lactose, galactose, mannose or xylose. The N-alkoxy- or N-aryloxy-substituted compounds can then be converted into the desired polyhydroxy fatty acid amides by reaction with fatty acid methyl esters in the presence of an alkoxide as catalyst.
Der Gehalt an nichtionischen Tensiden beträgt in den Wasch- oder Reinigungsmitteln bevorzugt 5 bis 30 Gew.-%, vorzugsweise 7 bis 20 Gew.-% und insbesondere 9 bis 15 Gew.-%, jeweils bezogen auf das gesamte Wasch- oder Reinigungsmittel.The content of nonionic surfactants in the detergents or cleaners is preferably 5 to 30 wt .-%, preferably 7 to 20 wt .-% and in particular 9 to 15 wt .-%, each based on the total detergent or cleaning agent.
Als anionische Tenside werden beispielsweise solche vom Typ der Sulfonate und Sulfate eingesetzt. Als Tenside vom Sulfonat-Typ kommen dabei vorzugsweise C9-13-Alkylbenzolsulfonate, Olefinsulfonate, d.h. Gemische aus Alken- und Hydroxyalkansulfonaten sowie Disulfonaten, wie man sie beispielsweise aus C12-16-Monoolefinen mit end- oder innenständiger Doppelbindung durch Sulfonieren mit gasförmigem Schwefeltrioxid und anschließende alkalische oder saure Hydrolyse der Sulfonierungsprodukte erhält, in Betracht Geeignet sind auch Alkansulfonate, die aus C12-18-Alkanen beispielsweise durch Sulfochlorierung oder Sulfoxidation mit anschließender Hydrolyse bzw. Neutralisation gewonnen werden. Ebenso sind auch die Ester von α-Sulfofettsäuren (Estersulfonate), zum Beispiel die α-sulfonierten Methylester der hydrierten Kokos-, Palmkern- oder Talgfettsäuren geeignet.As anionic surfactants, for example, those of the sulfonate type and sulfates are used. The surfactants of the sulfonate type are preferably C 9-13 -alkylbenzenesulfonates, olefinsulfonates, ie mixtures of alkene and hydroxyalkanesulfonates and disulfonates, as are obtained, for example, from C 12-16 -monoolefins having terminal or internal double bonds by sulfonation with gaseous sulfur trioxide Also suitable are alkanesulfonates which are obtained from C 12-18 -alkanes, for example by sulfochlorination or sulfoxidation with subsequent hydrolysis or neutralization. Likewise suitable are the esters of α-sulfo fatty acids (ester sulfonates), for example the α-sulfonated methyl esters of hydrogenated coconut, palm kernel or tallow fatty acids.
Weitere geeignete Aniontenside sind sulfierte Fettsäureglycerinester. Unter Fettsäureglycerinestern sind die Mono-. Di- und Triester sowie deren Gemische zu verstehen, wie sie bei der Herstellung durch Veresterung von einem Monoglycerin mit 1 bis 3 Mol Fettsäure oder bei der Umesterung von Triglyceriden mit 0,3 bis 2 Mol Glycerin erhalten werden. Bevorzugte sulfierte Fettsäureglycerinester sind dabei die Sulfierprodukte von gesättigten Fettsäuren mit 6 bis 22 Kohlenstoffatomen, beispielsweise der Capronsäure, Caprylsäure, Caprinsäure, Myristinsäure, Laurinsa̅ure, Palmitinsäure, Stearinsäure oder Behensäure.Further suitable anionic surfactants are sulfated fatty acid glycerol esters. Among fatty acid glycerol esters are the mono-. To understand di- and triesters and their mixtures as they obtained in the preparation by esterification of a monoglycerol with 1 to 3 moles of fatty acid or in the transesterification of triglycerides with 0.3 to 2 moles of glycerol. Preferred sulfated fatty acid glycerol esters are the sulfonation products of saturated fatty acids having 6 to 22 carbon atoms, for example caproic acid, caprylic acid, capric acid, myristic acid, lauric acid, palmitic acid, stearic acid or behenic acid.
Als Alk(en)ylsulfate werden die Alkali- und insbesondere die Natriumsalze der Schwefelsäurehalbester der C12-C16-Fettalkohole, beispielsweise aus Kokosfettalkohol, Talgfettalkohol, Lauryl-, Myristyl-, Cetyl- oder Stearylalkohol oder der C10-C20-Oxoalkohole und diejenigen Halbester sekundärer Alkohole dieser Kettenlängen bevorzugt. Weiterhin bevorzugt sind Alk(en)ylsulfate der genannten Kettenlänge, welche einen synthetischen, auf petrochemischer Basis hergestellten geradkettigen Alkylrest enthalten, die ein analoges Abbauverhalten besitzen wie die adäquaten Verbindungen auf der Basis von fettchemischen Rohstoffen. Aus waschtechnischem Interesse sind die C12-C16-Alkylsulfate und C12-C15-Alkylsulfate sowie C14-C15-Alkylsulfate bevorzugt. Auch 2,3-Alkylsulfate, welche als Handelsprodukte der Shell Oil Company unter dem Namen DANⓂ erhalten werden können, sind geeignete Aniontenside.Alk (en) ylsulfates are the alkali metal salts and in particular the sodium salts of the sulfuric monoesters of C 12 -C 16 fatty alcohols, for example coconut fatty alcohol, tallow fatty alcohol, lauryl, myristyl, cetyl or stearyl alcohol or the C 10 -C 20 oxo alcohols and those half-esters of secondary alcohols of these chain lengths are preferred. Also preferred are alk (en) ylsulfates of said chain length, which contain a synthetic, produced on a petrochemical basis straight-chain alkyl radical, which have an analogous degradation behavior as the adequate compounds based on oleochemical raw materials. Of washing technology interest, the C 12 -C 16 alkyl sulfates and C 12 -C 15 alkyl sulfates and C 14 -C 15 alkyl sulfates are preferred. Also 2,3-alkyl sulfates, which can be obtained as commercial products of Shell Oil Company under the name DAN Ⓜ , are suitable anionic surfactants.
Auch die Schwefelsäuremonoester der mit 1 bis 6 Mol Ethylenoxid ethoxylierten geradkettigen oder verzweigten C7-21-Alkahole, wie 2-Methyl-verzweigte C9-11-Alkohole mit im Durchschnitt 3,5 Mol Ethylenoxid (EO) oder C12-16-Fettalkohole mit 1 bis 4 EO, sind geeignet. Sie werden in Reinigungsmitteln aufgrund ihres hohen Schaumverhaltens nur in relativ geringen Mengen, beispielsweise in Mengen von 1 bis 5 Gew.-%, eingesetzt.Also the sulfuric acid monoesters of the straight-chain or branched C 7-21 -alkahoxyls ethoxylated with 1 to 6 mol of ethylene oxide, such as 2-methyl-branched C 9-11- alcohols having on average 3.5 mol of ethylene oxide (EO) or C 12-16 Fatty alcohols with 1 to 4 EO are suitable. Due to their high foaming behavior, they are only used in detergents in relatively small amounts, for example in amounts of from 1 to 5% by weight.
Weitere geeignete Aniontenside sind auch die Salze der Alkylsulfobernsteinsäure, die auch als Sulfosuccinate oder als Sulfobernsteinsäureester bezeichnet werden und die Monoester und/oder Diester der Sulfobernsteinsäure mit Alkoholen, vorzugsweise Fettalkoholen und insbesondere ethoxylierten Fettalkoholen darstellen. Bevorzugte Sulfosuccinate enthalten C6-18-Fettalkoholreste oder Mischungen aus diesen. Insbesondere bevorzugte Sulfosuccinate enthalten einen Fettalkoholrest, der sich von ethoxylierten Fettalkoholen ableitet, die für sich betrachtet nichtionische Teside darstellen. Dabei sind wiederum Sulfosuccinate, deren Fettalkohol-Reste sich von ethoxylierten Fettalkoholen mit eingeengter Homologenverteilung ableiten, besonders bevorzugt. Ebenso ist es auch möglich, Alk(en)ylbernsteinsäure mit vorzugsweise 8 bis 18 Kohlenstoffatomen in der Alk(en)ylkette oder deren Salze einzusetzen.Further suitable anionic surfactants are also the salts of alkylsulfosuccinic acid, which are also referred to as sulfosuccinates or as sulfosuccinic acid esters and the monoesters and / or diesters of sulfosuccinic acid with alcohols, preferably fatty alcohols and in particular ethoxylated fatty alcohols. Preferred sulfosuccinates contain C 6-18 fatty alcohol residues or mixtures of these. Particularly preferred sulfosuccinates contain a fatty alcohol residue derived from ethoxylated fatty alcohols, which by themselves are nonionic tesides. Sulfosuccinates, whose fatty alcohol residues are derived from ethoxylated fatty alcohols with a narrow homolog distribution, are again particularly preferred. Likewise, it is also possible to use alk (en) ylsuccinic acid having preferably 8 to 18 carbon atoms in the alk (en) yl chain or salts thereof.
Insbesondere bevorzugte anionische Tenside sind Seifen. Geeignet sind gesättigte und ungesättigte Fettsäureseifen, wie die Salze der Laurinsäure, Myristinsäure, Palmitinsäure, Stearinsäure, (hydrierten) Erucasäure und Behensäure sowie insbesondere aus natürlichen Fettsäuren, zum Beispiel Kokos-, Palmkern-, Olivenöl- oder Talgfettsäuren, abgeleitete Seifengemische.Particularly preferred anionic surfactants are soaps. Suitable are saturated and unsaturated fatty acid soaps, such as the salts of lauric acid, myristic acid, palmitic acid, stearic acid, (hydrogenated) erucic acid and behenic acid and, in particular, soap mixtures derived from natural fatty acids, for example coconut, palm kernel, olive oil or tallow fatty acids.
Die anionischen Tenside einschließlich der Seifen können in Form ihrer Natrium-, Kalium- oder Ammoniumsalze sowie als lösliche Salze organischer Basen, wie Mono-, Di- oder Triethanolamin, vorliegen. Vorzugsweise liegen die anionischen Tenside in Form ihrer Natrium- oder Kaliumsalze, insbesondere in Form der Natriumsalze vor.The anionic surfactants, including the soaps, may be in the form of their sodium, potassium or ammonium salts and as soluble salts of organic bases, such as mono-, di- or triethanolamine. The anionic surfactants are preferably present in the form of their sodium or potassium salts, in particular in the form of the sodium salts.
Der Gehalt bevorzugter Wasch- oder Reinigungsmittel an anionischen Tensiden beträgt 2 bis 30 Gew.-%, vorzugsweise 4 bis 25 Gew.-% und insbesondere 5 bis 22 Gew.-%, jeweils bezogen auf das gesamte Wasch- oder Reinigungsmittel.The content of preferred detergents or cleaning agents to anionic surfactants is 2 to 30 wt .-%, preferably 4 to 25 wt .-% and in particular 5 to 22 wt .-%, each based on the total washing or cleaning agent.
Zusätzlich zu der Textil-pflegenden Zusammensetzung und den Tensiden können die Wasch- oder Reinigungsmittel weitere Inhaltsstoffe enthalten, die die anwendungstechnischen und/oder ästhetischen Eigenschaften des Wasch- oder Reinigungsmittel s weiter verbessern. Im Rahmen der vorliegenden Erfindung enthalten bevorzugte Wasch- oder Reinigungsmittel zusätzlich einen oder mehrere Stoffe aus der Gruppe der Gerüststoff, Bleichmittel, Bleichaktivatoren, Enzyme, Parfüme, Parfümträger, Fluoreszenzmittel, Farbstoffe, Schauminhibitoren, Silikonöle, Antiredepositionsmittel, optischen Aufheller, Vergrauungsinhibitoren, Einlaufverhinderer, Knitterschutzmittel, Farbübertragungsinhibitoren, antimikrobiellen Wirkstoffe, Germizide, Fungizide, Antioxidantien, Konservierungsmittel, Korrosionsinhibitoren, Antistatika, Bittermittel, Bügelhilfsmittel, Phobier- und Imprägniermittel, Quell- und Schiebefestmittel, neutrale Füllsalze sowie UV-Absorber.In addition to the textile-care composition and the surfactants, the detergents or cleaning agents may contain further ingredients which further improve the performance and / or aesthetic properties of the washing or cleaning agent s. In the context of the present invention, preferred washing or cleaning agents additionally contain one or more substances from the group of builders, bleaches, bleach activators, enzymes, perfumes, perfume carriers, fluorescers, dyes, foam inhibitors, silicone oils, antiredeposition agents, optical brighteners, grayness inhibitors, anti-shrinkage agents, anti-crease agents , Color transfer inhibitors, antimicrobial agents, germicides, fungicides, antioxidants, preservatives, corrosion inhibitors, antistatic agents, bittering agents, ironing aids, repellents and impregnating agents, swelling and anti-slip agents, neutral filler salts and UV absorbers.
Als Gerüststoffe, die in den Wasch- oder Reinigungsmitteln enthalten sein können, sind insbesondere Silikate, Aluminiumsilikate (insbesondere Zeolithe), Carbonate, Salze organischer Di- und Polycarbonsäuren sowie Mischungen dieser Stoffe zu nennen.Suitable builders which may be present in the detergents or cleaners are in particular silicates, aluminum silicates (in particular zeolites), carbonates, salts of organic di- and polycarboxylic acids and mixtures of these substances.
Geeignete kristalline, schichtförmige Natriumsilikate besitzen die allgemeine Formel NaMSixO2x+1 H2O, wobei M Natrium oder Wasserstoff bedeutet, x eine Zahl von 1,9 bis 4 und y eine Zahl von 0 bis 20 ist und bevorzugte Werte für x 2, 3 oder 4 sind. Bevorzugte kristalline Schichtsilikate der angegebenen Formel sind solche, in denen M für Natrium steht und x die Werte 2 oder 3 annimmt Insbesondere sind sowohl ß- als auch δ-Natriumdisilikate Na2Si2O5 · yH2O bevorzugt.Suitable crystalline layered sodium silicates have the general formula NaMSi x O 2x + 1 H 2 O, where M is sodium or hydrogen, x is a number from 1.9 to 4 and y is a number from 0 to 20 and preferred values for x 2 , 3 or 4 are. Preferred crystalline layer silicates corresponding to the above formula are those in which M is sodium and x assumes the value 2 or 3. In particular, both .beta.- and δ-sodium Na 2 Si 2 O 5 · yH 2 O preferred.
Einsetzbar sind auch amorphe Natriumsilikate mit einem Modul Na2O : SiO2 von 1 : 2 bis 1 : 3,3, vorzugsweise von 1 : 2 bis 1 : 2,8 und insbesondere von 1 : 2 bis 1 : 2,6, welche löseverzögert sind und Sekundärwascheigenschaften aufweisen. Die Löseverzögerung gegenüber herkömmlichen amorphen Natriumsilikaten kann dabei auf verschiedene Weise, beispielsweise durch Oberflächenbehandlung, Compoundierung, Kompaktierung/ Verdichtung oder durch Übertrocknung hervorgerufen worden sein. Im Rahmen dieser Erfindung wird unter dem Begriff "amorph" auch "röntgenamorph" verstanden. Dies heißt, dass die Silikate bei Röntgenbeugungsexperimenten keine scharfen Röntgenreflexe liefern, wie sie für kristalline Substanzen typisch sind, sondern allenfalls ein oder mehrere Maxima der gestreuten Röntgenstrahlung, die eine Breite von mehreren Gradeinheiten des Beugungswinkels aufweisen. Es kann jedoch sehr wohl sogar zu besonders guten Buildereigenschaften führen, wenn die Silikatpartikel bei Elektronenbeugungsexperimenten verwaschene oder sogar scharfe Beugungsmaxima liefern. Dies ist so zu interpretieren, dass die Produkte mikrokristalline Bereiche der Größe 10 bis einige Hundert nm aufweisen, wobei Werte bis maximal 50 nm und insbesondere bis maximal 20 nm bevorzugt sind. Insbesondere bevorzugt sind verdichtete/kompaktierte amorphe Silikate, compoundierte amorphe Silikate und übertrocknete röntgenamorphe Silikate.It is also possible to use amorphous sodium silicates with a Na 2 O: SiO 2 modulus of from 1: 2 to 1: 3.3, preferably from 1: 2 to 1: 2.8 and in particular from 1: 2 to 1: 2.6, which Delayed and have secondary washing properties. The dissolution delay compared with conventional amorphous sodium silicates may have been caused in various ways, for example by surface treatment, compounding, compaction / densification or by overdrying. In the context of this invention, the term "amorphous" is also understood to mean "X-ray amorphous". This means that the silicates do not yield sharp X-ray reflections typical of crystalline substances in X-ray diffraction experiments, but at most one or more maxima of the scattered X-rays which have a width of several degrees of diffraction angle. However, it may well even lead to particularly good builder properties if the silicate particles provide blurred or even sharp diffraction maxima in electron diffraction experiments. This is to be interpreted as meaning that the products have microcrystalline regions of size 10 to a few hundred nm, with values of up to a maximum of 50 nm and in particular up to a maximum of 20 nm being preferred. Particularly preferred are compacted / compacted amorphous silicates, compounded amorphous silicates and overdried X-ray amorphous silicates.
Der eingesetzte feinkristalline, synthetische und gebundenes Wasser enthaltende Zeolith ist vorzugsweise Zeolith A und/oder P. Als Zeolith P wird Zeolith MAP® (Handelsprodukt der Firma Crosfield) besonders bevorzugt. Geeignet sind jedoch auch Zeolith X sowie Mischungen aus A, X und/oder P. Kommerziell erhältlich und im Rahmen der vorliegenden Erfindung bevorzugt einsetzbar ist beispielsweise auch ein Co-Kristallisat aus Zeolith X und Zeolith A (ca. 80 Gew.-% Zeolith X), das von der Firma SASOL unter dem Markennamen VEGOBOND AX® vertrieben wird und durch die Formel
nNa2O · (1-n)K2O · Al2O3 · (2 - 2,5)SiO2 · (3,5 - 5,5) H2O
n = 0,90 - 1,0
beschrieben werden kann. Der Zeolith kann als sprühgetrocknetes Pulver oder auch als ungetrocknete, von ihrer Herstellung noch feuchte, stabilisierte Suspension zum Einsatz kommen. Für den Fall, dass der Zeolith als Suspension eingesetzt wird, kann diese geringe Zusätze an nichtionischen Tensiden als Stabilisatoren enthalten, beispielsweise 1 bis 3 Gew.-%, bezogen auf Zeolith, an ethoxylierten C12-C18-Fettalkoholen mit 2 bis 5 Ethylenoxidgruppen, C12-C14-Fettalkoholen mit 4 bis 5 Ethylenoxidgruppen oder ethoxylierten Isotridecanolen, Geeignete Zeolithe weisen eine mittlere Teilchengröße von weniger als 10 µm (Volumenverteilung; Meßmethode:The finely crystalline, synthetic and bound water-containing zeolite used is preferably zeolite A and / or P. As zeolite P, zeolite MAP® (commercial product from Crosfield) is particularly preferred. Also suitable, however, are zeolite X and mixtures of A, X and / or P. Commercially available and preferably usable in the context of the present invention is, for example, a cocrystal of zeolite X and zeolite A (about 80% by weight of zeolite X) ) marketed by the company SASOL under the brand name VEGOBOND AX® and by the formula
nNa 2 O • (1-n) K 2 O • Al 2 O 3 • (2 - 2.5) SiO 2 • (3.5-5.5) H 2 O
n = 0.90 - 1.0
can be described. The zeolite can be used as a spray-dried powder or else as undried, still moist, stabilized suspension of its preparation. In the event that the zeolite is used as a suspension, it may contain minor additions of nonionic surfactants as stabilizers, for example 1 to 3 wt .-%, based on zeolite, of ethoxylated C 12 -C 18 fatty alcohols having 2 to 5 ethylene oxide groups , C 12 -C 14 -fatty alcohols having 4 to 5 ethylene oxide groups or ethoxylated isotridecanols, suitable zeolites have an average particle size of less than 10 microns (volume distribution;
Coulter Counter) auf und enthalten vorzugsweise 18 bis 22 Gew.-%, insbesondere 20 bis 22 Gew.-% an gebundenem Wasser.Coulter Counter) and preferably contain 18 to 22 wt .-%, in particular 20 to 22 wt .-% of bound water.
Selbstverständlich ist auch ein Einsatz der allgemein bekannten Phosphate als Buildersubstanzen möglich, sofern ein derartiger Einsatz nicht aus ökologischen Gründen vermieden werden sollte. Geeignet sind insbesondere die Natriumsalze der Orthophosphate, der Pyrophosphate und insbesondere der Tripolyphosphate.Of course, a use of the well-known phosphates as builders is possible, unless such use should not be avoided for environmental reasons. Particularly suitable are the sodium salts of orthophosphates, pyrophosphates and in particular tripolyphosphates.
Organische Builder, welche in dem Wasch- oder Reinigungsmittel vorhanden sein können, umfassen Polycarboxylatpolymere wie Polyacrylate und Acrylsäure/Maleinsäure-Copolymere, Polyaspartate und monomere Polycarboxylate wie Citrate, Gluconate, Succinate oder Malonate, die bevorzugt als Natriumsalze eingesetzt werden.Organic builders that may be present in the detergent or cleaning agent include polycarboxylate polymers such as polyacrylates and acrylic acid / maleic acid copolymers, polyaspartates and monomeric polycarboxylates such as citrates, gluconates, succinates or malonates, which are preferably used as the sodium salts.
Unter den als Bleichmittel dienenden, in Wasser H2O2 liefernden Verbindungen haben das Natriumperborattetrahydrat und das Natriumperboratmonohydrat besondere Bedeutung. Weitere brauchbare Bleichmittel sind beispielsweise Natriumpercarbonat, Peroxypyrophosphate, Citratperhydrate sowie H2O2 liefernde persaure Salze oder Persäuren, wie Perbenzoate, Peroxophthalate, Diperazelainsäure, Phthaloiminopersäure oder Diperdodecandisäure.Among the compounds serving as bleaches in water H 2 O 2 , sodium perborate tetrahydrate and sodium perborate monohydrate are of particular importance. Other useful bleaching agents are, for example, sodium percarbonate, peroxypyrophosphates, citrate perhydrates and H 2 O 2 -producing peracidic salts or peracids, such as perbenzoates, peroxophthalates, diperazelaic acid, phthaloiminoperacid or diperdodecanedioic acid.
Um beim Waschen bei Temperaturen von 60°C und darunter eine verbesserte Bleichwirkung zu erreichen, können Bleichaktivatoren in die Wasch- oder Reinigungsmittel eingearbeitet werden. Als Bleichaktivatoren können Verbindungen, die unter Perhydrolysebedingungen aliphatische Peroxocarbonsäuren mit vorzugsweise 1 bis 10 C-Atomen, insbesondere 2 bis 4 C-Atomen, und/oder gegebenenfalls substituierte Perbenzoesäure ergeben, eingesetzt werden. Geeignet sind Substanzen, die O- und/oder N-Acylgruppen der genannten C-Atomzahl und/oder gegebenenfalls substituierte Benzoylgruppen tragen. Bevorzugt sind mehrfach acylierte Alkylendiamine, insbesondere Tetraacetylethylendiamin (TAED), acylierte Triazinderivate, insbesondere 1,5-Diacetyl-2,4-dioxohexahydro-1,3,5-triazin (DADHT), acylierte Glykolurile, insbesondere Tetraacetylglykoluril (TAGU), N-Acylimide, insbesondere N-Nonanoylsuccinimid (NOSI), acylierte Phenolsulfonate, insbesondere n-Nonanoyl- oder Isononanoyloxybenzolsulfonat (n-bzw. iso-NOBS), Carbonsäureanhydride, insbesondere Phthalsäureanhydrid, acylierte mehrwertige Alkohole, insbesondere Triacetin, Ethylenglykoldiacetat und 2,5-Diacetoxy-2,5-dihydrofuran.In order to achieve an improved bleaching effect when washing at temperatures of 60 ° C and below, bleach activators can be incorporated into the detergents or cleaners. As bleach activators, it is possible to use compounds which, under perhydrolysis conditions, give aliphatic peroxycarboxylic acids having preferably 1 to 10 C atoms, in particular 2 to 4 C atoms, and / or optionally substituted perbenzoic acid. Suitable substances are those which carry O- and / or N-acyl groups of the stated C atom number and / or optionally substituted benzoyl groups. Preference is given to polyacylated alkylenediamines, in particular tetraacetylethylenediamine (TAED), acylated triazine derivatives, in particular 1,5-diacetyl-2,4-dioxohexahydro-1,3,5-triazine (DADHT), acylated glycolurils, in particular tetraacetylglycoluril (TAGU), N- Acylimides, in particular N-nonanoylsuccinimide (NOSI), acylated phenolsulfonates, in particular n-nonanoyl or isononanoyloxybenzenesulfonate (n-iso-NOBS), carboxylic anhydrides, in particular phthalic anhydride, acylated polyhydric alcohols, in particular triacetin, ethylene glycol diacetate and 2,5-diacetoxy- 2,5-dihydrofuran.
Zusätzlich zu den konventionellen Bleichaktivatoren oder an deren Stelle können auch sogenannte Bleichkatalysatoren in die Wasch- oder Reinigungsmittel eingearbeitet werden. Bei diesen Stoffen handelt es sich um bleichverstärkende Übergangsmetallsalze bzw. Übergangsmetallkomplexe wie beispielsweise Mn-, Fe-, Co-, Ru- oder Mo-Salenkomplexe oder-carbonylkomplexe. Auch Mn-, Fe-, Co-, Ru-, Mo-, Ti-, V- und Cu-Komplexe mit stickstoffhaltigen Tripod-Liganden sowie Co-, Fe-, Cu- und Ru-Amminkomplexe sind als Bleichkatalysatoren verwendbar.In addition to the conventional bleach activators or in their place also so-called bleach catalysts can be incorporated into the detergents or cleaning agents. For these substances are bleach-enhancing transition metal salts or transition metal complexes such as Mn, Fe, Co, Ru or Mo-salene complexes or carbonyl complexes. Mn, Fe, Co, Ru, Mo, Ti, V and Cu complexes with nitrogen-containing tripod ligands and Co, Fe, Cu and Ru ammine complexes can also be used as bleach catalysts.
Das Wasch- oder Reinigungsmittel kann Enzyme in verkapselter Form und/oder direkt in dem Wasch- oder Reinigungsmittel enthalten. Als Enzyme kommen insbesondere solche aus der Klassen der Hydrolasen wie der Proteasen, Esterasen, Lipasen bzw, lipolytisch wirkende Enzyme, Amylasen, Cellulasen bzw. andere Glykosylhydrolasen, Hemicellulase, Cutinasen, β-Glucanasen, Oxidasen, Peroxidasen, Perhydrolasen, Mannanasen und/oder Laccasen und Gemische der genannten Enzyme in Frage. Alle diese Hydrolasen tragen in der Wäsche zur Entfernung von Verfleckungen wie protein-, fett- oder stärkehaltigen Verfleckungen und Vergrauungen bei. Cellulasen und andere Glykosylhydrolasen können darüber hinaus durch das Entfernen von Pilling und Mikrofibrillen zur Farberhaltung und zur Erhöhung der Weichheit des Textils beitragen. Zur Bleiche bzw. zur Hemmung der Farbübertragung können auch Oxireduktasen eingesetzt werden. Besonders gut geeignet sind aus Bakterienstämmen oder Pilzen wie Bacillus subtilis, Bacillus licheniformis, Streptomyces griseus und Humicola insolens gewonnene enzymatische Wirkstoffe. Vorzugsweise werden Proteasen vom Subtilisin-Typ und insbesondere Proteasen, die aus Bacillus lentus gewonnen werden, eingesetzt. Dabei sind Enzymmischungen, beispielsweise aus Protease und Amylase oder Protease und Lipase bzw. lipolytisch wirkenden Enzymen oder Protease und Cellulase oder aus Cellulase und Lipase bzw. lipolytisch wirkenden Enzymen oder aus Protease, Amylase und Lipase bzw. lipolytisch wirkenden Enzymen oder Protease, Lipase bzw. lipolytisch wirkenden Enzymen und Cellulase, insbesondere jedoch Protease und/oder Lipase-haltige Mischungen bzw. Mischungen mit lipolytisch wirkenden Enzymen von besonderem Interesse. Beispiele für derartige lipolytisch wirkende Enzyme sind die bekannten Cutinasen. Auch Peroxidasen oder Oxidasen haben sich in einigen Fällen als geeignet erwiesen. Zu den geeigneten Amylasen zahlen insbesondere α-Amylasen, Iso-Amylasen, Pullulanasen und Pektinasen. Als Cellulasen werden vorzugsweise Cellobiohydrolasen, Endoglucanasen und β-Glucosidasen, die auch Cellobiasen genannt werden, bzw. Mischungen aus diesen eingesetzt Da sich verschiedene Cellulase-Typen durch ihre CMCase- und Avicelase-Aktivitäten unterscheiden, können durch gezielte Mischungen der Cellulasen die gewünschten Aktivitäten eingestellt werden.The washing or cleaning agent may contain enzymes in encapsulated form and / or directly in the washing or cleaning agent. Suitable enzymes include in particular those from the classes of hydrolases such as proteases, esterases, lipases or lipolytic enzymes, amylases, cellulases or other glycosyl hydrolases, hemicellulases, cutinases, β-glucanases, oxidases, peroxidases, perhydrolases, mannanases and / or laccases and mixtures of said enzymes in question. All of these hydrolases in the wash contribute to the removal of stains such as proteinaceous, greasy or starchy stains and graying. In addition, cellulases and other glycosyl hydrolases may contribute to color retention and to enhancing the softness of the fabric by removing pilling and microfibrils. Oxireductases can also be used for bleaching or inhibiting color transfer. Particularly suitable are enzymatic agents obtained from bacterial strains or fungi such as Bacillus subtilis, Bacillus licheniformis, Streptomyces griseus and Humicola insolens. Preferably, subtilisin-type proteases and in particular proteases derived from Bacillus lentus are used. In this case, enzyme mixtures, for example from protease and amylase or protease and lipase or lipolytic enzymes or protease and cellulase or from cellulase and lipase or lipolytic enzymes or from protease, amylase and lipase or lipolytic enzymes or protease, lipase or lipolytic enzymes and cellulase, but in particular protease and / or lipase-containing mixtures or mixtures with lipolytic enzymes of particular interest. Examples of such lipolytic enzymes are the known cutinases. Peroxidases or oxidases have also proved suitable in some cases. In particular, α-amylases, iso-amylases, pullulanases and pectinases pay particular attention to the suitable amylases. Cellulases used are preferably cellobiohydrolases, endoglucanases and β-glucosidases, which are also called cellobiases, or mixtures thereof. Since different types of cellulases differ in their CMCase and avicelase activities, targeted mixtures of the cellulases can set the desired activities become.
Die Enzyme können an Trägerstoffe adsorbiert sein, um sie gegen vorzeitige Zersetzung zu schützen. Der Anteil der Enzyme oder der Enzymgranulate direkt in dem Wasch- oder Reinigungsmittel kann beispielsweise etwa 0,01 bis 5 Gew.-%, vorzugsweise 0,12 bis etwa 2,5 Gew.-% betragen.The enzymes may be adsorbed to carriers to protect against premature degradation. The proportion of enzymes or enzyme granules directly in the washing or cleaning agent may for example be about 0.01 to 5 wt .-%, preferably 0.12 to about 2.5 wt .-% amount.
Es kann, beispielsweise bei speziellen Wasch- oder Reinigungsmitteln für Konsumenten mit Allergien und/oder sensibler Haut, aber auch bevorzugt sein, dass das Wasch- oder Reinigungsmittel keine Enzyme enthält.However, it may also be preferred, for example in the case of special detergents or cleaners for consumers with allergies and / or sensitive skin, that the washing or cleaning agent contains no enzymes.
In einer Ausführungsform enthalt das Wasch- oder Reinigungsmittel gegebenenfalls ein oder mehrere Parfüms in einer Menge von üblicherweise bis 10 Gew.-%, vorzugsweise 0,5 bis 7 Gew.-%, insbesondere 1 bis 3 Gew.-%. Dabei ist die Menge an eingesetztem Parfüm auch von der Art des Wasch- oder Reinigungsmittels abhängig. Es ist aber insbesondere bevorzugt, dass das Parfüm über die Textil-weichmachende Zusammensetzung in das Wasch- oder Reinigungsmittel eingebracht wird. Es ist allerdings auch möglich, dass das Wasch- oder Reinigungsmittel Parfüm enthält, welches nicht Ober die Textil-weichmachende Zusammensetzung in das Wasch- oder Reinigungsmittel eingebracht wird.In one embodiment, the washing or cleaning agent optionally contains one or more perfumes in an amount of usually up to 10 wt .-%, preferably 0.5 to 7 wt .-%, in particular 1 to 3 wt .-%. The amount of perfume used is also dependent on the type of detergent or cleaning agent. However, it is particularly preferred that the perfume is introduced into the washing or cleaning agent via the textile softening composition. However, it is also possible for the washing or cleaning agent to contain perfume which is not introduced into the washing or cleaning agent above the textile softening composition.
Um den ästhetischen Eindruck der Wasch- oder Reinigungsmittel zu verbessern, können sie (gegebenenfalls auch nur teilweise) mit geeigneten Farbstoffen eingefärbt werden. Bevorzugte Farbstoffe, deren Auswahl dem Fachmann keinerlei Schwierigkeit bereitet, besitzen eine hohe Lagerstabilität und Unempfindlichkeit gegenüber den übrigen Inhaltsstoffen der Wasch- oder Reinigungsmittel und gegen Licht sowie keine ausgeprägte Substantivität gegenüber Textilfasern, um diese nicht anzufärben.In order to improve the aesthetic impression of the detergents or cleaners, they may (optionally only partially) be colored with suitable dyes. Preferred dyes, the selection of which presents no difficulty to the skilled person, have a high storage stability and insensitivity to the other ingredients of detergents or cleaning agents and to light and no pronounced substantivity to textile fibers so as not to stain them.
Als Schauminhibitoren, die in den Wasch- oder Reinigungsmitteln eingesetzt werden können, kommen beispielsweise Seifen, Paraffine oder Silikonöle in Betracht, die gegebenenfalls auf Trägermaterialien aufgebracht sein können.Suitable foam inhibitors which can be used in the detergents or cleaners are, for example, soaps, paraffins or silicone oils, which may optionally be applied to support materials.
Geeignete Soil-Release-Polymere, die auch als "Antiredepositionsmittel" bezeichnet werden, sind beispielsweise nichtionische Celluloseether wie Methylcellulose und Methylhydroxypropylcellulose mit einem Anteil an Methoxygruppen von 15 bis 30 Gew,-% und an Hydroxypropylgruppen von 1 bis 15 Gew.-%, jeweils bezogen auf den nichtionischen Celluloseether sowie die aus dem Stand der Technik bekannten Polymere der Phthalsäure und/oder Terephthalsäure bzw. von deren Derivaten, insbesondere Polymere aus Ethylenterephthalaten und/oder Polyethylen- und/oder Polypropylenglykolterephthalaten oder anionisch und/oder nichtionisch modifizierten Derivaten von diesen. Geeignete Derivate umfassen die sulfonierten Derivate der Phthalsäure- und Terephthalsäure-Polymere. Eine weitere Klasse an geeigneten Soil-Release-Polymeren, insbesondere für Baumwoll-haltige Textilien, stellen modifizierte, beispielsweise alkoxylierte und/oder quatemierte und/oder oxidierte, Polyamine dar. Die Polyamine sind beispielsweise Polyalkylenamine, wie Polyethylenamine, oder Polyalkylenimine, wie Polyethylenimine, Bevorzugte Beispiele für diese Klasse an Soil-Release-Polymeren sind ethoxylierte Polyethylenimine und ethoxylierte Polyethylenamine.Suitable soil release polymers, also referred to as "anti-redeposition agents", include, for example, nonionic cellulose ethers such as methyl cellulose and methyl hydroxypropyl cellulose having a methoxy group content of 15 to 30% by weight and hydroxypropyl groups of 1 to 15% by weight, respectively based on the nonionic cellulose ether and the known from the prior art polymers of phthalic acid and / or terephthalic acid or derivatives thereof, in particular polymers of ethylene terephthalates and / or polyethylene and / or polypropylene glycol terephthalates or anionic and / or nonionic modified derivatives thereof. Suitable derivatives include the sulfonated derivatives of the phthalic and terephthalic acid polymers. Another class of suitable soil-release polymers, in particular for cotton-containing textiles, are modified, for example alkoxylated and / or quaternized and / or oxidized, polyamines. The polyamines are, for example, polyalkyleneamines, such as polyethyleneamines, or polyalkylenimines, such as polyethylenimines, Preferred examples of this class of soil release polymers are ethoxylated polyethylenimines and ethoxylated polyethyleneamines.
Optische Aufheller (sogenannte "Weißtöner") können den Wasch- oder Reinigungsmitteln zugesetzt werden, um Vergrauungen und Vergilbungen der behandelten Textilen Flächengebilden zu beseitigen. Diese Stoffe ziehen auf die Faser auf und bewirken eine Aufhellung und vorgetäuschte Bleichwirkung, indem sie unsichtbare Ultraviolettstrahlung in sichtbares längerwelliges Licht umwandeln, wobei das aus dem Sonnenlicht absorbierte ultraviolette Licht als schwach bläuliche Fluoreszenz abgestrahlt wird und mit dem Gelbton der vergrauten bzw. vergilbten Wäsche reines Weiß ergibt. Geeignete Verbindungen stammen beispielsweise aus den Substanzklassen der 4,4'-Diamino-2,2'-stilbendisultonsäuren (Flavonsäuren), 4,4'-Distyryl-biphenylen, Methylumbelliferone, Cumarine, Dihydrochinolinone, 1,3-Diarylpyrazoline, Naphthalsäureimide, Benzoxazol-, Benzisoxazol- und Benzimidazol-Systeme sowie der durch Heterocyclen substituierten Pyrenderivate. Die optischen Aufheller werden üblicherweise in Mengen zwischen 0 und 0,3 Gew.-%, bezogen auf das fertige Wasch- oder Reinigungsmittel, eingesetzt.Optical brighteners (so-called "whiteners") can be added to the detergents or cleaners to eliminate graying and yellowing of the treated textile fabrics. These fabrics impinge on the fiber and cause whitening and bleaching by transforming invisible ultraviolet radiation into visible longer wavelength light, emitting the ultraviolet light absorbed from the sunlight as faint bluish fluorescence, and pure with the yellowness of the grayed or yellowed wash White results. Suitable compounds are derived, for example, from the substance classes of 4,4'-diamino-2,2'-stilbenedisultonic acids (flavonic acids), 4,4'-distyrylbiphenyls, methylumbelliferones, coumarins, dihydroquinolinones, 1,3-diarylpyrazolines, naphthalic acid imides, benzoxazole , Benzisoxazole and benzimidazole systems as well as heterocyclic substituted pyrene derivatives. The optical brighteners are usually used in amounts of from 0 to 0.3% by weight, based on the finished detergent or cleaning agent.
Vergrauungsinhibitoren haben die Aufgabe, den von der Faser abgelösten Schmutz in der Flotte suspendiert zu halten und so das Wederaufziehen des Schmutzes zu verhindern. Hierzu sind wasserlosliche Kolloide meist organischer Natur geeignet, beispielsweise Leim, Gelatine, Salze von Ethersulfonsäuren der Stärke oder der Cellulose oder Salze von sauren Schwefelsäureestem der Cellulose oder der Stärke. Auch wasserlösliche, saure Gruppen enthaltende Polyamide sind für diesen Zweck geeignet. Weiterhin lassen sich lösliche Stärkepräparate und andere als die obengenannten Stärkeprodukte verwenden, zum Beispiel abgebaute Stärke, Aldehydstärken usw. Auch Polyvinylpyrrolidon ist brauchbar. Bevorzugt werden jedoch Celluloseether wie Carboxymethylcellulose (Na-Salz), Methylcellulose, Hydroxyalkylcellulose und Mischether wie Methylhydroxyethylcellulose, Methylhydroxypropylcellulose, Methylcarboxymethylcellulose und deren Gemische in Mengen von 0,1 bis 5 Gew.-%, bezogen auf die Wasch- oder Reinigungsmittel, eingesetzt.Graying inhibitors have the task of keeping suspended from the fiber debris suspended in the fleet and so prevent the Nederaufziehen the dirt. Water-soluble colloids of mostly organic nature are suitable for this purpose, for example glue, gelatine, salts of ether sulfonic acids or cellulose or salts of acidic sulfuric acid esters of cellulose or starch. Also, water-soluble polyamides containing acidic groups are suitable for this purpose. It is also possible to use soluble starch preparations and starch products other than those mentioned above, for example degraded starch, aldehyde starches, etc. Polyvinylpyrrolidone is also useful. However, preference is given to using cellulose ethers such as carboxymethylcellulose (Na salt), methylcellulose, hydroxyalkylcellulose and mixed ethers such as methylhydroxyethylcellulose, methylhydroxypropylcellulose, methylcarboxymethylcellulose and mixtures thereof in amounts of from 0.1 to 5% by weight, based on the washing or cleaning agents.
Um während des Waschens und/oder des Reinigens von gefärbten Textilien die Farbstoffablösung und/oder die Farbstoffübertragung auf andere Textilien wirksam zu unterdrücken, kann das Wasch- oder Reinigungsmittel einen Farbübertragungsinhibitor enthalten. Es ist bevorzugt, dass der Farbübertragungsinhibitor ein Polymer oder Copolymer von cyclischen Aminen wie beispielsweise Vinylpyrrolidon und/oder Vinylimidazol ist. Als Farbübertragungsinhibitor geeignete Polymere umfassen Polyvinylpyrrolidon (PVP), Polyvinylimidazol (PVI), Copolymere von Vinylpyrrolidon und Vinylimidazol (PVP/PVI), Polyvinylpyridin-N-oxid, Poly-N-carboxymethyl-4-vinylpyridiumchlorid sowie Mischungen daraus. Besonders bevorzugt werden Polyvinylpyrrolidon (PVP), Polyvinylimidazol (PVI) oder Copolymere von Vinylpyrrolidon und Vinylimidazol (PVP/PVI) als Farbübertragungsinhibitor eingesetzt. Die eingesetzten Polyvinylpyrrolidone (PVP) besitzen bevorzugt ein mittleres Molekular gewicht von 2.500 bis 400.000 und sind kommerziell von ISP Chemicals als PVP K 15, PVP K 30, PVP K 60 oder PVP K 90 oder von der BASF als Sokalan® HP 50 oder Sokalan® HP 53 erhältlich. Die eingesetzten Copolymere von Vinylpyrrolidon und Vinylimidazol (PVP/PVI) weisen vorzugsweise ein Molekulargewicht im Bereich von 5.000 bis 100.000 auf. Kommerziell erhältlich ist ein PVP/PVI-Copolymer beispielsweise von der BASF unter der Bezeichnung Sokalan® HP 56.In order to effectively suppress dye release and / or dye transfer to other fabrics during washing and / or cleaning of dyed fabrics, the washing or cleaning agent may contain a dye transfer inhibitor. It is preferred that the dye transfer inhibitor is a polymer or copolymer of cyclic amines such as Vinylpyrrolidone and / or vinylimidazole is. Suitable color transfer inhibiting polymers include polyvinylpyrrolidone (PVP), polyvinylimidazole (PVI), copolymers of vinylpyrrolidone and vinylimidazole (PVP / PVI), polyvinylpyridine-N-oxide, poly-N-carboxymethyl-4-vinylpyridium chloride, and mixtures thereof. Particular preference is given to using polyvinylpyrrolidone (PVP), polyvinylimidazole (PVI) or copolymers of vinylpyrrolidone and vinylimidazole (PVP / PVI) as color transfer inhibitor. The polyvinylpyrrolidones (PVP) used preferably have an average molecular weight of 2,500 to 400,000 and are commercially available from ISP Chemicals as PVP K 15, PVP K 30, PVP K 60 or PVP K 90 or from BASF as Sokalan® HP 50 or Sokalan® HP 53 available. The copolymers of vinylpyrrolidone and vinylimidazole (PVP / PVI) used preferably have a molecular weight in the range from 5,000 to 100,000. Commercially available is a PVP / PVI copolymer, for example from BASF under the name Sokalan® HP 56th
Die Menge an Farbübertragungsinhibitor bezogen auf die Gesamtmenge des Wasch- oder Reinlgungsmittel liegt bevorzugt von 0,01 bis 2 Gew.-%, vorzugsweise von 0,05 bis 1 Gew.-% und mehr bevorzugt von 0,1 bis 0,5 Gew.-%.The amount of dye transfer inhibitor based on the total amount of the detergent is preferably from 0.01 to 2% by weight, preferably from 0.05 to 1% by weight, and more preferably from 0.1 to 0.5% by weight. -%.
Alternativ können aber auch enzymatische Systeme, umfassend eine Peroxidase und Wasserstoffperoxid beziehungsweise eine in Wasser Wasserstoffperoxid-liefernde Substanz als Farbübertragungsinhibitor eingesetzt werden. Der Zusatz einer Mediatorverbindung für die Peroxidase, zum Beispiel eines Acetosyringons, eines Phenolderivats oder eines Phenotiazins oder Phenoxazins, ist in diesem Fall bevorzugt, wobei auch zusätzlich die obengenannten polymeren Farbübertragunginhibitoren eingesetzt werden können.Alternatively, however, it is also possible to use enzymatic systems comprising a peroxidase and hydrogen peroxide or a substance which produces hydrogen peroxide in water as a color transfer inhibitor. The addition of a mediator compound for the peroxidase, for example an acetosyringone, a phenol derivative or a phenotiazine or phenoxazine, is preferred in this case, whereby the abovementioned polymeric color transfer inhibitors may additionally be used.
Da textile Flächengebilde, insbesondere aus Reyon, Zellwolle, Baumwolle und deren Mischungen, zum Knittern neigen können, weil die Einzelfasern gegen Durchbiegen, Knicken, Pressen und Quetschen quer zur Faserrichtung empfindlich sind, können die Wasch- oder Reinigungsmittel synthetische Knitterschutzmittel enthalten. Hierzu zählen beispielsweise synthetische Produkte auf der Basis von Fettsäuren, Fettsäureestern, Fettsäureamiden, -alkylolestern, -alkylolamiden oder Fettalkoholen, die meist mit Ethylenoxid umgesetzt sind, oder Produkte auf der Basis von Lecithin oder modifizierter Phosphorsäureester.Since textile fabrics, in particular of rayon, rayon, cotton and their mixtures, can tend to wrinkle, because the individual fibers are sensitive to bending, buckling, pressing and squeezing transverse to the fiber direction, the detergents or cleaning agents may contain synthetic crease inhibitors. These include, for example, synthetic products based on fatty acids, fatty acid esters, fatty acid amides, alkylol esters, -alkylolamides or fatty alcohols, which are usually reacted with ethylene oxide, or products based on lecithin or modified phosphoric acid ester.
Zur Bekämpfung von Mikroorganismen können die Wasch- oder Reinigungsmittel antimikrobielle Wirkstoffe enthalten. Hierbei unterscheidet man je nach antimikrobiellem Spektrum und Wirkungsmechanismus zwischen Bakteriostatika und Bakteriziden, Fungistatika und Fungiziden usw.To combat microorganisms washing or cleaning agents may contain antimicrobial agents. Depending on the antimicrobial spectrum and mechanism of action, a distinction is made between bacteriostats and bactericides, fungistatics and fungicides, etc.
Wichtige Stoffe aus diesen Gruppen sind beispielsweise Benzalkoniumchloride, Alkylarylsulfonate, Halogenphenole und Phenolmercuriacetat, wobei bei den erfindungemäßen Wasch- oder Reinigungsmitteln auch gänzlich auf diese Verbindungen verzichtet werden kann.Important substances from these groups are, for example, benzalkonium chlorides, alkylarylsulfonates, halophenols and phenol mercuriacetate, it also being possible entirely to dispense with these compounds in the detergents or cleaners according to the invention.
Die erfindungsgemäßen Wasch- oder Reinigungsmittel können Konservierungsmittel enthalten, wobei vorzugsweise nur solche eingesetzt werden, die kein oder nur ein geringes hautsensibilisierendes Potential besitzen. Beispiele sind Sorbinsäure und seine Salze, Benzoesäure und seine Salze, Salicylsäure und seine Salze, Phenoxyethanol, 3-lod-2-propynylbutylcarbamat, Natrium N-(hydroxymethyl)glycinat, Biphenyl-2-ol sowie Mischungen davon. Ein geeignetes Konservierungsmittel stellt die Iösungsmittelfrele, wassrige Kombination von Diazolldinylharnstoff, Natriumbenzoat und Kaliumsorbat (erhältlich als Euxyl® K 500 ex Schuelke & Mayr) dar, welches in einem pH-Bereich bis 7 eingesetzt werden kann.The detergents or cleaners according to the invention may contain preservatives, it being preferred to use only those which have no or only a low skin-sensitizing potential. Examples are sorbic acid and its salts, benzoic acid and its salts, salicylic acid and its salts, phenoxyethanol, 3-iodo-2-propynyl butylcarbamate, sodium N- (hydroxymethyl) glycinate, biphenyl-2-ol and mixtures thereof. A suitable preservative is the solvent mixture, aqueous combination of diazolidinyl urea, sodium benzoate and potassium sorbate (available as Euxyl® K 500 ex Schuelke & Mayr), which can be used in a pH range up to 7.
Um unerwünschte, durch Sauerstoffeinwirkung und andere oxidative Prozesse verursachte Veränderungen an den Wasch- oder Reinigungsmittel und/oder den behandelten textilen Flächengebilden zu verhindern, können die Wasch- oder Reinigungsmittel Antioxidantien enthalten. Zu dieser. Verbindungsklasse gehören beispielsweise substituierte Phenole, Hydrochinone, Benzcatechine und aromatische Amine sowie organische Sulfide, Polysulfide, Dithiocarbamate, Phosphite, Phosphonate und Vitamin E.In order to prevent undesirable changes to the detergents or cleaners and / or the treated fabrics caused by the action of oxygen and other oxidative processes, the detergents or cleaners may contain antioxidants. To this. Class of compounds include, for example, substituted phenols, hydroquinones, catechols and aromatic amines, as well as organic sulfides, polysulfides, dithiocarbamates, phosphites, phosphonates and vitamin E.
Ein erhöhter Tragekomfort kann aus der zusätzlichen Verwendung von Antistatika resultieren, die den Wasch- oder Reinigungsmitteln beigefügt werden. Antistatika vergrößern die Oberfiächenleitfähigkeit und ermöglichen damit ein verbessertes Abfließen gebildeter Ladungen. Äußere Antistatika sind in der Regel Substanzen mit wenigstens einem hydrophilen Molekülliganden und geben auf den Oberflächen einen mehr oder minder hygroskopischen Film. Diese zumeist grenzflächenaktiven Antistatika lassen sich in stickstoffhaltige (Amine, Amide, quartäre Ammoniumverbindungen), phosphorhaltige (Phosphorsäureester) und schwefelhaltige (Alkylsulfonate, Alkylsulfate) Antistatika unterteilen. Lauryl-(bzw, Stearyl-)dimethylbenzylammoniumchloride eignen sich als Antistatika für textile Flächengebilde bzw. als Zusatz zu Wasch- oder Reinigungsmitteln, wobei zusätzlich ein Avivageeffekt erzielt wird.Increased comfort may result from the additional use of antistatic agents added to the detergents or cleaners. Antistatic agents increase the surface conductivity and thus enable an improved outflow of formed charges. External antistatic agents are generally substances with at least one hydrophilic molecule ligand and give a more or less hygroscopic film on the surfaces. These mostly surface-active antistatic agents can be subdivided into nitrogen-containing (amines, amides, quaternary ammonium compounds), phosphorus-containing (phosphoric acid esters) and sulfur-containing (alkyl sulfonates, alkyl sulfates) antistatic agents. Lauryl (or, stearyl) dimethylbenzylammonium chlorides are suitable as antistatic agents for textile fabrics or as an additive to laundry detergents or cleaners, wherein additionally a softening effect is achieved.
Zur Verbesserung des der Wiederbenetzbarkeit der behandelten textilen Flächengebilde und zur Erleichterung des Bügelns der behandelten textilen Flächengebilde können in den Wasch- oder Reinigungsmitteln beispielsweise Silikonderivate eingesetzt werden. Diese verbessern zusätzlich das Ausspülverhalten der Wasch- oder Reinigungsmittel durch ihre schauminhibierendenTo improve the rewettability of the treated fabrics and to facilitate the ironing of the treated fabrics, for example, silicone derivatives can be used in the detergents or cleaners. These additionally improve the rinsing out of the washing or cleaning agents by their foam-inhibiting
Eigenschaften. Bevorzugte Silikonderivate sind beispielsweise Polydialkyl- oder Alkylarylsiloxane, bei denen die Alkylgruppen ein bis fünf C-Atome aufweisen und ganz oder teilweise fluoriert sind. Bevorzugte Silikone sind Polydimethylsiloxane, die gegebenenfalls derivatisiert sein können und dann aminofunktionell oder quaterniert sind bzw. Si-OH-, Si-H- und/oder Si-Cl-Bindungen aufweisen. Die Viskositäten der bevorzugten Silikone liegen bei 25°C im Bereich zwischen 100 und 100.000 mPas, wobei die Silikone in Mengen zwischen 0,2 und 5 Gew.-%, bezogen auf das gesamte Wasch- oder Reinigungsmittel eingesetzt werden können.Properties. Preferred silicone derivatives are, for example, polydialkyl or alkylaryl siloxanes in which the alkyl groups have one to five carbon atoms and are completely or partially fluorinated. Preferred silicones are polydimethylsiloxanes, which may optionally be derivatized and are then amino-functional or quaternized or have Si-OH, Si-H and / or Si-Cl bonds. The viscosities of the preferred silicones are in the range between 100 and 100,000 mPas at 25 ° C., wherein the silicones can be used in amounts of between 0.2 and 5% by weight, based on the total detergent or cleaning agent.
Schließlich können die Wasch- oder Reinigungsmittel auch UV-Absorber enthalten, die auf die behandelten textilen Flächengebilde aufziehen und die Lichtbeständigkeit der Fasern verbessern. Verbindungen, die diese gewünschten Eigenschaften aufweisen, sind beispielsweise die durch strahlungslose Desaktivierung wirksamen Verbindungen und Derivate des Benzophenons mit Substituenten in 2- und/oder 4-Stellung. Weiterhin sind auch substituierte Benzotriazole, in 3-Stellung Phenyl-substituierte Acrylate (Zimtsäurederivate), gegebenenfalls mit Cyanogruppen in 2-Stellung, Salicylate, organische Ni-Komplexe sowie Naturstoffe wie Umbelliferon und die körpereigene Urocansäure geeignet.Finally, the detergents or cleaners may also contain UV absorbers which are applied to the treated fabrics and improve the light fastness of the fibers. Compounds having these desired properties include, for example, the non-radiative deactivating compounds and derivatives of benzophenone having substituents in the 2- and / or 4-position. Also suitable are substituted benzotriazoles, phenyl-substituted acrylates (cinnamic acid derivatives) in the 3-position, optionally with cyano groups in the 2-position, salicylates, organic Ni complexes and natural substances such as umbelliferone and the body's own urocanic acid.
Um die durch Schwermetalle katalysierte Zersetzung bestimmter Waschmittel-Inhaltsstoffe zu vermeiden, können Stoffe eingesetzt werden, die Schwermetalle komplexieren. Geeignete Schwermetallkomplexbildner sind beispielsweise die Alkalisalze der Ethylendiamintetraessigsäure (EDTA) oder der Nitrilotriessigsäure (NTA) sowie Alkalimetallsalze von anionischen Polyelektrolyten wie Polymaleaten und Polysulfonaten.In order to avoid the catalyzed by heavy metals decomposition of certain detergent ingredients, substances that complex heavy metals can be used. Suitable heavy metal complexing agents are, for example, the alkali metal salts of ethylenediaminetetraacetic acid (EDTA) or nitrilotriacetic acid (NTA) and alkali metal salts of anionic polyelectrolytes such as polymaleates and polysulfonates.
Eine bevorzugte Klasse von Komplexbildnern sind die Phosphonate, die in bevorzugten Wasch- oder Reinigungsmittel in Mengen von 0,01 bis 2,5 Gew.-%, vorzugsweise 0,02 bis 2 Gew.-% und insbesondere von 0,03 bis 1,5 Gew.-% enthalten sind. Zu diesen bevorzugten Verbindungen zählen insbesondere Organophosphonate wie beispielsweise 1-Hydroxyethan-1,1-diphosphonsäure (HEDP), Aminotri(methylenphosphonsäure) (ATMP), Diethylentriamin-penta(methylenphosphonsäure) (DTPMP bzw. DETPMP) sowie 2-Phosphonobutan-1,2,4-tricarbonsäure (PBS-AM), die zumeist in Form ihrer Ammonium- oder Alkalimetallsalze eingesetzt werden.A preferred class of complexing agents are the phosphonates, which in preferred detergents or cleaners in amounts of 0.01 to 2.5 wt .-%, preferably 0.02 to 2 wt .-% and in particular from 0.03 to 1, 5 wt .-% are included. These preferred compounds include in particular organophosphonates such as 1-hydroxyethane-1,1-diphosphonic acid (HEDP), aminotri (methylenephosphonic acid) (ATMP), diethylenetriamine penta (methylenephosphonic acid) (DTPMP or DETPMP) and 2-phosphonobutane-1,2 , 4-tricarboxylic acid (PBS-AM), which are used mostly in the form of their ammonium or alkali metal salts.
Zusätzlich können noch neutrale Füllsalze wie Natriumsulfat oder Natriumbicarbonat in dem festen Wasch- oder Reinigungsmittel enthalten sein.In addition, neutral fillers such as sodium sulfate or sodium bicarbonate may be included in the solid detergent or cleaner.
Die erfindungsgemäßen Wasch- oder Reinigungsmittel können insbesondere zum Reinigen und Konditionieren von textilen Flächengebilden verwendet werden.The washing or cleaning agents according to the invention can be used in particular for cleaning and conditioning textile fabrics.
Zur Herstellung der erfindungsgemäßen Wasch- oder Reinigungsmittel wird zunächst das Wasch- oder Reinigungsmittel ohne die Textil-pflegende Verbindung nach bekannten Verfahren, welche beispielsweise Tröcknungsschritte, Mischungsschritte, Verdichtungsschritte, Formgebungsschritte und/oder die nachträgliche Zugabe wärmeempfindlicher Inhaltsstoffe ("Post Addition") umfassen können, hergestellt. Anschließend wird das erhaltene Produkt mit einer erfindungsgemäßen festen, Textil-pflegenden Zusammensetzung vermischt. Zur Herstellung von Wasch- oder Reinigungsmittelformkörpern können sich dem Mischungsschritt weitere Verdichtungs- und/oder Formgebungsschritte anschließen.To prepare the detergents or cleaners according to the invention, the washing or cleaning agent without the textile-care compound is first prepared by known processes, which may include, for example, topping steps, mixing steps, densification steps, shaping steps and / or the subsequent addition of heat-sensitive ingredients ("post-addition") , produced. Subsequently, the resulting product is mixed with a solid, textile-care composition according to the invention. For the preparation of detergent tablets, the mixing step may be followed by further compaction and / or shaping steps.
In Tabelle 1 sind erfindungsgemäße Textil-pflegende Zusammensetzungen E2 bis E5 gezeigt.
Zum Vergleich der Duftintensität eines herkömmlichen flüssigen Weichspülers (Gehalt an Textilweichmachendem Diesterquat: 15 Gew.-%) mit den festen, Textil-pflegenden Zusammensetzungen E2 bis E5 wurde Frotteegewebe einerseits mit einem festem, im Handel erhältlichen Waschmittel und dem herkömmlichen Weichspüler sowie andererseits mit dem selben Waschmittel und jeweils den festen Textil-pflegenden Zusammensetzungen E2 bis E5 in einer Waschmaschine (Miele Novotronic W 985) behandelt. Nach hängender Trocknung wurde die Duftintensität bestimmt. In allen Fallen (an feuchter, frisch gewaschener Wäsche, an getrockneter Wäsche nach einem Tag und an getrockneter Wäsche nach sieben Tagen) war die Duftintensität bei der Behandlung mit den erfindungsgemaßen Textil-pflegenden Zusammensetzungen E2 bis E5 stärker als bei der Behandlung mit dem herkömmlichen Weichspüler.To compare the scent intensity of a conventional liquid softener (content of fabric softening diester quat: 15 wt .-%) with the solid textile care compositions E2 to E5 terry fabric was on the one hand with a solid, commercially available detergent and the conventional softener and on the other hand with the the same detergent and each of the solid textile-care compositions E2 to E5 in a washing machine (Miele Novotronic W 985) treated. After hanging drying, the intensity of the scent was determined. In all cases (on wet, freshly washed laundry, on dried laundry after one day and on dry laundry after seven days), the intensity of the fragrance in the treatment with the textile-care compositions E2 to E5 according to the invention was greater than in the case of the treatment with the conventional fabric softener ,
Weiterhin zeigten die erfindungsgemäßen Textil-pflegenden Zusammensetzungen im Vergleich mit Wasser einen weichmachenden Effekt (die mit Wasser bzw. Textil-pflegender Zusammensetzung behandelten Gewebe wurden dazu nach der Behandlung und hängender Trocknung von einem Panel bestehend aus 5 Personen abgegriffen). Zusätzlich sind die erfindungsgemäßen Textil-pflegenden Zusammensetzungen in der Lage, die Härte von Wasser zu reduzieren. Dazu wurde zunächst die Härte von Leitungswasser mittels Analysestäbchen "Gesamthärtetest" (Fa. Merck) gemäß den Vorschriften des Herstellers bestimmt. Anschließend wurden dem Leitungswasser die erfindungsgemäße feste Textil-pflegende Zusammensetzung E2 in einer Konzentration, wie sie in den Vorschriften des Herstellers angegeben ist, zugefügt und die Härte des Wassers bestimmt. Die Wasserhärte wurde von 16 °dH auf 3 °dH reduziert.Furthermore, the textile-care compositions according to the invention exhibited a softening effect in comparison with water (the fabrics treated with water or textile-care composition were tapped after treatment and hanging drying from a panel consisting of 5 persons). In addition, the fabric care compositions of the present invention are capable of reducing the hardness of water. For this purpose, first the hardness of tap water was determined by means of analysis sticks "total hardness test" (Merck) according to the manufacturer's instructions. The tap water was then added to the solid textile care composition E2 according to the invention in a concentration as specified in the manufacturer's instructions, and the hardness of the water was determined. The water hardness was reduced from 16 ° dH to 3 ° dH.
Zur Herstellung eines erfindungsgemäßen Wasch- oder Reinigungsmittels wurde ein festes, unparfümiertes Wasch- oder Reinigungsmittel mit 10 Gew.-% (bezogen auf die Gesamtmenge an fertigem Wasch- oder Reinigungsmittel) der Textil-pflegenden Zusammensetzung E2 gemischt.To prepare a washing or cleaning agent according to the invention, a solid, unscented washing or cleaning agent was mixed with 10% by weight (based on the total amount of finished washing or cleaning agent) of the textile-care composition E2 .
Das erfindungsgemäßen Wasch- oder Reinigungsmittel zeigte gute reinigende und konditionierende Eigenschaften.The washing or cleaning agent according to the invention showed good cleaning and conditioning properties.
Weder bei separater Verwendung der Textil-pflegenden Zusammensetzung noch eingebracht in einem Wasch- oder Reinigungsmittel wurden Kalkablagerungen auf der Wäsche und/oder Ablagerungen/Rückstände in der Einspülkammer der Waschmaschinen beobachtet.Lime deposits on the laundry and / or deposits / residues in the dispensing compartment of the washing machines were not observed either with separate use of the textile-care composition or incorporated in a washing or cleaning agent.
Claims (13)
- A solid, textile-care composition comprising a soap matrix, a textile-care compound distributed in said matrix and a perfume, wherein the soap matrix contains additional additives selected from the group consisting of polypropylene glycol, dipropylene glycol, ethylene glycol, diethylene glycol, 1,3-butylene glycol, 2,3-butylene glycol, sorbitol, glycerol, mannitol, glucose, sucrose, galactose, fructose, lactose, dextrose and mixtures thereof.
- The solid, textile-care composition according to claim 1, characterized in that the textile-care is selected from textile-softening compounds, bleaching agents, bleaching activators, enzymes, silicone oils, anti-redeposition agents, optical brighteners, graying inhibitors, shrinkage preventers, anti-crease agents, color-transfer inhibitors, antimicrobial active ingredients, germicides, fungicides, antioxidants, antistatic agents, ironing aids, waterproofing and impregnating agents, anti-swelling and anti-slip agents, UV absorbers and mixtures thereof.
- The solid, textile-care composition according to either claim 1 or claim 2, characterized in that the textile-care compound is a textile-softening compound.
- The solid, textile-care composition according to claim 3, characterized in that the textile-softening compound is selected from polysiloxanes, textile-softening clays, cationic polymers and mixtures thereof.
- The solid, textile-care composition according to one of claims 1 to 4, characterized in that the soap base contains sodium salts of fatty acids selected from the group consisting of palm oil fatty acids, palm kernel oil fatty acids, coconut fatty acids, peanut fatty acids, tallow fatty acids, stearic acid, oleic acid, soy fatty acids, olive oil fatty acids and mixtures thereof.
- The solid, textile-care composition according to one of claims 1 to 5, characterized in that the matrix of the solid, textile-care composition contains from 50 to 98 wt.%, preferably from 90 to 97 wt.%, soap.
- The solid, textile-care composition according to one of claims 1 to 6, characterized in that the perfume content is from 0.1 to 20 wt.%, preferably from 1 to 10 wt.%, and particularly preferably from 2 to 7 wt.%.
- The solid, textile-care composition according to one of claims 1 to 7, characterized in that the solid, textile-care composition is present in particulate form.
- The solid, textile-care composition according to claim 8, characterized in that the solid textile-care composition has particle sizes in the range of from 0.6 to 30 mm, in particular from 0.8 to 7 mm, and particularly preferably from 1 to 3 mm.
- A method for producing a solid, textile-care composition that comprises a soap matrix, additional additives selected from the group consisting of polypropylene glycol, dipropylene glycol, ethylene glycol, diethylene glycol, 1,3-butylene glycol, 2,3-butylene glycol, sorbitol, glycerol, mannitol, glucose, sucrose, galactose, fructose, lactose, dextrose and mixtures thereof, a textile-care compound distributed in said matrix and a perfume, in which the ingredients are mixed and the mixture obtained is then extruded through a rhombic perforated plate.
- The use of the solid, textile-care composition according to one of claims 1 to 9 for conditioning textile fabrics.
- A washing or cleaning agent comprising a solid, textile-care composition according to one of claims 1 to 9.
- The use of a washing or cleaning agent according to claim 12 for cleaning and conditioning textile fabrics.
Priority Applications (1)
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PL07726684T PL2029716T3 (en) | 2006-04-06 | 2007-03-07 | Solid textile care composition based on soap |
Applications Claiming Priority (2)
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DE102006016586A DE102006016586A1 (en) | 2006-04-06 | 2006-04-06 | Solid, soap-based textile softening composition |
PCT/EP2007/052126 WO2007115870A1 (en) | 2006-04-06 | 2007-03-07 | Solid textile care composition based on soap |
Publications (2)
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EP2029716A1 EP2029716A1 (en) | 2009-03-04 |
EP2029716B1 true EP2029716B1 (en) | 2016-07-13 |
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US (1) | US7989412B2 (en) |
EP (1) | EP2029716B1 (en) |
DE (1) | DE102006016586A1 (en) |
ES (1) | ES2596002T3 (en) |
PL (1) | PL2029716T3 (en) |
WO (1) | WO2007115870A1 (en) |
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DE102006016578A1 (en) * | 2006-04-06 | 2007-10-11 | Henkel Kgaa | Solid textile softening composition with a water-soluble polymer |
TR201007716A2 (en) * | 2010-09-21 | 2010-12-21 | Dalan Ki̇mya Endüstri̇ Anoni̇m Şi̇rketi̇ | Performance enhancing particles |
US20130065812A1 (en) * | 2011-09-14 | 2013-03-14 | Ecolab Usa Inc. | Water-dilutable solid concentrate |
JP6224474B2 (en) * | 2014-02-05 | 2017-11-01 | 川研ファインケミカル株式会社 | Bar soap composition |
ES2906189T3 (en) * | 2016-08-17 | 2022-04-13 | Zobele Holding Spa | Water-soluble tablet and method of manufacturing said water-soluble tablet |
US11441106B2 (en) | 2017-06-27 | 2022-09-13 | Henkel Ag & Co. Kgaa | Particulate fragrance enhancers |
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US3226329A (en) * | 1961-09-14 | 1965-12-28 | Procter & Gamble | Germicidal cleansing composition |
US3915882A (en) * | 1972-11-10 | 1975-10-28 | Procter & Gamble | Soap compositions |
US5206019A (en) * | 1989-05-30 | 1993-04-27 | Moleculon, Inc. | Soap compositions containing liquid-loaded powders |
FR2725456B1 (en) * | 1994-10-07 | 1996-12-27 | Rhone Poulenc Chimie | SOLID, GRANULAR COMPOSITION COMPRISING A LIQUID INGREDIENT EMBEDDED IN A SOLID MATRIX, METHOD OF PREPARATION AND USE IN A POWDER DETERGENT COMPOSITION |
DE19620792A1 (en) * | 1996-05-23 | 1997-11-27 | Zschimmer & Schwarz Gmbh & Co | Binary mixtures for making semi synthetic toilet soaps |
US6403543B1 (en) * | 2000-05-16 | 2002-06-11 | Original Bradford Soap Works, Inc. | Soap with suspended articles |
US20060234902A1 (en) * | 2005-04-19 | 2006-10-19 | Unilever Home & Personal Care Usa | Fabric care article and method |
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- 2006-04-06 DE DE102006016586A patent/DE102006016586A1/en not_active Withdrawn
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US7989412B2 (en) | 2011-08-02 |
WO2007115870A1 (en) | 2007-10-18 |
EP2029716A1 (en) | 2009-03-04 |
US20090099055A1 (en) | 2009-04-16 |
PL2029716T3 (en) | 2017-04-28 |
DE102006016586A1 (en) | 2007-10-11 |
ES2596002T3 (en) | 2017-01-04 |
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