CN106350284A - Laundry gel beads for washing real silk fabrics and preparation method of laundry gel beads - Google Patents
Laundry gel beads for washing real silk fabrics and preparation method of laundry gel beads Download PDFInfo
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- CN106350284A CN106350284A CN201610713215.7A CN201610713215A CN106350284A CN 106350284 A CN106350284 A CN 106350284A CN 201610713215 A CN201610713215 A CN 201610713215A CN 106350284 A CN106350284 A CN 106350284A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
- C11D1/831—Mixtures of non-ionic with anionic compounds of sulfonates with ethers of polyoxyalkylenes without phosphates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/08—Liquid soap, e.g. for dispensers; capsuled
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2041—Dihydric alcohols
- C11D3/2044—Dihydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2065—Polyhydric alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
- C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/008—Polymeric surface-active agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
- C11D1/721—End blocked ethers
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
Abstract
The invention relates to the field of detergents and particularly relates to laundry gel beads for washing real silk fabrics and a preparation method of the laundry gel beads. The laundry gel beads for washing the real silk fabrics are prepared from water-soluble films and cleaning fluid in the water-soluble films, wherein the cleaning fluid is prepared from the following ingredients: propylene glycol, sorbitol, glycerine, dodecylbenzene sulfonic acid, ethanolamine, a nonionic surfactant, cocinic acid, a maleic acid/acrylic acid copolymer, a chelating agent, a bactericide, quaternary ammonium salt organosiloxane, a color contamination preventive, deionized water, flavoring essence, an anticorrosive agent, a bitterant and enzymes. According to the product provided by the invention, the structure of real silk is protected during washing, and the bactericide and compliance ingredients form a protective film on the surface of the real silk, so that clothing is prevented from becoming mildewy or being damaged by worms during storage.
Description
Technical field
The present invention relates to detergent applications, more particularly to a kind of real silk fabric the washing solidifying pearl of laundry and its preparation side
Method.
Background technology
Traditional liquid detergent main active substances are linear dodecylbenzene sulfonate and other builders；Straight chain dodecane
Base benzene sulfonate derives from petroleum chemicals, belongs to non-renewable raw material, and this raw material is intolerant to hard water, goes down dirt in water environment from the beginning
Power substantially reduces, and is unfavorable for washing；Other auxiliary agents, 4a zeolite, such as sodium tripolyphosphate contain phosphorus, are unfavorable for environmental conservation；Aluminum is pure
Alkali, Caustic soda alkalescence are higher, so that medicated clothing is faded, damaging laundry；Natrii Sulfas belong to implant, and inefficient cycle utilizes, can be to operation band
Carry out unnecessary waste.Additionally, conventional liquid detergent utilizes conventional surfactants and alkaline assistant, only there is washing cleaning
Effect, submissive less effective.
It is many that Chinese invention patent application (application number cn201510437124.0 applying date 2015.07.23) discloses one kind
The solidifying pearl of function laundry, its weight percent composition includes: c14-16 alkene sulfonic acid sodium 30-35%, fatty alcohol-polyoxyethylene ether
(9eo) 15-20%, DBSA 10-12%, kation alkyl many glucosides 5-8%, disodiumedetate
0.01-0.03%, d- pantothenylol 1-2%, phenoxyethanol 0.3-0.7%, essence 0.1-0.3%, triclosan 0.05-0.1%, albumen
Enzyme 0.01-0.03%, balance of deionized water.This product has washing, nursing, sterilization, smelly eliminating, pleasant mental and body multi-efficiency,
Energy-saving and emission-reduction, easy to use.
Chinese invention patent application (application number cn201510436322.5 applying date 2015.07.23) discloses a kind of essence
Oil wash clothing coagulates pearl, and its weight percent composition includes: 20～25% c14-16 alkene sulfonic acid sodium, 15～20% poly alkyl alcohol
Oxygen vinyl Ether (9eo), 10～12% polyoxyethylenated alcohol sodium sulfate, 8～10% Laurel alcohol sulfuric ester triethanolamine
Salt, 2～4% Polyethylene Glycol, 1～3% many glucosides of kation alkyl, 1～2% d- pantothenylol, 0.3～0.7% benzene oxygen
Ethanol, 0.05～0.01% disodiumedetate, 0.5～1% jasmin quintessence oil, 0.05～0.1% triclosan,
0.1～0.2% protease, 0.002～0.005% red 33 pigments, balance of deionized water.This product has washing, shield
Reason, sterilization, smelly eliminating, pleasant mental and body multi-efficiency, easy to use.
Chinese invention patent application (application number cn201610216176.x applying date 2016.04.09) discloses a kind of soft
Along solidifying pearl of laundry and preparation method thereof, this laundry coagulate pearl include 25～35% isomery c13 fatty alcohol-polyoxyethylene ether, 10～20%
Fatty alcohol-polyoxyethylene ether (9eo), 10～20% polyoxyethylenated alcohol sodium sulfate, 5～10% fatty alcohol-polyoxyethylene ether
(7eo), 1.5～2.5% washing synergist wr, 1.5～2.5% isomeric alcohol polyethenoxy ether, 0.8～1.5% cation are submissive
Agent, 0.02～0.05% antibacterial, 0.5～1.0% microcapsule essence, 0.01-0.03% alkaline protease and 20～38% are molten
Agent (propylene glycol), this product have stronger tax fragrance, safe and convenient to use, washability and submissive effect preferable the features such as.
Above-mentioned various laundries are coagulated pearl and are had different formulations, also have different functions and effect simultaneously, solidifying with laundry
The popularization of pearl, to laundry, solidifying pearl has different demands it is therefore necessary to develop production to the product of subdivision for consumer.
Content of the invention
First purpose of the present invention is to provide a kind of real silk fabric washing laundry solidifying pearl, and pearl washing real silk is coagulated in this laundry
During its structure is protected, antibacterial and submissive composition form protecting film on real silk surface, prevent medicated clothing from depositing process
Middle generation is gone mouldy or is damaged by worms.Second object of the present invention is the preparation method providing above-mentioned laundry to coagulate pearl.
In order to realize above-mentioned first purpose, present invention employs following technical scheme:
A kind of real silk fabric washing, with the solidifying pearl of laundry, is made up of water soluble film and its interior cleanout fluid, quality hundred pressed by cleanout fluid
Divide and prepared by following component than meter:
Propylene glycol 9-23%
Sorbitol 2-9%
Glycerol 5-8%
DBSA 10-30%
Ethanolamine 3-10%
Nonionic surfactant 5-40%
Cocinic acid 5-15%
Maleic acid/acrylic copolymer 0.5-2%
Chelating agen 0.5-2%
Antibacterial 0.2-1%
Quaternary ammonium salt organosiloxane 0.4-1.5%
Anti- colour contamination agent 0.5-2.0%
Deionized water 3-20%
Essence 0.7-2%
Preservative 0.05-0.2%
Aversive agent 0.0001-0.02%
Enzyme 0.05-2%.
Preferably, this cleanout fluid is prepared by following component by mass percentage:
Propylene glycol 10-20%
Sorbitol 3-7%
Glycerol 6-7%
DBSA 15-25%
Ethanolamine 4-8%
Nonionic surfactant 10-35%
Cocinic acid 8-12%
Maleic acid/acrylic copolymer 0.8-1.5%
Chelating agen 0.8-1.5%
Antibacterial 0.2-1%
Quaternary ammonium salt organosiloxane 0.4-1.5%
Anti- colour contamination agent 0.5-2.0%
Deionized water 5-15%
Essence 0.8-1.5%
Preservative 0.05-0.2%
Aversive agent 0.0001-0.02%
Enzyme 0.1-1.5%.
Preferably, described content of propylene glycol 12-19%, and sorbitol content is in 2-5%.Product moisture-retaining capacity is
Good, content of propylene glycol increases, and water soluble film easily becomes dry, becomes fragile.
Preferably, the water content of cleanout fluid is in 8-18%, product appearance and optimal stability.Water content is little, water-soluble
Film easily becomes dry, becomes fragile, and water content is big, and product is softer, is easily broken.
Preferably, during ethanol content 0.6-2%, optimal to product solubilising and the impact to abnormal smells from the patient, content is little, and product holds
Easily muddy, content is many, can affect the taste of final products.
Preferably, described nonionic surfactant includes the polyoxyethylene ether of alkyl phenol, aliphatic alcohol polyethenoxy
One or more of ether, fatty acid methyl ester APEO and detergent 6501.Preferably, described fatty alcohol polyoxy second
Alkene ether selects polyoxyethylene lauryl ether, 12-14 carbon primary alconol polyoxyethylene ether, 12-14 carbon secondary alcohol polyoxyethylene ether, collateralization 13
Carbon Guerbet polyoxyethylenated alcohol, collateralization 10 carbon Guerbet polyoxyethylenated alcohol, 10 carbon polyoxyethylenated alcohol of straight chain,
One or more of 8 carbon capryl alcohol polyoxyethylene ether of straight chain, 8 carbon isooctanol polyethoxylate of straight chain.
Preferably, aeo-7:aeo-9=1.7:1-2.3:1 or aeo-9:aeo- in described nonionic surfactant
3=1:1.2 1:2；Described nonionic surfactant: DBSA=2:8-3:7.Above-mentioned formulation actives
The dirt-removing power brought is the strongest.
Ethanolamine is used for generating DBSA ethanolamine and cocinic acid ethanolamine.Preferably, described second
Hydramine selects one or more of monoethanolamine, triethanolamine, diethanolamine to mix.During neutralization DBSA,
Preferably select raw material to be ordered as: monoethanolamine, triethanolamine, diethanolamine.
Preferably, in benzoic acid, sodium benzoate, sorbic acid, potassium sorbate, calcium propionate selected by described preservative
Plant or multiple mixing.
Preferably, described aversive agent selects one of saccharin benzylamine amide and benzene first DEXAMETHASONE SODIUM PHOSPHATE ammonium or two kinds of mixing.
Preferably, described enzyme selects one or more of protease, Digestive Enzyme, amylase, cellulase to mix.
Preferably, described antibacterial adopts triclosan to compound with other.
Preferably, acylamide polymer is selected in described anti-colour contamination agent.
In order to realize above-mentioned second purpose, present invention employs following technical scheme:
A kind of method that pearl is coagulated in laundry prepared described in any one technical scheme above-mentioned, the method includes following step
Rapid:
1) propylene glycol, Sorbitol, glycerol, DBSA, monoethanolamine, nonionic surfactant, Cortex cocois radiciss are pressed
Oleic acid, maleic acid/acrylic copolymer, chelating agen order sequentially add raw material, when temperature is less than 50 DEG C, add antibacterial, season
Ammonium salt organosiloxane, anti-colour contamination agent, deionized water, essence, preservative, aversive agent and enzyme mixing；
2), after liquid is qualified, carry out water soluble film packaging.
Preferably, the optional material polyvinyl alcohol of described water soluble film, polyvinyl acetal, Polyvinylpyrrolidone,
Polyacrylic acid, maleic acid/acrylic copolymer, starch, gelatin, xanthan gum, guar gum, hydroxypropyl methyl cellulose, and with
One or more of the homopolymerization of upper composition, copolymer and altered contents mix.
The present invention, due to employing above-mentioned technical scheme, is compared with common aqueous based systems liquid detergent, can make active matter
Content dramatically increases (content is up to more than 80%), accomplishes the ultra concentration of real meaning, reduces packaging consumption, storage space and fortune
Defeated cost.During the product washing real silk of the present invention, its structure is protected, antibacterial and submissive composition are on real silk surface
Form protecting film, produce during preventing medicated clothing from depositing and go mouldy or damage by worms..
Specific embodiment
Embodiment 1
A kind of real silk fabric washing, with the solidifying pearl of laundry, is made up of water soluble film and its interior cleanout fluid, quality hundred pressed by cleanout fluid
Divide and prepared by following component than meter:
The method that pearl is coagulated in above-mentioned laundry, the method comprises the following steps:
1) propylene glycol, Sorbitol, glycerol, DBSA, monoethanolamine, nonionic surfactant, Cortex cocois radiciss are pressed
Oleic acid, maleic acid/acrylic copolymer, chelating agen order sequentially add raw material, when temperature is less than 50 DEG C, add antibacterial, season
Ammonium salt organosiloxane, anti-colour contamination agent, deionized water, essence, preservative, aversive agent and enzyme mixing；
2), after liquid is qualified, carry out water soluble film packaging.Manner of packing can be selected for water seal or heat-sealing.Water soluble film can be gathered material selection
Vinyl alcohol, polyvinyl acetal, Polyvinylpyrrolidone, polyacrylic acid, maleic acid/acrylic copolymer, starch, gelatin,
Xanthan gum, guar gum, hydroxypropyl methyl cellulose, and the homopolymerization of above composition, copolymer and altered contents.The composition of film can
To be the mixing of above single component or Multiple components.
Quantitative package of the present invention, easy to use, liquid will not be made to be stained with to hand；Reduce the waste in using；Concentrated formulations
Take less space in the family.Packaging uses water soluble film, in temperature 0-70 DEG C, can be all soluble in water in 4 minutes, no matter
Machine washing, hand washing, all easily.
Embodiment 2
A kind of real silk fabric washing, with the solidifying pearl of laundry, is made up of water soluble film and its interior cleanout fluid, quality hundred pressed by cleanout fluid
Divide and prepared by following component than meter:
The method that pearl is coagulated in above-mentioned laundry, the method comprises the following steps:
1) propylene glycol, Sorbitol, glycerol, DBSA, monoethanolamine, nonionic surfactant, Cortex cocois radiciss are pressed
Oleic acid, maleic acid/acrylic copolymer, chelating agen order sequentially add raw material, when temperature is less than 50 DEG C, add antibacterial, season
Ammonium salt organosiloxane, anti-colour contamination agent, deionized water, essence, preservative, aversive agent and enzyme mixing；
2), after liquid is qualified, carry out water soluble film packaging.Manner of packing can be selected for water seal or heat-sealing.Water soluble film can be gathered material selection
Vinyl alcohol, polyvinyl acetal, Polyvinylpyrrolidone, polyacrylic acid, maleic acid/acrylic copolymer, starch, gelatin,
Xanthan gum, guar gum, hydroxypropyl methyl cellulose, and the homopolymerization of above composition, copolymer and altered contents.The composition of film can
To be the mixing of above single component or Multiple components.
Embodiment 3
A kind of real silk fabric washing, with the solidifying pearl of laundry, is made up of water soluble film and its interior cleanout fluid, quality hundred pressed by cleanout fluid
Divide and prepared by following component than meter:
The method that pearl is coagulated in above-mentioned laundry, the method comprises the following steps:
1) propylene glycol, Sorbitol, glycerol, DBSA, monoethanolamine, nonionic surfactant, Cortex cocois radiciss are pressed
Oleic acid, maleic acid/acrylic copolymer, chelating agen order sequentially add raw material, when temperature is less than 50 DEG C, add antibacterial, season
Ammonium salt organosiloxane, anti-colour contamination agent, deionized water, essence, preservative, aversive agent and enzyme mixing；
2), after liquid is qualified, carry out water soluble film packaging.Manner of packing can be selected for water seal or heat-sealing.Water soluble film can be gathered material selection
Vinyl alcohol, polyvinyl acetal, Polyvinylpyrrolidone, polyacrylic acid, maleic acid/acrylic copolymer, starch, gelatin,
Xanthan gum, guar gum, hydroxypropyl methyl cellulose, and the homopolymerization of above composition, copolymer and altered contents.The composition of film can
To be the mixing of above single component or Multiple components.
Claims (10)
1. a kind of washing of real silk fabric is with the solidifying pearl of laundry, by water soluble film and its interior cleanout fluid constitutes it is characterised in that cleanout fluid
Prepared by following component by mass percentage:
2. a kind of real silk fabric washing according to claim 1 coagulates pearl with laundry it is characterised in that quality hundred pressed by cleanout fluid
Divide and prepared by following component than meter:
3. a kind of real silk fabric washing according to claim 1 and 2 with the solidifying pearl of laundry it is characterised in that: content of propylene glycol
For 12-19%, and sorbitol content is 2-5%.
4. a kind of real silk fabric washing according to claim 1 with the solidifying pearl of laundry it is characterised in that non-ionic surface active
Agent is included in polyoxyethylene ether, fatty alcohol-polyoxyethylene ether, fatty acid methyl ester APEO and the detergent 6501 of alkyl phenol
One or more；Preferably, fatty alcohol-polyoxyethylene ether select polyoxyethylene lauryl ether, 12-14 carbon primary alconol polyoxyethylene ether,
12-14 carbon secondary alcohol polyoxyethylene ether, collateralization 13 carbon Guerbet polyoxyethylenated alcohol, collateralization 10 carbon Guerbet alcohol polyoxies
Vinyl Ether, 10 carbon polyoxyethylenated alcohol of straight chain, 8 carbon capryl alcohol polyoxyethylene ether of straight chain, 8 carbon isooctanol polyoxyethylene of straight chain
One or more of ether.
5. a kind of real silk fabric washing according to claim 1 with the solidifying pearl of laundry it is characterised in that non-ionic surface active
Aeo-7:aeo-9=1.7:1-2.3:1 or aeo-9:aeo-3=1:1.2 1:2 in agent；Described nonionic surfactant:
DBSA=2:8-3:7.
6. a kind of real silk fabric washing according to claim 1 coagulates pearl with laundry it is characterised in that ethanolamine is from single second
One or more of hydramine, triethanolamine, diethanolamine mix.
7. a kind of real silk fabric washing laundry according to claim 1 coagulates pearl it is characterised in that aversive agent selects saccharin
One of benzyl ammonium amide and benzene first DEXAMETHASONE SODIUM PHOSPHATE ammonium or two kinds of mixing；Enzyme is selected in protease, Digestive Enzyme, amylase, cellulase
One or more mixing.
8. a kind of real silk fabric washing according to claim 1 coagulates pearl with laundry it is characterised in that antibacterial is using pure as jade
Newly compound with other；Acylamide polymer is selected in anti-colour contamination agent.
9. a kind of laundry prepared described in claim 1～8 any one claim coagulates the method for pearl it is characterised in that the party
Method comprises the following steps:
1) press propylene glycol, Sorbitol, glycerol, DBSA, monoethanolamine, nonionic surfactant, cocinic acid,
Maleic acid/acrylic copolymer, chelating agen order sequentially add raw material, when temperature is less than 50 DEG C, add antibacterial, quaternary ammonium salt to have
Organic siloxane, anti-colour contamination agent, deionized water, essence, preservative, aversive agent and enzyme mixing；
2), after liquid is qualified, carry out water soluble film packaging.
10. laundry according to claim 9 coagulates the preparation method of pearl it is characterised in that water soluble film can material selection polyethylene
Alcohol, polyvinyl acetal, Polyvinylpyrrolidone, polyacrylic acid, maleic acid/acrylic copolymer, starch, gelatin, xanthan
Glue, guar gum, hydroxypropyl methyl cellulose, and one or more of the homopolymerization of above composition, copolymer and altered contents
Mixing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610713215.7A CN106350284A (en) | 2016-08-23 | 2016-08-23 | Laundry gel beads for washing real silk fabrics and preparation method of laundry gel beads |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610713215.7A CN106350284A (en) | 2016-08-23 | 2016-08-23 | Laundry gel beads for washing real silk fabrics and preparation method of laundry gel beads |
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| CN106350284A true CN106350284A (en) | 2017-01-25 |
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| CN201610713215.7A Pending CN106350284A (en) | 2016-08-23 | 2016-08-23 | Laundry gel beads for washing real silk fabrics and preparation method of laundry gel beads |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110396457A (en) * | 2019-07-08 | 2019-11-01 | 广州灵润生物科技有限公司 | A kind of anti-colour contamination is done washing solidifying pearl and preparation method thereof |
| WO2020106917A1 (en) * | 2018-11-21 | 2020-05-28 | Henkel IP & Holding GmbH | Unit dose detergent packs with anti-yellowing and anti-efflorescence formulations |
| CN111592942A (en) * | 2020-06-11 | 2020-08-28 | 浙江施维康生物医学材料有限公司 | Color-crossing-preventing washing condensation bead and preparation method thereof |
| CN111607471A (en) * | 2020-07-01 | 2020-09-01 | 浙江施维康生物医学材料有限公司 | Softening laundry gel bead and preparation method and application thereof |
| CN111607470A (en) * | 2020-07-01 | 2020-09-01 | 浙江施维康生物医学材料有限公司 | Sterilizing and bacteriostatic washing gel bead and preparation method thereof |
| CN111704965A (en) * | 2020-07-14 | 2020-09-25 | 福建恒安集团有限公司 | Washing gel bead with 8 times of cleaning power and preparation method thereof |
| CN112538758A (en) * | 2020-12-15 | 2021-03-23 | 上海家化联合股份有限公司 | Fabric care compositions with softening, antistatic, and shade drying odor removal properties |
| CN112592774A (en) * | 2020-12-21 | 2021-04-02 | 上海东大化学有限公司 | Washing gel bead for wool fabric washing and preparation method thereof |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2020106917A1 (en) * | 2018-11-21 | 2020-05-28 | Henkel IP & Holding GmbH | Unit dose detergent packs with anti-yellowing and anti-efflorescence formulations |
| CN110396457A (en) * | 2019-07-08 | 2019-11-01 | 广州灵润生物科技有限公司 | A kind of anti-colour contamination is done washing solidifying pearl and preparation method thereof |
| CN111592942A (en) * | 2020-06-11 | 2020-08-28 | 浙江施维康生物医学材料有限公司 | Color-crossing-preventing washing condensation bead and preparation method thereof |
| CN111607471A (en) * | 2020-07-01 | 2020-09-01 | 浙江施维康生物医学材料有限公司 | Softening laundry gel bead and preparation method and application thereof |
| CN111607470A (en) * | 2020-07-01 | 2020-09-01 | 浙江施维康生物医学材料有限公司 | Sterilizing and bacteriostatic washing gel bead and preparation method thereof |
| CN111704965A (en) * | 2020-07-14 | 2020-09-25 | 福建恒安集团有限公司 | Washing gel bead with 8 times of cleaning power and preparation method thereof |
| CN111704965B (en) * | 2020-07-14 | 2021-10-15 | 福建恒安集团有限公司 | Washing gel bead with 8 times of cleaning power and preparation method thereof |
| CN112538758A (en) * | 2020-12-15 | 2021-03-23 | 上海家化联合股份有限公司 | Fabric care compositions with softening, antistatic, and shade drying odor removal properties |
| CN112592774A (en) * | 2020-12-21 | 2021-04-02 | 上海东大化学有限公司 | Washing gel bead for wool fabric washing and preparation method thereof |
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Application publication date: 20170125 |