CN102242022A - Environment-friendly type hyperconcentration biological enzyme liquid laundry detergent and preparation method thereof - Google Patents
Environment-friendly type hyperconcentration biological enzyme liquid laundry detergent and preparation method thereof Download PDFInfo
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- CN102242022A CN102242022A CN 201110160696 CN201110160696A CN102242022A CN 102242022 A CN102242022 A CN 102242022A CN 201110160696 CN201110160696 CN 201110160696 CN 201110160696 A CN201110160696 A CN 201110160696A CN 102242022 A CN102242022 A CN 102242022A
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- Prior art keywords
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- biological enzyme
- environment
- hyperconcentration
- friendly type
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
- 102000004190 Enzymes Human genes 0.000 title claims abstract description 51
- 108090000790 Enzymes Proteins 0.000 title claims abstract description 51
- 239000007788 liquid Substances 0.000 title claims abstract description 49
- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- 239000003599 detergent Substances 0.000 title abstract description 5
- 238000005406 washing Methods 0.000 claims abstract description 31
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 18
- -1 polyoxyethylene Polymers 0.000 claims abstract description 16
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims abstract description 15
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 13
- 239000011734 sodium Substances 0.000 claims abstract description 13
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 13
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 11
- 239000002253 acid Substances 0.000 claims abstract description 11
- 230000003165 hydrotropic effect Effects 0.000 claims abstract description 11
- 239000001509 sodium citrate Substances 0.000 claims abstract description 11
- 239000002904 solvent Substances 0.000 claims abstract description 11
- 239000003381 stabilizer Substances 0.000 claims abstract description 11
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229940088598 enzyme Drugs 0.000 claims description 46
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 29
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 24
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 18
- 238000003756 stirring Methods 0.000 claims description 14
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 10
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 claims description 10
- 150000002632 lipids Chemical class 0.000 claims description 9
- 108091005804 Peptidases Proteins 0.000 claims description 7
- XEFQLINVKFYRCS-UHFFFAOYSA-N Triclosan Chemical group OC1=CC(Cl)=CC=C1OC1=CC=C(Cl)C=C1Cl XEFQLINVKFYRCS-UHFFFAOYSA-N 0.000 claims description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 7
- 239000002994 raw material Substances 0.000 claims description 7
- 229960003500 triclosan Drugs 0.000 claims description 7
- 239000003643 water by type Substances 0.000 claims description 7
- 229940100555 2-methyl-4-isothiazolin-3-one Drugs 0.000 claims description 6
- BWRPYSJNBVBIRP-FLFBIERCSA-N Ineketone Chemical compound O[C@H]1C[C@@](C)(C=C)C=C2C(=O)C[C@]3(O)C(C)(C)CCC[C@H]3[C@@]21C BWRPYSJNBVBIRP-FLFBIERCSA-N 0.000 claims description 6
- BWRPYSJNBVBIRP-UHFFFAOYSA-N Ineketone Natural products OC1CC(C)(C=C)C=C2C(=O)CC3(O)C(C)(C)CCCC3C21C BWRPYSJNBVBIRP-UHFFFAOYSA-N 0.000 claims description 6
- 229910021538 borax Inorganic materials 0.000 claims description 6
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 claims description 6
- 235000011187 glycerol Nutrition 0.000 claims description 6
- 239000011344 liquid material Substances 0.000 claims description 6
- BEGLCMHJXHIJLR-UHFFFAOYSA-N methylisothiazolinone Chemical compound CN1SC=CC1=O BEGLCMHJXHIJLR-UHFFFAOYSA-N 0.000 claims description 6
- 238000005070 sampling Methods 0.000 claims description 6
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 6
- 239000004328 sodium tetraborate Substances 0.000 claims description 6
- 229940038773 trisodium citrate Drugs 0.000 claims description 6
- 229960004418 trolamine Drugs 0.000 claims description 6
- NSFKBZXCXCJZDQ-UHFFFAOYSA-N cumene;sodium Chemical compound [Na].CC(C)C1=CC=CC=C1 NSFKBZXCXCJZDQ-UHFFFAOYSA-N 0.000 claims description 5
- 235000013772 propylene glycol Nutrition 0.000 claims description 5
- 229940048842 sodium xylenesulfonate Drugs 0.000 claims description 5
- QUCDWLYKDRVKMI-UHFFFAOYSA-M sodium;3,4-dimethylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1C QUCDWLYKDRVKMI-UHFFFAOYSA-M 0.000 claims description 5
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 5
- CUVLMZNMSPJDON-UHFFFAOYSA-N 1-(1-butoxypropan-2-yloxy)propan-2-ol Chemical compound CCCCOCC(C)OCC(C)O CUVLMZNMSPJDON-UHFFFAOYSA-N 0.000 claims description 4
- OAYXUHPQHDHDDZ-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethanol Chemical compound CCCCOCCOCCO OAYXUHPQHDHDDZ-UHFFFAOYSA-N 0.000 claims description 4
- XYVAYAJYLWYJJN-UHFFFAOYSA-N 2-(2-propoxypropoxy)propan-1-ol Chemical compound CCCOC(C)COC(C)CO XYVAYAJYLWYJJN-UHFFFAOYSA-N 0.000 claims description 4
- BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 claims description 4
- 238000001514 detection method Methods 0.000 claims description 4
- RWNUSVWFHDHRCJ-UHFFFAOYSA-N 1-butoxypropan-2-ol Chemical compound CCCCOCC(C)O RWNUSVWFHDHRCJ-UHFFFAOYSA-N 0.000 claims description 3
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims description 3
- 239000004382 Amylase Substances 0.000 claims description 3
- 102000013142 Amylases Human genes 0.000 claims description 3
- 108010065511 Amylases Proteins 0.000 claims description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- 108010059892 Cellulase Proteins 0.000 claims description 3
- 239000004367 Lipase Substances 0.000 claims description 3
- 102000004882 Lipase Human genes 0.000 claims description 3
- 108090001060 Lipase Proteins 0.000 claims description 3
- 102000035195 Peptidases Human genes 0.000 claims description 3
- WNLRTRBMVRJNCN-UHFFFAOYSA-L adipate(2-) Chemical compound [O-]C(=O)CCCCC([O-])=O WNLRTRBMVRJNCN-UHFFFAOYSA-L 0.000 claims description 3
- 230000032683 aging Effects 0.000 claims description 3
- 235000019418 amylase Nutrition 0.000 claims description 3
- 229940106157 cellulase Drugs 0.000 claims description 3
- 239000000470 constituent Substances 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 3
- 235000019421 lipase Nutrition 0.000 claims description 3
- 229940040461 lipase Drugs 0.000 claims description 3
- 238000012856 packing Methods 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 8
- 125000001931 aliphatic group Chemical group 0.000 abstract description 3
- 239000004744 fabric Substances 0.000 abstract description 3
- 150000002191 fatty alcohols Chemical class 0.000 abstract 2
- 229910019142 PO4 Inorganic materials 0.000 abstract 1
- 230000000844 anti-bacterial effect Effects 0.000 abstract 1
- 230000002421 anti-septic effect Effects 0.000 abstract 1
- 239000003899 bactericide agent Substances 0.000 abstract 1
- 238000005282 brightening Methods 0.000 abstract 1
- 235000021317 phosphate Nutrition 0.000 abstract 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 abstract 1
- 229940051841 polyoxyethylene ether Drugs 0.000 abstract 1
- 229920000056 polyoxyethylene ether Polymers 0.000 abstract 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 abstract 1
- 239000000047 product Substances 0.000 description 15
- 235000019263 trisodium citrate Nutrition 0.000 description 8
- 230000000694 effects Effects 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 6
- 230000007613 environmental effect Effects 0.000 description 5
- 239000004365 Protease Substances 0.000 description 4
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 description 4
- 239000013543 active substance Substances 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 238000005265 energy consumption Methods 0.000 description 3
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 3
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 230000006641 stabilisation Effects 0.000 description 2
- 238000011105 stabilization Methods 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 1
- TUNFSRHWOTWDNC-UHFFFAOYSA-N Myristic acid Natural products CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000002894 chemical waste Substances 0.000 description 1
- 238000005202 decontamination Methods 0.000 description 1
- 230000003588 decontaminative effect Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000012851 eutrophication Methods 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- 238000002372 labelling Methods 0.000 description 1
- 239000004973 liquid crystal related substance Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 239000012263 liquid product Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- 239000008237 rinsing water Substances 0.000 description 1
- 210000002374 sebum Anatomy 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- HLBBKKJFGFRGMU-UHFFFAOYSA-M sodium formate Chemical compound [Na+].[O-]C=O HLBBKKJFGFRGMU-UHFFFAOYSA-M 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
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- Detergent Compositions (AREA)
Abstract
Description
Claims (9)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN 201110160696 CN102242022B (en) | 2011-06-15 | 2011-06-15 | Environment-friendly type hyperconcentration biological enzyme liquid laundry detergent and preparation method thereof |
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CN 201110160696 CN102242022B (en) | 2011-06-15 | 2011-06-15 | Environment-friendly type hyperconcentration biological enzyme liquid laundry detergent and preparation method thereof |
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CN102242022A true CN102242022A (en) | 2011-11-16 |
CN102242022B CN102242022B (en) | 2012-12-19 |
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Cited By (36)
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CN102559421A (en) * | 2011-12-23 | 2012-07-11 | 广州立白企业集团有限公司 | Enzyme-containing fabric detergent with synergistic anticorrosion effect |
CN102634420A (en) * | 2012-03-31 | 2012-08-15 | 天津天狮生物发展有限公司 | Concentrated clothes cleaning agent and preparation method thereof |
CN102660397A (en) * | 2012-03-31 | 2012-09-12 | 天津天狮生物发展有限公司 | Detergent for cleaning underwear and preparation method thereof |
CN103255003A (en) * | 2013-06-04 | 2013-08-21 | 沈宇杰 | Washing agent |
CN103468422A (en) * | 2013-09-12 | 2013-12-25 | 上海制皂(集团)如皋有限公司 | Anti-static color-protecting laundry detergent |
CN103525594A (en) * | 2013-10-23 | 2014-01-22 | 杨解定 | Fatty acid-containing laundry detergent |
CN103710985A (en) * | 2013-11-29 | 2014-04-09 | 江苏中新资源集团有限公司 | Fabric mildew-resistant fragrant treatment agent and preparation method thereof |
CN103773622A (en) * | 2012-10-25 | 2014-05-07 | 阳紫威 | Liquid detergent |
CN103773623A (en) * | 2014-02-25 | 2014-05-07 | 章方军 | Composite enzyme detergent, and preparation method and use thereof |
CN103865676A (en) * | 2014-02-13 | 2014-06-18 | 上海方木精细化工有限公司 | Concentrated liquid detergent |
WO2014147469A1 (en) * | 2013-03-22 | 2014-09-25 | Decisiones Ambientales, S.A. De C.V. | System and method for washing mechanical parts |
CN104862109A (en) * | 2015-06-15 | 2015-08-26 | 马建剑 | Novel detergent for fabric containing wool and preparation method of novel detergent |
CN104987960A (en) * | 2015-07-13 | 2015-10-21 | 于文 | Fabric fiber care type bio-enzyme laundry detergent and preparation method thereof |
CN105062703A (en) * | 2015-07-27 | 2015-11-18 | 东莞市香与化工有限公司 | Protease super-concentrated laundry detergent and preparation method thereof |
WO2015172678A1 (en) * | 2014-05-12 | 2015-11-19 | The Procter & Gamble Company | Method of laundering fabric |
WO2015172282A1 (en) * | 2014-05-12 | 2015-11-19 | The Procter & Gamble Company | Liquid anti-microbial laundry detergent composition |
CN105155306A (en) * | 2015-07-23 | 2015-12-16 | 百宁纺织化工(中山)有限公司 | Formula for osmotic agent |
CN105385509A (en) * | 2015-11-30 | 2016-03-09 | 成都九十度工业产品设计有限公司 | Concentrated type laundry detergent |
CN105400620A (en) * | 2015-11-27 | 2016-03-16 | 北京市创新精细化工有限责任公司 | Super-concentrated multifunctional detergent for low-temperature water washing |
CN105462703A (en) * | 2016-01-04 | 2016-04-06 | 保洁丽日用品(深圳)有限公司 | Underwear washing agent and preparing method thereof |
CN105754737A (en) * | 2014-12-19 | 2016-07-13 | 北京绿伞化学股份有限公司 | Concentrated laundry liquid for water-soluble membrane packaging and preparing method thereof |
CN105820888A (en) * | 2016-04-21 | 2016-08-03 | 刘爱华 | Decontaminating bactericidal clothing detergent |
CN105886170A (en) * | 2014-12-12 | 2016-08-24 | 上海和黄白猫有限公司 | Enzyme-containing concentrated low foam type laundry detergent and preparation method thereof |
CN106232788A (en) * | 2014-05-20 | 2016-12-14 | 宝洁公司 | There is the low surfactant of the sudsing profile of improvement, high carbon acid salt liquid laundry detergent composition |
CN106635466A (en) * | 2016-09-22 | 2017-05-10 | 长兴净安环保科技有限公司 | Down jacket dry-cleaning agent and preparation method thereof |
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CN106854539A (en) * | 2017-01-04 | 2017-06-16 | 长沙协浩吉生物工程有限公司 | A kind of compound method of collar cleaner machine washing liquid |
CN106957836A (en) * | 2017-04-07 | 2017-07-18 | 聂麒曌 | Hydrogen peroxide decomposes enzyme stabilizers |
CN107418765A (en) * | 2017-07-27 | 2017-12-01 | 合肥远科服装设计有限公司 | A kind of degerming liquid detergent not hurt hands of color protection |
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CN108410593A (en) * | 2018-03-27 | 2018-08-17 | 靖西市秀美边城农业科技有限公司 | A kind of multiple-effect type liquid detergent and preparation method thereof |
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CN108559655A (en) * | 2018-06-08 | 2018-09-21 | 康柏利科技(苏州)有限公司 | A kind of Superconcentrated washing liquid and preparation method thereof |
CN108676629A (en) * | 2018-06-13 | 2018-10-19 | 北京日光旭升精细化工技术研究所 | Remove bloodstain cleaning agent and preparation method thereof |
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Cited By (47)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102559421B (en) * | 2011-12-23 | 2014-06-25 | 广州立白企业集团有限公司 | Enzyme-containing fabric detergent with synergistic anticorrosion effect |
CN102559421A (en) * | 2011-12-23 | 2012-07-11 | 广州立白企业集团有限公司 | Enzyme-containing fabric detergent with synergistic anticorrosion effect |
CN102660397B (en) * | 2012-03-31 | 2015-10-28 | 天津天狮生物发展有限公司 | A kind of for washing composition cleaning underwear and preparation method thereof |
CN102634420A (en) * | 2012-03-31 | 2012-08-15 | 天津天狮生物发展有限公司 | Concentrated clothes cleaning agent and preparation method thereof |
CN102660397A (en) * | 2012-03-31 | 2012-09-12 | 天津天狮生物发展有限公司 | Detergent for cleaning underwear and preparation method thereof |
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