CN102634420B - A kind of concentrated clothes detergent and preparation method thereof - Google Patents
A kind of concentrated clothes detergent and preparation method thereof Download PDFInfo
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- CN102634420B CN102634420B CN201210093523.6A CN201210093523A CN102634420B CN 102634420 B CN102634420 B CN 102634420B CN 201210093523 A CN201210093523 A CN 201210093523A CN 102634420 B CN102634420 B CN 102634420B
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- cooled
- laureth
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- sodium
- stir
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- 239000003599 detergent Substances 0.000 title claims abstract description 28
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- 238000003756 stirring Methods 0.000 claims abstract description 32
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims abstract description 24
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 16
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 16
- 239000011734 sodium Substances 0.000 claims abstract description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000000463 material Substances 0.000 claims abstract description 11
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims abstract description 10
- 239000001110 calcium chloride Substances 0.000 claims abstract description 10
- 229910001628 calcium chloride Inorganic materials 0.000 claims abstract description 10
- SFNALCNOMXIBKG-UHFFFAOYSA-N ethylene glycol monododecyl ether Chemical compound CCCCCCCCCCCCOCCO SFNALCNOMXIBKG-UHFFFAOYSA-N 0.000 claims abstract description 10
- HEGSGKPQLMEBJL-RKQHYHRCSA-N octyl beta-D-glucopyranoside Chemical compound CCCCCCCCO[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O HEGSGKPQLMEBJL-RKQHYHRCSA-N 0.000 claims abstract description 10
- 239000000843 powder Substances 0.000 claims abstract description 10
- RRLOOYQHUHGIRJ-UHFFFAOYSA-M sodium;ethyl sulfate Chemical compound [Na+].CCOS([O-])(=O)=O RRLOOYQHUHGIRJ-UHFFFAOYSA-M 0.000 claims abstract description 10
- 229940100555 2-methyl-4-isothiazolin-3-one Drugs 0.000 claims abstract description 8
- 239000004382 Amylase Substances 0.000 claims abstract description 8
- 102000013142 Amylases Human genes 0.000 claims abstract description 8
- 108010065511 Amylases Proteins 0.000 claims abstract description 8
- 150000001335 aliphatic alkanes Chemical class 0.000 claims abstract description 8
- 235000019418 amylase Nutrition 0.000 claims abstract description 8
- JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910021538 borax Inorganic materials 0.000 claims abstract description 8
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims abstract description 8
- BEGLCMHJXHIJLR-UHFFFAOYSA-N methylisothiazolinone Chemical compound CN1SC=CC1=O BEGLCMHJXHIJLR-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000004328 sodium tetraborate Substances 0.000 claims abstract description 8
- 235000010339 sodium tetraborate Nutrition 0.000 claims abstract description 8
- 230000001954 sterilising effect Effects 0.000 claims abstract description 8
- FKMHSNTVILORFA-UHFFFAOYSA-N 2-[2-(2-dodecoxyethoxy)ethoxy]ethanol Chemical compound CCCCCCCCCCCCOCCOCCOCCO FKMHSNTVILORFA-UHFFFAOYSA-N 0.000 claims abstract description 6
- DWHIUNMOTRUVPG-UHFFFAOYSA-N 2-[2-[2-[2-[2-[2-(2-dodecoxyethoxy)ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethanol Chemical compound CCCCCCCCCCCCOCCOCCOCCOCCOCCOCCOCCO DWHIUNMOTRUVPG-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229920002884 Laureth 4 Polymers 0.000 claims abstract description 6
- 229940057905 laureth-3 Drugs 0.000 claims abstract description 6
- 229940031674 laureth-7 Drugs 0.000 claims abstract description 6
- 229940062711 laureth-9 Drugs 0.000 claims abstract description 6
- ONJQDTZCDSESIW-UHFFFAOYSA-N polidocanol Chemical compound CCCCCCCCCCCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO ONJQDTZCDSESIW-UHFFFAOYSA-N 0.000 claims abstract description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 21
- 239000008367 deionised water Substances 0.000 claims description 9
- 229910021641 deionized water Inorganic materials 0.000 claims description 9
- 239000002994 raw material Substances 0.000 claims description 8
- 230000001105 regulatory effect Effects 0.000 claims description 7
- 239000000796 flavoring agent Substances 0.000 claims description 4
- 235000019634 flavors Nutrition 0.000 claims description 4
- 235000005979 Citrus limon Nutrition 0.000 claims description 2
- 244000131522 Citrus pyriformis Species 0.000 claims description 2
- 244000223014 Syzygium aromaticum Species 0.000 claims description 2
- 235000016639 Syzygium aromaticum Nutrition 0.000 claims description 2
- 238000000034 method Methods 0.000 claims description 2
- 238000005406 washing Methods 0.000 abstract description 9
- 239000004744 fabric Substances 0.000 abstract description 3
- 239000002689 soil Substances 0.000 abstract description 3
- 230000007613 environmental effect Effects 0.000 abstract description 2
- 239000012467 final product Substances 0.000 abstract 1
- 238000004659 sterilization and disinfection Methods 0.000 abstract 1
- 239000007788 liquid Substances 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 3
- -1 alkyl glycoside Chemical class 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 238000003307 slaughter Methods 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229930182470 glycoside Natural products 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
Abstract
The invention discloses a kind of concentrated clothes detergent and preparation method thereof, preparation process is: by water heat sterilization; Add Calcium Chloride Powder Anhydrous, stir molten; Add laureth sodium sulfovinate, stir molten; Add laureth-9, laureth-7 and laureth-3 when being cooled to 73-77 DEG C, stir molten; Adding borax when being cooled to 68-72 DEG C stirs molten; Add C14-17 Seconary Alkane Sulphonate Sodium when being cooled to 58-62 DEG C, stir molten; Add octyl glucoside when being cooled to 48-52 DEG C, stir molten; Regulate pH; When being cooled to 43-47 DEG C, adding two propyloic cocoyl ethyl tetrahydroglyoxaline sodium and methyl alcohol, stir evenly; When being cooled to 37-39 DEG C, adding Sumizyme MP, amylase, methylchloroisothiazandnone, methylisothiazolinone and essence, stir evenly, to obtain final product.Clean-out system of the present invention is biodegradable, safety and environmental protection, and character is gentle, cleans and protects both hands, and soil removability is strong, and usage quantity is few, is suitable for washing various material fabric.
Description
Technical field
The invention belongs to household cleaning product, specifically a kind of concentrated clothes detergent.
Background technology
For the development of detergent industry, enrichment has become the trend of globalization, is also the task of top priority.Liquid washing agent is described as " energy-saving product ", and concentrated type liquid washing agent is that in liquid washing agent, quantity is maximum, with the fastest developing speed, a series products of most exploitation future.
Current China concentrated liquid detergent product is in the starting stage, and the ratio accounted in articles for washing is very little.And in the industrially developed country such as the U.S., West Europe and Japan, its development has reached considerable scale, and the rate of increase of concentrated liquid detergent exceeds 2 ~ 3 times of articles for washing rate of increase.Therefore, the emphasis in the articles for washing structural adjustment of concentrated cleaning product Ying Shi China is developed.
Summary of the invention
The object of the invention is to overcome the deficiencies in the prior art, a kind of concentrated clothes detergent is provided.
Second object of the present invention is to provide a kind of preparation method of concentrated clothes detergent.
Technical scheme of the present invention is summarized as follows:
A preparation method for concentrated clothes detergent, comprises the steps:
(1) raw material is taken by weight percentage:
Calcium Chloride Powder Anhydrous 0.01-0.02%, laureth sodium sulfovinate 8-12%, laureth-94-8%, laureth-74-8%, laureth-32-6%, octyl glucoside 2-3%, borax 1-2%, C14-17 Seconary Alkane Sulphonate Sodium 2-4%, two propyloic cocoyl ethyl tetrahydroglyoxaline sodium 1-2%, methyl alcohol 0.5-1%, Sumizyme MP 0.3-0.5%, methylchloroisothiazandnone 0.01-0.03%, methylisothiazolinone 0.01-0.03%, amylase 0.2-0.5%, essence 0.1-0.2%, all the other are deionized water;
(2) weigh deionized water and put into container, be heated to 78-82 DEG C of sterilizing 10-15 minute; Add described Calcium Chloride Powder Anhydrous, stirring and dissolving; Add described laureth sodium sulfovinate, fully stir and treat that material all dissolves;
(3) add laureth-9, laureth-7 and laureth-3 when being cooled to 73-77 DEG C, insulated and stirred is dissolved;
(4) add borax when being cooled to 68-72 DEG C, insulated and stirred is dissolved;
(5) add C14-17 Seconary Alkane Sulphonate Sodium when being cooled to 58-62 DEG C, insulated and stirred is dissolved;
(6) add octyl glucoside when being cooled to 48-52 DEG C, insulated and stirred is dissolved; PH=6-8 is regulated with citric acid;
(7), when being cooled to 43-47 DEG C, adding two propyloic cocoyl ethyl tetrahydroglyoxaline sodium and methyl alcohol, stir;
(8) when being cooled to 37-39 DEG C, add Sumizyme MP, amylase, methylchloroisothiazandnone, methylisothiazolinone and essence, after stirring, obtain concentrated clothes detergent.
Described essence is lemon flavor essence or cloves flavor essence.
Concentrated clothes detergent prepared by aforesaid method.
One of the present invention concentrates clothes detergent not phosphate-containing and alkyl benzene material; not containing white dyes and harmful heavy metal element; biodegradable; safety and environmental protection, includes the surface active ingredients such as alkyl glycoside, and product property is gentle; clean and protect both hands; soil removability is strong, and usage quantity is few, is applicable to wash various material fabric.
Embodiment
Below in conjunction with specific embodiment, the present invention is further illustrated.
The proportioning raw materials of embodiment 1-embodiment 5 is in table 1
Table 1:
Embodiment 6
A preparation method for concentrated clothes detergent, comprises the steps:
(1) raw material listed by embodiment 1 is taken by weight;
(2) weigh deionized water and put into container, be heated to 80 DEG C of sterilizings 13 minutes; Add Calcium Chloride Powder Anhydrous, stirring and dissolving; Add described laureth sodium sulfovinate, fully stir and treat that material all dissolves;
(3) add laureth-9, laureth-7 and laureth-3 when being cooled to 75 DEG C, insulated and stirred is dissolved;
(4) add borax when being cooled to 70 DEG C, insulated and stirred is dissolved;
(5) add C14-17 Seconary Alkane Sulphonate Sodium when being cooled to 60 DEG C, insulated and stirred is dissolved;
(6) add octyl glucoside when being cooled to 50 DEG C, insulated and stirred is dissolved; PH=7 is regulated with citric acid;
(7), when being cooled to 45 DEG C, adding two propyloic cocoyl ethyl tetrahydroglyoxaline sodium, methyl alcohol, stir;
(8) when being cooled to 38 DEG C, add Sumizyme MP, amylase, methylchloroisothiazandnone, methylisothiazolinone, essence, after stirring, obtain concentrated clothes detergent.
Embodiment 7
A preparation method for concentrated clothes detergent, comprises the steps:
(1) raw material listed by embodiment 2 is taken by weight;
(2) weigh deionized water and put into container, be heated to 78 DEG C of sterilizings 15 minutes; Add described Calcium Chloride Powder Anhydrous, stirring and dissolving; Add described laureth sodium sulfovinate, fully stir and treat that material all dissolves;
(3) add laureth-9, laureth-7 and laureth-3 when being cooled to 73 DEG C, insulated and stirred is dissolved;
(4) add borax when being cooled to 68 DEG C, insulated and stirred is dissolved;
(5) add C14-17 Seconary Alkane Sulphonate Sodium when being cooled to 58 DEG C, insulated and stirred is dissolved;
(6) add octyl glucoside when being cooled to 48 DEG C, insulated and stirred is dissolved; PH=8 is regulated with citric acid;
(7), when being cooled to 43 DEG C, adding two propyloic cocoyl ethyl tetrahydroglyoxaline sodium and methyl alcohol, stir;
(8) when being cooled to 37 DEG C, add Sumizyme MP, amylase, methylchloroisothiazandnone, methylisothiazolinone and essence, after stirring, obtain concentrated clothes detergent.
Embodiment 8
A preparation method for concentrated clothes detergent, comprises the steps:
(1) raw material listed by embodiment 3 is taken by weight;
(2) weigh deionized water and put into container, be heated to 82 DEG C of sterilizings 10 minutes; Add described Calcium Chloride Powder Anhydrous, stirring and dissolving; Add described laureth sodium sulfovinate, fully stir and treat that material all dissolves;
(3) add laureth-9, laureth-7 and laureth-3 when being cooled to 77 DEG C, insulated and stirred is dissolved;
(4) add borax when being cooled to 72 DEG C, insulated and stirred is dissolved;
(5) add C14-17 Seconary Alkane Sulphonate Sodium when being cooled to 62 DEG C, insulated and stirred is dissolved;
(6) add octyl glucoside when being cooled to 52 DEG C, insulated and stirred is dissolved; PH=6 is regulated with citric acid;
(7), when being cooled to 47 DEG C, adding two propyloic cocoyl ethyl tetrahydroglyoxaline sodium and methyl alcohol, stir;
(8) when being cooled to 39 DEG C, add Sumizyme MP, amylase, methylchloroisothiazandnone, methylisothiazolinone and essence, after stirring, obtain concentrated clothes detergent.
Embodiment 9
A preparation method for concentrated clothes detergent, comprises the steps:
(1) raw material listed by embodiment 4 is taken by weight;
(2) weigh deionized water and put into container, be heated to 80 DEG C of sterilizings 14 minutes; Add Calcium Chloride Powder Anhydrous, stirring and dissolving; Add described laureth sodium sulfovinate, fully stir and treat that material all dissolves;
(3)-(5) are with embodiment 6
(6) add octyl glucoside when being cooled to 50 DEG C, insulated and stirred is dissolved; PH=7 is regulated with citric acid;
(7)-(8) are with embodiment 6.
Embodiment 10
A preparation method for concentrated clothes detergent, comprises the steps:
(1) raw material listed by embodiment 5 is taken by weight;
(2) weigh deionized water and put into container, be heated to 80 DEG C of sterilizings 14 minutes; Add Calcium Chloride Powder Anhydrous, stirring and dissolving; Add described laureth sodium sulfovinate, fully stir and treat that material all dissolves;
(3)-(5) are with embodiment 6
(6) add octyl glucoside when being cooled to 50 DEG C, insulated and stirred is dissolved; PH=7 is regulated with citric acid;
(7)-(8) are with embodiment 6.
Embodiment 11
Effect experimental:
Get the work suit (comprising jacket and trousers, jack per line) that 36 pig slaughtering factory slaughter hall workmans wear 1 day, be divided into 6 groups at random, often organize 6, the 1st group is use commercially available conventional detergent, machine washing, and water consumption 10L/ overlaps, and clean-out system consumption 20mL/ overlaps; 2-6 group is followed successively by concentrated clothes detergent prepared by embodiment 6-10, and water consumption 10L/ overlaps, and clean-out system consumption 5mL/ overlaps; The working suit of 1-6 group is each before washing to be soaked 5 minutes, and within 20 minutes, cleaned by work suit during the 1st group of use, the 2-6 group used time is followed successively by 11; 13; 12; 12; 13 minutes, working suit is cleaned.
Experimental result shows, concentrated clothes detergent soil removability of the present invention is strong, and usage quantity is few, is applicable to wash various material fabric.
Claims (3)
1. a preparation method for concentrated clothes detergent, is characterized in that comprising the steps:
(1) raw material is taken by weight percentage:
Calcium Chloride Powder Anhydrous 0.01-0.02%, laureth sodium sulfovinate 8-12%, laureth-94-8%, laureth-74-8%, laureth-32-6%, octyl glucoside 2-3%, borax 1-2%, C
14-17seconary Alkane Sulphonate Sodium 2-4%, two propyloic cocoyl ethyl tetrahydroglyoxaline sodium 1-2%, methyl alcohol 0.5-1%, Sumizyme MP 0.3-0.5%, methylchloroisothiazandnone 0.01-0.03%, methylisothiazolinone 0.01-0.03%, amylase 0.2-0.5%, essence 0.1-0.2%, all the other are deionized water;
(2) weigh deionized water and put into container, be heated to 78-82 DEG C of sterilizing 10-15 minute; Add described Calcium Chloride Powder Anhydrous, stirring and dissolving; Add described laureth sodium sulfovinate, fully stir and treat that material all dissolves;
(3) add laureth-9, laureth-7 and laureth-3 when being cooled to 73-77 DEG C, insulated and stirred is dissolved;
(4) add borax when being cooled to 68-72 DEG C, insulated and stirred is dissolved;
(5) C is added when being cooled to 58-62 DEG C
14-17seconary Alkane Sulphonate Sodium, insulated and stirred is dissolved;
(6) add octyl glucoside when being cooled to 48-52 DEG C, insulated and stirred is dissolved; PH=6-8 is regulated with citric acid;
(7), when being cooled to 43-47 DEG C, adding two propyloic cocoyl ethyl tetrahydroglyoxaline sodium and methyl alcohol, stir;
(8) when being cooled to 37-39 DEG C, add Sumizyme MP, amylase, methylchloroisothiazandnone, methylisothiazolinone and essence, after stirring, obtain concentrated clothes detergent.
2. the preparation method of a kind of concentrated clothes detergent according to claim 1, is characterized in that described essence is lemon flavor essence or cloves flavor essence.
3. the concentrated clothes detergent prepared of the method for claim 1 or 2.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210093523.6A CN102634420B (en) | 2012-03-31 | 2012-03-31 | A kind of concentrated clothes detergent and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210093523.6A CN102634420B (en) | 2012-03-31 | 2012-03-31 | A kind of concentrated clothes detergent and preparation method thereof |
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| Publication Number | Publication Date |
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| CN102634420A CN102634420A (en) | 2012-08-15 |
| CN102634420B true CN102634420B (en) | 2015-10-28 |
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Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103897841A (en) * | 2012-12-26 | 2014-07-02 | 青岛锦涟鑫商贸有限公司 | Textile washing agent |
| CN103897849A (en) * | 2012-12-26 | 2014-07-02 | 青岛锦涟鑫商贸有限公司 | Detergent for fiber fabric |
| CN104629944A (en) * | 2013-11-11 | 2015-05-20 | 青岛锦涟鑫商贸有限公司 | Clothes cleaning compound |
| CN103740492A (en) * | 2013-12-27 | 2014-04-23 | 天津天狮生物发展有限公司 | Concentrated washing solution and preparation method thereof |
| CN106987436A (en) * | 2017-03-17 | 2017-07-28 | 长沙协浩吉生物工程有限公司 | A kind of compound method of wood furniture ferment cleaning agent |
| CN107603758A (en) * | 2017-10-13 | 2018-01-19 | 洛娃科技实业集团有限公司 | A kind of liquid detergent and preparation method |
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| CN102154068A (en) * | 2011-03-03 | 2011-08-17 | 天津天狮生物发展有限公司 | Multifunctional detergent and preparation method thereof |
| CN102242022A (en) * | 2011-06-15 | 2011-11-16 | 于文 | Environment-friendly type hyperconcentration biological enzyme liquid laundry detergent and preparation method thereof |
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2012
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102154068A (en) * | 2011-03-03 | 2011-08-17 | 天津天狮生物发展有限公司 | Multifunctional detergent and preparation method thereof |
| CN102242022A (en) * | 2011-06-15 | 2011-11-16 | 于文 | Environment-friendly type hyperconcentration biological enzyme liquid laundry detergent and preparation method thereof |
Non-Patent Citations (1)
| Title |
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| 《系列羧酸盐型咪唑啉磷酸酯的合成与性能》;李春霞等;《精细化工》;20071130;第24卷(第11期);P1064-1068 * |
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