CN102634421B - laundry detergent and preparation method thereof - Google Patents
laundry detergent and preparation method thereof Download PDFInfo
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- CN102634421B CN102634421B CN201210094273.8A CN201210094273A CN102634421B CN 102634421 B CN102634421 B CN 102634421B CN 201210094273 A CN201210094273 A CN 201210094273A CN 102634421 B CN102634421 B CN 102634421B
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- Prior art keywords
- laureth
- cooled
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- laundry detergent
- sodium
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- 239000003599 detergent Substances 0.000 title claims abstract description 32
- 238000002360 preparation method Methods 0.000 title claims abstract description 16
- 238000003756 stirring Methods 0.000 claims abstract description 39
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 31
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims abstract description 30
- 238000001816 cooling Methods 0.000 claims abstract description 22
- 238000010438 heat treatment Methods 0.000 claims abstract description 22
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 20
- 239000011734 sodium Substances 0.000 claims abstract description 20
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 20
- 239000000843 powder Substances 0.000 claims abstract description 14
- 229940100555 2-methyl-4-isothiazolin-3-one Drugs 0.000 claims abstract description 10
- 239000004382 Amylase Substances 0.000 claims abstract description 10
- 102000013142 Amylases Human genes 0.000 claims abstract description 10
- 108010065511 Amylases Proteins 0.000 claims abstract description 10
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims abstract description 10
- 150000001335 aliphatic alkanes Chemical class 0.000 claims abstract description 10
- 235000019418 amylase Nutrition 0.000 claims abstract description 10
- JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910021538 borax Inorganic materials 0.000 claims abstract description 10
- 239000001110 calcium chloride Substances 0.000 claims abstract description 10
- 229910001628 calcium chloride Inorganic materials 0.000 claims abstract description 10
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims abstract description 10
- SFNALCNOMXIBKG-UHFFFAOYSA-N ethylene glycol monododecyl ether Chemical compound CCCCCCCCCCCCOCCO SFNALCNOMXIBKG-UHFFFAOYSA-N 0.000 claims abstract description 10
- BEGLCMHJXHIJLR-UHFFFAOYSA-N methylisothiazolinone Chemical compound CN1SC=CC1=O BEGLCMHJXHIJLR-UHFFFAOYSA-N 0.000 claims abstract description 10
- HEGSGKPQLMEBJL-RKQHYHRCSA-N octyl beta-D-glucopyranoside Chemical compound CCCCCCCCO[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O HEGSGKPQLMEBJL-RKQHYHRCSA-N 0.000 claims abstract description 10
- 239000004328 sodium tetraborate Substances 0.000 claims abstract description 10
- 235000010339 sodium tetraborate Nutrition 0.000 claims abstract description 10
- RRLOOYQHUHGIRJ-UHFFFAOYSA-M sodium;ethyl sulfate Chemical compound [Na+].CCOS([O-])(=O)=O RRLOOYQHUHGIRJ-UHFFFAOYSA-M 0.000 claims abstract description 10
- 239000002994 raw material Substances 0.000 claims abstract description 9
- FKMHSNTVILORFA-UHFFFAOYSA-N 2-[2-(2-dodecoxyethoxy)ethoxy]ethanol Chemical compound CCCCCCCCCCCCOCCOCCOCCO FKMHSNTVILORFA-UHFFFAOYSA-N 0.000 claims abstract description 8
- DWHIUNMOTRUVPG-UHFFFAOYSA-N 2-[2-[2-[2-[2-[2-(2-dodecoxyethoxy)ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethanol Chemical compound CCCCCCCCCCCCOCCOCCOCCOCCOCCOCCOCCO DWHIUNMOTRUVPG-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229920002884 Laureth 4 Polymers 0.000 claims abstract description 8
- 229940057905 laureth-3 Drugs 0.000 claims abstract description 8
- 229940031674 laureth-7 Drugs 0.000 claims abstract description 8
- 229940062711 laureth-9 Drugs 0.000 claims abstract description 8
- ONJQDTZCDSESIW-UHFFFAOYSA-N polidocanol Chemical compound CCCCCCCCCCCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO ONJQDTZCDSESIW-UHFFFAOYSA-N 0.000 claims abstract description 8
- 230000001954 sterilising effect Effects 0.000 claims abstract description 8
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 21
- 239000008367 deionised water Substances 0.000 claims description 16
- 229910021641 deionized water Inorganic materials 0.000 claims description 16
- 239000000203 mixture Substances 0.000 claims description 10
- -1 Prifer6813 Chemical compound 0.000 claims description 8
- 239000000463 material Substances 0.000 claims description 7
- 238000010792 warming Methods 0.000 claims description 7
- 244000178870 Lavandula angustifolia Species 0.000 claims description 2
- 235000010663 Lavandula angustifolia Nutrition 0.000 claims description 2
- 241000220317 Rosa Species 0.000 claims description 2
- 239000000796 flavoring agent Substances 0.000 claims description 2
- 235000019634 flavors Nutrition 0.000 claims description 2
- 239000001102 lavandula vera Substances 0.000 claims description 2
- 235000018219 lavender Nutrition 0.000 claims description 2
- 238000000034 method Methods 0.000 claims description 2
- 206010040880 Skin irritation Diseases 0.000 abstract description 3
- 230000036556 skin irritation Effects 0.000 abstract description 3
- 231100000475 skin irritation Toxicity 0.000 abstract description 3
- 239000012467 final product Substances 0.000 abstract 1
- 238000002156 mixing Methods 0.000 abstract 1
- 238000005406 washing Methods 0.000 description 17
- 238000004140 cleaning Methods 0.000 description 8
- 239000007788 liquid Substances 0.000 description 8
- 239000000126 substance Substances 0.000 description 4
- 239000000975 dye Substances 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000011241 protective layer Substances 0.000 description 2
- 230000000638 stimulation Effects 0.000 description 2
- 206010028980 Neoplasm Diseases 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 201000011510 cancer Diseases 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 231100000481 chemical toxicant Toxicity 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
Abstract
The invention discloses a kind of laundry detergent and preparation method thereof, preparation process: take raw material; By laureth-7, laureth-9, Prifer? 6813, laureth-3 and laureth sodium sulfovinate add water, and mixing obtains basestocks; Water is poured in Cooling or heating jar, add Calcium Chloride Powder Anhydrous and dissolve; Add basestocks, intensification sterilizing; Be cooled to 58-62 DEG C, add C14-17 Seconary Alkane Sulphonate Sodium, stir molten; Be cooled to 48-52 DEG C, add octyl glucoside, stir molten, regulate pH; Be cooled to 43-47 DEG C, add two propyloic cocoyl ethyl tetrahydroglyoxaline sodium, methyl alcohol and borax, stir evenly; Be cooled to 36-40 DEG C, add Sumizyme MP, amylase, methylchloroisothiazandnone, methylisothiazolinone and essence, stir evenly, to obtain final product.Laundry detergent of the present invention is to little to skin irritation.Clean effective.
Description
Technical field
The invention belongs to household cleaning product, relate to a kind of laundry detergent and preparation method thereof specifically.
Background technology
China washing liquid market with average annual 27.2% speed increment, nearest 3 years grown beyond 100%.Meanwhile, the average annual growth rate in washing powder market is only 2.2%.It was expected, domestic washing liquid will reach 30% after 2015.And in the U.S., the market share of current washing liquid has exceeded washing powder, accounting has reached more than 80%, has greatly the gesture of alternative washing powder.
No matter be washing liquid or washing powder, topmost requirement is that opponent does not produce stimulation, namely hand is not hindered when washing clothes, tradition washing liquid detersive power is strong, rinsing compared with difficult, water consumption is large, chemical residual is more, simultaneously all with the addition of chemical assistant, such as white dyes, sequestrant, organic solvent etc. in most of washing liquid on the market.Especially white dyes is the chemical composition causing and bring out cancer, the stimulation that also there is opponent had.
Summary of the invention
The object of the invention is to overcome the deficiencies in the prior art, provide a kind of biological degradation rate high, Man & Nature environment is had no effect.Without phosphorus, without toxic chemicals such as aluminium, unstressed configuration whitening agent, the simultaneously bland laundry detergent of opponent.
Second object of the present invention is to provide a kind of preparation method of laundry detergent.
Technical scheme of the present invention is summarized as follows:
A preparation method for laundry detergent, comprises the steps:
(1) raw material is taken by weight percentage: Calcium Chloride Powder Anhydrous 0.01-0.02%, laureth sodium sulfovinate 4-8%, laureth-93-5%, laureth-73-5%, laureth-31-3%, Prifer68130.5-1.2%, octyl glucoside 1-3%, borax 1-2%, C14-17 Seconary Alkane Sulphonate Sodium 2-4%, two propyloic cocoyl ethyl tetrahydroglyoxaline sodium 1-2%, methyl alcohol 0.5-1%, Sumizyme MP 0.3-0.5%, methylchloroisothiazandnone 0.01-0.03%, methylisothiazolinone 0.01-0.03%, amylase 0.2-0.5%, essence 0.1-0.2%, all the other are deionized water,
(2) under normal temperature condition, described laureth-7, laureth-9, Prifer6813, laureth-3 and laureth sodium sulfovinate are added in first Cooling or heating jar, adds a small amount of deionized water, make it mix, obtain basestocks;
(3), under normal temperature condition, residue deionized water is poured in second Cooling or heating jar, drop into described Calcium Chloride Powder Anhydrous, stirring and dissolving;
(4) described basestocks is rendered in second Cooling or heating jar under normal temperature condition, fully stir after material all dissolves, be warming up to 85 DEG C-90 DEG C sterilizing 10-15 minute;
(5) be cooled to 58-62 DEG C, add described C14-17 Seconary Alkane Sulphonate Sodium, stirring and dissolving;
(6) be cooled to 48-52 DEG C, add described octyl glucoside, insulated and stirred is dissolved, and adds citric acid and regulates pH=6-8;
(7) be cooled to 43-47 DEG C, add described two propyloic cocoyl ethyl tetrahydroglyoxaline sodium, methyl alcohol and borax, stir;
(8) be cooled to 36-40 DEG C, add described Sumizyme MP, amylase, methylchloroisothiazandnone, methylisothiazolinone and essence, after stirring, obtain a kind of laundry detergent.
Described essence is rose scent essence or lavender flavor type essence.
Laundry detergent prepared by aforesaid method.
A kind of cleaning clothes washing composition of the present invention is not only rich in the activeconstituents taking from natural matter; clean effective; experiment prove laundry detergent of the present invention use after to skin water loss rate very close to the skin water loss rate before use; illustrate that laundry detergent of the present invention is little to skin irritation; a kind of cleaning clothes washing composition of the present invention can save energy, reduce Harmful chemicals accumulation in the environment and harm, be beneficial to protection of the environment.
Embodiment
Below in conjunction with specific embodiment, the present invention is further illustrated.
The proportioning raw materials of embodiment 1-embodiment 5 is in table 1
Table 1
ProductName Prifer6813 is that CrodaSingaporePteLtd produces sale, Components Name: Alkylester.
Embodiment 6
A preparation method for laundry detergent, comprises the steps:
(1) raw material shown in embodiment 1 is taken by weight percentage:
(2) under normal temperature condition, described laureth-7, laureth-9, Prifer6813, laureth-3 and laureth sodium sulfovinate are added in first Cooling or heating jar, adds a small amount of deionized water, make it mix, obtain basestocks;
(3), under normal temperature condition, residue deionized water is poured in second Cooling or heating jar, drop into described Calcium Chloride Powder Anhydrous, stirring and dissolving;
(4) described basestocks is rendered in second Cooling or heating jar under normal temperature condition, fully stir after material all dissolves, be warming up to 87 DEG C of sterilizings 13 minutes;
(5) be cooled to 6 () DEG C, add described C14-17 Seconary Alkane Sulphonate Sodium, stirring and dissolving;
(6) be cooled to 50 DEG C, add described octyl glucoside, insulated and stirred is dissolved, and adds citric acid and regulates pH=7;
(7) be cooled to 45 DEG C, add described two propyloic cocoyl ethyl tetrahydroglyoxaline sodium, methyl alcohol and borax, stir;
(8) be cooled to 38 DEG C, add described Sumizyme MP, amylase, methylchloroisothiazandnone, methylisothiazolinone and essence, after stirring, obtain a kind of laundry detergent.
Embodiment 7
A preparation method for laundry detergent, comprises the steps:
(1) raw material shown in embodiment 2 is taken by weight percentage:
(2) under normal temperature condition, described laureth-7, laureth-9, Prifer6813, laureth-3 and laureth sodium sulfovinate are added in first Cooling or heating jar, adds a small amount of deionized water, make it mix, obtain basestocks;
(3), under normal temperature condition, residue deionized water is poured in second Cooling or heating jar, drop into described Calcium Chloride Powder Anhydrous, stirring and dissolving;
(4) described basestocks is rendered in second Cooling or heating jar under normal temperature condition, fully stir after material all dissolves, be warming up to 85 DEG C of sterilizings 15 minutes;
(5) be cooled to 58 DEG C, add described C14-17 Seconary Alkane Sulphonate Sodium, stirring and dissolving;
(6) be cooled to 48 DEG C, add described octyl glucoside, insulated and stirred is dissolved, and adds citric acid and regulates pH=8;
(7) be cooled to 43 DEG C, add described two propyloic cocoyl ethyl tetrahydroglyoxaline sodium, methyl alcohol and borax, stir;
(8) be cooled to 36 DEG C, add described Sumizyme MP, amylase, methylchloroisothiazandnone, methylisothiazolinone and essence, after stirring, obtain a kind of laundry detergent.
Embodiment 8
A preparation method for laundry detergent, comprises the steps:
(1) raw material shown in embodiment 3 is taken by weight percentage:
(2) under normal temperature condition, described laureth-7, laureth-9, Prifer6813, laureth-3 and laureth sodium sulfovinate are added in first Cooling or heating jar, adds a small amount of deionized water, make it mix, obtain basestocks;
(3), under normal temperature condition, residue deionized water is poured in second Cooling or heating jar, drop into described Calcium Chloride Powder Anhydrous, stirring and dissolving;
(4) described basestocks is rendered in second Cooling or heating jar under normal temperature condition, fully stir after material all dissolves, be warming up to 86 DEG C of sterilizings 13 minutes;
(5) be cooled to 59 DEG C, add described C14-17 Seconary Alkane Sulphonate Sodium, stirring and dissolving;
(6) be cooled to 49 DEG C, add described octyl glucoside, insulated and stirred is dissolved, and adds citric acid and regulates pH=7;
(7) be cooled to 44 DEG C, add described two propyloic cocoyl ethyl tetrahydroglyoxaline sodium, methyl alcohol and borax, stir;
(8) be cooled to 37 DEG C, add described Sumizyme MP, amylase, methylchloroisothiazandnone, methylisothiazolinone and essence, after stirring, obtain a kind of laundry detergent.
Embodiment 9
A preparation method for laundry detergent, comprises the steps:
(1) raw material shown in embodiment 4 is taken by weight percentage:
(2) under normal temperature condition, described laureth-7, laureth-9, Prifer6813, laureth-3 and laureth sodium sulfovinate are added in first Cooling or heating jar, adds a small amount of deionized water, make it mix, obtain basestocks;
(3), under normal temperature condition, residue deionized water is poured in second Cooling or heating jar, drop into described Calcium Chloride Powder Anhydrous, stirring and dissolving;
(4) described basestocks is rendered in second Cooling or heating jar under normal temperature condition, fully stir after material all dissolves, be warming up to 88 DEG C of sterilizings 11 minutes;
(5) be cooled to 61 DEG C, add described C14-17 Seconary Alkane Sulphonate Sodium, stirring and dissolving;
(6) be cooled to 51 DEG C, add described octyl glucoside, insulated and stirred is dissolved, and adds citric acid and regulates pH=8;
(7) be cooled to 46 DEG C, add described two propyloic cocoyl ethyl tetrahydroglyoxaline sodium, methyl alcohol and borax, stir;
(8) be cooled to 39 DEG C, add described Sumizyme MP, amylase, methylchloroisothiazandnone, methylisothiazolinone and essence, after stirring, obtain a kind of laundry detergent.
Embodiment 10
A preparation method for laundry detergent, comprises the steps:
(1) raw material shown in embodiment 5 is taken by weight percentage:
(2) under normal temperature condition, described laureth-7, laureth-9, Prifer6813, laureth-3 and laureth sodium sulfovinate are added in first Cooling or heating jar, adds a small amount of deionized water, make it mix, obtain basestocks;
(3), under normal temperature condition, residue deionized water is poured in second Cooling or heating jar, drop into described Calcium Chloride Powder Anhydrous, stirring and dissolving;
(4) described basestocks is rendered in second Cooling or heating jar under normal temperature condition, fully stir after material all dissolves, be warming up to 90 DEG C of sterilizings 10 minutes;
(5) be cooled to 62 DEG C, add described C14-17 Seconary Alkane Sulphonate Sodium, stirring and dissolving;
(6) be cooled to 52 DEG C, add described octyl glucoside, insulated and stirred is dissolved, and adds citric acid and regulates pH=6;
(7) be cooled to 47 DEG C, add described two propyloic cocoyl ethyl tetrahydroglyoxaline sodium, methyl alcohol and borax, stir;
(8) be cooled to 40 DEG C, add described Sumizyme MP, amylase, methylchloroisothiazandnone, methylisothiazolinone and essence, after stirring, obtain a kind of laundry detergent.
Embodiment 11
Skin water loss test experiments.The function of skin water loss TEWL to assessment moisture of skin protective layer is very important parameter, has been widely recognized in the world.Moisture of skin protective layer is more intact, and the content of moisture will be higher, and the numerical value of skin water loss TEWL is lower, and the unit of TEWL is: g/hm
2.Skinanalysis apparatus is TewameterTM300.
Choose women 90 people between 20-50 year, be divided into 6 groups at random, often organize 15 people, under identical relative humidity (50%), temperature (25 DEG C) condition, respectively with the common commercially available washing liquid of certain brand and laundry detergent of the present invention (being followed successively by embodiment 6-10 preparation) cleaning hand, get same area carry out cleaning before and the rear skin test of cleaning.Before and after using laundry detergent of the present invention (being followed successively by embodiment 6-10 preparation) cleaning, water loss difference is on average followed successively by 11.3g/hm
2, 12.1g/hm
2, 12.0g/hm
2, 11.8g/hm
2and 12.4g/hm
2, use water loss difference average out to 27.1g/hm before and after the common commercially available washing liquid cleaning of certain brand
2, experimental result shows, after laundry detergent of the present invention uses to skin water loss rate very close to the skin water loss rate before use, illustrate that laundry detergent of the present invention is little to skin irritation.
Embodiment 12
Get the underwear (upper and lower clothing is a set of) that 18 are worn 5 days, be divided into 6 groups at random, often organize 3 covers, the 1st group is use commercially available conventional detergent, machine washing, water consumption 10L, clean-out system consumption 20mL; 2-6 group is followed successively by laundry detergent prepared by embodiment 6-10, water consumption 10L, clean-out system consumption 10mL; Each warm water soaking 20 minutes before washing, the 1st group when using 20 minutes, cleaned by underwear, the 2-6 group used time is followed successively by 14,15,15,14 and 15 minutes, is cleaned by underwear.
Claims (3)
1. a preparation method for laundry detergent, is characterized in that comprising the steps:
(1) raw material is taken by weight percentage: Calcium Chloride Powder Anhydrous 0.01-0.02%, laureth sodium sulfovinate 4-8%, laureth-93-5%, laureth-73-5%, laureth-31-3%, Prifer68130.5-1.2%, octyl glucoside 1-3%, borax 1-2%, C14-17 Seconary Alkane Sulphonate Sodium 2-4%, two propyloic cocoyl ethyl tetrahydroglyoxaline sodium 1-2%, methyl alcohol 0.5-1%, Sumizyme MP 0.3-0.5%, methylchloroisothiazandnone 0.01-0.03%, methylisothiazolinone 0.01-0.03%, amylase 0.2-0.5%, essence 0.1-0.2%, all the other are deionized water, described Prifer6813 is that CrodaSingaporePteLtd produces sale,
(2) under normal temperature condition, described laureth-7, laureth-9, Prifer6813, laureth-3 and laureth sodium sulfovinate are added in first Cooling or heating jar, adds a small amount of deionized water, make it mix, obtain basestocks;
(3), under normal temperature condition, residue deionized water is poured in second Cooling or heating jar, drop into described Calcium Chloride Powder Anhydrous, stirring and dissolving;
(4) described basestocks is rendered in second Cooling or heating jar under normal temperature condition, fully stir after material all dissolves, be warming up to 85 DEG C-90 DEG C sterilizing 10-15 minute;
(5) be cooled to 58-62 DEG C, add described C14-17 Seconary Alkane Sulphonate Sodium, stirring and dissolving;
(6) be cooled to 48-52 DEG C, add described octyl glucoside, insulated and stirred is dissolved, and adds citric acid and regulates pH=6-8;
(7) be cooled to 43-47 DEG C, add described two propyloic cocoyl ethyl tetrahydroglyoxaline sodium, methyl alcohol and borax, stir;
(8) be cooled to 36-40 DEG C, add described Sumizyme MP, amylase, methylchloroisothiazandnone, methylisothiazolinone and essence, after stirring, obtain a kind of laundry detergent.
2. the preparation method of a kind of laundry detergent according to claim 1, is characterized in that described essence is rose scent essence or lavender flavor type essence.
3. the laundry detergent prepared of the method for claim 1 or 2.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210094273.8A CN102634421B (en) | 2012-03-31 | 2012-03-31 | laundry detergent and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210094273.8A CN102634421B (en) | 2012-03-31 | 2012-03-31 | laundry detergent and preparation method thereof |
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| Publication Number | Publication Date |
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| CN102634421A CN102634421A (en) | 2012-08-15 |
| CN102634421B true CN102634421B (en) | 2016-02-17 |
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Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103740492A (en) * | 2013-12-27 | 2014-04-23 | 天津天狮生物发展有限公司 | Concentrated washing solution and preparation method thereof |
| CN107418765A (en) * | 2017-07-27 | 2017-12-01 | 合肥远科服装设计有限公司 | A kind of degerming liquid detergent not hurt hands of color protection |
| CN107603758A (en) * | 2017-10-13 | 2018-01-19 | 洛娃科技实业集团有限公司 | A kind of liquid detergent and preparation method |
| CN108441299B (en) * | 2018-04-13 | 2021-03-16 | 华阳新兴科技（天津）集团有限公司 | Water replacement type film anti-rust oil and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1322802A (en) * | 2001-06-04 | 2001-11-21 | 贾发颂 | Phosphate-free liquid detergent and its compounding process |
| CN102154068A (en) * | 2011-03-03 | 2011-08-17 | 天津天狮生物发展有限公司 | Multifunctional detergent and preparation method thereof |
-
2012
- 2012-03-31 CN CN201210094273.8A patent/CN102634421B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1322802A (en) * | 2001-06-04 | 2001-11-21 | 贾发颂 | Phosphate-free liquid detergent and its compounding process |
| CN102154068A (en) * | 2011-03-03 | 2011-08-17 | 天津天狮生物发展有限公司 | Multifunctional detergent and preparation method thereof |
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| CN102634421A (en) | 2012-08-15 |
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