CN1322802A - Phosphate-free liquid detergent and its compounding process - Google Patents
Phosphate-free liquid detergent and its compounding process Download PDFInfo
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- CN1322802A CN1322802A CN 01114233 CN01114233A CN1322802A CN 1322802 A CN1322802 A CN 1322802A CN 01114233 CN01114233 CN 01114233 CN 01114233 A CN01114233 A CN 01114233A CN 1322802 A CN1322802 A CN 1322802A
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Abstract
The present invention relates to fine chemical industry. The detergent of the present invention is produced with sodium alkylbenzenesulfonate, fatty alcohol polyoxyethyleneether sodium sulfate, cocoanut oil amidopropyl betaine, cocinin diethanolamide, liquid proteinase, glycerine, calcium chloride, deionized water and other material and through certain technological process. The detergent has high detergency, disinfection effect and no damage to body and clothing, and is used in washing clothing, including underclothing.
Description
The present invention relates to a kind of liquid washing agent, particularly relate to a kind of phosphate-free liquid detergent, belong to the fine chemistry industry class.
As everyone knows, the major function of washing composition is scrubbing.In order to adapt to user's needs, emerge all kinds in the market, emerge in an endless stream as washing composition such as environment-friendly type, sterilization types.But, most washing composition are being taken into account under the multiple functional situation, the major function of often having ignored scrubbing, edit with Mr. Wang Daquan, Chemical Industry Press publishes, in two ones the 797th page of the title " fine chemistry industry flow chart ", name of product " underwear detergent with sterilizing ", the technical characterstic of this product is the without phosphorus environmental protection that helps, added the higher pure as jade new work disinfectant of security, but because main component concentration 30% sodium alkyl benzene sulfonate (content is 20%) is bigger to water hardness susceptibility in this product, and stable influential to liquid protease, unsuitable enzyme-added in product, when more protein dirt, it is indifferent that it removes dirt, especially not strong to the underclothes detersive power.
Purpose of the present invention is exactly in order to remedy above-mentioned technical deficiency, by changing component and weight percent thereof, provides a kind of safety non-toxic, strong detergency, wash degree height, phosphate-free liquid detergent and method for formulating thereof simple for production.
Technical scheme of the present invention is to realize like this.The present invention is made of following material component and weight percent thereof: the sodium alkyl benzene sulfonate 0-10% of concentration 30% is selected in preparation for use, polyoxyethylenated alcohol sodium sulfate 5-20%, the Oleum Cocois amido propyl betaine 10-20% of concentration 30%, coconut acid diethanolamide (1: 1 type) 2-6%, liquid protease .3-1%, glycerine 2-5%, borax 0.5-2%, deionized water 50-60% and a little pH regulator agent (add-on of conditioning agent is the pH value-7.5 that makes this washing composition).Method for formulating of the present invention is: at first the sodium alkyl benzene sulfonate add-on with concentration 30% is 0-10%, the polyoxyethylenated alcohol sodium sulfate add-on is 5-20%, the Oleum Cocois amido propyl betaine add-on of concentration 30% is 10-20%, 1: 1 type of coconut acid diethanolamide, its add-on is 2-6%, add together that to fill temperature be that 50-60 ℃ of add-on is in the reactor of 50-60% deionized water, thorough mixing, cool the temperature to then below 30 ℃, be the glycerine add-on 2-5% again, the borax add-on is 0.5-2%, the liquid protease add-on is that 0.3-1% and calcium chloride add-on are 0.05-0.1%, sequentially it being added above-mentioned mixed solution mixes, add the pH regulator agent with above-mentioned mixed solution adjust pH to 7-7.5, be more than or equal to 99% with concentration again, add-on is that the triclosan of 0.3-1% adds and to stir (can use agitator, also can manually stir) in the mixed solution and be finished product (phosphate-free liquid detergent).The adding of above-mentioned component glycerine and borax plays the stabilize proteins enzyme, and the adding of calcium chloride plays the activated protein enzyme.
Phosphate-free liquid detergent involved in the present invention and method for formulating thereof, owing to add the anti-performance of hard water that polyoxyethylenated alcohol sodium sulfate can improve washing composition, can improve simultaneously the stability of proteolytic enzyme, it again can with concentration 30% sodium alkyl benzene sulfonate synergy decontamination; Because concentration 30% sodium alkyl benzene sulfonate consumption reduces or do not add, also reduced the degreasing destruction of this washing composition in addition to high-grade clothing.It is at the composition of underclothes dirt and add that the present invention adds liquid protease, can improve the soil removability of the present invention and the property rate of exchange greatly.The present invention have without phosphorus environmental, clothing is not had that burn into is harmless, soil removability strong (its clean effect doubles than existing free phosphate detergent), wash degree height, has effect such as sterilization concurrently; Technology of the present invention is simple, easy to make, be easy to produce in batches, can be widely used in various clothings, particularly to the washing of underclothes, clean effect spy is good.
Embodiments of the invention 1: prepare by following component and weight percent thereof, and can make finished product by above-mentioned method for formulating;
Composition per-cent
Sodium alkyl benzene sulfonate (concentration 30%) 0%
Polyoxyethylenated alcohol sodium sulfate 18%
Oleum Cocois amido propyl betaine (concentration 30%) 20%
1: 1 type 3% of coconut acid diethanolamide
Liquid protease 0.3%
Glycerine 3%
Borax 1%
Triclosan (concentration 〉=99%) 0.3%
Calcium chloride 0.06%
The deionized water surplus
The pH regulator agent a little
Embodiment 2: prepare by following component and weight percent thereof, and can make finished product by above-mentioned method for formulating;
Composition per-cent
Sodium alkyl benzene sulfonate (concentration 30%) 5%
Polyoxyethylenated alcohol sodium sulfate 15%
Oleum Cocois amido propyl betaine (concentration 30%) 15%
1: 1 type 4% of coconut acid diethanolamide
Liquid protease 0.35%
Glycerine 3%
Borax 0.5%
Triclosan (concentration 〉=99%) 0.4%
Calcium chloride 0.06%
The deionized water surplus
The pH regulator agent a little
Embodiment 3: prepare by following component and weight percent thereof, and can make finished product by above-mentioned method for formulating;
Composition per-cent
Sodium alkyl benzene sulfonate (concentration 30%) 6%
Fat polyoxyethylenated alcohol sodium sulfate 12%
Oleum Cocois amido propyl betaine (concentration 30%) 20%
1: 1 type 4% of coconut acid diethanolamide
Liquid protease 1%
Glycerine 5%
Borax 2%
Triclosan (concentration 〉=99%) 0.3%
Calcium chloride 0.06%
The deionized water surplus
The pH regulator agent a little
Illustrate: surplus is meant that the add-on percentage ratio of deionized water equals absolutely to deduct the difference of other each component add-on percentage ratio sum gained.
Claims (2)
1, a kind of phosphate-free liquid detergent, it is characterized in that, it is to select following component and weight percent thereof for use: the sodium alkyl benzene sulfonate 0-10% of concentration 30%, polyoxyethylenated alcohol sodium sulfate 5-20%, the Oleum Cocois amido propyl betaine 10-20% of concentration 30%, coconut acid diethanolamide (1: 1 type) 2--6%, liquid protease 0.3-10%, glycerine 2-5%, borax 0.5-2%, concentration is more than or equal to 99% triclosan 0.3%-1%, calcium chloride 0.05-0.1%, deionized water 50-60%.
2, a kind of method for formulating of phosphate-free liquid detergent according to claim 1, it is characterized in that, at first with the sodium alkyl benzene sulfonate of concentration 30%, its add-on is 0-10%, polyoxyethylenated alcohol sodium sulfate, its add-on is 5-20%, the Oleum Cocois amido propyl betaine of concentration 30%, its add-on is 10-20%, 1: 1 type of coconut acid diethanolamide, its add-on is 2-6%, and adding temperature together is that 50-60 ℃ of add-on is thorough mixing in the 50-60% deionized water; Cooling the temperature to then below 30 ℃, is the glycerine add-on 2-5% again, and its add-on of borax is 0.5-2%, and its add-on of liquid protease is that 0.3-1% and its add-on of calcium chloride are 0.05-0.1%, it is added in the above-mentioned mixed solution mix sequentially; To 7-7.5, is 99% with concentration again with a small amount of pH regulator agent adjust pH, and add-on is that the triclosan of 0.3-1% adds to stir in the mixed solution and is finished product.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 01114233 CN1322802A (en) | 2001-06-04 | 2001-06-04 | Phosphate-free liquid detergent and its compounding process |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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CN 01114233 CN1322802A (en) | 2001-06-04 | 2001-06-04 | Phosphate-free liquid detergent and its compounding process |
Publications (1)
Publication Number | Publication Date |
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CN1322802A true CN1322802A (en) | 2001-11-21 |
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CN 01114233 Pending CN1322802A (en) | 2001-06-04 | 2001-06-04 | Phosphate-free liquid detergent and its compounding process |
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Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101985586A (en) * | 2010-11-29 | 2011-03-16 | 陕西永泰生物工程有限责任公司 | Detergent composition special for vegetables and fruits and preparation method thereof |
CN101985585A (en) * | 2010-11-29 | 2011-03-16 | 陕西永泰生物工程有限责任公司 | All cotton cloth detergent composition and preparation method thereof |
CN101985584A (en) * | 2010-11-29 | 2011-03-16 | 陕西永泰生物工程有限责任公司 | Detergent composition for silk and woolen clothes and preparation method thereof |
CN101457182B (en) * | 2009-01-08 | 2011-03-30 | 立宇化学技术(郑州)有限公司 | Liquid enzyme film cleaning agent |
CN101422149B (en) * | 2007-10-31 | 2011-08-17 | 李忠泽 | Environmental protection efficient disinfectant prepared by coconut oil as basis raw material |
CN102443494A (en) * | 2010-10-11 | 2012-05-09 | 郑州大学 | Washing agent specially used for female underpants and its preparation method |
CN102634421A (en) * | 2012-03-31 | 2012-08-15 | 天津天狮生物发展有限公司 | Clothes washing agent and preparation method thereof |
CN104099185A (en) * | 2014-06-25 | 2014-10-15 | 无锡市崇安区科技创业服务中心 | Liquid detergent special for underwears and preparation method for liquid detergent |
CN108384673A (en) * | 2018-05-08 | 2018-08-10 | 罗彦明 | Environment friendly laundry liquid |
CN108410596A (en) * | 2018-05-08 | 2018-08-17 | 罗彦明 | Multifunctional laundry liquid and its preparation process |
CN109666547A (en) * | 2018-12-17 | 2019-04-23 | 福州立洁生物科技有限公司 | A kind of Antibiotic liquid detergent and preparation method thereof |
CN109735400A (en) * | 2019-01-11 | 2019-05-10 | 钱潮 | Cashmere woolen garment dedicated wet lotion |
-
2001
- 2001-06-04 CN CN 01114233 patent/CN1322802A/en active Pending
Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101422149B (en) * | 2007-10-31 | 2011-08-17 | 李忠泽 | Environmental protection efficient disinfectant prepared by coconut oil as basis raw material |
CN101457182B (en) * | 2009-01-08 | 2011-03-30 | 立宇化学技术(郑州)有限公司 | Liquid enzyme film cleaning agent |
CN102443494A (en) * | 2010-10-11 | 2012-05-09 | 郑州大学 | Washing agent specially used for female underpants and its preparation method |
CN101985584B (en) * | 2010-11-29 | 2013-01-23 | 陕西永泰生物工程有限责任公司 | Detergent composition for silk and woolen clothes and preparation method thereof |
CN101985585A (en) * | 2010-11-29 | 2011-03-16 | 陕西永泰生物工程有限责任公司 | All cotton cloth detergent composition and preparation method thereof |
CN101985584A (en) * | 2010-11-29 | 2011-03-16 | 陕西永泰生物工程有限责任公司 | Detergent composition for silk and woolen clothes and preparation method thereof |
CN101985586A (en) * | 2010-11-29 | 2011-03-16 | 陕西永泰生物工程有限责任公司 | Detergent composition special for vegetables and fruits and preparation method thereof |
CN102634421A (en) * | 2012-03-31 | 2012-08-15 | 天津天狮生物发展有限公司 | Clothes washing agent and preparation method thereof |
CN102634421B (en) * | 2012-03-31 | 2016-02-17 | 天津天狮生物发展有限公司 | laundry detergent and preparation method thereof |
CN104099185A (en) * | 2014-06-25 | 2014-10-15 | 无锡市崇安区科技创业服务中心 | Liquid detergent special for underwears and preparation method for liquid detergent |
CN108384673A (en) * | 2018-05-08 | 2018-08-10 | 罗彦明 | Environment friendly laundry liquid |
CN108410596A (en) * | 2018-05-08 | 2018-08-17 | 罗彦明 | Multifunctional laundry liquid and its preparation process |
CN109666547A (en) * | 2018-12-17 | 2019-04-23 | 福州立洁生物科技有限公司 | A kind of Antibiotic liquid detergent and preparation method thereof |
CN109735400A (en) * | 2019-01-11 | 2019-05-10 | 钱潮 | Cashmere woolen garment dedicated wet lotion |
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