CN102443494A - Washing agent specially used for female underpants and its preparation method - Google Patents
Washing agent specially used for female underpants and its preparation method Download PDFInfo
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- CN102443494A CN102443494A CN2010105024451A CN201010502445A CN102443494A CN 102443494 A CN102443494 A CN 102443494A CN 2010105024451 A CN2010105024451 A CN 2010105024451A CN 201010502445 A CN201010502445 A CN 201010502445A CN 102443494 A CN102443494 A CN 102443494A
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Abstract
The invention belongs to a washing agent, concretely relates to the washing agent specially used for female underpants with the characteristics of stable product performance, long storage life, strong multienzyme decomposition capability on organic matter, good effect for cleaning the contaminants on the female underpants, bacteriostasis and disinfection, and its preparation method. The washing agent comprises the following raw materials by weight part: 50-118 parts of surfactant, 10-34 parts of propylene glycol, 10-34 parts of triethanolamine, 1 part of ethylparaben, 12-40 parts of enzyme stabilizing agent, 1-26 parts of sodium hydrosulphite, 0.04-2 parts of calcium chloride, 2-25 parts of sodium citrate, 4-20 parts of citric acid, 2-15 parts of protease, 3-10 parts of biological enzyme used for compound and 11-238 parts of deionized water; has the advantages of good hard water resistance, nontoxicity and innocuousness, flexibility, antistatic property and shrink resistance, and is capable of obviously increasing the softness of the washed cotton fabric, so that the fabric is soft and the color is white, the washing agent has inhibition effects for a plurality of bacteria and mildew, and the cleanness and sanitation of the underpants can be ensured.
Description
Technical field
The invention belongs to washing composition, be specifically related to that a kind of product performance are stable, the shelf lives long, multienzyme decomposing organic matter ability is strong, clean underpants for women special purpose detergent of the effective and antibacterial disinfection of dirt on the underpants for women and preparation method thereof.
Background technology
The application of enzyme in Betengent product is one of great technical progress in the detergent industry evolution.What the initial stage used is single proteolytic enzyme, has developed the application of glycase, cellulase, lypase later on successively, and the synergistic application of two or more enzyme.These development make washing composition over-all properties be improved significantly, quality product has had large increase.But enzyme itself is a protein structure; Enzyme is in active condition in liquid washing agent; Proteolytic enzyme can decompose other enzymes of destruction; Even decomposition of protein enzyme self, so other enzymes can not be composite in same system with proteolytic enzyme, even it is also shorter to contain the liquid washing agent storage life of single proteolytic enzyme.And with the multienzyme detergent that solid particulate exists, do not disturb mutually between the multiple prozyme, be beneficial to storage, but will earlier the solid particulate dissolving that contains multienzyme be scattered in the water when using, discharge enzyme, produce actively, give like this to operate and bring a lot of inconvenience.
The cleaning of underpants for women has brought a lot of troubles for numerous women compatriot in the daily life; The bloodstain that particularly is stained with between holiday and usual attached to the secretory product such as leukorrhea on the underpants; These spots are difficult to clean up, and as easy as rolling off a logly stay yellow vestige, and are particularly evident on the cotton underpants.Usually wash underpants for women with washing powder; Tend to cause spot residual; And because harmful chemicals such as the phosphorus that washing powder contains, benzene, lead are difficult for thoroughly removing; The clothing of residual these noxiouss of long-time dress can cause pachylosis, peels, itch, and seriously then can cause diseases such as contact dermatitis.And washing powder clean the back residual sodium alkyl benzene sulfonate be prone to cause the women to suffer from vaginitis, mammary cancer, be that hysteromyoma, Infertility, gynopathic arch-criminal are taken place.
Summary of the invention
The objective of the invention is to overcome defective of the prior art and provide that a kind of product performance are stable, the shelf lives long, multienzyme decomposing organic matter ability is strong, clean underpants for women special purpose detergent of the effective and antibacterial disinfection of dirt on the underpants for women and preparation method thereof.
The objective of the invention is to realize like this: formulated according to parts by weight by following raw material: tensio-active agent 50-118 part, Ucar 35 10-34 part, trolamine 10-34 part, 1 part of ethyl p-hydroxybenzoate, enzyme stabilizers 12-40 part, S-WAT 1-26 part, calcium chloride 0.04-2 part, Trisodium Citrate 2-25 part, Hydrocerol A 4-20 part, proteolytic enzyme 2-15 part are composite with enzyme 3-10 part and deionized water 11-238 part.Described tensio-active agent is selected from AEO, AS and APG and their mixture.Described enzyme stabilizers is selected from borax and sodium acetate and their mixture.Describedly compositely be selected from glycase with enzyme, cellulase and lypase and their mixture.
The preparation method of underpants for women special purpose detergent of the present invention comprises the steps:
A, be dissolved in ethyl p-hydroxybenzoate in the Ucar 35 after;
B, the mixing solutions among the step a is added tensio-active agent mix;
C, deionized water is heated to 30 ℃-40 ℃;
D, the deionized water after the heating among the step c added fully dissolving in the mixture that adds among the step b behind the tensio-active agent;
E, the mixture that adds in the steps d behind the deionized water dissolving is added enzyme stabilizers, S-WAT, uniform mixing behind calcium chloride and the Trisodium Citrate successively;
F, the mixing solutions that obtains among the step e is added trolamine, uniform mixing;
G, the mixing solutions behind the adding trolamine among the step f is extremely neutral with the lemon acid for adjusting pH;
H, add proteolytic enzyme and composite and stir with enzyme with being adjusted to neutral solution in the step g, finished product.
The present invention and Business Name are: the Doraemon woman pants washing composition that Shanghai Doraemon makeup ltd produces compares.
1, kapillary identification method
The first step: get 1mL the present invention and 1mL contrast product and be positioned over respectively in two beakers, in two beakers, add ordinary tap water respectively and be diluted to 500 times; Second step: the fresh rabbit blood of kapillary absorption equivalent of getting 100 altogether is subsequent use; The 3rd step: 100 among the step b kapillaries of drawing fresh rabbit blood are divided into identical two groups of quantity put into described two beakers of step a respectively; The 4th step: described two beakers of step c were used ultrasonic cleaning respectively 10 minutes.
Wash result is: it is 38 that the present invention cleans the pipe number, and contrast product is cleaned several 9 of pipe.
2, standard soiled cloth method
The first step: get 1mL the present invention and 1mL contrast product and be positioned over respectively in two beakers, in two beakers, add ordinary tap water and be diluted to 400 times; Second step: the cotton calico is cut into the rectangle calico of a wide 5cm of long 10cm, rectangle cotton calico is immersed in the fresh rabbit blood, take out after 5 minutes and dry; The 3rd step: the rectangle cotton calico after drying among the step b is cut into the square of the wide 5cm of two block length 5cm, puts into described two beakers of step a respectively; The 4th step: described two beakers of step c were used ultrasonic cleaning respectively 10 minutes; The 5th step: compare after the cotton calico of the wide 5cm of two block length 5cm dried.
Cleaning performance: thoroughly to clean be 3 minutes to bloodstain on the cotton, and to clean fully be 2 minutes to bloodstain on the cotton, on the cotton bloodstain with clean before not too big difference be 1 minute
Wash result is: the present invention must be divided into 3 fens, and contrast product must be divided into 1 fen.
3, washing method in kind
The first step: collect 20 of underpants speckling with women's menstrual blood; Second step: get 20mL the present invention and 20mL contrast product and be positioned over respectively in two small washing machines, in two small washing machines, add ordinary tap water respectively and be diluted to 400 times; The 3rd step: with 20 of the underpants of the women's menstrual blood among the step a, be divided into two groups of equal amts, put into described two small washing machines of step b respectively; The 4th step: the women's menstrual blood underpants in described two small washing machines of step c cleaned respectively 10 minutes; The 5th step: 20 women's menstrual blood underpants are dried compare.
Cleaning performance: thoroughly to clean be 3 minutes to bloodstain on the underpants, and to clean fully be 2 minutes to bloodstain on the underpants, on the underpants bloodstain with clean before not too big difference be 1 minute
Wash result is: the present invention must be divided into 26 fens, and contrast product must be divided into 14 fens.
The present invention uses Ucar 35, trolamine, S-WAT and enzyme stabilizers can effectively protect multiple biological enzyme activity; Prevent to decompose each other to destroy, cooperate the composite cleanup action of kinds of surface promoting agent and the preservative activity of ethyl p-hydroxybenzoate to process the present invention again; Product performance of the present invention are stable, the shelf lives is long, and multienzyme decomposing organic matter ability is strong, clean the respond well of dirt on the underpants, antibacterial disinfectant effect arranged, and bloodstain is had the clean effect of mystery.Neutral pH of the present invention, composition is natural, character is gentle, does not hinder skin and is fit to hand washing.The anti-hard water property of the present invention is good, nontoxic and have performances such as flexibility, static resistance and shrink resistance concurrently, can obviously increase wash the back cotton fabric have softly, fabric sofetening and color and luster are brightened.The present invention contains disinfection sanitizer, and various bacteria, mould are all had restraining effect, can guarantee the underpants sanitation and hygiene.The without phosphorus prescription of the present invention, the height environmental protection, biological degradability surpasses 90%.Using only needs when of the present invention the washing composition dilution is got final product, easy to operate, is easy to rinsing.
The present invention is fit to the cleaning of underpants for women, particularly speckles with the underpants of menstruation bloodstain, can increase obviously that to wash having of back cotton fabric soft, and fabric sofetening, color and luster are brightened.The present invention is suitable for the cleaning that the fabric and the medicine equipment of bloodstain are infected with by hospital, the for example cleaning of article such as scalpel, mosquito forceps, medical endoscope equally.The medical endoscope passage is narrow; Use the back owing to be infected with organism such as blood, mucous membrane tissue, human excrement and urine; And cause obstruction; Difficulty very when so the washing composition that uses common washing composition or contain single enzyme cleans this type of apparatus, and cleaning performance is bad, and residual things such as bacterium are prone to when reusing, cause infection.The present invention contains highly active enzyme, and plurality of enzymes acts synergistically, and can effectively decompose human secretion, has both reduced the high maintenance service of instruments, reaches better effect in the time of can making sterilization again, avoids occurring superinfection.
Embodiment
The present invention is formulated according to parts by weight by following raw material: tensio-active agent 50-118 part, Ucar 35 10-34 part, trolamine 10-34 part, 1 part of ethyl p-hydroxybenzoate, enzyme stabilizers 12-40 part, S-WAT 1-26 part, calcium chloride 0.04-2 part, Trisodium Citrate 2-25 part, Hydrocerol A 4-20 part, proteolytic enzyme 2-15 part are composite with enzyme 3-10 part and deionized water 11-238 part.Described tensio-active agent is selected from AEO, AS and APG and their mixture.Described enzyme stabilizers is selected from borax and sodium acetate and their mixture.Describedly compositely be selected from glycase with enzyme, cellulase and lypase and their mixture.
The preparation method of underpants for women special purpose detergent of the present invention comprises the steps:
A, be dissolved in ethyl p-hydroxybenzoate in the Ucar 35 after;
B, the mixing solutions among the step a is added tensio-active agent mix;
C, deionized water is heated to 30 ℃-40 ℃;
D, the deionized water after the heating among the step c added fully dissolving in the mixture that adds among the step b behind the tensio-active agent;
E, the mixture that adds in the steps d behind the deionized water dissolving is added enzyme stabilizers, S-WAT, uniform mixing behind calcium chloride and the Trisodium Citrate successively;
F, the mixing solutions that obtains among the step e is added trolamine, uniform mixing;
G, the mixing solutions behind the adding trolamine among the step f is extremely neutral with the lemon acid for adjusting pH;
H, add proteolytic enzyme and composite and stir with enzyme with being adjusted to neutral solution in the step g, finished product.
Below in conjunction with specific embodiment, further specify the present invention:
Embodiment 1
AEO 50 grams, Ucar 35 10 grams, trolamine 10 grams, ethyl p-hydroxybenzoate 1 gram, borax 12 grams, S-WAT 1 gram, calcium chloride 0.04 gram, Trisodium Citrate 2 grams, Hydrocerol A 4 grams, proteolytic enzyme 2 grams, glycase 3 grams and deionized water 11 grams.
A, be dissolved in ethyl p-hydroxybenzoate in the Ucar 35 after;
B, the mixing solutions among the step a is added AEO mix;
C, deionized water is heated to 30 ℃;
D, the deionized water after the heating among the step c added fully dissolving in the mixture that adds among the step b behind the AEO;
E, the mixture that adds in the steps d behind the deionized water dissolving is added borax, S-WAT, uniform mixing behind calcium chloride and the Trisodium Citrate successively;
F, the mixing solutions that obtains among the step e is added trolamine, uniform mixing;
G, the mixing solutions behind the adding trolamine among the step f is extremely neutral with the lemon acid for adjusting pH;
H, neutral solution adds proteolytic enzyme and glycase stirs with being adjusted in the step g, finished product.
Embodiment 2
AS 84 grams, Ucar 35 22 grams, trolamine 22 grams, 1 part of ethyl p-hydroxybenzoate, sodium acetate 26 grams, S-WAT 13.5 grams, calcium chloride 1.02 grams, Trisodium Citrate 13.5 grams, Hydrocerol A 12 grams, proteinase 8 .5 gram, cellulase 6.5 grams and deionized water 124.5 grams.
A, be dissolved in ethyl p-hydroxybenzoate in the Ucar 35 after;
B, the mixing solutions among the step a is added AS mix;
C, deionized water is heated to 35 ℃;
D, the deionized water after the heating among the step c added fully dissolving in the mixture that adds among the step b behind the AS;
E, the mixture that adds in the steps d behind the deionized water dissolving is added sodium acetate, S-WAT, uniform mixing behind calcium chloride and the Trisodium Citrate successively;
F, the mixing solutions that obtains among the step e is added trolamine, uniform mixing;
G, the mixing solutions behind the adding trolamine among the step f is extremely neutral with the lemon acid for adjusting pH;
H, neutral solution adds proteolytic enzyme and cellulase stirs with being adjusted in the step g, finished product.
Embodiment 3
APG 118 grams, Ucar 35 34 grams, trolamine 34 grams, ethyl p-hydroxybenzoate 1 gram, borax 10 grams, sodium acetate 30 grams, S-WAT 26 grams, calcium chloride 2 grams, Trisodium Citrate 25 grams, Hydrocerol A 20 grams, proteolytic enzyme 15 grams, lypase 10 grams and deionized water 238 grams.
A, be dissolved in ethyl p-hydroxybenzoate in the Ucar 35 after;
B, the mixing solutions among the step a is added APG mix;
C, deionized water is heated to 40 ℃;
D, the deionized water after the heating among the step c added fully dissolving in the mixture that adds among the step b behind the APG;
E, the mixture that adds in the steps d behind the deionized water dissolving is added borax, sodium acetate, S-WAT, uniform mixing behind calcium chloride and the Trisodium Citrate successively;
F, the mixing solutions that obtains among the step e is added trolamine, uniform mixing;
G, the mixing solutions behind the adding trolamine among the step f is extremely neutral with the lemon acid for adjusting pH;
H, neutral solution adds proteolytic enzyme and lypase stirs with being adjusted in the step g, finished product.
Embodiment 4
AEO 40 grams, AS 20 grams, APG 110 grams, Ucar 35 60 grams, trolamine 60 grams, ethyl p-hydroxybenzoate 3 grams, borax 30 grams, sodium acetate 10 grams, S-WAT 35 grams, calcium chloride 4 grams, Trisodium Citrate 50 grams, Hydrocerol A 40 grams, protease 30 gram, glycase 5 grams, cellulase 4 grams, lypase 11 grams and deionized water 488 grams.
A, be dissolved in ethyl p-hydroxybenzoate in the Ucar 35 after;
B, the mixing solutions among the step a is added AEO, AS and APG mix;
C, deionized water is heated to 32 ℃;
D, the deionized water after the heating among the step c added among the step b add AEO, fully dissolve in the mixture behind AS and the APG;
E, the mixture that adds in the steps d behind the deionized water dissolving is added borax, sodium acetate, S-WAT, uniform mixing behind calcium chloride and the Trisodium Citrate successively;
F, the mixing solutions that obtains among the step e is added trolamine, uniform mixing;
G, the mixing solutions behind the adding trolamine among the step f is extremely neutral with the lemon acid for adjusting pH;
H, add proteolytic enzyme, glycase with being adjusted to neutral solution in the step g, cellulase and lypase stir, finished product.
Embodiment 5
AEO 1360 grams and AS 1000 grams, Ucar 35 680 grams, trolamine 680 grams, ethyl p-hydroxybenzoate 30 grams, borax 600 grams, sodium acetate 200 grams, S-WAT 520 grams, calcium chloride 40 grams, Trisodium Citrate 500 grams, Hydrocerol A 400 grams, protease 3 00 gram, glycase 120 grams, cellulase 70 grams and deionized water 3500 grams.
A, be dissolved in ethyl p-hydroxybenzoate in the Ucar 35 after;
B, the mixing solutions among the step a is added AEO and AS mixes;
C, deionized water is heated to 38 ℃;
D, the deionized water after the heating among the step c added fully dissolving in the mixture that adds among the step b behind AEO and the AS;
E, the mixture that adds in the steps d behind the deionized water dissolving is added borax, sodium acetate, S-WAT, uniform mixing behind calcium chloride and the Trisodium Citrate successively;
F, the mixing solutions that obtains among the step e is added trolamine, uniform mixing;
G, the mixing solutions behind the adding trolamine among the step f is extremely neutral with the lemon acid for adjusting pH;
H, add proteolytic enzyme, glycase and cellulase and stir being adjusted to neutral solution in the step g, finished product.
Embodiment 6
AEO 50 grams, APG 115 grams, Ucar 35 68 grams, trolamine 60 grams, ethyl p-hydroxybenzoate 3 grams, borax 50 grams, S-WAT 52 grams, calcium chloride 4 grams, Trisodium Citrate 50 grams, Hydrocerol A 40 grams, protease 30 gram, glycase 15 grams, lypase 5 grams and deionized water 458 grams.
A, be dissolved in ethyl p-hydroxybenzoate in the Ucar 35 after;
B, the mixing solutions among the step a is added AEO and APG mixes;
C, deionized water is heated to 32 ℃;
D, the deionized water after the heating among the step c added fully dissolving in the mixture that adds among the step b behind AEO and the APG;
E, the mixture that adds in the steps d behind the deionized water dissolving is added borax, S-WAT, uniform mixing behind calcium chloride and the Trisodium Citrate successively;
F, the mixing solutions that obtains among the step e is added trolamine, uniform mixing;
G, the mixing solutions behind the adding trolamine among the step f is extremely neutral with the lemon acid for adjusting pH;
H, add proteolytic enzyme with being adjusted to neutral solution in the step g, glycase and lypase stir, finished product.
Embodiment 7
AS 15 grams, APG 36 grams, Ucar 35 16 grams, trolamine 18 grams, ethyl p-hydroxybenzoate 0.9 gram, borax 10 grams, S-WAT 16 grams, calcium chloride 1.6 grams, Trisodium Citrate 18 grams, Hydrocerol A 16 grams, proteolytic enzyme 12.5 grams, cellulase 4 grams, lypase 6 grams and deionized water 130 grams.
A, be dissolved in ethyl p-hydroxybenzoate in the Ucar 35 after;
B, the mixing solutions among the step a is added AS and APG mixes;
C, deionized water is heated to 34 ℃;
D, the deionized water after the heating among the step c added fully dissolving in the mixture that adds among the step b behind AS and the APG;
E, the mixture that adds in the steps d behind the deionized water dissolving is added borax, S-WAT, uniform mixing behind calcium chloride and the Trisodium Citrate successively;
F, the mixing solutions that obtains among the step e is added trolamine, uniform mixing;
G, the mixing solutions behind the adding trolamine among the step f is extremely neutral with the lemon acid for adjusting pH;
H, add proteolytic enzyme with being adjusted to neutral solution in the step g, cellulase and lypase stir, finished product.
The present invention is not limited to the foregoing description.
Claims (5)
1. underpants for women special purpose detergent; It is characterized in that: formulated according to parts by weight by following raw material: tensio-active agent 50-118 part, Ucar 35 10-34 part, trolamine 10-34 part, 1 part of ethyl p-hydroxybenzoate, enzyme stabilizers 12-40 part, S-WAT 1-26 part, calcium chloride 0.04-2 part, Trisodium Citrate 2-25 part, Hydrocerol A 4-20 part, proteolytic enzyme 2-15 part are composite with enzyme 3-10 part and deionized water 11-238 part.
2. underpants for women special purpose detergent according to claim 1 is characterized in that: described tensio-active agent is selected from AEO, AS and APG and their mixture.
3. underpants for women special purpose detergent according to claim 1 is characterized in that: described enzyme stabilizers is selected from borax and sodium acetate and their mixture.
4. underpants for women special purpose detergent according to claim 1 is characterized in that: describedly compositely be selected from glycase with enzyme, cellulase and lypase and their mixture.
5. the preparation method of the described underpants for women special purpose detergent of claim 1 is characterized in that: comprise the steps:
A, be dissolved in ethyl p-hydroxybenzoate in the Ucar 35 after;
B, the mixing solutions among the step a is added tensio-active agent mix;
C, deionized water is heated to 30 ℃-40 ℃;
D, the deionized water after the heating among the step c added fully dissolving in the mixture that adds among the step b behind the tensio-active agent;
E, the mixture that adds in the steps d behind the deionized water dissolving is added enzyme stabilizers, S-WAT, uniform mixing behind calcium chloride and the Trisodium Citrate successively;
F, the mixing solutions that obtains among the step e is added trolamine, uniform mixing;
G, the mixing solutions behind the adding trolamine among the step f is extremely neutral with the lemon acid for adjusting pH;
H, add proteolytic enzyme and composite and stir with enzyme with being adjusted to neutral solution in the step g, finished product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN 201010502445 CN102443494B (en) | 2010-10-11 | 2010-10-11 | Washing agent specially used for female underpants and its preparation method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN 201010502445 CN102443494B (en) | 2010-10-11 | 2010-10-11 | Washing agent specially used for female underpants and its preparation method |
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| CN102443494A true CN102443494A (en) | 2012-05-09 |
| CN102443494B CN102443494B (en) | 2013-01-23 |
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| CN106590975A (en) * | 2016-12-07 | 2017-04-26 | 四川昂迈维商贸有限公司 | Novel cloth washing water and preparation method thereof |
| CN106753825A (en) * | 2016-12-30 | 2017-05-31 | 江阴市本特塞缪森生命科学研究院有限公司 | A kind of composition for cleaning underwear |
| CN110408481A (en) * | 2019-08-16 | 2019-11-05 | 浙江芬尼奇工贸有限公司 | A kind of clothing stain removal agent and its preparation process |
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| CN110408481A (en) * | 2019-08-16 | 2019-11-05 | 浙江芬尼奇工贸有限公司 | A kind of clothing stain removal agent and its preparation process |
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| Publication number | Publication date |
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| CN102443494B (en) | 2013-01-23 |
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