KR101753371B1 - Washing Tablet - Google Patents
Washing Tablet Download PDFInfo
- Publication number
- KR101753371B1 KR101753371B1 KR1020170028570A KR20170028570A KR101753371B1 KR 101753371 B1 KR101753371 B1 KR 101753371B1 KR 1020170028570 A KR1020170028570 A KR 1020170028570A KR 20170028570 A KR20170028570 A KR 20170028570A KR 101753371 B1 KR101753371 B1 KR 101753371B1
- Authority
- KR
- South Korea
- Prior art keywords
- weight
- washing
- sodium
- tablet
- hydrogen
- Prior art date
Links
- 238000005406 washing Methods 0.000 title claims abstract description 50
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 32
- 238000000034 method Methods 0.000 claims abstract description 3
- 239000001257 hydrogen Substances 0.000 claims description 22
- 229910052739 hydrogen Inorganic materials 0.000 claims description 22
- 239000003599 detergent Substances 0.000 claims description 18
- 108091005804 Peptidases Proteins 0.000 claims description 14
- GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 claims description 13
- 239000000203 mixture Substances 0.000 claims description 13
- 239000000843 powder Substances 0.000 claims description 13
- 239000004365 Protease Substances 0.000 claims description 12
- GVJHHUAWPYXKBD-UHFFFAOYSA-N (±)-α-Tocopherol Chemical compound OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 claims description 11
- 230000000694 effects Effects 0.000 claims description 11
- 102000004190 Enzymes Human genes 0.000 claims description 10
- 108090000790 Enzymes Proteins 0.000 claims description 10
- 102000011782 Keratins Human genes 0.000 claims description 10
- 108010076876 Keratins Proteins 0.000 claims description 10
- 229940088598 enzyme Drugs 0.000 claims description 10
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 claims description 9
- 235000019419 proteases Nutrition 0.000 claims description 9
- 238000009472 formulation Methods 0.000 claims description 8
- 108090001060 Lipase Proteins 0.000 claims description 7
- 102000004882 Lipase Human genes 0.000 claims description 7
- 239000004367 Lipase Substances 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 claims description 7
- 235000019421 lipase Nutrition 0.000 claims description 7
- 229940045872 sodium percarbonate Drugs 0.000 claims description 7
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 6
- 102000004157 Hydrolases Human genes 0.000 claims description 6
- 108090000604 Hydrolases Proteins 0.000 claims description 6
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 6
- 229910052791 calcium Inorganic materials 0.000 claims description 6
- 239000011575 calcium Substances 0.000 claims description 6
- 239000011734 sodium Substances 0.000 claims description 6
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 6
- 235000011152 sodium sulphate Nutrition 0.000 claims description 6
- 102000035195 Peptidases Human genes 0.000 claims description 5
- 229930003427 Vitamin E Natural products 0.000 claims description 5
- WIGCFUFOHFEKBI-UHFFFAOYSA-N gamma-tocopherol Natural products CC(C)CCCC(C)CCCC(C)CCCC1CCC2C(C)C(O)C(C)C(C)C2O1 WIGCFUFOHFEKBI-UHFFFAOYSA-N 0.000 claims description 5
- 150000002431 hydrogen Chemical class 0.000 claims description 5
- 235000019165 vitamin E Nutrition 0.000 claims description 5
- 239000011709 vitamin E Substances 0.000 claims description 5
- 229940046009 vitamin E Drugs 0.000 claims description 5
- 108090000371 Esterases Proteins 0.000 claims description 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 4
- 239000003513 alkali Substances 0.000 claims description 4
- 230000002366 lipolytic effect Effects 0.000 claims description 4
- 229910052708 sodium Inorganic materials 0.000 claims description 4
- 229910000031 sodium sesquicarbonate Inorganic materials 0.000 claims description 4
- 235000018341 sodium sesquicarbonate Nutrition 0.000 claims description 4
- 239000007921 spray Substances 0.000 claims description 4
- WCTAGTRAWPDFQO-UHFFFAOYSA-K trisodium;hydrogen carbonate;carbonate Chemical compound [Na+].[Na+].[Na+].OC([O-])=O.[O-]C([O-])=O WCTAGTRAWPDFQO-UHFFFAOYSA-K 0.000 claims description 4
- 108010004032 Bromelains Proteins 0.000 claims description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- 108010019160 Pancreatin Proteins 0.000 claims description 3
- 108090000526 Papain Proteins 0.000 claims description 3
- 108090000608 Phosphoric Monoester Hydrolases Proteins 0.000 claims description 3
- 102000004160 Phosphoric Monoester Hydrolases Human genes 0.000 claims description 3
- 229940055695 pancreatin Drugs 0.000 claims description 3
- 229940055729 papain Drugs 0.000 claims description 3
- 235000019834 papain Nutrition 0.000 claims description 3
- 235000019833 protease Nutrition 0.000 claims description 2
- 239000011780 sodium chloride Substances 0.000 claims description 2
- 159000000000 sodium salts Chemical class 0.000 claims description 2
- 238000007906 compression Methods 0.000 claims 1
- 230000006835 compression Effects 0.000 claims 1
- 238000002845 discoloration Methods 0.000 abstract description 8
- 239000000835 fiber Substances 0.000 abstract description 8
- 238000011109 contamination Methods 0.000 abstract description 3
- JTEDVYBZBROSJT-UHFFFAOYSA-N indole-3-butyric acid Chemical compound C1=CC=C2C(CCCC(=O)O)=CNC2=C1 JTEDVYBZBROSJT-UHFFFAOYSA-N 0.000 description 13
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 11
- -1 kemarin Chemical compound 0.000 description 9
- 210000003491 skin Anatomy 0.000 description 8
- 238000000354 decomposition reaction Methods 0.000 description 7
- 238000004061 bleaching Methods 0.000 description 6
- 238000004140 cleaning Methods 0.000 description 6
- 238000003912 environmental pollution Methods 0.000 description 6
- 239000003921 oil Substances 0.000 description 6
- 235000018102 proteins Nutrition 0.000 description 6
- 102000004169 proteins and genes Human genes 0.000 description 6
- 108090000623 proteins and genes Proteins 0.000 description 6
- 239000004094 surface-active agent Substances 0.000 description 6
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 4
- 239000004264 Petrolatum Substances 0.000 description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 239000011230 binding agent Substances 0.000 description 4
- 239000004744 fabric Substances 0.000 description 4
- 230000001965 increasing effect Effects 0.000 description 4
- QQWAKSKPSOFJFF-UHFFFAOYSA-N oxiran-2-ylmethyl 2,2-dimethyloctanoate Chemical compound CCCCCCC(C)(C)C(=O)OCC1CO1 QQWAKSKPSOFJFF-UHFFFAOYSA-N 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 235000019271 petrolatum Nutrition 0.000 description 4
- 229940066842 petrolatum Drugs 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 239000007916 tablet composition Substances 0.000 description 4
- 239000012459 cleaning agent Substances 0.000 description 3
- 238000005868 electrolysis reaction Methods 0.000 description 3
- 239000006081 fluorescent whitening agent Substances 0.000 description 3
- 229940024999 proteolytic enzymes for treatment of wounds and ulcers Drugs 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 206010040880 Skin irritation Diseases 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 239000007844 bleaching agent Substances 0.000 description 2
- 230000000593 degrading effect Effects 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 230000002708 enhancing effect Effects 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 230000009931 harmful effect Effects 0.000 description 2
- 230000003301 hydrolyzing effect Effects 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 229910052746 lanthanum Inorganic materials 0.000 description 2
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 208000017520 skin disease Diseases 0.000 description 2
- 231100000475 skin irritation Toxicity 0.000 description 2
- 230000036556 skin irritation Effects 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- 230000001954 sterilising effect Effects 0.000 description 2
- WSWCOQWTEOXDQX-MQQKCMAXSA-M (E,E)-sorbate Chemical compound C\C=C\C=C\C([O-])=O WSWCOQWTEOXDQX-MQQKCMAXSA-M 0.000 description 1
- 208000002874 Acne Vulgaris Diseases 0.000 description 1
- 206010003645 Atopy Diseases 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 208000001840 Dandruff Diseases 0.000 description 1
- 206010015150 Erythema Diseases 0.000 description 1
- 241000588724 Escherichia coli Species 0.000 description 1
- 239000004471 Glycine Substances 0.000 description 1
- 208000007514 Herpes zoster Diseases 0.000 description 1
- ZCQWOFVYLHDMMC-UHFFFAOYSA-N Oxazole Chemical compound C1=COC=N1 ZCQWOFVYLHDMMC-UHFFFAOYSA-N 0.000 description 1
- 108700019535 Phosphoprotein Phosphatases Proteins 0.000 description 1
- 102000045595 Phosphoprotein Phosphatases Human genes 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- PJANXHGTPQOBST-VAWYXSNFSA-N Stilbene Natural products C=1C=CC=CC=1/C=C/C1=CC=CC=C1 PJANXHGTPQOBST-VAWYXSNFSA-N 0.000 description 1
- 241000700605 Viruses Species 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 206010000496 acne Diseases 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000023555 blood coagulation Effects 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000003183 carcinogenic agent Substances 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 235000019621 digestibility Nutrition 0.000 description 1
- 102000038379 digestive enzymes Human genes 0.000 description 1
- 108091007734 digestive enzymes Proteins 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 235000013601 eggs Nutrition 0.000 description 1
- 231100000321 erythema Toxicity 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 239000005556 hormone Substances 0.000 description 1
- 229940088597 hormone Drugs 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000036039 immunity Effects 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- CMGJQFHWVMDJKK-UHFFFAOYSA-N lanthanum;trihydrate Chemical compound O.O.O.[La] CMGJQFHWVMDJKK-UHFFFAOYSA-N 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 230000003211 malignant effect Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 239000011941 photocatalyst Substances 0.000 description 1
- 230000008635 plant growth Effects 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 235000004252 protein component Nutrition 0.000 description 1
- 230000002797 proteolythic effect Effects 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 235000015170 shellfish Nutrition 0.000 description 1
- 230000009759 skin aging Effects 0.000 description 1
- 229940057950 sodium laureth sulfate Drugs 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- SXHLENDCVBIJFO-UHFFFAOYSA-M sodium;2-[2-(2-dodecoxyethoxy)ethoxy]ethyl sulfate Chemical compound [Na+].CCCCCCCCCCCCOCCOCCOCCOS([O-])(=O)=O SXHLENDCVBIJFO-UHFFFAOYSA-M 0.000 description 1
- 229940075554 sorbate Drugs 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 239000003206 sterilizing agent Substances 0.000 description 1
- PJANXHGTPQOBST-UHFFFAOYSA-N stilbene Chemical compound C=1C=CC=CC=1C=CC1=CC=CC=C1 PJANXHGTPQOBST-UHFFFAOYSA-N 0.000 description 1
- 235000021286 stilbenes Nutrition 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 210000000434 stratum corneum Anatomy 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 229930003799 tocopherol Natural products 0.000 description 1
- 229960001295 tocopherol Drugs 0.000 description 1
- 239000011732 tocopherol Substances 0.000 description 1
- 235000010384 tocopherol Nutrition 0.000 description 1
- 238000003911 water pollution Methods 0.000 description 1
- GVJHHUAWPYXKBD-IEOSBIPESA-N α-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-IEOSBIPESA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0047—Detergents in the form of bars or tablets
- C11D17/0065—Solid detergents containing builders
- C11D17/0073—Tablets
- C11D17/0086—Laundry tablets
-
- C11D11/0017—
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38609—Protease or amylase in solid compositions only
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38627—Preparations containing enzymes, e.g. protease or amylase containing lipase
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38636—Preparations containing enzymes, e.g. protease or amylase containing enzymes other than protease, amylase, lipase, cellulase, oxidase or reductase
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/12—Soft surfaces, e.g. textile
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
본 발명은 워싱 타블렛에 관한 것으로, 보다 상세하게는 고농축 때 분해용 특수 효소성분과 수소바인더를 응용하여 섬유에 묻은 인체 방출 기름 등의 찌든 때와 흔적을 신속하게 분해, 제거하되 피부자극을 없애고 수질 오염을 방지하면서 거품이 일지 않게 하여 세척수 사용을 줄이고, 나아가 세탁 후에도 섬유의 변색이나 손상까지 방지할 수 있도록 개량된 워싱 타블렛에 관한 것이다.More particularly, the present invention relates to a washing tablet, and more particularly, to a method for dissolving and removing stains and traces of human body oil, To an improved washing tablet which is capable of reducing the use of washing water by preventing bubbles while preventing contamination and further preventing discoloration or damage of the fibers even after washing.
Description
본 발명은 수소 워싱 타블렛에 관한 것으로, 보다 상세하게는 고농축 때 분해용 특수 효소성분과 수소바인더를 응용하여 섬유에 묻은 인체 방출 기름 등의 찌든 때와 흔적을 신속하게 분해, 제거하되 피부자극을 없애고 수질 오염을 방지하면서 거품이 일지 않게 하여 세척수 사용을 줄이고, 나아가 세탁 후에도 섬유의 변색이나 손상까지 방지할 수 있도록 개량된 수소 워싱 타블렛에 관한 것이다.More particularly, the present invention relates to a hydrogen washing tablet, and more particularly, to a hydrogen washing tablet which is applied with a special enzyme component for decomposition and a hydrogen binder to dissolve and remove stains and traces of human body oil, The present invention relates to an improved hydrogen washing tablet capable of preventing water contamination while preventing bubbles from being used to reduce the use of washing water and further preventing discoloration or damage of the fiber even after washing.
일반적으로, 세탁에 사용되는 세제는 직물의 세정을 돕기 위해 직물을 세탁할 때 첨가하는 물질이다.Generally, the detergent used for washing is a substance added when washing the fabric to help clean the fabric.
이러한 세탁 세제는 주로 분말 또는 과립 형태의 고체가 사용되고 있으며, 최근에는 액상 세제도 시판되고 있다.Such laundry detergents are mainly used in the form of powders or granules in solid form, and recently liquid detergents have also been commercially available.
그런데, 종래 개시된 세제들은 분말, 과립, 액상을 불문하고 세정력을 높이기 위해 거품발생을 증가시키도록 거품발생제 함량을 증대시키고 있어 그만큼 세탁을 위한 물 사용량이 증가하게 되어 세탁수 낭비가 심한 단점이 있다.However, the conventional detergents have a disadvantage in that the amount of the foaming agent is increased so as to increase the foam generation to increase the washing power regardless of the powder, granule or liquid phase, .
특히, 거품발생을 증대시키면서 세정력(섬유에 찌든 때, 기름, 단백질 등에 활성을 부여하여 쉽게 분리되도록 하는 것)을 높이기 위한 계면활성제로 소듐라우릴설페이트나 혹은 소듐라우레스설페이트 등의 합성계면활성제를 사용하기 때문에 수질오염을 유발시키고, 이와 같은 세제를 통해 세탁된 섬유를 착용했을 때 피부와 접촉되면서 피지막과 각질층을 파괴하여 피부노화를 촉진하고 각종 피부병을 유발시키는 등 인체에 해롭게 작용하는 단점이 있다.Particularly, as a surfactant for increasing the foam generation while increasing the washing power (to be easily separated by imparting activity to oils, proteins and the like when stained with fibers), a synthetic surfactant such as sodium lauryl sulfate or sodium laureth sulfate It has a disadvantage that it causes harmful effects on the human body such as causing skin pollution and destroying the sebaceous membrane and stratum corneum in contact with the skin when the laundered fiber is worn through such detergent to promote skin aging and various skin diseases .
또한, 종래 세탁 세제에는 스틸벤, 크마린, 옥사졸, 나프타루이미드 유도체를 주재로 한 형광증백제가 포함되는데, 이는 자외선을 흡수하여 자색 계통의 형광을 발하고 누렇게 변하는 변색을 방지하기 위해 첨가되지만 인체에 유해하고 환경오염과 발암성 물질이어서 배제시켜야 한다.Conventional laundry detergents include fluorescent whitening agents based on stilbene, kemarin, oxazole, and naphtha luimide derivatives, which absorbs ultraviolet light and emits fluorescence of a purple color system and is added to prevent discoloration that changes in yellow However, it should be excluded because it is harmful to human body and it is an environmental pollution and carcinogenic substance.
뿐만 아니라, 변색을 방지하고 흰 색상을 강화시키기 위해 첨가되는 표백제 또한 인체에 유익한 것은 아닌 바, 경우에 따라서는 환경오염을 유발하고, 피부를 자극하기 때문에 이또한 기피해야 하지만 현재 통용되는 대부분의 세탁 세제에는 세탁 성능을 향상시키기 위해 이들이 함유되어 있어 개선이 필요한 시점이다.In addition, the bleaching agent added to prevent discoloration and enhance the white color is not beneficial to the human body. In some cases, it causes environmental pollution and stimulates the skin. Therefore, most of the currently used laundry Detergents contain these to improve washing performance and are in need of improvement.
이와 같은 문제 인식에 기반하여 활성단백질 분해효소와 인체에 완전히 무해한 산소계 표백기능을 갖는 성분들을 이용하여 농축시킨 알(정) 형태(하기 참고도면 참조)의 고상 세탁세제인 일명 '워싱 타블렛'이 개시된 바 있다.Based on the above-described problem recognition, a so-called "washing tablet" which is a solid laundry detergent concentrate (see reference figure) using active proteolytic enzymes and components having an oxygen bleaching function completely harmless to the human body is disclosed There is a bar.
[참고도면][Reference drawing]
이러한 워싱 타블렛은 제형 압축정제로서 소형 고농축이어서 사용 및 관리가 편리하고, 화학성분을 사용하지 않음으로 인해 인체 유해성 및 환경오염, 수질오염을 예방하며, 고분해성임에 반해 잔류 세제가 없어 피부 트러블 문제도 해소하고, 거품발생이 거의 없이도 세탁 가능한 효과 등 많은 장점에도 불구하고, 세정력이 조금 떨어지기 때문에 이에 대한 보완이 필요하다.Such a washing tablet is a compressed and tableted formulation and is compact and highly concentrated so that it is easy to use and manage and prevents chemical harmfulness, environmental pollution and water pollution because it does not use a chemical component, It is necessary to compensate for the deterioration of the cleaning ability because the detergency is slightly lowered, despite the many advantages such as the effect of being able to be washed without bubble generation.
특히, 계면활성제를 사용하지 않기 때문에 인체에 무해하고 환경오염을 일으키기 않으면서도 계면 활성기능을 강화시켜 찌든 때, 기름, 먼지 등의 이물 분리를 용이하게 하여 세탁력을 강화시킬 필요가 있다.Particularly, since a surfactant is not used, it is necessary to enhance the detergency by facilitating the separation of foreign matter such as oil and dust when the surfactant function is strengthened without harming the human body and causing environmental pollution.
뿐만 아니라, 제형 정제, 즉 타블렛(Tablet)임에도 불구하고, 제형성이 약해 세탁전 보관시 습기를 차단해야 하는 불편함으로 인해 관리상 주의가 요구되는 단점이 있다.In addition, despite tablet formulation, that is, tablet, there is a disadvantage that maintenance is required due to the inconvenience that moisture is blocked during storage before washing due to weak formulation.
본 발명은 상술한 바와 같은 종래 기술상의 제반 문제점들을 감안하여 이를 해결하고자 창출된 것으로, 고농축 때 분해용 특수 효소성분과 수소바인더를 응용하여 섬유에 묻은 인체 방출 기름 등의 찌든 때와 흔적을 신속하게 분해, 제거하되 피부자극을 없애고 수질 오염을 방지하면서 거품이 일지 않게 하여 세척수 사용을 줄이고, 나아가 세탁 후에도 섬유의 변색이나 손상까지 방지할 수 있도록 개량된 워싱 타블렛을 제공함에 그 주된 목적이 있다.DISCLOSURE Technical Problem The present invention has been made in view of the above-described problems in the prior art, and has been made to solve the above-mentioned problems. It is an object of the present invention to provide a method of producing a hydrogen- It is a main object of the present invention to provide an improved washing tablet which is capable of preventing skin irritation, preventing water contamination, reducing the use of washing water by preventing bubbles, and further preventing discoloration or damage of fibers even after washing.
본 발명은 상기한 목적을 달성하기 위한 수단으로, 세탁 세제로 사용되는 워싱 타블렛에 있어서; 상기 워싱 타블렛은 고기능성 활성단백질 분해효소 15-20중량%와, 지방 분해효소 7-10중량%와, 기능성 가수분해효소 7-10중량%, 과탄산나트륨 2-4중량%와, 빌더 0.5-1.5중량%와, 황산나트륨 0.5-1.5중량%, 알칼리제 10-15중량%, 수소칼슘분말 25-30중량% 및 나머지 수소이온수로 이루어진 타블렛 조성물을 분무과립기로 과립화시킨 다음, 과립화된 원료를 벌크에 충진 후 압축하여 제형 정제로 제조한 것을 특징으로 하는 수소 워싱 타블렛을 제공한다.The present invention provides a washing tablet used as a laundry detergent, comprising: The washing tablet comprises 15-20% by weight of high-activity active protease, 7-10% by weight of lipolytic enzyme, 7-10% by weight of functional hydrolase, 2-4% by weight of sodium percarbonate, By weight of sodium chloride, 0.5-1.5% by weight of sodium sulfate, 10-15% by weight of an alkali agent, 25-30% by weight of hydrogen calcium powder and balance hydrogen ion water is granulated with a spray granulator, And then compressed to prepare a tablet for purification.
이때, 상기 고기능성 활성단백질 분해효소는 프로테아제(Protease), 파파인(Papain), 브로멜라인(Bromelin), 판크레아틴(Pancreatin)이 각각 1:1:1:1의 중량비로 혼합한 혼합물이고; 상기 지방 분해효소는 리파아제(Lipase)이며; 상기 기능성 가수분해효소는 에스테라아제(Esterase), 포스파타아제(Phosphatase)가 각각 1:1의 중량비로 혼합된 혼합물이고; 상기 빌더는 비타민 E와 케라틴이 2:1의 중량비로 합성된 것이며; 상기 알칼리제는 천연 알칼리제인 세스키탄산나트륨(Sodium Sesqui Carbonate)인 것에도 그 특징이 있다.Herein, the high-activity active proteinase is a mixture of Protease, Papain, Bromelin, and Pancreatin in a weight ratio of 1: 1: 1: 1, respectively; The lipolytic enzyme is a lipase; Wherein the functional hydrolase is a mixture of esterase and phosphatase at a weight ratio of 1: 1, respectively; The builder is a vitamin E and keratin synthesized at a weight ratio of 2: 1; The alkaline agent is also characterized by being a sodium alkaline sodium salt (sodium sesquicarbonate).
또한, 상기 수소이온수는 기능 발현을 위해 1.2-1.8ppm의 수소이온농도를 유지하는 것에도 그 특징이 있다.The hydrogen ion water is also characterized by maintaining a hydrogen ion concentration of 1.2-1.8 ppm for functional expression.
본 발명에 따르면, 고농축 때 분해용 특수 효소성분과 수소바인더를 응용하여 섬유에 묻은 인체 방출 기름 등의 찌든 때와 흔적을 신속하게 분해, 제거하되 피부자극을 없애고 수질 오염을 방지하면서 거품이 일지 않게 하여 세척수 사용을 줄이고, 나아가 세탁 후에도 섬유의 변색이나 손상까지 방지하는 효과를 얻을 수 있다.According to the present invention, by application of a special enzyme component for decomposition and a hydrogen binder at high concentration, it is possible to quickly decompose and remove stains and traces of human body oil, which are imbedded in fibers, and prevent skin irritation, Thereby reducing the use of the washing water and further preventing discoloration or damage of the fiber even after washing.
이하에서는, 본 발명에 따른 바람직한 실시예를 보다 상세하게 설명하기로 한다.Hereinafter, preferred embodiments according to the present invention will be described in detail.
본 발명 설명에 앞서, 이하의 특정한 구조 내지 기능적 설명들은 단지 본 발명의 개념에 따른 실시예를 설명하기 위한 목적으로 예시된 것으로, 본 발명의 개념에 따른 실시예들은 다양한 형태로 실시될 수 있으며, 본 명세서에 설명된 실시예들에 한정되는 것으로 해석되어서는 아니된다.Before describing the present invention, the following specific structural or functional descriptions are merely illustrative for the purpose of describing an embodiment according to the concept of the present invention, and embodiments according to the concept of the present invention may be embodied in various forms, And should not be construed as limited to the embodiments described herein.
또한, 본 발명의 개념에 따른 실시예는 다양한 변경을 가할 수 있고 여러 가지 형태를 가질 수 있으므로, 본 발명의 사상 및 기술 범위에 포함되는 모든 변경물, 균등물 내지 대체물을 포함하는 것으로 이해되어야 한다.In addition, it should be understood that the embodiments according to the concept of the present invention include various modifications, equivalents, and alternatives included in the spirit and technical scope of the present invention, .
본 발명에 따른 워싱 타블렛도 종래와 마찬가지로 제형 정제, 즉 알(정) 형태로 형성된다.The washing tablet according to the present invention is also formed in the form of tablets, that is, eggs (tablets) as in the prior art.
하지만, 기존과 달리 제형성을 완벽하게 유지할 수 있도록 특수성분을 포함하여 내습성을 갖지만, 실제 세탁시에는 세탁수에 일정시간 침지될 경우 물에 잘 녹아 쉽게 풀어질 수 있도록 구성된다.However, unlike the conventional ones, it has moisture resistance including special ingredients so as to maintain the formability perfectly, but when it is immersed in washing water for a certain time, it is easily dissolved in water and can be easily loosened.
또한, 기존과 달리 세척력 강화를 위해 특수성분인 수소바인더를 더 포함한다.In addition, unlike the conventional one, it contains a hydrogen binder, which is a special component for enhancing the detergency.
보다 구체적으로, 본 발명에 따른 수소 워싱 타블렛은 고기능성 활성단백질 분해효소 15-20중량%와, 지방 분해효소 7-10중량%와, 기능성 가수분해효소 7-10중량%, 과탄산나트륨 2-4중량%와, 빌더 0.5-1.5중량%와, 황산나트륨 0.5-1.5중량%, 알칼리제 10-15중량%, 수소칼슘분말 25-30중량% 및 나머지 수소이온수로 이루어진 타블렛 조성물을 분무과립기로 과립화시킨 다음, 과립화된 원료를 벌크에 충진 후 압축하여 제형 정제로 제조된다.More specifically, the hydrogen washing tablet according to the present invention comprises 15-20% by weight of high-activity active protease, 7-10% by weight of lipase, 7-10% by weight of functional hydrolase, 2-4 By weight of a builder, 0.5-1.5% by weight of a builder, 0.5-1.5% by weight of sodium sulfate, 10-15% by weight of an alkali agent, 25-30% by weight of a hydrogen calcium powder and remaining hydrogen ion water is granulated with a spray granulator , The granulated raw material is packed in a bulk and compressed to form a tablet.
이때, 상기 고기능성 활성단백질 분해효소는 인체의 피부에서 나오는 땀이나 기름에 포함된 단백질 성분을 완전히 분해하기 위해 첨가되는 것으로, 단백질 가수분해 효소인 프로테아제(Protease)를 비롯하여, 단백질 세정효과를 높이기 위한 파파인(Papain), 단백질 분해 효과를 높이면서 자양물 흡수력을 증대시키는 브로멜라인(Bromelin), 소화 효소로 사용되지만 단백질 소화력이 뛰어나 단백질 분해력이 매우 우수한 판크레아틴(Pancreatin)을 각각 1:1:1:1의 중량비로 혼합한 상태에서 상기 조성비만큼 첨가 사용하도록 한다.At this time, the high-activity active protein degrading enzyme is added to completely decompose protein components contained in sweat or oil contained in the skin of the human body, and it includes protease, which is a protein hydrolyzing enzyme, 1: 1: 1: 1, 1: 1, 1: 1, 1: 1, 1: 1, 1: 1, and 1: 1, respectively), which are used as digestive enzymes but have excellent protein digestibility and excellent proteolytic power, 1 by weight in terms of the composition ratio.
이 경우, 상기 고기능성 활성단백질 분해효소가 20중량%를 초과하게 되면 피부 접촉시 홍반이 동반될 수 있고, 체내 흡수시 혈액응고에 장애를 일으킬 수 있으므로 20중량% 이하로 첨가되어야 하며, 15중량% 미만으로 첨가되면 단백질 분해력이 급격히 떨어지므로 상기 범위로 한정해야 한다.In this case, when the amount of the high-activity active protease is more than 20% by weight, it may be accompanied by erythema upon contact with the skin, and it may cause obstruction of blood coagulation upon absorption into the body. %, It is necessary to limit to the above-mentioned range, since the protein degrading ability drops sharply.
또한, 상기 지방 분해효소는 지질(기름)에서 카르복시산과 알코올 사이의 결합을 끊어 지방을 가수분해하는 리파아제(Lipase)가 사용된다.Further, the lipase is a lipase which hydrolyzes lipids (oil) by breaking bonds between the carboxylic acids and the alcohols.
아울러, 상기 기능성 가수분해효소로는 에스테르 결합을 끊어 가수분해하는 에스테라아제(Esterase), 인산을 가수분해하는 포스파타아제(Phosphatase)를 각각 1:1의 중량비로 혼합한 상태에서 상기 조성비만큼 첨가 사용하도록 한다.As the functional hydrolytic enzyme, an esterase which hydrolyzes the ester bond and hydrolyzes phosphatase which hydrolyzes the phosphoric acid is mixed at a weight ratio of 1: 1, do.
그리고, 상기 과탄산나트륨은 탄산나트륨과 과산화수소를 혼합하여 형성된 Na2CO4ㆍH2O로서, 형광증백제 또는 계면활성제가 전혀 들어 있지 않은 100% 산소계 살균 및 표백제로서 기능하도록 첨가된다.The sodium percarbonate is Na 2 CO 4 .H 2 O formed by mixing sodium carbonate and hydrogen peroxide. The sodium percarbonate is added to function as a 100% oxygen sterilizing and bleaching agent containing no fluorescent whitening agent or surfactant at all.
이러한 과탄산나트륨은 탄산나트륨에 과산화수소가 붙어 있는 형태이기 때문에 물과 만나면 쉽게 녹으면서 활성이 커져 살균, 표백 기능을 강화하게 되며, pH는 10-11에 해당한다.Since sodium percarbonate is in the form of hydrogen peroxide attached to sodium carbonate, when it is in contact with water, it easily dissolves and becomes active, enhancing its sterilization and bleaching function, and its pH is 10-11.
하지만, 과탄산나트륨은 4중량%를 초과하여 과량 첨가되면 섬유와 염료 사이의 결합을 끊어 탈색을 유발하므로 반드시 4중량%를 초과하지 않아야 하며, 2중량% 미만으로 첨가되면 살균 표백 기능이 거의 없기 때문에 상기 범위로 한정해야 한다.However, when sodium percarbonate is added in an excess amount exceeding 4% by weight, the bond between the fiber and the dye is broken to cause discoloration, and therefore, it should not exceed 4% by weight. If less than 2% by weight is added, Should be limited to the above range.
그리고, 상기 빌더는 제형을 유지하기 위한 것으로, 비타민 E(토코페놀)와 케라틴을 2:1의 중량비로 합성하여 사용하며, 비타민 E는 피부에 흡수되었을 때 활성산소를 제거하여 노화를 방지하고 면역력을 강화시키며 직물의 손상을 줄이기 위해 사용되며, 케라틴은 뜨거운 물이나 찬물에 쉽게 녹지 않으며 또한 단백질 분해효소에 의해서도 쉽게 분해되지 않기 때문에 무해하면서도 친환경적이고 제형성을 유지하는데 적당하다.The builder is used to maintain the formulations. Vitamin E (tocopherol) and keratin are synthesized at a weight ratio of 2: 1, and when vitamin E is absorbed into the skin, active oxygen is removed to prevent aging, And keratin is harmless, environmentally friendly, and suitable for maintaining the formation, since it is not readily soluble in hot or cold water and is not easily decomposed by proteolytic enzymes.
다만, 물에 쉽게 녹지 않을 뿐만 아니라, 단백질 분해효소에 의해서도 잘 분해되지 않기 때문에 세탁 후 찌꺼기로 남을 수 있으므로 미량 사용해야 하며, 본 발명에서는 제형성만 유지할 수 있도록 0.5-1.5중량%의 범위로 첨가한다.However, not only does it not easily dissolve in water, but it can not be decomposed well by proteolytic enzymes, so it can be left as a residue after washing. Therefore, it should be used in a small amount, and in the present invention, it is added in the range of 0.5-1.5 wt% .
또한, 상기 황산나트륨은 인체에 무해하고 환경오염성이 전혀 없으나 물과 접촉시 쉽게 녹으면서 케라틴의 분자사슬을 끊어 분해하는 능력을 갖추고 있으므로 제형 유지를 위해 첨가되는 케라틴을 분해하기 위해 빌더와 동일량으로 첨가된다.In addition, the sodium sulfate is harmless to the human body and has no environmental pollution. However, since sodium sulfate has the ability to dissolve the keratin molecule chain by dissolving it easily when it is in contact with water, it is possible to decompose the keratin added to maintain the formulation, do.
다만, 제형 제정 상태일 때는 케라틴 분해에 영향을 미치지 않지만, 세탁을 위해 세제로 투입된 후 물과 반응하게 되면 케라틴을 분해하여 세탁 후 찌꺼기가 생기지 않도록 함은 물론 케라틴을 분해 제거하기 때문에 제형 제정을 구성하는 다른 성분들의 활성이 커지면서 세척력을 강화시키게 된다.However, it does not affect keratin decomposition when formulated, but when it is added to detergent for washing, it reacts with water to decompose keratin so that it does not cause any residue after washing, and keratin is decomposed and removed. The activity of the other components is increased and the cleaning force is strengthened.
아울러, 상기 알칼리제는 분말 상으로 첨가되며 세척력을 강화시키기 위한 것으로, 천연 알칼리제인 세스키탄산나트륨(Sodium Sesqui Carbonate)은 Na2CO3ㆍNaHCO3ㆍ2H2O로 표현되며, 천연 무기물로서 수질오염이나 환경오염을 유발하지 않으면서 인체에 무해하고(피부자극 없음), 물에 쉽게 녹으며, 수용액은 약알카리성을 띄며, 단백질 분해, 찌든 때 분리 세척을 더욱 보강하기 위한 세척력 강화제, 혹은 세척력 보강제로 첨가된다. 특히, 워싱 타블렛의 변질, 변색을 억제하는 기능도 포함한다.In addition, the alkali agent is added in powder form to enhance the washing power. The sodium alkaline salt, sodium sesquicarbonate, is expressed as Na 2 CO 3 .NaHCO 3 .2H 2 O, It is harmless to the human body (it does not irritate the skin) without causing environmental pollution, easily dissolves in water, the aqueous solution has weak alkalinity, is detergent for protein decomposition, do. In particular, it also includes a function of suppressing deterioration and discoloration of a washing tablet.
이때, 상기 알카리제가 10중량% 미만으로 첨가되면 세정 효과를 증대시킬 수 없을 뿐만 아니라 흡습성을 저해하여 제형성을 약화시킬 수 있고, 15중량%를 초과하면 알칼리성이 과하게 되고 젤화를 촉진하므로 세탁시에는 세탁성을 저해할 수 있기 때문에 상기 범위로 한정하여야 한다.If the amount of the alkaline agent is less than 10% by weight, the cleaning effect can not be enhanced and the hygroscopicity can be impaired to weaken the formulation. If the amount is more than 15% by weight, It is required to be limited to the above-mentioned range because it may hinder washing property.
그리고, 상기 수소칼슘분말은 수소음이온은 미분화된 패각류의 작은 기공에 흡장(흡수 저장)시켜서 만든 일종의 '수소분말'로서, 특수세척력을 강화시키기 위한 것이다.The hydrogen calcium powder is a kind of 'hydrogen powder' which is formed by storing (absorbing and storing) hydrogen anions in small pores of undifferentiated shellfishes to enhance special washing power.
이때, 수소음이온은 희토류(예. 란타넘(Lanthanum, 원자번호 57))를 물, 특히 더운 물에 접촉시키면 수산화란타넘(La(OH)3)이 되면서 수소를 내어 놓기 때문에 쉽게 얻을 수 있으며, 자연상태에서는 폭포수 주변에서 쉽게 얻을 수 있다. 다만, 전기분해를 통해서는 수소음이온을 얻기 매우 어려운데 이는 물을 전기분해하였을 때 수소양이온만 나오기 때문에 전기분해 형태로 생성하지는 않는다.At this time, the hydrogen anion can easily be obtained because it releases hydrogen with lanthanum (eg, Lanthanum (atomic number 57)) to water, especially hot water, as lanthanum hydroxide (La (OH) 3 ) It is easy to get around the waterfall in the natural state. However, it is very difficult to obtain hydrogen anion through electrolysis because it produces hydrogen cation only when electrolysis of water does not produce electrolysis.
이러한 수소칼슘분말은 바이러스, 세균(대장균) 사멸능력이 뛰어나고, 중금속 및 이물 분해능력이 탁월하며, 비듬이나 여드름 혹은 아토피와 대상포진 등 악성 피부병 자정능력도 뛰어나고, 섬유와 계면에서 이물 분해 능력이 매우 우수하므로 본 발명에서는 특수세척제로 기능하기 위해 첨가된다.These hydrogen calcium powders are excellent in the ability to kill viruses, bacteria (Escherichia coli), excellent in the ability to decompose heavy metals and foreign matter, have excellent self-cleaning ability of malignant skin diseases such as dandruff, acne or atopy and shingles, And is added in order to function as a special cleaning agent in the present invention.
다만, 30중량%를 초과하면 분말상이 과포화되어 제형이 어렵고, 25중량% 미만으로 첨가되면 단시가 분해능력, 즉 단시간 세척을 강화시키기 어렵기 때문에 상기 범위로 한정하여야 한다.However, when it exceeds 30% by weight, the powder phase is supersaturated and difficult to form, and when it is added in an amount of less than 25% by weight, it is difficult to enhance the decomposition ability, that is, short-
아울러, 상기 수소이온수는 일종의 바인더로서, 더 정확하게는 수소양이온수이며, 과립화 후 제형 제정을 위해 첨가되며, 특히 살균 정화된 수소이온수를 통해 강력한 항산화기능은 물론 면역력을 강화시키므로 세탁한 섬유를 입게 되면 잔류된 수소이온이 인체에 유익한 영향을 미치게 된다.In addition, the hydrogen ion water is a kind of binder, more precisely, a hydrogen cation water, and is added for formulation after granulation. Especially, sterilized purified hydrogen ion water strengthens the strong antioxidative function as well as immunity, The remaining hydrogen ions have a beneficial effect on the human body.
특히, 본 발명에서 수소이온수는 기능 발현을 위해 최소한 1.2ppm 이상의 수소이온이 포함되어야 하며, 바람직하게는 1.2-1.8ppm을 유지하여 한다.In particular, in the present invention, the hydrogen ion water should contain at least 1.2 ppm of hydrogen ions for maintaining its function, preferably 1.2-1.8 ppm.
이 경우, 수소이온의 농도는 수소농도측정기인 PH-35A를 통해 측정할 수 있다.In this case, the concentration of the hydrogen ions can be measured through the PH-35A which is a hydrogen concentration measuring instrument.
덧붙여, 상기 타블렛 조성물에는 기능 강화를 위해 추가적으로 트리에탄올아민(Triethanolamine), 페트롤라툼(petrolatum), IBA(Indole-3-Butyric acid), 글리시딜 네오데카노에이트(Glycidyl neodecanoate)를 더 첨가할 수 있다.In addition, triethanolamine, petrolatum, indole-3-butyric acid (IBA), and glycidyl neodecanoate may be further added to the tablet composition in order to enhance the function of the tablet composition .
이때, 첨가량은 상기 타블렛 조성물 100중량부에 대해, 트리에탄올아민(Triethanolamine) 1.5-2.5중량부, 페트롤라툼(petrolatum) 0.5-1.5중량부, IBA(Indole-3-Butyric acid), 3-5중량부, 글리시딜 네오데카노에이트(Glycidyl neodecanoate) 1-2중량부이며, 트리에탄올아민은 약알카리성으로서 산도 조절을 위해 첨가되는 일종의 완충제이고, 페트롤라툼은 비결정성인 고체탄화수소를 주성분으로 하는 흰색 연고모양의 물질로서 방수 기능이 있어 워싱 타블렛을 보관할 때 제형성을 강화시키기 위해 첨가되며, IBA는 인돌부틸산으로서 보통은 식물의 생장에 직접 관여하여 호르몬이 탄수화물 흐름방향으로 이끄는 물질이지만 본 발명에서는 수분을 밀어내면서 직물로부터 이물, 때 등의 잔류물질을 분해하는 분해능을 증대시키기 위해 첨가되고, 글리시딜 네오데카노에이트는 윤활성을 부여하여 제형을 용이하게 하면서 특히 발색을 억제하기 위해 첨가될 수 있다.In this case, the amount of addition is preferably 1.5-2.5 parts by weight of triethanolamine, 0.5-1.5 parts by weight of petrolatum, indole-3-butyric acid (IBA), 3-5 parts by weight , And 1 to 2 parts by weight of glycidyl neodecanoate. The triethanolamine is a weakly alkaline buffer added to control acidity. Petrolatum is a white ointment-like material mainly composed of amorphous solid hydrocarbons IBA is indolebutyric acid, which is usually involved directly in the growth of plants, leading to the direction of the hormone's carbohydrate flow. In the present invention, however, Is added to increase the decomposition ability to decompose the remaining substances such as foreign matters and the like from the fabric while the glycidyl neodecanoate is lubricated While facilitating the formulation to give it can be especially added in order to suppress the color development.
이상에서 설명한 바와 같은 워싱 타블렛은 사용상 편리성을 추구한 국내 최초 수소발생형 타블렛 효소세제로서, 기존 세제와는 차원이 다른 고농축 분해능력을 구비하여 찌든때, 단백질성 때, 지방성 때를 완전하고 깔끔하게 단시간내 분해하는 특성을 갖는다.The washing tablet as described above is the first hydrogen-generating tablet enzyme detergent in Korea that pursues ease of use. It has a high concentration decomposition ability which is different from that of the conventional detergent. Therefore, the washing tablet is completely and neatly And has a property of decomposing in a short time.
특히, 친환경 성분들로 이루어져 피부 자극이 없고 수질을 오염시키지 않는데, 이를 테면 기존 세제와 달리 형광증백제가 함유되어 있지 않으며, 계면활성제 자체가 없어 거품 발생이 억제되고, 세탁 능력을 강화시키는 특성이 있다.Especially, it is composed of environmentally friendly ingredients, and it does not irritate the skin and does not pollute water quality. In other words, unlike conventional detergents, it does not contain a fluorescent whitening agent, has no surfactant itself and suppresses foaming, have.
이하, 실시예에 대하여 설명한다.Hereinafter, examples will be described.
본 발명에 따른 워싱 타블렛의 세탁력을 확인하기 위해 다음 실시예들과 같이 시료를 만든 후 세척력을 테스트하였다.In order to confirm the washing power of the washing tablet according to the present invention, washing powers were tested after preparing samples as in the following examples.
이때, 세척력 기준은 다음 [표 1]과 같다.At this time, the cleaning power standard is shown in Table 1 below.
[실시예 1][Example 1]
프로테아제(Protease), 파파인(Papain), 브로멜라인(Bromelin), 판크레아틴(Pancreatin)이 각각 1:1:1:1의 중량비로 혼합한 고기능성 활성단백질 분해효소 16.5중량%와; 지방 분해효소인 리파아제(Lipase) 8.5중량%와; 에스테라아제(Esterase), 포스파타아제(Phosphatase)가 각각 1:1의 중량비로 혼합된 기능성 가수분해효소 8.5중량%와; 과탄산나트륨 3중량%와; 비타민 E와 케라틴이 2:1의 중량비로 합성된 빌더 1중량%와; 황산나트륨 1중량%와; 천연 알칼리제인 세스키탄산나트륨(Sodium Sesqui Carbonate) 12.5중량%와; 수소칼슘분말 27중량% 및 나머지 수소이온수로 이루어진 타블렛 조성물을 분무과립기로 과립화시킨 다음, 과립화된 원료를 벌크에 충진 후 압축하여 제형 정제로 제조하여 워싱 타블렛 제1시료로 만들었다.16.5% by weight of a highly functional active protease, in which protease, Papain, Bromelin, and Pancreatin were mixed at a weight ratio of 1: 1: 1: 1, respectively; 8.5% by weight of lipase, lipase; 8.5% by weight of a functional hydrolase mixed with a 1: 1 weight ratio of esterase and phosphatase, respectively; 3% by weight sodium percarbonate; 1% by weight builder of vitamin E and keratin synthesized at a weight ratio of 2: 1; 1% by weight of sodium sulfate; 12.5% by weight of sodium alkaline earth sorbate (Sodium Sesqui Carbonate); 27% by weight of calcium hydrogen powder and remaining hydrogen ion water was granulated with a spray granulator, and then the granulated raw material was packed in a bulk and compressed to prepare a tablet as a first tablet for a washing tablet.
[실시예 2][Example 2]
상기 실시예 1의 타블렛 조성물에 상기 타블렛 조성물 100중량부를 기준으로 트리에탄올아민(Triethanolamine) 2.0중량부, 페트롤라툼(petrolatum) 1.0중량부, IBA(Indole-3-Butyric acid), 4.0중량부, 글리시딜 네오데카노에이트(Glycidyl neodecanoate) 1.5중량부를 더 첨가하여 워싱 타블렛 제2시료를 만들었다.2.0 parts by weight of triethanolamine, 1.0 part by weight of petrolatum, 4.0 parts by weight of indole-3-butyric acid, 4.0 parts by weight of glycine, And 1.5 parts by weight of dyneodecanoate (Glycidyl neodecanoate) were further added to prepare a second sample of the washing tablet.
그리고, 상기 제1,2시료에 대해 세정제로서 사용가능한지 여부를 상기 표 1에 준하여 테스트하였다.Whether or not the first and second samples were usable as a cleaning agent was tested in accordance with Table 1 above.
테스트 결과, 제1시료는 BULK DENSITY 0.89, 입도(10mesh) 8.8%, 외관 및 향취는 표준품과 동일하였으며, 유효산소량은 5.6, 수분함량은 4.3%, pH(1% Water Soln.) 10.5로서 합격기준에 모두 부합하였다.The test results showed that the first sample had a BULK DENSITY of 0.89, a particle size of 8.8%, an appearance and an odor of 5.8, a moisture content of 4.3% and a pH of 1% Respectively.
또한, 제2시료의 경우에도 BULK DENSITY 0.91, 입도(10mesh) 8.6%, 외관 및 향취는 표준품과 동일하였으며, 유효산소량은 5.1, 수분함량은 3.9%, pH(1% Water Soln.) 10.7로서 합격기준에 모두 부합하였다.The second sample also had BULK DENSITY of 0.91, particle size (10mesh) of 8.6%, appearance and odor of the same as the standard product, effective oxygen content of 5.1, water content of 3.9%, pH (1% Water Soln.) 10.7 All the criteria were met.
뿐만 아니라, 세척력도 테스트하였는데, 상온수를 사용하는 와류식세탁기에서 저수위(40L) 기준 습식인공오염포(1kg)에 대해 본 발명에 따른 제1시료와 제2시료 각 1정(3.4g) 사용시 세척력(%)은 각각 40.4%와 41.8%였고, 표백력(%)은 각각 9.6%와 9.9%였다.In addition, the washing power was also tested. In the case of using one sample (3.4 g) of the first sample and the second sample according to the present invention for a wet artificial contaminated cloth (1 kg) based on a low water level (40 L) in a swirl type washing machine using hot water, (%) Were 40.4% and 41.8%, respectively, and the bleaching power (%) was 9.6% and 9.9%, respectively.
그리고, 거품 발생 여부는 육안으로 확인하였으나 세탁 도중, 세탁 후 모두 거의 거품이 일지 않았고, 세탁 후 배수시에도 거품발생이 거의 없었다.In addition, the bubbles were visually inspected, but almost no bubbles were formed during washing and after washing, and bubbles were hardly generated even after washing and draining.
이것은 일반분말세제 40g과 동등 혹은 그 이상의 세척력과 표백력을 제공하는 것으로 본 발명에 따른 제형 제정 형태, 즉 타블렛 형태의 워싱 타블렛이 우수한 세척력과 표백력을 가짐을 확인하는 예였다.This provides an equivalent or greater detergency and bleaching power to 40 grams of a conventional powder detergent, which was an example of confirming that the tablet formulation according to the present invention, i.e. tablet tablet wash tablets, has excellent cleaning and bleaching power.
Claims (3)
상기 워싱 타블렛은 고기능성 활성단백질 분해효소 15-20중량%와, 지방 분해효소 7-10중량%와, 기능성 가수분해효소 7-10중량%, 과탄산나트륨 2-4중량%와, 빌더 0.5-1.5중량%와, 황산나트륨 0.5-1.5중량%, 알칼리제 10-15중량%, 수소칼슘분말 25-30중량% 및 나머지 수소이온수로 이루어진 타블렛 조성물을 분무과립기로 과립화시킨 다음, 과립화된 원료를 벌크에 충진 후 압축하여 제형 정제로 제조되되,
상기 고기능성 활성단백질 분해효소는 프로테아제(Protease), 파파인(Papain), 브로멜라인(Bromelin), 판크레아틴(Pancreatin)이 각각 1:1:1:1의 중량비로 혼합한 혼합물이고;
상기 지방 분해효소는 리파아제(Lipase)이며;
상기 기능성 가수분해효소는 에스테라아제(Esterase), 포스파타아제(Phosphatase)가 각각 1:1의 중량비로 혼합된 혼합물이고;
상기 빌더는 비타민 E와 케라틴이 2:1의 중량비로 합성된 것이며;
상기 알칼리제는 천연 알칼리제인 세스키탄산나트륨(Sodium Sesqui Carbonate)인 것을 특징으로 하는 수소 워싱 타블렛.
A washing tablet for use as a laundry detergent;
The washing tablet comprises 15-20% by weight of high-activity active protease, 7-10% by weight of lipolytic enzyme, 7-10% by weight of functional hydrolase, 2-4% by weight of sodium percarbonate, By weight of sodium chloride, 0.5-1.5% by weight of sodium sulfate, 10-15% by weight of an alkali agent, 25-30% by weight of hydrogen calcium powder and balance hydrogen ion water is granulated with a spray granulator, Filling and compression to produce a formulation tablet,
The high-activity active proteinase is a mixture of Protease, Papain, Bromelin, and Pancreatin in a weight ratio of 1: 1: 1: 1, respectively;
The lipolytic enzyme is a lipase;
Wherein the functional hydrolase is a mixture of esterase and phosphatase at a weight ratio of 1: 1, respectively;
The builder is a vitamin E and keratin synthesized at a weight ratio of 2: 1;
Wherein the alkaline agent is a sodium alkaline sodium salt (Sodium Sesqui Carbonate).
상기 수소이온수는 기능 발현을 위해 1.2-1.8ppm의 수소이온농도를 유지하는 것을 특징으로 하는 수소 워싱 타블렛.
The method according to claim 1,
Wherein the hydrogen ion water maintains a hydrogen ion concentration of 1.2-1.8 ppm for functional expression.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020170028570A KR101753371B1 (en) | 2017-03-06 | 2017-03-06 | Washing Tablet |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020170028570A KR101753371B1 (en) | 2017-03-06 | 2017-03-06 | Washing Tablet |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR101753371B1 true KR101753371B1 (en) | 2017-07-04 |
Family
ID=59356765
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020170028570A KR101753371B1 (en) | 2017-03-06 | 2017-03-06 | Washing Tablet |
Country Status (1)
| Country | Link |
|---|---|
| KR (1) | KR101753371B1 (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20190070189A (en) | 2017-12-12 | 2019-06-20 | 박규섭 | Hydrogen Containing Enzyme Tablet Detergent |
| CN110184136A (en) * | 2019-06-03 | 2019-08-30 | 大连双迪创新科技研究院有限公司 | Hydrogen-rich detergent |
| KR102333166B1 (en) | 2021-09-10 | 2021-12-02 | 주식회사 지원정 | Method for manufacturing Washing tablet |
| CN114806725A (en) * | 2022-04-19 | 2022-07-29 | 青岛嘉乐宝环保用品有限公司 | Efficient household cleaning agent and preparation method thereof |
| KR102654384B1 (en) | 2024-01-02 | 2024-04-03 | 주식회사 블루워시 | Method for manufacturing tablet laundry detergent |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4264713B2 (en) * | 2003-05-07 | 2009-05-20 | ライオン株式会社 | Bleach cleaning composition |
| JP4358623B2 (en) | 2001-08-13 | 2009-11-04 | イーコラブ インコーポレイティド | Solid detergent composition and method for solidifying detergent composition |
| WO2015022874A1 (en) * | 2013-08-13 | 2015-02-19 | 株式会社シャレックス | Hydrogen-containing antimicrobial agent |
-
2017
- 2017-03-06 KR KR1020170028570A patent/KR101753371B1/en active IP Right Grant
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4358623B2 (en) | 2001-08-13 | 2009-11-04 | イーコラブ インコーポレイティド | Solid detergent composition and method for solidifying detergent composition |
| JP4264713B2 (en) * | 2003-05-07 | 2009-05-20 | ライオン株式会社 | Bleach cleaning composition |
| WO2015022874A1 (en) * | 2013-08-13 | 2015-02-19 | 株式会社シャレックス | Hydrogen-containing antimicrobial agent |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20190070189A (en) | 2017-12-12 | 2019-06-20 | 박규섭 | Hydrogen Containing Enzyme Tablet Detergent |
| KR102018898B1 (en) | 2017-12-12 | 2019-09-05 | 박규섭 | Hydrogen Containing Enzyme Tablet Detergent |
| CN110184136A (en) * | 2019-06-03 | 2019-08-30 | 大连双迪创新科技研究院有限公司 | Hydrogen-rich detergent |
| KR102333166B1 (en) | 2021-09-10 | 2021-12-02 | 주식회사 지원정 | Method for manufacturing Washing tablet |
| CN114806725A (en) * | 2022-04-19 | 2022-07-29 | 青岛嘉乐宝环保用品有限公司 | Efficient household cleaning agent and preparation method thereof |
| KR102654384B1 (en) | 2024-01-02 | 2024-04-03 | 주식회사 블루워시 | Method for manufacturing tablet laundry detergent |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR101753371B1 (en) | Washing Tablet | |
| EP2831214B1 (en) | Cleaning compositions comprising ph-switchable amine surfactants | |
| AT14818U1 (en) | CLEANING AGENTS CONTAINING CARBAMIDE AND / OR AT LEAST ONE DERIVATIVE HIERVON | |
| KR20160061771A (en) | Dishwashing detergent composition comprising spinach extract and manufacturing method thereof | |
| CN108359543A (en) | The aerobic foam washing compound powder of environment-friendly highly efficient decontamination that safe pro-skin, profession are sterilized | |
| US8637441B1 (en) | Non-foaming detergent and preparation method thereof | |
| KR20190070189A (en) | Hydrogen Containing Enzyme Tablet Detergent | |
| KR101565097B1 (en) | liquid detergent composition | |
| CN106118914A (en) | A kind of aminoacid adult's liquid detergent | |
| KR102258489B1 (en) | Tablet-Type Hydrogen Laundry Detergent | |
| KR20030070056A (en) | Method of laundering clothes and detergent composition therefor | |
| KR102333166B1 (en) | Method for manufacturing Washing tablet | |
| CN110016390A (en) | A kind of liquid detergent and preparation method thereof removing formaldehyde | |
| KR20160132644A (en) | Eco-friendly foaming detergent and its manufacturing method | |
| KR102039428B1 (en) | Detergent laundry ball | |
| CN101376869A (en) | Yanbai laundry powder | |
| KR101935851B1 (en) | Washing Ball | |
| JP2007031635A (en) | Soap composition | |
| KR20180038360A (en) | Eco-friendly detergent or eco-friendly cleanser composition comprising eco-friendly heavy metal removing agent or stabilizing agent for removing or stabilizing heavy metal in fine dust such as yellow sand and the like | |
| CN113355175A (en) | Trace efficient laundry detergent and preparation method thereof | |
| JP2835710B2 (en) | Denture cleaning composition | |
| ES2307676T3 (en) | USE OF A CLEANING PRODUCT CONCENTRATE AND PROCEDURE FOR CLEANING SURGICAL INSTRUMENTAL. | |
| RU2038366C1 (en) | Powdery detergent | |
| KR102654384B1 (en) | Method for manufacturing tablet laundry detergent | |
| CN109825376A (en) | Dish washing liquid and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| E902 | Notification of reason for refusal | ||
| E701 | Decision to grant or registration of patent right | ||
| GRNT | Written decision to grant |