RU2038366C1 - Powdery detergent - Google Patents

Abstract

FIELD: domestic chemistry. SUBSTANCE: the powdery detergent comprises (wt ): 10-20 a mixture of anoinic and nonionic surfactants; 5-10 complexing agent (diphonate); 0.01-10 zeolite and/or sodium tripolyphosphate; 5-15 sodium dicarbonate; 1-10.0 liquid soda glass; 0.5-2 sodium carboxymethyl cellulose; 0.05-0.15 optical bleaching agents; 0.5-2 alkaline protease; 0.001-1 complex CO₂-extract or hydrophytoconcentrate made of a mixture of hops and barley sprouts or complex CO₂-extract or hydrophytoconcentrate made of a mixture of carrot seeds and barley sprouts; 0.001-1 CO₂-extract or hydrophytoconcentrate made of hemp or CO₂-extract or hydrophytoconcentrate made of grape seeds; 0.001-0.5 CO₂- extract of mint or menthol or a mixture of CO₂-extract made of mint and menthol at a 2:1 weight ratio; 0.05-0.5 aroma; and up to 100 sodium sulfate and water. EFFECT: improved properties of the powdery detergent. 2 tbl

Description

 The invention relates to the production of universal synthetic detergents with biological additives for washing.

 In the production of synthetic detergents, a large place is given to bleaching agents and means to remove grease and protein stains.

For example, a well-known detergent composition contains 1-15% non-ionic surfactants, 1-50% non-condensed phosphate-based chelate compounds and alkaline lipase with an activity of more than 30% at pH 9. The composition is effective for removing fatty contaminants [1]
An effective detergent for washing clothes with a low irritating effect on the skin is also known, containing 1-60% alkyl glycosides, 0.1-40 surfactants having a sulfate, sulfonate or both of these groups or a betaine system, 0.1-10% of amine oxides, 0 , 1-10% surfactants containing a polyoxyethylene moiety, 0.01-3% mono- or sesquiterpene hydrocarbon and 0.0001-0.1% 2,4,5-trialkylisothiazolone-3 or 2-alkylbenzothiazolones-3 (C ₁ alkyls -C ₁₈ ) [2]
The detergent contains surfactants 11-25% sodium tripolyphosphate 20-28% sodium carboxymethyl cellulose (Na = CMC) 0.5-1.0; liquid sodium glass 1-2; soda ash 0.1-3.0; chalk 1-5; optical brightener 0.1-0.3; perfume 0.1-0.2 Na Cl 1-3.0; blue dye 0.00001-0.0001; water up to 100 [3]
Closest to the claimed detergent "Biolan" [4] containing, by weight.

Surfactants (in terms of 15.0 to 100% of the main
substances), including:
a) alkylbenzenesulfone -
you (sulfonol 40% solution, or 45% solution) 11.0
b) ethoxylated
fatty alcohols (synth
nol ALM-10 or synta
nol ACSE-12 or syntanol N DS-10 or sintamid-5) 3.0 c) soap powder 1.0
or soap shavings or
synthetic fatty acid fractions C ₁₇ -C ₂₀ 0.9
or fatty acids are techno-
salome (distill
lined) or a mixture thereof and
technical caustic soda (in
100% of the main
substances) for saponification of fatty acids 0.15 Diphonate 8.0 Zeolite 0-10.0 Sodium liquid glass 5.0 Sodium bicarbonate 10.0 Sodium tripolyphosphate 10.0-20.0 Optical brightener 0.1 Alkaline protease enzyme preparation (granular) 1.0 Fragrance 0.2
Sodium sulfate
or
Sodium Sulfate
and Water Up to 100.0
"Biolan" is used for washing and removing protein contaminants, shows good detergent properties in hard water, does not require a high temperature to remove contaminants, is low-phosphate, but it has an overdrying and allergic effect on the skin of the hands.

 The washing basis of this product, creating an alkaline environment when washing products, has a pronounced ability to inhibit reparative processes in the skin. The introduction of a soft surfactant into the detergent base does not mitigate the negative effect on the skin of the hands. When using this detergent, the alkali, combining with the protein part of the epidermis, transfers them to alkaline albuminates that are easily soluble in water, which are removed by rinsing the laundry, while the content of the so-called sulfhydryl groups and fatty components in the skin is reduced, which is accompanied by a feeling of excessive dryness , tightness and glossiness of the skin, the appearance of peeling and irritation. In addition, the Na-A zeolite and alkaline prosthesis contained in the detergent are irritating, being moderate allergens. That is, the powder causes chemical damage to the molecules of deoxyribonucleic acid (DNA) resulting from exposure to alkali, sodium chloride, zeolite and sodium silicate, because this product has an indiscriminate detergent effect, which leads to the need to use hand protection (creams, gloves )

 Sodium tripolyphosphate, Na-A zeolite and diphonate are used as complexing agents (to soften water), sodium chloride, sodium tripolyphosphate, Na-A zeolite are used to enhance the washing action.

 Diphonate is a complexing composition based on partially substituted sodium salts of aminomethylphosphonic, hydroxyethylidene diphosphonic, phosphorous and hydrochloric acids.

 Zeolites Na-A are microporous crystalline aluminosilicates of a crystalline structure with high ion-exchange ability and very small particle sizes.

 Sodium carboxymethyl cellulose is used to prevent graying of textiles during repeated washing and as a stabilizer for the action of surfactants.

 Sodium silicate (liquid sodium glass) is used to form powder granules during drying during production and as an inhibitor of metal corrosion.

 Sodium sulfate is introduced as a neutral filler to improve the marketability of the powder.

 Optical brighteners give the product a whitening effect and allow you to abandon blue to eliminate yellowness when washing white products.

 Alkaline protease is used as a bioadditive, leading to the hydrolysis of protein substrates.

 The invention solves the problem of creating a highly effective whitening detergent with new additional functions that does not cause allergic reactions on the skin and mucous membranes, overdrying the skin and thinning it.

The goal is achieved by the fact that in a powder detergent containing a mixture of anionic and nonionic surfactants, diphonate, zeolite and / or sodium tripolyphosphate, sodium bicarbonate, liquid sodium glass, sodium carboxymethyl cellulose, optical brighteners, alkaline protease, perfume, sodium sulfate water, further administered an integrated CO ₂ extract gidrofitokontsentrat or from a mixture of hops and barley germs or integrated CO ₂ extract of carrots or gidrofitokontsentrat barley seeds and germs, CO ₂ extract or rods rofitokontsentrat hemp or CO ₂ extract of grape seeds or gidrofitokontsentrat, CO ₂ extract of peppermint or menthol or a mixture of CO ₂ extract of mint and menthol in a weight ratio of 2: 1. The components of the formulation are taken in the following ratio, wt.

A mixture of anionic and non-
ionogenic surface
active substances 10.0-20.0
Diphonate 5.0-10.0
Zeolite (Na-A) 0.01-10.0
and / or
Sodium tripolyphosphate 0.01-20.0
Sodium bicarbonate 5.0-15.0
Liquid sodium glass 1.0-10.0
Sodium Carboxymethyl
cellulose 0.5-2.0
Optical brighteners 0.05-0.15
Alkaline protease 0.5-2.0
Complex CO ₂ extract
or
Hydrophytoconcentrate from
a mixture of hops and barley sprouts
or
Complex CO ₂ extract
or
Hydrophytoconcentrate from
mixtures of carrot seeds and
barley sprouts 0.001-1.0
CO ₂ extract or hydro-
hemp phytoconcentrate
or
CO ₂ extract or hydrophi
grape toconcentrate
seeds 0.001-1.0
Mint or menthol CO ₂ extract
or
A mixture of CO ₂ mint extract
and menthol in mass
wearing 2: 1 0.001-0.5
Fragrance 0.05-0.5
Sodium sulfate or
Sodium Sulfate
and
water up to 100.0
Surface anionic substances create a highly alkaline environment, providing a good washing effect, have a high foaming ability in soft water. But when washing textiles with a machine, high foaming is undesirable. Therefore, a mixture of soap chips or FFA and caustic soda and a mixture of anionic and non-inogenous surfactants are introduced into the proposed agent. Non-inogenic surfactants soften the skin, are less sensitive to water hardness elements, have low foaming ability and good emulsifying properties. However, their introduction into the formulation does not solve the problem of reducing the harmful effects of detergent on the skin of the hands. This can be achieved by introducing extinguishing additives, biologically active substances of plant origin, such as CO ₂ extracts and plant hydrophytoconcentrates.

CO ₂ extracts are obtained by extraction with liquid carbon dioxide of plant materials with a moisture content of not more than 12% under pressure. They are either oily liquids or ointment-like substances that dissolve in vegetable oils, various solvents, surfactants, and perfumes, etc.

Hydrophytoconcentrates for SMS are obtained from waste from various food industries or from meal after CO ₂ extraction by grinding raw materials, isolating the hydrophilic fraction and drying with an adsorbent, which is used as a mixture of structure-forming and surface-active substances (a mixture of CMC or Na = CMC or gelatin or gelatinized starch or the like with sodium lauryl sulfate or oleate or stearate or the like)
Complex CO ₂ -extract N 12 obtained by extraction of liquid mixture of carbon dioxide with a blend of barley sprouts and hops contains: essential and fatty oils, waxes, carotenoids, tocopherols, sterols and sterols, free polyunsaturated (vitamin F factor) and bound acids. A small amount contains acids containing hormonal oil. The properties of the complex CO ₂ extract N 12 repeat the properties of the raw material. It has vitaminizing, nourishing, hydrating properties.

Complex CO ₂ extract N 13 is a mixture of vitamin substances of carrot seeds and barley sprouts, balanced at the stage of preparation for extraction. Extractives that turn into a complex CO ₂ extract: biologically active acids (Vitamin F factor) tocopherols, sterols, carotenoids, phospholipids, fatty oil, waxes, sterols, provide a hydrant, nourishing, plasticizing effect.

Hydrophytoconcentrates from complexes of raw mixes: sprouts of barley and hops or sprouts of barley and carrot seeds can fully replace CO ₂ extracts, contain proteins, tannins, water-soluble vitamins, mucus.

CO ₂ hemp seed extract contains fatty oil, unsaturated fatty acids, glycerides, vitamin K, cholesterol. It has analgesic and anti-inflammatory properties.

The CO ₂ extract of grape seeds contains sterols, tocopherols, carotenoids, free and bound fatty acids. It has antioxidant hydratant properties.

Hydrophytoconcentrates from hemp or grape seeds contain mucus, proteins, tannins, water-soluble vitamins and can replace CO ₂ extracts in the detergent formulation.

The mint CO ₂ extract contains up to 40% menthol (as part of an essential oil), carotenoids, tocopherols, waxes, free and bound acids. It has a local anesthetic, analgesic, antiseptic antispasmodic effect. It is a natural flavor and odor stabilizer.

 Synthetic menthol is a product of chemical synthesis, is a pure menthol with a characteristic odor and taste, which is a natural fragrance, exhibits a local anesthetic property.

The high washing action of powder SMS is ensured by adsorption at the phase boundaries and the formation of miscells, dispersion and dissolution of contaminants. The introduction into the formulation of a protected agent of vegetable biologically active substances of CO ₂ extracts or hydrophytoconcentrates in combination with non-inorganic surfactants due to plant waxes and filler fillers in hydrophytoconcentrates contained in CO ₂ extracts increases the solubilization of water-insoluble substances. The combination of waxes or membranous fillers with soap chips or powder as part of a surfactant enhances the washing and foaming effect of SMS.

 It is known that the introduction of sodium tripolyphosphate to soften water has an extremely negative effect on the quality of wastewater generated during washing, as phosphorus-containing complexes practically do not decompose into safe components and make synthetic detergents environmentally hazardous.

To mitigate the negative impact on the environment by reducing the concentration of sodium tripolyphosphate in detergents while maintaining the ability of high-quality washing in hard water, complexon diphonate is introduced. Diphonate is a complexing composition based on partially substituted sodium salts of aminomethylphosphonic, hydroxyethylidene diphosphonic, phosphorous and hydrochloric acids. The introduction of complex-forming components of CO ₂ -extracts or hydrophytoconcentrates enhances the complexing effects of diphonate and zeolite, which, with the total use of all components, can reduce the concentration of sodium tripolyphosphate by 1.5-2 times; at the same time, the developed synthetic detergent becomes environmentally friendly.

 The process of removing contaminants from surfaces is reversible, i.e. contaminants can be deposited on products again, therefore, the detergent should not only remove contaminants, but also hold them in the form of suspensions, preventing their re-deposition on the fabric, i.e. the detergent must have a stabilizing effect.

 But a synthetic detergent is more hydrophilic than fat soaps and has a small stabilizing ability. To prevent graying of tissues after repeated treatment with SMS solutions, it is necessary to introduce antiresorption agents into the formulation. These are, in addition to sodium carboxymethyl cellulose, as part of the formulation, waxes of CO extracts and an additional amount of sodium carboxymethyl cellulose as part of powder hydrophytoconcentrates. The introduction of plant-based additives enhances the effect of a linear anionic colloid, which has a large electronegative charge, which is distributed throughout the macromolecule.

 Most plant fibers in water are negatively charged due to the selective adsorption of hydroxyl ions. Pollution also has a negative charge in water.

The introduced complex based on Na-CMC increases the negative charge of the fibers, as a result of which there is a strong electrostatic repulsion between the fiber and the pollution, exceeding the forces that hold the pollution on the fiber. This leads to the displacement of contamination from the fiber or to such a strong loosening of contamination that it is easily removed by mechanical action. Thus, the combination of Na-CMC with CO ₂ extracts or hydrophytoconcentrates containing plant complexing agents enhances the effect of suspensions.

An additional enhancement of electrostatic repulsion between fiber and contamination is provided by a combination of sodium bicarbonate with CO ₂ extracts or hydrophytoconcentrates, which improves the cleaning properties of the proposed tool.

 An approximate calculation of the dosages of carbon dioxide extracts was carried out according to the concentration of the main biologically active components and data on the dosages of individual biologically active substances in similar detergents with tocopherols and waxes.

, где P_э дозировка экстракта,
Р_БАВ дозировка биологически активных компонентов,
С_БАВ концентрация БАВ в экстрактах,
Ориентировочные дозировки вводимых СО₂-экстрактов были определены:
Комплексный СО₂-экстракт
из смеси ростков ячменя и
хмеля (N 12)
или
Комплексный СО₂-экстракт
из смеси семян моркови и рост-
ков ячменя (N 13)
и/или
Гидрофитоконцентраты из
купажных сырьевых смесей
N 12 или N13 0,001-1,5
СО₂-экстракт конопли
или
СО₂-экстракт виноградных семян
и/или
Гидрофитоконцентраты из
этого сырья 0,001-1,5
СО₂-экстракт мяты 0,001-1,5
Для изучения влияния дозировки СО₂-экстрактов на моющую способность средства, обогащения его биологически активными веществами проведена серия опытов с использованием математического планирования на симплексе. Так как наибольшее влияние на дополнительные функции синтетического моющего средства оказывают поверхностно-активные вещества и растительные БАВ, то варьированию подвергались именно эти компоненты рецептуры (табл. 1). где
х₁ комплексный СО₂-экстракт N 12
или
комплексный СО₂-экстракт N 13
х₂ СО₂-экстракт конопли
или
СО₂-экстракт виноградных семян
х₃ СО₂-экстракт мяты
х₄ смесь ПАВ
х₅ остальное
В качестве показателей, характеризующих свойства конечного продукта, определялись рН 1,00%-ного раствора, по ГОСТ 22567.1-77 пенообразующая способность при 50^оС, по ОСТ 6-15-1574-87 моющая способность при 50^оС, содержание токоферолов в средстве.According to a generalized analysis of the recommended dosages of biologically active substances and their concentrations in extracts, the dosages of the introduced ingredients are determined by the formula:
P _e

where P _{e the} dosage of the extract,
R _BAS dosage of biologically active components,
With _{biologically active substances, the} concentration of biologically active substances in extracts,
Estimated dosages of the introduced CO ₂ extracts were determined:
Complex CO ₂ extract
from a mixture of barley sprouts and
hops (N 12)
or
Complex CO ₂ extract
from a mixture of carrot seeds and growth -
Barley Cove (N 13)
and / or
Hydrophytoconcentrates from
blending raw mixes
N 12 or N13 0.001-1.5
CO ₂ hemp extract
or
CO ₂ grape seed extract
and / or
Hydrophytoconcentrates from
of this raw material 0.001-1.5
Mint CO ₂ extract 0.001-1.5
To study the effect of the dosage of CO ₂ extracts on the washing ability of the product, enriching it with biologically active substances, a series of experiments was carried out using mathematical planning on a simplex. Since surfactants and vegetable biologically active substances have the greatest influence on the additional functions of synthetic detergents, it was these components of the formulation that were subjected to variation (Table 1). Where
x ₁ complex CO ₂ extract N 12
or
complex CO ₂ extract N 13
x ₂ CO ₂ hemp extract
or
CO ₂ grape seed extract
x ₃ CO ₂ mint extract
x ₄ surfactant mixture
x ₅ rest
As indices characterizing the properties of the final product were determined by pH 1.00% solution, GOST 22567.1-77 foaming capacity ^at 50 ° C for TPO 6-15-1574-87 detergency ^at 50 ° C, the content of tocopherols in means.

The essence of the method for determining the washing ability of SMS is a comparative assessment of the washing ability of the test detergent and the composition of the comparison. Washing ability was defined as the ratio of the degree of removal of contamination on cotton fabric with the solution of the test detergent to the degree of removal of pollution on the same fabric, under the same conditions of washing with the standard solution. The reference was the composition of the comparison, prepared on the basis of linear alkylbenzenesulfonate (surfactant) company "Hulz" (Marlon-ARL). The washing was carried out on a Linitest laboratory washing machine under the following conditions:
Detergent dose 5 g / l Bath module 1:90
Calcium gesture
bone
water 5.35 mEq / L
Type of fabric Cotton
Type of pollution of fabric Protein
Duration of washing 2 min 20 + wash temperature 40 ^{° C} + 5 2 Number of washes
As a result of the studies, data were obtained that underwent further mathematical processing to verify the adequacy of the proposed model and optimize it in order to determine the best options.

 The regression equations for the studied indicators of the effectiveness of the mixture, the content of tocopherols, pH, washing ability and foaming ability were analyzed by constructing the correct simplex tetrahedron. The points inside the tetrahedron correspond to four-component systems. Graphically, such a system is represented in the form of sections of a three-dimensional simplex by planes perpendicular to one of its axes. The transition from one section to another corresponds to a change in the fourth component.

When performing studies, data on the "content of tocopherols", pH, washing ability, foaming were obtained by mixing CO ₂ extracts and a mixture of surfactants.

 The scheme (Table 1) consists of 15 experiments, the 16th control to verify the adequacy of the developed model.

1. The content of tocopherols:
Y ₁ = 3.2X ₂ + 1.5X ₃ + 3.6X ₁ X ₂ + 0.2X ₁ X ₃ +
1.8X ₂ X ₃ + 3.6X ₂ X ₄ + 3.6X ₂ X ₅ + 0.6X ₃ X ₄ +
+ 0.2X ₃ X ₅
2. Foaming ability:
Y ₂ = 94X ₁ + 92X ₂ + 90X ₃ + 94X ₄ + 120X ₅ +
+ 20X ₁ X ₂ + 16X ₁ X ₃ + 4X ₁ X ₄ + 32X ₁ X ₅ +
+ 12X ₂ X ₃ + 16X ₂ X ₄ + 36X ₂ X ₅ + 32X ₃ X ₄ +
+ 36X ₃ X ₅ + 20X ₄ X ₅
3. Washing ability:
Y ₃ = 66.8X ₁ + 69.1X ₂ + 68.9X ₃ + 67.4X ₄ +
+ 75.3X ₅ 3.4X ₁ X ₂ 3.4X ₁ X ₃ 0.8X ₁ X ₄ +
+ 20.2X ₁ X ₅ + 34X ₂ X ₃ 5X ₂ X ₄ + 17.2X ₂ X ₅
6.6X ₃ X ₄ + 19.6X ₃ X ₅ + 18.6X ₄ X ₅
4. pH:
Y ₄ 11X ₁ + 9.5X ₂ + 10X ₃ + 11X ₄ + 12X ₅ +
+ X ₁ X ₂ 2X ₁ X ₅ 5X ₂ X ₃ + 2,2X ₂ X ₄ +
+ X ₂ X ₅ 0,8X ₃ X ₄ 1,2X ₃ X ₅ 2X ₄ X ₅
An analysis of empirically obtained data on revealing the dependence of the content of biologically active substances on the composition of synthetic detergent makes it possible to determine with high accuracy the optimal ratio of the components: CO ₂ extracts and surfactant mixtures. When the deviation from the levels is equal to 0.4, the maximum saturation with lines of equal values of the surface of the simplex is observed in the mixing region with the prevailing content of complex CO ₂ -extract N 12 or complex CO ₂ -extract N 13 and CO ₂ -extract of hemp or CO ₂ -extract of grape seed. The optimal dosage should be taken to achieve good values of quality indicators: A mixture of surfactants 10-20
Integrated СО ₂ -
extract N 12
or
Complex CO ₂ - extract N 13 0.01-1.0
CO ₂ hemp extract
or
CO ₂ extract of grape seeds 0.01-1.0
By analyzing various dosage combinations of the extracts used and the surfactant mixture as a result of creating a new synthetic detergent formulation, the ability of the extracts to reduce the dosage of expensive perfumes, as well as improve the quality of laundered items due to the high content of fatty oils that increase the content of natural soap and enhance the antiresorption properties of the product by retaining contaminants in the solution and preventing their re-settling on the fibers and with a minimum concentration and 0.001%
With the exception of extracts, the identical properties of a synthetic detergent are achieved by increasing the dosages of a mixture of surfactants by 5-10% alkaline protease by 0.5-1.0%
A general assessment of the quality of synthetic detergent in terms of detergent action showed a decrease in residual contamination with the introduction of CO ₂ -extract complex N 12 or N 13, CO ₂ -extract of hemp or grape seeds by an average of 5% in comparison with the prototype.

Thus, the introduction of a complex CO ₂ extract from barley and hop sprouts or from a mixture of carrot seeds and barley sprouts or hydrophytoconcentrates from these blend raw materials, CO ₂ hemp extract or grape seeds or their hydrophytoconcentrates and peppermint CO ₂ extract together with ingredients formulations provides mitigation of the harmful effects on the skin of the hands, high quality washing, saving perfume.

 The combination of surfactants and carbon dioxide extracts in the complex allows you to preserve the natural state of the skin due to the high content of the lipid complex in the extracts and the presence of a large number of over-spraying substances.

The method of preparing a synthetic detergent is as follows: in the mixer for preparing the composition, equipped with a heating jacket and a stirrer, load the calculated amount of surfactant, diphonate, Na-A zeolite and / or sodium tripolyphosphate, sodium bicarbonate, liquid sodium glass, sodium- carboxymethylcellulose, sodium sulfate, optical brightener and water at a temperature of 70-90 ^{° C,} the composition was stirred for 10-15 minutes and then through a decanter trap is pumped into the feed mixer where lead final mixing the composition for 10 minutes

Before serving for spraying, the composition is homogenized while grinding large particles formed during the preparation of the composition. The pumps then pump the mixture to spray through nozzles in the drying towers. Sodium bicarbonate, alkaline protease is added to the resulting powder. Fragrance, CO ₂ -extracts or GFK are introduced at the final stage by spraying.

 Below is an example of the preparation of SMS recipes per 1 ton of finished product. Other examples are given in table. 2.

In the reactor to prepare the composition is loaded, kg: 100% sulfonol 76.0; soap powder 5.0; diphonate 50.0; optical brightener 1.0; liquid sodium glass 50.0; sodium bicarbonate 100.0; sodium tripolyphosphate 100.0; Zeolite Na-A 50.0; sodium carboxymethyl cellulose 12.0; sodium sulfate 495.5 and water. At a temperature of 70-90 ^{° C} the composition was stirred for 15 min. Next, the finished composition is pumped through a settling trap into a feed mixer, where final mixing is performed for 10 minutes. The composition is homogenized in a homogenizer for 15 minutes. Next, the pump is sprayed through nozzles in the drying tower. After drying, the powder is mixed with 8.0 kg of alkaline protease. A mixture of 19.0 kg of syntanol, 2 kg of fragrance and 0.5 kg of complex CO ₂ extract from a mixture of barley and hop sprouts, 0.5 kg of CO ₂ extract of grape seeds and 0.5 kg of CO ₂ mint extract is fed into powder spraying at the final stage.

 Evaluation of the consumer properties of a synthetic detergent showed an improvement in the appearance of the skin of the hands; the skin is elastic; there is no feeling of tightness and glossiness;

 The introduction of a new SMS into production will expand the range of products in high demand.

Claims (1)

POWDER DETERGENT, containing a mixture of anionic and nonionic surfactants, a complexing composition based on partially substituted sodium salts of aminomethylphosphonic, hydroxyethylidene diphosphonic, phosphorous and hydrochloric acid-diphonate, zeolite and / or sodium tripolyphosphate, sodium triphosphonate, sodium triphosphate; , optical brighteners, alkaline protease, perfume, sodium sulfate and water, characterized in that it further comprises a complex CO ₂ -extra an act, or a hydrophytoconcentrate from a mixture of hops and barley sprouts, or a complex CO ₂ extract, or a hydrophytoconcentrate from a mixture of carrot seeds and barley sprouts, a CO ₂ extract or hemp hydrophytoconcentrate, or a CO ₂ extract or grape seed hydrophytoconcentrate, CO ₂ extract peppermint or menthol, or a mixture of a CO ₂ extract of peppermint and menthol in a mass ratio of 2 1 in the following ratio of components, wt. A mixture of anionic and nonionic surfactants 10.0 - 20.0
Diphonate 5.0 10.0
Zeolite and / or 0.01 10.0
Sodium tripolyphosphate 0.01 20.0
Sodium bicarbonate 5.0 15.0
Liquid sodium glass 1.0 10.0
Sodium carboxymethyl cellulose 0.5 2.0
Optical brighteners 0.05 0.15
Alkaline protease 0.5 2.0
Complex CO ₂ extract or hydrophytoxicentrate from a mixture of hops and barley sprouts
Complex CO ₂ extract or hydrophytoxicentrate from a mixture of carrot seeds and barley sprouts 0.001 1.0
CO ₂ extract, or hemp hydrophytoconcentrate,
or CO ₂ extract, or grape seed hydrophytoconcentrate 0.001 1.0
Peppermint CO ₂ Extract or Menthol
or
A mixture of CO ₂ extract of peppermint and menthol in a mass ratio of 2 1 0.001 0.5
Fragrance 0.05 0.5
Sodium Sulfate and Water Up to 100.0

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