WO2006040189A1 - Composition comprising a hop extract benefit agent - Google Patents
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- WO2006040189A1 WO2006040189A1 PCT/EP2005/011171 EP2005011171W WO2006040189A1 WO 2006040189 A1 WO2006040189 A1 WO 2006040189A1 EP 2005011171 W EP2005011171 W EP 2005011171W WO 2006040189 A1 WO2006040189 A1 WO 2006040189A1
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- hop extract
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- hop
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/40—Products in which the composition is not well defined
- C11D7/44—Vegetable products
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N61/00—Biocides, pest repellants or attractants, or plant growth regulators containing substances of unknown or undetermined composition, e.g. substances characterised only by the mode of action
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/08—Magnoliopsida [dicotyledons]
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2/00—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor
- A61L2/16—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor using chemical substances
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/01—Deodorant compositions
- A61L9/013—Deodorant compositions containing animal or plant extracts, or vegetable material
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0068—Deodorant compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
Definitions
- TITLE Composition comprising a hop extract benefit agent
- the invention relates to a home-care or fabric-care or institutional-cleaning or industrial-cleaning composition comprising a benefit agent.
- the composition can provide benefits such as preventing bacteria proliferation.
- the invention also relates to a process of treating a surface for example against bacteria proliferation, comprising the step of applying onto the surface a composition according to the invention. This can provide cleaning, disinfection, suppression of odors, and/or prevention of malodors.
- a product must bring more than the basic cleaning benefit: It has to provide a safe, healthy and pleasant environment which explains for example the success for formulations that "clean and disinfect and suppress malodors" at the same time.
- the drawbacks of these "bleach systems" are that they are sometimes very aggressive on delicate fabric or surfaces.
- these bleach may lead to restrictions regarding freedom to formulate because of stability problems at alkaline pH or because of incompatibility with some ingredients of the formulation (enzymes).
- WO02085109 disinfection of hard surfaces in the house with thymol, geraniol, carvacrol, citrai, terpinene, carvone, limonene.
- WO9802044 describes the use of thymol, eugenol, verbenone, eucalyptol, terpineol, cinnamic acid in hard surfaces and laundry detergent formulations.
- natural ingredients mentioned above are not considered as completely safe, although they benefit from a great impact in consumers mind because they have a natural origin.
- Others essential oils are under scrutiny and the Directive European 2003/15/EC now limits the amount of some fragrances or oils in cosmetics and detergents in order to reduce the risk of skin irritation or sensitization that may occur by repeated exposure to these compounds.
- Limonene, geraniol, eugenol cinnamal and cinnamyl alcohol are amongst the essential oils that need to be incorporated at levels below 100 ppm for rinse off formulations and below 10 ppm for leave on formulations, in order to limit the risk of allergy and sensitization. These low amounts can limit the benefits thereof.
- the SCCNFP Stemific Committee on cosmetic products and non food products intended for consumers
- compositions to be used by consumers such as home-care or fabric-care compositions or institutional cleaning compositions or industrial cleaning compositions
- GRAS Generally Recognised As Safe
- Hop extracts such as hop acids (alpha acids also referred as to Humulone and Beta acids also referred as to Lupulone) present in hop have been long known and used for their bacteriostatic and bacteriocidal functions in the beer industry.
- Hop acids include the alpha and beta acids and their GRAS derivatives traditionnaly used for the preparation of beer like: humulone, cohumulone, adhumulone, iso humulone, iso cohumulone, iso adhumulones, dishydro iso alpha acids, tetrahydro isoalpha acids, hexahydro iso alpha acids, hexahydrolupulone, hexahydrocolupulone ( hexahydro beta acids)...
- hop acids used alone or in blends
- hop compounds like iso alpha acids are weak acids that can cross cytoplasmic membranes and disrupt the pH gradient of the cell, which results in the starving of the cell.
- references about this topic include the following documents: Simpson,W.J., Smith, A.R.W., J.appl.Bacteriol., 1992,72,327-334.
- Sakamoto.K. Van veen H.W, Saito. H, Kobayashi.H, Konings.W.N, Appl. And Environmet.l Microbiol., 2002,68,11 , 5374-5378.
- Beta acids from hop have been shown as demonstrating superior efficiency against development of gram + bacteria and claimed for use in food preservation. This is for example described in documents US 5,286,506 and US 6,475,537. New methods have been described to optimize the stability of hop beta acids by converting them to hexahydro beta acids. This is for example described in document US 5,166,449.
- the invention provides a home-care, or fabric-care, or institutional-cleaning or industrial-cleaning composition comprising a hop extract.
- the composition can be for example a hard surface cleaner or detergent composition.
- the invention provides a process of treatment a surface for preventing bacteria proliferation, cleaning, disinfecting, suppressing odors, and/or preventing malodor, comprising the step of applying onto the surface a composition comprising a hop extract.
- the invention provides the use of a hop extract in a home-care, or fabric-care, or an institutional-cleaning or industrial-cleaning composition, as an agent for preventing bacteria proliferation, cleaning, disinfecting, suppressing odors, and/or preventing malodor.
- the composition, the process can provide the treating for preventing bacteria proliferation, cleaning, disinfecting, suppressing odors, and/or preventing of malodors, while addressing at least some concerns about safety (the composition being GRAS) 1 and/or being non sensitizing for users.
- the composition can provide disinfecting as well as odor and/or malodor control benefits, while trying to prevent any risk of sensitization by skin contact and/or inhalation, during the cleaning step to remove source of malodor and/or while the consumer wears the clothes to neutralize the gram + bacteria that can be present on skin and are responsible for the malodor generation.
- This is believed to be true for the detergent used to clean clothes in the home as well as for the detergents used to clean linen and clothes, carpets and upholstery in collectivities such as schools, restaurants, hotels, hospitals, elderly homes where the risk of contamination by gram + bacteria is even greater.
- This operation of disinfecting clothes and/or preventing malodor generation due to resident bacteria on skin can be done without being detrimental to the skin and without risking to generate irritation and sensitization through skin contact and inhalation.
- the composition can provide bacteriostatic, bactericidal and/or malodor treatment to surfaces in the home, like those that are susceptible to be contaminated by gram + bacteria, while diminishing the risks of sensitization of the consumer by skin contact and/or inhalation.
- the composition can provide bacteriostatic, bactericidal and/or malodor treatment, while preventing any risk of sensitization by skin contact and/or inhalation.
- the composition can provide bacteriostatic , bactericidal and/or malodor treatment to surfaces while trying to prevent any risk of sensitization by skin contact and/or inhalation.
- the hop extract of the composition can be especially efficient against proliferation of the following:
- hop extract refers to compounds or compositions of matter obtained from hop, as well as compounds or compositions of matters chemically derived thereof.
- composition comprising a hop extract refers to a composition that can be used as such, or to a composition that is to be diluted before or during use (it can be referred to a "concentrate composition”) or to a composition in a diluted form (it can be referred to a "diluted composition”).
- hard surface refers to any surface found in homes or institutional buildings, or in industrial buildings, or in furniture, provided that the surface is not a fabric such as clothes, furniture fabrics, curtains, sheets. Hard surfaces especially include dishware, silverware, and any other surfaces that need to be cleaned regularly. Of course hard surfaces do not include skin or hair.
- composition of the invention comprises a hop extract.
- composition of whole hop varies according to the varieties.
- An example of a typical composition has been given by Stevens, R. (1987), Hops, an Introduction to Brewing
- Beta acids 4%
- Other resins 3%
- Whole hop is usually processed through liquid CO 2 or supercritical CO 2 to obtain the useful fractions of active components like alpha acids, beta acids and essential oils.
- the alpha and beta acids can be further processed and isomerised.
- hop extracts of interest for the invention are available on the market for brewery applications at Hopsteiner ( Germany), John I. Haas ( USA), Botanix (UK) . They comprise blends or pure extracts of active matter such as hop beta acids, hop alpha acids and their isomerised or reduced derivatives. Some examples of hop extracts composition are given hereafter for illustration:
- bitter acids component of the hops used in beer making and particularly the beta- acids have now been found to be useful as bactericides in food products.
- the most prevalent groups of bitter acids found as components of hops are the alpha-acids and the beta-acids, also referred to as humulones and lupulones, respectively. Both contribute bitterness to beer, but the alpha-acids are much more intense in this regard than the beta-acids.
- Producers of hop extracts isolate the alpha and beta acids commercially by various chromatographic techniques and have recently developed a technique to separate the two acid fractions using liquid carbon dioxide under supercritical conditions.
- a by-product of the operation is a product which contains approximately 61 weight percent beta-acids, the remainder consisting essentially of hops resins.
- This by-product can be standardized with malto-dextrin or other food grade carrier, spray-dried, and used as an antibacterial food ingredient.
- a preferred beta hop acids component is commercially available as a natural flavor extract containing 1 weight percent beta hop acids.
- the alpha-acids contained in hops are commonly known as humulone, cohumulone and adhumulone, while the beta-acids contained in hops are commonly known as lupulone, colupulone and adlupulone.
- Derivatives of the hop acids or hop resins which have demonstrated antibacterial properties such as hexahydrocolupulone and tetrahydroisohumulone, as disclosed in U.S. Pat. No. 5,455,038, are specifically contemplated for use in association with the present invention.
- Also considered as specifically contemplated for use in association with the present invention is the use of the acid salt forms of the hops acids or hops resins.
- the hop extract comprises preferably at least 5% by weight the active matter.
- composition comprising the hop extract
- the composition comprising the hop extract can be in different forms.
- the form usually depends upon the use of the composition.
- the composition can be a for example liquid, a gel, a foaming liquid, foam, a powder, or a tablet.
- Liquid compositions can be dispensed for example by spraying, by pouring or applying with a liquid dispensing device such as rollers or pumps.
- compositions can be diluted prior to being used, or during use. Dilution is preferably performed with water. Dilution rates usually depend upon the use of the composition.
- dilutions approaches can depend upon the very consumer that uses the composition.
- dilution rates can be of from 5 to
- the amount of hop extract in the composition is preferably of lower than 5% by weight, and preferably of higher than 100 ppm by weight.
- Concentrate compositions can advantageously comprise from 0.5% to 5% by weight of the hop extract.
- Diluted compositions can advantageously comprise from 100 ppm to 0.5% by weight of the hop extract.
- composition is a liquid composition
- a liquid concentrate composition said composition can comprise a liquid medium, preferably an aqueous medium, an alcoholic medium, or a hydroxy-alcoholic medium.
- the medium can be a part of the composition, a part of a concentrate composition, or a part of a diluted composition, for example the diluting medium.
- compositions will usually comprise further ingredients of home-care or fabric-care or institutional-cleaning or industrial-cleaning compositions.
- the further ingredients usually depend upon the use, destination and/or form of the composition. These further ingredients are known by the one skilled in the art of preparing compositions comprising several ingredients (or "formulations") to serve a use or a market.
- compositions that comprise a surfactant are for example useful in compositions that are to provide cleaning or degreasing, such as dish-washing compositions (hand dishwashing or automatic dishwashing), laundry compositions, hard-surface cleaning compositions, industrial cleaning or degreasing compositions.
- Useful surfactants include anionic, non ionic, cationic, amphoteric (including zwitterionic) surfactants and mixtures thereof.
- Anionic Surfactants include anionic, non ionic, cationic, amphoteric (including zwitterionic) surfactants and mixtures thereof.
- Anionic surfactants useful in the present invention are preferably selected from the group consisting of, linear alkylbenzene sulfonates, alpha olefin sulfonates, paraffin sulfonates, methyl ester sulfonates, alkyl sulfates, alkyl alkoxy sulfates, alkyl sulfonates, alkyl alkoxy carboxylate, alkyl alkoxylated sulfates, sarcosinates, taurinates, and mixtures thereof.
- alkyl ester sulfonates are desirable because they can be made with renewable, nonpetroleum resources.
- Preparation of the alkyl ester sulfonates surfactants components can be effected according to known methods disclosed in the technical literature. For instance, linear esters of C 8 -C 2 O carboxylic acids can be sulfonated with gaseous SO 3 according to "The Journal of the American Oil Chemists Society," 52 (1975), pp. 323-329. Suitable starting materials would include natural fatty substances as derived from tallow, palm, and coconut oils, etc.
- the preferred alkyl ester sulfonate surfactant especially for laundry applications, comprises alkyl ester sulfonate surfactants of the structural formula: 0
- R 3 is a C 8 -C 20 hydrocarbyl, preferably an alkyl, or combination thereof
- R 4 is a C 1 -C 6 hydrocarbyl, preferably an alkyl, or combination thereof
- M is a soluble salt- forming cation.
- Suitable salts include metal salts such as sodium, potassium, and lithium salts, and substituted or unsubstituted ammonium salts, such as methyl-, dimethyl, - trimethyl, and quaternary ammonium cations, e.g. tetramethyl-ammonium and dimethyl piperdinium, and cations derived from alkanolamines, e.g. monoethanol-amine, diethanolamine, and triethanolamine.
- R 3 is C- I0 -C 16 alkyl
- R 4 is methyl, ethyl or isopropyl.
- methyl ester sulfonates wherein R 3 is C 14 -C 16 alkyl.
- Alkyl sulfate surfactants are another type of anionic surfactant of importance for use herein.
- dissolution of alkyl sulfates can be obtained, as well as improved formulability in liquid detergent formulations are water soluble salts or acids of the formula ROSO 3 M wherein R preferably is a C 10 -C 24 hydrocarbyl, preferably an alkyl or hydroxyalkyl having a C 10 - C 20 alkyl component, more preferably a Ci 2 -C 18 alkyl or hydroxyalkyl, and M is H or a cation, e.g., an alkali or alkaline (Group IA or Group HA) metal cation (e.g., sodium, potassium, lithium, magnesium, calcium), substituted or unsubstituted ammonium cations such as
- alkyl chains of Ci 2 -C 16 are preferred for lower wash temperatures (e.g., below about 50 ° C) and C 16 -Ci 8 alkyl chains are preferred for higher wash temperatures (e.g., above about 5O 0 C).
- these surfactants include surfactants sold by Rhodia under the Rhodapan Trade Name.
- Alkyl alkoxylated sulfate surfactants are another category of useful anionic surfactant.
- surfactants are water soluble salts or acids typically of the formula RO(A) m SO 3 M wherein R is an unsubstituted C 10 -C 24 alkyl or hydroxyalkyl group having a C 10 -C 24 alkyl component, preferably a C 12 -C 20 alkyl or hydroxyalkyl, more preferably C 12 - C- I ⁇ alkyl or hydroxyalkyl, A is an ethoxy or propoxy unit, m is greater than zero, typically between about 0.5 and about 6, more preferably between about 0.5 and about 3, and M is H or a cation which can be, for example, a metal cation (e.g., sodium, potassium, lithium, calcium, magnesium, etc.), ammonium or substituted-ammonium cation.
- R is an unsubstituted C 10 -C 24 alkyl or hydroxyalkyl group having a C 10 -C 24 alkyl component, preferably a C 12 -C 20 alkyl
- Alkyl ethoxylated sulfates as well as alkyl propoxylated sulfates are contemplated herein.
- Specific examples of substituted ammonium cations include methyl-, dimethyl-, trimethyl-ammonium and quaternary ammonium cations, such as tetramethyl- ammonium, dimethyl piperidinium and cations derived from alkanolamines, e.g. monoethanolamine, diethanolamine, and triethanolamine, and mixtures thereof.
- Exemplary surfactants are C 12 -C 18 alkyl polyethoxylate (1.0) sulfate, C 12 -C 18 alkyl polyethoxylate (2.25) sulfate, Ci 2 -Ci 8 alkyl polyethoxylate (3.0) sulfate, and Ci 2 -C 18 alkyl polyethoxylate (4.0) sulfate wherein M is conveniently selected from sodium and potassium.
- Surfactants for use herein can be made from natural or synthetic alcohol feedstocks. Chain lengths represent average hydrocarbon distributions, including branching. Examples of these surfactants include surfactants sold by Rhodia under the Rhodapex Trade Name.
- Anionic Surfactants can also be included in the compositions hereof. These can include salts (including, for example, sodium, potassium, ammonium, and substituted ammonium salts such as mono-, di- and triethanolamine salts) of soap, C 8 -C 20 linear alkylbenzenesulphonat.es, for example sold by Rhodia under the Rhodacal trande name, C 8 -C 22 primary or secondary alkanesulphonates, C 8 -C 24 olefinsulphonates, sulphonated polycarboxylic acids prepared by sulphonation of the pyrolyzed product of alkaline earth metal citrates, e.g., as described in British patent specification No.
- salts including, for example, sodium, potassium, ammonium, and substituted ammonium salts such as mono-, di- and triethanolamine salts
- C 8 -C 20 linear alkylbenzenesulphonat.es for example sold by Rhodia under the Rhoda
- alkyl glycerol sulfonates alkyl glycerol sulfonates, fatty acyl glycerol sulfonates, fatty oleyl glycerol sulfates, alkyl phenol ethylene oxide ether sulfates, paraffin sulfonates, alkyl phosphates, isothionates such as the acyl isothionates, N-acyl taurates, fatty acid amides of methyl tauride, alkyl succinamates and sulfosuccinates, monoesters of sulfosuccinate, for example sold by Rhodia under the Geropon trade name (especially saturated and unsaturated Ci 2 -C 18 monoesters) diesters of sulfosuccinate (especially saturated and unsaturated C 6 -C t4 diesters), N-acyl_sarcosinates, sulfates of alkylpolysaccharides
- Suitable nonionic detergent surfactants are generally disclosed in U.S. Patent 3,929,678, Laughlin et al., issued December 30, 1975, at column 13, line 14 through column 16, line 6, incorporated herein by reference.
- Exemplary, non-limiting classes of useful nonionic surfactants include: alkyl dialkyl amine oxide, for example sold by
- Rhodia under the Rhodamox trade name alkyl ethoxylate, for example sold by Rhodia under the Rhodasurf trade name, alkanoyl glucose amide, alkyl betaines, for example sold by Rhodia under the Mirataine trade name, and mixtures thereof.
- Other nonionic surfactants for use herein include: The polyethylene, polypropylene, and polybutylene oxide condensates of alkyl phenols. In general, the polyethylene oxide condensates are preferred. These compounds include the condensation products of alkyl phenols having an alkyl group containing from about 6 to about 12 carbon atoms in either a straight chain or branched chain configuration with the alkylene oxide.
- the ethylene oxide is present in a amount equal to from about 5 to about 25 moles of ethylene oxide per mole of alkyle phenol.
- nonionic surfactants of this type include surfactants sold by Rhodia under the lgepal trade name . These are commonly referred to as phenol alkoxylates, (e.g., alkyl phenol ethoxylates).
- the condensation products of aliphatic alcohols with from about 1 to about 25 moles of ethylene oxide can either be straight or branched, primary or secondary, and generally contains from about 8 to about 22 carbon atoms. Particularly preferred are the condensation products of alcohols having an alkyl group containing from about 10 to about 20 carbon atoms with from about 2 to about 18 moles of ethylene oxide per mole of alcohol.
- nonionic surfactants of this type include TergitolB 15-S-9 (the condensation product of Cn-C 15 linear secondary alcohol with 9 moles ethylene oxide), Tergitol 24-L-6 NMW (the condensation product of C 12 -C 14 primary alcohol with 6 moles ethylene oxide with a narrow molecular weight distribution), both marketed by Union Carbide Corporation; Neodol® 45-9 (the condensation product of C 14 -C 15 linear alcohol with 9 moles of ethylene oxide), Neodol® 23-6.5 (the condensation product of C 12 -C 13 linear alcohol with 6.5 moles of ethylene oxide), Neodol® 45-7 (the condensation product of Ci 4 -C 15 linear alcohol with 7 moles of ethylene oxide), Neodol® 45-4 (the condensation product of Ci 4 -C 15 linear alcohol with 4 moles of ethylene oxide), marketed by Shell Chemical Company, Rhodasurf IT, DB, and B marketed by Rhodia, Plurafac LF 403, marketed by BASF, and Kyr
- nonionic surfactants include Dobanol 91-8® marketed by Shell Chemical Co. and Genapol UD-080® marketed by Hoechst. This category of nonionic surfactant is referred to generally as "alkyl ethoxylates.”
- alkyl ethoxylates The condensation products of ethylene oxide with a hydrophobic base formed by the condensation of propylene oxide with propylene glycol. The hydrophobic portion of these compounds preferably has a molecular weight of from about 1500 to about 1800 and exhibits water insolubility.
- polyoxyethylene moieties tends to increase the water solubility of the molecule as a whole, and the liquid character of the product is retained up to the point where the polyoxyethylene content is about 50% of the total weight of the condensation product, which corresponds to condensation with up to about 40 moles of ethylene oxide.
- examples of compounds of this type include certain of the commercially-available Pluronic® surfactants, marketed by BASF, and Antarox, marketed by Rhodia.
- Pluronic® surfactants marketed by BASF
- Antarox marketed by Rhodia.
- the hydrophobic moiety of these products consists of the reaction product of ethylenediamine and excess propylene oxide, and generally has a molecular weight of from about 2500 to about 3000.
- This hydrophobic moiety is condensed with ethylene oxide to the extent that the condensation product contains from about 40% to about 80% by weight of polyoxyethylene and has a molecular weight of from about 5,000 to about 11 ,000.
- Examples of this type of nonionic surfactant include certain of the commercially available TetronicB compounds, marketed by BASF.
- Semi-polar nonionic surfactants are a special category of nonionic surfactants which include water-soluble amine oxides containing one alkyl moiety of from about 10 to about 18 carbon atoms and 2 moieties selected from the group consisting of alkyl groups and hydroxyalkyl groups containing from about 1 to about 3 carbon atoms; water-soluble phosphine oxides containing one alkyl moiety of from about 10 to about 18 carbon atoms and 2 moieties selected from the group consisting of alkyl groups and hydroxyalkyl groups containing from about 1 to about 3 carbon atoms; and water-soluble sulfoxides containing one alkyl moiety of from about 10 to about 18 carbon atoms and a moiety selected from the group consisting of alkyl and hydroxyalkyl moieties of from about 1 to about 3 carbon atoms.
- Semi-polar nonionic detergent surfactants include the amine oxide surfactants having the formula: O
- R 3 is an alkyl, hydroxyalkyl, or alkyl phenyl group or mixtures thereof containing from about 8 to about 22 carbon atoms
- R 4 is an alkylene or hydroxyalkylene group containing from about 2 to about 3 carbon atoms or mixtures thereof
- x is from 0 to about 3
- each R 5 is an alkyl or hydroxyalkyl group containing from about 1 to about 3 carbon atoms or a polyethylene oxide group containing from about 1 to about 3 ethylene oxide groups.
- the R 5 groups can be attached to each other, e.g., through an oxygen or nitrogen atom, to form a ring structure.
- These amine oxide surfactants in particular include Ci 0 -Ci 8 alkyl dimethyl amine oxides and C 8 -C 12 alkoxy ethyl dihydroxy ethyl amine oxides.
- Any reducing saccharide containing 5 or 6 carbon atoms can be used, e.g., glucose, galactose and galactosyl moieties can be substituted for the glucosyl moieties.
- the hydrophobic group is attached at the 2-, 3-, 4-, etc. positions thus giving a glucose or galactose as opposed to a glucoside or galactoside.
- the intersaccharide bonds can be, e.g., between the one position of the additional saccharide units and the 2-, 3-, A-, and/or 6- positions on the preceding saccharide units.
- a polyalkylene-oxide chain joining the hydrophobic moiety and the polysaccharide moiety.
- the preferred alkyleneoxide is ethylene oxide.
- Typical hydrophobic groups include alkyl groups, either saturated or unsaturated, branched or unbranched containing from about 8 to about 18, preferably from about 10 to about 16, carbon atoms.
- the alkyl group is a straight chain saturated alkyl group.
- the alkyl group can contain up to about 3 hydroxy groups and/or the polyalkyleneoxide chain can contain up to about 10, preferably less than 5, alkyleneoxide moieties.
- Suitable alkyl polysaccharides are octyl, nonyl, decyl, undecyldodecyl, tridecyl, tetradecyl, pentadecyl, hexadecyl, heptadecyl, and octadecyl, di-, tri-, tetra-, penta-, and hexaglucosides, galactosides, lactosides, glucoses, fructosides, fructoses and/or galactoses.
- Suitable mixtures include coconut alkyl, di-, tri-, tetra-, and pentaglucosides and tallow alkyl tetra-, penta-, and hexa-glucosides.
- the preferred alkylpolyglycosides have the formula: R 2 O(C n H 2n O) t (glycosyl) x wherein R 2 is selected from the group consisting of alkyl, alkyl-phenyl, hydroxyalkyl, hydroxyalkylphenyl, and mixtures thereof in which the alkyl groups contain from about 10 to about 18, preferably from about 12 to about 14, carbon atoms; n is 2 or 3, preferably 2; t is from 0 to about 10, preferably 0; and x is from about 1.3 to about 10, preferably from about 1.3 to about 3, most preferably from about 1.3 to about 2.7.
- the glycosyl is preferably derived from glucose.
- the alcohol or alkylpolyethoxy alcohol is formed first and then reacted with glucose, or a source of glucose, to form the glucoside (attachment at the l-position).
- the additional glycosyl units can then be attached between their 1 position and the preceding glycosyl units 2-, 3-, 4- and/or 6-position, preferably predominantly the 2-position.
- Non ionic surfactant include fatty acid amide surfactants having the formula: O
- R 6 is an alkyl group containing from about 7 to about 21 (preferably from about 9 to about 17) carbon atoms and each R 7 is selected from the group consisting of hydrogen, C 1 -C 4 alkyl, C 1 -C 4 hydroxyalkyl, and -(C 2 H 4 O) x H where x varies from about 1 to about 3.
- Preferred amides are C 8 -C 2O ammonia amides, monoethanolamides, diethanolamides, and isopropanolamides.
- Cationic detersive surfactants can also be included in detergent compositions of the present invention.
- Cationic surfactants include the ammonium surfactants such as alkyldimethylammonium halogenides, and those surfactants having the formula: [R 2 (0R 3 ) y ] [R 4 (OR 3 ) y ] 2 R 5 N + X " wherein R 2 is an alkyl or alkyl benzyl group having from about 8 to about 18 carbon atoms in the alkyl chain, each R 3 is selected from the group consisting Of-CH 2 CH 2 -, -CH 2 CH(CH 3 )-, -CH 2 CH(CH 2 OH)-, -CH 2 CH 2 CH 2 -, and mixtures thereof; each R 4 is selected from the group consisting of C 1 -C 4 alky], C 1 -C 4 hydroxyalkyl, benzyl, ring structures formed by joining the two R 4 groups,
- R 6 is any hexose or hexose polymer having a molecular weight less than about 1000, and hydrogen when y is not 0;
- R 5 is the same as R 4 or is an alkyl chain wherein the total number of carbon atoms of R 2 plus R 5 is not more than about 18; each y is from 0 to about 10 and the sum of the y values is from 0 to about 15; and
- X is any compatible anion.
- Ampholytic surfactants can be incorporated into the detergent compositions hereof. These surfactants can be broadly described as aliphatic derivatives of secondary or tertiary amines, or aliphatic derivatives of heterocyclic secondary and tertiary amines in which the aliphatic radical can be straight chain or branched.
- One of the aliphatic substituents contains at least about 8 carbon atoms, typically from about 8 to about 18 carbon atoms, and at least one contains an anionic water-solubilizing group, e.g., carboxy, sulfonate, sulfate. See U.S. Patent No. 3,929,678 to Laughlin et al., issued
- Preferred amphoteric include C 12 -C 18 alkyl ethoxylates ("AE") including the so-called narrow peaked alkyl ethoxylates and C 6 -C 12 alkyl phenol alkoxylates (especially ethoxylates and mixed ethoxy/propoxy), C 12 -C 18 betaines and sulfobetaines ("sultaines”),
- Zwitterionic surfactants can also be incorporated into the detergent compositions hereof. These surfactants can be broadly described as derivatives of secondary and tertiary amines, derivatives of heterocyclic secondary and tertiary amines, or derivatives of quaternary ammonium, quaternary phosphonium or tertiary sulfonium compounds.
- Ampholytic and zwitterionic surfactants are generally used in combination with one or more anionic and/or nonionic surfactants.
- compositions include:
- deposition polymers such as silicones
- the composition is:
- a fabric care composition for example a pre-spotting composition, a detersive composition, or a rinsing composition
- a carpet cleaning composition for example a carpet cleaning spray, foam, or foaming liquid, - a softening and/or antiwrinkling and/or easy-ironing composition,
- laundry product composition in a liquid form, powder form or tablet form, that can be use in hand washing or in automatic washing,
- an automatic dishwashing composition in a liquid form, in a powder form, or in a tablet form, - a glass cleaning composition, including a window cleaning composition or a car windshield composition,
- a toilet bowl cleaning composition a rim block, or a rim liquid
- a shower rinse for providing disinfection and/or suppression of odors and/or prevention of malodor for clothes, curtains, sheets, furniture fabrics or car fabrics,
- the composition can be used for treating a surface against proliferation of bacteria. Accordingly, the composition can be used in a process of treating a surface against bacteria proliferation, comprising the step of applying onto surface a composition comprising a hop extract.
- the process (or treatment or use) can provide cleaning, disinfection, suppression of odors, and/or prevention of malodors.
- the surface can be for example a fabric or a hard surface.
- the surface is a fabric surface
- composition is fabric-care composition
- the composition comprising the hop extract is applied onto the surface during a washing process, preferably an automatic process, comprising the following steps: - optionally applying a pre-spotting composition onto the fabric surface,
- the composition comprising the hop extract being the pre-spotting composition, the detersive composition, or the rinsing composition.
- the composition comprising the hop extract can be a rinsing composition such as a softening and/or antiwrinkling and/or easy-ironing composition.
- the composition comprising the hop extract can also be a detersive laundry-product composition in a liquid form, in a powder form, or in a tablet form, optionally being a multiple benefit composition providing cleaning and softening and/or antiwrinkling and/or easy-ironing.
- the surface is a fabric surface, for example clothes, curtains, sheets, furniture fabrics or car fabrics, and
- composition comprising the hop extract is applied onto the surface by spraying.
- the composition can be a spray, used on a regularly basis or not, to prevent malodors and/or to suppress them, such as for example some spray compositions marketed as "Frebreze” by the Procter and Gamble company.
- the composition can also be used in ironing ("starching" compositions or "ironing moisturizing” compositions).
- the surface is a carpet
- the composition is a carpet cleaning composition, in the form of a liquid, a foaming liquid, a spray, or a spraying composition
- the composition is applied onto the carpet, the carpet is cleaned, and then optionally rinsed.
- Cleaning the carpet can be performed by any mean, for example by washing and/or shampooing.
- the surface is a hard surface
- composition is applied onto the surface by a process comprising the following steps:
- composition optionally diluted
- composition can by applied onto the surface by any appropriate mean.
- the applying processes and means can depend upon the surface to be treated, and upon the user.
- the surface in this embodiment can be:
- - glass for example comprised in windows, or cars windshields,
- - tile or ceramic for example comprised in kitchens, bathrooms, toilet bowls, showers, china, dishware, floors, - metal, for example comprised in silverware, car body parts, window frames, or floors,
- - plastic for example comprised in dishware, silverware, cars, windows, furniture, or floors,
- the composition can be applied by immersing the dishware into a diluted composition, by applying a concentrate composition directly onto the dishware, or by applying the composition onto a cleaning device such as a sponge, cloth, pad, scrub, brush or any other mean.
- the composition can be applied in diluted form through conventional automatic dishwashing schemes.
- the composition can be applied by any conventional mean, including direct spraying, spraying after dilution, application with using vehicles such as mops, pads, wipes, cloths, sponges, papers...
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- Life Sciences & Earth Sciences (AREA)
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- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Health & Medical Sciences (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Zoology (AREA)
- Dentistry (AREA)
- Agronomy & Crop Science (AREA)
- Veterinary Medicine (AREA)
- Public Health (AREA)
- Animal Behavior & Ethology (AREA)
- Environmental Sciences (AREA)
- Plant Pathology (AREA)
- Epidemiology (AREA)
- Mycology (AREA)
- Botany (AREA)
- Pest Control & Pesticides (AREA)
- Natural Medicines & Medicinal Plants (AREA)
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Abstract
Description
Claims
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US61937104P | 2004-10-15 | 2004-10-15 | |
US60/619,371 | 2004-10-15 |
Publications (1)
Publication Number | Publication Date |
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WO2006040189A1 true WO2006040189A1 (en) | 2006-04-20 |
Family
ID=35530831
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2005/011171 WO2006040189A1 (en) | 2004-10-15 | 2005-10-14 | Composition comprising a hop extract benefit agent |
Country Status (1)
Country | Link |
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WO (1) | WO2006040189A1 (en) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
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WO2009148800A1 (en) * | 2008-06-06 | 2009-12-10 | The Procter & Gamble Company | Hand fabric laundering system |
WO2009148801A1 (en) * | 2008-06-06 | 2009-12-10 | The Procter & Gamble Company | Hand fabric laundering method |
US9890350B2 (en) | 2015-10-28 | 2018-02-13 | Ecolab Usa Inc. | Methods of using a soil release polymer in a neutral or low alkaline prewash |
US20220304919A1 (en) * | 2021-03-25 | 2022-09-29 | The Procter & Gamble Company | Edible Oral Compositions Comprising Hops |
US11690792B2 (en) | 2019-09-30 | 2023-07-04 | The Procter & Gamble Company | Oral care compositions comprising hops beta acids and metal ions |
US11918681B2 (en) | 2019-09-30 | 2024-03-05 | The Procter & Gamble Company | Oral care compositions comprising hops beta acid and amino acid |
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WO2001006877A1 (en) * | 1999-07-27 | 2001-02-01 | Rhodia Inc. | Hops acid antibacterial compositions |
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Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2009148800A1 (en) * | 2008-06-06 | 2009-12-10 | The Procter & Gamble Company | Hand fabric laundering system |
WO2009148801A1 (en) * | 2008-06-06 | 2009-12-10 | The Procter & Gamble Company | Hand fabric laundering method |
US9890350B2 (en) | 2015-10-28 | 2018-02-13 | Ecolab Usa Inc. | Methods of using a soil release polymer in a neutral or low alkaline prewash |
US10377979B2 (en) | 2015-10-28 | 2019-08-13 | Ecolab Usa Inc. | Methods of using a soil release polymer in a prewash composition |
US11690792B2 (en) | 2019-09-30 | 2023-07-04 | The Procter & Gamble Company | Oral care compositions comprising hops beta acids and metal ions |
US11696881B2 (en) | 2019-09-30 | 2023-07-11 | The Procter & Gamble Company | Oral care compositions comprising hops beta acids and fluoride ions |
US11918681B2 (en) | 2019-09-30 | 2024-03-05 | The Procter & Gamble Company | Oral care compositions comprising hops beta acid and amino acid |
US20220304919A1 (en) * | 2021-03-25 | 2022-09-29 | The Procter & Gamble Company | Edible Oral Compositions Comprising Hops |
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