CN106118914A - A kind of aminoacid adult's liquid detergent - Google Patents

A kind of aminoacid adult's liquid detergent Download PDF

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Publication number
CN106118914A
CN106118914A CN201610536560.8A CN201610536560A CN106118914A CN 106118914 A CN106118914 A CN 106118914A CN 201610536560 A CN201610536560 A CN 201610536560A CN 106118914 A CN106118914 A CN 106118914A
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CN
China
Prior art keywords
aminoacid
liquid detergent
adult
amino acid
surfactant
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610536560.8A
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Chinese (zh)
Inventor
张健
张燕飞
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nantong Jia Jia Biological Technology Co., Ltd.
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张健
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Filing date
Publication date
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Priority to CN201610536560.8A priority Critical patent/CN106118914A/en
Publication of CN106118914A publication Critical patent/CN106118914A/en
Priority to PCT/CN2017/090461 priority patent/WO2018006734A1/en
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/04—Carboxylic acids or salts thereof
    • C11D1/10—Amino carboxylic acids; Imino carboxylic acids; Fatty acid condensates thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/37—Mixtures of compounds all of which are anionic
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/001—Softening compositions
    • C11D3/0015—Softening compositions liquid
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/044—Hydroxides or bases
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2065—Polyhydric alcohols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/34—Organic compounds containing sulfur
    • C11D3/3481—Organic compounds containing sulfur containing sulfur in a heterocyclic ring, e.g. sultones or sulfolanes
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50—Perfumes
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • C11D1/721—End blocked ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/74—Carboxylates or sulfonates esters of polyoxyalkylene glycols

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)
  • Cosmetics (AREA)

Abstract

The invention discloses a kind of aminoacid adult's liquid detergent, comprise amino acid surfactant；Described amino acid surfactant is main active ingredient；The weight ratio of described amino acid surfactant is 0.1 25%；Described aminoacid adult's liquid detergent possibly together with water, wetting agent, thickening agent and preservative, its percentage by weight be respectively as follows: water be 70 85%, wetting agent be 5 30%, thickening agent 0.1 6% and preservative be 0.1 1%；Aminoacid of the present invention adult's liquid detergent has the advantage that (1) really with product that amino acid surfactant is unique cleaning agent；The gentleest non-stimulated；(3) highly effective plaque-removing；(4) Low-foam and easily crosses water；(5) physical disinfection, safe and reliable；The most do not hinder clothes, gorgeous as new, " without classification, clean dirt, degerming de-taste, submissive medicated clothing ".

Description

A kind of aminoacid adult's liquid detergent
Technical field
The present invention relates to a kind of adult's liquid detergent, more particularly, it relates to one is unique with amino acid surfactant Aminoacid adult's liquid detergent of cleaning composition, safety and environmental protection, belongs to daily necessities field.
Background technology
Along with integration and the development of trade globalization of World Economics, culture background, technical merit and environmental regulation by Gradually becoming three large driving forces of articles for washing development of globalization, the articles for washing in the whole world will tend to variation, but energy-conservation, water saving, Efficiently, gentle, easy to use and meet the master that the product of safety and environmental requirement will be the development of current and future cleaning product Flow path direction.Owing to liquid detergent overcomes some shortcomings of detergent, development is quickly.It is known that containing a large amount of nothings in detergent The filler Matrii Sulfas Exsiccatus of any cleaning function, its mass fraction is more than 40%, causes great wave in terms of resource and the energy Take, the most also can cause dust pollution, be unfavorable for environmental protection.And liquid detergent instead of first bright with aboundresources and inexpensive water Powder, uses biodegradable surfactant as main component and to be aided with that phosphorus-free adjuvant is compounding to be formed.Due to equipment investment Few, production technology is easy, and performance gentleness is non-stimulated, it is easy to the feature such as dissolves and easy to use, is gradually accepted by people.
But its deficiency, the effective ingredient of existing liquid detergent is also had as a kind of emerging rising fluid product Mainly surfactant, it is mainly raw material with synthetic surfactant, such as sodium laurylsulfate.But it is the most degradable Maybe cannot degrade, to environment.Along with the progressively enhancing of people's environmental consciousness, the following developing direction of liquid detergent will be With environment-friendly and green type as main flow.In addition to having the function of strong detergency, harmless, sterilizing, gentle high bubble, also should hold Degradable, free from environmental pollution.
In recent years, along with going deep into aminoacid research, aminoacid is also more and more applied to every field.Its In, aminoacid application in household chemicals is also the problem of a research the most worth, and aminoacid daily use chemicals product are also by increasingly Many people are accepted and are pursued.In daily use chemicals product industrial quarters, aminoacid daily use chemicals product one of opera involving much singing and action the most especially, it is daily chemical industry It is filled with new vitality.
Aminoacid is containing amino and the common name of a class organic compound of carboxyl.It is that composition organism protein is the most same The most basic material that vital movement is relevant, is the ultimate unit constituting protein molecule in vivo, with biological life Activity has close relationship.It has special physiological function in antibody, is indispensable nutritional labeling in organism One of.
To this end, we have developed a kind of take amino acid surfactant as the amino uniquely cleaning composition, safety and environmental protection Acid adult's liquid detergent.
Summary of the invention
Present invention is primarily targeted at offer a kind of with amino acid surfactant for uniquely cleaning composition, safety and ring The aminoacid adult's liquid detergent protected.
For realizing aforementioned invention purpose, the technical solution used in the present invention includes: a kind of aminoacid adult's liquid detergent, comprises Amino acid surfactant；Described amino acid surfactant is main active ingredient；The weight of described amino acid surfactant Amount ratio is 0.1-25%；
Described aminoacid adult's liquid detergent is possibly together with water, wetting agent, thickening agent and preservative, and its percentage by weight is respectively For:
Water is 70-85%；
Wetting agent is 5-30%；
Thickening agent 0.1-6%；
Preservative is 0.1-1%；
The pH scope of described aminoacid adult's liquid detergent is between 6-8.
Preferably, described amino acid whose weight ratio is 5-20%.
Preferably, described amino acid whose weight ratio is 10-15%.
Preferably, described amino acid surfactant is based on alanine type surfactant, alanine type surface activity It is more than 60% that agent accounts for the percentage by weight of total surfactant, and wherein alanine type surfactant accounts for total surfactant Percentage by weight is more than 70% more preferably.
Preferably, described alanine type surfactant is including at least N-lauroyl-L-the third ammonia that concentration is more than 98% One in acid sodium and cocoamido sodium propionate.
Compared with prior art, the present invention at least has the advantage that
Aminoacid of the present invention adult's liquid detergent has the advantage that 1, uses amino acid surfactant is main Active ingredient, instead of traditional liquid detergent surfactant, such as sodium laurylsulfate；Remove chemical detergent to remain human body Injury and the pollution of environment, and non-stimulated, without allergy, underclothes and baby's medicated clothing be suitable for use；2, Low-foam and easily cross water, Discharge less, low energy consumption；3, highly effective plaque-removing；4, physical disinfection, safe and reliable；5, gentle amino acid surfactant liquid is used Formula, has and washes the multi-functional protecting unification, does not hinder clothes, gorgeous as new, " without classification, clean dirt, degerming de-taste, soft Along medicated clothing "；6, high-environmental, degradable, liquid detergent uses amino acid surfactant, its biological degradability more than 99.9%, Reaching allied substances degree of degradation peak, after discharging, the impact on environment is preferably minimized degree, meets low-carbon environment-friendly theory.
Accompanying drawing explanation
Fig. 1 is the page 1 of the survey report of aminoacid of the present invention adult's liquid detergent；
Fig. 2 is the page 2 of the survey report of aminoacid of the present invention adult's liquid detergent.
Detailed description of the invention
Below by specific embodiment, the present invention is described in further detail.
Aminoacid of the present invention adult's liquid detergent, comprises amino acid surfactant；Described amino acid surface activity Agent is as main active ingredient；Described amino acid surfactant is based on alanine type surfactant, alanine type table It is more than 60% that face activating agent accounts for the percentage by weight of total surfactant, and wherein alanine type surfactant accounts for total surface work Property agent percentage by weight be more than 70% more preferably；Described alanine type surfactant is more than 98% including at least concentration One in N-lauroyl-ALANINE sodium and cocoamido sodium propionate.
Described aminoacid adult's liquid detergent is possibly together with water, glycerol, sodium hydroxide, DOE-120 methyl glucoside polyoxy second Alkene (120) ether dioleate, CAB-35 cocamido propyl betaine, AEO-9 fatty alcohol-polyoxyethylene ether, Kazon and essence.
The ph value scope of described aminoacid adult's liquid detergent is between 6-8.
The percentage by weight of component of described aminoacid adult's liquid detergent is shown in Table one, table two, lists 10 embodiments altogether.
In view of deficiency of the prior art, inventor, through studying for a long period of time and putting into practice in a large number, is proposed the present invention's Technical scheme.This technical scheme, its implementation process and principle etc. will be further explained as follows.
Aminoacid we be all very familiar with, it is one of the numerous bioactive molecules building living organism, or builds people Somatic cell, the basic material of reparation tissue.
Aminoacid is the ultimate unit constituting protein, protein it be one of most important bioactive molecule in organism, Enzyme including catalysis metabolism.
Amino acid whose effect has a lot, and noxious substance in our human body can be excreted by it, effectively alleviate radiation, Pollute the injury that human body is caused.Get rid of the metabolite that body is internal after violent motion, thus there is promotion essence Many fast quick-recoveries such as god, body, muscle, therefore have well help to raising body function.
It is 98% that amino acid surfactant in aminoacid adult's liquid detergent that the present invention is produced at least contains concentration One in above N-lauroyl-ALANINE sodium salt and cocamidopropyl alanine sodium salt, instead of traditional surface and lives Property agent, if sodium laurylsulfate is main surfactant.Through overtesting: use weight ratio be total surfactant 60% with Under alanine type surfactant produced aminoacid adult liquid detergent, foaming abundancy degree weight/power ratio than for total surface activity Aminoacid adult's liquid detergent that the alanine type surfactant of more than the 60% of agent is produced is low, and stability is the most relatively poor, Dirt-removing power is poor.
In aminoacid of the present invention adult's liquid detergent, in addition to described aminoacid ingredient, also include preparing liquid detergent Base stock.
Data involved in table one, table two refer to parts by weight, aminoacid adult laundry in embodiment 1 to embodiment 10 The gross weight number of liquid is 100.
Table one
Table two
The core of the present invention is to use amino acid surfactant to add aminoacid to as major surfactant composition In adult's liquid detergent and verify its nontoxic, corrosion-free, pollution-free, noresidue and the quickest in aminoacid adult's liquid detergent Clear dirty removal capacities, refers to the survey report shown in accompanying drawing 1-2.
Compared with prior art, the present invention at least has the advantage that
Aminoacid of the present invention adult's liquid detergent has the advantage that 1, uses amino acid surfactant is main Want active ingredient, instead of traditional liquid detergent surfactant, such as sodium laurylsulfate；Remove chemical detergent to remain people The injury of body and the pollution of environment, and non-stimulated, without allergy, underclothes and baby's medicated clothing be suitable for use；2, Low-foam and easily mistake Water, discharge less, low energy consumption；3, highly effective plaque-removing；4, physical disinfection, safe and reliable；5, gentle amino acid surfactant is used Liquid formulations, has and washes the multi-functional protecting unification, does not hinder clothes, gorgeous as new, " without classification, cleans dirt, degerming goes Taste, submissive medicated clothing "；6, high-environmental, degradable, liquid detergent uses amino acid surfactant, and its biological degradability is 99.9% Above, reaching allied substances degree of degradation peak, after discharging, the impact on environment is preferably minimized degree, meets low-carbon environment-friendly reason Read.
Above-described embodiment, only for technology design and the feature of the explanation present invention, its object is to allow person skilled in the art Scholar will appreciate that present disclosure and is carried out, and can not limit the scope of the invention with this, all according to the present invention The equivalence that spirit is made changes or modifies, and all should contain within the scope of the present invention.

Claims (5)

1. aminoacid adult's liquid detergent, it is characterised in that comprise amino acid surfactant；Described amino acid surface activity Agent is main active ingredient；The weight ratio of described amino acid surfactant is 0.1-25%；
Described aminoacid adult's liquid detergent is possibly together with water, wetting agent, thickening agent and preservative, and its percentage by weight is respectively as follows:
Water is 70-85%；
Wetting agent is 5-30%；
Thickening agent 0.1-6%；
Preservative is 0.1-1%；
The pH scope of described aminoacid adult's liquid detergent is between 6-8.
2. according to the aminoacid adult's liquid detergent described in claim 1, it is characterised in that described amino acid surfactant Weight ratio is 5-20%.
3. according to the aminoacid adult's liquid detergent described in claim 2, it is characterised in that described amino acid surfactant Weight ratio is 10-15%.
4. according to the aminoacid adult's liquid detergent described in claim 1 or 2 or 3, it is characterised in that described amino acid surface is lived Property agent is based on alanine type surfactant, and alanine type surfactant accounts for the percentage by weight of total surfactant and is More than 60%, wherein alanine type surfactant accounts for the percentage by weight of total surfactant is more than 70% more preferably.
5. according to the aminoacid adult's liquid detergent described in claim 4, it is characterised in that described alanine type surfactant Including at least the one in N-lauroyl-ALANINE sodium that concentration is more than 98% and cocoamido sodium propionate.
CN201610536560.8A 2016-07-08 2016-07-08 A kind of aminoacid adult's liquid detergent Pending CN106118914A (en)

Priority Applications (2)

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CN201610536560.8A CN106118914A (en) 2016-07-08 2016-07-08 A kind of aminoacid adult's liquid detergent
PCT/CN2017/090461 WO2018006734A1 (en) 2016-07-08 2017-06-28 Amino acid-based laundry detergent for adult

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Cited By (6)

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CN106590981A (en) * 2016-11-17 2017-04-26 苏州三君日化科技有限公司 Laundry detergent containing sodium lauroyl sarcosine salt and cocoamido sodium propionate
WO2018006734A1 (en) * 2016-07-08 2018-01-11 张健 Amino acid-based laundry detergent for adult
WO2019233375A1 (en) * 2018-06-04 2019-12-12 苏州欧丽特生物医药有限公司 Self-assembled amino acid supramolecular polymer, preparation therefor, and application thereof
WO2019233377A1 (en) * 2018-06-04 2019-12-12 苏州欧丽特生物医药有限公司 Novel self-assembled amino acid supramolecular polymer, preparation method therefor, and application thereof
CN113174300A (en) * 2021-04-14 2021-07-27 大连工业大学 Grease-based acyl amino acid salt infant laundry detergent and preparation method thereof
JP7502800B2 (en) 2018-06-04 2024-06-19 ▲蘇▼州欧▲麗▼特生物医▲薬▼有限公司 Amino acid self-assembled supramolecular polymers and their preparation and use

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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2018006734A1 (en) * 2016-07-08 2018-01-11 张健 Amino acid-based laundry detergent for adult
CN106590981A (en) * 2016-11-17 2017-04-26 苏州三君日化科技有限公司 Laundry detergent containing sodium lauroyl sarcosine salt and cocoamido sodium propionate
WO2019233375A1 (en) * 2018-06-04 2019-12-12 苏州欧丽特生物医药有限公司 Self-assembled amino acid supramolecular polymer, preparation therefor, and application thereof
WO2019233377A1 (en) * 2018-06-04 2019-12-12 苏州欧丽特生物医药有限公司 Novel self-assembled amino acid supramolecular polymer, preparation method therefor, and application thereof
JP2021527117A (en) * 2018-06-04 2021-10-11 ▲蘇▼州欧▲麗▼特生物医▲薬▼有限公司 Amino acid self-assembled supramolecular polymer and its production and use
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US11566110B2 (en) 2018-06-04 2023-01-31 Suzhou Oulit Biopharm Co., Ltd Self-assembled amino acid supramolecular polymer, preparation therefor, and application thereof
JP7502800B2 (en) 2018-06-04 2024-06-19 ▲蘇▼州欧▲麗▼特生物医▲薬▼有限公司 Amino acid self-assembled supramolecular polymers and their preparation and use
CN113174300A (en) * 2021-04-14 2021-07-27 大连工业大学 Grease-based acyl amino acid salt infant laundry detergent and preparation method thereof

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