WO2018006734A1 - Amino acid-based laundry detergent for adult - Google Patents

Amino acid-based laundry detergent for adult Download PDF

Info

Publication number
WO2018006734A1
WO2018006734A1 PCT/CN2017/090461 CN2017090461W WO2018006734A1 WO 2018006734 A1 WO2018006734 A1 WO 2018006734A1 CN 2017090461 W CN2017090461 W CN 2017090461W WO 2018006734 A1 WO2018006734 A1 WO 2018006734A1
Authority
WO
WIPO (PCT)
Prior art keywords
amino acid
surfactant
adult
laundry detergent
laundry liquid
Prior art date
Application number
PCT/CN2017/090461
Other languages
French (fr)
Chinese (zh)
Inventor
张健
张燕飞
Original Assignee
张健
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 张健 filed Critical 张健
Publication of WO2018006734A1 publication Critical patent/WO2018006734A1/en

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/04Carboxylic acids or salts thereof
    • C11D1/10Amino carboxylic acids; Imino carboxylic acids; Fatty acid condensates thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88Ampholytes; Electroneutral compounds
    • C11D1/94Mixtures with anionic, cationic or non-ionic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/37Mixtures of compounds all of which are anionic
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005Other compounding ingredients characterised by their effect
    • C11D3/001Softening compositions
    • C11D3/0015Softening compositions liquid
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/04Water-soluble compounds
    • C11D3/044Hydroxides or bases
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2003Alcohols; Phenols
    • C11D3/2065Polyhydric alcohols
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/34Organic compounds containing sulfur
    • C11D3/3481Organic compounds containing sulfur containing sulfur in a heterocyclic ring, e.g. sultones or sulfolanes
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50Perfumes
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/72Ethers of polyoxyalkylene glycols
    • C11D1/721End blocked ethers
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/74Carboxylates or sulfonates esters of polyoxyalkylene glycols

Definitions

  • the invention relates to an adult laundry liquid, and more particularly to an amino acid adult laundry liquid which is a safe and environmentally friendly amino acid surfactant, and belongs to the field of consumer goods for daily use.
  • the laundry liquid overcomes some of the shortcomings of the washing powder, it has developed rapidly. As we all know, the washing powder contains a large amount of filler powder without any washing effect, and its mass fraction is more than 40%, which causes great waste in resources and energy, and also causes dust pollution in production, which is not conducive to environmental protection. .
  • the laundry liquid replaces the Yuanming powder with abundant and inexpensive water, and is made up of a biodegradable surfactant as a main component and supplemented with a phosphorus-free additive. Due to the low investment in equipment, simple production process, mild and non-irritating properties, easy to dissolve and easy to use, it is gradually accepted by people.
  • the active ingredient of the existing laundry liquid is mainly a surfactant, which is mainly composed of a chemically synthesized surfactant such as sodium lauryl sulfate.
  • a surfactant such as sodium lauryl sulfate.
  • it is not easily degraded or degraded, causing pollution to the environment.
  • the future development direction of laundry liquid will be based on environmentally friendly green type.
  • strong decontamination harmless to the human body, sterilization, mild and high foaming, it should also be easily degraded and not pollute the environment.
  • amino acids have been increasingly used in various fields.
  • the application of amino acids in daily chemicals is also a subject worthy of study, and amino acid daily chemicals have been accepted and sought after by more and more people.
  • amino acid daily chemicals are undoubtedly one of the highlights, which has injected new vitality into the Japanese chemical industry.
  • Amino acids are a general term for a class of organic compounds containing amino and carboxyl groups. It is the most basic substance that constitutes a biological protein and is related to life activities. It is the basic unit that constitutes a protein molecule in a living body and has a close relationship with the life activities of a living being. It has special physiological functions in antibodies and is one of the indispensable nutrients in the body.
  • the main object of the present invention is to provide an amino acid adult laundry liquid which is safe and environmentally friendly with an amino acid surfactant as the sole cleansing ingredient.
  • the technical solution adopted by the present invention comprises: an amino acid adult laundry liquid comprising an amino acid surfactant; the amino acid surfactant is a main active ingredient; and the weight ratio of the amino acid surfactant is 0.1- 25%;
  • the amino acid adult laundry liquid also contains water, a moisturizer, a thickener and a preservative, and the weight percentages thereof are respectively:
  • the humectant is 5-30%
  • Preservative is 0.1-1%
  • the amino acid adult laundry liquid has a pH in the range of 6-8.
  • the weight ratio of the amino acids is 5-20%.
  • the weight ratio of the amino acids is 10-15%.
  • the amino acid surfactant is mainly alanine type surfactant, and the alanine type surfactant accounts for more than 60% by weight of the total surfactant, wherein the alanine type surfactant accounts for the total.
  • the weight percentage of the surfactant is preferably 70% or more.
  • the alanine type surfactant comprises at least one of sodium N-lauroyl-L-alaninate and sodium cocamidopropionate in a concentration of 98% or more.
  • the present invention has at least the following advantages:
  • the amino acid adult laundry liquid of the invention has the following advantages: 1.
  • the amino acid surfactant is used as the main active ingredient, instead of the traditional laundry liquid surfactant, such as sodium lauryl sulfate; the chemical detergent residue is removed from the human body. Damage and environmental pollution, and no stimulation, no allergies, close-fitting clothing and baby clothes are suitable for use; 2, low foam easy to pass water, less emissions, low energy consumption; 3, efficient stain removal; 4, physical disinfection, safe and reliable; 5, using a mild amino acid surfactant liquid formula, with multiple functions of washing and protecting, not hurting clothes, gorgeous as new, "no classification, cleaning dirt, sterilization and taste, soft clothing”; 6, high environmental protection, Easy to degrade, the laundry liquid uses amino acid surfactant, its biodegradability is above 99.9%, achieving the highest degree of degradation of similar substances, and minimizing the impact on the environment after discharge. The degree is in line with the low carbon environmental protection concept.
  • Figure 1 is the first page of the test report of the amino acid adult laundry detergent of the present invention.
  • Figure 2 is a second page of the test report for the amino acid adult laundry detergent of the present invention.
  • the amino acid adult laundry liquid of the invention comprises an amino acid surfactant; the amino acid surfactant is used as a main active ingredient; the amino acid surfactant is mainly alanine type surfactant, and the alanine type surface
  • the active agent accounts for more than 60% by weight of the total surfactant, wherein the alanine surfactant is more preferably 70% by weight or more of the total surfactant; the alanine surfactant contains at least the concentration. It is one of 98% or more of sodium N-lauroyl-L-alaninate and sodium cocamidopropionate.
  • the amino acid adult laundry detergent also contains water, glycerin, sodium hydroxide, DOE-120 methyl glucoside polyoxyethylene (120) ether dioleate, CAB-35 cocamidopropyl betaine, AEO-9 fat Alcohol polyoxyethylene ether, carson and flavor.
  • the amino acid adult laundry liquid has a pH in the range of 6-8.
  • the weight percentages of the components of the amino acid adult laundry liquid are shown in Table 1 and Table 2. A total of 10 examples are listed.
  • Amino acids are familiar to us. They are one of the many biologically active molecules that build biological organisms, or the basic materials for building human cells and repairing human tissues.
  • Amino acids are the basic unit of protein, which is one of the most important active molecules in the body, including enzymes that catalyze metabolism.
  • the amino acid surfactant in the amino acid adult laundry liquid produced by the invention contains at least one of N-lauroyl-L-alanine sodium salt and cocamido alanine sodium salt at a concentration of 98% or more.
  • traditional surfactants such as sodium lauryl sulfate Active agent.
  • Amino acid adult laundry detergent produced by using alanine surfactant in a weight ratio of less than 60% of total surfactant, alanine having a foam richness ratio of more than 60% by weight of total surfactant The amino acid produced by the surfactant is low in adult laundry liquid, relatively stable in stability, and poor in detergency.
  • amino acid adult laundry liquid of the present invention in addition to the amino acid component, a basic raw material for preparing a laundry liquid is also included.
  • Tables 1 and 2 refers to parts by weight, and the total weight fraction of the amino acid adult laundry liquid in Examples 1 to 10 is 100.
  • the core of the invention is to use an amino acid surfactant as a main surface active ingredient to be added to an amino acid adult laundry liquid and verify its non-toxic, non-corrosive, non-polluting, residue-free and high-efficiency fast-cleaning ability in an amino acid adult laundry liquid. See the inspection report shown in Figure 1-2 for details.
  • the present invention has at least the following advantages:
  • the amino acid adult laundry liquid of the invention has the following advantages: 1. Using an amino acid table
  • the surfactant is the main active ingredient, which replaces the traditional laundry liquid surfactant, such as sodium lauryl sulfate; it eliminates the harm of chemical detergent residue to the human body and the environment, and is non-irritating, non-allergic, close-fitting clothing and baby.
  • Clothing is suitable for use; 2, low foam easy to pass water, less emissions, low energy consumption; 3, efficient stain removal; 4, physical disinfection, safe and reliable; 5, using a mild amino acid surfactant liquid formula, with a wash and a protective
  • the multiple functions not hurting clothes, bright and new, "no need to sort, clean dirt, remove bacteria, taste, soft clothes"; 6, high environmental protection, easy to degrade, the use of amino acid surfactants in laundry detergent, its biodegradability is 99.9 Above 100%, the highest degree of degradation of similar substances is achieved, and the environmental impact after discharge is minimized, in line with the concept of low carbon environmental protection.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)
  • Cosmetics (AREA)

Abstract

A detergent for adult laundry, comprising the following components provided in the respective weight percentages: 0.1-25% of an amino acid-based surfactant; 70-85% of water; 5-30% of a humectant; 0.1-6% of a thickening agent; and 0.1-1% of a preservative. The detergent has a pH of 6-8.

Description

一种氨基酸成人洗衣液An amino acid adult laundry liquid 技术领域Technical field
本发明涉及一种成人洗衣液,更具体地说,涉及一种以氨基酸表面活性剂为唯一清洁成份、安全且环保的氨基酸成人洗衣液,属于日用消费品领域。The invention relates to an adult laundry liquid, and more particularly to an amino acid adult laundry liquid which is a safe and environmentally friendly amino acid surfactant, and belongs to the field of consumer goods for daily use.
背景技术Background technique
随着世界经济的一体化和贸易全球化的发展,文化背景、技术水平和环保法规逐渐成为洗涤用品全球化发展的三大驱动力,全球的洗涤用品将趋向多样化,但节能、节水、高效、温和、使用方便以及符合安全与环保要求的产品将是当前及未来洗涤产品发展的主流方向。由于洗衣液克服了洗衣粉的一些缺点,发展很快。众所周知,洗衣粉中含有大量无任何洗涤作用的填充剂元明粉,其质量份数大于40%,在资源和能源方面造成了极大的浪费,在生产中还会造成粉尘污染,不利于环保。而洗衣液以资源丰富且价廉的水代替了元明粉,采用可生物降解的表面活性剂作为主要成分并辅以无磷助剂复配而成。由于设备投资少,生产工艺简便,性能温和无刺激,易于溶解和使用方便等特点,逐渐被人们所接受。With the integration of the world economy and the development of trade globalization, cultural background, technical level and environmental protection regulations have gradually become the three driving forces for the global development of detergents. The global detergent products will tend to be diversified, but energy-saving, water-saving, Products that are efficient, gentle, easy to use, and meet safety and environmental requirements will be the mainstream of current and future laundry product development. Since the laundry liquid overcomes some of the shortcomings of the washing powder, it has developed rapidly. As we all know, the washing powder contains a large amount of filler powder without any washing effect, and its mass fraction is more than 40%, which causes great waste in resources and energy, and also causes dust pollution in production, which is not conducive to environmental protection. . The laundry liquid replaces the Yuanming powder with abundant and inexpensive water, and is made up of a biodegradable surfactant as a main component and supplemented with a phosphorus-free additive. Due to the low investment in equipment, simple production process, mild and non-irritating properties, easy to dissolve and easy to use, it is gradually accepted by people.
但作为一种新兴的有发展前途的液体产品也有它的不足,现有洗衣液的有效成分主要是表面活性剂,其主要以化学合成表面活性剂,如月桂醇硫酸钠为原料。但它不易降解或无法降解,对环境造成污染。随着人们环保意识的逐步增强,洗衣液未来的发展方向将是以环保绿色型为主流。除了有强去污力、对人体无害、杀菌消毒、温和高泡的功能外,还应容易降解、不污染环境。However, as an emerging promising liquid product, it also has its shortcomings. The active ingredient of the existing laundry liquid is mainly a surfactant, which is mainly composed of a chemically synthesized surfactant such as sodium lauryl sulfate. However, it is not easily degraded or degraded, causing pollution to the environment. With the gradual enhancement of people's awareness of environmental protection, the future development direction of laundry liquid will be based on environmentally friendly green type. In addition to strong decontamination, harmless to the human body, sterilization, mild and high foaming, it should also be easily degraded and not pollute the environment.
近年来,随着对氨基酸研究的深入,氨基酸也被越来越多的应用于各个领域。其中,氨基酸在日用化学品中的应用也是一个很值得研究的课题,氨基酸日化品也被越来越多的人所接受和追捧。日化品工业界中,氨基酸日化品无疑更是重头戏之一,它为日化工业注入了新的活力。In recent years, with the deepening of amino acid research, amino acids have been increasingly used in various fields. Among them, the application of amino acids in daily chemicals is also a subject worthy of study, and amino acid daily chemicals have been accepted and sought after by more and more people. In the daily chemical industry, amino acid daily chemicals are undoubtedly one of the highlights, which has injected new vitality into the Japanese chemical industry.
氨基酸是含有氨基和羧基的一类有机化合物的通称。它是构成生物体蛋白质并同生命活动有关的最基本的物质,是在生物体内构成蛋白质分子的基本单位,与生物的生命活动有着密切的关系。它在抗体内具有特殊的生理功能,是生物体内不可缺少的营养成分之一。 Amino acids are a general term for a class of organic compounds containing amino and carboxyl groups. It is the most basic substance that constitutes a biological protein and is related to life activities. It is the basic unit that constitutes a protein molecule in a living body and has a close relationship with the life activities of a living being. It has special physiological functions in antibodies and is one of the indispensable nutrients in the body.
为此,我们研发了一种以氨基酸表面活性剂为唯一清洁成份、安全且环保的氨基酸成人洗衣液。To this end, we have developed an amino acid adult laundry detergent with amino acid surfactant as the only cleansing ingredient, safe and environmentally friendly.
发明内容Summary of the invention
本发明的主要目的在于提供一种以氨基酸表面活性剂为唯一清洁成份、安全且环保的氨基酸成人洗衣液。The main object of the present invention is to provide an amino acid adult laundry liquid which is safe and environmentally friendly with an amino acid surfactant as the sole cleansing ingredient.
为实现前述发明目的,本发明采用的技术方案包括:一种氨基酸成人洗衣液,包含氨基酸表面活性剂;所述氨基酸表面活性剂为主要活性成份;所述氨基酸表面活性剂的重量比为0.1-25%;In order to achieve the foregoing object, the technical solution adopted by the present invention comprises: an amino acid adult laundry liquid comprising an amino acid surfactant; the amino acid surfactant is a main active ingredient; and the weight ratio of the amino acid surfactant is 0.1- 25%;
所述氨基酸成人洗衣液还含有水、保湿剂、增稠剂和防腐剂,其重量百分比分别为:The amino acid adult laundry liquid also contains water, a moisturizer, a thickener and a preservative, and the weight percentages thereof are respectively:
水为70-85%;Water is 70-85%;
保湿剂为5-30%;The humectant is 5-30%;
增稠剂0.1-6%;Thickener 0.1-6%;
防腐剂为0.1-1%;Preservative is 0.1-1%;
所述氨基酸成人洗衣液的pH范围在6-8之间。The amino acid adult laundry liquid has a pH in the range of 6-8.
优选的,所述氨基酸的重量比为5-20%。Preferably, the weight ratio of the amino acids is 5-20%.
优选的,所述氨基酸的重量比为10-15%。Preferably, the weight ratio of the amino acids is 10-15%.
优选的,所述氨基酸表面活性剂以丙氨酸型表面活性剂为主,丙氨酸型表面活性剂占总表面活性剂的重量百分比为60%以上,其中丙氨酸型表面活性剂占总表面活性剂的重量百分比为70%以上更好。Preferably, the amino acid surfactant is mainly alanine type surfactant, and the alanine type surfactant accounts for more than 60% by weight of the total surfactant, wherein the alanine type surfactant accounts for the total. The weight percentage of the surfactant is preferably 70% or more.
优选的,所述丙氨酸型表面活性剂至少包含浓度为98%以上的N-月桂酰-L-丙氨酸钠和椰油酰氨基丙酸钠中的一种。Preferably, the alanine type surfactant comprises at least one of sodium N-lauroyl-L-alaninate and sodium cocamidopropionate in a concentration of 98% or more.
与现有技术相比,本发明至少具有如下优点:Compared with the prior art, the present invention has at least the following advantages:
本发明所述的氨基酸成人洗衣液具有以下优点:1、采用氨基酸表面活性剂为主要活性成份,代替了传统的洗衣液表面活性剂,如月桂醇硫酸钠;免去化学洗涤剂残留对人体的伤害和环境的污染,且无刺激、无过敏、贴身衣物和宝宝衣物均适合使用;2、低泡易过水、排放少、低能耗;3、高效去渍;4、物理消毒,安全可靠;5、采用温和的氨基酸表面活性剂液体配方,具有洗护合一的多重功能,不伤衣服,艳丽如新,“无需分类,清洗污垢,除菌去味,柔顺衣物”;6、高环保、易降解,洗衣液使用氨基酸表面活性剂,其生物降解度在99.9%以上,达到同类物质降解度最高值,将排放后对环境的影响降到最低 程度,符合低碳环保理念。The amino acid adult laundry liquid of the invention has the following advantages: 1. The amino acid surfactant is used as the main active ingredient, instead of the traditional laundry liquid surfactant, such as sodium lauryl sulfate; the chemical detergent residue is removed from the human body. Injury and environmental pollution, and no stimulation, no allergies, close-fitting clothing and baby clothes are suitable for use; 2, low foam easy to pass water, less emissions, low energy consumption; 3, efficient stain removal; 4, physical disinfection, safe and reliable; 5, using a mild amino acid surfactant liquid formula, with multiple functions of washing and protecting, not hurting clothes, gorgeous as new, "no classification, cleaning dirt, sterilization and taste, soft clothing"; 6, high environmental protection, Easy to degrade, the laundry liquid uses amino acid surfactant, its biodegradability is above 99.9%, achieving the highest degree of degradation of similar substances, and minimizing the impact on the environment after discharge. The degree is in line with the low carbon environmental protection concept.
附图说明DRAWINGS
图1是本发明所述的氨基酸成人洗衣液的检验报告的第一页;Figure 1 is the first page of the test report of the amino acid adult laundry detergent of the present invention;
图2是本发明所述的氨基酸成人洗衣液的检验报告的第二页。Figure 2 is a second page of the test report for the amino acid adult laundry detergent of the present invention.
具体实施方式detailed description
下面通过具体实施例对本发明作进一步的详细说明。The invention will now be further described in detail by way of specific examples.
本发明所述的氨基酸成人洗衣液,包含氨基酸表面活性剂;所述氨基酸表面活性剂作为主要活性成份;所述的氨基酸表面活性剂以丙氨酸型表面活性剂为主,丙氨酸型表面活性剂占总表面活性剂的重量百分比为60%以上,其中丙氨酸型表面活性剂占总表面活性剂的重量百分比为70%以上更好;所述丙氨酸型表面活性剂至少包含浓度为98%以上的N-月桂酰-L-丙氨酸钠和椰油酰氨基丙酸钠中的一种。The amino acid adult laundry liquid of the invention comprises an amino acid surfactant; the amino acid surfactant is used as a main active ingredient; the amino acid surfactant is mainly alanine type surfactant, and the alanine type surface The active agent accounts for more than 60% by weight of the total surfactant, wherein the alanine surfactant is more preferably 70% by weight or more of the total surfactant; the alanine surfactant contains at least the concentration. It is one of 98% or more of sodium N-lauroyl-L-alaninate and sodium cocamidopropionate.
所述氨基酸成人洗衣液还含有水、甘油、氢氧化钠、DOE-120甲基葡萄糖苷聚氧乙烯(120)醚二油酸酯、CAB-35椰油酰胺丙基甜菜碱、AEO-9脂肪醇聚氧乙烯醚、卡松和香精。The amino acid adult laundry detergent also contains water, glycerin, sodium hydroxide, DOE-120 methyl glucoside polyoxyethylene (120) ether dioleate, CAB-35 cocamidopropyl betaine, AEO-9 fat Alcohol polyoxyethylene ether, carson and flavor.
所述氨基酸成人洗衣液的ph值范围在6-8之间。The amino acid adult laundry liquid has a pH in the range of 6-8.
所述氨基酸成人洗衣液的组分的重量百分比见表一、表二,共列举了10个实施例。The weight percentages of the components of the amino acid adult laundry liquid are shown in Table 1 and Table 2. A total of 10 examples are listed.
鉴于现有技术中的不足,本案发明人经长期研究和大量实践,得以提出本发明的技术方案。如下将对该技术方案、其实施过程及原理等作进一步的解释说明。In view of the deficiencies in the prior art, the inventors of the present invention have been able to propose the technical solution of the present invention through long-term research and extensive practice. The technical solution, its implementation process and principle, etc. will be further explained as follows.
氨基酸我们都很熟悉,它是构建生物机体的众多生物活性分子之一,还是构建人体细胞、修复人体组织的基础材料。Amino acids are familiar to us. They are one of the many biologically active molecules that build biological organisms, or the basic materials for building human cells and repairing human tissues.
氨基酸是构成蛋白质的基本单位,蛋白质它是生物体内最重要的活性分子之一,包括催化代谢的酶。Amino acids are the basic unit of protein, which is one of the most important active molecules in the body, including enzymes that catalyze metabolism.
氨基酸的作用有很多,它能够将我们人体内有毒物质排出体外,有效的减轻辐射、污染对人体所造成的伤害。排除机体在剧烈的运动以后体内的代谢产物,从而具有促进精神、机体、肌肉等多方面的快速恢复,因此对提高机体机能有很好的帮助。There are many functions of amino acids, which can excrete toxic substances in our human body and effectively reduce the damage caused by radiation and pollution. Excluding the body's metabolites after intense exercise, thus promoting rapid recovery of the spirit, body, muscles, etc., so it is very helpful to improve the body function.
本发明所生产的氨基酸成人洗衣液中的氨基酸表面活性剂至少含有浓度为98%以上的N-月桂酰-L-丙氨酸钠盐和椰油酰胺基丙氨酸钠盐中的一种,代替了传统的表面活性剂,如月桂醇硫酸钠为主的表面 活性剂。经过试验:采用重量比为总表面活性剂的60%以下的丙氨酸型表面活性剂所生产的氨基酸成人洗衣液,泡沫丰富度比重量比为总表面活性剂的60%以上的丙氨酸型表面活性剂所生产的氨基酸成人洗衣液低,稳定性也相对较差,去污能力较差。The amino acid surfactant in the amino acid adult laundry liquid produced by the invention contains at least one of N-lauroyl-L-alanine sodium salt and cocamido alanine sodium salt at a concentration of 98% or more. Instead of traditional surfactants, such as sodium lauryl sulfate Active agent. Tested: Amino acid adult laundry detergent produced by using alanine surfactant in a weight ratio of less than 60% of total surfactant, alanine having a foam richness ratio of more than 60% by weight of total surfactant The amino acid produced by the surfactant is low in adult laundry liquid, relatively stable in stability, and poor in detergency.
本发明所述的氨基酸成人洗衣液中,除所述氨基酸成分外,还包括配制洗衣液的基本原料。In the amino acid adult laundry liquid of the present invention, in addition to the amino acid component, a basic raw material for preparing a laundry liquid is also included.
表一、表二中所涉及的数据是指重量份数,实施例1至实施例10中氨基酸成人洗衣液的总重量份数均为100。The data referred to in Tables 1 and 2 refers to parts by weight, and the total weight fraction of the amino acid adult laundry liquid in Examples 1 to 10 is 100.
表一Table I
Figure PCTCN2017090461-appb-000001
Figure PCTCN2017090461-appb-000001
Figure PCTCN2017090461-appb-000002
Figure PCTCN2017090461-appb-000002
表二Table II
Figure PCTCN2017090461-appb-000003
Figure PCTCN2017090461-appb-000003
本发明的核心在于采用氨基酸表面活性剂作为主要表面活性成分添加到氨基酸成人洗衣液中并验证其在氨基酸成人洗衣液中的无毒、无腐蚀、无污染、无残留和高效快速清除污能力,详见附图1-2所示的检验报告。The core of the invention is to use an amino acid surfactant as a main surface active ingredient to be added to an amino acid adult laundry liquid and verify its non-toxic, non-corrosive, non-polluting, residue-free and high-efficiency fast-cleaning ability in an amino acid adult laundry liquid. See the inspection report shown in Figure 1-2 for details.
与现有技术相比,本发明至少具有如下优点:Compared with the prior art, the present invention has at least the following advantages:
本发明所述的氨基酸成人洗衣液具有以下优点:1、采用氨基酸表 面活性剂为主要活性成份,代替了传统的洗衣液表面活性剂,如月桂醇硫酸钠;免去化学洗涤剂残留对人体的伤害和环境的污染,且无刺激、无过敏、贴身衣物和宝宝衣物均适合使用;2、低泡易过水、排放少、低能耗;3、高效去渍;4、物理消毒,安全可靠;5、采用温和的氨基酸表面活性剂液体配方,具有洗护合一的多重功能,不伤衣服,艳丽如新,“无需分类,清洗污垢,除菌去味,柔顺衣物”;6、高环保、易降解,洗衣液使用氨基酸表面活性剂,其生物降解度在99.9%以上,达到同类物质降解度最高值,将排放后对环境的影响降到最低程度,符合低碳环保理念。The amino acid adult laundry liquid of the invention has the following advantages: 1. Using an amino acid table The surfactant is the main active ingredient, which replaces the traditional laundry liquid surfactant, such as sodium lauryl sulfate; it eliminates the harm of chemical detergent residue to the human body and the environment, and is non-irritating, non-allergic, close-fitting clothing and baby. Clothing is suitable for use; 2, low foam easy to pass water, less emissions, low energy consumption; 3, efficient stain removal; 4, physical disinfection, safe and reliable; 5, using a mild amino acid surfactant liquid formula, with a wash and a protective The multiple functions, not hurting clothes, bright and new, "no need to sort, clean dirt, remove bacteria, taste, soft clothes"; 6, high environmental protection, easy to degrade, the use of amino acid surfactants in laundry detergent, its biodegradability is 99.9 Above 100%, the highest degree of degradation of similar substances is achieved, and the environmental impact after discharge is minimized, in line with the concept of low carbon environmental protection.
上述实施例只为说明本发明的技术构思及特点,其目的在于让熟悉此项技术的人士能够了解本发明的内容并加以实施,并不能以此限制本发明的保护范围,凡根据本发明精神实质所作的等效变化或修饰,都应涵盖在本发明的保护范围内。 The above embodiments are only intended to illustrate the technical concept and the features of the present invention, and the purpose of the present invention is to enable those skilled in the art to understand the contents of the present invention and not to limit the scope of the present invention. Equivalent changes or modifications made in substantial form are intended to be included within the scope of the invention.

Claims (5)

  1. 一种氨基酸成人洗衣液,其特征在于,包含氨基酸表面活性剂;所述氨基酸表面活性剂为主要活性成份;所述氨基酸表面活性剂的重量比为0.1-25%;An amino acid adult laundry liquid, characterized in that it comprises an amino acid surfactant; the amino acid surfactant is a main active ingredient; and the weight ratio of the amino acid surfactant is 0.1-25%;
    所述氨基酸成人洗衣液还含有水、保湿剂、增稠剂和防腐剂,其重量百分比分别为:The amino acid adult laundry liquid also contains water, a moisturizer, a thickener and a preservative, and the weight percentages thereof are respectively:
    水为70-85%;Water is 70-85%;
    保湿剂为5-30%;The humectant is 5-30%;
    增稠剂0.1-6%;Thickener 0.1-6%;
    防腐剂为0.1-1%;Preservative is 0.1-1%;
    所述氨基酸成人洗衣液的pH范围在6-8之间。The amino acid adult laundry liquid has a pH in the range of 6-8.
  2. 根据权利要求1所述的氨基酸成人洗衣液,其特征在于,所述氨基酸表面活性剂的重量比为5-20%。The amino acid adult laundry detergent according to claim 1, wherein the amino acid surfactant has a weight ratio of 5 to 20%.
  3. 根据权利要求2所述的氨基酸成人洗衣液,其特征在于,所述氨基酸表面活性剂的重量比为10-15%。The amino acid adult laundry detergent according to claim 2, wherein the amino acid surfactant has a weight ratio of 10-15%.
  4. 根据权利要求1或2或3所述的氨基酸成人洗衣液,其特征在于,所述氨基酸表面活性剂以丙氨酸型表面活性剂为主,丙氨酸型表面活性剂占总表面活性剂的重量百分比为60%以上,其中丙氨酸型表面活性剂占总表面活性剂的重量百分比为70%以上更好。The amino acid adult laundry detergent according to claim 1 or 2 or 3, wherein the amino acid surfactant is mainly an alanine type surfactant, and the alanine type surfactant is a total surfactant. The weight percentage is 60% or more, and more preferably, the alanine type surfactant accounts for 70% by weight or more of the total surfactant.
  5. 根据权利要求4所述的氨基酸成人洗衣液,其特征在于,所述丙氨酸型表面活性剂至少包含浓度为98%以上的N-月桂酰-L-丙氨酸钠和椰油酰氨基丙酸钠中的一种。 The amino acid adult laundry detergent according to claim 4, wherein the alanine type surfactant comprises at least a concentration of 98% or more of sodium N-lauroyl-L-alaninate and cocoamidopropyl One of sodium.
PCT/CN2017/090461 2016-07-08 2017-06-28 Amino acid-based laundry detergent for adult WO2018006734A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201610536560.8A CN106118914A (en) 2016-07-08 2016-07-08 A kind of aminoacid adult's liquid detergent
CN201610536560.8 2016-07-08

Publications (1)

Publication Number Publication Date
WO2018006734A1 true WO2018006734A1 (en) 2018-01-11

Family

ID=57282463

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/CN2017/090461 WO2018006734A1 (en) 2016-07-08 2017-06-28 Amino acid-based laundry detergent for adult

Country Status (2)

Country Link
CN (1) CN106118914A (en)
WO (1) WO2018006734A1 (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3805249A4 (en) * 2018-06-04 2022-04-27 Suzhou Oulit Biopharm Co., Ltd. Novel self-assembled amino acid supramolecular polymer, preparation method therefor, and application thereof
EP3805200A4 (en) * 2018-06-04 2022-04-27 Suzhou Oulit Biopharm Co., Ltd. Self-assembled amino acid supramolecular polymer, preparation therefor, and application thereof
RU2790660C2 (en) * 2018-06-04 2023-02-28 Сучжоу Оулит Биофарм Ко., Лтд Self-assembling amino acid supramolecular polymer, its production and use
CN116396809A (en) * 2023-03-30 2023-07-07 橙的(福建)卫生用品有限责任公司 Preparation method of kitchen wet tissue

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106118914A (en) * 2016-07-08 2016-11-16 张健 A kind of aminoacid adult's liquid detergent
CN106590981A (en) * 2016-11-17 2017-04-26 苏州三君日化科技有限公司 Laundry detergent containing sodium lauroyl sarcosine salt and cocoamido sodium propionate
CN113174300A (en) * 2021-04-14 2021-07-27 大连工业大学 Grease-based acyl amino acid salt infant laundry detergent and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102892823A (en) * 2010-04-14 2013-01-23 路博润高级材料公司 Thickened amino acid surfactant compositions and methods therefor
CN103301051A (en) * 2012-03-07 2013-09-18 南京华狮化工有限公司 Transparent beauty treatment soap composition
CN104302754A (en) * 2013-05-16 2015-01-21 Jt株式会社 Hydrogel soap composition, hydrogel soap, and preparation method therefor
CN106118914A (en) * 2016-07-08 2016-11-16 张健 A kind of aminoacid adult's liquid detergent

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103126939B (en) * 2011-11-23 2016-02-17 苏州维美生物科技有限公司 A kind of containing N-lauroyl-ALANINE sodium salt or the potassium salt bath gel as surfactant
CN103126925A (en) * 2011-11-23 2013-06-05 苏州维美生物科技有限公司 Hair shampoo with N-lauroyl-L-alanine sodium salt or potassium salt as surfactant
WO2013178684A2 (en) * 2012-05-30 2013-12-05 Clariant International Ltd. Composition containing amino acid surfactants, betaines and n-methyl-n-acylglucamines and having improved foam quality and higher viscosity
CN103961275A (en) * 2013-02-03 2014-08-06 广州无患子生物科技有限公司 Daily necessities containing all-natural source surfactant and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102892823A (en) * 2010-04-14 2013-01-23 路博润高级材料公司 Thickened amino acid surfactant compositions and methods therefor
CN103301051A (en) * 2012-03-07 2013-09-18 南京华狮化工有限公司 Transparent beauty treatment soap composition
CN104302754A (en) * 2013-05-16 2015-01-21 Jt株式会社 Hydrogel soap composition, hydrogel soap, and preparation method therefor
CN106118914A (en) * 2016-07-08 2016-11-16 张健 A kind of aminoacid adult's liquid detergent

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3805249A4 (en) * 2018-06-04 2022-04-27 Suzhou Oulit Biopharm Co., Ltd. Novel self-assembled amino acid supramolecular polymer, preparation method therefor, and application thereof
EP3805200A4 (en) * 2018-06-04 2022-04-27 Suzhou Oulit Biopharm Co., Ltd. Self-assembled amino acid supramolecular polymer, preparation therefor, and application thereof
US11540993B2 (en) 2018-06-04 2023-01-03 Suzhou Oulit Biopharm Co., Ltd Self-assembled amino acid supramolecular polymer, preparation method therefor, and application thereof
US11566110B2 (en) 2018-06-04 2023-01-31 Suzhou Oulit Biopharm Co., Ltd Self-assembled amino acid supramolecular polymer, preparation therefor, and application thereof
RU2790660C2 (en) * 2018-06-04 2023-02-28 Сучжоу Оулит Биофарм Ко., Лтд Self-assembling amino acid supramolecular polymer, its production and use
CN116396809A (en) * 2023-03-30 2023-07-07 橙的(福建)卫生用品有限责任公司 Preparation method of kitchen wet tissue

Also Published As

Publication number Publication date
CN106118914A (en) 2016-11-16

Similar Documents

Publication Publication Date Title
WO2018006734A1 (en) Amino acid-based laundry detergent for adult
WO2018006733A1 (en) Amino acid-based baby shampoo and shower foam
WO2018006732A1 (en) Amino acid-based detergent for utensil and kitchen
CN101812383B (en) Disinfecting detergent and preparation method thereof
CN103961275A (en) Daily necessities containing all-natural source surfactant and preparation method thereof
CN104059790B (en) A kind of handguard concentrates liquid detergent
CN101851564B (en) Laundry detergent used for washing underwear
CN105623903A (en) High-dirt-removing-power antibacterial protective laundry detergent and preparation method thereof
CN103468429B (en) A kind of for the natural liquid laundry detergent in ultraviolet washing machine and preparation method
CN104013542A (en) Washing product and composition thereof
WO2018006735A1 (en) Amino acid-based laundry detergent for baby
CN105969557A (en) Salt composite and method for tableware cleaning
CN106221966A (en) A kind of nanometer Superconcentrated washing sheet and preparation method thereof
CN103194328B (en) Cosolvent-free high-power concentrated detergent and preparation method thereof
CN105708764A (en) Liquid soap containing aloe extract
CN104164315A (en) Multifunctional detergent
WO2018006731A1 (en) Amino acid-based silicone oil-free shampoo
CN104789373A (en) An antibacterial environmental-friendly type tableware cleaning agent
CN106867724A (en) A kind of efficient, preparation of the new type closet cleaning agent of easily biological-degradable
CN106511109A (en) Antibacterial hand sanitizer and preparation method thereof
WO2018006736A1 (en) Amino acid-based spray wash detergent
CN102994242A (en) Hyperconcentration detergent powder
CN105296197A (en) Environment-friendly biological liquid detergent
WO2018006730A1 (en) Amino acid-based detergent for fruit and vegetable
CN110591834A (en) Laundry detergent containing okra extract and raspberry enzyme and preparation method of laundry detergent

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 17823546

Country of ref document: EP

Kind code of ref document: A1

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 17823546

Country of ref document: EP

Kind code of ref document: A1