CN103468429B - A kind of for the natural liquid laundry detergent in ultraviolet washing machine and preparation method - Google Patents
A kind of for the natural liquid laundry detergent in ultraviolet washing machine and preparation method Download PDFInfo
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- CN103468429B CN103468429B CN201310465749.9A CN201310465749A CN103468429B CN 103468429 B CN103468429 B CN 103468429B CN 201310465749 A CN201310465749 A CN 201310465749A CN 103468429 B CN103468429 B CN 103468429B
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- titanium oxide
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- 239000007788 liquid Substances 0.000 title claims abstract description 70
- 239000003599 detergent Substances 0.000 title claims abstract description 67
- 238000005406 washing Methods 0.000 title claims abstract description 34
- 238000002360 preparation method Methods 0.000 title claims description 8
- 239000000843 powder Substances 0.000 claims abstract description 25
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 25
- 239000008367 deionised water Substances 0.000 claims abstract description 23
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 23
- 239000000463 material Substances 0.000 claims abstract description 20
- 238000003756 stirring Methods 0.000 claims abstract description 18
- 239000000126 substance Substances 0.000 claims abstract description 17
- 230000008719 thickening Effects 0.000 claims abstract description 16
- 239000000203 mixture Substances 0.000 claims abstract description 13
- 239000002594 sorbent Substances 0.000 claims abstract description 13
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000000839 emulsion Substances 0.000 claims description 18
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 15
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 15
- 230000015572 biosynthetic process Effects 0.000 claims description 10
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 8
- 238000002156 mixing Methods 0.000 claims description 8
- 108010010803 Gelatin Proteins 0.000 claims description 5
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 5
- 239000008273 gelatin Substances 0.000 claims description 5
- 229920000159 gelatin Polymers 0.000 claims description 5
- 235000019322 gelatine Nutrition 0.000 claims description 5
- 235000011852 gelatine desserts Nutrition 0.000 claims description 5
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 claims description 5
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 claims description 4
- 229920002101 Chitin Polymers 0.000 claims description 4
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 4
- 235000010413 sodium alginate Nutrition 0.000 claims description 4
- 239000000661 sodium alginate Substances 0.000 claims description 4
- 229940005550 sodium alginate Drugs 0.000 claims description 4
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 4
- 240000003291 Armoracia rusticana Species 0.000 claims description 3
- 235000011330 Armoracia rusticana Nutrition 0.000 claims description 3
- 229920002472 Starch Polymers 0.000 claims description 3
- 239000000470 constituent Substances 0.000 claims description 3
- 239000013078 crystal Substances 0.000 claims description 3
- 239000002808 molecular sieve Substances 0.000 claims description 3
- 235000019353 potassium silicate Nutrition 0.000 claims description 3
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims description 3
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 3
- 235000019698 starch Nutrition 0.000 claims description 3
- 239000008107 starch Substances 0.000 claims description 3
- ZEMPKEQAKRGZGQ-AAKVHIHISA-N 2,3-bis[[(z)-12-hydroxyoctadec-9-enoyl]oxy]propyl (z)-12-hydroxyoctadec-9-enoate Chemical compound CCCCCCC(O)C\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CC(O)CCCCCC)COC(=O)CCCCCCC\C=C/CC(O)CCCCCC ZEMPKEQAKRGZGQ-AAKVHIHISA-N 0.000 claims description 2
- 244000215068 Acacia senegal Species 0.000 claims description 2
- 229920001817 Agar Polymers 0.000 claims description 2
- 244000056139 Brassica cretica Species 0.000 claims description 2
- 235000003351 Brassica cretica Nutrition 0.000 claims description 2
- 235000003343 Brassica rupestris Nutrition 0.000 claims description 2
- 229920001353 Dextrin Polymers 0.000 claims description 2
- 239000004375 Dextrin Substances 0.000 claims description 2
- 229920000084 Gum arabic Polymers 0.000 claims description 2
- 229920001615 Tragacanth Polymers 0.000 claims description 2
- 235000010489 acacia gum Nutrition 0.000 claims description 2
- 239000000205 acacia gum Substances 0.000 claims description 2
- 239000008272 agar Substances 0.000 claims description 2
- 235000010419 agar Nutrition 0.000 claims description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 2
- 239000000305 astragalus gummifer gum Substances 0.000 claims description 2
- QKSKPIVNLNLAAV-UHFFFAOYSA-N bis(2-chloroethyl) sulfide Chemical compound ClCCSCCCl QKSKPIVNLNLAAV-UHFFFAOYSA-N 0.000 claims description 2
- 235000010418 carrageenan Nutrition 0.000 claims description 2
- 229920001525 carrageenan Polymers 0.000 claims description 2
- 238000004140 cleaning Methods 0.000 claims description 2
- 238000005202 decontamination Methods 0.000 claims description 2
- 230000003588 decontaminative effect Effects 0.000 claims description 2
- 235000019425 dextrin Nutrition 0.000 claims description 2
- 235000019197 fats Nutrition 0.000 claims description 2
- 150000004676 glycans Chemical class 0.000 claims description 2
- 235000010460 mustard Nutrition 0.000 claims description 2
- 239000001814 pectin Substances 0.000 claims description 2
- 235000010987 pectin Nutrition 0.000 claims description 2
- 229920001277 pectin Polymers 0.000 claims description 2
- 229920001282 polysaccharide Polymers 0.000 claims description 2
- 239000005017 polysaccharide Substances 0.000 claims description 2
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 2
- 235000017557 sodium bicarbonate Nutrition 0.000 claims description 2
- 235000017550 sodium carbonate Nutrition 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 21
- 239000002689 soil Substances 0.000 abstract description 18
- 238000004659 sterilization and disinfection Methods 0.000 abstract description 6
- 230000006378 damage Effects 0.000 abstract description 5
- 230000007613 environmental effect Effects 0.000 abstract description 3
- 238000012356 Product development Methods 0.000 abstract description 2
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- 230000002860 competitive effect Effects 0.000 abstract description 2
- 239000000356 contaminant Substances 0.000 abstract description 2
- 238000006731 degradation reaction Methods 0.000 abstract description 2
- 230000001954 sterilising effect Effects 0.000 abstract description 2
- 239000004744 fabric Substances 0.000 description 7
- 229920000742 Cotton Polymers 0.000 description 6
- -1 alkyl glycoside Chemical class 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000003912 environmental pollution Methods 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 2
- 239000010865 sewage Substances 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 1
- 241000195493 Cryptophyta Species 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 241000276489 Merlangius merlangus Species 0.000 description 1
- 240000004808 Saccharomyces cerevisiae Species 0.000 description 1
- 241000580955 Sapindus mukorossi Species 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- OUUQCZGPVNCOIJ-UHFFFAOYSA-M Superoxide Chemical compound [O-][O] OUUQCZGPVNCOIJ-UHFFFAOYSA-M 0.000 description 1
- 241000700605 Viruses Species 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000000274 adsorptive effect Effects 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000002305 electric material Substances 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 229930182470 glycoside Natural products 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 239000000976 ink Substances 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 239000002957 persistent organic pollutant Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000516 sunscreening agent Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
Abstract
The present invention relates to a kind of is the liquid laundry detergent of main component containing P25 nano titanium dioxide powder.Liquid laundry detergent of the present invention is with P25 nano titanium dioxide powder for main component, and auxiliary material is antiseptic-germicide, sorbent material, water-softening chemicals, thickening material and balance deionized water, by all compositions by certain proportioning continuously stirring at a suitable temperature, form uniform natural liquid laundry detergent.The invention has the advantages that liquid laundry detergent forms primarily of natural component, be applicable to ultraviolet washing machine, there is better laundry effect, environment friendly and pollution-free, do not hinder hand, the skin of human body is safe from harm, soil removability is strong, sterilization effect is obvious, and energy degradation of contaminant, is conducive to the competitive power of product development and realizes environmental friendliness.
Description
Technical field
The present invention relates to the liquid laundry detergent of daily living article, particularly a kind of containing natural component, the liquid laundry detergent not adding any chemical additive, can use in specific ultraviolet washing machine, under ultraviolet irradiation, liquid laundry detergent can play superpower soil removability, belongs to clothing washing agent product scope.
Background technology
There is rich and varied laundry product in the market, such as washing powder, washing liquid, washing soap, washing ball etc., but manyly all contain chemical reagent, not only to certain injury that the skin of the mankind produces, also can be entered in body by other approach, have certain harm to health, although and washing ball is not synthesized into by chemical substance, but the discharge of the sewage after washing ball washing can cause environmental pollution, so this area still needs more natural laundry product.The present inventor, by concentrated research, finds that P25 nano titanium oxide is under ultraviolet irradiation, has superpower soil removability, superpower adsorptive power and the ability of sterilization and disinfection.Therefore; using P25 nano titanium oxide as effective constituent; by rational compatibility, be aided with washing composition and commonly use auxiliary material, obtained liquid laundry detergent can use in ultraviolet washing machine; make the clean effect of liquid laundry detergent better; not only sterilization and disinfection is carried out to wash water, also the sewage after clothing and washing is processed, triple process; germ resistance is good, and protection of the environment does not hinder hand.
Also there are some about anti-ultraviolet liquid laundry detergent in prior art.Such as: CN200610014455.4 discloses a kind of ultraviolet-resistant washing emulsion; this liquid laundry detergent has good wetting ability and lipophilicity; in washing process; the film of one deck secure rigid can be formed in garment surface; ultraviolet blocking-up is through being also radiated at the most of ultraviolet radiation absorption on clothing; effectively improve the uvioresistant effect of fabric, also can provide efficient preventing coating protection to the color on clothes fiber.This liquid laundry detergent is made up of polyoxyethylenated alcohol sodium sulfate, alkyl glycoside, alcohol ether carboxylate, coconut oil diethanol amide, alkenyl sulphonate, thickening material, softener and sun-screening agent.But this liquid laundry detergent is not made up of natural component, there is certain harm to environment, and waste certain resource, do not advocate the theory of safety energy-conserving environment protection.
Summary of the invention
Based on all deficiencies existed in prior art, present inventor has performed and concentrate on studies, after paying a large amount of creative work, complete the present invention.
Specifically, the object of the invention is in order to P25 nano titanium oxide is applied in liquid laundry detergent, especially the liquid laundry detergent of necessarily filling a prescription is introduced this field of washing composition, Nano titanium dioxide has been widely used in the fields such as the electric material of plastics, rubber, functional fibre, ink, coating, weaving, paper industry, sun care preparations and photoelectrical solar conversion, and has good effect.But be not also applied to the field of washing composition so far, the formula of liquid laundry detergent of the present invention does not add any chemosynthesis material, under the irradiation of UV-light, generate the very strong superoxide anion radical of chemical activity and hydroxyl free radical, attack organism, reach the effect of degradable organic pollutant, there is superpower soil removability, the effect of good sterilization and disinfection, and the water after washing is processed, overcome washing effect not good, the present situation of the wasting of resources and environmental pollution.This liquid laundry detergent, under specific composition proportion, has multi-efficiency, and not only consumption is few, and washing effect is better, adheres to the theory of sustainable development, and provides a kind of safety, environmental protection, energy-conservation novel nano-material liquid laundry detergent.
The invention provides a kind of liquid laundry detergent, containing P25 nano titanium oxide as decontamination effective constituent, under the irradiation of UV-light, there is superpower soil removability, the washing effect reached, can use in ultraviolet washing machine.P25 nano titanium oxide preferably uses powder type, can select to mix crystal formation, wherein Detitanium-ore-type 80%, rutile-type 20%, and the consumption in liquid laundry detergent is 5%-40(wt) %.Liquid laundry detergent of the present invention also containing this area usual auxiliaries, comprises antiseptic-germicide, sorbent material, water-softening chemicals and thickening material, well known its each self-contained conventional substances kind and the addition in liquid laundry detergent.Wherein that the growth of certain micro-organisms (bacterium, fungi, yeast, algae and virus etc.) or breeding can be made to remain on is necessary below horizontal for antiseptic-germicide, reach the effect of disinfection, be selected from one or more the mixture in nanometer silver powder, chitin, mustard, Viscotrol C, horseradish; Sorbent material can adsorb wherein some composition effectively from gas or liquid, reaches better clean effect, is selected from one or more the mixture in 4A molecular sieve, shell powder, porous alumina; Water-softening chemicals is a kind of highly effective chelating dispersion agent, has very excellent complex ability to the metal ion such as calcium, magnesium, strengthens washability, is selected from one or more in EDETATE SODIUM, water glass, sodium carbonate, sodium bicarbonate; Thickening material can improve liquid viscosity, is selected from sodium alginate, starch, pectin, agar, gelatin, marine alga fat, carrageenin, dextrin, tragacanth gum, polysaccharide element derivative, one or more mixture in gum arabic.
Liquid laundry detergent of the present invention contains P25 nano titanium oxide 5%-40%, preferred 20-30%; Antiseptic-germicide 1%-4%, preferred 3-4%; Sorbent material 5%-35%, preferred 20-30%; Water-softening chemicals 2%-5%, preferred 4-5%; Thickening material 5%-10%, preferred 6-8%; Optionally, other conventional natural promoter of this area can also be contained in liquid laundry detergent.If no special instructions, all by weight percentage, the percentage composition of each component is in liquid laundry detergent gross weight for benchmark, and common solvent system is deionized water for the percentage ratio in the present invention.
The invention provides a kind of preparation method of liquid laundry detergent, take each composition according to the above ratio, by antiseptic-germicide, sorbent material, water-softening chemicals and other optional natural promoter add in deionized water and form emulsion, are joined by thickening material in this emulsion, continuously stirring, be settled to gross weight 100% with deionized water, and continue to stir the uniform liquid laundry detergent of formation.Whipping temp is not particularly limited, and is as the criterion, such as, can selects 30-70 DEG C, such as 35 DEG C, 40 DEG C, 45 DEG C, 50 DEG C, 55 DEG C, 60 DEG C, 65 DEG C can form homogeneous latex emulsion.
The present invention also provides P25 nano titanium dioxide powder preparing the purposes in liquid laundry detergent.
The present invention also provides the application of above-mentioned liquid laundry detergent in preparing washing goods.
The present invention also provides a kind of Cleaning preparations containing above-mentioned liquid laundry detergent.
Alternatively, the present invention relates to a kind of is the liquid laundry detergent of main component containing P25 nano titanium dioxide powder, auxiliary material is antiseptic-germicide, sorbent material, water-softening chemicals, thickening material and balance deionized water, by all compositions by certain proportioning continuously stirring at a suitable temperature, form uniform natural liquid laundry detergent.
The invention has the advantages that liquid laundry detergent forms primarily of natural component, be applicable to ultraviolet washing machine, there is better laundry effect, environment friendly and pollution-free, do not hinder hand, the skin of human body is safe from harm, soil removability is strong, sterilization effect is obvious, and energy degradation of contaminant, is conducive to the competitive power of product development and realizes environmental friendliness.
Embodiment
Below by specific embodiment, the present invention is described in detail, but these exemplary embodiments not intended to be form any type of any restriction to real protection scope of the present invention.
Embodiment 1:
By P25 nano titanium dioxide powder 30%, nanometer silver powder 4%, 4A molecular sieve 30%, the mixing of EDETATE SODIUM 5% powder, be dissolved in appropriate deionized water, form emulsion, sodium alginate 6% is added in this emulsion, continuously stirring at 45 DEG C, be settled to gross weight 100% to remain deionized water, continue to stir the uniform liquid laundry detergent of formation.
The effect data washed is carried out with the liquid laundry detergent of embodiment 1:
The take off data of blancometer and the calculating of soil removal efficiency
Cloth whiteness after the whiteness washing of the fair and clear degree soiled cotton bar of clean band
64.52 13.37 55.31
The calculating of soil removal efficiency: [(55.31-13.37)/(64.52-13.37)] × 100%=82%
Embodiment 2:
By P25 nano titanium dioxide powder 30%, chitin powder 4%, oyster shell whiting 30%, the mixing of sodium carbonate 5% powder, be dissolved in appropriate deionized water, form emulsion, starch 7% is added in this emulsion, continuously stirring at 50 DEG C, be settled to gross weight 100% to remain deionized water, continue to stir the uniform liquid laundry detergent of formation.
The effect data washed is carried out with the liquid laundry detergent of embodiment 2:
The take off data of blancometer and the calculating of soil removal efficiency
Cloth whiteness after the whiteness washing of the fair and clear degree soiled cotton bar of clean band
62.62 14.01 51.87
The calculating of soil removal efficiency: [(51.87-14.01)/(62.62-14.01)] × 100%=78%
Embodiment 3:
By P25 nano titanium dioxide powder 30%, horseradish powder 3%, how empty aluminum oxide 25%, the mixing of water glass 4% powder, be dissolved in appropriate deionized water, form emulsion, gelatin 8% is added in this emulsion, continuously stirring at 55 DEG C, be settled to gross weight 100% to remain deionized water, continue to stir the uniform liquid laundry detergent of formation.
The effect data washed is carried out with the liquid laundry detergent of embodiment 3:
The take off data of blancometer and the calculating of soil removal efficiency
Cloth whiteness after the whiteness washing of the fair and clear degree soiled cotton bar of clean band
61.40 13.76 52.35
The calculating of soil removal efficiency: [(52.35-13.76)/(61.40-13.76)] × 100%=81%
Embodiment 4:
By P25 nano titanium dioxide powder 30%, chitin 3%, how empty aluminum oxide 30%, the mixing of sodium carbonate 4% powder, be dissolved in appropriate deionized water, form emulsion, gelatin 8% is added in this emulsion, continuously stirring at 50 DEG C, be settled to gross weight 100% to remain deionized water, continue to stir the uniform liquid laundry detergent of formation.
The effect data washed is carried out with the liquid laundry detergent of embodiment 4:
The take off data of blancometer and the calculating of soil removal efficiency
Cloth whiteness after the whiteness washing of the fair and clear degree soiled cotton bar of clean band
62.38 13.53 51.25
The calculating of soil removal efficiency: [(51.25-13.53)/(62.38-13.53)] × 100%=77%
Embodiment 5:
By P25 nano titanium dioxide powder 30%, nanometer silver 4%, shell powder 30%, the mixing of EDETATE SODIUM 5% powder, be dissolved in appropriate deionized water, form emulsion, gelatin 6% is added in this emulsion, continuously stirring at 45 DEG C, be settled to gross weight 100% to remain deionized water, continue to stir the uniform liquid laundry detergent of formation.
The effect data washed is carried out with the liquid laundry detergent of embodiment 5:
The take off data of blancometer and the calculating of soil removal efficiency
Cloth whiteness after the whiteness washing of the fair and clear degree soiled cotton bar of clean band
62.26 13.42 51.14
The calculating of soil removal efficiency: [(51.14-13.42)/(62.26-13.42)] × 100%=77%
Embodiment 6:
By P25 nano titanium dioxide powder 30%, Seed of Chinese Soapberry extracting solution 5%, nanometer silver 4%, shell powder 30%, the mixing of EDETATE SODIUM 5% powder, be dissolved in appropriate deionized water, form emulsion, sodium alginate 8% is added in this emulsion, continuously stirring at 55 DEG C, be settled to gross weight 100% to remain deionized water, continue to stir the uniform liquid laundry detergent of formation.
The effect data washed is carried out with the liquid laundry detergent of embodiment 6:
The take off data of blancometer and the calculating of soil removal efficiency
Cloth whiteness after the whiteness washing of the fair and clear degree soiled cotton bar of clean band
61.59 12.49 52.09
The calculating of soil removal efficiency: [(52.09-12.49)/(61.59-12.49)] × 100%=81%.
Claims (9)
1. a liquid laundry detergent, containing P25 nano titanium oxide as decontamination effective constituent, wherein P25 nano titanium oxide accounts for the 5%-40% of liquid laundry detergent gross weight; Described liquid laundry detergent uses in ultraviolet washing machine;
Described liquid laundry detergent is also containing antiseptic-germicide, sorbent material, water-softening chemicals and thickening material;
Described liquid laundry detergent take gross weight as benchmark, is made up of the component of following weight percent, and each component shared weight percentage in liquid laundry detergent is: P25 nano titanium oxide 5%-40%; Antiseptic-germicide 1%-4%; Sorbent material 5%-35%; Water-softening chemicals 2%-5%; Thickening material 5%-10%; Surplus is deionized water;
Described P25 nano titanium oxide selects mixing crystal formation, and wherein Detitanium-ore-type accounts for 80%, rutile-type accounts for 20%.
2. liquid laundry detergent as claimed in claim 1, take wherein gross weight as benchmark, is made up of the component of following weight percent, and each component shared weight percentage in liquid laundry detergent is: P25 nano titanium oxide 20-30%; Antiseptic-germicide 3-4%; Sorbent material 20-30%; Water-softening chemicals 4-5%; Thickening material 6-8%; Surplus is deionized water.
3. liquid laundry detergent as claimed in claim 1, wherein antiseptic-germicide is selected from one or more in nanometer silver powder, chitin, mustard, Viscotrol C, horseradish; Sorbent material be selected from 4A molecular sieve, shell powder, porous alumina one or more; Water-softening chemicals be selected from EDETATE SODIUM, water glass, sodium carbonate, sodium bicarbonate one or more; Thickening material be selected from sodium alginate, starch, pectin, agar, gelatin, marine alga fat, carrageenin, dextrin, tragacanth gum, polysaccharide element derivative, in gum arabic one or more.
4. the preparation method of liquid laundry detergent according to any one of claim 1-3, other composition except thickening material is added in appropriate amount of deionized water and is mixed to form emulsion, thickening material is added in this emulsion, continuously stirring, be settled to gross weight 100% with deionized water, continue to stir until form uniform liquid laundry detergent.
5. preparation method as claimed in claim 4, wherein whipping temp is 30-70 DEG C.
6.P25 nano titanium dioxide powder is preparing the purposes in liquid laundry detergent, and described P25 nano titanium oxide accounts for the 5%-40% of liquid laundry detergent gross weight; Described liquid laundry detergent is also containing antiseptic-germicide, sorbent material, water-softening chemicals and thickening material;
Described liquid laundry detergent take gross weight as benchmark, is made up of the component of following weight percent, and each component shared weight percentage in liquid laundry detergent is: P25 nano titanium oxide 5%-40%; Antiseptic-germicide 1%-4%; Sorbent material 5%-35%; Water-softening chemicals 2%-5%; Thickening material 5%-10%; Surplus is deionized water;
Described P25 nano titanium oxide selects mixing crystal formation, and wherein Detitanium-ore-type accounts for 80%, rutile-type accounts for 20%.
7. purposes as claimed in claim 6, described liquid laundry detergent take gross weight as benchmark, is made up of the component of following weight percent, and each component shared weight percentage in liquid laundry detergent is: P25 nano titanium oxide 20-30%; Antiseptic-germicide 3-4%; Sorbent material 20-30%; Water-softening chemicals 4-5%; Thickening material 6-8%; Surplus is deionized water.
8. the application of the liquid laundry detergent according to any one of claim 1-3 in preparing washing goods.
9. a Cleaning preparations, containing the liquid laundry detergent according to any one of claim 1-3.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
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| CN103710182B (en) * | 2013-12-31 | 2015-10-14 | 慈溪市顺达实业有限公司 | A kind of health environment-friendly based on Living marine resources washes clean goods and preparation method |
| CN103923769B (en) * | 2014-04-30 | 2017-04-05 | 茹晖 | A kind of ecological detergent and preparation method thereof |
| CN105088758A (en) * | 2014-05-05 | 2015-11-25 | 江苏聚威新材料有限公司 | Finishing method for interweaved fabric |
| CN108410596B (en) * | 2018-05-08 | 2020-04-07 | 福州秘庄日化有限公司 | Multifunctional laundry detergent and preparation process thereof |
| CN108384673B (en) * | 2018-05-08 | 2020-06-09 | 杭州妙洁日化科技有限公司 | Environment-friendly laundry detergent |
| CN108559659A (en) * | 2018-06-21 | 2018-09-21 | 界首市洁净日用品有限公司 | Antibacterial anti-colour contamination liquid detergent of one kind and preparation method thereof |
| CN112646672A (en) * | 2019-10-10 | 2021-04-13 | 杨子凡 | Cleaning block for washing machine tank and preparation method thereof |
| CN111454788A (en) * | 2020-04-24 | 2020-07-28 | 谷雨河生物科技有限公司 | Energy-saving water-saving low-foam pregnant woman and infant laundry detergent production process and formula |
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| CN1552836A (en) * | 2003-06-05 | 2004-12-08 | 柯积发 | Nanometer antibacterial non-phosphate washing powder |
| CN102824277A (en) * | 2012-09-06 | 2012-12-19 | 南京市口腔医院 | Application of nanometer titania photocatalyst in false tooth antibiosis and cleaning |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN1552836A (en) * | 2003-06-05 | 2004-12-08 | 柯积发 | Nanometer antibacterial non-phosphate washing powder |
| CN102824277A (en) * | 2012-09-06 | 2012-12-19 | 南京市口腔医院 | Application of nanometer titania photocatalyst in false tooth antibiosis and cleaning |
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