CN1552836A - Nanometer antibacterial non-phosphate washing powder - Google Patents
Nanometer antibacterial non-phosphate washing powder Download PDFInfo
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- CN1552836A CN1552836A CNA031238580A CN03123858A CN1552836A CN 1552836 A CN1552836 A CN 1552836A CN A031238580 A CNA031238580 A CN A031238580A CN 03123858 A CN03123858 A CN 03123858A CN 1552836 A CN1552836 A CN 1552836A
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Abstract
A nanometer bactericidal phosphor-free multi-enzyme detergent powder consists of nanometer bactericidal, composite enzyme, non-ionic surfactant and anionic surfactant. It achieves strong bactericidal and cleaning abilities, easily rinsing, no damage to fabrics, no environmental pollution and no irritation for skin.
Description
Technical field
The present invention relates to a kind of enzymatic detergent, the without phosphorus plurality of enzymes washing powder of particularly a kind of nanometer degerming relates in particular to the without phosphorus plurality of enzymes washing powder of a kind of nanometer degerming.
Background technology
Use down because phosphatic washing powder is a large amount of, a large amount of phosphorous washess enter river, river, lake, sea, destroy water quality, cause ecological overbalance, very big to environmental destruction, produce grave danger to physical environment, and high phosphorus washing powder skin irritation, still can make us producing trace and itch and wash back air dried clothes.
In the daily life, panoramic bacterium such as intestinal bacteria, streptococcus aureus, Candida albicans and black-koji mould depend on and grow on people's clothing, common washing composition can not effectively suppress to kill various bacteria, easily causes cross infection, serious threat people's health when washing.Common washing composition detersive power at low temperatures easily lost efficacy, and can not remove spot, troublesome effectively; And common washing powder can not reach the purpose of removing bacterium, as winter temperature on the low side, the effect of common washing powder reduces greatly, can not effectively remove the spot on the clothing, especially the fats spot.
Summary of the invention
The purpose of this invention is to provide a kind of enzymatic detergent, provide a kind of nanometer degerming without phosphorus plurality of enzymes washing powder especially, relate in particular to the without phosphorus plurality of enzymes washing powder of a kind of nanometer degerming.The shortcoming that has overcome that present washing powder bacteria-eliminating efficacy is poor, detersive power is not good enough, is difficult for rinsing, skin is had stimulation, damages fabric, environment is polluted.
The objective of the invention is to be achieved through the following technical solutions:
A kind of enzymatic detergent belongs to the strong without phosphorus prescription of a kind of non-ionic surface active, comprises following component: nano antibacterial agent, prozyme agent and nonionogenic tenside and anion surfactant;
Described nano antibacterial agent is selected from inorganic nano antiseptic and organic nano antiseptic-germicide, especially inorganic nano photocatalysis antibacterial agent, the agent of described inorganic nano photocatalysis antibacterial can be selected from nano zine oxide (nmZnO), nano titanium oxide etc., the size range≤30nm of its nanometer.
Described prozyme agent is selected from industrial enzyme, as proteolytic enzyme, lipase, amylase, pancreatin etc., the proportioning ratio of plurality of enzymes agent especially is a lipase in the described prozyme agent: proteolytic enzyme: other industrial enzyme is (0.5-5): (0.5-5): (0.5-3), especially be 3: 1: 1 or 1: 3: 1, described other industrial enzyme is selected from amylase, pancreatin.
Proteolytic enzyme is under the cooperation of all the other two kinds of enzymes under the normal temperature, can reach best clean effect, the characteristics of lipase are to make washing composition also can reach good removal ability to fat when low temperature, thereby can effectively strengthen the detersive power of this prescription in prescription based on the prozyme agent of lipase.
Described washing powder comprises following parts by weight of component: nano antibacterial agent 0.05-0.5,12 fatty alcohol-polyoxyethylene ether 3-9, sodium polyacrylate 1-5, Sodium dodecylbenzene sulfonate 2-8, yellow soda ash 20-30, concentrated crystal soda 6-12, water glass 16-24, Xylo-Mucine 0.05-5, sodium sulfate 1-5, zeolite 18-26, white dyes 0.05-0.5, an amount of, the composite enzyme agent of spices 0.1-1.5, deionized water 1-7;
Especially be following parts by weight of component: nano antibacterial agent 0.1-0.3,12 fatty alcohol-polyoxyethylene ether 5-7, sodium polyacrylate 2-4, Sodium dodecylbenzene sulfonate 4-6, yellow soda ash 23-27, concentrated crystal soda 8-10, water glass 18-22, Xylo-Mucine 1-3, sodium sulfate 2.5-3.5, zeolite 20-24, white dyes 0.1-0.2, spices 0-0.05, composite enzyme agent 0.1-1.0, deionized water 3-5;
Be preferably following parts by weight of component: nano antibacterial agent 0.2,12 fatty alcohol-polyoxyethylene ether 6, sodium polyacrylate 3, Sodium dodecylbenzene sulfonate 5, yellow soda ash 25, concentrated crystal soda 9, water glass 20, Xylo-Mucine 2, sodium sulfate 3,4A zeolite 22, white dyes 0.15, spices 0.01, composite enzyme agent 0.5, deionized water 3-5.
Washing powder of the present invention can add the available any auxiliary material of industry, can be prepared as industrial any formulation, as pulvis, liquid preparation, tablet etc.
The mechanism of washing powder of the present invention prepares based on following main raw material and performance thereof:
1, the present invention is based on the nanometer degerming agent, and prozyme is helped it, and synergy reaches the bacteria-eliminating efficacy of washing powder.
2, the degerming agent of nanometer degerming non-phosphide detergent of the present invention, when being subjected to sunlight and ultraviolet irradiation under the inorganic nano titanium dioxide normal temperature, reduction potential is high, space around making produces atomic oxygen, have anti-microbial effect, can freely decomposite mobile electronics in water and in the system of air existence, stay the hole of positively charged simultaneously, progressively produce the hydroxyl radical free radical that reaction generates, react with bacterium and bacterium excretory toxin, thereby bacterium and toxin are killed, after bacterium is killed, Ag
+Swash again from coming out, carry out next round with other bacterium colony and kill, and can remain on and reach that no new bacterium multiplies in 90 days.
Carry out the quantitative disinfecting test of nano zine oxide, when the degree of depth of nano zine oxide is 1%, after 5 minutes, sterilizing rate to streptococcus aureus is 98.86%, to colibacillary sterilizing rate is 99.93%, and under the cooperation of prozyme and 4A zeolite, effectively having improved detersive power of the present invention, its characteristics that showing are to make washing composition also can reach effective decontamination to various dirts when low temperature.
3, known nano antibacterial agent, especially inorganic nano catalytic antimicrobial agent, particularly inorganic nano such as nano zine oxide, nano titanium oxide photocatalysis antibacterial agent, it is strong to have thermostability, and function is lasting, safe and reliable characteristics, extremely strong chemically reactive is arranged, can with multiple organic substance, react as organism in stain and the bacterium and excretory toxin thereof, thereby the elimination stain is killed bacterium, remains and toxin.
12 fatty alcohol-polyoxyethylene ether, trade(brand)name " peregal ", molecular formula RO (CH
2CH
2)
nH, normal temperature for white lotion, are a kind of nonionic surface active agent down, have good penetration, wet performance, emulsification and soil-removing action.
Sodium polyacrylate (PAAS) is colourless or yellow thick liquid for lower molecular weight, structural formula
Be mainly used in red sinking agent, emulsifing thickener and water treatment are a kind of dirt dispersion agents efficiently with flocculation agent etc.
Sodium dodecylbenzene sulfonate, i.e. linear alkyl benzene sulfonate sodium, molecular formula C
18H
29O
3SN
a, white is to faint yellow powdery solid, and commodity mostly are the white pulpous state aqueous solution, and are soluble in water, stable to alkali, diluted acid, have performances such as good decontamination, foaming, wetting, dispersion, and biological degradability is greater than 90%.
Yellow soda ash claims soda ash again, is commonly called as soda, washes powder, molecular formula Na
2CO
3, molecular weight 106.00 is noncrystalline things of white, natural originates in lake and the hot spring.Have certain detersive power, with soil release, and absorption property is arranged preferably and promote the foam nucleus formation, share the infringement that can reduce fabric with water glass with fatty dirt saponification.
Concentrated crystal soda, molecular formula Na
2CO
3NaHCO
32H
2O, white needle-like crystals is mainly used in preparation washing and tanning agent etc.
Water glass claims bubble flower alkali again, molecular formula Na
2SiO
2, molecular weight 122.14.The white powdery is mainly used washing composition, and the auxiliary agent of metal washing plays the softening of water effect.
Xylo-Mucine (CMC), polymerization degree n be greater than 200, molecular formula ((C
6H
7O
2COH
2) OCH
2COONa) n is a white powder.
Sodium sulfate, its Na
2SO
410 water things be the big prism of colourless branch crystallographic system, white powdered anhydrous sodium sulphate, molecular weight 142 is as the auxiliary agent of washing powder.Because gegenion concentration increases, play the effect of compression ionogenic surfactant diffusion double layer, surface excess is increased, in solution, easily be split into micelle, thereby reduce the surface tension and the CMC of washings, help effects such as wetting, decontamination.
Zeolite such as 4A zeolite claim zeolite, molecular sieve again, have the screening molecularity, are the aluminosilicate of aqueous calcium, sodium and barium, strontium potassium, the general name of mineral.General light color is alkalescence in solution, shock absorption is arranged, and dispersed and antiredeposition performance are arranged, and urges photo etching to share with the nanometer degerming, effectively strengthens the effect of kill bacteria, with tensio-active agent coordinative role is arranged, to fish, algae, people's safety non-toxic.
White dyes, as CBS-X, VBL, 3D-3,3D-4 type, CBS-X is a vinylbenzene biphenyl type derivative.Outward appearance is faint yellow green powder, water soluble, at room temperature cellulosic fibre, polymeric amide, thiozell all there be good brightening and brightening effect, and have good little cyan mediation dissolution dispersity, since nonnitrogenous in the molecule, so extremely anti-chlorine floats, oxygen floats agent and strong acid-base, behind repetitive scrubbing, can not make the fabric yellowing or turn green, a part is by biological degradation in water, and another part is by the day photolysis, and is extremely safe to human body.
Spices, industrial spices can bring people's aromatic odour, and the multiple essence of odor type as artificial pamorusa oil (Rhizoma et radix valerianae oil), and contains strong fragrance lemon flavour and existing fruity flavor etc.
Composite enzyme agent is as proteolytic enzyme, lipase and diastatic compound preparation.
1. proteolytic enzyme, the blue-greenish colour particle is the synthesis of detergent specific enzyme, its major ingredient is 2709 Sumizyme MPs.
2. lipase, its characteristics that showing are to make washing composition also can reach good removal ability to fat when low temperature.Its soil removability can be along with to the increase of washing times and show more obviously.
3. amylase is the starch hydrolysis can be become the enzyme of dextrin or maltose, can remove the dirt of chocolate, mashed potato, noodles, congee etc.
Above enzyme agent can coexist after processing treatment, utilizes the synergy of plurality of enzymes preparation, can improve the clean effect to clothing greatly.
Enzymatic detergent of the present invention, especially the preparation method of the without phosphorus plurality of enzymes washing powder of nanometer degerming, can adopt existing technology of preparing preparation, as the attached polymer molding technology, described the attached polymer molding method is with the attached polymer molding manufactured powdery condition washing composition, be nearly 20 years new developing technology, so-called agglomeration is meant the gathering mutually under given conditions of solid materials and liquid material, becomes a kind of technology of certain granular product.
Specifically may further comprise the steps:
In white dyes, add 12 fatty alcohol-polyoxyethylene ether in will filling a prescription earlier, add deionized water, sodium polyacrylate, Sodium dodecylbenzene sulfonate, yellow soda ash, concentrated crystal soda, Xylo-Mucine, sodium sulfate again, stir, described stirring is preferably and whenever adds a kind of raw material stirring and add a kind of raw material down again after evenly; Add water glass and 4A zeolite again and stir, add nano-photo catalytic antiseptic-germicide, spices, prozyme agent then and make resulting mixture, sieve, described sieving sieved more than being preferably 8 orders, and especially 10 orders sieve, promptly.
The present invention has the following advantages:
1, washing powder strong detergency of the present invention, clean effect is remarkable at low temperatures for outstanding tool.
2, the synergy of utilizing the plurality of enzymes preparation to close antiseptic-germicide can improve the clean effect to clothing greatly; Utilize the chemically reactive of nano antibacterial agent, can eliminate stain effectively, bacterium, remains and toxin are killed.
3, the present invention also have good, the easy rinsing of bacteria-eliminating efficacy, non-stimulated to skin, damage fabric, the advantage of phosphorous environmentally safe not.
Embodiment
Embodiment 1
Take by weighing following component (kilogram): 15nm nano zine oxide 0.1,12 fatty alcohol-polyoxyethylene ether 6, sodium polyacrylate 3, Sodium dodecylbenzene sulfonate 5, yellow soda ash 25, concentrated crystal soda 9, water glass 20, Xylo-Mucine 2, sodium sulfate 3,4A zeolite 22, CBS-X0.1, lemon flavour 0.01, prozyme agent 0.5, deionized water 4;
Described prozyme agent is a lipase: proteolytic enzyme: amylase is 3: 1: 1;
The preparation method is: add 12 fatty alcohol-polyoxyethylene ether in will filling a prescription earlier in CBS-X, add deionized water, sodium polyacrylate, Sodium dodecylbenzene sulfonate, yellow soda ash, concentrated crystal soda, Xylo-Mucine, sodium sulfate again, stir, add a kind of raw material down for whenever adding a kind of raw material stirring again after evenly during stirring; Add water glass and 4A zeolite again and stir, add nano zine oxide, lemon flavour, prozyme agent then and make mixture, 10 orders that sieve, packing is promptly.
Washing powder of the present invention is used for washing clothes, and especially high temperature season uses, and as temperature height in summer, lipase is that the ratio of master's prozyme reaches best soil-release antibacterial effect.
Embodiment 2
Take by weighing following component (kilogram): 8nm nano zine oxide 0.05,12 fatty alcohol-polyoxyethylene ether 3, sodium polyacrylate 1, Sodium dodecylbenzene sulfonate 2, yellow soda ash 20, concentrated crystal soda 6, water glass 16, Xylo-Mucine 0.05, sodium sulfate 1, zeolite 18, VBL0.05, spices 0.5, prozyme agent 0.1, deionized water 1;
Described prozyme agent is a lipase: proteolytic enzyme: amylase is 1: 3: 1;
The preparation method is: add 12 fatty alcohol-polyoxyethylene ether in will filling a prescription earlier in VBL, add deionized water, sodium polyacrylate, Sodium dodecylbenzene sulfonate, yellow soda ash, concentrated crystal soda, Xylo-Mucine, sodium sulfate again, stir, add a kind of raw material down for whenever adding a kind of raw material stirring again after evenly during stirring; Add water glass and 4A zeolite again and stir, add nano zine oxide, lemon flavour, prozyme agent then and make mixture, 20 orders that sieve, packing is promptly.
Washing powder of the present invention is used for washing clothes, and especially low temperature season uses, and is low as winter temperature, and the egg enzyme is that the ratio of master's prozyme reaches best soil-release antibacterial effect.
Embodiment 3
Take by weighing following component (kilogram): 15 nano titanium oxides, 0.5,12 fatty alcohol-polyoxyethylene ether 9, sodium polyacrylate 5, Sodium dodecylbenzene sulfonate 8, yellow soda ash 30, concentrated crystal soda 12, water glass 24, Xylo-Mucine 5, sodium sulfate 5, zeolite 26, CBS-X0.5, Rhizoma et radix valerianae oil 0.2, prozyme agent 1.5, deionized water 7;
Described prozyme agent is a lipase: proteolytic enzyme: amylase is 5: 5: 3;
The preparation method is: add 12 fatty alcohol-polyoxyethylene ether in will filling a prescription earlier in CBS-X, add deionized water, sodium polyacrylate, Sodium dodecylbenzene sulfonate, yellow soda ash, concentrated crystal soda, Xylo-Mucine, sodium sulfate again, stir, add a kind of raw material down for whenever adding a kind of raw material stirring again after evenly during stirring; Add water glass and 4A zeolite again and stir, add nano titanium oxide, Rhizoma et radix valerianae oil, prozyme agent then and make mixture, 20 orders that sieve, packing is promptly.
Embodiment 4
Take by weighing following component (kilogram): 2nm nano zine oxide 0.1,12 fatty alcohol-polyoxyethylene ether 5, sodium polyacrylate 2, Sodium dodecylbenzene sulfonate 4, yellow soda ash 23, concentrated crystal soda 8, water glass 18, Xylo-Mucine 1, sodium sulfate 2.5, zeolite 20, CBS-X 0.1, apple flavour 0.02, prozyme agent 0.2, deionized water 3;
Described prozyme agent is a lipase: proteolytic enzyme: amylase is 0.6: 0.5: 1;
The preparation method is with embodiment 1.
Embodiment 5
Liquid preparation of the present invention
Batching and method are with embodiment 1, and described method mixture adds entry to 1000ml.
Claims (10)
1, a kind of enzymatic detergent comprises following component: nano antibacterial agent, prozyme agent and nonionogenic tenside and anion surfactant.
2, enzymatic detergent according to claim 1, described nano antibacterial agent are selected from inorganic nano antiseptic and organic nano antiseptic-germicide.
3, enzymatic detergent according to claim 2, the agent of described inorganic nano photocatalysis antibacterial can be selected from nano zine oxide, nano titanium oxide, the size range≤30nm of its nanometer; Described prozyme agent is selected from industrial enzyme.
4, enzymatic detergent according to claim 3, described industrial enzyme can be proteolytic enzyme, lipase, amylase, pancreatin; The proportioning ratio can be lipase: proteolytic enzyme: other industrial enzyme is (0.5-5): (0.5-5): (0.5-3).
5, enzymatic detergent according to claim 4, described proportioning ratio is 3: 1: 1 or 1: 3: 1.
6, according to claim 1 or 4 described enzymatic detergents, described washing powder comprises following parts by weight of component: nano antibacterial agent 0.05-0.5,12 fatty alcohol-polyoxyethylene ether 3-9, sodium polyacrylate 1-5, Sodium dodecylbenzene sulfonate 2-8, yellow soda ash 20-30, concentrated crystal soda 6-12, water glass 16-24, Xylo-Mucine 0.05-5, sodium sulfate 1-5, zeolite 18-26, white dyes 0.05-0.5, an amount of, the composite enzyme agent of spices 0.1-1.5, deionized water 1-7;
7, according to claim 1 or 6 described enzymatic detergents, described washing powder can be following parts by weight of component: nano antibacterial agent 0.1-0.3,12 fatty alcohol-polyoxyethylene ether 5-7, sodium polyacrylate 2-4, Sodium dodecylbenzene sulfonate 4-6, yellow soda ash 23-27, concentrated crystal soda 8-10, water glass 18-22, Xylo-Mucine 1-3, sodium sulfate 2.5-3.5, zeolite 20-24, white dyes 0.1-0.2, spices 0-0.05, composite enzyme agent 0.1-1.0, deionized water 3-5.
8, enzymatic detergent according to claim 1, described washing powder can be following parts by weight of component: nano antibacterial agent 0.2,12 fatty alcohol-polyoxyethylene ether 6, sodium polyacrylate 3, Sodium dodecylbenzene sulfonate 5, yellow soda ash 25, concentrated crystal soda 9, water glass 20, Xylo-Mucine 2, sodium sulfate 3,4A zeolite 22, white dyes 0.15, spices 0.01, composite enzyme agent 0.5, deionized water 3-5.
9, enzymatic detergent according to claim 1, described washing powder can be industrial any formulation, as pulvis, liquid preparation, tablet etc.
10, the preparation method of the described enzymatic detergent of claim 1-9 may further comprise the steps:
Add 12 fatty alcohol-polyoxyethylene ether in the white dyes, add deionized water, sodium polyacrylate, Sodium dodecylbenzene sulfonate, yellow soda ash, concentrated crystal soda, Xylo-Mucine, sodium sulfate again, stir; Add water glass and zeolite again and stir, add nano-photo catalytic antiseptic-germicide, spices, prozyme agent then and make resulting mixture, sieve, promptly.
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|---|---|---|---|
| CNB031238580A CN100487098C (en) | 2003-06-05 | 2003-06-05 | Nanometer antibacterial non-phosphate washing powder |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB031238580A CN100487098C (en) | 2003-06-05 | 2003-06-05 | Nanometer antibacterial non-phosphate washing powder |
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| CN1552836A true CN1552836A (en) | 2004-12-08 |
| CN100487098C CN100487098C (en) | 2009-05-13 |
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