CN101240293B - Bran extract and cleansing composition comprising bran extract and preparation method thereof - Google Patents
Bran extract and cleansing composition comprising bran extract and preparation method thereof Download PDFInfo
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- CN101240293B CN101240293B CN2007100906088A CN200710090608A CN101240293B CN 101240293 B CN101240293 B CN 101240293B CN 2007100906088 A CN2007100906088 A CN 2007100906088A CN 200710090608 A CN200710090608 A CN 200710090608A CN 101240293 B CN101240293 B CN 101240293B
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- testa tritici
- extract
- enzyme reaction
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
- A61K8/9783—Angiosperms [Magnoliophyta]
- A61K8/9794—Liliopsida [monocotyledons]
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents ; Methods for using cleaning compositions
- C11D11/04—Special methods for preparing compositions containing mixtures of detergents ; Methods for using cleaning compositions by chemical means, e.g. by sulfonating in the presence of other compounding ingredients followed by neutralising
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
- A61K2800/85—Products or compounds obtained by fermentation, e.g. yoghurt, beer, wine
Abstract
The invention provides a wheat bran extract, a detergent composite comprising the extract and a manufacturing method thereof, wherein the wheat bran extract is obtained by adding the mixed water, sugar and salts into the wheat bran and then performing an enzyme reaction; the wheat bran, water, sugar and salts are mixed according to a certain proportion, and then filtered to obtain the bran extract after the enzyme reaction on certain conditions, the bran extract is used as a raw material of the detergent and applied to a recipe of the detergent to obtain a composite for washing; the composite has the remarkable washing, skin-protecting and water-saving effects, and also has the practical significance to improve and enhance the quality of detergent products.
Description
Technical field
The cleaning composition that the invention provides a kind of Testa Tritici extract and contain this Testa Tritici extract, and preparation method thereof, specifically, the present invention adds pure water, sugar and salt mixing with Testa Tritici to carry out filtering after the enzyme reaction, obtain the Testa Tritici extract, again this extract and known washing composition batching are allocated the manufacturing processed that combines a kind of new cleaning composition.
Background technology
Usually alleged washing composition is meant that people are in order to remove the employed various preparations of the pollutent that is washed on the article.At present, the main raw material of the washing composition of family expenses is a synthetic surfactant, and it has stronger washing usefulness, provides convenience for people's production and life, but has also brought many problems.Along with improving constantly of people's living standard, the usage quantity of washing composition also significantly increases, and a large amount of synthetic detergents flows into the river course, infiltrates the face of land with sewage, because these washing composition are not easy to be decomposed, becomes one of reason of environmental pollution; On the other hand, when using these washing composition to remove dirt, also removed inherent grease on people's skin, made the keratinous dryness be full of cracks of skin, easily by infectation of bacteria; More seriously part remains in the active inorganic substance of the lip-deep synthetic surface of tableware, enters human body with food, brings harm to human health.
In order to overcome the problems referred to above of synthetic detergent, people begin to utilize natural matter to produce household detergent.For example, utilize preparations such as shell and insect shell to contain kitchen detergent of chitosan and preparation method thereof (No. the 0486861st, Republic of Korea's patent of invention); Natural phant such as coconut, balloonflower root washing composition constituent and preparation technology (Republic of Korea's publication 2004-0099828 number); Contain the cosmetic detergent constituent (No. the 0163118th, Republic of Korea's patent of invention) of elm Cortex ulmi pumilae extract etc.
But the production cost of the raw material of the natural detergent constituent of having developed at present is than higher, and the raw material resources of the high-quality natural detergent constituent that has are rare, has brought difficulty for large-scale production.Therefore, how utilizing the existing natural resource, overcome above-mentioned these deficiencies, produce low cost, dynamical environment friendly washing articles for use, is the research and development focus of present this area.In very long human history, people expect utilizing the abundant Testa Tritici of raw material resources very early, promptly utilize abundant material such as the starch that contains in the Testa Tritici, protein, Mierocrystalline cellulose, these macromolecular compounds, the molecule that can adsorb other materials, have and remove foreign matter preferably, particularly remove the effect of the heavy metal in the agricultural chemicals, though people and know that not really science mechanism, useful for a long time whole meal flour among the people improves looks, utilizes the way of the soup washing bowls and chopsticks of cooking noodle.Though be rich in the material that the mankind are highly profitable in the Testa Tritici, owing to reasons such as people's understanding deficiency, extractive technique are undeveloped, a large amount of Testa Triticis is at present still mainly as the feed of raise poultry, domestic animal.
Summary of the invention
In view of above-mentioned present situation, the washing constituent that the present invention is intended to develop a kind of efficient, environmental protection, does not injure the natural detergent composition of skin and contain this composition.
The object of the invention is to provide a kind of Testa Tritici extract, and this extract obtains by Testa Tritici being added the enzyme reaction of carrying out self after entry, sugar, the salt.
The present invention also aims to provide a kind of cleaning composition that contains the Testa Tritici extract, in the said composition, per 100 weight parts (unit) contain the Testa Tritici extracting solution of 60-99 weight part, and all the other are washing composition batching well known in the art.
The present invention also aims to provide a kind of preparation method who contains the cleaning composition of Testa Tritici extract, after earlier Testa Tritici, pure water, sugar and salt mixing being carried out enzyme reaction under given conditions, obtaining containing the Testa Tritici extract through filtering, the more conventional batch composition of this extract and washing composition to be allocated the cleaning composition that combines a kind of new environmental protection.
To achieve these goals, the invention provides a kind of Testa Tritici extract, wherein this extract is to carry out the resulting extract of enzyme reaction again after Testa Tritici adds entry, sugar, salt mixing.
Testa Tritici extract of the present invention is the materials of wheat wheat bran to be added entry, sugar, salt mix that to carry out enzyme reaction more resulting, and the step of this reaction comprises:
(a). Testa Tritici and water are mixed stirring, and this process is the stage ((a) stage) of once extracting, and obtains extracting solution No. one time;
(b). add sugar, salt mixing in an above-mentioned extracting solution, stir, this process is the stage of second extraction;
Also can when adding sugar, salt, also add entry in this process;
(c). the enzyme that utilizes in the Testa Tritici to be contained carries out enzyme reaction to other composition that contains in the Testa Tritici, and this process is the enzyme reaction stage, obtains the extracting solution after the enzyme reaction;
(d). with the extracting liquid filtering after the enzyme reaction, promptly obtain the Testa Tritici extract.
The above-mentioned Testa Tritici extract that obtains can be liquid form (being the Wheat bran extracting solution), and the solid or the semi-solid form that also can be extracting solution through obtaining after concentrating among the present invention be referred to as various forms Testa Tritici extract or wheat bran extract.
In the above-mentioned step that makes the Testa Tritici extract, described Testa Tritici and water mix the water that the stage of once extracting of stirring specifically comprises employing pH 6.0-7.0, preferred pure water, the preferred 25-30 of temperature ℃, churning time is at least 0.5 hour, preferred 0.5-2 hour, the speed of stirring (for example rotating speed in the suitability for industrialized production) was preferably 1500-2000rpm.
The stage of described second extraction comes down to the process that secondary leaches, and specifically is included under preferred temperature 25-30 ℃, adds sugar, salt stirring, and the speed of stirring (rotating speed) is preferably 450-750rpm, and churning time is at least 1 hour, is preferably 1-3 hour.
Also can look the concentration decision of an extracting solution in the second extraction stage and whether also add water, if concentration higher (dense thick) or solid/semi-solid form, can in an above-mentioned extracting solution (thing), add entry, sugar, salt mixing, stir, the preferred 6.0-7.0 of pH value of the water that is adopted, more preferably pure water.
The described enzyme reaction stage preferably carries out under 25-30 ℃ temperature, and the time is at least 12 hours, from commercial viability and cost consideration, and preferred 12-48 hour.
The above-mentioned reaction process that obtains wheat extract, the ratio of raw material and water is generally realizing being as the criterion in this area, in a preferred embodiment, 50 kilograms of Testa Triticis add 1000 liters in water, after the enzyme reaction through filtering, finally obtain about 400 liters of extracting solutions, remaining moisture content is penetrated in the Testa Tritici behind the water extraction after, and filtration is removed.Resulting herein Testa Tritici extract is that every 100kg extract is obtained through above-mentioned technology by the 12.5kg Testa Tritici.
Following detailed description obtains each stage of Testa Tritici extract of the present invention, is beneficial to those skilled in the art and understands technical scheme of the present invention more.
At first,, promptly once extract the stage, Testa Tritici need be immersed in the water (preferred pure water) that can be beneficial to dissolving wheat wheat bran composition and stir, obtain an extracting solution (also can be described as and once leach mixed solution) of leaching section composition in the fs.
Testa Tritici is meant in the course of processing of wheat-flour, sifts out remaining byproduct behind most of starch, mainly is made up of the crushed material of the pericarp of wheat, endosperm, plumule, contains materials such as starch, food fiber, mineral substance, amino acid, VITAMIN.In the course of processing of wheat-flour, what contain in the wheat has the nearly 70-80% of antiacidization material of extremely important meaning in Testa Tritici to human body.At present, to the deep processing and utilization of Testa Tritici, various countries are carrying out scientific research widely, but have really begun the also very few of actual production at present, most of wheat bran still is used for animal rearing as feed, therefore as raw material of the present invention---and the source of Testa Tritici is very extensive.
Can control to can the thorough mixing Testa Tritici and be easy to stir and be advisable for the water yield of Shi Yonging (amount of purified water) in this course, and is good can obtain extraction (leaching) the liquid production concentration with economic implications, and the pH value of employed water is preferably 6.0-7.0; The speed that stirs preferably is controlled at 1500-2000rpm, and temperature preferably is controlled at 25-30 ℃, and churning time is at least 0.5 hour, preferred 0.5-2 hour.In embodiment preferred for this invention, proper method is under 25 ℃ temperature, with 1800rpm speed, stirs 1 hour.Promptly can effectively destroy the cell walls of wheat pericarp etc. through a large amount of this method and steps of experiment showed,, other chemical reactions take place but be unlikely original composition.
In subordinate phase, i.e. in the second extraction stage, in the extracting solution that need in the fs, obtain, add sugar, salt stirring, and can optionally add an amount of water (pure water) and stir, carry out second extraction and leaching.The pH value of the water that is adopted is identical with the fs.
Adding sugar is in order to make the middle molecule of said extracted liquid (mixed solution) stable.Starch in the extracting solution transforms the maltose that generates the meta-bolites that decomposes and neutralization is made up of protein, fat etc. is played important effect under diastatic effect, therefore add the generation that sugar can promote maltose in extracting solution.In addition, can promote generation, and promote viscosity the gel that separates water soluble cellulose (for example piperylene, pectin etc.) the formation reticulattion that contains in the Testa Tritici.Mentioned sugar can be white sugar, muscovado and fructose etc. among the present invention, and preferred granulated sugar is even more ideal with the effect of using muscovado.
Adding salt is in order to promote the formation of mucedin.Mucedin be by prolamine and flour gluten in conjunction with the protein that forms, the suction back forms wire and progressively expand into the radiation structure, these radioactivity structures intersect to form reticulattion, and these reticulated structures can play the effect of absorbing fats.Discharge gas and be generated as small bubble in this process, bubble can reduce molecular surface tension force to be played to separate and is washed dirt and dirt, thereby plays cleaning function.The mentioned salt of the present invention can be edible salt, mainly refers to sodium salt, preferred sodium-chlor.
In the extracting solution that obtains in the fs, per 100 gram extracting solutions add 80-120 gram water (pure water), and 0.1-3 restrain sugar, and 0.1-3 restrains salt, and stirring velocity is 450-750rpm, under 25-30 ℃ temperature lasting 1-3 hour; Relatively Shi Yi method is with 600rpm speed, continues to stir 2 hours under 25 ℃ temperature.It is in order not only to destroy the Testa Tritici cell walls but also not destroy polymer substances such as the protein that formed, polysaccharide that this stage is adopted the stirring at low speed purpose.
In the phase III, be the enzyme reaction stage, mainly with the resulting Testa Tritici extracting solution of subordinate phase under 25-30 ℃ of temperature, stop to stir, left standstill 12-24 hour, and made protein in the wheat bran, starch, fat etc. under the effect of the enzyme that wheat bran itself contains, carry out enzyme reaction.The method of comparative optimization is to place under 25 ℃ of temperature 24 hours, and placing 24 hours was for the various enzymes of inherent are fully separated out, and 25-30 ℃ of temperature of maintenance is in order to make enzyme reaction more abundant.By above-mentioned reaction, the starch in the wheat bran, protein etc. are decomposed the macromolecular compound that generation has washing effect by inherent enzyme in the wheat bran.The inherent enzyme mainly contains lipase (lipase), amylase (amylase) and proteolytic enzyme (protease) in the Testa Tritici, lipase can become steatolysis lipid acid and glycerine, contain abundant calcium and albumin in the wheat bran and can play the lipolytic effect of promotion lipase, amylase is one of representational saccharifying enzyme, it can be hydrolyzed into starch glucose, maltose (maltose), low molecule dextrin carbohydrates such as (dextrin); Proteolytic enzyme (protease) is a kind of enzyme of decomposing protein, and it can resolve into protein peptide (peptide) class, and then generates amino acid, and can promote the liquefaction and the saccharification of wheat bran effective constituent.
Can generate water solutable edible fiber by above-mentioned enzyme digestion reaction, for example: materials such as piperylene, pectin, gel and phlegmatic temperament, the water solutable edible fiber suction force is strong, can combine with water and make fatty coagulative precipitation easily; In the meta-bolites that the maltose that transform to be generated by starch can quicken to be made up of protein, lipid acid etc. and decompose, can also play the effect of eliminating toxin; Carbohydrate in the wheat bran has improved viscosity after being shifted by water dissolution as polyose, plays the effect of absorption, absorption, removal greasy dirt and peculiar smell.
In the quadravalence section, i.e. filtration stage, it is that sediment separate out and upper strata mixing liquid adopt common filtering technique to filter after the enzyme digestion reaction of phase III finishes.Conventional isolation technique such as that filtration can be adopted is centrifugal, gac and filtration, more regular separation can be used 200mesh screen filtering separation.The wheat bran extracting solution of obtaining through filtration the growing of yeast, mould and other bacteriums, preferably adds sanitas and preservatives in order to prevent it.Preservatives preferred sodium benzoate herein (sodium benzoate), and the preferred methyl p-hydroxybenzoate of sanitas (para methyl paraben, methylparaben).
The Testa Tritici extract that the present invention extracts can be widely used in the production of kitchen detergent (prescription stain remover), meal lotion, makeup, bathing agents, shampoo as natural decontamination raw material.
The present invention also provides a kind of composition that contains the Testa Tritici extract, said composition is cleaning composition (washing composition), it is for by Testa Tritici extracting solution that said process the is produced raw material as cleaning composition of the present invention, the Testa Tritici extract that contains 60～99 weight parts in the composition of wherein per 100 weight parts, add tensio-active agent again, content and conventional production of detergents technology according to the known tensio-active agent of detergent industry are carried out proportioning, preparation, but can also add solvation (solubilizing agent) as required in right amount, other additive such as spices can produce the washing constituent that contains Testa Tritici extract of the present invention.
Above-mentioned tensio-active agent can be selected from anion surfactant (for example: linear alkylbenzene sulfonate (LAS)), fatty alcohol sulfate salt (FAS), Fatty Alcohol(C12-C14 and C12-C18) Vinyl Ether sulfuric acid (FAES), sulfonated (AOS), nonionogenic tenside (for example: total free aminoacids (FAA)), 1-3 kind arbitrarily in fatty amine oxide (FAO) or the Voranol EP 2001 (AE).
Testa Tritici extract of the present invention is that every 100kg extract is obtained through above-mentioned technology by the 12.5kg Testa Tritici.
Cleaning composition provided by the invention; it contains above-mentioned Testa Tritici extract; Testa Tritici extract 60-99 part wherein; tensio-active agent 10-20 part; but solvation 0.5-4 part, sanitas 0.01-1 part, spices 0.01-1 part; Derma-Guard 0.1-3 part, stablizer 0.1-3 part and thickening material 0.1-3 part.
The present invention carries out enzyme digestion reaction by Testa Tritici, sugar and salt and filters, and as the stoste of producing detergent composition, this stoste is the main raw material that the invention provides a kind of novel cleaning composition with resulting extracting solution.In the batching of said composition; the Testa Tritici extracting solution of the present invention that contains 60-99 unit in the cleaning composition of per 100 units (washing composition); the amount of preferably wheat wheat bran extract is a 75-85 unit; more preferably tensio-active agent 10-20 unit, but solvation 0.5-4 unit, sanitas 0.01-1 unit; spices 0.01-1 unit; Derma-Guard 0.1-3 unit, stablizer 0.1-3 unit, thickening material 0.1-3 unit.
More than be weight unit.Above-mentioned " part " also is a weight unit, can be mg, g, kg etc.
The present invention also provides a kind of manufacture method that contains the detergent composition of Testa Tritici extract, comprising:
(a) Testa Tritici and water mixing stirring are obtained extracting solution No. one time;
(b) in an extracting solution, add sugar, salt mixing stirring;
(c) enzyme that utilizes in the Testa Tritici to be contained carries out enzyme reaction to the composition in the Testa Tritici in (b);
(d), obtain Testa Tritici extract (liquid) with the extracting liquid filtering that obtains after the enzyme reaction;
(e) in the Testa Tritici extract, add the known tensio-active agent of detergent applications, making the weight content of Testa Tritici extract in composition is 60-99 part/100 part, preferred 65-90 part, also preferably add the conventional additive that adopts of detergent applications, tensio-active agent and each content of additive also are this area conventional amount used and ratio, can obtain composition of the present invention.
The present invention also provides the above-mentioned application of cleaning composition in washing composition, makeup, hair washing or shower product that contains the Testa Tritici extract.
The cleaning composition that contains the Testa Tritici extract of the present invention has the following advantages:
At first, has better economic.That the present invention has used is that the wheat-flour course of processing produces, up to the present in a large number as feed byproduct---wheat bran is as raw material, and raw material sources are extensive, and raw materials cost is low;
Secondly, has the feature of environmental protection preferably.The present invention uses natural material and obtains by bioprocesses, and therefore extracting composition itself has favorable biological degradability, compares with other detergent raw materials that use synthetic technology to produce, and has tangible environmental-protecting performance.Throw out after the separation is development and use further, also can be used as feed or fertilizer of crops, can obviously reduce the investment of environmental protection aspect;
The 3rd, the detergent composition that the present invention extracts, every index all meets the industry standard of washing composition, and tangible washing synergism is arranged.And the water solutable edible fiber in the present composition contains and Mierocrystalline cellulose bonded phenol (phenol), not only has the antiacid usefulness that turns into, all right absorbing fats; The meta-bolites that the maltose that contains etc. can neutralize and be made of depositions such as protein, fat makes its cleaning that is decomposed easily; The polyose carbohydrate that contains is active adsorption greasy dirt and peculiar smell thing in water;
The 4th, the composition that the present invention extracts has the advantages of good skin provide protection.Generally speaking, the washing composition of the synthetic or natural washing raw material production of the utilization of Xiao Shouing all needs to add Derma-Guard on the market.Although for the injury of the tensio-active agent that prevents to add to skin, when utilizing this constituent to make the washing composition commodity, also can add a certain amount of Derma-Guard, but this composition itself contains abundant glycerine (glycerine), the nutrient substance that skin such as VITAMIN and mineral substance is essential, even do not add Derma-Guard, composition of the present invention also has good protective action to skin;
The 5th, the composition that the present invention extracts has good washing.General washing composition in use needs more water flushing.It is flushable neat and tidy using the washing composition of the composition production that the present invention extracts to use less water.
Description of drawings
Fig. 1: the technical process that contains the detergent composition of wheat bran composition of the present invention.
Embodiment
Describe the present invention in detail below in conjunction with accompanying drawing, but do not limit practical range of the present invention.
Embodiment 1 Testa Tritici preparation method of extract
Once extract the stage: at first, utilize the byproduct that forms in the wheat-flour course of processing---Testa Tritici 50kg, add pH value and be 500 liters of 6.5 pure water, under 25 ℃ of temperature, stirred 1 hour, produce an extracting solution (mixed solution) with the 1800rpm rotating speed; This stage also can be described as once and leaches the stage, sees Fig. 1;
The second extraction stage: in resulting extracting solution of the stage of once extracting, add the ph value again and be 500 liters of 6.5 distilled water, muscovado 10kg, mineral salt (NaCl) 3kg, the rotating speed with 600rpm under 25 ℃ of temperature stirred 2 hours, produced secondary raffinate (mixed solution); This stage also can be described as secondary and leaches the stage;
The enzyme reaction stage: secondary raffinate without any stirring, was placed 24 hours under 25 ℃ of temperature, made it that enzyme reaction take place.Be that starch, protein, fat etc. in Testa Tritici and the secondary raffinate thereof enzymolysis takes place under the effect of inherent amylase, proteolytic enzyme, lipase etc. transform, generate composition, obtain mixed solution with good washing effect;
Filtration stage: the mixed solution that the enzyme reaction stage obtains is placed precipitation, and making does not have the dissolved precipitation of solid material to get off.Upper solution is filtered with 200 (mesh) screen, obtain 400 liters of extracting solutions.In order to prevent bacteria breed such as yeast, mould in the filtered liquid, add Sodium Benzoate (sodium benzoate) and methyl p-hydroxybenzoate (methylparaben), make concentration reach 0.1% and fully stir and can reach fungistatic effect.
Utilize the Testa Tritici extracting solution of producing in this example, carry out the allotment combination of other batchings, can be made into the washing composition that contains the Testa Tritici constituent according to the detergent industry standard.As shown in Figure 1.
The food ingredient of the detergent composition that contains the Testa Tritici extract that embodiment 2 the present invention produce
In the Testa Tritici extract (stoste or title immersion liquid) that embodiment 1 makes; but add tensio-active agent solvation, food antiseptics, spices, Derma-Guard, stablizer and thickening material and mixing, finally make the composition (washing composition) that contains the Testa Tritici extract.Batching composition and composition analysis see Table 1, table 2:
Table 1. food ingredient table
Table 2. Testa Tritici immersion liquid analysis of components table (100g)
The effect of invention:
The detergent composition that contains the Testa Tritici extract of the present invention; because reasonably utilized byproduct---the Testa Tritici that produces in the wheat-flour course of processing; therefore raw material sources are extensive; not only have favorable economic benefit and environment protecting, also have washing preferably, skin care and water-saving result.Composition of the present invention can be widely used in the production of makeup, kitchen detergent, meal lotion, scouring agent, shampoo.
The embodiment 3 Testa Tritici extract dish washing detergents that contain of the present invention
In the Testa Tritici extract (stoste) that embodiment 1 makes; add tensio-active agent sulfonated (AOS); but weight ratio is 15% solvation (solubility promoter; for example pure; weight ratio is 1.8%), food antiseptics (Sodium Benzoate and methyl p-hydroxybenzoate; weight ratio is 0.1), lemon flavour 0.1%, Derma-Guard (Jojoba oil 1.0%), stablizer (amine oxide 1.0%) and thickening material (Natvosol 1.0%) and mix; finally make the composition that contains the Testa Tritici extract, i.e. dish washing detergent.Process contrasts with the industry examination criteria of Korea S's dish washing detergent, and every index all meets the standard of dish washing detergent, and assay sees Table 3.
The dish washing detergent laboratory inspection that table 3. contains the Testa Tritici extracting solution is reported the result
| Interventions Requested and reference value | The dish washing detergent lab test results |
| Stability ,-3 °----10 ° (24hr) | By (no crystallization) |
| (40±1)℃(24hr) | By (nothing is outstanding turbid, does not have precipitation, and is no spoiled) |
| PH value (25 ℃, 1% solution) (4.0～10.5) | 6.8 |
| Gross activity thing content, % (〉=15) | 19％ |
| Methyl alcohol, mg/g (≤1) | 0.3 |
| Formaldehyde, mg/g (≤0.1) | 0 |
| White dyes must not detect | Do not detect |
| Arsenic (in 1% solution in arsenic), mg/kg (≤0.05) | 0.01 |
| Plumbous (in 1% solution in lead), mg/kg (≤1) | 0.1 |
| Total number of bacterial colony, individual/g (≤1000) | 100 |
| Coliform, individual/100g (≤3) | 0 |
| Detersive power (being not less than the standard dish washing detergent) | Well |
The embodiment 4 Testa Tritici extract washing composition that contain of the present invention
In the Testa Tritici extract (stoste) that embodiment 1 makes; add tensio-active agent linear alkylbenzene sulfonate (LAS); fatty alcohol sulfate salt (FAS) and sulfonated (AOS); the weight ratio of this tensio-active agent adds up to 15%; but solvation (alcohol; weight ratio is 3%); food antiseptics (Sodium Benzoate; weight ratio is 0.05%); lemon flavour 0.01%; Derma-Guard (Jojoba oil 2.0%); stablizer (amine oxide is an amount of) and thickening material (Natvosol is an amount of) also mix; finally make the composition that contains the Testa Tritici extract, i.e. washing composition.
Embodiment 5 cleaning compositions that contain the Testa Tritici extract of the present invention
In the Testa Tritici extract (stoste) that embodiment 1 makes; add tensio-active agent total free aminoacids (FAA) and Voranol EP 2001 (AE); but the total weight of this tensio-active agent is 15%, other additive as solvation, food antiseptics, lemon flavour, Derma-Guard, stablizer and thickening material and embodiment 4 with; mix, finally make the cleaning composition that contains the Testa Tritici extract.
The present invention illustrates as above that with preferred embodiment so it is not in order to qualification the present invention, and change or retouching that those skilled in the art are done in the scope that does not break away from this patent all belong to equivalence of the present invention and change, and should be included in the scope of institute of the present invention desire protection.
Claims (7)
1. Testa Tritici extract, this extract are that Testa Tritici adds entry, sugar, salt and carries out the resulting extract of enzyme reaction again after mixing; Wherein said sugar is granulated sugar, and described salt is sodium salt, and the described step of carrying out enzyme reaction after entry, sugar, salt mix again that adds comprises:
(a). Testa Tritici and water are mixed stirring, obtain extracting solution No. one time; The water yield of using in this process controls to energy thorough mixing Testa Tritici and is easy to and stirs, and the pH value of employed water is 6.0-7.0, stirring velocity 1500-2000rpm, temperature 25-30 ℃, churning time 0.5-2 hour;
(b). in an extracting solution, add sugar, salt, mix, stir; Wherein, in a described extracting solution, per 100 gram extracting solutions add the water of 80-120 gram pH 6.0-7.0, and 0.1-3 restrains sugar, and 0.1-3 restrains salt, and stirring velocity 450-750rpm continues 1-3 hour under 25-30 ℃ temperature;
(c). leave standstill under 25-30 ℃ temperature and carried out enzyme reaction in 12-24 hour, it is that the enzyme that utilizes in the Testa Tritici to be contained reacts the composition that contains in the Testa Tritici, obtains the extracting solution after the enzyme reaction;
(d). with the extracting liquid filtering after the enzyme reaction, promptly obtain the Testa Tritici extract.
2. Testa Tritici extract according to claim 1, wherein, the ratio of Testa Tritici raw material and water is: 50 kilograms of Testa Triticis add 1000 liters in water.
3. Testa Tritici extract according to claim 1 and 2, this Testa Tritici extract of every 100kg is obtained through extracting by the 12.5kg Testa Tritici.
4. Testa Tritici extract according to claim 1, this Testa Tritici extract are what prepare in accordance with the following methods:
Once extract the stage: Testa Tritici 50kg, add pH value and be 500 liters of 6.5 pure water, under 25 ℃ of temperature, stirred 1 hour with the 1800rpm rotating speed, produce extracting solution No. one time;
The second extraction stage: in resulting extracting solution of the stage of once extracting, add the ph value again and be 500 liters of 6.5 distilled water, muscovado 10kg, mineral salt 3kg, the rotating speed with 600rpm under 25 ℃ of temperature stirred 2 hours, produced secondary raffinate;
The enzyme reaction stage: secondary raffinate without any stirring, was placed 24 hours under 25 ℃ of temperature, made it that enzyme reaction take place, obtain mixed solution;
Filtration stage: the mixed solution that the enzyme reaction stage obtains is placed precipitation, and making does not have the dissolved precipitation of solid material to get off, and upper solution is filtered with the 200mesh screen, obtains 400 liters of extracting solutions.
5. cleaning composition, contain each described Testa Tritici extract among the claim 1-4 of 75～85 weight parts in the composition of per 100 weight parts, tensio-active agent 10-20 weight part, but solvation 0.5-4 weight part, sanitas 0.01-1 weight part, spices 0.01-1 weight part, Derma-Guard 0.1-3 weight part, stablizer 0.1-3 weight part and thickening material 0.1-3 weight part; The described Testa Tritici extract of every 100kg is obtained through extracting by the 12.5kg Testa Tritici.
6. method for preparing the described cleaning composition of claim 5 comprises:
(a). Testa Tritici and water are mixed stirring, obtain extracting solution No. one time;
(b). in an extracting solution, add sugar, salt, mix, stir;
(c). leave standstill and carry out enzyme reaction, it is that the enzyme that utilizes in the Testa Tritici to be contained reacts the composition that contains in the Testa Tritici, obtains the extracting solution after the enzyme reaction;
(d). with the extracting liquid filtering after the enzyme reaction, promptly obtain the Testa Tritici extract;
(e). add tensio-active agent in the Testa Tritici extract, making the weight content of Testa Tritici extract in composition is 60-99 part/100 part.
7. cleaning composition as claimed in claim 5, its product form are kitchen detergent, dish washing detergent, makeup, hair washing or shower product.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR10-2007-0013334 | 2007-02-08 | ||
| KR1020070013334 | 2007-02-08 | ||
| KR1020070013334A KR100868929B1 (en) | 2007-02-08 | 2007-02-08 | Cleansing composition comprising red-dog extract and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
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| CN101240293A CN101240293A (en) | 2008-08-13 |
| CN101240293B true CN101240293B (en) | 2011-10-19 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN2007100906088A Expired - Fee Related CN101240293B (en) | 2007-02-08 | 2007-03-30 | Bran extract and cleansing composition comprising bran extract and preparation method thereof |
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| Country | Link |
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| JP (1) | JP5266255B2 (en) |
| KR (1) | KR100868929B1 (en) |
| CN (1) | CN101240293B (en) |
| WO (1) | WO2008096966A1 (en) |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103409248A (en) * | 2013-06-21 | 2013-11-27 | 魏文贞 | Detergent composition |
| WO2014210230A1 (en) | 2013-06-27 | 2014-12-31 | The Procter & Gamble Company | Personal care articles |
| CN104250927B (en) * | 2014-06-09 | 2016-04-13 | 浙江纺织服装科技有限公司 | A kind of fabric wormwood microcapsule dressing agent and preparation method thereof |
| CN116536368B (en) * | 2023-06-26 | 2023-10-13 | 广东迪美新材料科技有限公司 | Bacillus marinus fermentation product, preparation method and application thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1513963A (en) * | 2002-12-31 | 2004-07-21 | 张少建 | Mud bath soap and its preparation method |
| KR20040099828A (en) * | 2003-05-20 | 2004-12-02 | 유병언 | Composition for laundry detergents containing natural plants |
| CN1840673A (en) * | 2006-01-19 | 2006-10-04 | 江南大学 | Process for preparing feruoylated oligosaccharide by enzymolysis of wheat bran |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB382148A (en) | 1932-01-26 | 1932-10-20 | Herbert Walter | Process of producing a plastic substance for cleaning walls and the like |
| JPH0251599A (en) * | 1988-08-16 | 1990-02-21 | Hime Tsubaki:Kk | Detergent composition containing enzyme |
| KR930002848B1 (en) * | 1990-12-20 | 1993-04-12 | 제일제당 주식회사 | Detergent composition and their preparation |
| KR970002055B1 (en) * | 1994-12-09 | 1997-02-21 | 제일제당 주식회사 | Liquid detergent composition |
| JP3887451B2 (en) * | 1997-04-16 | 2007-02-28 | 株式会社パーマケム・アジア | Circulating or suction water treatment agent for toilet |
| JP2000136125A (en) * | 1998-10-29 | 2000-05-16 | Kumano Yushi Kk | Hand cleaner |
| JP3947668B2 (en) * | 2000-12-22 | 2007-07-25 | 株式会社資生堂 | Associative thickener for aqueous solvents, gel-like composition and emulsion composition containing the same |
| JP2002285191A (en) * | 2001-03-26 | 2002-10-03 | Lion Corp | Liquid detergent composition |
| JP3886738B2 (en) * | 2001-05-24 | 2007-02-28 | 花王株式会社 | Cleaning composition |
| JP4856321B2 (en) * | 2001-06-01 | 2012-01-18 | 花王株式会社 | Skin wiping composition |
| JP2003128563A (en) * | 2001-10-25 | 2003-05-08 | Ichimaru Pharcos Co Ltd | Cosmetic composition, drink or food |
| US20050201965A1 (en) * | 2004-03-11 | 2005-09-15 | The Procter & Gamble Company | Personal cleansing compositions |
| JP2006347911A (en) * | 2005-06-14 | 2006-12-28 | Ogawa & Co Ltd | Moisture retention plant extract, and external preparation, cosmetic product, bathing agent and detergent containing the extract |
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2007
- 2007-02-08 KR KR1020070013334A patent/KR100868929B1/en active IP Right Grant
- 2007-03-30 CN CN2007100906088A patent/CN101240293B/en not_active Expired - Fee Related
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2008
- 2008-01-15 JP JP2009548985A patent/JP5266255B2/en active Active
- 2008-01-15 WO PCT/KR2008/000243 patent/WO2008096966A1/en active Application Filing
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1513963A (en) * | 2002-12-31 | 2004-07-21 | 张少建 | Mud bath soap and its preparation method |
| KR20040099828A (en) * | 2003-05-20 | 2004-12-02 | 유병언 | Composition for laundry detergents containing natural plants |
| CN1840673A (en) * | 2006-01-19 | 2006-10-04 | 江南大学 | Process for preparing feruoylated oligosaccharide by enzymolysis of wheat bran |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101240293A (en) | 2008-08-13 |
| KR20080074358A (en) | 2008-08-13 |
| JP5266255B2 (en) | 2013-08-21 |
| WO2008096966A1 (en) | 2008-08-14 |
| JP2010518221A (en) | 2010-05-27 |
| KR100868929B1 (en) | 2008-11-17 |
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