CN103642602B - A kind of liquid detergent - Google Patents
A kind of liquid detergent Download PDFInfo
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- CN103642602B CN103642602B CN201310719550.4A CN201310719550A CN103642602B CN 103642602 B CN103642602 B CN 103642602B CN 201310719550 A CN201310719550 A CN 201310719550A CN 103642602 B CN103642602 B CN 103642602B
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Abstract
The present invention relates to a kind of liquid detergent, this liquid detergent mainly adopts natural and green safety tensio-active agent tea saponin, alkyl glycoside, and dodecanamide propyl amine oxide is raw material.The present invention is compared with the liquid detergent based on petrochemical materials, raw material sources very abundant and belong to renewable resources, be nontoxic gentle material, without any side effects to human body, this liquid detergent has good antibacterial bacteriostatic function, strong detergency, free from environmental pollution, the features such as use safety, have good wash dining set and the effect of gourd, fruit and vegetable, thus adapt to different consumer demand, can suitability for industrialized production be realized.
Description
Technical field
The present invention relates to articles for washing, specifically a kind of liquid detergent.
Background technology
Society is along with the enhancing of environmental consciousness, and people propose three large basic demands in the pursuit to the clean product of Novel washing: Green Product; Use safety, do not hinder the neutral products of hand; High detersive power product.Health safety issues for many years involved by detergent for tableware series products more and more causes the concern of people.The chemical residual of liquid detergent likely affects HUMAN HEALTH directly or indirectly.Therefore use not harmful to human, do not destroy living environment, the liquid detergent of non-toxic and non-pollution green safety just becomes the task of top priority.The industrially developed country such as current Europe, the U.S., Japan are in the selection of liquid detergent main ingredient, pay close attention to environmental safety, the security of composition selected by it to HUMAN HEALTH and ecotope is better than the developing countries such as South East Asia, more obviously be better than the liquid detergent main component that China is current, slower in the development of China's Environmental Protection in China type dish washing detergent.Along with the progressively enhancing of people's environmental consciousness, the developing direction in dish washing detergent future will be for main flow with environment-friendly and green type.
Through verification pertinent literature, Chinese Patent Application No. 01134178.5 discloses a kind of natural detergent, adds a small amount of soluble perfume mixing match form by Chinese honey locust leaching cream and tea saponin crystal." family's herbal medicine handbook " Guangzhou press publishes in January, 2002, learns that Chinese honey locust has few poison, valetudinarian, invalid and contraindication in pregnancy.With the liquid detergent that Chinese honey locust is made as starting material, for wash dining set or fruit, difficulty washes down residual poison, if there is drink by mistake, consequence is by hardly imaginable.Chinese Patent Application No. 201210241913.3 discloses a kind of liquid detergent containing tea saponin, containing polyoxyethylenated alcohol sodium sulfate in this liquid detergent, diox by product diox can be produced in the process of production polyoxyethylenated alcohol sodium sulfate and belong to toxic substance, can be irritant to skin, eye and respiratory system, and may cause damage to liver, kidney and neural system, life-time service also may be carcinogenic.Wherein tea saponin content is 1% ~ 4%, and consumption has been washing assistant effect less, instead of main component.
The maximum liquid detergent main component of current application is Oil derivative instruments sodium alkyl benzene sulfonate (LAS) and aliphatic alcohol polyethenoxy sodium sulfate (AES), and because they are water-soluble, cost is low, and scourability is good, thus its essence always out in the cold fall.According to relevant report, artificial experiment is cultivated stomach cancer cell, is injected the deterioration that soapless soap base substance LAS can accelerate cancer cells.The blood dissolubility of LAS is also very strong, easily causes the change of oxyphorase, causes anemia.Diox by product ， diox can be produced in the process of production AES and belong to toxic substance, can be irritant to skin, eye and respiratory system, and may cause damage to liver, kidney and neural system, life-time service also may be carcinogenic.
Family expenses liquid detergent pH value should be neutral or slight alkalinity.Excellent removes oiliness, emulsifying property, wettability; To skin action temperature and; Good foaming power; Biological degradability is good; Soltion viscosity is easy to regulate; To human non-toxic." household chemicals " Chemical Industry Press publishes in January, 2008, learn that tensio-active agent to the pungency of skin generally: cats product > anion surfactant > amphoteric ionic surfactant ≈ nonionogenic tenside, actives nonionogenic tenside conventional in synthetic detergent does not all have carcinogenesis, and thus liquid detergent selects nonionogenic tenside more safer than anion surfactant.
Because tea saponin is natural green product, belong to nonionogenic tenside, there is the performances such as good emulsifying, dispersion, foaming, decontamination, wetting, sterilization, anti-inflammatory, itself easy biological degradation does not pollute the environment, performance is soft, the aqueous solution is subacidity, is that the liquid detergent that tensio-active agent is made into meets the demand of human consumer to green safety with tea saponin.From social effect, extraction and the exploitation of tea saponin fundamentally embody the green chemical industry system turned waste into wealth, and decrease the pollution of grouts accumulation to environment.From production source, about there is fifty-five million mu mountain region in China for planting tea tree, and the by product tea waste obtained after annual tea seed oil expression about has 500,000 tons, produces provide rich in natural resources for tea saponin.From economic benefit, the excellent property of tea saponin, is widely used, and has wide market outlook, and it had both met the needs of human consumer to natural green product, simultaneously again for manufacturer creates good economic benefit.
Summary of the invention
The object of the invention is to overcome above-mentioned weak point, provide a kind of without any side effects, have certain antibacterial and bacteriostasis, the liquid detergent of the high-grade green safety of high-content tea saponin.
The object of the invention is to be realized by following scheme:
A liquid detergent for green safety containing tea saponin, is characterized in that being made up of the component of following weight per-cent:
Above-mentioned each component concentration percentage ratio sum equals 100%.
A kind of liquid detergent, comprises by the component of following weight per-cent:
Tea saponin 5 ~ 20%; Alkyl glycoside 15 ~ 25%; The dodecanamide propyl amine oxide of 1 ~ 10%; All the other are water.
In order to better thickening foam stabilizing effect, described component also comprises the sucrose fatty ester that weight percent is no more than 6%.
Stable in order to better decontamination foaming effect and foaming, described component also comprise weight percent be no more than 3% sodium alkyl sulfate, be no more than 0.1% disodium EDTA.
In order to improve product quality, improving product outward appearance, described component also comprise weight percent be no more than 8% Flos Lonicerae extractive solution, be no more than the essence of 0.2%, be no more than potassium sorbate, Sodium Benzoate or the Kathon CG of 0.15%.
The preparation method of described liquid detergent, by described weight percent, tea saponin is dissolved in deionized water, be heated to 40 ~ 50 DEG C, add alkyl glycoside, dodecanamide propyl amine oxide at this temperature while stirring, stir, with citric acid or aqueous sodium hydroxide solution adjusted to ph to 6 ~ 7.5, obtain product.
Preferably, while adding alkyl glycoside, dodecanamide propyl amine oxide, the sucrose fatty ester being no more than 6% is added.
Preferably, add while adding alkyl glycoside be no more than 3% sodium alkyl sulfate, be no more than 0.1% disodium EDTA.
Be more preferably, tea saponin is dissolved in deionized water, be heated to 40 ~ 50 DEG C, add alkyl glycoside, dodecanamide propyl amine oxide at this temperature while stirring, stir, until solution be down to continue to add after room temperature the Flos Lonicerae extractive solution being no more than 8%, the essence being no more than 0.2%, be no more than 0.15% potassium sorbate, Sodium Benzoate or Kathon CG.
Alkyl glycoside APG, synthesized by renewable resources natural fat alcohol and glucose, it is the more comprehensive new non-ionic surfactants of a kind of performance, have the characteristic of conventional nonionic and anion surfactant concurrently, having high surface, good ecological security and intermiscibility, is internationally recognized first-selection " green " functional surfactant.APG is nontoxic, safety little to skin irritation, and thickening, thickening, detersive power are remarkable, can generation synergism composite with various nonionic surface active agent, and APG is not in Product Safety (containing harmful by-products dioxan), and mildness and germ resistance have advantage.With APG Substitute For Partial AES, LAS, 6501, AEO, peregal, K12, AOS preparation meal lotion Be very effective.The washing composition be made up of APG has good solubility, mildness, nontoxic and easily rinsing.APG as a kind of cosurfactant, and can not only be more suitable for for making principal surfactant in dish washing detergent.
Dodecanamide propyl amine oxide is a kind of special nonionogenic tenside, has the character of amphoterics.There is good thickening and antistatic, soft, foam enhancing, steady bubble and detergency ability; Also there is sterilization, lime soap dispersing power, and biological degradability is good, belongs to environment-friendly type daily chemical products.Dodecanamide propyl amine oxide is then mainly used in all kinds of transparent liquid washings, as dish washing detergent, bath wash dew wait formula in as foam enhancing, suds-stabilizing agent, the consistency of thickening material and the resistance to overturning of product can be improved.Dodecanamide propyl amine oxide to skin as mild as a dove, as during as moisturizing, can give skin smooth comfort.It is compared with traditional thickening material 6501, has low-consuming, that security is high, efficiency is high, wettability is good, detergency is strong feature.
Sodium alkyl sulfate is a kind of anion surfactant of excellent property, has good decontamination washing, foam performance, safety non-toxic, is now widely used in the daily chemical products such as toothpaste.
Sucrose fatty ester is edible nonionogenic tenside prepared by a kind of natural matter, can be widely used in foodstuffs industry, can play the effect that thickening is surely steeped in this formulation product.
Disodium EDTA is a kind of complexing of metal ion agent and antioxidant synergist, stablizer of conventional safety.
Flos Lonicerae extractive solution has removing toxic substances, anti-inflammatory, virus killing, sterilization and antipruritic effect, especially has certain restraining effect to streptococcus aureus, intestinal bacteria etc.
Tableware detergent prepared by the present invention has strong detergency, and viscosity is suitable for, good appearance, Phosphateless environmentally friendly, the advantage of safety; PH value is than now commercially product is low simultaneously, little to skin irritation; And raw material sources are wide, simple process, without particular requirement, is easy to industrialization.In formula, all surface promoting agent is the tensio-active agent of green safety, and many has selected nonionogenic tenside, therefore safer, gentle.Tea saponin simultaneously under this formula is as main component, can play good decontamination washing and antibacterial bacteriostatic function.There is good wash dining set and the effect of gourd, fruit and vegetable, without any side effects.
The liquid detergent of green safety prepared by the present invention is compared with existing liquid detergent, formula rationally, wherein natural safety surface promoting agent tea saponin and green safety Surfactants Alkyl content very high, play primary surfactant, raw material sources very abundant and belong to renewable resources, raw materials usedly be green safety material, be nontoxic gentle material, without any side effects to human body, this liquid detergent has good antibacterial bacteriostatic function, strong detergency, free from environmental pollution, use safety, well meet the demand of current human consumer to green safety, therefore have good value for applications.
Embodiment
The liquid detergent of embodiment 1 one kinds of green safeties
It adopts following formula:
Above-mentioned each component concentration percentage ratio sum equals 100%.
Being prepared as of described liquid detergent: joined by deionized water in stirring tank, by described weight percent configuration 100g liquid detergent, be dissolved in deionized water by tea saponin 10g, be heated to 50 DEG C, heated and stirred is even.After material dissolution, add alkyl glycoside 20g, dodecanamide propyl amine oxide 6g at this temperature while stirring, stir, with citric acid or aqueous sodium hydroxide solution adjustment pH to 6.5, add deionized water and be settled to 100g, treat that solution is down to room temperature, obtain product.
The liquid detergent of embodiment 2 one kinds of green safeties
It adopts following formula:
Above-mentioned each component concentration percentage ratio sum equals 100%.
Being prepared as of described liquid detergent: joined by water in stirring tank, by described weight percent configuration 100g liquid detergent, be dissolved in deionized water by tea saponin 10g, be heated to 45 DEG C, heated and stirred is even.After material dissolution, add alkyl glycoside 20g, sodium alkyl sulfate 1g, dodecanamide propyl amine oxide 6g, sucrose fatty ester 5g, disodium EDTA 0.1g at this temperature while stirring, stir, by citric acid or aqueous sodium hydroxide solution adjusted to ph to 6, add water and be settled to 100g, treat that solution is down to room temperature, obtain product.
The liquid detergent of embodiment 3 one kinds of green safeties
It adopts following formula:
Above-mentioned each component concentration percentage ratio sum equals 100%.
Being prepared as of described liquid detergent: joined by deionized water in stirring tank, by described weight percent configuration 100g liquid detergent, be dissolved in deionized water by tea saponin 10g, be heated to 40 DEG C, heated and stirred is even.After material dissolution, add alkyl glycoside 20g, sodium alkyl sulfate 1g, dodecanamide propyl amine oxide 6g, sucrose fatty ester 5g, disodium EDTA 0.1g at this temperature while stirring, stir, by citric acid or aqueous sodium hydroxide solution adjusted to ph to 6, add water and be settled to 100g, treat that solution is down to room temperature, obtain product.
The liquid detergent of embodiment 4 one kinds of green safeties
It adopts following formula:
Above-mentioned each component concentration percentage ratio sum equals 100%.
Being prepared as of described liquid detergent: joined by deionized water in stirring tank, by described weight percent configuration 100g liquid detergent, be dissolved in deionized water by tea saponin 15g, be heated to 45 DEG C, heated and stirred is even.After material dissolution, add alkyl glycoside 25g, sodium alkyl sulfate 1.5g, dodecanamide propyl amine oxide 3g, sucrose fatty ester 4g, disodium EDTA 0.1g at this temperature while stirring, stir, by citric acid or aqueous sodium hydroxide solution adjusted to ph to 7.5, add water and be settled to 100g, treat that solution is down to room temperature, continue to add Flos Lonicerae extractive solution 6g, essence 0.2g, potassium sorbate 0.05g, obtain product.
The liquid detergent of embodiment 5 one kinds of green safeties
It adopts following formula:
Above-mentioned each component concentration percentage ratio sum equals 100%.
Being prepared as of described liquid detergent: joined by deionized water in stirring tank, by described weight percent configuration 100g liquid detergent, be dissolved in deionized water by tea saponin 20g, be heated to 50 DEG C, heated and stirred is even.After material dissolution, add alkyl glycoside 15g, sodium alkyl sulfate 1.5g, dodecanamide propyl amine oxide 7g, sucrose fatty ester 5g, disodium EDTA 0.1g at this temperature while stirring, stir, adjusted to ph to 7.5, be down to after room temperature until solution and continue to add Flos Lonicerae extractive solution 5g, essence 0.05g, Sodium Benzoate 0.05g, obtain product.
The liquid detergent of embodiment 6 one kinds of high-grade green safeties
It adopts following formula:
Above-mentioned each component concentration percentage ratio sum equals 100%.
Being prepared as of described liquid detergent: joined by deionized water in stirring tank, by described weight percent configuration 100g liquid detergent, be dissolved in deionized water by tea saponin 5g, be heated to 50 DEG C, heated and stirred is even.After material dissolution, add alkyl glycoside 25g, sodium alkyl sulfate 3g, dodecanamide propyl amine oxide 8g, sucrose fatty ester 2g, disodium EDTA 0.1g at this temperature while stirring, stir, adjusted to ph to 7.5, be down to after room temperature until solution and continue to add Flos Lonicerae extractive solution 6g, essence 0.01g, Kathon CG 0.15g, obtain product.
Can produce in formula range on demand, not describe one by one herein.
Just the present invention will be further described for above-described embodiment, and its main purpose is to understand content of the present invention better.
Claims (2)
1. a liquid detergent, is made up of the component of following weight per-cent:
Tea saponin 15%, alkyl glycoside 25%, sodium alkyl sulfate 1.5%, dodecanamide propyl amine oxide 3%, sucrose fatty ester 4%, Flos Lonicerae extractive solution 6%, disodium EDTA 0.1%, potassium sorbate 0.05%, essence 0.2%, all the other are deionized water;
Its preparation process is: by above-mentioned formula, and deionized water joins in stirring tank, is first dissolved in deionized water by tea saponin, is heated to 45 DEG C and stirs; Add alkyl glycoside, sodium alkyl sulfate, dodecanamide propyl amine oxide, sucrose fatty ester, disodium EDTA while stirring; And by citric acid or aqueous sodium hydroxide solution adjusted to ph to 7.5, then the constant volume that adds water; Treat that solution is down to room temperature, continue to add Flos Lonicerae extractive solution, potassium sorbate and essence, obtain product.
2. a liquid detergent, is made up of the component of following weight per-cent:
Tea saponin 20%, alkyl glycoside 15%, sodium alkyl sulfate 1.5%, dodecanamide propyl amine oxide 7%, sucrose fatty ester 5%, Flos Lonicerae extractive solution 5%, disodium EDTA 0.1%, Sodium Benzoate 0.05%, essence 0.05%, all the other are deionized water;
Its preparation process is: by above-mentioned formula, and deionized water joins in stirring tank, is first dissolved in deionized water by tea saponin, is heated to 50 DEG C and stirs; Add alkyl glycoside, sodium alkyl sulfate, dodecanamide propyl amine oxide, sucrose fatty ester, disodium EDTA while stirring; Adjusted to ph to 7.5, then the constant volume that adds water; Treat that solution is down to room temperature, continue to add Flos Lonicerae extractive solution, Sodium Benzoate and essence, obtain product.
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| CN201310719550.4A CN103642602B (en) | 2013-12-20 | 2013-12-20 | A kind of liquid detergent |
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| CN201310719550.4A CN103642602B (en) | 2013-12-20 | 2013-12-20 | A kind of liquid detergent |
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| CN103642602B true CN103642602B (en) | 2015-08-19 |
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| CN106367216A (en) * | 2016-08-26 | 2017-02-01 | 华侨大学 | Tea saponin liquid detergent |
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| CN108130217A (en) * | 2017-12-04 | 2018-06-08 | 陈景英 | It is a kind of that there is the cleaning agent for dinnerware of handguard |
| CN108060027A (en) * | 2017-12-20 | 2018-05-22 | 陈景芳 | A kind of multifuctional cleaning agent |
| CN108624420A (en) * | 2018-06-21 | 2018-10-09 | 界首市洁净日用品有限公司 | A kind of concentration fruits and vegetables detergent powder and preparation method thereof containing modified activated carbon |
| CN111592944B (en) * | 2020-05-21 | 2021-07-27 | 上海毅诺生物科技有限公司 | Multi-surface cleaning agent containing tea saponin modified surfactant |
| CN113621447A (en) * | 2020-10-23 | 2021-11-09 | 湖南汉清生物技术有限公司 | Pollution-free dish washer is with imitateing tea saponin detergent by force and processing equipment thereof |
| CN112920910A (en) * | 2021-01-27 | 2021-06-08 | 赵宝华 | Liquid detergent formula |
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Effective date of registration: 20210309 Address after: 245000 No.7 Huangshan North Road, Haiyang Town, Xiuning County, Huangshan City, Anhui Province Patentee after: Anhui youqirun Health Technology Co.,Ltd. Address before: 245000 Huangshan North Road, Haiyang Town, Xiuning County, Huangshan City, Anhui Province Patentee before: HUANGSHAN HUISHAN BIOTECHNOLOGY Co.,Ltd. |