CN103725439B - A kind of preparation method of liquid detergent - Google Patents
A kind of preparation method of liquid detergent Download PDFInfo
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- CN103725439B CN103725439B CN201310712217.0A CN201310712217A CN103725439B CN 103725439 B CN103725439 B CN 103725439B CN 201310712217 A CN201310712217 A CN 201310712217A CN 103725439 B CN103725439 B CN 103725439B
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- liquid detergent
- deionized water
- tea saponin
- amine oxide
- propyl amine
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- 239000003599 detergent Substances 0.000 title claims abstract description 56
- 239000007788 liquid Substances 0.000 title claims abstract description 50
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- -1 alkyl glycoside Chemical class 0.000 claims abstract description 41
- ILRSCQWREDREME-UHFFFAOYSA-N dodecanamide Chemical compound CCCCCCCCCCCC(N)=O ILRSCQWREDREME-UHFFFAOYSA-N 0.000 claims abstract description 36
- WGYKZJWCGVVSQN-UHFFFAOYSA-N propylamine Chemical compound CCCN WGYKZJWCGVVSQN-UHFFFAOYSA-N 0.000 claims abstract description 36
- 239000001397 quillaja saponaria molina bark Substances 0.000 claims abstract description 25
- 229930182490 saponin Natural products 0.000 claims abstract description 25
- 150000007949 saponins Chemical class 0.000 claims abstract description 25
- 229930182470 glycoside Natural products 0.000 claims abstract description 17
- 238000003756 stirring Methods 0.000 claims description 28
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 27
- 241001122767 Theaceae Species 0.000 claims description 24
- 239000008367 deionised water Substances 0.000 claims description 20
- 229910021641 deionized water Inorganic materials 0.000 claims description 20
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 18
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 18
- 229910052708 sodium Inorganic materials 0.000 claims description 13
- 239000011734 sodium Substances 0.000 claims description 13
- 239000003109 Disodium ethylene diamine tetraacetate Substances 0.000 claims description 12
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 claims description 12
- 229930006000 Sucrose Natural products 0.000 claims description 12
- 235000019301 disodium ethylene diamine tetraacetate Nutrition 0.000 claims description 12
- 239000005720 sucrose Substances 0.000 claims description 12
- 241000628997 Flos Species 0.000 claims description 10
- CHHHXKFHOYLYRE-UHFFFAOYSA-M 2,4-Hexadienoic acid, potassium salt (1:1), (2E,4E)- Chemical compound [K+].CC=CC=CC([O-])=O CHHHXKFHOYLYRE-UHFFFAOYSA-M 0.000 claims description 5
- 239000004302 potassium sorbate Substances 0.000 claims description 5
- 235000010241 potassium sorbate Nutrition 0.000 claims description 5
- 229940069338 potassium sorbate Drugs 0.000 claims description 5
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 claims description 5
- 235000010234 sodium benzoate Nutrition 0.000 claims description 5
- 239000004299 sodium benzoate Substances 0.000 claims description 5
- 239000000463 material Substances 0.000 abstract description 12
- 230000000694 effects Effects 0.000 abstract description 9
- 231100000252 nontoxic Toxicity 0.000 abstract description 7
- 230000003000 nontoxic effect Effects 0.000 abstract description 7
- 239000002994 raw material Substances 0.000 abstract description 5
- 239000013543 active substance Substances 0.000 abstract description 4
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 4
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- 230000003385 bacteriostatic effect Effects 0.000 abstract description 3
- 235000009852 Cucurbita pepo Nutrition 0.000 abstract description 2
- 240000001980 Cucurbita pepo Species 0.000 abstract description 2
- 238000003912 environmental pollution Methods 0.000 abstract description 2
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- 244000269722 Thea sinensis Species 0.000 abstract 1
- 239000000047 product Substances 0.000 description 23
- 239000000243 solution Substances 0.000 description 18
- 238000005406 washing Methods 0.000 description 8
- 239000000126 substance Substances 0.000 description 7
- 230000008719 thickening Effects 0.000 description 7
- 238000004090 dissolution Methods 0.000 description 6
- 239000004094 surface-active agent Substances 0.000 description 5
- 239000003945 anionic surfactant Substances 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 239000006227 byproduct Substances 0.000 description 4
- 238000005202 decontamination Methods 0.000 description 4
- 230000003588 decontaminative effect Effects 0.000 description 4
- 238000004851 dishwashing Methods 0.000 description 4
- 230000002708 enhancing effect Effects 0.000 description 4
- 230000007613 environmental effect Effects 0.000 description 4
- 239000006260 foam Substances 0.000 description 4
- 238000005187 foaming Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical compound [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 4
- QYYMDNHUJFIDDQ-UHFFFAOYSA-N 5-chloro-2-methyl-1,2-thiazol-3-one;2-methyl-1,2-thiazol-3-one Chemical compound CN1SC=CC1=O.CN1SC(Cl)=CC1=O QYYMDNHUJFIDDQ-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- 241000931143 Gleditsia sinensis Species 0.000 description 3
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 230000036541 health Effects 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 231100000614 poison Toxicity 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 229910052938 sodium sulfate Inorganic materials 0.000 description 3
- 235000011152 sodium sulphate Nutrition 0.000 description 3
- 230000001954 sterilising effect Effects 0.000 description 3
- 238000004659 sterilization and disinfection Methods 0.000 description 3
- 239000003440 toxic substance Substances 0.000 description 3
- 206010040880 Skin irritation Diseases 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 230000003110 anti-inflammatory effect Effects 0.000 description 2
- 230000000711 cancerogenic effect Effects 0.000 description 2
- 231100000315 carcinogenic Toxicity 0.000 description 2
- 230000001804 emulsifying effect Effects 0.000 description 2
- 239000002085 irritant Substances 0.000 description 2
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- 210000003734 kidney Anatomy 0.000 description 2
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- 239000000344 soap Substances 0.000 description 2
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- 239000002699 waste material Substances 0.000 description 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
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- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- 240000003553 Leptospermum scoparium Species 0.000 description 1
- 235000015459 Lycium barbarum Nutrition 0.000 description 1
- 206010028980 Neoplasm Diseases 0.000 description 1
- ZMUQGGLSCIDPLS-UHFFFAOYSA-N Saponin 5 Natural products COC(=O)C1(C)CCC2(CCC3(C)C(=CCC4C5(C)CCC(OC6OC(CO)C(O)C(O)C6OC7OC(CO)C(O)C(O)C7OC8OC(C)C(O)C(O)C8O)C(C)(C)C5CCC34C)C2C1)C(=O)O ZMUQGGLSCIDPLS-UHFFFAOYSA-N 0.000 description 1
- 206010040867 Skin hypertrophy Diseases 0.000 description 1
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- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229940077388 benzenesulfonate Drugs 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
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- 238000002386 leaching Methods 0.000 description 1
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- 239000006210 lotion Substances 0.000 description 1
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- 235000012054 meals Nutrition 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
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- 230000003020 moisturizing effect Effects 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 229920000191 poly(N-vinyl pyrrolidone) Polymers 0.000 description 1
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- Detergent Compositions (AREA)
Abstract
The present invention relates to a kind of preparation method of liquid detergent, this liquid detergent mainly adopts natural and green safety tensio-active agent tea saponin, alkyl glycoside, and dodecanamide propyl amine oxide is raw material.The present invention is compared with the liquid detergent based on petrochemical materials, raw material sources very abundant and belong to renewable resources, be nontoxic gentle material, without any side effects to human body, this liquid detergent has good antibacterial bacteriostatic function, strong detergency, free from environmental pollution, the features such as use safety, have good wash dining set and the effect of gourd, fruit and vegetable, thus adapt to different consumer demand, can suitability for industrialized production be realized.
Description
Technical field
The present invention relates to a kind of articles for washing, specifically a kind of preparation method of liquid detergent, belong to daily-use chemical industry washing composition technical field.
Background technology
Society is along with the enhancing of environmental consciousness, and people propose three large basic demands in the pursuit to the clean product of Novel washing: Green Product; Use safety, do not hinder the neutral products of hand; High detersive power product.Health safety issues for many years involved by detergent for tableware series products more and more causes the concern of people.The chemical residual of liquid detergent likely affects HUMAN HEALTH directly or indirectly.Therefore use not harmful to human, do not destroy living environment, the liquid detergent of non-toxic and non-pollution green safety just becomes the task of top priority.The industrially developed country such as current Europe, the U.S., Japan are in the selection of liquid detergent main ingredient, pay close attention to environmental safety, the security of composition selected by it to HUMAN HEALTH and ecotope is better than the developing countries such as South East Asia, more obviously be better than the liquid detergent main component that China is current, slower in the development of China's Environmental Protection in China type dish washing detergent.Along with the progressively enhancing of people's environmental consciousness, the developing direction in dish washing detergent future will be for main flow with environment-friendly and green type.
Through verification pertinent literature, Chinese Patent Application No. 01134178.5 discloses a kind of natural detergent, adds a small amount of soluble perfume mixing match form by Chinese honey locust leaching cream and tea saponin crystal." family's herbal medicine handbook " Guangzhou press publishes in January, 2002, learns that Chinese honey locust has few poison, valetudinarian, invalid and contraindication in pregnancy.With the liquid detergent that Chinese honey locust is made as starting material, for wash dining set or fruit, difficulty washes down residual poison, if there is drink by mistake, consequence is by hardly imaginable.Chinese Patent Application No. 201210241913.3 discloses a kind of liquid detergent containing tea saponin, containing polyoxyethylenated alcohol sodium sulfate in this liquid detergent, diox by product diox can be produced in the process of production polyoxyethylenated alcohol sodium sulfate and belong to toxic substance, can be irritant to skin, eye and respiratory system, and may cause damage to liver, kidney and neural system, life-time service also may be carcinogenic.Wherein tea saponin content is 1% ~ 4%, and consumption has been washing assistant effect less, instead of main component.
The maximum liquid detergent main component of current application is Oil derivative instruments sodium alkyl benzene sulfonate (LAS) and aliphatic alcohol polyethenoxy sodium sulfate (AES), and because they are water-soluble, cost is low, and scourability is good, thus its essence always out in the cold fall.According to relevant report, artificial experiment is cultivated stomach cancer cell, is injected the deterioration that soapless soap base substance LAS can accelerate cancer cells.The blood dissolubility of LAS is also very strong, easily causes the change of oxyphorase, causes anemia.Diox by product ， diox can be produced in the process of production AES and belong to toxic substance, can be irritant to skin, eye and respiratory system, and may cause damage to liver, kidney and neural system, life-time service also may be carcinogenic.
Family expenses liquid detergent pH value should be neutral or slight alkalinity.Excellent removes oiliness, emulsifying property, wettability; To skin action temperature and; Good foaming power; Biological degradability is good; Soltion viscosity is easy to regulate; To human non-toxic." household chemicals " Chemical Industry Press publishes in January, 2008, learn that tensio-active agent to the pungency of skin generally: cats product > anion surfactant > amphoteric ionic surfactant ≈ nonionogenic tenside, actives nonionogenic tenside conventional in synthetic detergent does not all have carcinogenesis, and thus liquid detergent selects nonionogenic tenside more safer than anion surfactant.
Because tea saponin is natural green product, belong to nonionogenic tenside, there is the performances such as good emulsifying, dispersion, foaming, decontamination, wetting, sterilization, anti-inflammatory, itself easy biological degradation does not pollute the environment, performance is soft, the aqueous solution is subacidity, is that the liquid detergent that tensio-active agent is made into meets the demand of human consumer to green safety with tea saponin.From social effect, extraction and the exploitation of tea saponin fundamentally embody the green chemical industry system turned waste into wealth, and decrease the pollution of grouts accumulation to environment.From production source, about there is fifty-five million mu mountain region in China for planting tea tree, and the by product tea waste obtained after annual tea seed oil expression about has 500,000 tons, produces provide rich in natural resources for tea saponin.From economic benefit, the excellent property of tea saponin, is widely used, and has wide market outlook, and it had both met the needs of human consumer to natural green product, simultaneously again for manufacturer creates good economic benefit.
Summary of the invention
The object of the invention is to overcome above-mentioned weak point, provide a kind of without any side effects, have certain antibacterial and bacteriostasis, the liquid detergent of the high-grade green safety of high-content tea saponin.
The object of the invention is to be realized by following scheme:
A liquid detergent for high-grade green safety containing tea saponin, is characterized in that being made up of the component of following weight per-cent:
Above-mentioned each component concentration percentage ratio sum equals 100%.
A kind of liquid detergent, comprises by the component of following weight per-cent:
Tea saponin 5 ~ 20%; Alkyl glycoside 15 ~ 25%; The dodecanamide propyl amine oxide of 1 ~ 10%; All the other are water.
In order to better thickening foam stabilizing effect, described component also comprises the sucrose fatty ester that weight percent is no more than 6%.
Stable in order to better decontamination foaming effect and foaming, described component also comprise weight percent be no more than 3% sodium alkyl sulfate, be no more than 0.1% disodium EDTA.
In order to improve product quality, improving product outward appearance, described component also comprise weight percent be no more than 8% Flos Lonicerae extractive solution, be no more than the essence of 0.2%, be no more than potassium sorbate, Sodium Benzoate or the Kathon CG of 0.15%.
The preparation method of described liquid detergent, by described weight percent, tea saponin is dissolved in deionized water, be heated to 40 ~ 50 DEG C, add alkyl glycoside, dodecanamide propyl amine oxide at this temperature while stirring, stir, with citric acid or aqueous sodium hydroxide solution adjusted to ph to 6 ~ 7.5, obtain product.
Preferably, while adding alkyl glycoside, dodecanamide propyl amine oxide, the sucrose fatty ester being no more than 6% is added.
Preferably, add while adding alkyl glycoside be no more than 3% sodium alkyl sulfate, be no more than 0.1% disodium EDTA.
Be more preferably, tea saponin is dissolved in deionized water, be heated to 40 ~ 50 DEG C, add alkyl glycoside, dodecanamide propyl amine oxide at this temperature while stirring, stir, until solution be down to continue to add after room temperature the Flos Lonicerae extractive solution being no more than 8%, the essence being no more than 0.2%, be no more than 0.15% potassium sorbate, Sodium Benzoate or Kathon CG.
Alkyl glycoside APG, synthesized by renewable resources natural fat alcohol and glucose, it is the more comprehensive new non-ionic surfactants of a kind of performance, have the characteristic of conventional nonionic and anion surfactant concurrently, having high surface, good ecological security and intermiscibility, is internationally recognized first-selection " green " functional surfactant.APG is nontoxic, safety little to skin irritation, and thickening, thickening, detersive power are remarkable, can generation synergism composite with various nonionic surface active agent, and APG is not in Product Safety (containing harmful by-products dioxan), and mildness and germ resistance have advantage.With APG Substitute For Partial AES, LAS, 6501, AEO, peregal, K12, AOS preparation meal lotion Be very effective.The washing composition be made up of APG has good solubility, mildness, nontoxic and easily rinsing.APG as a kind of cosurfactant, and can not only be more suitable for for making principal surfactant in dish washing detergent.
Dodecanamide propyl amine oxide is a kind of special nonionogenic tenside, has the character of amphoterics.There is good thickening and antistatic, soft, foam enhancing, steady bubble and detergency ability; Also there is sterilization, lime soap dispersing power, and biological degradability is good, belongs to environment-friendly type daily chemical products.Dodecanamide propyl amine oxide is then mainly used in all kinds of transparent liquid washings, as dish washing detergent, bath wash dew wait formula in as foam enhancing, suds-stabilizing agent, the consistency of thickening material and the resistance to overturning of product can be improved.Dodecanamide propyl amine oxide to skin as mild as a dove, as during as moisturizing, can give skin smooth comfort.It is compared with traditional thickening material 6501, has low-consuming, that security is high, efficiency is high, wettability is good, detergency is strong feature.
Sodium alkyl sulfate is a kind of anion surfactant of excellent property, has good decontamination washing, foam performance, safety non-toxic, is now widely used in the daily chemical products such as toothpaste.
Sucrose fatty ester is edible nonionogenic tenside prepared by a kind of natural matter, can be widely used in foodstuffs industry, can play the effect that thickening is surely steeped in this formulation product.
Disodium EDTA is a kind of complexing of metal ion agent and antioxidant synergist, stablizer of conventional safety.
Flos Lonicerae extractive solution has removing toxic substances, anti-inflammatory, virus killing, sterilization and antipruritic effect, especially has certain restraining effect to streptococcus aureus, intestinal bacteria etc.
Tableware detergent prepared by the present invention has strong detergency, and viscosity is suitable for, good appearance, Phosphateless environmentally friendly, the advantage of safety; PH value is than now commercially product is low simultaneously, little to skin irritation; And raw material sources are wide, simple process, without particular requirement, is easy to industrialization.In formula, all surface promoting agent is the tensio-active agent of green safety, and many has selected nonionogenic tenside, therefore safer, gentle.Tea saponin simultaneously under this formula is as main component, can play good decontamination washing and antibacterial bacteriostatic function.There is good wash dining set and the effect of gourd, fruit and vegetable, without any side effects.
The liquid detergent of green safety prepared by the present invention is compared with existing liquid detergent, formula rationally, wherein natural safety surface promoting agent tea saponin and green safety Surfactants Alkyl content very high, play primary surfactant, raw material sources very abundant and belong to renewable resources, raw materials usedly be green safety material, be nontoxic gentle material, without any side effects to human body, this liquid detergent has good antibacterial bacteriostatic function, strong detergency, free from environmental pollution, use safety, well meet the demand of current human consumer to green safety, therefore have good value for applications.
Embodiment
The liquid detergent of embodiment 1 one kinds of green safeties
It adopts following formula:
Above-mentioned each component concentration percentage ratio sum equals 100%.
Being prepared as of described liquid detergent: joined by deionized water in stirring tank, by described weight percent configuration 100g liquid detergent, be dissolved in deionized water by tea saponin 10g, be heated to 50 DEG C, heated and stirred is even.After material dissolution, add alkyl glycoside 20g, dodecanamide propyl amine oxide 6g at this temperature while stirring, stir, with citric acid or aqueous sodium hydroxide solution adjustment pH to 6.5, add deionized water and be settled to 100g, treat that solution is down to room temperature, obtain product.
The liquid detergent of embodiment 2 one kinds of green safeties
It adopts following formula:
Above-mentioned each component concentration percentage ratio sum equals 100%.
Being prepared as of described liquid detergent: joined by water in stirring tank, by described weight percent configuration 100g liquid detergent, be dissolved in deionized water by tea saponin 10g, be heated to 45 DEG C, heated and stirred is even.After material dissolution, add alkyl glycoside 20g, sodium alkyl sulfate 1g, dodecanamide propyl amine oxide 6g, sucrose fatty ester 5g, disodium EDTA 0.1g at this temperature while stirring, stir, by citric acid or aqueous sodium hydroxide solution adjusted to ph to 6, add water and be settled to 100g, treat that solution is down to room temperature, obtain product.
The liquid detergent of embodiment 3 one kinds of green safeties
It adopts following formula:
Above-mentioned each component concentration percentage ratio sum equals 100%.
Being prepared as of described liquid detergent: joined by deionized water in stirring tank, by described weight percent configuration 100g liquid detergent, be dissolved in deionized water by tea saponin 10g, be heated to 40 DEG C, heated and stirred is even.After material dissolution, add alkyl glycoside 20g, sodium alkyl sulfate 1g, dodecanamide propyl amine oxide 6g, sucrose fatty ester 5g, disodium EDTA 0.1g at this temperature while stirring, stir, by citric acid or aqueous sodium hydroxide solution adjusted to ph to 6, add water and be settled to 100g, treat that solution is down to room temperature, obtain product.
The liquid detergent of embodiment 4 one kinds of green safeties
It adopts following formula:
Above-mentioned each component concentration percentage ratio sum equals 100%.
Being prepared as of described liquid detergent: joined by deionized water in stirring tank, by described weight percent configuration 100g liquid detergent, be dissolved in deionized water by tea saponin 15g, be heated to 45 DEG C, heated and stirred is even.After material dissolution, add alkyl glycoside 25g, sodium alkyl sulfate 1.5g, dodecanamide propyl amine oxide 3g, sucrose fatty ester 4g, disodium EDTA 0.1g at this temperature while stirring, stir, by citric acid or aqueous sodium hydroxide solution adjusted to ph to 7.5, add water and be settled to 100g, treat that solution is down to room temperature, continue to add Flos Lonicerae extractive solution 6g, essence 0.2g, potassium sorbate 0.05g, obtain product.
The liquid detergent of embodiment 5 one kinds of green safeties
It adopts following formula:
Above-mentioned each component concentration percentage ratio sum equals 100%.
Being prepared as of described liquid detergent: joined by deionized water in stirring tank, by described weight percent configuration 100g liquid detergent, be dissolved in deionized water by tea saponin 20g, be heated to 50 DEG C, heated and stirred is even.After material dissolution, add alkyl glycoside 15g, sodium alkyl sulfate 1.5g, dodecanamide propyl amine oxide 7g, sucrose fatty ester 5g, disodium EDTA 0.1g at this temperature while stirring, stir, adjusted to ph to 7.5, be down to after room temperature until solution and continue to add Flos Lonicerae extractive solution 5g, essence 0.05g, Sodium Benzoate 0.05g, obtain product.
The liquid detergent of embodiment 6 one kinds of high-grade green safeties
It adopts following formula:
Above-mentioned each component concentration percentage ratio sum equals 100%.
Being prepared as of described liquid detergent: joined by deionized water in stirring tank, by described weight percent configuration 100g liquid detergent, be dissolved in deionized water by tea saponin 5g, be heated to 50 DEG C, heated and stirred is even.After material dissolution, add alkyl glycoside 25g, sodium alkyl sulfate 3g, dodecanamide propyl amine oxide 8g, sucrose fatty ester 2g, disodium EDTA 0.1g at this temperature while stirring, stir, adjusted to ph to 7.5, be down to after room temperature until solution and continue to add Flos Lonicerae extractive solution 6g, essence 0.01g, Kathon CG 0.15g, obtain product.
Can produce in formula range on demand, not describe one by one herein.
Just the present invention will be further described for above-described embodiment, and its main purpose is to understand content of the present invention better.
Claims (2)
1. a preparation method for liquid detergent, its preparation process is:
By the formula of liquid detergent, deionized water joins in stirring tank, is first dissolved in deionized water by tea saponin, is heated to 45 DEG C and stirs; Add alkyl glycoside, sodium alkyl sulfate, dodecanamide propyl amine oxide, sucrose fatty ester, disodium EDTA while stirring; And by citric acid or aqueous sodium hydroxide solution adjusted to ph to 7.5, then the constant volume that adds water; Treat that solution is down to room temperature, continue to add Flos Lonicerae extractive solution, potassium sorbate and essence, obtain product;
Wherein, described liquid detergent is made up of the component of following weight per-cent: tea saponin 15%, alkyl glycoside 25%, sodium alkyl sulfate 1.5%, dodecanamide propyl amine oxide 3%, sucrose fatty ester 4%, Flos Lonicerae extractive solution 6%, disodium EDTA 0.1%, potassium sorbate 0.05%, essence 0.2%, all the other are deionized water.
2. a preparation method for liquid detergent, its preparation process is:
By liquid detergent formula, deionized water joins in stirring tank, is first dissolved in deionized water by tea saponin, is heated to 50 DEG C and stirs; Add alkyl glycoside, sodium alkyl sulfate, dodecanamide propyl amine oxide, sucrose fatty ester, disodium EDTA while stirring; Adjusted to ph to 7.5, then the constant volume that adds water; Treat that solution is down to room temperature, continue to add Flos Lonicerae extractive solution, Sodium Benzoate and essence, obtain product;
Wherein, described liquid detergent is made up of the component of following weight per-cent: tea saponin 20%, alkyl glycoside 15%, sodium alkyl sulfate 1.5%, dodecanamide propyl amine oxide 7%, sucrose fatty ester 5%, Flos Lonicerae extractive solution 5%, disodium EDTA 0.1%, Sodium Benzoate 0.05%, essence 0.05%, all the other are deionized water.
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| CN105255596B (en) * | 2015-10-29 | 2018-07-10 | 广州赛莱拉生物基因工程有限公司 | A kind of Antibiotic liquid detergent containing Folium Artemisiae Argyi extract |
| CN105482915A (en) * | 2016-02-01 | 2016-04-13 | 东莞品派实业投资有限公司 | Skin-protecting bactericidal cleanser essence |
| CN106086902A (en) * | 2016-08-05 | 2016-11-09 | 宁波高新区斯汀环保科技有限公司 | A kind of preparation method of environmental type water base metal cleaning agent |
| CN108130217A (en) * | 2017-12-04 | 2018-06-08 | 陈景英 | It is a kind of that there is the cleaning agent for dinnerware of handguard |
| CN107955738A (en) * | 2017-12-04 | 2018-04-24 | 湖南金昌生物技术有限公司 | A kind of Tea Saponin neutrality vegetables and fruits cleaning agent and preparation method thereof |
| CN113621447A (en) * | 2020-10-23 | 2021-11-09 | 湖南汉清生物技术有限公司 | Pollution-free dish washer is with imitateing tea saponin detergent by force and processing equipment thereof |
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| CN102010798A (en) * | 2010-11-27 | 2011-04-13 | 郴州邦尔泰苏仙油脂有限公司 | Detergent for washing tableware or vegetables and fruits by hands |
| CN102517160A (en) * | 2011-12-07 | 2012-06-27 | 广州青能健日用品有限公司 | Biological environment-friendly antioxidant abluent and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102010798A (en) * | 2010-11-27 | 2011-04-13 | 郴州邦尔泰苏仙油脂有限公司 | Detergent for washing tableware or vegetables and fruits by hands |
| CN102517160A (en) * | 2011-12-07 | 2012-06-27 | 广州青能健日用品有限公司 | Biological environment-friendly antioxidant abluent and preparation method thereof |
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Effective date of registration: 20240612 Address after: 245400 Haiyang Town Mount Huangshan North Road, Xiuning County, Mount Huangshan City, Anhui Province Patentee after: HUANGSHAN HUISHAN EDIBLE OIL Co.,Ltd. Country or region after: China Address before: 245000 No.7 Huangshan North Road, Haiyang Town, Xiuning County, Huangshan City, Anhui Province Patentee before: Anhui youqirun Health Technology Co.,Ltd. Country or region before: China |