CN103725439A - Preparation method of liquid detergent - Google Patents
Preparation method of liquid detergent Download PDFInfo
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- CN103725439A CN103725439A CN201310712217.0A CN201310712217A CN103725439A CN 103725439 A CN103725439 A CN 103725439A CN 201310712217 A CN201310712217 A CN 201310712217A CN 103725439 A CN103725439 A CN 103725439A
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- liquid detergent
- add
- detergent
- preparation
- tea saponin
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- 239000003599 detergent Substances 0.000 title claims abstract description 57
- 239000007788 liquid Substances 0.000 title claims abstract description 49
- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- -1 alkyl glycoside Chemical class 0.000 claims abstract description 35
- 241001122767 Theaceae Species 0.000 claims abstract description 23
- 239000001397 quillaja saponaria molina bark Substances 0.000 claims abstract description 22
- 229930182490 saponin Natural products 0.000 claims abstract description 22
- 150000007949 saponins Chemical class 0.000 claims abstract description 22
- 229930182470 glycoside Natural products 0.000 claims abstract description 17
- ILRSCQWREDREME-UHFFFAOYSA-N dodecanamide Chemical compound CCCCCCCCCCCC(N)=O ILRSCQWREDREME-UHFFFAOYSA-N 0.000 claims description 32
- WGYKZJWCGVVSQN-UHFFFAOYSA-N propylamine Chemical compound CCCN WGYKZJWCGVVSQN-UHFFFAOYSA-N 0.000 claims description 32
- 238000003756 stirring Methods 0.000 claims description 26
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 21
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 18
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 18
- 239000008367 deionised water Substances 0.000 claims description 16
- 229910021641 deionized water Inorganic materials 0.000 claims description 16
- 229910052708 sodium Inorganic materials 0.000 claims description 10
- 239000011734 sodium Substances 0.000 claims description 10
- 239000003109 Disodium ethylene diamine tetraacetate Substances 0.000 claims description 9
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 claims description 9
- 229930006000 Sucrose Natural products 0.000 claims description 9
- 235000019301 disodium ethylene diamine tetraacetate Nutrition 0.000 claims description 9
- 239000005720 sucrose Substances 0.000 claims description 9
- 241000628997 Flos Species 0.000 claims description 7
- CHHHXKFHOYLYRE-UHFFFAOYSA-M 2,4-Hexadienoic acid, potassium salt (1:1), (2E,4E)- Chemical compound [K+].CC=CC=CC([O-])=O CHHHXKFHOYLYRE-UHFFFAOYSA-M 0.000 claims description 4
- QYYMDNHUJFIDDQ-UHFFFAOYSA-N 5-chloro-2-methyl-1,2-thiazol-3-one;2-methyl-1,2-thiazol-3-one Chemical compound CN1SC=CC1=O.CN1SC(Cl)=CC1=O QYYMDNHUJFIDDQ-UHFFFAOYSA-N 0.000 claims description 4
- 239000004302 potassium sorbate Substances 0.000 claims description 4
- 235000010241 potassium sorbate Nutrition 0.000 claims description 4
- 229940069338 potassium sorbate Drugs 0.000 claims description 4
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 claims description 4
- 235000010234 sodium benzoate Nutrition 0.000 claims description 4
- 239000004299 sodium benzoate Substances 0.000 claims description 4
- ZMUQGGLSCIDPLS-UHFFFAOYSA-N Saponin 5 Natural products COC(=O)C1(C)CCC2(CCC3(C)C(=CCC4C5(C)CCC(OC6OC(CO)C(O)C(O)C6OC7OC(CO)C(O)C(O)C7OC8OC(C)C(O)C(O)C8O)C(C)(C)C5CCC34C)C2C1)C(=O)O ZMUQGGLSCIDPLS-UHFFFAOYSA-N 0.000 claims description 2
- 239000012467 final product Substances 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 14
- 230000000694 effects Effects 0.000 abstract description 11
- 231100000252 nontoxic Toxicity 0.000 abstract description 7
- 230000003000 nontoxic effect Effects 0.000 abstract description 7
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 4
- 239000002994 raw material Substances 0.000 abstract description 4
- 239000004094 surface-active agent Substances 0.000 abstract description 4
- 238000003912 environmental pollution Methods 0.000 abstract description 2
- 235000012055 fruits and vegetables Nutrition 0.000 abstract description 2
- 231100000331 toxic Toxicity 0.000 abstract description 2
- 230000002588 toxic effect Effects 0.000 abstract description 2
- JNGWKQJZIUZUPR-UHFFFAOYSA-N [3-(dodecanoylamino)propyl](hydroxy)dimethylammonium Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)[O-] JNGWKQJZIUZUPR-UHFFFAOYSA-N 0.000 abstract 1
- 238000004140 cleaning Methods 0.000 abstract 1
- 238000009776 industrial production Methods 0.000 abstract 1
- 239000000047 product Substances 0.000 description 23
- 239000000243 solution Substances 0.000 description 18
- 239000000126 substance Substances 0.000 description 7
- 238000005406 washing Methods 0.000 description 7
- 238000004090 dissolution Methods 0.000 description 6
- 230000008719 thickening Effects 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 5
- 239000013543 active substance Substances 0.000 description 4
- 239000003945 anionic surfactant Substances 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 239000006227 byproduct Substances 0.000 description 4
- 238000005202 decontamination Methods 0.000 description 4
- 230000003588 decontaminative effect Effects 0.000 description 4
- 238000004851 dishwashing Methods 0.000 description 4
- 230000002708 enhancing effect Effects 0.000 description 4
- 230000007613 environmental effect Effects 0.000 description 4
- 238000005187 foaming Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 230000001737 promoting effect Effects 0.000 description 4
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical compound [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- 241000931143 Gleditsia sinensis Species 0.000 description 3
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 3
- 239000006260 foam Substances 0.000 description 3
- 230000036541 health Effects 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 231100000614 poison Toxicity 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 229910052938 sodium sulfate Inorganic materials 0.000 description 3
- 235000011152 sodium sulphate Nutrition 0.000 description 3
- 230000001954 sterilising effect Effects 0.000 description 3
- 238000004659 sterilization and disinfection Methods 0.000 description 3
- 239000003440 toxic substance Substances 0.000 description 3
- 206010040880 Skin irritation Diseases 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 230000003110 anti-inflammatory effect Effects 0.000 description 2
- 230000003385 bacteriostatic effect Effects 0.000 description 2
- 230000000711 cancerogenic effect Effects 0.000 description 2
- 231100000315 carcinogenic Toxicity 0.000 description 2
- 230000001804 emulsifying effect Effects 0.000 description 2
- 239000002085 irritant Substances 0.000 description 2
- 231100000021 irritant Toxicity 0.000 description 2
- 210000003734 kidney Anatomy 0.000 description 2
- 210000004185 liver Anatomy 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 230000001537 neural effect Effects 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- 239000002574 poison Substances 0.000 description 2
- 210000002345 respiratory system Anatomy 0.000 description 2
- 230000036556 skin irritation Effects 0.000 description 2
- 231100000475 skin irritation Toxicity 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- 231100000167 toxic agent Toxicity 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 208000005623 Carcinogenesis Diseases 0.000 description 1
- 235000009024 Ceanothus sanguineus Nutrition 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- 235000009852 Cucurbita pepo Nutrition 0.000 description 1
- 240000001980 Cucurbita pepo Species 0.000 description 1
- 241000282326 Felis catus Species 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- 240000003553 Leptospermum scoparium Species 0.000 description 1
- 235000015459 Lycium barbarum Nutrition 0.000 description 1
- 206010028980 Neoplasm Diseases 0.000 description 1
- 241000191967 Staphylococcus aureus Species 0.000 description 1
- 208000005718 Stomach Neoplasms Diseases 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 241000700605 Viruses Species 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 208000007502 anemia Diseases 0.000 description 1
- 230000001139 anti-pruritic effect Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229940077388 benzenesulfonate Drugs 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- 239000010495 camellia oil Substances 0.000 description 1
- 201000011510 cancer Diseases 0.000 description 1
- 230000036952 cancer formation Effects 0.000 description 1
- 231100000504 carcinogenesis Toxicity 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000000536 complexating effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000004064 cosurfactant Substances 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
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- 238000000605 extraction Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 206010017758 gastric cancer Diseases 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 150000002338 glycosides Chemical class 0.000 description 1
- 241000411851 herbal medicine Species 0.000 description 1
- 239000003845 household chemical Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 230000000968 intestinal effect Effects 0.000 description 1
- 239000002563 ionic surfactant Substances 0.000 description 1
- 230000002147 killing effect Effects 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 235000012054 meals Nutrition 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000003020 moisturizing effect Effects 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 229920000191 poly(N-vinyl pyrrolidone) Polymers 0.000 description 1
- 230000035935 pregnancy Effects 0.000 description 1
- 235000019633 pungent taste Nutrition 0.000 description 1
- 230000000452 restraining effect Effects 0.000 description 1
- 230000000192 social effect Effects 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 201000011549 stomach cancer Diseases 0.000 description 1
- 239000000271 synthetic detergent Substances 0.000 description 1
- 229940034610 toothpaste Drugs 0.000 description 1
- 239000000606 toothpaste Substances 0.000 description 1
- 238000012795 verification Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
Abstract
The invention relates to a preparation method of a liquid detergent. The liquid detergent mainly comprises raw materials of lauramidopropyl dimethylamine oxide, and natural, green and safe surfactants including tea saponin and alkyl glycoside. Compared with a liquid detergent adopting petrochemical materials as main materials, the liquid detergent disclosed by the invention is abundant in material source, belongs to renewable resources, is a non-toxic mild material, and is free of toxic and side effects on a human body. The liquid detergent has a useful antibacterial function, is strong in detergency, free of environmental pollution, and safe to use, has a good effect on cleaning tableware, and fruits and vegetables, and the like, so that the detergent can adapt to the requirements of different consumers, the industrial production of the detergent can be achieved.
Description
Technical field
The present invention relates to a kind of articles for washing, a kind of preparation method of liquid detergent specifically, belongs to daily-use chemical industry washing composition technical field.
Background technology
Society is along with the enhancing of environmental consciousness, and people have proposed three large basic demands on to the pursuit of the clean product of Novel washing: Green Product; Use neutral products safe, that do not hinder hand; High detersive power product.The related health safety issues of detergent for tableware series products more and more causes people's concern for many years.The chemical residual of liquid detergent likely affects HUMAN HEALTH directly or indirectly.Therefore the liquid detergent that use harmful to human not, does not destroy living environment, non-toxic and non-pollution green safety just becomes the task of top priority.The industrially developed country such as current Europe, the U.S., Japan are aspect the selection of liquid detergent main ingredient, pay close attention to environmental safety, its selected composition is better than the developing countries such as South East Asia to the security of HUMAN HEALTH and ecotope, more obviously be better than the current liquid detergent main component of China, slower in the development of China's Environmental Protection in China type dish washing detergent.Along with the progressively enhancing of people's environmental consciousness, the developing direction in dish washing detergent future will be take environment-friendly and green type as main flow.
Through verification pertinent literature, Chinese Patent Application No. 01134178.5 discloses a kind of natural detergent, by Chinese honey locust leaching cream and tea saponin crystal, adds a small amount of soluble perfume mixing match to form.The herbal medicine handbook > > of < < family Guangzhou press publishes in January, 2002, learns that Chinese honey locust has few poison, valetudinarian, invalid and contraindication in pregnancy.The liquid detergent of making as starting material with Chinese honey locust, for wash dining set or fruit, difficulty washes down residual poison, if there is mistake drink, consequence is by hardly imaginable.Chinese Patent Application No. 201210241913.3 discloses a kind of liquid detergent that contains tea saponin, in this liquid detergent, contain polyoxyethylenated alcohol sodium sulfate, in the process of production polyoxyethylenated alcohol sodium sulfate, can produce diox by product diox and belong to toxic substance, can be irritant to skin, eye and respiratory system, and may cause damage to liver, kidney and neural system, life-time service also may be carcinogenic.Wherein tea saponin content is 1%～4%, and consumption has been washing assistant effect less, rather than main component.
At present the maximum liquid detergent main component of application is Oil derivative instruments sodium alkyl benzene sulfonate (LAS) and aliphatic alcohol polyethenoxy sodium sulfate (AES), and because they are water-soluble, cost is low, and scourability is good, thus its essence always out in the cold fall.According to relevant report, stomach cancer cell is cultivated in artificial experiment, injection soapless soap base substance LAS can accelerate the deterioration of cancer cells.The blood dissolubility of LAS is also very strong, easily causes the variation of oxyphorase, causes anemia.In the process of production AES, can produce diox by product ， diox and belong to toxic substance, can be irritant to skin, eye and respiratory system, and may cause damage to liver, kidney and neural system, life-time service also may be carcinogenic.
Family expenses liquid detergent pH value should be neutrality or slight alkalinity.Good in oiliness, emulsifying property, wettability; To skin action temperature and; Good foaming power; Biological degradability is good; Soltion viscosity is easy to regulate; Nontoxic to human body.< < household chemicals > > Chemical Industry Press publishes in January, 2008, learn that tensio-active agent to the pungency of skin generally: cats product > anion surfactant > amphoteric ionic surfactant ≈ nonionogenic tenside, actives nonionogenic tenside conventional in synthetic detergent does not all have carcinogenesis, thereby liquid detergent selects nonionogenic tenside more safer than anion surfactant.
Because tea saponin is natural green product, belong to nonionogenic tenside, there is the performances such as good emulsifying, dispersion, foaming, decontamination, wetting, sterilization, anti-inflammatory, itself easy biological degradation does not pollute the environment, performance is soft, the aqueous solution is subacidity, and the liquid detergent being made into take tea saponin as tensio-active agent meets the demand of human consumer to green safety.From social effect, the extraction of tea saponin and exploitation have fundamentally embodied the green chemical industry system turning waste into wealth, and have reduced grouts and have piled up the pollution to environment.From producing source, approximately there is fifty-five million mu mountain region in China for planting tea tree, and the by product tea waste obtaining after annual tea seed oil expression approximately has 500,000 tons, for tea saponin, produces rich in natural resources is provided.From economic benefit, the excellent property of tea saponin, is widely used, and has wide market outlook, and it had both met the needs of human consumer to natural green product, simultaneously again for manufacturer has created good economic benefit.
Summary of the invention
The object of the invention is to overcome above-mentioned weak point, a kind of without any side effects, liquid detergent with high-grade green safety certain antibacterial and bacteriostasis, high-content tea saponin is provided.
The object of the invention is to realize by following scheme:
A liquid detergent for the high-grade green safety that contains tea saponin, is characterized in that being comprised of the component of following weight per-cent:
Above-mentioned each component concentration percentage ratio sum equals 100%.
A kind of liquid detergent, comprises the component by following weight per-cent:
Tea saponin 5～20%; Alkyl glycoside 15～25%; 1～10% dodecanamide propyl amine oxide; All the other are water.
For better thickening, surely steep effect, described component also comprises that weight percent is no more than 6% sucrose fatty ester.
Stable for better decontamination foaming effect and foaming, described component also comprises that weight percent is no more than 3% sodium alkyl sulfate, is no more than 0.1% disodium EDTA.
In order to improve product quality, improving product outward appearance, described component also comprises that weight percent is no more than 8% Flos Lonicerae extractive solution, is no more than 0.2% essence, is no more than 0.15% potassium sorbate, Sodium Benzoate or Kathon CG.
The preparation method of described liquid detergent, by described weight percent, tea saponin is dissolved in deionized water, be heated to 40～50 ℃, at this temperature, add while stirring alkyl glycoside, dodecanamide propyl amine oxide, stir, with citric acid or aqueous sodium hydroxide solution, adjust pH value to 6～7.5, obtain product.
Preferably, when adding alkyl glycoside, dodecanamide propyl amine oxide, add the sucrose fatty ester that is no more than 6%.
Preferably, when adding alkyl glycoside, add and be no more than 3% sodium alkyl sulfate, be no more than 0.1% disodium EDTA.
Be more preferably, tea saponin is dissolved in deionized water, be heated to 40～50 ℃, at this temperature, add while stirring alkyl glycoside, dodecanamide propyl amine oxide, stir, after solution is down to room temperature, continue to add to be no more than 8% Flos Lonicerae extractive solution, to be no more than 0.2% essence, to be no more than 0.15% potassium sorbate, Sodium Benzoate or Kathon CG.
Alkyl glycoside APG, synthetic by renewable resources natural fat alcohol and glucose, it is the more comprehensive new non-ionic surfactants of a kind of performance, have the characteristic of common nonionic and anion surfactant concurrently, having high surface, good ecological security and intermiscibility, is internationally recognized first-selection " green " functional surface promoting agent.APG is nontoxic,, safety little to skin irritation, thickening, tackify, detersive power are remarkable, can with the composite generation synergism of various nonionic surface active agent, APG is in Product Safety (not containing toxic byproduct dioxan), mildness and germ resistance have advantage.With APG Substitute For Partial AES, LAS, 6501, AEO, peregal, K12, AOS, prepare meal lotion effect remarkable.The washing composition of being made by APG has good solubility, mildness, nontoxic and easily rinsing.APG can not only be served as a kind of cosurfactant, and is more suitable for making main tensio-active agent for dish washing detergent.
Dodecanamide propyl amine oxide is a kind of special nonionogenic tenside, has the character of amphoterics.There is good thickening and antistatic, soft, foam enhancing, surely bubble and detergency ability; Also there is sterilization, lime soap dispersing power, and biological degradability is good, belongs to environment-friendly type daily chemical products.Dodecanamide propyl amine oxide is mainly used in all kinds of transparent liquid washingss, as dish washing detergent, bathe wash reveal wait formula in as foam enhancing, suds-stabilizing agent, can improve the consistency of thickening material and the resistance to overturning of product.Dodecanamide propyl amine oxide to skin as mild as a dove, when as moisturizing, can be given skin smooth comfort.It,, compared with traditional thickening material 6501, has feature low-consuming, safe, that efficiency is high, wettability good, detergency is strong.
Sodium alkyl sulfate is a kind of anion surfactant of excellent property, has good decontamination washing, foam performance, and safety non-toxic, is now widely used in the daily chemical products such as toothpaste.
Sucrose fatty ester is edible nonionogenic tenside prepared by a kind of natural matter, can be widely used in foodstuffs industry, can play the effect of the steady bubble of thickening in this formulation product.
Disodium EDTA is a kind of complexing of metal ion agent of conventional safety and antioxidant synergist, stablizer.
Flos Lonicerae extractive solution has removing toxic substances, anti-inflammatory, virus killing, sterilization and antipruritic effect, especially streptococcus aureus, intestinal bacteria etc. is had to certain restraining effect.
Tableware detergent prepared by the present invention has strong detergency, suitable viscosity, good appearance, Phosphateless environmentally friendly, the advantage of safety; PH value is lower than product on present market simultaneously, little to skin irritation; And raw material sources are wide, simple process, without particular requirement, is easy to industrialization.In formula, all surface promoting agent is the tensio-active agent of green safety, and many nonionogenic tensides of having selected, therefore safer, gentle.Tea saponin under this formula is as main component simultaneously, can bring into play good decontamination washing and antibacterial bacteriostatic function.There is the effect of good wash dining set and gourd, fruit and vegetable, without any side effects.
The liquid detergent of green safety prepared by the present invention is compared with existing liquid detergent, formula rationally, wherein natural safety surface promoting agent tea saponin and green safety Surfactants Alkyl content are very high, play major surfaces promoting agent, raw material sources very abundant and belong to renewable resources, the raw materials used green safety material that is, be nontoxic gentle material, without any side effects to human body, this liquid detergent has good antibacterial bacteriostatic function, strong detergency, free from environmental pollution, use safety, well met the demand of current human consumer to green safety, therefore have good value for applications.
Embodiment
The liquid detergent of 1 one kinds of green safeties of embodiment
It adopts following formula:
Above-mentioned each component concentration percentage ratio sum equals 100%.
Being prepared as of described liquid detergent: deionized water is joined in stirring tank, by described weight percent configuration 100g liquid detergent, tea saponin 10g is dissolved in deionized water, be heated to 50 ℃, heated and stirred is even.After material dissolution, at this temperature, add while stirring alkyl glycoside 20g, dodecanamide propyl amine oxide 6g, stir, with citric acid or aqueous sodium hydroxide solution, adjust pH to 6.5, add deionized water and be settled to 100g, treat that solution is down to room temperature, obtain product.
The liquid detergent of 2 one kinds of green safeties of embodiment
It adopts following formula:
Above-mentioned each component concentration percentage ratio sum equals 100%.
Being prepared as of described liquid detergent: water is joined in stirring tank, by described weight percent configuration 100g liquid detergent, tea saponin 10g is dissolved in deionized water, be heated to 45 ℃, heated and stirred is even.After material dissolution, at this temperature, add while stirring alkyl glycoside 20g, sodium alkyl sulfate 1g, dodecanamide propyl amine oxide 6g, sucrose fatty ester 5g, disodium EDTA 0.1g, stir, by citric acid or aqueous sodium hydroxide solution adjustment pH value to 6, add water and be settled to 100g, treat that solution is down to room temperature, obtain product.
The liquid detergent of 3 one kinds of green safeties of embodiment
It adopts following formula:
Above-mentioned each component concentration percentage ratio sum equals 100%.
Being prepared as of described liquid detergent: deionized water is joined in stirring tank, by described weight percent configuration 100g liquid detergent, tea saponin 10g is dissolved in deionized water, be heated to 40 ℃, heated and stirred is even.After material dissolution, at this temperature, add while stirring alkyl glycoside 20g, sodium alkyl sulfate 1g, dodecanamide propyl amine oxide 6g, sucrose fatty ester 5g, disodium EDTA 0.1g, stir, by citric acid or aqueous sodium hydroxide solution adjustment pH value to 6, add water and be settled to 100g, treat that solution is down to room temperature, obtain product.
The liquid detergent of 4 one kinds of green safeties of embodiment
It adopts following formula:
Above-mentioned each component concentration percentage ratio sum equals 100%.
Being prepared as of described liquid detergent: deionized water is joined in stirring tank, by described weight percent configuration 100g liquid detergent, tea saponin 15g is dissolved in deionized water, be heated to 45 ℃, heated and stirred is even.After material dissolution, at this temperature, add while stirring alkyl glycoside 25g, sodium alkyl sulfate 1.5g, dodecanamide propyl amine oxide 3g, sucrose fatty ester 4g, disodium EDTA 0.1g, stir, by citric acid or aqueous sodium hydroxide solution adjustment pH value to 7.5, add water and be settled to 100g, treat that solution is down to room temperature, continue to add Flos Lonicerae extractive solution 6g, essence 0.2g, potassium sorbate 0.05g, obtain product.
The liquid detergent of 5 one kinds of green safeties of embodiment
It adopts following formula:
Above-mentioned each component concentration percentage ratio sum equals 100%.
Being prepared as of described liquid detergent: deionized water is joined in stirring tank, by described weight percent configuration 100g liquid detergent, tea saponin 20g is dissolved in deionized water, be heated to 50 ℃, heated and stirred is even.After material dissolution, at this temperature, add while stirring alkyl glycoside 15g, sodium alkyl sulfate 1.5g, dodecanamide propyl amine oxide 7g, sucrose fatty ester 5g, disodium EDTA 0.1g, stir, adjust pH value to 7.5, after solution is down to room temperature, continue to add Flos Lonicerae extractive solution 5g, essence 0.05g, Sodium Benzoate 0.05g, obtain product.
The liquid detergent of 6 one kinds of high-grade green safeties of embodiment
It adopts following formula:
Above-mentioned each component concentration percentage ratio sum equals 100%.
Being prepared as of described liquid detergent: deionized water is joined in stirring tank, by described weight percent configuration 100g liquid detergent, tea saponin 5g is dissolved in deionized water, be heated to 50 ℃, heated and stirred is even.After material dissolution, at this temperature, add while stirring alkyl glycoside 25g, sodium alkyl sulfate 3g, dodecanamide propyl amine oxide 8g, sucrose fatty ester 2g, disodium EDTA 0.1g, stir, adjust pH value to 7.5, after solution is down to room temperature, continue to add Flos Lonicerae extractive solution 6g, essence 0.01g, Kathon CG 0.15g, obtain product.
Can in formula range, produce on demand, not describe one by one herein.
Just the present invention will be further described for above-described embodiment, and its main purpose is in order to understand better content of the present invention.
Claims (4)
1. the preparation method of a liquid detergent, comprise the steps: by described weight percent, tea saponin 5～20% is dissolved in deionized water, be heated to 40～50 ℃, at this temperature, add while stirring alkyl glycoside 15～25%, dodecanamide propyl amine oxide 1～10%, stir, adjust pH value to 6～7.5 and get final product with citric acid or aqueous sodium hydroxide solution.
2. the preparation method of liquid detergent as claimed in claim 1, is characterized in that: when adding alkyl glycoside, dodecanamide propyl amine oxide, add the sucrose fatty ester that is no more than 6%.
3. the preparation method of liquid detergent as claimed in claim 1 or 2, is characterized in that: when adding alkyl glycoside, add to be no more than 3% sodium alkyl sulfate, to be no more than 0.1% disodium EDTA.
4. the preparation method of liquid detergent as claimed in claim 1 or 2, it is characterized in that: tea saponin is dissolved in deionized water, be heated to 40～50 ℃, at this temperature, add while stirring alkyl glycoside, dodecanamide propyl amine oxide, stir, after solution is down to room temperature, continue to add to be no more than 8% Flos Lonicerae extractive solution, to be no more than 0.2% essence, to be no more than 0.15% potassium sorbate, Sodium Benzoate or Kathon CG.
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| CN105255596A (en) * | 2015-10-29 | 2016-01-20 | 广州赛莱拉生物基因工程有限公司 | Antibacterial dish-washing detergent containing argy wormwood leaf extract |
| CN105482915A (en) * | 2016-02-01 | 2016-04-13 | 东莞品派实业投资有限公司 | Skin-protecting bactericidal cleanser essence |
| CN106086902A (en) * | 2016-08-05 | 2016-11-09 | 宁波高新区斯汀环保科技有限公司 | A kind of preparation method of environmental type water base metal cleaning agent |
| CN107955738A (en) * | 2017-12-04 | 2018-04-24 | 湖南金昌生物技术有限公司 | A kind of Tea Saponin neutrality vegetables and fruits cleaning agent and preparation method thereof |
| CN108130217A (en) * | 2017-12-04 | 2018-06-08 | 陈景英 | It is a kind of that there is the cleaning agent for dinnerware of handguard |
| CN113621447A (en) * | 2020-10-23 | 2021-11-09 | 湖南汉清生物技术有限公司 | Pollution-free dish washer is with imitateing tea saponin detergent by force and processing equipment thereof |
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| CN102517160A (en) * | 2011-12-07 | 2012-06-27 | 广州青能健日用品有限公司 | Biological environment-friendly antioxidant abluent and preparation method thereof |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105255596A (en) * | 2015-10-29 | 2016-01-20 | 广州赛莱拉生物基因工程有限公司 | Antibacterial dish-washing detergent containing argy wormwood leaf extract |
| CN105255596B (en) * | 2015-10-29 | 2018-07-10 | 广州赛莱拉生物基因工程有限公司 | A kind of Antibiotic liquid detergent containing Folium Artemisiae Argyi extract |
| CN105482915A (en) * | 2016-02-01 | 2016-04-13 | 东莞品派实业投资有限公司 | Skin-protecting bactericidal cleanser essence |
| CN106086902A (en) * | 2016-08-05 | 2016-11-09 | 宁波高新区斯汀环保科技有限公司 | A kind of preparation method of environmental type water base metal cleaning agent |
| CN107955738A (en) * | 2017-12-04 | 2018-04-24 | 湖南金昌生物技术有限公司 | A kind of Tea Saponin neutrality vegetables and fruits cleaning agent and preparation method thereof |
| CN108130217A (en) * | 2017-12-04 | 2018-06-08 | 陈景英 | It is a kind of that there is the cleaning agent for dinnerware of handguard |
| CN113621447A (en) * | 2020-10-23 | 2021-11-09 | 湖南汉清生物技术有限公司 | Pollution-free dish washer is with imitateing tea saponin detergent by force and processing equipment thereof |
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| CN103725439B (en) | 2015-08-19 |
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